The baobab, Adansonia digitata L. plays an important role in the economy of local populations. The oil from the seeds of the baobab fruit is nowadays highly prized because of its numerous cosmetic and therapeutic appl...The baobab, Adansonia digitata L. plays an important role in the economy of local populations. The oil from the seeds of the baobab fruit is nowadays highly prized because of its numerous cosmetic and therapeutic applications and its composition of unsaturated fatty acids, sterols and tocopherols. However, unlike refined oils, locally extracted baobab oil has not undergone purification operations to ensure its quality. Only a filtration on special cloths is carried out after decantation. Indeed, the oil obtained after pressing is cloudy because of the presence of various impurities. It therefore requires treatment operations to make it more attractive and of higher quality. Therefore, in order to provide innovative solutions to local companies to improve the quality of vegetable oils, a study of clarification (treatment) of crude oil is necessary. An experimental device has been developed in the laboratory. It includes a glass column and a filter bed of dune sand and activated carbon. This study has shown the efficiency of the experimental device. Indeed, the activated carbon, thanks to its adsorbing power, has allowed a significant decrease in turbidity at the 5% threshold, from 14.61 NTU for the raw oil to 0.08 NTU for the oil filtered on 3% carbon and 0.033 NTU for the oil filtered on 5% carbon. That is to say an abatement higher than 95%. This decrease in turbidity could be correlated with the decrease in brown index from 187.39<sup>a</sup> for the initial crude oil to 128.53<sup>d</sup> for the oil treated with 3% activated carbon versus 187.59<sup>a</sup> for the oil filtered on cloths. The lowest brown index was observed with the filtration using 5% activated carbon (35.99<sup>b</sup>). Thus, for the yellowness index, only the filtration on 5% charcoal allowed to obtain a significant decrease in yellowness. The yellowing index of the oil with 5% was 44.67<sup>b</sup> against 79.04<sup>a</sup> for the oil filtered with 3% activated carbon, 86.33<sup>a</sup> for the crude oil and 86.46<sup>a</sup> for the oil filtered on cloths. Finally, the oil sample treated with 5% activated carbon had the clearest clarity than the other samples with a clarity (L) equal to 97.98<sup>c</sup> against 95.63<sup>d</sup> for the oil treated with 3% carbon and 94.99<sup>b</sup> for the oil filtered on filter cloths. According to the results obtained, the experimental device made it possible to obtain a clearer baobab oil with a low brown index, thus improving the sensory quality of the oil.展开更多
Terpenoids have drawn much attention to scientists in synthesizing high-performance bio-jet fuels due to their ring structures,which feature potential high densities.Here,a facile biphasic catalytic process has been d...Terpenoids have drawn much attention to scientists in synthesizing high-performance bio-jet fuels due to their ring structures,which feature potential high densities.Here,a facile biphasic catalytic process has been developed for the production of high-density tricyclic hydrocarbon biofuels from a monoterpenoid,1,8-cineole,using sulfuric acid(H2SO4)as the homogeneous catalyst.A^100%conversion of 1,8-cineole and a>40%carbon yield of cyclic dimers were achieved at 100℃within two hours.The mechanism for the acid-catalyzed conversion of 1,8-cineole to cyclic hydrocarbon dimers were explored.In particular,the formation of the diene intermediates and the following dimerization of dienes was essential to synthesize tricyclic terpene dimers.The biphasic catalytic process accelerated the deoxygenation rate and enabled the dimerization with the aid of organic solvent while controlling the reaction rates to avoid the formation of solid residues.Moreover,this process also facilitated the product separation by organic solvent extraction while enabling easy recycle of the homogenous catalysts.展开更多
文摘The baobab, Adansonia digitata L. plays an important role in the economy of local populations. The oil from the seeds of the baobab fruit is nowadays highly prized because of its numerous cosmetic and therapeutic applications and its composition of unsaturated fatty acids, sterols and tocopherols. However, unlike refined oils, locally extracted baobab oil has not undergone purification operations to ensure its quality. Only a filtration on special cloths is carried out after decantation. Indeed, the oil obtained after pressing is cloudy because of the presence of various impurities. It therefore requires treatment operations to make it more attractive and of higher quality. Therefore, in order to provide innovative solutions to local companies to improve the quality of vegetable oils, a study of clarification (treatment) of crude oil is necessary. An experimental device has been developed in the laboratory. It includes a glass column and a filter bed of dune sand and activated carbon. This study has shown the efficiency of the experimental device. Indeed, the activated carbon, thanks to its adsorbing power, has allowed a significant decrease in turbidity at the 5% threshold, from 14.61 NTU for the raw oil to 0.08 NTU for the oil filtered on 3% carbon and 0.033 NTU for the oil filtered on 5% carbon. That is to say an abatement higher than 95%. This decrease in turbidity could be correlated with the decrease in brown index from 187.39<sup>a</sup> for the initial crude oil to 128.53<sup>d</sup> for the oil treated with 3% activated carbon versus 187.59<sup>a</sup> for the oil filtered on cloths. The lowest brown index was observed with the filtration using 5% activated carbon (35.99<sup>b</sup>). Thus, for the yellowness index, only the filtration on 5% charcoal allowed to obtain a significant decrease in yellowness. The yellowing index of the oil with 5% was 44.67<sup>b</sup> against 79.04<sup>a</sup> for the oil filtered with 3% activated carbon, 86.33<sup>a</sup> for the crude oil and 86.46<sup>a</sup> for the oil filtered on cloths. Finally, the oil sample treated with 5% activated carbon had the clearest clarity than the other samples with a clarity (L) equal to 97.98<sup>c</sup> against 95.63<sup>d</sup> for the oil treated with 3% carbon and 94.99<sup>b</sup> for the oil filtered on filter cloths. According to the results obtained, the experimental device made it possible to obtain a clearer baobab oil with a low brown index, thus improving the sensory quality of the oil.
文摘Terpenoids have drawn much attention to scientists in synthesizing high-performance bio-jet fuels due to their ring structures,which feature potential high densities.Here,a facile biphasic catalytic process has been developed for the production of high-density tricyclic hydrocarbon biofuels from a monoterpenoid,1,8-cineole,using sulfuric acid(H2SO4)as the homogeneous catalyst.A^100%conversion of 1,8-cineole and a>40%carbon yield of cyclic dimers were achieved at 100℃within two hours.The mechanism for the acid-catalyzed conversion of 1,8-cineole to cyclic hydrocarbon dimers were explored.In particular,the formation of the diene intermediates and the following dimerization of dienes was essential to synthesize tricyclic terpene dimers.The biphasic catalytic process accelerated the deoxygenation rate and enabled the dimerization with the aid of organic solvent while controlling the reaction rates to avoid the formation of solid residues.Moreover,this process also facilitated the product separation by organic solvent extraction while enabling easy recycle of the homogenous catalysts.
文摘通过单因素试验和正交试验,研究了果胶酶对柚子汁的澄清工艺.单因素试验结果表明,果胶酶用量为0.08～0.10 g/L,pH值为3.0～4.0,温度为25～35℃,酶解时间为1.5～2.5h条件下,果胶酶对柚子汁澄清处理的效果较好,果汁中的可溶性固形物含量基本不变.正交试验得到的果胶酶澄清柚子汁的最佳工艺条件为果胶酶用量0.09 g/L,最适pH值为3.5,酶解温度25℃,酶解时间1.5 h.
