Aqueous zinc metal batteries(AZMBs)are promising candidates for next-generation energy storage due to the excellent safety, environmental friendliness, natural abundance, high theoretical specific capacity, and low re...Aqueous zinc metal batteries(AZMBs)are promising candidates for next-generation energy storage due to the excellent safety, environmental friendliness, natural abundance, high theoretical specific capacity, and low redox potential of zinc(Zn) metal. However,several issues such as dendrite formation, hydrogen evolution, corrosion, and passivation of Zn metal anodes cause irreversible loss of the active materials. To solve these issues, researchers often use large amounts of excess Zn to ensure a continuous supply of active materials for Zn anodes. This leads to the ultralow utilization of Zn anodes and squanders the high energy density of AZMBs. Herein, the design strategies for AZMBs with high Zn utilization are discussed in depth, from utilizing thinner Zn foils to constructing anode-free structures with theoretical Zn utilization of 100%, which provides comprehensive guidelines for further research. Representative methods for calculating the depth of discharge of Zn anodes with different structures are first summarized. The reasonable modification strategies of Zn foil anodes, current collectors with pre-deposited Zn, and anode-free aqueous Zn metal batteries(AF-AZMBs) to improve Zn utilization are then detailed. In particular, the working mechanism of AF-AZMBs is systematically introduced. Finally, the challenges and perspectives for constructing high-utilization Zn anodes are presented.展开更多
Edible fungi are large fungi with high added value that can be utilized as resources.They are rich in high-quality protein,carbohydrate,various vitamins,mineral elements and other nutrients,and are characterized by hi...Edible fungi are large fungi with high added value that can be utilized as resources.They are rich in high-quality protein,carbohydrate,various vitamins,mineral elements and other nutrients,and are characterized by high protein,low sugar,low fat and low cholesterol.In addition,edible fungi contain a variety of bioactive substances,such as polysaccharides,dietary fiber,steroids,polyphenols,and most of these compounds have antioxidant,anti-tumor and other physiological functions.This review comprehensively discusses the bioactive components and functional characteristics of edible fungi(such as antioxidant,anti-aging,hypolipidemic activities,etc.).Then the recent developments and prospect in the high-valued utilization of edible fungi are discussed and summarized.The objective of this review is to improve the understanding of health-promoting properties of edible fungi,and provide reference for the industrial production of edible fungi-based health products.展开更多
Pilbara blending iron ore powder （PB powder） is blending ores with good and poor quality iron ores, so how to use PB power effectively is a problem. The self-characteristics of PB powder and its single-components we...Pilbara blending iron ore powder （PB powder） is blending ores with good and poor quality iron ores, so how to use PB power effectively is a problem. The self-characteristics of PB powder and its single-components were studied respectively such as the macroscopic properties, microscopic properties, and high-temperature properties the behavior and effect in the sintering were mastered. Then based on the new ore-proportioning idea of iron ores sintering characteristics complementary, the principles on the effective use of PB powder were discussed, and was fur ther validated through the sintering pot test and industrial production. The results show that PB powder is composed of three kinds of iron ore, and the sintering characteristics of different iron ores are obviously discrepant. With the ore-proportioning optimization based on the iron ores sintering characteristics complementary, the proportion of PB iron ore powder can be increased to more than 45 %.展开更多
Direct collection of uranium from low uranium systems via adsorption remains challenging.Fibrous sorbent materials with amidoxime(AO)groups are promising adsorbents for uranium extraction from seawater.However,low AO ...Direct collection of uranium from low uranium systems via adsorption remains challenging.Fibrous sorbent materials with amidoxime(AO)groups are promising adsorbents for uranium extraction from seawater.However,low AO adsorption group utilization remains an issue.We herein fabricated a branched structure containing AO groups on polypropylene/polyethylene spun-laced nonwoven(PP/PE SNW)fibers using grafting polymerization induced by radiation(RIGP)to improve AO utilization.The chemical structures,thermal properties,and surface morphologies of the raw and treated PP/PE SNW fibers were studied.The results show that an adsorptive functional layer with a branching structure was successfully anchored to the fiber surface.The adsorption properties were investigated using batch adsorption experiments in simulated seawater with an initial uranium concentration of 500μg·L^(−1)(pH 4,25℃).The maximum adsorption capacity of the adsorbent material was 137.3 mg·g^(−1)within 24 h;moreover,the uranyl removal reached 96%within 240 min.The adsorbent had an AO utilization rate of 1/3.5 and was stable over a pH range of 4–10,with good selectivity and reusability,demonstrating its potential for seawater uranium extraction.展开更多
Evolutionary algorithms(EAs)have been used in high utility itemset mining(HUIM)to address the problem of discover-ing high utility itemsets(HUIs)in the exponential search space.EAs have good running and mining perform...Evolutionary algorithms(EAs)have been used in high utility itemset mining(HUIM)to address the problem of discover-ing high utility itemsets(HUIs)in the exponential search space.EAs have good running and mining performance,but they still require huge computational resource and may miss many HUIs.Due to the good combination of EA and graphics processing unit(GPU),we propose a parallel genetic algorithm(GA)based on the platform of GPU for mining HUIM(PHUI-GA).The evolution steps with improvements are performed in central processing unit(CPU)and the CPU intensive steps are sent to GPU to eva-luate with multi-threaded processors.Experiments show that the mining performance of PHUI-GA outperforms the existing EAs.When mining 90%HUIs,the PHUI-GA is up to 188 times better than the existing EAs and up to 36 times better than the CPU parallel approach.展开更多
China is short of potassium resources, it only produces about 30 t of potash fertilizers per year. While China used about 650 t of potash fertilizer in 2000 by importing more than 95% of its potash fertilizers from Ca...China is short of potassium resources, it only produces about 30 t of potash fertilizers per year. While China used about 650 t of potash fertilizer in 2000 by importing more than 95% of its potash fertilizers from Canada or Europe. So, using varieties with high K utilization efficiency was very important.展开更多
Coal fly ash is an industrial by-product generated during the combustion of coal for energy production. Due to the increasing annual consumption of coal power and the serious potential environmental threats of coal fl...Coal fly ash is an industrial by-product generated during the combustion of coal for energy production. Due to the increasing annual consumption of coal power and the serious potential environmental threats of coal fly ash, a considerable amount of research on the utilization of coal fly ash has been undertaken worldwide. Vitrification seems to be one of the most promising options for reusing this industrial waste. This paper presents a short overview of the production of unique high performance glass-ceramics using coal fly ash as a raw material. A detailed description of the methodologies for the synthesis of glass-ceramics from coal fly ash and the principal crystal phases, corresponding property and possible usage of those materials are introduced. Investigations revealed that converting coal fly ash into high performance glass-ceramic materials is a promising new approach to improve the utilization of this industrial by-product. This conversion not only alleviates the problems with disposal but also converts a waste material into a high value-added marketable commodity.展开更多
Light-field displays typically consist of a two-dimensional(2D)display panel and a light modulation device.The 2D panel presents synthesized parallax images,with the total information content of the three-dimensional(...Light-field displays typically consist of a two-dimensional(2D)display panel and a light modulation device.The 2D panel presents synthesized parallax images,with the total information content of the three-dimensional(3D)light feld dictated by the panel's total resolution.Angular resolution serves as a critical metric for light-field displays,where higher angular resolution correlates with a more realistic 3D visual experience.However,the improvement of angular resolution is typically accompanied by a reduction in spatial resolution,due to the limitations of the 2D display panel's total resolution.To address this challenge,a light-feld display method with enhanced information utilization is introduced,achieved through the independent modulation of chrominance and luminance.A static light-field image display system is proposed to verify the feasibility of this method.The system employs a bidirectional angular modulation grating(BAMG)and a collimated light source(CLS)to create uniformly distributed viewpoints in space.A luminance modulation film(LMF)and a chrominance modulation film(CMF)are utilized to modulate the light-field information,with chrominance and luminance synthesized images printed at pixel densities of 720 pixels per inch(PPl)and 8000 dots per inch(DPl),respectively,to align with the differential sensitivities of the human visual system.In the experiment,the proposed display system achieves a full-parallax,high-fidelity color display with a 98.2°horizontal and 97.7°vertical field of view(FOV).So,the light-feld display method of modulating chrominance and luminance separately has been proven to achieve high-fidelity display effects.展开更多
A new sterile line UP-3s, which carries the Dominant Early Maturity Gene (DEMG), was bred on the farm of University of Arkansas at Pine Bluff (UAPB). UP-3s and two check sterile lines, Jin23-A and Xie-A which do not c...A new sterile line UP-3s, which carries the Dominant Early Maturity Gene (DEMG), was bred on the farm of University of Arkansas at Pine Bluff (UAPB). UP-3s and two check sterile lines, Jin23-A and Xie-A which do not carry the Dominant Early Maturity Gene, were crossed with a group of different maturity restorer lines, PB-1R, PB-5R,PB11, PB-13R, PB-20, PB-21, PB-22R, and PB-23R. Eighteen new hybrid rice combinations of these crosses were then tested at UAPB in 2012 and 2013. The results showed that panicle differentiation (PD) of hybrids from female parent UP-3s (DEMG) crossed with the 8 male parents, were earlier than the hybrids from female parent Jin23-A or Xie-A crossed with the 8 male parents. The PD of these earlier hybrids was before Jun 25 and heading was before July 20. Early PD and heading avoided the high temperature (over 34°C) period which usually occurs after July 20 in Arkansas. The yields of these earlier maturity hybrids with female parent UP-3s were higher than those of the late maturity hybrids thatwereF1 progeny of sterile lines Jin23-A or Xie-A (these two female parent checks with non-DEMG). These results showed that the DEMG sterile line UP-3s can be adopted in making crosses with later maturity restorer lines to obtain earlier maturity hybrids to avoid the high temperature period in Arkansas.展开更多
This paper explores the integrated utilization of low-grade thermal energy in hot coal mines, based on analysis of original heating, refrigerating, mine draining, bath draining and air exhaust systems, and in combinat...This paper explores the integrated utilization of low-grade thermal energy in hot coal mines, based on analysis of original heating, refrigerating, mine draining, bath draining and air exhaust systems, and in combination with the actual conditions of Tangkou Coal Mine in Shandong Province. It presents a set of comprehensive and integrated utilization schemes for the various different kinds of low quality heat energy. With heat pumps, the recycling of the low quality heat energy from the drainage, bathing water and the exhaust air can occur in winter, and in summer, there exists condensed heat of the refrigerating system. When in conjunction with solar collectors, the thermal utilization of solar power can be realized for the whole year. The system achieves mine drainage and bathing water purification and recycling, as well as purifying exhaust air by water spraying. It also satisfies the demands of a whole year＇s bathing heat for the coal mine, with refrigeration in summer, and heating for the ground house and shaft house in winter. It is able to integrate different kinds of low quality heat energy and low emission drainage and dust, and can replace the traditional boiler heating system. Finally, the system reduces conventional energy consumption and the amount of mine water drainage.展开更多
The yield potential of current rice varieties has reached a high plateau and fluc-tuated within a narrow range. Based on the theory and practice of rice breedingfor super-high-yield, we put forward a concept of "...The yield potential of current rice varieties has reached a high plateau and fluc-tuated within a narrow range. Based on the theory and practice of rice breedingfor super-high-yield, we put forward a concept of " Two high and one early",which means high biomass and high efficiency of light energy conversion, as wellas fast growing in the early growth stage. The agronomic characters of 15 U. S展开更多
With the rapid development of Camellia oleifera industry, more and more Camellia nut shells have been produced, leading to serious environmental pollution problem. This paper reviews the works on the characterization ...With the rapid development of Camellia oleifera industry, more and more Camellia nut shells have been produced, leading to serious environmental pollution problem. This paper reviews the works on the characterization of the physical and chemical properties of Camellia nut shells, active ingredient extraction, its application in chemical production, growing media and animal feed and its properties as a biomass. Based on the review, we proposed a novel all-component high value application strategy to covert camellia nut shells into high value biomasses, which could realize waste recycling and environmental protection.展开更多
Preparation of high purity ruthenium nitrosyl nitrate using spent Ru-Zn/ZrO_(2)catalyst was studied,including melting and leaching to obtain potassium ruthenate solution,reduction,dissolving,concentrating and drying t...Preparation of high purity ruthenium nitrosyl nitrate using spent Ru-Zn/ZrO_(2)catalyst was studied,including melting and leaching to obtain potassium ruthenate solution,reduction,dissolving,concentrating and drying to obtain ruthenium trichloride,nitrosation and hydrolysis to obtain ruthenium nitrosyl hydroxide,removing of K^(+)and Cl^(-),and neutralization with nitric acid.The effects of temperature,concentration,time and pH on the yield and purity of intermediates and final product were studied,and the optimum process conditions were obtained.The yield of ruthenium nitrosyl nitrate is 92%,the content of ruthenium in high purity product is 32.16%,and the content of Cl^(-)and K^(+)are much less than 0.005%.The reaction kinetics of ruthenium nitrosyl chloride to ruthenium nitrosyl hydroxide was studied.The reaction orders of Ru(NO)Cl_(3)at 40,55 and 70℃are 0.39,0.37 and 0.39,respectively,while those of KOH are 0.16,0.15 and 0.17,respectively.The activation energy is-2.33 k J/mol.展开更多
The formation mechanism of high salinity geothermal water is significant for utilizing geothermal resources and mineral resources.The high salinity in geothermal water may be derived from the geothermal mother fluid o...The formation mechanism of high salinity geothermal water is significant for utilizing geothermal resources and mineral resources.The high salinity in geothermal water may be derived from the geothermal mother fluid or from the evaporite dissolution.It is difficult to distinguish between these two sources because they may have similar hydrochemistry.In this paper,water chemistry and stable isotopes were used to explore the high salinity geothermal water in Yanchanghe geothermal field,central China.It is a lowtemperature hydrothermal system in the inland karst area.The thermal water is Cl-Na type with high salinity(TDS>8,400 mg/L).The modified silicon thermometer is more suitable and the reasonable result is about 58.8℃.The maximum circulation depth is 1.9 km.Using the temperature of hot and cold water to estimate the mixing ratio is 58%-81%.Saturation index(SI),Na/1000-K/100-Mg1/2 and Gibbs diagram suggest that the main source of salt in geothermal water is derived from the evaporite dissolution,which provides Cl-of 11,264-31,279 mg/L and Na+of 9,272-21,236 mg/L.We found the combination of temperature and hydrogeochemistry can be used to investigate the formation mechanism and mixing process of high-salinity geothermal water formed in a karst low-temperature hydrothermal system.展开更多
基金the financial support from the National Natural Science Foundation of China (Grant Nos. 52201201, 52372171)the State Key Lab of Advanced Metals and Materials (Grant No. 2022Z-11)+1 种基金the Fundamental Research Funds for the Central Universities (Grant No. 00007747, 06500205)the Initiative Postdocs Supporting Program (Grant No. BX20190002)。
文摘Aqueous zinc metal batteries(AZMBs)are promising candidates for next-generation energy storage due to the excellent safety, environmental friendliness, natural abundance, high theoretical specific capacity, and low redox potential of zinc(Zn) metal. However,several issues such as dendrite formation, hydrogen evolution, corrosion, and passivation of Zn metal anodes cause irreversible loss of the active materials. To solve these issues, researchers often use large amounts of excess Zn to ensure a continuous supply of active materials for Zn anodes. This leads to the ultralow utilization of Zn anodes and squanders the high energy density of AZMBs. Herein, the design strategies for AZMBs with high Zn utilization are discussed in depth, from utilizing thinner Zn foils to constructing anode-free structures with theoretical Zn utilization of 100%, which provides comprehensive guidelines for further research. Representative methods for calculating the depth of discharge of Zn anodes with different structures are first summarized. The reasonable modification strategies of Zn foil anodes, current collectors with pre-deposited Zn, and anode-free aqueous Zn metal batteries(AF-AZMBs) to improve Zn utilization are then detailed. In particular, the working mechanism of AF-AZMBs is systematically introduced. Finally, the challenges and perspectives for constructing high-utilization Zn anodes are presented.
基金This review was financially supported by the Key Projects of the National Research and Development Program of China(Grant No.2018YFD0400204).
文摘Edible fungi are large fungi with high added value that can be utilized as resources.They are rich in high-quality protein,carbohydrate,various vitamins,mineral elements and other nutrients,and are characterized by high protein,low sugar,low fat and low cholesterol.In addition,edible fungi contain a variety of bioactive substances,such as polysaccharides,dietary fiber,steroids,polyphenols,and most of these compounds have antioxidant,anti-tumor and other physiological functions.This review comprehensively discusses the bioactive components and functional characteristics of edible fungi(such as antioxidant,anti-aging,hypolipidemic activities,etc.).Then the recent developments and prospect in the high-valued utilization of edible fungi are discussed and summarized.The objective of this review is to improve the understanding of health-promoting properties of edible fungi,and provide reference for the industrial production of edible fungi-based health products.
文摘Pilbara blending iron ore powder （PB powder） is blending ores with good and poor quality iron ores, so how to use PB power effectively is a problem. The self-characteristics of PB powder and its single-components were studied respectively such as the macroscopic properties, microscopic properties, and high-temperature properties the behavior and effect in the sintering were mastered. Then based on the new ore-proportioning idea of iron ores sintering characteristics complementary, the principles on the effective use of PB powder were discussed, and was fur ther validated through the sintering pot test and industrial production. The results show that PB powder is composed of three kinds of iron ore, and the sintering characteristics of different iron ores are obviously discrepant. With the ore-proportioning optimization based on the iron ores sintering characteristics complementary, the proportion of PB iron ore powder can be increased to more than 45 %.
基金supported by the National Natural Science Foundation of China(Nos.11675247,22176194).
文摘Direct collection of uranium from low uranium systems via adsorption remains challenging.Fibrous sorbent materials with amidoxime(AO)groups are promising adsorbents for uranium extraction from seawater.However,low AO adsorption group utilization remains an issue.We herein fabricated a branched structure containing AO groups on polypropylene/polyethylene spun-laced nonwoven(PP/PE SNW)fibers using grafting polymerization induced by radiation(RIGP)to improve AO utilization.The chemical structures,thermal properties,and surface morphologies of the raw and treated PP/PE SNW fibers were studied.The results show that an adsorptive functional layer with a branching structure was successfully anchored to the fiber surface.The adsorption properties were investigated using batch adsorption experiments in simulated seawater with an initial uranium concentration of 500μg·L^(−1)(pH 4,25℃).The maximum adsorption capacity of the adsorbent material was 137.3 mg·g^(−1)within 24 h;moreover,the uranyl removal reached 96%within 240 min.The adsorbent had an AO utilization rate of 1/3.5 and was stable over a pH range of 4–10,with good selectivity and reusability,demonstrating its potential for seawater uranium extraction.
基金This work was supported by the National Natural Science Foundation of China(62073155,62002137,62106088,62206113)the High-End Foreign Expert Recruitment Plan(G2023144007L)the Fundamental Research Funds for the Central Universities(JUSRP221028).
文摘Evolutionary algorithms(EAs)have been used in high utility itemset mining(HUIM)to address the problem of discover-ing high utility itemsets(HUIs)in the exponential search space.EAs have good running and mining performance,but they still require huge computational resource and may miss many HUIs.Due to the good combination of EA and graphics processing unit(GPU),we propose a parallel genetic algorithm(GA)based on the platform of GPU for mining HUIM(PHUI-GA).The evolution steps with improvements are performed in central processing unit(CPU)and the CPU intensive steps are sent to GPU to eva-luate with multi-threaded processors.Experiments show that the mining performance of PHUI-GA outperforms the existing EAs.When mining 90%HUIs,the PHUI-GA is up to 188 times better than the existing EAs and up to 36 times better than the CPU parallel approach.
文摘China is short of potassium resources, it only produces about 30 t of potash fertilizers per year. While China used about 650 t of potash fertilizer in 2000 by importing more than 95% of its potash fertilizers from Canada or Europe. So, using varieties with high K utilization efficiency was very important.
基金financial support of the project from the National Natural Science Foundation of China, China (No. 51172016)
文摘Coal fly ash is an industrial by-product generated during the combustion of coal for energy production. Due to the increasing annual consumption of coal power and the serious potential environmental threats of coal fly ash, a considerable amount of research on the utilization of coal fly ash has been undertaken worldwide. Vitrification seems to be one of the most promising options for reusing this industrial waste. This paper presents a short overview of the production of unique high performance glass-ceramics using coal fly ash as a raw material. A detailed description of the methodologies for the synthesis of glass-ceramics from coal fly ash and the principal crystal phases, corresponding property and possible usage of those materials are introduced. Investigations revealed that converting coal fly ash into high performance glass-ceramic materials is a promising new approach to improve the utilization of this industrial by-product. This conversion not only alleviates the problems with disposal but also converts a waste material into a high value-added marketable commodity.
基金supported by the National Key Research and Development Program of China(2023YFB3611500)National Natural Science Foundation of China(62175015,62335002,62075016).
文摘Light-field displays typically consist of a two-dimensional(2D)display panel and a light modulation device.The 2D panel presents synthesized parallax images,with the total information content of the three-dimensional(3D)light feld dictated by the panel's total resolution.Angular resolution serves as a critical metric for light-field displays,where higher angular resolution correlates with a more realistic 3D visual experience.However,the improvement of angular resolution is typically accompanied by a reduction in spatial resolution,due to the limitations of the 2D display panel's total resolution.To address this challenge,a light-feld display method with enhanced information utilization is introduced,achieved through the independent modulation of chrominance and luminance.A static light-field image display system is proposed to verify the feasibility of this method.The system employs a bidirectional angular modulation grating(BAMG)and a collimated light source(CLS)to create uniformly distributed viewpoints in space.A luminance modulation film(LMF)and a chrominance modulation film(CMF)are utilized to modulate the light-field information,with chrominance and luminance synthesized images printed at pixel densities of 720 pixels per inch(PPl)and 8000 dots per inch(DPl),respectively,to align with the differential sensitivities of the human visual system.In the experiment,the proposed display system achieves a full-parallax,high-fidelity color display with a 98.2°horizontal and 97.7°vertical field of view(FOV).So,the light-feld display method of modulating chrominance and luminance separately has been proven to achieve high-fidelity display effects.
文摘A new sterile line UP-3s, which carries the Dominant Early Maturity Gene (DEMG), was bred on the farm of University of Arkansas at Pine Bluff (UAPB). UP-3s and two check sterile lines, Jin23-A and Xie-A which do not carry the Dominant Early Maturity Gene, were crossed with a group of different maturity restorer lines, PB-1R, PB-5R,PB11, PB-13R, PB-20, PB-21, PB-22R, and PB-23R. Eighteen new hybrid rice combinations of these crosses were then tested at UAPB in 2012 and 2013. The results showed that panicle differentiation (PD) of hybrids from female parent UP-3s (DEMG) crossed with the 8 male parents, were earlier than the hybrids from female parent Jin23-A or Xie-A crossed with the 8 male parents. The PD of these earlier hybrids was before Jun 25 and heading was before July 20. Early PD and heading avoided the high temperature (over 34°C) period which usually occurs after July 20 in Arkansas. The yields of these earlier maturity hybrids with female parent UP-3s were higher than those of the late maturity hybrids thatwereF1 progeny of sterile lines Jin23-A or Xie-A (these two female parent checks with non-DEMG). These results showed that the DEMG sterile line UP-3s can be adopted in making crosses with later maturity restorer lines to obtain earlier maturity hybrids to avoid the high temperature period in Arkansas.
文摘This paper explores the integrated utilization of low-grade thermal energy in hot coal mines, based on analysis of original heating, refrigerating, mine draining, bath draining and air exhaust systems, and in combination with the actual conditions of Tangkou Coal Mine in Shandong Province. It presents a set of comprehensive and integrated utilization schemes for the various different kinds of low quality heat energy. With heat pumps, the recycling of the low quality heat energy from the drainage, bathing water and the exhaust air can occur in winter, and in summer, there exists condensed heat of the refrigerating system. When in conjunction with solar collectors, the thermal utilization of solar power can be realized for the whole year. The system achieves mine drainage and bathing water purification and recycling, as well as purifying exhaust air by water spraying. It also satisfies the demands of a whole year＇s bathing heat for the coal mine, with refrigeration in summer, and heating for the ground house and shaft house in winter. It is able to integrate different kinds of low quality heat energy and low emission drainage and dust, and can replace the traditional boiler heating system. Finally, the system reduces conventional energy consumption and the amount of mine water drainage.
文摘The yield potential of current rice varieties has reached a high plateau and fluc-tuated within a narrow range. Based on the theory and practice of rice breedingfor super-high-yield, we put forward a concept of " Two high and one early",which means high biomass and high efficiency of light energy conversion, as wellas fast growing in the early growth stage. The agronomic characters of 15 U. S
文摘With the rapid development of Camellia oleifera industry, more and more Camellia nut shells have been produced, leading to serious environmental pollution problem. This paper reviews the works on the characterization of the physical and chemical properties of Camellia nut shells, active ingredient extraction, its application in chemical production, growing media and animal feed and its properties as a biomass. Based on the review, we proposed a novel all-component high value application strategy to covert camellia nut shells into high value biomasses, which could realize waste recycling and environmental protection.
基金Project(22178392)supported by the National Natural Science Foundation of China。
文摘Preparation of high purity ruthenium nitrosyl nitrate using spent Ru-Zn/ZrO_(2)catalyst was studied,including melting and leaching to obtain potassium ruthenate solution,reduction,dissolving,concentrating and drying to obtain ruthenium trichloride,nitrosation and hydrolysis to obtain ruthenium nitrosyl hydroxide,removing of K^(+)and Cl^(-),and neutralization with nitric acid.The effects of temperature,concentration,time and pH on the yield and purity of intermediates and final product were studied,and the optimum process conditions were obtained.The yield of ruthenium nitrosyl nitrate is 92%,the content of ruthenium in high purity product is 32.16%,and the content of Cl^(-)and K^(+)are much less than 0.005%.The reaction kinetics of ruthenium nitrosyl chloride to ruthenium nitrosyl hydroxide was studied.The reaction orders of Ru(NO)Cl_(3)at 40,55 and 70℃are 0.39,0.37 and 0.39,respectively,while those of KOH are 0.16,0.15 and 0.17,respectively.The activation energy is-2.33 k J/mol.
基金supported by the National Natural Science Foundation of China(Grant number:41440027)。
文摘The formation mechanism of high salinity geothermal water is significant for utilizing geothermal resources and mineral resources.The high salinity in geothermal water may be derived from the geothermal mother fluid or from the evaporite dissolution.It is difficult to distinguish between these two sources because they may have similar hydrochemistry.In this paper,water chemistry and stable isotopes were used to explore the high salinity geothermal water in Yanchanghe geothermal field,central China.It is a lowtemperature hydrothermal system in the inland karst area.The thermal water is Cl-Na type with high salinity(TDS>8,400 mg/L).The modified silicon thermometer is more suitable and the reasonable result is about 58.8℃.The maximum circulation depth is 1.9 km.Using the temperature of hot and cold water to estimate the mixing ratio is 58%-81%.Saturation index(SI),Na/1000-K/100-Mg1/2 and Gibbs diagram suggest that the main source of salt in geothermal water is derived from the evaporite dissolution,which provides Cl-of 11,264-31,279 mg/L and Na+of 9,272-21,236 mg/L.We found the combination of temperature and hydrogeochemistry can be used to investigate the formation mechanism and mixing process of high-salinity geothermal water formed in a karst low-temperature hydrothermal system.
