Photoelectrocatalysis(PEC)is a promising approach that can convert renewable solar energy into chemical energy,while most concern is concentrated on PEC water splitting to obtain high‐value‐added fuel—hydrogen.In p...Photoelectrocatalysis(PEC)is a promising approach that can convert renewable solar energy into chemical energy,while most concern is concentrated on PEC water splitting to obtain high‐value‐added fuel—hydrogen.In practice,more economic benefits can be produced based on PEC technique,such as H_(2)O oxidative H_(2)O_(2) synthesis,organic selective oxidation,organic pollutants degradation and CO_(2) reduction.Although there are plenty of excellent reviews focusing on the PEC water splitting system,the production of various high‐value‐added chemicals in PEC systems has not been discussed synthetically.This Account will focus on the production process of various high‐value‐added chemicals through PEC technology.The photoelectrode design,reaction environment and working mechanisms of PEC systems are also discussed in detail.We believe that this comprehensive Account of the expanded application of photoelectrocatalysis can add an inestimable impetus to the follow‐up development of this technology.展开更多
The leather manufacture, with a history of thousands of years, is a sustainable industry that converts animal hides and skins, the by-products of meat industry, into high-value-added products, leather. According to th...The leather manufacture, with a history of thousands of years, is a sustainable industry that converts animal hides and skins, the by-products of meat industry, into high-value-added products, leather. According to the statistics of the Food and Agriculture Organization of the United Nations, there were an average of 3.82 billion cattle, sheep and goats in stock and 1.37 billion cattle, sheep and goats slaughtered around the world in each year during 2014–2023.展开更多
In 2024,the global market share of Korean shipbuilding industry further declined,and the global market share of newbuild orderbook fell to less than 20% in terms of CGT,and its competitive advantages weakened in multi...In 2024,the global market share of Korean shipbuilding industry further declined,and the global market share of newbuild orderbook fell to less than 20% in terms of CGT,and its competitive advantages weakened in multiple high value-added shipbuilding markets.展开更多
China is the largest producer and consumer of calcium carbide in the world.The calcium carbide industry is an indispensable industry to support the basic life of people.The huge production capacity of calcium carbide ...China is the largest producer and consumer of calcium carbide in the world.The calcium carbide industry is an indispensable industry to support the basic life of people.The huge production capacity of calcium carbide is accompanied by a large number of solid waste carbide slag.Due to the immature treatment technology of carbide slag,a large number of carbide slag are stacked on-site,resulting in land occupation,air-drying,easy take-off ash,and pollution of the environment and water resources.In China,calcium carbide is mainly used to produce acetylene and further utilized,80%of which is used to produce polyvinyl chloride(PVC).A large amount of carbide slag is not used,while only a small part is used in the traditional building materials industry,flue gas desulfurization,sewage treatment,etc.,however,the economic benefits are poor.Therefore,converting the solid waste carbide slag produced by the calcium carbide industry into high value-added CaCO3,CaCl2,CaSO4 whiskers,etc.has become a potential way to expand the development field of the calcium carbide industry and is environmentally friendly.This paper focuses on summarizing the traditional and emerging high value-added utiliza-tion technologies of carbide slag,and then introduces the application research of carbide slag in carbon emission reduction.Finally,the defects of these technologies are summarized and further research directions are prospected.This study provides basic guidance for the diversified development of efficient resource utilization of carbide slag.Graphical abstract Diversified development of calcium carbide industry,resource utilization of solid waste carbide slag and its application of carbon emission reduction have been fully reviewed.展开更多
文摘Photoelectrocatalysis(PEC)is a promising approach that can convert renewable solar energy into chemical energy,while most concern is concentrated on PEC water splitting to obtain high‐value‐added fuel—hydrogen.In practice,more economic benefits can be produced based on PEC technique,such as H_(2)O oxidative H_(2)O_(2) synthesis,organic selective oxidation,organic pollutants degradation and CO_(2) reduction.Although there are plenty of excellent reviews focusing on the PEC water splitting system,the production of various high‐value‐added chemicals in PEC systems has not been discussed synthetically.This Account will focus on the production process of various high‐value‐added chemicals through PEC technology.The photoelectrode design,reaction environment and working mechanisms of PEC systems are also discussed in detail.We believe that this comprehensive Account of the expanded application of photoelectrocatalysis can add an inestimable impetus to the follow‐up development of this technology.
文摘The leather manufacture, with a history of thousands of years, is a sustainable industry that converts animal hides and skins, the by-products of meat industry, into high-value-added products, leather. According to the statistics of the Food and Agriculture Organization of the United Nations, there were an average of 3.82 billion cattle, sheep and goats in stock and 1.37 billion cattle, sheep and goats slaughtered around the world in each year during 2014–2023.
文摘In 2024,the global market share of Korean shipbuilding industry further declined,and the global market share of newbuild orderbook fell to less than 20% in terms of CGT,and its competitive advantages weakened in multiple high value-added shipbuilding markets.
基金The authors would like to acknowledge the support from the National Natural Science Foundation of China(Nos.51876150 and 21736008).
文摘China is the largest producer and consumer of calcium carbide in the world.The calcium carbide industry is an indispensable industry to support the basic life of people.The huge production capacity of calcium carbide is accompanied by a large number of solid waste carbide slag.Due to the immature treatment technology of carbide slag,a large number of carbide slag are stacked on-site,resulting in land occupation,air-drying,easy take-off ash,and pollution of the environment and water resources.In China,calcium carbide is mainly used to produce acetylene and further utilized,80%of which is used to produce polyvinyl chloride(PVC).A large amount of carbide slag is not used,while only a small part is used in the traditional building materials industry,flue gas desulfurization,sewage treatment,etc.,however,the economic benefits are poor.Therefore,converting the solid waste carbide slag produced by the calcium carbide industry into high value-added CaCO3,CaCl2,CaSO4 whiskers,etc.has become a potential way to expand the development field of the calcium carbide industry and is environmentally friendly.This paper focuses on summarizing the traditional and emerging high value-added utiliza-tion technologies of carbide slag,and then introduces the application research of carbide slag in carbon emission reduction.Finally,the defects of these technologies are summarized and further research directions are prospected.This study provides basic guidance for the diversified development of efficient resource utilization of carbide slag.Graphical abstract Diversified development of calcium carbide industry,resource utilization of solid waste carbide slag and its application of carbon emission reduction have been fully reviewed.
