Diazopyridine–nickel complexes,1 and 2,were obtained by mixing di(4-pyridyl)diazomethane,D1py2,with Ni(R-hfpip)_(2);hfpip=4-(4-R-phenylimino)-1,1,1,5,5,5-hexafluoro-2-pentanone and R=n-hexyl(1)and n-octyl(2),in a 1:1...Diazopyridine–nickel complexes,1 and 2,were obtained by mixing di(4-pyridyl)diazomethane,D1py2,with Ni(R-hfpip)_(2);hfpip=4-(4-R-phenylimino)-1,1,1,5,5,5-hexafluoro-2-pentanone and R=n-hexyl(1)and n-octyl(2),in a 1:1 ratio.The discrete reference complex[Ni(n-hexyl-hfpip)(4NOpy)_(2)](3)was also prepared.展开更多
基金supported by Platform for Drug Discovery,Informatics,and Structural Life Science from the Ministry of Education,Culture,Sports,Science and Technology(MEXT),Japan.S.K.appreciates Grants-in-Aid for Scientific Research(B)(2)(no.25288038)from the Japan Society for the Promotion of Science(JSPS)PRESTO program on Molecular Technology from Japan Science Technology Agency(JST).
文摘Diazopyridine–nickel complexes,1 and 2,were obtained by mixing di(4-pyridyl)diazomethane,D1py2,with Ni(R-hfpip)_(2);hfpip=4-(4-R-phenylimino)-1,1,1,5,5,5-hexafluoro-2-pentanone and R=n-hexyl(1)and n-octyl(2),in a 1:1 ratio.The discrete reference complex[Ni(n-hexyl-hfpip)(4NOpy)_(2)](3)was also prepared.
