Developing facile and economical strategies to fabricate nitrogen-doped porous carbon anode is desirable for dual-carbon potassium ion hybrid capacitors(PIHCs).Here,a high-concentration edge-nitrogen-doped porous carb...Developing facile and economical strategies to fabricate nitrogen-doped porous carbon anode is desirable for dual-carbon potassium ion hybrid capacitors(PIHCs).Here,a high-concentration edge-nitrogen-doped porous carbon(NPC)anode is synthesized by a template-free strategy,in which the total content of pyrrolic nitrogen and pyridinic nitrogen accounts for more than 80%of the nitrogen atoms.As a result,the NPC anode displays a capacity of 315.4 mA h g^(−1)at a current rate of 0.1 A g^(−1)and 189.1 mA h g^(−1)at 5 A g^(−1).Ex situ characterizations and density functional theory calculations demonstrate the high-concentration edge-nitrogen doping enhances K^(+)adsorption and electronic conductivity of carbon materials,resulting in good electrochemical performance.The assembled NPC//CMK-3 PIHC delivers an energy density of 71.1 W h kg^(−1)at a power density of 771.9 W kg^(−1)over 8,000 cycles.展开更多
基金funding support from the Fundamental Research Funds for the Central Universities(Grants KY2060000150,GG2060127001,and WK2060000040)support from USTC Center for Micro and Nano-scale Research and Fabrication and NEWARE。
文摘Developing facile and economical strategies to fabricate nitrogen-doped porous carbon anode is desirable for dual-carbon potassium ion hybrid capacitors(PIHCs).Here,a high-concentration edge-nitrogen-doped porous carbon(NPC)anode is synthesized by a template-free strategy,in which the total content of pyrrolic nitrogen and pyridinic nitrogen accounts for more than 80%of the nitrogen atoms.As a result,the NPC anode displays a capacity of 315.4 mA h g^(−1)at a current rate of 0.1 A g^(−1)and 189.1 mA h g^(−1)at 5 A g^(−1).Ex situ characterizations and density functional theory calculations demonstrate the high-concentration edge-nitrogen doping enhances K^(+)adsorption and electronic conductivity of carbon materials,resulting in good electrochemical performance.The assembled NPC//CMK-3 PIHC delivers an energy density of 71.1 W h kg^(−1)at a power density of 771.9 W kg^(−1)over 8,000 cycles.
