With the aspect of equivalent diffusion layer an analytical chronoamperometric current equation on an oblate hemispheroid microelectrode for reversible electrochemical condition is derived. To verify this equation the...With the aspect of equivalent diffusion layer an analytical chronoamperometric current equation on an oblate hemispheroid microelectrode for reversible electrochemical condition is derived. To verify this equation the chronoammograms have been obtained with benzoquinone in McIlvaine buffer solution (pH 7.0) at a mercury oblate hemispheroid microelectrode. The experimental results agree with the theoretical conclusions.展开更多
基金Project supported by the National Natural Science Foundation of China.
文摘With the aspect of equivalent diffusion layer an analytical chronoamperometric current equation on an oblate hemispheroid microelectrode for reversible electrochemical condition is derived. To verify this equation the chronoammograms have been obtained with benzoquinone in McIlvaine buffer solution (pH 7.0) at a mercury oblate hemispheroid microelectrode. The experimental results agree with the theoretical conclusions.
