One-pot solvothermal reaction of transition metal Cd（II ） salt with （2E,2′E）-3,3′- （（propane-1,3-diylbis（oxy））bis（2,1-phenylene））diacrylic acid （H2ppa） and 1,10-phenanthroline （phen） generates a meso...One-pot solvothermal reaction of transition metal Cd（II ） salt with （2E,2′E）-3,3′- （（propane-1,3-diylbis（oxy））bis（2,1-phenylene））diacrylic acid （H2ppa） and 1,10-phenanthroline （phen） generates a meso-helicate, [Cd（ppa）（phen）（H2O）]2, and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy, and photoluminescent property. The complex crys- tallizes in monoclinic, space group P21/c with a = 13.4622（7）, b = 24.8452（12）, c = 8.9314（4） A, β = 97.564（1）°, V = 2961.3（2） A3, C66H56N4O14Cd2, Mr = 1353.97, Dc = 1.518 g/cm3, μ（MoKa） = 0.789 mm-1, F（000） = 1376, Z = 2, the final R = 0.0248 and wR = 0.0667 for 4673 observed reflections （I 〉 2σ（I））. The I-D supramolecular chain is built up from the complex by π-π stacking interactions, and inter-chain hydrogen bonds prompt the I-D chains into a 2-D layer. The title compound shows strong photoluminescence with emission maximum at 2 = 445 nm upon λEx, max = 240 nm.展开更多
The development of artificial supramolecular double-stranded helical structures has received widespread attention;however,the reports focusing on the construction and resolution of double-stranded helical assemblies b...The development of artificial supramolecular double-stranded helical structures has received widespread attention;however,the reports focusing on the construction and resolution of double-stranded helical assemblies based on terpyridine are relatively scarce.Herein,we report a series of extremely low-symmetry double-stranded helicates(S^(3),S^(4),and S^(R/S))based on the head-totail coordination mode of ladder-style ligands(L^(3),L^(4),and LR/S),which are apparently different from the conventional helicates with symmetrical axis.The ladder-style tridentate ligand L^(3)was first designed and synthesized by characteristic consecutive unsymmetrical modification of terpyridine.The chiral group 2,6-bis(oxazolinyl)pyridine(Py Box)was designed at the tail of tridentate ligand L^(3)and achieved the chiral resolution of the assembly.Moreover,the self-assembly of mixed three ladder-style ligands(didentate L2,tridentate L^(3),and tetradentate L^(4))and single terpyridine ligand(L^(1))with Zn(Ⅱ)also exhibited excellent narcissistic self-sorting behavior,without any statistical mixture.展开更多
In-depth studies of hierarchical self-assembly with chirality inversion and asymmetry amplification are indispensable for understanding the chiral transfer rule in assembly systems and construction of circularly polar...In-depth studies of hierarchical self-assembly with chirality inversion and asymmetry amplification are indispensable for understanding the chiral transfer rule in assembly systems and construction of circularly polarized luminescence(CPL)active materials.Herein,a coordination-driven primary assembly of pyrene-based chiral ligand and Zn(OTf)2 was employed for the construction of homochiral metal–organic helicate with a triple helix structure,tunable emission color,and significant chirality amplification.More excitingly,the metal–organic helicate further assembled into well-ordered hierarchical nanoarchitectures with the aid of C–H⋯πinteraction andπ–πstacking,showing significant CPL enhancement and unexpected handedness inversion.Thus,the|glum|increased from 5.20×10^(−5) to 5.60×10^(−2),and the|gabs|rose from 3.80×10^(−4) to 1.04×10^(−2) over the entire hierarchical self-assembly process.The multiple supramolecular interactions not only endowed the resultant metal–organic helicate with efficient chirality transmission and tunable emission color but also guided the(supra)molecular building block of metal–organic helicate organizing into the hierarchically chiral nanoarchitecture in a directional manner.This work provides insight into the metal–organic helicate-mediated hierarchical self-assembly and aids the development of CPLactive materials with dynamic chirality modulation and enhanced chiroptical performance.展开更多
Chiral tetraphenylethylene(TPE) dicycle tetraaldehyde and TPE dicycle tetraacids bearing optically pure groups on the cycles were designed and synthesized. Due to the propeller-like conformation immobilization of TPE ...Chiral tetraphenylethylene(TPE) dicycle tetraaldehyde and TPE dicycle tetraacids bearing optically pure groups on the cycles were designed and synthesized. Due to the propeller-like conformation immobilization of TPE unit, this new class of TPE dicycle was resolved into M-and P-enantiomers, which could emit strong circular polarized luminescence(CPL). Interestingly,these TPE helicates displayed exceptional ability of molecule recognition. While the TPE dicycle tetraaldehyde could detect the microscale water in anhydrous tetrahydrofuran, the chiral TPE dicycle tetraacid could display different fluorescent color after interacting with two enantiomers of a wide variety of chiral amines including monoamines, diamines, and aminols, which could be applied to chiral recognition of these chiral amines. Furthermore, the emission wavelength of TPE dicycle tetraacid was found to change linearly with the enantiomer purity of chiral amine from enantiomer excess(ee) percent-100% to +100%, for the first time showing the potential for quantitative chiral analysis of chiral amines based on emission wavelength change. The emission wavelength was affected less by environmental factors than fluorescence intensity, which would enable the chiral analysis based on wavelength change with higher accuracy and repeatability.展开更多
A new approach to generating supramolecular architectures, based on easy-to-prepare schiff base ligands, is described together with its application to the self-assembly of supramolecular neutral double helicates.
To get large dissymmetric factor(g_(lum))of organic circularly polarized luminescence(CPL)materials is still a great challenge.Although helical chirality and planar chirality are usual efficient access to enhancement ...To get large dissymmetric factor(g_(lum))of organic circularly polarized luminescence(CPL)materials is still a great challenge.Although helical chirality and planar chirality are usual efficient access to enhancement of CPL,they are not combined together to boost CPL.Here,a new tetraphenylethylene(TPE)tetracycle acid helicate bearing both helical chirality and planar chirality was designed and synthesized.Uniquely,synergy of the helical chirality and planar chirality was used to boost CPL signals both in solution and in helical self-assemblies.In the presence of octadecylamine,the TPE helicate could form helical nanofibers that emitted strong CPL signals with an absolute g_(lum)value up to 0.237.Exceptionally,followed by addition of para-phenylenediamine,the g_(lum)value was successively increased to 0.387 due to formation of bigger helical nanofibers.Compared with that of TPE helicate itself,the CPL signal of the self-assemblies was not only magnified by 104-fold but also inversed,which was very rare result for CPL-active materials.Surprisingly,the interaction of TPE helicate with xylylenediamine even gave a gel,which was transformed into suspension by shaking.Unexpectedly,the suspension showed 40-fold stronger CPL signals than the gel with signal direction inversion each other.Using synergy of the helical chirality and planar chirality to significantly boost CPL intensity provides a new strategy in preparation of organic CPL materials having very large g_(lum)value.展开更多
Autografting is the gold standard for surgical repair of nerve defects>5 mm in length;however,autografting is associated with potential complications at the nerve donor site.As an alternative,nerve guidance conduit...Autografting is the gold standard for surgical repair of nerve defects>5 mm in length;however,autografting is associated with potential complications at the nerve donor site.As an alternative,nerve guidance conduits may be used.The ideal conduit should be flexible,resistant to kinks and lumen collapse,and provide physical cues to guide nerve regeneration.We designed a novel flexible conduit using electrospinning technology to create fibers on the innermost surface of the nerve guidance conduit and employed melt spinning to align them.Subsequently,we prepared disordered electrospun fibers outside the aligned fibers and helical melt-spun fibers on the outer wall of the electrospun fiber lumen.The presence of aligned fibers on the inner surface can promote the extension of nerve cells along the fibers.The helical melt-spun fibers on the outer surface can enhance resistance to kinking and compression and provide stability.Our novel conduit promoted nerve regeneration and functional recovery in a rat sciatic nerve defect model,suggesting that it has potential for clinical use in human nerve injuries.展开更多
A numerical simulation analysis is conducted to examine the unsteady hydrodynamic characteristics of vortex-induced vibration(VIV)and the suppression effect of helical strakes on VIV in subsea pipelines.The analysis u...A numerical simulation analysis is conducted to examine the unsteady hydrodynamic characteristics of vortex-induced vibration(VIV)and the suppression effect of helical strakes on VIV in subsea pipelines.The analysis uses the standard k−εturbulence model for 4.5-and 12.75-inch pipes,and its accuracy is verified by comparing the results with large-scale hydrodynamic experiments.These experiments are designed to evaluate the suppression efficiency of VIV with and without helical strakes,focusing on displacement and drag coefficients under different flow conditions.Furthermore,the influence of important geometric parameters of the helical strakes on drag coefficients and VIV suppression efficiency at different flow rates is compared and discussed.Numerical results agree well with experimental data for drag coefficient and vortex shedding frequency.Spring-pipe self-excited vibration experimental tests reveal that the installation of helical strakes substantially reduces the drag coefficient of VIV within a certain flow rate range,achieving suppression efficiencies exceeding 90%with strake heights larger than 0.15D.Notably,the optimized parameter combination of helical strakes,with a pitch of 15D,a fin height of 0.2D,and 45°edge slopes,maintains high suppression efficiency,thereby exhibiting superior performance.This study provides a valuable reference for the design and application of helical strakes and VIV suppression in subsea engineering.展开更多
Atomic-scale doping strategies and structure design play pivotal roles in tailoring the electronic structure and physicochemical property of electromagnetic wave absorption(EMWA)materials.However,the relationship betw...Atomic-scale doping strategies and structure design play pivotal roles in tailoring the electronic structure and physicochemical property of electromagnetic wave absorption(EMWA)materials.However,the relationship between configuration and electromagnetic(EM)loss mechanism has remained elusive.Herein,drawing inspiration from the DNA transcription process,we report the successful synthesis of novel in situ Mn/N co-doped helical carbon nanotubes with ultrabroad EMWA capability.Theoretical calculation and EM simulation confirm that the orbital coupling and spin polarization of the Mn–N4–C configuration,along with cross polarization generated by the helical structure,endow the helical converters with enhanced EM loss.As a result,HMC-8 demonstrates outstanding EMWA performance,achieving a minimum reflection loss of−63.13 dB at an ultralow thickness of 1.29 mm.Through precise tuning of the graphite domain size,HMC-7 achieves an effective absorption bandwidth(EAB)of 6.08 GHz at 2.02 mm thickness.Furthermore,constructing macroscale gradient metamaterials enables an ultrabroadband EAB of 12.16 GHz at a thickness of only 5.00 mm,with the maximum radar cross section reduction value reaching 36.4 dB m2.This innovative approach not only advances the understanding of metal–nonmetal co-doping but also realizes broadband EMWA,thus contributing to the development of EMWA mechanisms and applications.展开更多
Inspired by the ubiquitous helical structures in nature,research on artificial helices has attracted increasing attention.As a unique and complex three-dimensional(3D)geometry in the microscopic world,the micro-/nano ...Inspired by the ubiquitous helical structures in nature,research on artificial helices has attracted increasing attention.As a unique and complex three-dimensional(3D)geometry in the microscopic world,the micro-/nano helix has significant advantages in wide applications due to its distinctive properties at the micro-scale.Micro-/nanotechnology is advancing rapidly.The geometric complexity of helical structure poses technical challenges for the manufacturing at the micro-/nanoscale,requiring some emerging manufacturing techniques.In this review,we systematically classify and summarize existing manufacturing methods for micro/nano helical structures and their underlying mechanisms.Based on the unique physical properties of helical structures at the microscale,their latest applications are analyzed across different fields.Finally,we conclude the challenges and future research directions of micro-/nano helices in manufacturing methods and applications.展开更多
Cylindrical cross sections are critical components in offshore structures, including jacket platform legs, pipelines, mooring lines, and risers. Thesecylindrical structures are subjected to vortex-induced vibrations (...Cylindrical cross sections are critical components in offshore structures, including jacket platform legs, pipelines, mooring lines, and risers. Thesecylindrical structures are subjected to vortex-induced vibrations (VIV) due to strong ocean currents, where vortices generated during fluid flowresult in significant vibrations in crossflow and in-flow directions. Such vibrations can lead to severe damage to platforms, cables, and risersystems. Consequently, mitigating VIV caused by vortex-induced forces is important. This study investigates the hydrodynamic performance offive strake models relative to a bare cylinder at moderate Reynolds numbers. The models encompass one conventional continuous helical strake(HS) and four helical discrete strake (HDS) with varying segment spacing between the fins. The hydrodynamic performance, specifically liftand drag force coefficients, was computed using a Reynolds averaged Navier –Stokes-based CFD solver and validated with experimentalmeasurements. The conventional HS suppresses 95% of the lift force but increases the drag force by up to a maximum of 48% in measurements.The HDS suppress the lift force by 70%–88% and increase the drag force by 15%–30%, which is less than the increase observed with the HS.Flow visualization showed that HS and HDS cylinders mitigate vortex-induced forces by altering the vortex-shedding pattern along the length ofthe cylinder. The HDS achieves a reduction in drag compared with the conventional continuous HS. The segment spacing is found to significantlyimpact the reduction in vortex-induced forces.展开更多
Natural biomolecular structures possess an inherent ability to encode chiral conformations,thus the generation and regulation of chiroptical activity is crucial.While artificial polymers hold special significance in u...Natural biomolecular structures possess an inherent ability to encode chiral conformations,thus the generation and regulation of chiroptical activity is crucial.While artificial polymers hold special significance in understanding life's origins,the fundamental connections between the racemic architecture and functional characteristics still need to be fully investigated.Herein,this study reports the generation and regulation of the global chirality and helical sense in racemic polymer systems,focusing on the synergistic effects of liquid crystallinity(LC)and solvophobic interaction.By systematically varying the length of alkyl spacers and the degree of polymerization(DP)of the core-forming azobenzene(Azo)blocks,the chiral communications,morphological transitions and chiroptical properties of the racemic nanoaggregates can be precisely controlled.Furthermore,the proposed“first come,first serve”(FF)and the“late-comer lives above”(LA)effect are broadly applicable and are expected to be applied to various types of racemic polymer systems.This work provides valuable insights into the design of self-assembled systems with tunable global chirality and morphology,thereby advancing the understanding of the origins of homochirality in nature.展开更多
Bio-inspired magnetic helical microrobots have great potential for biomedical and micromanipulation applications. Precise interaction with objects in liquid environments is an important prerequisite and challenge for ...Bio-inspired magnetic helical microrobots have great potential for biomedical and micromanipulation applications. Precise interaction with objects in liquid environments is an important prerequisite and challenge for helical microrobots to perform various tasks. In this study, an automatic control method is proposed to realize the axial docking of helical microrobots with arbitrarily placed cylindrical objects in liquid environments. The docking process is divided into ascent, approach, alignment, and insertion stages. First, a 3D docking path is planned according to the positions and orientations of the microrobot and the target object. Second, a steering-based 3D path-following controller guides the helical microrobot to rise away from the container bottom and approach the target along the path. Third, based on path design with gravity compensation and steering output limits, alignment of position and orientation can be accomplished simultaneously. Finally, the helical microrobot completes the docking under the rotating magnetic field along the target orientation. Experiments verified the automatic docking of the helical microrobot with static targets, including connecting with micro-shafts and inserting into micro-tubes. The object grasping of a reconfigurable helical microrobot aided by 3D automatic docking was also demonstrated. This method enables precise docking of helical microrobots with objects, which might be used for capture and sampling, in vivo navigation control, and functional assembly of microrobots.展开更多
Rational tuning of chiral nanostructures of supramolecular assemblies as catalysts and investigating their chiral morphology-enantioselectivity dependence is rarely reported. Herein, we report a series of supramolecul...Rational tuning of chiral nanostructures of supramolecular assemblies as catalysts and investigating their chiral morphology-enantioselectivity dependence is rarely reported. Herein, we report a series of supramolecular M/P-helical nanoribbons(HNs) assembled from the chiral L/D-glutamate-based amphiphiles(L/D-Glu C16) and Cu(Ⅱ) ions, with their helical screw pitches adjusted from 217 nm to 104 nm through the facile regulation of their water/organic solvent assembly environment. They were then used as ideal models to reveal the chiral morphology-enantioselectivity relationship by catalyzing the asymmetric Diels-Alder reaction. Better enantioselectivity was achieved with more twist morphology. Experimental evidences of stronger chiral transfer effect from the supramolecular HNs with more twist to the aza-chalcone as reactant were obtained to understand such dependence. Our study demonstrates a new perspective for designing supramolecular catalysts with higher enantioselectivity.展开更多
Spiral pile foundations,as a promising type of foundation,are of significant importance for the development of offshore wind energy,particularly as it moves toward deeper waters.This study conducted a physical experim...Spiral pile foundations,as a promising type of foundation,are of significant importance for the development of offshore wind energy,particularly as it moves toward deeper waters.This study conducted a physical experiment on a three-spiral-pile jacket foundation under deep-buried sandy soil conditions.During the experiment,horizontal displacement was applied to the structure to thoroughly investigate the bearing characteristics of the three-spiral-pile jacket foundation.This study also focused on analyzing the bearing mechanisms of conventional piles compared with spiral piles with different numbers of blades.Three different working conditions were set up and compared,and key data,such as the horizontal bearing capacity,pile shaft axial force,and spiral blade soil pressure,were measured and analyzed.The results show the distinct impacts of the spiral blades on the compressed and tensioned sides of the foundation.Specifically,on the compressed side,the spiral blades effectively enhance the restraint of the soil on the pile foundation,whereas on the tensioned side,an excessive number of spiral blades can negatively affect the structural tensile performance to some extent.This study also emphasizes that the addition of blades to the side of a single pile is the most effective method for increasing the bearing capacity of the foundation.This research aims to provide design insights into improving the bearing capacity of the foundation.展开更多
Gear assembly errors can lead to the increase of vibration and noise of the system,which affect the stability of system.The influence can be compensated by tooth modification.Firstly,an improved three-dimensional load...Gear assembly errors can lead to the increase of vibration and noise of the system,which affect the stability of system.The influence can be compensated by tooth modification.Firstly,an improved three-dimensional loaded tooth contact analysis(3D-LTCA)method which can consider tooth modification and coupling assembly errors is proposed,and mesh stiffness calculated by proposed method is verified by MASTA software.Secondly,based on neural network,the surrogate model(SM)that maps the relationship between modification parameters and mesh mechanical parameters is established,and its accuracy is verified.Finally,SM is introduced to establish an optimization model with the target of minimizing mesh stiffness variations and obtaining more even load distribution on mesh surface.The results show that even considering training time,the efficiency of gear pair optimization by surrogate model is still much higher than that by LTCA method.After optimization,the mesh stiffness fluctuation of gear pair with coupling assembly error is reduced by 34.10%,and difference in average contact stresses between left and right regions of the mesh surface is reduced by 62.84%.展开更多
Combining the advantages of high efficiency,low-pressure drop,and large throughput,the pore arrayenhanced tube-in-tube microchannel(PA-TMC) is a promising microreactor for industrial applications.However,most of the m...Combining the advantages of high efficiency,low-pressure drop,and large throughput,the pore arrayenhanced tube-in-tube microchannel(PA-TMC) is a promising microreactor for industrial applications.However,most of the mass transfer takes place in the upstream pore region,while the contribution of the downstream annulus is limited.In this work,helical wires were introduced into the annulus by adhering to the outer surface of the inner tube.Mixing behavior and mass transfer of liquid-liquid twophase flow in PA-TMC with different helical wires have been systematically studied by a combination of experiments and volume of fluid(VOF) method.The introduction of helical wires improves the overall volumetric mass transfer coefficient KLa by up to 133% and the mass transfer efficiency E by up to 117%.The simulation results show that the helical wire brings extra phase mixing regions and increases the specific interface area,while accelerating the fluid flow and expanding the area of enhanced turbulent dissipation rate.Influences of helical wires in various configurations are compared by the comprehensive index I concerning the pressure drop and mass transfer performance simultaneously and a new correlation between KLa and specific energy consumption φ is proposed.This research deepens the understanding of the mixing behavior and mass transfer in the PA-TMCs and provides practical experience for the process intensification of microchannel reactors.展开更多
A series of optically active copolymers with various feed ratios have been synthesized through helix-sense-selective copolymerization catalyzed by[Rh(norbornadiene)Cl]2-triethylamine.This process involves two proline-...A series of optically active copolymers with various feed ratios have been synthesized through helix-sense-selective copolymerization catalyzed by[Rh(norbornadiene)Cl]2-triethylamine.This process involves two proline-derived acetylene monomers,(S)-N-(4-chlorophenyl)carbamoyl-2-ethynyl pyrrolidine(MCl)and(S)-N-(tert-butoxycarbonyl)-2-ethynyl pyrrolidine,followed by acidic deprotection and neutralization.These copolymers adopt helical conformations with a preferred handedness,as demonstrated by nuclear magnetic resonance spectroscopy and a series of spectroscopic analyses.The chiroptical activity intensity of copolymer has been found to increase with MCl content.Consequently,the enantioseparation capabilities of copolymers containing 95 mol%,90 mol%,and 85 mol%MCl units have been assessed as chiral stationary phases in high-performance liquid chromatography because of their good chiroptical activities.These chiral stationary phases effectively enantioseparate racemic alcohols,sulfoxides,amides,and metal complexes.Notably,the copolymer with 90 mol%MCl shows superior chiral recognition ability,especially for 1-(2,4-dichlorophenyl)-2-(1H-imidazol-1-yl)ethanol(α=1.19)and 4-methylbenzenesulfinamide(α=1.47).Insights from molecular dynamic simulation and autodock analysis indicate that hydrogen bonding andπ-πstacking interactions between the chiral stationary phases and enantiomers play a key role for successful chiral separation.Our contribution not only demonstrates the importance of hydrogen bonding donor and copolymer chiroptical activity of chiral stationary phases for chiral resolution,but will also provide valuable insights for the future development of novel stationary phases.展开更多
Liquid crystal elastomers(LCEs)exhibit exceptional reversible deformation and unique physical properties owing to their order-disorder phase transition under external stimuli.Among these deformations,helical structure...Liquid crystal elastomers(LCEs)exhibit exceptional reversible deformation and unique physical properties owing to their order-disorder phase transition under external stimuli.Among these deformations,helical structures have attracted attention owing to their distinctive configurations and promising applications in biomimetics and microelectronics.However,the helical deformation behavior of fiber actuators is critically influenced by their morphologies and alignments;yet,the underlying mechanisms are not fully understood.Through a two-step azaMichael addition reaction and direct ink writing(DIW)4D printing technology,fiber-based LCE actuators with a core-sheath alignment structure were fabricated and exhibited reversible helical deformation upon heating.By adjusting the printing parameters,the filament number,width,thickness,and core-sheath structure of the fiber actuators can be precisely controlled,resulting in deformation behaviors,such as contraction,bending,and helical twisting.Finite element simulations were performed to investigate the deformation behaviors of the fiber actuators,providing insights into the variations in stress and strain during the shape-changing process,which can be used to explain the shape-morphing mechanism.These findings demonstrate that the precise tuning of printing parameters enables the controllable construction of LCE actuator morphology and customization of their functional properties,paving the way for advanced applications in smart fabrics,biomedical engineering,and flexible electronics.展开更多
NiTi alloy lattice structures are crucial for reusable energy absorption due to their shape memory effects.However,existing NiTi alloy lattice structures always suffer from localized deformation bands during loading,c...NiTi alloy lattice structures are crucial for reusable energy absorption due to their shape memory effects.However,existing NiTi alloy lattice structures always suffer from localized deformation bands during loading,causing local strains to exceed the recoverable strain limit of the alloy and significantly reducing their reusable energy-absorbing capacity.In this study,we developed a NiTi alloy helical lattice structure(HLS)to effectively prevent localized deformation bands.This is attributed to its struts distributing stress and strain uniformly through torsional deformation,thereby alleviating local stress concentrations and suppressing the formation of localized deformation bands.Additionally,its unit cells provide mutual support and reinforcement during deformation,effectively preventing the progression of localized deformation bands.The NiTi alloy HLS exhibits superior reusable energy absorption compared to previously reported reusable energy-absorbing materials/structures and enhanced damage tolerance under large compression strain.This study provides valuable insights for the development of high-performance reusable NiTi alloy energy-absorbing lattice structures.展开更多
基金Supported by the Science and Technology Projects of Chongqing Municipal Education Commission(KJ120632)Scientific Research Foundation Project of Chongqing Normal University (2011XLS30, 10XLZ005)
文摘One-pot solvothermal reaction of transition metal Cd（II ） salt with （2E,2′E）-3,3′- （（propane-1,3-diylbis（oxy））bis（2,1-phenylene））diacrylic acid （H2ppa） and 1,10-phenanthroline （phen） generates a meso-helicate, [Cd（ppa）（phen）（H2O）]2, and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy, and photoluminescent property. The complex crys- tallizes in monoclinic, space group P21/c with a = 13.4622（7）, b = 24.8452（12）, c = 8.9314（4） A, β = 97.564（1）°, V = 2961.3（2） A3, C66H56N4O14Cd2, Mr = 1353.97, Dc = 1.518 g/cm3, μ（MoKa） = 0.789 mm-1, F（000） = 1376, Z = 2, the final R = 0.0248 and wR = 0.0667 for 4673 observed reflections （I 〉 2σ（I））. The I-D supramolecular chain is built up from the complex by π-π stacking interactions, and inter-chain hydrogen bonds prompt the I-D chains into a 2-D layer. The title compound shows strong photoluminescence with emission maximum at 2 = 445 nm upon λEx, max = 240 nm.
基金supported by the Natural Science Foundation of Jilin Province(20230101027JC for M.Wang)the National Natural Science Foundation of China(22071079 for M.Wang)the Natural Science Foundation of Xinjiang Uygur Autonomous Region(2023D01C203 for J.Ma)。
文摘The development of artificial supramolecular double-stranded helical structures has received widespread attention;however,the reports focusing on the construction and resolution of double-stranded helical assemblies based on terpyridine are relatively scarce.Herein,we report a series of extremely low-symmetry double-stranded helicates(S^(3),S^(4),and S^(R/S))based on the head-totail coordination mode of ladder-style ligands(L^(3),L^(4),and LR/S),which are apparently different from the conventional helicates with symmetrical axis.The ladder-style tridentate ligand L^(3)was first designed and synthesized by characteristic consecutive unsymmetrical modification of terpyridine.The chiral group 2,6-bis(oxazolinyl)pyridine(Py Box)was designed at the tail of tridentate ligand L^(3)and achieved the chiral resolution of the assembly.Moreover,the self-assembly of mixed three ladder-style ligands(didentate L2,tridentate L^(3),and tetradentate L^(4))and single terpyridine ligand(L^(1))with Zn(Ⅱ)also exhibited excellent narcissistic self-sorting behavior,without any statistical mixture.
基金supported by the National Natural Science Foundation of China(grant no.22101208)the Fundamental Research Funds for the Central Universitiesthe Program for Professors of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning.
文摘In-depth studies of hierarchical self-assembly with chirality inversion and asymmetry amplification are indispensable for understanding the chiral transfer rule in assembly systems and construction of circularly polarized luminescence(CPL)active materials.Herein,a coordination-driven primary assembly of pyrene-based chiral ligand and Zn(OTf)2 was employed for the construction of homochiral metal–organic helicate with a triple helix structure,tunable emission color,and significant chirality amplification.More excitingly,the metal–organic helicate further assembled into well-ordered hierarchical nanoarchitectures with the aid of C–H⋯πinteraction andπ–πstacking,showing significant CPL enhancement and unexpected handedness inversion.Thus,the|glum|increased from 5.20×10^(−5) to 5.60×10^(−2),and the|gabs|rose from 3.80×10^(−4) to 1.04×10^(−2) over the entire hierarchical self-assembly process.The multiple supramolecular interactions not only endowed the resultant metal–organic helicate with efficient chirality transmission and tunable emission color but also guided the(supra)molecular building block of metal–organic helicate organizing into the hierarchically chiral nanoarchitecture in a directional manner.This work provides insight into the metal–organic helicate-mediated hierarchical self-assembly and aids the development of CPLactive materials with dynamic chirality modulation and enhanced chiroptical performance.
基金the National Natural Science Foundation of China (22072050 and 22372066) for financial support。
文摘Chiral tetraphenylethylene(TPE) dicycle tetraaldehyde and TPE dicycle tetraacids bearing optically pure groups on the cycles were designed and synthesized. Due to the propeller-like conformation immobilization of TPE unit, this new class of TPE dicycle was resolved into M-and P-enantiomers, which could emit strong circular polarized luminescence(CPL). Interestingly,these TPE helicates displayed exceptional ability of molecule recognition. While the TPE dicycle tetraaldehyde could detect the microscale water in anhydrous tetrahydrofuran, the chiral TPE dicycle tetraacid could display different fluorescent color after interacting with two enantiomers of a wide variety of chiral amines including monoamines, diamines, and aminols, which could be applied to chiral recognition of these chiral amines. Furthermore, the emission wavelength of TPE dicycle tetraacid was found to change linearly with the enantiomer purity of chiral amine from enantiomer excess(ee) percent-100% to +100%, for the first time showing the potential for quantitative chiral analysis of chiral amines based on emission wavelength change. The emission wavelength was affected less by environmental factors than fluorescence intensity, which would enable the chiral analysis based on wavelength change with higher accuracy and repeatability.
基金Project supported by the National Nature Science Foundation of China (No. 29771020)Tianjin Natural Science Foundation
文摘A new approach to generating supramolecular architectures, based on easy-to-prepare schiff base ligands, is described together with its application to the self-assembly of supramolecular neutral double helicates.
基金National Natural Science Foundation of China(Nos.22072050,22372066 and 22301090)the Open Research Fund(No.2024JYBKF05)of Key Laboratory of Material Chemistry for Energy Conversion and Storage(HUST)Ministry of Educationthe China Postdoctoral Science Foundation(No.2023M731189)for financial support,and thank the Analytical and Testing Centre at Huazhong University of Science and Technology for measurement.
文摘To get large dissymmetric factor(g_(lum))of organic circularly polarized luminescence(CPL)materials is still a great challenge.Although helical chirality and planar chirality are usual efficient access to enhancement of CPL,they are not combined together to boost CPL.Here,a new tetraphenylethylene(TPE)tetracycle acid helicate bearing both helical chirality and planar chirality was designed and synthesized.Uniquely,synergy of the helical chirality and planar chirality was used to boost CPL signals both in solution and in helical self-assemblies.In the presence of octadecylamine,the TPE helicate could form helical nanofibers that emitted strong CPL signals with an absolute g_(lum)value up to 0.237.Exceptionally,followed by addition of para-phenylenediamine,the g_(lum)value was successively increased to 0.387 due to formation of bigger helical nanofibers.Compared with that of TPE helicate itself,the CPL signal of the self-assemblies was not only magnified by 104-fold but also inversed,which was very rare result for CPL-active materials.Surprisingly,the interaction of TPE helicate with xylylenediamine even gave a gel,which was transformed into suspension by shaking.Unexpectedly,the suspension showed 40-fold stronger CPL signals than the gel with signal direction inversion each other.Using synergy of the helical chirality and planar chirality to significantly boost CPL intensity provides a new strategy in preparation of organic CPL materials having very large g_(lum)value.
基金supported by the National Natural Science Foundation of China,No.82202718the Natural Science Foundation of Beijing,No.L212050the China Postdoctoral Science Foundation,Nos.2019M664007,2021T140793(all to ZL)。
文摘Autografting is the gold standard for surgical repair of nerve defects>5 mm in length;however,autografting is associated with potential complications at the nerve donor site.As an alternative,nerve guidance conduits may be used.The ideal conduit should be flexible,resistant to kinks and lumen collapse,and provide physical cues to guide nerve regeneration.We designed a novel flexible conduit using electrospinning technology to create fibers on the innermost surface of the nerve guidance conduit and employed melt spinning to align them.Subsequently,we prepared disordered electrospun fibers outside the aligned fibers and helical melt-spun fibers on the outer wall of the electrospun fiber lumen.The presence of aligned fibers on the inner surface can promote the extension of nerve cells along the fibers.The helical melt-spun fibers on the outer surface can enhance resistance to kinking and compression and provide stability.Our novel conduit promoted nerve regeneration and functional recovery in a rat sciatic nerve defect model,suggesting that it has potential for clinical use in human nerve injuries.
基金Supported by the National Natural Science Foundation of China (Grant No. 52222111)the National Science and Technology Major Project of China “Key Technologies and Equipment for Deepwater Dry Oil and Gas Production and Processing Platforms”(No. 2024ZD1403300)+1 种基金Subproject 5 “Research on Safety Risk Assessment Technology System for Deepwater Dry Oil and Gas Production and Processing Platforms”(No. 2024ZD1403305)the China Scholarship Council (202306440019)。
文摘A numerical simulation analysis is conducted to examine the unsteady hydrodynamic characteristics of vortex-induced vibration(VIV)and the suppression effect of helical strakes on VIV in subsea pipelines.The analysis uses the standard k−εturbulence model for 4.5-and 12.75-inch pipes,and its accuracy is verified by comparing the results with large-scale hydrodynamic experiments.These experiments are designed to evaluate the suppression efficiency of VIV with and without helical strakes,focusing on displacement and drag coefficients under different flow conditions.Furthermore,the influence of important geometric parameters of the helical strakes on drag coefficients and VIV suppression efficiency at different flow rates is compared and discussed.Numerical results agree well with experimental data for drag coefficient and vortex shedding frequency.Spring-pipe self-excited vibration experimental tests reveal that the installation of helical strakes substantially reduces the drag coefficient of VIV within a certain flow rate range,achieving suppression efficiencies exceeding 90%with strake heights larger than 0.15D.Notably,the optimized parameter combination of helical strakes,with a pitch of 15D,a fin height of 0.2D,and 45°edge slopes,maintains high suppression efficiency,thereby exhibiting superior performance.This study provides a valuable reference for the design and application of helical strakes and VIV suppression in subsea engineering.
基金supported by the National Natural Science Foundation of China(22265021)the Aeronautical Science Foundation of China(2020Z056056003)Jiangxi Provincial Natural Science Foundation(20232BAB212004).
文摘Atomic-scale doping strategies and structure design play pivotal roles in tailoring the electronic structure and physicochemical property of electromagnetic wave absorption(EMWA)materials.However,the relationship between configuration and electromagnetic(EM)loss mechanism has remained elusive.Herein,drawing inspiration from the DNA transcription process,we report the successful synthesis of novel in situ Mn/N co-doped helical carbon nanotubes with ultrabroad EMWA capability.Theoretical calculation and EM simulation confirm that the orbital coupling and spin polarization of the Mn–N4–C configuration,along with cross polarization generated by the helical structure,endow the helical converters with enhanced EM loss.As a result,HMC-8 demonstrates outstanding EMWA performance,achieving a minimum reflection loss of−63.13 dB at an ultralow thickness of 1.29 mm.Through precise tuning of the graphite domain size,HMC-7 achieves an effective absorption bandwidth(EAB)of 6.08 GHz at 2.02 mm thickness.Furthermore,constructing macroscale gradient metamaterials enables an ultrabroadband EAB of 12.16 GHz at a thickness of only 5.00 mm,with the maximum radar cross section reduction value reaching 36.4 dB m2.This innovative approach not only advances the understanding of metal–nonmetal co-doping but also realizes broadband EMWA,thus contributing to the development of EMWA mechanisms and applications.
基金supported by the National Key R&D Program of China(Grant No.2022YFB4701200)the National Natural Science Foundation of China(Grant Nos.52335003,52405011 and U22A20176)+3 种基金the Guangdong Basic and Applied Basic Research Foundation(Grant Nos.2022B1515120078 and 2023A1515110313)the Shenzhen Natural Science Fund(the Stable Support Plan Program,Grant No.GXWD20231129161359002)the Shenzhen Science and Technology Program(Grant No.KQTD20210811090146075)Pre-research Task of State Key Laboratory of Robotics and Systems(HIT)(Grant No.SKLRS202421B).
文摘Inspired by the ubiquitous helical structures in nature,research on artificial helices has attracted increasing attention.As a unique and complex three-dimensional(3D)geometry in the microscopic world,the micro-/nano helix has significant advantages in wide applications due to its distinctive properties at the micro-scale.Micro-/nanotechnology is advancing rapidly.The geometric complexity of helical structure poses technical challenges for the manufacturing at the micro-/nanoscale,requiring some emerging manufacturing techniques.In this review,we systematically classify and summarize existing manufacturing methods for micro/nano helical structures and their underlying mechanisms.Based on the unique physical properties of helical structures at the microscale,their latest applications are analyzed across different fields.Finally,we conclude the challenges and future research directions of micro-/nano helices in manufacturing methods and applications.
文摘Cylindrical cross sections are critical components in offshore structures, including jacket platform legs, pipelines, mooring lines, and risers. Thesecylindrical structures are subjected to vortex-induced vibrations (VIV) due to strong ocean currents, where vortices generated during fluid flowresult in significant vibrations in crossflow and in-flow directions. Such vibrations can lead to severe damage to platforms, cables, and risersystems. Consequently, mitigating VIV caused by vortex-induced forces is important. This study investigates the hydrodynamic performance offive strake models relative to a bare cylinder at moderate Reynolds numbers. The models encompass one conventional continuous helical strake(HS) and four helical discrete strake (HDS) with varying segment spacing between the fins. The hydrodynamic performance, specifically liftand drag force coefficients, was computed using a Reynolds averaged Navier –Stokes-based CFD solver and validated with experimentalmeasurements. The conventional HS suppresses 95% of the lift force but increases the drag force by up to a maximum of 48% in measurements.The HDS suppress the lift force by 70%–88% and increase the drag force by 15%–30%, which is less than the increase observed with the HS.Flow visualization showed that HS and HDS cylinders mitigate vortex-induced forces by altering the vortex-shedding pattern along the length ofthe cylinder. The HDS achieves a reduction in drag compared with the conventional continuous HS. The segment spacing is found to significantlyimpact the reduction in vortex-induced forces.
基金support from the National Natural Science Foundation of China(22301208,92356305)Natural Science Foundation of Anhui Province(2308085J15)+2 种基金Natural Science Foundation of Anhui Provincial Higher Education Institutions(2023AH010012)Natural Science Foundation of Jiangsu Province(BK20230505)Jiangsu Funding Program for Excellent Postdoctoral Talent,Key Laboratory of Polymeric Material Design and Synthesis for Biomedical Function,the Priority Academic Program Development(PAPD)of Jiangsu Higher Education Institutions,Program of Innovative Research Team of Soochow University and Postgraduate Research&Practice Innovation Program of Jiangsu Province.
文摘Natural biomolecular structures possess an inherent ability to encode chiral conformations,thus the generation and regulation of chiroptical activity is crucial.While artificial polymers hold special significance in understanding life's origins,the fundamental connections between the racemic architecture and functional characteristics still need to be fully investigated.Herein,this study reports the generation and regulation of the global chirality and helical sense in racemic polymer systems,focusing on the synergistic effects of liquid crystallinity(LC)and solvophobic interaction.By systematically varying the length of alkyl spacers and the degree of polymerization(DP)of the core-forming azobenzene(Azo)blocks,the chiral communications,morphological transitions and chiroptical properties of the racemic nanoaggregates can be precisely controlled.Furthermore,the proposed“first come,first serve”(FF)and the“late-comer lives above”(LA)effect are broadly applicable and are expected to be applied to various types of racemic polymer systems.This work provides valuable insights into the design of self-assembled systems with tunable global chirality and morphology,thereby advancing the understanding of the origins of homochirality in nature.
基金supported by the National Natural Science Foundation of China(No.62273117)Pre-research Task(No.SKLRS202418B)of State Key Laboratory of Robotics and Systems(HIT).
文摘Bio-inspired magnetic helical microrobots have great potential for biomedical and micromanipulation applications. Precise interaction with objects in liquid environments is an important prerequisite and challenge for helical microrobots to perform various tasks. In this study, an automatic control method is proposed to realize the axial docking of helical microrobots with arbitrarily placed cylindrical objects in liquid environments. The docking process is divided into ascent, approach, alignment, and insertion stages. First, a 3D docking path is planned according to the positions and orientations of the microrobot and the target object. Second, a steering-based 3D path-following controller guides the helical microrobot to rise away from the container bottom and approach the target along the path. Third, based on path design with gravity compensation and steering output limits, alignment of position and orientation can be accomplished simultaneously. Finally, the helical microrobot completes the docking under the rotating magnetic field along the target orientation. Experiments verified the automatic docking of the helical microrobot with static targets, including connecting with micro-shafts and inserting into micro-tubes. The object grasping of a reconfigurable helical microrobot aided by 3D automatic docking was also demonstrated. This method enables precise docking of helical microrobots with objects, which might be used for capture and sampling, in vivo navigation control, and functional assembly of microrobots.
基金support of this research by the National Natural Science Foundation of China(Nos.22202171,21922202,and 22272146)the Natural Science Foundation of Jiangsu Basic Research Program(No.BK20220559)+1 种基金the Natural Science Foundation of the Higher Education Institutions of Jiangsu Province(No.22KJD150009)the Jiangsu Specially-Appointed Professor Plan(Z.Xi)from the Jiangsu Education Department。
文摘Rational tuning of chiral nanostructures of supramolecular assemblies as catalysts and investigating their chiral morphology-enantioselectivity dependence is rarely reported. Herein, we report a series of supramolecular M/P-helical nanoribbons(HNs) assembled from the chiral L/D-glutamate-based amphiphiles(L/D-Glu C16) and Cu(Ⅱ) ions, with their helical screw pitches adjusted from 217 nm to 104 nm through the facile regulation of their water/organic solvent assembly environment. They were then used as ideal models to reveal the chiral morphology-enantioselectivity relationship by catalyzing the asymmetric Diels-Alder reaction. Better enantioselectivity was achieved with more twist morphology. Experimental evidences of stronger chiral transfer effect from the supramolecular HNs with more twist to the aza-chalcone as reactant were obtained to understand such dependence. Our study demonstrates a new perspective for designing supramolecular catalysts with higher enantioselectivity.
基金The National Natural Science Foundation of China(No.52171274).
文摘Spiral pile foundations,as a promising type of foundation,are of significant importance for the development of offshore wind energy,particularly as it moves toward deeper waters.This study conducted a physical experiment on a three-spiral-pile jacket foundation under deep-buried sandy soil conditions.During the experiment,horizontal displacement was applied to the structure to thoroughly investigate the bearing characteristics of the three-spiral-pile jacket foundation.This study also focused on analyzing the bearing mechanisms of conventional piles compared with spiral piles with different numbers of blades.Three different working conditions were set up and compared,and key data,such as the horizontal bearing capacity,pile shaft axial force,and spiral blade soil pressure,were measured and analyzed.The results show the distinct impacts of the spiral blades on the compressed and tensioned sides of the foundation.Specifically,on the compressed side,the spiral blades effectively enhance the restraint of the soil on the pile foundation,whereas on the tensioned side,an excessive number of spiral blades can negatively affect the structural tensile performance to some extent.This study also emphasizes that the addition of blades to the side of a single pile is the most effective method for increasing the bearing capacity of the foundation.This research aims to provide design insights into improving the bearing capacity of the foundation.
基金Project(11972112)supported by the National Natural Science Foundation of ChinaProject(N2103024)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(J2019-IV-0018-0086)supported by the National Science and Technology Major Project,China。
文摘Gear assembly errors can lead to the increase of vibration and noise of the system,which affect the stability of system.The influence can be compensated by tooth modification.Firstly,an improved three-dimensional loaded tooth contact analysis(3D-LTCA)method which can consider tooth modification and coupling assembly errors is proposed,and mesh stiffness calculated by proposed method is verified by MASTA software.Secondly,based on neural network,the surrogate model(SM)that maps the relationship between modification parameters and mesh mechanical parameters is established,and its accuracy is verified.Finally,SM is introduced to establish an optimization model with the target of minimizing mesh stiffness variations and obtaining more even load distribution on mesh surface.The results show that even considering training time,the efficiency of gear pair optimization by surrogate model is still much higher than that by LTCA method.After optimization,the mesh stiffness fluctuation of gear pair with coupling assembly error is reduced by 34.10%,and difference in average contact stresses between left and right regions of the mesh surface is reduced by 62.84%.
基金the National Natural Science Foundation of China(22208320)the Science and Technology Program of Henan Province(212102210044)The Henan Association for Science and Technology Youth Talent Support Program(2022HYTP026).
文摘Combining the advantages of high efficiency,low-pressure drop,and large throughput,the pore arrayenhanced tube-in-tube microchannel(PA-TMC) is a promising microreactor for industrial applications.However,most of the mass transfer takes place in the upstream pore region,while the contribution of the downstream annulus is limited.In this work,helical wires were introduced into the annulus by adhering to the outer surface of the inner tube.Mixing behavior and mass transfer of liquid-liquid twophase flow in PA-TMC with different helical wires have been systematically studied by a combination of experiments and volume of fluid(VOF) method.The introduction of helical wires improves the overall volumetric mass transfer coefficient KLa by up to 133% and the mass transfer efficiency E by up to 117%.The simulation results show that the helical wire brings extra phase mixing regions and increases the specific interface area,while accelerating the fluid flow and expanding the area of enhanced turbulent dissipation rate.Influences of helical wires in various configurations are compared by the comprehensive index I concerning the pressure drop and mass transfer performance simultaneously and a new correlation between KLa and specific energy consumption φ is proposed.This research deepens the understanding of the mixing behavior and mass transfer in the PA-TMCs and provides practical experience for the process intensification of microchannel reactors.
基金supported by the National Natural Science Foundation of China(Nos.52273002 and 52333008)the funding of Boya Postdoctoral Fellowship at Peking University,BMS Junior Fellow Program and the National Funding Program for Postdoctoral Researchers(No.GZC20230031).
文摘A series of optically active copolymers with various feed ratios have been synthesized through helix-sense-selective copolymerization catalyzed by[Rh(norbornadiene)Cl]2-triethylamine.This process involves two proline-derived acetylene monomers,(S)-N-(4-chlorophenyl)carbamoyl-2-ethynyl pyrrolidine(MCl)and(S)-N-(tert-butoxycarbonyl)-2-ethynyl pyrrolidine,followed by acidic deprotection and neutralization.These copolymers adopt helical conformations with a preferred handedness,as demonstrated by nuclear magnetic resonance spectroscopy and a series of spectroscopic analyses.The chiroptical activity intensity of copolymer has been found to increase with MCl content.Consequently,the enantioseparation capabilities of copolymers containing 95 mol%,90 mol%,and 85 mol%MCl units have been assessed as chiral stationary phases in high-performance liquid chromatography because of their good chiroptical activities.These chiral stationary phases effectively enantioseparate racemic alcohols,sulfoxides,amides,and metal complexes.Notably,the copolymer with 90 mol%MCl shows superior chiral recognition ability,especially for 1-(2,4-dichlorophenyl)-2-(1H-imidazol-1-yl)ethanol(α=1.19)and 4-methylbenzenesulfinamide(α=1.47).Insights from molecular dynamic simulation and autodock analysis indicate that hydrogen bonding andπ-πstacking interactions between the chiral stationary phases and enantiomers play a key role for successful chiral separation.Our contribution not only demonstrates the importance of hydrogen bonding donor and copolymer chiroptical activity of chiral stationary phases for chiral resolution,but will also provide valuable insights for the future development of novel stationary phases.
基金financially supported by the National Natural Science Foundation of China(Nos.52103145 and 11832007)Science&Technology Department of Sichuan Province(No.2025ZNSFSC0352)State Key Laboratory of Polymer Materials Engineering(No.sklpme-2024-1-03)。
文摘Liquid crystal elastomers(LCEs)exhibit exceptional reversible deformation and unique physical properties owing to their order-disorder phase transition under external stimuli.Among these deformations,helical structures have attracted attention owing to their distinctive configurations and promising applications in biomimetics and microelectronics.However,the helical deformation behavior of fiber actuators is critically influenced by their morphologies and alignments;yet,the underlying mechanisms are not fully understood.Through a two-step azaMichael addition reaction and direct ink writing(DIW)4D printing technology,fiber-based LCE actuators with a core-sheath alignment structure were fabricated and exhibited reversible helical deformation upon heating.By adjusting the printing parameters,the filament number,width,thickness,and core-sheath structure of the fiber actuators can be precisely controlled,resulting in deformation behaviors,such as contraction,bending,and helical twisting.Finite element simulations were performed to investigate the deformation behaviors of the fiber actuators,providing insights into the variations in stress and strain during the shape-changing process,which can be used to explain the shape-morphing mechanism.These findings demonstrate that the precise tuning of printing parameters enables the controllable construction of LCE actuator morphology and customization of their functional properties,paving the way for advanced applications in smart fabrics,biomedical engineering,and flexible electronics.
基金financially supported by the National Key R&D Program of China(No.2022YFB4600500)the National Safety Academic Fund(Nos.U2130201 and U2330105).
文摘NiTi alloy lattice structures are crucial for reusable energy absorption due to their shape memory effects.However,existing NiTi alloy lattice structures always suffer from localized deformation bands during loading,causing local strains to exceed the recoverable strain limit of the alloy and significantly reducing their reusable energy-absorbing capacity.In this study,we developed a NiTi alloy helical lattice structure(HLS)to effectively prevent localized deformation bands.This is attributed to its struts distributing stress and strain uniformly through torsional deformation,thereby alleviating local stress concentrations and suppressing the formation of localized deformation bands.Additionally,its unit cells provide mutual support and reinforcement during deformation,effectively preventing the progression of localized deformation bands.The NiTi alloy HLS exhibits superior reusable energy absorption compared to previously reported reusable energy-absorbing materials/structures and enhanced damage tolerance under large compression strain.This study provides valuable insights for the development of high-performance reusable NiTi alloy energy-absorbing lattice structures.
