Two isostructural helical coordination polymers, {[Cu（dps）2（Hssa）-（H2O）2]＇3H2O}n （1） and {[Mn（dps）2（Hssa）（H2O）2]＇2H2O}n （2）, have been synthesized by the solvothermal reaction of dps and Hsssa with C...Two isostructural helical coordination polymers, {[Cu（dps）2（Hssa）-（H2O）2]＇3H2O}n （1） and {[Mn（dps）2（Hssa）（H2O）2]＇2H2O}n （2）, have been synthesized by the solvothermal reaction of dps and Hsssa with CuCI2 or Mn（CH3COO）2 （dps = 4,4＇-dipyridylsulfide, H3ssa -- 5- sulfosalicylic acid）. Both compounds crystallize in monoclinic, space group P21/n. In either complex, the central metal ion （Cu11 for compound 1 and MnIt for compound 2） is surrounded by one Hssa2- ligand, two coordinated aquas and three dps molecules with a N303 donor set in a distorted octahedral coordination geometry. Half of the dps is monodentate and another half acts as μ2-bridging ligands. It is through the bridging function of dps that the neighbouring metal centers are connected and a one-dimensional helical structure of compound 1 or 2 forms. Fluorescence studies indicate that compounds 1 and 2 have blue emission bands centered at 403 and 405 nm, respectively.展开更多
A new approach to generating supramolecular architectures, based on easy-to-prepare schiff base ligands, is described together with its application to the self-assembly of supramolecular neutral double helicates.
基金supported by the doctor scientific research start-up fund(No.10001076)of Luoyang Normal University
文摘Two isostructural helical coordination polymers, {[Cu（dps）2（Hssa）-（H2O）2]＇3H2O}n （1） and {[Mn（dps）2（Hssa）（H2O）2]＇2H2O}n （2）, have been synthesized by the solvothermal reaction of dps and Hsssa with CuCI2 or Mn（CH3COO）2 （dps = 4,4＇-dipyridylsulfide, H3ssa -- 5- sulfosalicylic acid）. Both compounds crystallize in monoclinic, space group P21/n. In either complex, the central metal ion （Cu11 for compound 1 and MnIt for compound 2） is surrounded by one Hssa2- ligand, two coordinated aquas and three dps molecules with a N303 donor set in a distorted octahedral coordination geometry. Half of the dps is monodentate and another half acts as μ2-bridging ligands. It is through the bridging function of dps that the neighbouring metal centers are connected and a one-dimensional helical structure of compound 1 or 2 forms. Fluorescence studies indicate that compounds 1 and 2 have blue emission bands centered at 403 and 405 nm, respectively.
基金Project supported by the National Nature Science Foundation of China (No. 29771020)Tianjin Natural Science Foundation
文摘A new approach to generating supramolecular architectures, based on easy-to-prepare schiff base ligands, is described together with its application to the self-assembly of supramolecular neutral double helicates.
