The ablation parameters such as threshold fluence, etch depth, ablation rate and the effect of material targets were investigated under the interaction of laser pulse with low intensity. The parameters of the laser sy...The ablation parameters such as threshold fluence, etch depth, ablation rate and the effect of material targets were investigated under the interaction of laser pulse with low intensity. The parameters of the laser system are： laser pulse energy in the range of 110–140 m J, wavelength1064 nm and pulse duration 20 ns. By macroscopic estimation of the outward images of the ablation and data obtained, we can conclude that the photothermal and photoionization processes have more influence for aluminum ablation. In contrast, for polymer samples, from the macroscopic observation of the border pattern at the irradiated spot, and also the data obtained from the experiment results, we deduce that both chemical change due to heating and photochemical dissociation were effective mechanisms of ablation. However, concerning the two polymer samples, apart from considering the same theoretical ablation model, it is conceived that the photomehanical specifications of PMMA are involved in the ablation parameters. The threshold fluence for an ablation rate of 30 laser shots were obtained as 12.4, 24.64, and 11.71 J cm^（-2）, for aluminum, silicon rubber and polymethylmethacrylate（PMMA） respectively.The ablation rate is exponentially decreased by the laser-shot number, especially for aluminum.Furthermore, the etch depth after 30 laser shots was measured as 180, 630 and 870 μm, for aluminum, silicon rubber and PMMA, respectively.展开更多
The primary objective of this study is to develop an innovative theoretical model to accurately predict the thermophysicalproperties of hybrid nanofluids designed to enhance cooling in solar panel applications.This re...The primary objective of this study is to develop an innovative theoretical model to accurately predict the thermophysicalproperties of hybrid nanofluids designed to enhance cooling in solar panel applications.This researchlays the groundwork for our future studies,which will focus on photovoltaic thermal applications.These nanofluidsconsist of water and nanoparticles of alumina(Al_(2)O_(3)),titanium dioxide(TiO_(2)),and copper(Cu),exploringvolumetric concentrations ranging from 0%to 4%for each type of nanoparticle,and up to 10%for total mixtures.The developed model accounts for complex interactions between the nanoparticles and the base fluid,as well assynergistic effects resulting from the coexistence of different nanoparticles.Detailed simulations have shownexceptional agreement with experimental results,reinforcing the credibility of our approach in accurately capturingthe thermophysical behavior of these hybrid nanofluids.Based on these results,our study proposes significantadvancements in the design and optimization of nanofluids for cooling applications in solar panels.These developmentsare crucial for improving the efficiency of solar installations by mitigating overheating effects,providinga solid foundation for practical applications in this rapidly evolving field.展开更多
The generalized α-model for anisotropic two-band superconductivity is consistently constructed with the consideration of weak interband electron–electron interaction.Tailored from the two-band BCS theory,the develop...The generalized α-model for anisotropic two-band superconductivity is consistently constructed with the consideration of weak interband electron–electron interaction.Tailored from the two-band BCS theory,the developed framework can be applied to investigate thermodynamic properties of intraband strong-coupling superconductors.Accordingly,we perform a calculation on the temperature dependence of specific heat and obtain an analytic expression for specific heat jump at the superconducting critical temperature.Meanwhile,we also compute the superfluid density and the spin susceptibility with this formalism.Given the low-temperature superconducting gaps from experimental measurement,all of our theoretical results can fit the experimental data of the layered two-band superconductor NbSe_(2) well.展开更多
We attempt to compute the Surface Average Heat Flow （SAHF） from long-term temperature observations of one hundred seventy-seven observational points at the depths of 0.8, 1.6, and 3.2 m, which were relatively evenly...We attempt to compute the Surface Average Heat Flow （SAHF） from long-term temperature observations of one hundred seventy-seven observational points at the depths of 0.8, 1.6, and 3.2 m, which were relatively evenly distributed in China's Mainland. We first employ Fourier transformation to remove the influence of atmospheric temperature variations from the observation series, which are classified into the type of the steady-state temperature monotonously increasing with depth （type I） and other three types. Then we compare our results obtained from the data of type I, of which the values are thought to equal to those of the mean borehole heat flow, with those obtained from traditional heat flow observations mainly distributed in North China Craton. In computations of the SAHF at the observation stations, we deduce the thermal diffusivity and volumetric specific heat of the soil by employing harmonic solutions of the heat conduction equation for the same moisture group as the first step, and then we determine the SAHF using Fourier＇s law. Our results indicate that the SAHF derived from shallow earth geothermal data can reflect the heat flow field to a large extent.展开更多
The specific heat capacities of Cu60Zr20Hfl0Til0 bulk metallic glass （BMG） and crystallized alloys were measured from 2 to 101 K. The effect of crystallization on the specific heat capacity of the BMG was studied. T...The specific heat capacities of Cu60Zr20Hfl0Til0 bulk metallic glass （BMG） and crystallized alloys were measured from 2 to 101 K. The effect of crystallization on the specific heat capacity of the BMG was studied. The effects of crystallization and the relationship between local modes and boson peak in the BMG were discussed. The specific heat capacity deviates from the simple Debye behaviors, showing the presence of local harmonic modes （Einstein oscillator） in the BMG and the crystallized alloy. Model calculation includes the contribution of one Debye mode and two Einstein modes for the BMG, one Debye mode and one Einstein mode for the crystallized alloy, showing an adequate description of the experimental data.展开更多
In order to effectively utilize the resources and energy of molten steel slag,the variation of precipitation phase and specific heat of air quenched steel slag(AQSS)particles during continuous cooling process was inve...In order to effectively utilize the resources and energy of molten steel slag,the variation of precipitation phase and specific heat of air quenched steel slag(AQSS)particles during continuous cooling process was investigated by FactSage and thermogravimetry differential scanning calorimetry.The cooling and solidification process of molten AQSS particles was simulated by Fluent.The microstructure changes in AQSS particles in solidification process were analyzed using an ultrahigh temperature laser confocal microscope and a scanning electron microscope.The results indicated that in the cooling process of molten AQSS particles,the precipitation of Ca_(2)Fe_(2)O_(5) resulted in the largest change of specific heat.Under the condition of slow cooling,the cooling rate is more obviously affected by specific heat.When the initial air velocity was 300 m s^(-1),there was the highest temperature difference in AQSS particles during cooling process.What is more,the compactness of the boundary region of AQSS particles was obviously better than that of its central region.展开更多
Arrhenius law implicates that only those molecules which possess the internal energy greater than the activation energy Ea can react. However, the internal energy will not be proportional to the gas temperature if the...Arrhenius law implicates that only those molecules which possess the internal energy greater than the activation energy Ea can react. However, the internal energy will not be proportional to the gas temperature if the specific heat ratio y and the gas constant R vary during chemical reaction processes. The varying y may affect significantly the chemical reaction rate calculated with the Arrhenius law under the constant γ assumption, which has been widely accepted in detonation and combustion simulations for many years. In this paper, the roles of variable γ and R in Arrhenius law applications are reconsidered, and their effects on the chemical reaction rate are demonstrated by simulating one- dimensional C-J and two-dimensional cellular detonations. A new overall one-step detonation model with variable γ and R is proposed to improve the Arrhenius law. Numerical experiments demonstrate that this improved Arrhenius law works well in predicting detonation phenomena with the numerical results being in good agreement with experimental data.展开更多
The thermal behavior,non-isothermal thermal decomposition reaction kinetics and specific heat capacity of hexanitro-hexaazaisowurtzitane(HNIW)were studied by differential scanning calorimeter(DSC)and Micro-DSCIapparat...The thermal behavior,non-isothermal thermal decomposition reaction kinetics and specific heat capacity of hexanitro-hexaazaisowurtzitane(HNIW)were studied by differential scanning calorimeter(DSC)and Micro-DSCIapparatus,The kinetic parameters of the thermal decomposition reaction(the apparent activation energy(E,)and pre-exponential factor(A))were calcu-lated by non-isothermal DSC curves.The results show that the differential mlechanism function and values of E,and A of the ther-mal decomposition reaction of HNIW are 3(1-a)[-ln(1-a)]"·,155.04 kJ·mol^(-1)and 10""s^(-1),respectively.The critical tem-perature of thermal explosion of the title compound is 226.60℃.The entropy of activation(AS·),enthalpy of activation(AH·)and free energy of activation(AG·)of this reaction are 11.60J·mol·K^(-1),152.04 kJ·mol^(-1)and 146.29 kJ·mol^(-1),respec-tively.The equation of specific heat capacity of HNIW with temperature is C,=0.2472+0.002705992Tin the temperature range of 283 K to 343K.The values of self-accelerating decomposition temperature,adiabatic time-to-maximum decomposition rate and adiabatic time-to-explosion are 486.5K,54.81s and 54.31s,respectively.Thermal sensitivity probability density distribution curve of HNIW is constructed.展开更多
A new lattice Boltzmann model for compressible perfect gas is proposed. The numerical example shows that it can be used to simulate shock wave and contact discontinuity. The results are comparable with those obtained ...A new lattice Boltzmann model for compressible perfect gas is proposed. The numerical example shows that it can be used to simulate shock wave and contact discontinuity. The results are comparable with those obtained by traditional methods. The ratio of specific heats gamma may be chosen according to the requirement of problems.展开更多
The correct determination of thermal parameters,such as thermal conductivity and specific heat of soil during freezing,is the most important and basic problem for the construction of an appropriate freezing method.In ...The correct determination of thermal parameters,such as thermal conductivity and specific heat of soil during freezing,is the most important and basic problem for the construction of an appropriate freezing method.In this study,a calculation model of three stages of soil temperature was established.At the unfrozen and frozen stages,the specific temperatures of dry soil,water,and ice are known.According to the principle of superposition,a calculation model of unfrozen and frozen soils can be established.Informed by a laboratory experiment,the latent heat of the adjacent zone was calculated for the freezing stage based on different water contents in the temperature section.Both the latent and specific heat of water,ice,and particles were calculated via superposition of the weight percentage content.A calculation model of the specific heat of the freezing stage was built,which provides both guidance and theoretical basis for the calculation of the specific heat of frozen soil.展开更多
N-（2,3-Dimethyl-phenyl）-N＇-（methoxyl formyl）thiourea was synthesized by the reacting of 2,3-dimethylaniline,potassium thiocyanate（KSCN） and methyl chloroformate（ClCOOCH 3）.Single crystal was obtained by slowl...N-（2,3-Dimethyl-phenyl）-N＇-（methoxyl formyl）thiourea was synthesized by the reacting of 2,3-dimethylaniline,potassium thiocyanate（KSCN） and methyl chloroformate（ClCOOCH 3）.Single crystal was obtained by slowly evaporation solvent at room temperature.The structure was characterized by elemental analysis,IR and X-ray crystalography.The compound crystallized：a triclinic system with space group Pī,a=0.83440（12） nm,b=0.89113（13） nm,c=0.93015（13） nm,α=76.548（2） o,β=63.906（2） o,γ=82.538（2） o,V=0.60379（15） nm 3,Z=2,D c =1.311 mg/m 3,F（000）=252,μ=0.256 mm-1,R 1 =0.0379,wR 2 =0.0919.The specific heat capacity of the title compound was determined by a Micro-DSC method,and the specific heat capacity was 1.25 J·g-1 ·K-1 at 298.15 K.Thermodynamic functions,relative to those at the standard temperature of 298.15 K,were calculated via thermodynamic relationship.The thermal behavior of the title compound under a non-isothermal condition was studied by differential scanning calorimetry/thermogravimetric（DSC/TG） method.There was an obvious endothermic peak in the DSC curve,the peak temperature was 479.43 K.The compound mass loss was 89.94% observed from the TG curve.展开更多
The gas temperature within hypersonic boundary layer flow is so high that the specific heat of gas is no longer a constant but relates to temperature. How variable specific heat influences on boundary layer flow stabi...The gas temperature within hypersonic boundary layer flow is so high that the specific heat of gas is no longer a constant but relates to temperature. How variable specific heat influences on boundary layer flow stability is worth researching. The effect of the variable specific heat on the stability of hypersonic boundary layer flows is studied and compared with the case of constant specific heat based on the linear stability theory. It is found that the variable specific heat indeed has some effects on the neutral curves of both the first-mode and the second-mode waves and on the maximum rate of growth also. Therefore, the relationship between specific heat and temperature should be considered in the study of the stability of the boundary layer.展开更多
The magnetic effect and the magnetocaloric effect in La_2NiMnO_6（LNMO） double perovskite are studied using the Monte Carlo simulations.The magnetizations,specific heat values,and magnetic entropies are obtained for ...The magnetic effect and the magnetocaloric effect in La_2NiMnO_6（LNMO） double perovskite are studied using the Monte Carlo simulations.The magnetizations,specific heat values,and magnetic entropies are obtained for different exchange interactions and external magnetic fields.The adiabatic temperature is obtained.The transition temperature is deduced.The relative cooling power is established with a fixed value of exchange interaction.According to the master curve behaviors for the temperature dependence of △S_m^（max） predicted for different maximum fields,in this work it is confirmed that the paramagnetic-ferromagnetic phase transition observed for our sample is of a second order.The near room-temperature interaction and the superexchange interaction between Ni and Mn are shown to be due to the ferromagnetism of LNMO.展开更多
A novel process was proposed to strengthen the decomposition of the mixed rare earth concentrate by utilizing the microwave radiation.Mineralogical information on the mechanisms by which microwave heating improved the...A novel process was proposed to strengthen the decomposition of the mixed rare earth concentrate by utilizing the microwave radiation.Mineralogical information on the mechanisms by which microwave heating improved the leaching behavior of rare earth elements（REEs）,and an interpretation of the interrelationship between mineralogy,decomposition process,and leaching process were provided in this study.The influences of the temperature,time of microwave heating and contents of NaO H（mass ratio of NaO H to mixed rare earth concentrate）on the decomposition of mixed rare earth concentrate were investigated.The results revealed that the temperature was the main factor affecting the decomposition process.The recovery of REEs by hydrochloric acid leaching reached 93.28% under the microwave heating conditions：140 oC,30 min and 35.35% NaO H.The BET specific surface area and SEM analysis indicated that the particles of mixed rare earth concentrate were non-hole,while the particles presented a porous structure after heating the concentrate by microwave radiation.For the microwave treated sample after water leaching,the BET specific surface area was 11.04 m^2/g,which was higher than the corresponding values（6.94 m^2/g）for the mixed rare earth concentrate.This result could be attributed to the phase changes of bastnaesite and monazite,and a number of cracks induced by thermal stress.The increase of BET specific surface area resulted in an increase of the recovery of REEs by promoting interaction within the system of acid leaching.展开更多
On the basis of a generalized SSH model, an organic polymer ferromagnet theory is proposed at the finite temperature in the self-consistent mean field approximation, and the specific heat and charge density of the qua...On the basis of a generalized SSH model, an organic polymer ferromagnet theory is proposed at the finite temperature in the self-consistent mean field approximation, and the specific heat and charge density of the quasione-dimensional interehain coupling organic ferromagnets are presented. We find that an obvious feature is to present itself the round peak for the specific heat with the temperature. This indicates unambiguously the presence of the phase transition in the system. The transition temperature plays down with increasing of the interchain coupling t2 or decreasing of the electron repulsion u. The curves of charge density with the temperature debase monotonously. This result illustrates that the higher the temperature is, the more electrons are excited.展开更多
We report the pronounced low-temperature specific-heat Cpanomalies in the Mg_(59.5)Cu_(22.9)Ag_(6.6)Gd_(11)bulk metallic glass(BMG).The extrapolated electron’s temperature coefficientγ0Kis up to 681.8 mJ/(molGd·...We report the pronounced low-temperature specific-heat Cpanomalies in the Mg_(59.5)Cu_(22.9)Ag_(6.6)Gd_(11)bulk metallic glass(BMG).The extrapolated electron’s temperature coefficientγ0Kis up to 681.8 mJ/(molGd·K^(2))at 0 K,which is a heavy-fermion-like behavior.The low temperature specific heat indicates an enhancement of the conduction-electron effective mass m*below 7.5 K,suggesting that the Mg_(59.5)Cu_(22.9)Ag_(6.6)Gd_(11)BMG is not free-electron-like solid.The excess specific heat in the Mg-based BMG is interpreted with tunneling states and spin glass state(magnetism)which are determined by subtracting electrons’and phonons’contribution to the specific heat below 12 K.The Boson peak(BP)temperature is located at 27 K,which is much higher than the reported values of other BMGs.And,a BP height of 0.047 mJ/(mol·K^(4))is obtained due to reduced free volume during copper mold casting with a slow cooling rate.The electrical resistivity was also investigated between 2 and 300 K,which has a negative temperature coefficient of resistivity(TCR)below 35 K(Kondo temperature,TK)and a positive value of 3.9×10^(-4)/K above 35 K.There is a minimum at about 35 K for the electrical resistivity,which can be explained by the Kondo effect.For the resistivity above 35 K,it can be explained by the FaberZiman model due to the T-dependence change of structure factor.展开更多
Nanofluids are extensively applied in various heat transfer mediums for improving their heat transfer characteristics and hence their performance.Specific heat capacity of nanofluids,as one of the thermophysical prope...Nanofluids are extensively applied in various heat transfer mediums for improving their heat transfer characteristics and hence their performance.Specific heat capacity of nanofluids,as one of the thermophysical properties,performs principal role in heat transfer of thermal mediums utilizing nanofluids.In this regard,different studies have been carried out to investigate the influential factors on nanofluids specific heat.Moreover,several regression models based on correlations or artificial intelligence have been developed for forecasting this property of nanofluids.In the current review paper,influential parameters on the specific heat capacity of nanofluids are introduced.Afterwards,the proposed models for their forecasting and modeling are proposed.According to the reviewed works,concentration and properties of solid structures in addition to temperature affect specific heat capacity to large extent and must be considered as inputs for the models.Moreover,by using other effective factors,the accuracy and comprehensive of the models can be modified.Finally,some suggestions are offered for the upcoming works in the relevant topics.展开更多
A real-time sensing of the molecular distillation process temperature by a FLUKE brand thermograph Ti50 IR FlexCam and thermography technique was realized. After completion of the molecular distillation, three propert...A real-time sensing of the molecular distillation process temperature by a FLUKE brand thermograph Ti50 IR FlexCam and thermography technique was realized. After completion of the molecular distillation, three properties of heat transport chain cuts and residues obtained in the process were estimated by Differential Scanning Calorimetry （DSC） （specific heat, enthalpy, thermal conductivity）. These properties are of great importance for improving oil characterization and for future modeling and simulation of the molecular distillation process. The results show that through the method of Differential Scanning Calorimetry, profiles have been obtained from the variation of specific heat, enthalpy and thermal condutivity as a function of temperature for samples of cuts from the distillation （ASTM D-2892） and fractions of distillate and residue from the process of molecular distillation.展开更多
Thermal diffusivity, specific heat capacity and thermal conductivity of AI86Gd6TM8 （TM = Cu, Ni, Co, Fe, Mn, Cr, Ti, Zr, Mo, Ta） glass-forming alloys in the temperature range of 300-880 K were determined by laser fl...Thermal diffusivity, specific heat capacity and thermal conductivity of AI86Gd6TM8 （TM = Cu, Ni, Co, Fe, Mn, Cr, Ti, Zr, Mo, Ta） glass-forming alloys in the temperature range of 300-880 K were determined by laser flash method. The temperatures of endothermic and exothermic reactions of the alloys were determined by differential scanning calorimetry method. The alloys were prepared by conventional arc-melting technique under helium atmosphere. All the alloys studied exhibit strong supercooling of the liquidus temperatures up to 80 K, which indicates their good glass-forming ability. The specific heat capacity of the alloys achieves the Dulong-Petit＇s value in the temperature range of 350-550 K except Als6CrsGd6 and Als6ZrsGd6 compositions. The values of both thermal diffusivity and thermal conductivity of the alloy studied are significantly lower than those for pure aluminum. It is found that embedding 14% （mole fraction） of transition elements （Gd＋TM） in the aluminum matrix leads to significant decrease in the absolute magnitudes of both thermal diffusivity and thermal conductivity in crystalline state. The thermal conductivity of glass-forming Als6Gd6TMs alloys is strongly affected by directed chemical bonding between alloy components.展开更多
The thermal decomposition process was studied by the TG–DTA analyzer. The results show that the decomposition process of sodium hydroxyethyl sulfonate consisted of three stages: the mass loss for the first, the secon...The thermal decomposition process was studied by the TG–DTA analyzer. The results show that the decomposition process of sodium hydroxyethyl sulfonate consisted of three stages: the mass loss for the first, the second and third stages may be about the groups of CH_3CH_2OH, CH_3CHO and SO_2 volatilized, respectively. The decomposition residuum of three stages was analyzed by FT-IR, and the results of FT-IR agreed with the decomposition process predicted by theoretical weight loss. The specific heat capacity of sodium hydroxyethyl sulfonate was determined by differential scanning calorimetry(DSC). The melting temperature and melting enthalpy were obtained to be 465.41 K and 25.69 kJ·mol^(-1), respectively. The molar specific heat capacity of sodium hydroxyethyl sulfonate was determinated from 310.15 K to 365.15 K and expressed as a function of temperature.展开更多
文摘The ablation parameters such as threshold fluence, etch depth, ablation rate and the effect of material targets were investigated under the interaction of laser pulse with low intensity. The parameters of the laser system are： laser pulse energy in the range of 110–140 m J, wavelength1064 nm and pulse duration 20 ns. By macroscopic estimation of the outward images of the ablation and data obtained, we can conclude that the photothermal and photoionization processes have more influence for aluminum ablation. In contrast, for polymer samples, from the macroscopic observation of the border pattern at the irradiated spot, and also the data obtained from the experiment results, we deduce that both chemical change due to heating and photochemical dissociation were effective mechanisms of ablation. However, concerning the two polymer samples, apart from considering the same theoretical ablation model, it is conceived that the photomehanical specifications of PMMA are involved in the ablation parameters. The threshold fluence for an ablation rate of 30 laser shots were obtained as 12.4, 24.64, and 11.71 J cm^（-2）, for aluminum, silicon rubber and polymethylmethacrylate（PMMA） respectively.The ablation rate is exponentially decreased by the laser-shot number, especially for aluminum.Furthermore, the etch depth after 30 laser shots was measured as 180, 630 and 870 μm, for aluminum, silicon rubber and PMMA, respectively.
文摘The primary objective of this study is to develop an innovative theoretical model to accurately predict the thermophysicalproperties of hybrid nanofluids designed to enhance cooling in solar panel applications.This researchlays the groundwork for our future studies,which will focus on photovoltaic thermal applications.These nanofluidsconsist of water and nanoparticles of alumina(Al_(2)O_(3)),titanium dioxide(TiO_(2)),and copper(Cu),exploringvolumetric concentrations ranging from 0%to 4%for each type of nanoparticle,and up to 10%for total mixtures.The developed model accounts for complex interactions between the nanoparticles and the base fluid,as well assynergistic effects resulting from the coexistence of different nanoparticles.Detailed simulations have shownexceptional agreement with experimental results,reinforcing the credibility of our approach in accurately capturingthe thermophysical behavior of these hybrid nanofluids.Based on these results,our study proposes significantadvancements in the design and optimization of nanofluids for cooling applications in solar panels.These developmentsare crucial for improving the efficiency of solar installations by mitigating overheating effects,providinga solid foundation for practical applications in this rapidly evolving field.
文摘The generalized α-model for anisotropic two-band superconductivity is consistently constructed with the consideration of weak interband electron–electron interaction.Tailored from the two-band BCS theory,the developed framework can be applied to investigate thermodynamic properties of intraband strong-coupling superconductors.Accordingly,we perform a calculation on the temperature dependence of specific heat and obtain an analytic expression for specific heat jump at the superconducting critical temperature.Meanwhile,we also compute the superfluid density and the spin susceptibility with this formalism.Given the low-temperature superconducting gaps from experimental measurement,all of our theoretical results can fit the experimental data of the layered two-band superconductor NbSe_(2) well.
基金supported by the National Natural Science Foundation of China(Grant No.4087404741174084)
文摘We attempt to compute the Surface Average Heat Flow （SAHF） from long-term temperature observations of one hundred seventy-seven observational points at the depths of 0.8, 1.6, and 3.2 m, which were relatively evenly distributed in China's Mainland. We first employ Fourier transformation to remove the influence of atmospheric temperature variations from the observation series, which are classified into the type of the steady-state temperature monotonously increasing with depth （type I） and other three types. Then we compare our results obtained from the data of type I, of which the values are thought to equal to those of the mean borehole heat flow, with those obtained from traditional heat flow observations mainly distributed in North China Craton. In computations of the SAHF at the observation stations, we deduce the thermal diffusivity and volumetric specific heat of the soil by employing harmonic solutions of the heat conduction equation for the same moisture group as the first step, and then we determine the SAHF using Fourier＇s law. Our results indicate that the SAHF derived from shallow earth geothermal data can reflect the heat flow field to a large extent.
基金Project(082102230035)supported by the Foundation of Science and Technology Department of Henan Province,China
文摘The specific heat capacities of Cu60Zr20Hfl0Til0 bulk metallic glass （BMG） and crystallized alloys were measured from 2 to 101 K. The effect of crystallization on the specific heat capacity of the BMG was studied. The effects of crystallization and the relationship between local modes and boson peak in the BMG were discussed. The specific heat capacity deviates from the simple Debye behaviors, showing the presence of local harmonic modes （Einstein oscillator） in the BMG and the crystallized alloy. Model calculation includes the contribution of one Debye mode and two Einstein modes for the BMG, one Debye mode and one Einstein mode for the crystallized alloy, showing an adequate description of the experimental data.
基金This work was supported by the Natural Science Foundation of Chongqing,China(Project No.cstc2020jcyj-msxmX0043)the Fundamental Research Funds for the Central Universities(Project No.2020CDJ-LHZZ-084)the National Natural Science Foundation of China(No.51974047).
文摘In order to effectively utilize the resources and energy of molten steel slag,the variation of precipitation phase and specific heat of air quenched steel slag(AQSS)particles during continuous cooling process was investigated by FactSage and thermogravimetry differential scanning calorimetry.The cooling and solidification process of molten AQSS particles was simulated by Fluent.The microstructure changes in AQSS particles in solidification process were analyzed using an ultrahigh temperature laser confocal microscope and a scanning electron microscope.The results indicated that in the cooling process of molten AQSS particles,the precipitation of Ca_(2)Fe_(2)O_(5) resulted in the largest change of specific heat.Under the condition of slow cooling,the cooling rate is more obviously affected by specific heat.When the initial air velocity was 300 m s^(-1),there was the highest temperature difference in AQSS particles during cooling process.What is more,the compactness of the boundary region of AQSS particles was obviously better than that of its central region.
文摘Arrhenius law implicates that only those molecules which possess the internal energy greater than the activation energy Ea can react. However, the internal energy will not be proportional to the gas temperature if the specific heat ratio y and the gas constant R vary during chemical reaction processes. The varying y may affect significantly the chemical reaction rate calculated with the Arrhenius law under the constant γ assumption, which has been widely accepted in detonation and combustion simulations for many years. In this paper, the roles of variable γ and R in Arrhenius law applications are reconsidered, and their effects on the chemical reaction rate are demonstrated by simulating one- dimensional C-J and two-dimensional cellular detonations. A new overall one-step detonation model with variable γ and R is proposed to improve the Arrhenius law. Numerical experiments demonstrate that this improved Arrhenius law works well in predicting detonation phenomena with the numerical results being in good agreement with experimental data.
基金The National Nature Science Foundation of China(21173163)
文摘The thermal behavior,non-isothermal thermal decomposition reaction kinetics and specific heat capacity of hexanitro-hexaazaisowurtzitane(HNIW)were studied by differential scanning calorimeter(DSC)and Micro-DSCIapparatus,The kinetic parameters of the thermal decomposition reaction(the apparent activation energy(E,)and pre-exponential factor(A))were calcu-lated by non-isothermal DSC curves.The results show that the differential mlechanism function and values of E,and A of the ther-mal decomposition reaction of HNIW are 3(1-a)[-ln(1-a)]"·,155.04 kJ·mol^(-1)and 10""s^(-1),respectively.The critical tem-perature of thermal explosion of the title compound is 226.60℃.The entropy of activation(AS·),enthalpy of activation(AH·)and free energy of activation(AG·)of this reaction are 11.60J·mol·K^(-1),152.04 kJ·mol^(-1)and 146.29 kJ·mol^(-1),respec-tively.The equation of specific heat capacity of HNIW with temperature is C,=0.2472+0.002705992Tin the temperature range of 283 K to 343K.The values of self-accelerating decomposition temperature,adiabatic time-to-maximum decomposition rate and adiabatic time-to-explosion are 486.5K,54.81s and 54.31s,respectively.Thermal sensitivity probability density distribution curve of HNIW is constructed.
基金The project supported by the National Natural Science Foundation of China
文摘A new lattice Boltzmann model for compressible perfect gas is proposed. The numerical example shows that it can be used to simulate shock wave and contact discontinuity. The results are comparable with those obtained by traditional methods. The ratio of specific heats gamma may be chosen according to the requirement of problems.
基金This work was supported by the National Natural Science Foundation of China(No.41472253)the Key project of Natural Science Foundation of Tianjin City(No.6JCZDJC39000).
文摘The correct determination of thermal parameters,such as thermal conductivity and specific heat of soil during freezing,is the most important and basic problem for the construction of an appropriate freezing method.In this study,a calculation model of three stages of soil temperature was established.At the unfrozen and frozen stages,the specific temperatures of dry soil,water,and ice are known.According to the principle of superposition,a calculation model of unfrozen and frozen soils can be established.Informed by a laboratory experiment,the latent heat of the adjacent zone was calculated for the freezing stage based on different water contents in the temperature section.Both the latent and specific heat of water,ice,and particles were calculated via superposition of the weight percentage content.A calculation model of the specific heat of the freezing stage was built,which provides both guidance and theoretical basis for the calculation of the specific heat of frozen soil.
基金Supported by the National Natural Science Foundation of China(No.20571060)the Natural Science Foundation of Shaanxi Province,China(No.2007B08)
文摘N-（2,3-Dimethyl-phenyl）-N＇-（methoxyl formyl）thiourea was synthesized by the reacting of 2,3-dimethylaniline,potassium thiocyanate（KSCN） and methyl chloroformate（ClCOOCH 3）.Single crystal was obtained by slowly evaporation solvent at room temperature.The structure was characterized by elemental analysis,IR and X-ray crystalography.The compound crystallized：a triclinic system with space group Pī,a=0.83440（12） nm,b=0.89113（13） nm,c=0.93015（13） nm,α=76.548（2） o,β=63.906（2） o,γ=82.538（2） o,V=0.60379（15） nm 3,Z=2,D c =1.311 mg/m 3,F（000）=252,μ=0.256 mm-1,R 1 =0.0379,wR 2 =0.0919.The specific heat capacity of the title compound was determined by a Micro-DSC method,and the specific heat capacity was 1.25 J·g-1 ·K-1 at 298.15 K.Thermodynamic functions,relative to those at the standard temperature of 298.15 K,were calculated via thermodynamic relationship.The thermal behavior of the title compound under a non-isothermal condition was studied by differential scanning calorimetry/thermogravimetric（DSC/TG） method.There was an obvious endothermic peak in the DSC curve,the peak temperature was 479.43 K.The compound mass loss was 89.94% observed from the TG curve.
基金Project supported by the National Natural Science Foundation of China (Nos. 10772134 and90716007)
文摘The gas temperature within hypersonic boundary layer flow is so high that the specific heat of gas is no longer a constant but relates to temperature. How variable specific heat influences on boundary layer flow stability is worth researching. The effect of the variable specific heat on the stability of hypersonic boundary layer flows is studied and compared with the case of constant specific heat based on the linear stability theory. It is found that the variable specific heat indeed has some effects on the neutral curves of both the first-mode and the second-mode waves and on the maximum rate of growth also. Therefore, the relationship between specific heat and temperature should be considered in the study of the stability of the boundary layer.
文摘The magnetic effect and the magnetocaloric effect in La_2NiMnO_6（LNMO） double perovskite are studied using the Monte Carlo simulations.The magnetizations,specific heat values,and magnetic entropies are obtained for different exchange interactions and external magnetic fields.The adiabatic temperature is obtained.The transition temperature is deduced.The relative cooling power is established with a fixed value of exchange interaction.According to the master curve behaviors for the temperature dependence of △S_m^（max） predicted for different maximum fields,in this work it is confirmed that the paramagnetic-ferromagnetic phase transition observed for our sample is of a second order.The near room-temperature interaction and the superexchange interaction between Ni and Mn are shown to be due to the ferromagnetism of LNMO.
基金Project supported by the National Basic Research Program of China(973 program,2012CBA01205)
文摘A novel process was proposed to strengthen the decomposition of the mixed rare earth concentrate by utilizing the microwave radiation.Mineralogical information on the mechanisms by which microwave heating improved the leaching behavior of rare earth elements（REEs）,and an interpretation of the interrelationship between mineralogy,decomposition process,and leaching process were provided in this study.The influences of the temperature,time of microwave heating and contents of NaO H（mass ratio of NaO H to mixed rare earth concentrate）on the decomposition of mixed rare earth concentrate were investigated.The results revealed that the temperature was the main factor affecting the decomposition process.The recovery of REEs by hydrochloric acid leaching reached 93.28% under the microwave heating conditions：140 oC,30 min and 35.35% NaO H.The BET specific surface area and SEM analysis indicated that the particles of mixed rare earth concentrate were non-hole,while the particles presented a porous structure after heating the concentrate by microwave radiation.For the microwave treated sample after water leaching,the BET specific surface area was 11.04 m^2/g,which was higher than the corresponding values（6.94 m^2/g）for the mixed rare earth concentrate.This result could be attributed to the phase changes of bastnaesite and monazite,and a number of cracks induced by thermal stress.The increase of BET specific surface area resulted in an increase of the recovery of REEs by promoting interaction within the system of acid leaching.
基金National Natural Science Foundation of China under Grant Nos.10574047 and 20490210
文摘On the basis of a generalized SSH model, an organic polymer ferromagnet theory is proposed at the finite temperature in the self-consistent mean field approximation, and the specific heat and charge density of the quasione-dimensional interehain coupling organic ferromagnets are presented. We find that an obvious feature is to present itself the round peak for the specific heat with the temperature. This indicates unambiguously the presence of the phase transition in the system. The transition temperature plays down with increasing of the interchain coupling t2 or decreasing of the electron repulsion u. The curves of charge density with the temperature debase monotonously. This result illustrates that the higher the temperature is, the more electrons are excited.
基金Project supported by the National Natural Science Foundation of China(52171184,51771220,51771095)the Zhejiang Provincial Natural Science Foundation of China(LD19E010001)。
文摘We report the pronounced low-temperature specific-heat Cpanomalies in the Mg_(59.5)Cu_(22.9)Ag_(6.6)Gd_(11)bulk metallic glass(BMG).The extrapolated electron’s temperature coefficientγ0Kis up to 681.8 mJ/(molGd·K^(2))at 0 K,which is a heavy-fermion-like behavior.The low temperature specific heat indicates an enhancement of the conduction-electron effective mass m*below 7.5 K,suggesting that the Mg_(59.5)Cu_(22.9)Ag_(6.6)Gd_(11)BMG is not free-electron-like solid.The excess specific heat in the Mg-based BMG is interpreted with tunneling states and spin glass state(magnetism)which are determined by subtracting electrons’and phonons’contribution to the specific heat below 12 K.The Boson peak(BP)temperature is located at 27 K,which is much higher than the reported values of other BMGs.And,a BP height of 0.047 mJ/(mol·K^(4))is obtained due to reduced free volume during copper mold casting with a slow cooling rate.The electrical resistivity was also investigated between 2 and 300 K,which has a negative temperature coefficient of resistivity(TCR)below 35 K(Kondo temperature,TK)and a positive value of 3.9×10^(-4)/K above 35 K.There is a minimum at about 35 K for the electrical resistivity,which can be explained by the Kondo effect.For the resistivity above 35 K,it can be explained by the FaberZiman model due to the T-dependence change of structure factor.
基金This work was supported by College of Engineering and Technology,the American University of the Middle East,Kuwait.Homepage:https://www.aum.edu.kw.
文摘Nanofluids are extensively applied in various heat transfer mediums for improving their heat transfer characteristics and hence their performance.Specific heat capacity of nanofluids,as one of the thermophysical properties,performs principal role in heat transfer of thermal mediums utilizing nanofluids.In this regard,different studies have been carried out to investigate the influential factors on nanofluids specific heat.Moreover,several regression models based on correlations or artificial intelligence have been developed for forecasting this property of nanofluids.In the current review paper,influential parameters on the specific heat capacity of nanofluids are introduced.Afterwards,the proposed models for their forecasting and modeling are proposed.According to the reviewed works,concentration and properties of solid structures in addition to temperature affect specific heat capacity to large extent and must be considered as inputs for the models.Moreover,by using other effective factors,the accuracy and comprehensive of the models can be modified.Finally,some suggestions are offered for the upcoming works in the relevant topics.
文摘A real-time sensing of the molecular distillation process temperature by a FLUKE brand thermograph Ti50 IR FlexCam and thermography technique was realized. After completion of the molecular distillation, three properties of heat transport chain cuts and residues obtained in the process were estimated by Differential Scanning Calorimetry （DSC） （specific heat, enthalpy, thermal conductivity）. These properties are of great importance for improving oil characterization and for future modeling and simulation of the molecular distillation process. The results show that through the method of Differential Scanning Calorimetry, profiles have been obtained from the variation of specific heat, enthalpy and thermal condutivity as a function of temperature for samples of cuts from the distillation （ASTM D-2892） and fractions of distillate and residue from the process of molecular distillation.
基金Project(13-02-96036) supported by RFBR and the Government of Sverdlovsk Region of Russia
文摘Thermal diffusivity, specific heat capacity and thermal conductivity of AI86Gd6TM8 （TM = Cu, Ni, Co, Fe, Mn, Cr, Ti, Zr, Mo, Ta） glass-forming alloys in the temperature range of 300-880 K were determined by laser flash method. The temperatures of endothermic and exothermic reactions of the alloys were determined by differential scanning calorimetry method. The alloys were prepared by conventional arc-melting technique under helium atmosphere. All the alloys studied exhibit strong supercooling of the liquidus temperatures up to 80 K, which indicates their good glass-forming ability. The specific heat capacity of the alloys achieves the Dulong-Petit＇s value in the temperature range of 350-550 K except Als6CrsGd6 and Als6ZrsGd6 compositions. The values of both thermal diffusivity and thermal conductivity of the alloy studied are significantly lower than those for pure aluminum. It is found that embedding 14% （mole fraction） of transition elements （Gd＋TM） in the aluminum matrix leads to significant decrease in the absolute magnitudes of both thermal diffusivity and thermal conductivity in crystalline state. The thermal conductivity of glass-forming Als6Gd6TMs alloys is strongly affected by directed chemical bonding between alloy components.
文摘The thermal decomposition process was studied by the TG–DTA analyzer. The results show that the decomposition process of sodium hydroxyethyl sulfonate consisted of three stages: the mass loss for the first, the second and third stages may be about the groups of CH_3CH_2OH, CH_3CHO and SO_2 volatilized, respectively. The decomposition residuum of three stages was analyzed by FT-IR, and the results of FT-IR agreed with the decomposition process predicted by theoretical weight loss. The specific heat capacity of sodium hydroxyethyl sulfonate was determined by differential scanning calorimetry(DSC). The melting temperature and melting enthalpy were obtained to be 465.41 K and 25.69 kJ·mol^(-1), respectively. The molar specific heat capacity of sodium hydroxyethyl sulfonate was determinated from 310.15 K to 365.15 K and expressed as a function of temperature.
