Focusing on the conversion of pressure energy and internal energy under viscous dissipation,a heat-fluid-solid coupling method is established to study the flow and stress fields of 100 MPa submerged water jets.Results...Focusing on the conversion of pressure energy and internal energy under viscous dissipation,a heat-fluid-solid coupling method is established to study the flow and stress fields of 100 MPa submerged water jets.Results indicate that pressure energy to internal energy conversion primarily occurs at three locations:the nozzle wall,the potential core edge,and the impact wall,with the most intense conversion occurring at the impact wall.The impact temperature of the jet can reach 200℃,and the high-temperature region covers an area more than 4 times that of the high-pressure.Thermal stress can especially amplify erosion stress by more than 100%and expand the erosion area by more than 400%.Therefore,it serves as a dominant factor determining the optimal spray distance and jet angle in hard rock(E≥40 GPa).With increased spray distance or jet angle,impact pressure decreases,while the high-temperature zone moves toward the high-pressure region,thus increasing the overlap between the two regions.This extended overlap enhances the temperature-pressure coupling effect,consequently reducing the threshold pressure for jet-breaking rock.Therefore,the maximum erosion stress increases first and then decreases,and an optimal spray distance and jet angle exist.The optimal jet angle,defined by the maximum tensile stress,decreases with the dimensionless spray distance increase,ranging between 0°and 40°.This temperature-pressure coupling reduces rock-breaking threshold pressure by 15%-75%for elastic moduli of 40-80 GPa,with maximum erosion stress peaking at a dimensionless spray distance of 9 and jet angles of 15°-20°.When the overlap region decreases,the area affected by the temperature and pressure fields increases,leading to an increase in the rock-breaking area.It is important to note that reducing the rock-breaking threshold pressure and increasing the rock-breaking area are mutually exclusive objectives.It is necessary to optimize the design of the spray distance and jet angle according to the on-site rock-breaking requirements.展开更多
The double flapper-nozzle servo valve is widely used to launch and guide the equipment. Due to the large instantaneous flow rate of servo valve working under specific operating conditions, the temperature of servo val...The double flapper-nozzle servo valve is widely used to launch and guide the equipment. Due to the large instantaneous flow rate of servo valve working under specific operating conditions, the temperature of servo valve would reach 120℃ and the valve core and valve sleeve deform in a short amount of time. So the control precision of servo valve significantly decreases and the clamping stagnation phenomenon of valve core appears. In order to solve the problem of degraded control accuracy and clamping stagnation of servo valve under large temperature difference circumstance, the numerical simulation of heat-fluid-solid coupling by using finite element method is done. The simulation result shows that zero position leakage of servo valve is basically impacted by oil temperature and change of fit clearance. The clamping stagnation is caused by warpage-deformation and fit clearance reduction of the valve core and valve sleeve. The distribution roles of the temperature and thermal-deformation of shell, valve core and valve sleeve and the pressure, velocity and temperature field of flow channel are also analyzed. Zero position leakage and electromagnet＇s current when valve core moves in full-stroke are tested using Electro-hydraulic Servo-valve Characteristic Test-bed of an aerospace sciences and technology corporation. The experimental results show that the change law of experimental current at different oil temperatures is roughly identical to simulation current. The current curve of the electromagnet is smooth when oil temperature is below 80℃, but the amplitude of current significantly increases and the hairy appears when oil temperature is above 80℃. The current becomes smooth again after the warped valve core and valve sleeve are reground. It indicates that clamping stagnation is caused by warpage-deformation and fit clearance reduction of valve core and valve sleeve. This paper simulates and tests the heat-fluid-solid coupling of double flapper-nozzle servo valve, and the obtained results provide the reference value for the design of double flapper-nozzle force feedback servo valve.展开更多
Aiming at the synergistic rock-breaking mechanism of supercritical carbon dioxide(SC-CO_(2))jet pressure and tem-perature difference,a heat-fluid-solid calculation model of rock-breaking stress was established and ver...Aiming at the synergistic rock-breaking mechanism of supercritical carbon dioxide(SC-CO_(2))jet pressure and tem-perature difference,a heat-fluid-solid calculation model of rock-breaking stress was established and verified to be effective,and the variations of jet flow field and rock stress with jet standoff distance of SC-CO_(2),water and nitrogen were studied.With the increase of jet standoff distance,the jet pressure of SC-CO_(2) decreases and the jet temperature difference increases.The SC-CO_(2) jet is higher in pressure than the nitrogen jet and differs little from the water jet.Temperature difference of SC-CO_(2) jet is 5 times that of water jet and more than 2.5 ti mes that of nitrogen jet when the jet standoff distance is larger than 10.The tem-perature stress is the main reason why SC-CO_(2) jet is superior to water and nitrogen jets in rock-breaking.The rock under the SC-CO_(2) jet has greater rock stress,effective rock-breaking jet standoff distance and rock-breaking area.The jet pressure plays a major role in rock-breaking when the jet standoff distance is small,while the jet temperature difference plays a major role in rock-breaking when the jet standoff distance is large.The SC-CO_(2) jet is an efficient volume rock-breaking method,which results in tensile and shear failure on the rock surface under short time jet and large area tensile failure inside the rock simultaneously under long time jet.展开更多
Improving the absorbed gas to active desorption and seepage and delaying gas drainage attenuation are considered as key methods for increasing drainage efficiency and gas output.According to the solid mechanics theory...Improving the absorbed gas to active desorption and seepage and delaying gas drainage attenuation are considered as key methods for increasing drainage efficiency and gas output.According to the solid mechanics theory,the nonlinear Darcy seepage theory and thermodynamics,the heat-fluid-solid coupling model for gassy coal has been improved.The numerical model was founded from the improved multi-field coupling model by COMSOL Multiphysics and gas drainage by borehole down the coal seam enhanced by heat injection was modelled.The results show that the heatfluid-solid model with adsorption effects for gassy coal was well simulated by the improved multi-field model.The mechanism of coal seam gas desorption seepage under the combined action of temperature,stress and adsorption can be well described.Gas desorption and seepage can be enhanced by heat injection into coal seams.The gas drainage rate was directly proportional to the temperature of injected heat in the scope of 30-150 ℃ and increasing in the whole modelleddrainage process (0-1000 d).The increased level was maximum in the initial drainage time and decreasing gradually along with drainage time.The increasing ratio of drainage rate was maximum when the temperature raised from 30 to 60 ℃.Although the drainage rate would increase along with increasing temperature,when exceeding 60 ℃,the increasing ratio of drainage rate with rising temperature would decrease.Gas drainage promotion was more effective in coal seams with lower permeability than with higher permeability.The coal seam temperature in a 5 m distance surrounding the heat injection borehole would rise to around 60 ℃ in 3 months.That was much less than the time of gas drainage in the coal mines in sites with low permeability coal seams.Therefore,it is valuable and feasible to inject heat into coal seams to promote gas drainage,and this has strong feasibility for coal seams with low permeability which are widespread in China.展开更多
The coupling reactions of methanol and long-chain alkanes(n-dodecane,n-tetradecane and n-hexadecane)over CHA-type molecular sieves were studied in a fixed bed reactor.Over SAPO-34 and SSZ-13,it was found that the indu...The coupling reactions of methanol and long-chain alkanes(n-dodecane,n-tetradecane and n-hexadecane)over CHA-type molecular sieves were studied in a fixed bed reactor.Over SAPO-34 and SSZ-13,it was found that the induction period of methanol conversion was shortened by the introduction of long-chain alkanes.However,the addition of long-chain alkanes had little influence on the product distribution.Polymethylbenzenes and the derivatives were the main retained species on spent SSZ-13 catalyst,while adamantanes were the main retained species on SAPO-34.This indicates that coking species formation was mainly related to the further transformation of long-chain alkane/methanol coupling products at acid sites of the molecular sieve.These findings provide valuable information of long chain alkanes conversion and methanol reaction behavior of induction period over small pore CHA molecular sieves.展开更多
Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing addit...Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing additive-induced defects,and alleviating residual stress and deformation,all of which are critical for enhancing the mechanical performance of the manufactured parts.Integrating interlayer friction stir processing(FSP)into WAAM significantly enhances the quality of deposited materials.However,numerical simulation research focusing on elucidating the associated thermomechanical coupling mechanisms remains insufficient.A comprehensive numerical model was developed to simulate the thermomechanical coupling behavior in friction stir-assisted WAAM.The influence of post-deposition FSP on the coupled thermomechanical response of the WAAM process was analyzed quantitatively.Moreover,the residual stress distribution and deformation behavior under both single-layer and multilayer deposition conditions were investigated.Thermal analysis of different deposition layers in WAAM and friction stir-assisted WAAM was conducted.Results show that subsequent layer deposition induces partial remelting of the previously solidified layer,whereas FSP does not cause such remelting.Furthermore,thermal stress and deformation analysis confirm that interlayer FSP effectively mitigates residual stresses and distortion in WAAM components,thereby improving their structural integrity and mechanical properties.展开更多
Transition metal-catalyzed C—C coupling reactions are a core strategy for the construction of carbon-carbon bonds in organic synthesis.Their development has not only promoted the synthesis of drugs,materials,and natu...Transition metal-catalyzed C—C coupling reactions are a core strategy for the construction of carbon-carbon bonds in organic synthesis.Their development has not only promoted the synthesis of drugs,materials,and natural products,but also promoted the development of new synthetic methods,and has also made breakthroughs in mechanism innovation and catalyst design.On this basis,a copper-catalyzed radical reaction between ketones is reported,enabling the synthesis of 2-carbonyl-1,4-diones.The method exhibits excellent applicability to multiple structural types of ketones,including aliphatic ketones with diverse substituents,aromatic ketones,and various simple ketones not limited to acetone,with wide applications,easy implementation,low catalyst toxicity,and low cost,cost-effective,and the product is easy to separate and purify.展开更多
This study aims to promote the optimization and upgrading of the economic structure in rural areas of China by focusing on the coupling coordination mechanism between digital economy–agriculture integration and rural...This study aims to promote the optimization and upgrading of the economic structure in rural areas of China by focusing on the coupling coordination mechanism between digital economy–agriculture integration and rural revitalization.By examining panel data from 30 Chinese provinces,autonomous regions,and municipalities between 2011 and 2022,the research constructs a weight-based evaluation system that integrates subjective and objective methods and a coupling coordination model to reveal its dynamic evolution patterns.Key findings indicate that digital economy–agriculture integration and rural revitalization achieve cross-coupling through critical activities.The impact of digital-agriculture integration on advancing rural revitalization lags by 2–3 years.Although the coupling development degree between the two systems continues to improve,it remains at the stage of primary coordination.Regional disparities are significant,showing a gradient pattern of“high degree of coupling development in the east and low degree of coupling development in the west.”展开更多
Multilayer complex dynamical networks,characterized by the intricate topological connections and diverse hierarchical structures,present significant challenges in determining complete structural configurations due to ...Multilayer complex dynamical networks,characterized by the intricate topological connections and diverse hierarchical structures,present significant challenges in determining complete structural configurations due to the unique functional attributes and interaction patterns inherent to different layers.This paper addresses the critical question of whether structural information from a known layer can be used to reconstruct the unknown intralayer structure of a target layer within general weighted output-coupling multilayer networks.Building upon the generalized synchronization principle,we propose an innovative reconstruction method that incorporates two essential components in the design of structure observers,the cross-layer coupling modulator and the structural divergence term.A key advantage of the proposed reconstruction method lies in its flexibility to freely designate both the unknown target layer and the known reference layer from the general weighted output-coupling multilayer network.The reduced dependency on full-state observability enables more deployment in engineering applications with partial measurements.Numerical simulations are conducted to validate the effectiveness of the proposed structure reconstruction method.展开更多
A series of new chiral amide ligands were prepared from natural amino acids and applied to the copper-catalyzed asymmetric oxidative homocoupling reaction of 3-hydroxy-2-naphthoates.By optimizing the reaction conditio...A series of new chiral amide ligands were prepared from natural amino acids and applied to the copper-catalyzed asymmetric oxidative homocoupling reaction of 3-hydroxy-2-naphthoates.By optimizing the reaction conditions,it was found that when using L3(5 mol%)as the ligand,CuCl(5 mol%)as the catalyst,dichloromethane as the solvent,2,2,6,6-tetramethylpiperidine 1-oxyl(TEMPO)/O2 as the oxidant,and under the reaction condition of 40℃,this method exhibited good substrate tolerance.Under these conditions,a series of chiral 1,1'-bi-2-naphthol(BINOL)derivatives were synthesized with yields of 45%~90%and enantioselectivities ranging from 50∶50 to 97∶3.展开更多
The F_(1)-ATPase and V_(1)-ATPase are rotary biomotors.Alignment of their amino acid sequences,which originate from bovine heart mitochondria(1BMF)and Enterococcus hirae(3VR6),respectively,demonstrates that the segmen...The F_(1)-ATPase and V_(1)-ATPase are rotary biomotors.Alignment of their amino acid sequences,which originate from bovine heart mitochondria(1BMF)and Enterococcus hirae(3VR6),respectively,demonstrates that the segment forming the ATP catalytic pocket is highly conserved.Single-molecule experiments,however,have revealed subtle differences in efficiency between the F_(1) and V_(1) motors.Here,we perform both atomistic and coarse-grained molecular dynamics simulations to investigate the mechanochemical coupling and coordination in F_(1) and V_(1) ATPase.Our results show that the correlation between conformational changes in F_(1) is stronger than that in V_(1),indicating that the mechanochemical coupling in F_(1) is tighter than in V_(1).Moreover,the unidirectional rotation of F_(1) is more processive than that of V_(1),which accounts for the higher efficiency observed in F_(1) and explains the occasional backward steps detected in single-molecule experiments on V_(1).展开更多
The coupling effects among the flow field,temperature distribution and structural deformation in a turbine cannot be ignored,particularly during flight cycles when the turbine experiences varied operational states.Rel...The coupling effects among the flow field,temperature distribution and structural deformation in a turbine cannot be ignored,particularly during flight cycles when the turbine experiences varied operational states.Relying solely on steady-state solutions cannot predict the detrimental effects caused by hysteresis.Consequently,this paper employs a quasi-steady-state fluid-thermalstructure multidisciplinary coupling solution method,integrating transient solid heat conduction with steady-state flow field and static structural deformation solutions.After conducting a numerical simulation of a three-dimensional,five-stage,low-pressure turbine air system,the following conclusions are drawn:when boundary conditions attain high-power states through processes that are numerically identical but in opposite directions,slight variations in solid deformation significantly impact the flow field;when boundary conditions attain high-power states through processes that are directionally consistent but have different numerical values,the influence of the boundary condition change rate on the flow field surpasses that of solid deformation.In terms of turbine design parameters,a large difference in stage-reaction between adjacent stages at the lower radius of the turbine can lead to significant changes in the disc cavity flow field during flight cycles.The difference in the stage-reaction of 0.23 at 10%blade height in adjacent stages may induce severe gas ingress in the stator disc cavity.Thus,it is crucial to minimize this difference and to appropriately extend the duration of the deceleration phase to ensure the turbine's safe operation.展开更多
Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling ...Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling the automatic derivation of analytical expressions for the eigenmatrix elements via symbolic computation,eliminating the need for tedious manual calculations.Using this approach,we investigate the impact of magnetic hysteresis on magnon-magnon coupling in a system with interlayer Dzyaloshinskii-Moriya interaction(DMI).The magnetic hysteresis leads to an asymmetric magnetic field dependence of the resonance frequency and alters the number of degeneracy points between the pure optical and acoustic modes.Moreover,it can result in the coupling strength at the gap of the f–H phase diagram being nearly vanishing,contrary to the conventionally expected maximum.These results deepen the understanding of the effect of interlayer DMI on magnon–magnon coupling and the proposed universal method significantly streamlines the solving process of magnon–magnon coupling problems.展开更多
This study presents an implicit multiphysics coupling method integrating Computational Fluid Dynamics(CFD),the Multiphase Particle-in-Cell(MPPIC)model,and the Finite Element Method(FEM),implemented with OpenFOAM,Calcu...This study presents an implicit multiphysics coupling method integrating Computational Fluid Dynamics(CFD),the Multiphase Particle-in-Cell(MPPIC)model,and the Finite Element Method(FEM),implemented with OpenFOAM,CalculiX,and preCICE to simulate fluid-particle-structure interactions with large deformations.Mesh motion in the fluid field is handled using the radial basis function(RBF)method.The particle phase is modeled by MPPIC,where fluid-particle interaction is described through momentum exchange,and inter-particle collisions are characterized by collision stress.The structural field is solved by nonlinear FEM to capture large deformations induced by geometric nonlinearity.Coupling among fields is realized through a partitioned,parallel,and non-intrusive iterative strategy,ensuring stable transfer and convergence of interface forces and displacements.Notably,the influence of particles on the structure is not direct but mediated by the fluid,while structural motion directly affects particle dynamics.The results demonstrate that the proposed approach effectively captures multiphysics interaction processes and provides a valuable reference for numerical modeling of coupled fluid-particle-structure systems.展开更多
Global-and meso-scale dipolarizations are well-known features of Earth’s magnetosphere,but their coupling remains poorly understood.Here,using a new approach that combines two-dimentional(2D)ionospheric field-aligned...Global-and meso-scale dipolarizations are well-known features of Earth’s magnetosphere,but their coupling remains poorly understood.Here,using a new approach that combines two-dimentional(2D)ionospheric field-aligned current(FAC)maps with coordinated observations from a network of magnetospheric satellites,we directly show that individual global-scale dipolarizations can expand from the nightside to,or even into,the dayside.These expansions are enduring(20–30 minutes),slow(2–4 deg/min),and global in extent(up to 12 h in local time),consistent with previous statistical inferences but now explicitly observed.The expanding FACs form a two-sheet current system as described by the Boström II model.In contrast,meso-scale dipolarizations are bursty(a few minutes),fast(several tens deg/min),and localized(several hours in local time),as evidenced by auroral expansions and satellite data.They are associated with the line-current system as described by the Boström I model(i.e.,the substorm current wedge).Notably,meso-scale dipolarizations often emerge near the expanding edge of a global-scale dipolarization,suggesting a dynamic coupling between the two scales.These observations provide a complementary scenario to the simulation-based interpretation that global-scale dipolarizations result from the accumulation of meso-scale dipolarizations.Here,meso-scale dipolarizations appear far less frequently than in simulations and occur around the edge of global-scale dipolarizations.This result implies that meso-scale dipolarizations may be sporadically triggered during the azimuthal expansion of global-scale dipolarizations.展开更多
In this paper,a theoretical model is established for locally resonant plates with general resonators,and the corresponding governing equation is derived.The model provides a mathematical demonstration of the locally r...In this paper,a theoretical model is established for locally resonant plates with general resonators,and the corresponding governing equation is derived.The model provides a mathematical demonstration of the locally resonant effect,which contains two parts:the first part is induced by translation coupling,and the second part is induced by rotation coupling.The second part cannot be reflected by most existing theoretical models.The analytical solutions of the dynamic response are compared with the direct numerical simulation(DNS)results for two locally resonant plates with different resonator types,thereby validating the general applicability of the present model.The rotation coupling effect leads to the frequency-dependent effective rotational inertia density and anisotropic dispersion relation of the locally resonant plate,as well as the enhancement of the structural vibration suppression ability.展开更多
An efficient scheme is applied to generate a nonisospectral Botie-Pempinelli-Tu(BPT)integrable hierarchy under the case whereλ_(t)=n∑j=0 k_(j)(t)λ^(-j).Based on an expanding higherdimensional Lie algebra,we obtain ...An efficient scheme is applied to generate a nonisospectral Botie-Pempinelli-Tu(BPT)integrable hierarchy under the case whereλ_(t)=n∑j=0 k_(j)(t)λ^(-j).Based on an expanding higherdimensional Lie algebra,we obtain a nonisospectral BPT integrable coupling hieararchy.It follws that some new nonisospectral nonlinear systems are obtained by reducing these two nonisospectral BPT hierarchies.Actually,these nonisospectral integrable models that we obtained can enrich the existing integrable models and possibly describe new nonlinear phenomena.展开更多
The strong electron-phonon coupling in organic photovoltaic materials significantly impedes exciton transport and promotes charge recombination,thereby exerting a detrimental effect on the overall performance of organ...The strong electron-phonon coupling in organic photovoltaic materials significantly impedes exciton transport and promotes charge recombination,thereby exerting a detrimental effect on the overall performance of organic solar cells(OSCs).Mitigating electron-phonon coupling is therefore essential for developing high-performance OSCs.In this work,we introduce two solid additives,1-bromo-3-chloronaphthalene(BCN-1)and 1-chloro-3-bromonaphthalene(BCN-2),into the bulk heterojunction active layer to address this fundamental challenge.We demonstrate that BCN-2 effectively suppresses high-frequency lattice vibrations,which minimizes electron-phonon scattering and thereby promotes efficient and long-range exciton diffusion.As a result,the BCN-2 processed devices exhibit prolonged exciton lifetime and superior charge carrier mobility compared to the control devices.These synergistic improvements in photophysical properties such as charge transport,contribute to a remarkable power conversion efficiency of 19.72%in the PM6:L8-BO-based OSCs.This work underscores the suppression of electron-phonon coupling as a critical and general strategy for advancing the performance of organic photovoltaic devices.展开更多
With the rapid advancement of electromagnetic launch technology,enhancing the structural stability and thermal resistance of armatures has become essential for improving the overall efficiency and reliability of railg...With the rapid advancement of electromagnetic launch technology,enhancing the structural stability and thermal resistance of armatures has become essential for improving the overall efficiency and reliability of railgun systems.Traditional aluminum alloy armatures often suffer from severe ablation,deformation,and uneven current distribution under high pulsed currents,which limit their performance and service life.To address these challenges,this study employs the Johnson–Cook constitutive model and the finite element method to develop armature models of aluminum matrix composites with varying heterogeneous graphene volume fractions.The temperature,stress,and strain of the armatures during operation were analyzed to investigate the effects of different graphene volume fractions on the deformation and damage behavior of aluminum matrix composite armatures under the multi-field coupling of electromagnetic,thermal,and structural interactions.The results indicate that,compared to the 6061 aluminum alloy matrix,the graphene-reinforced aluminum matrix composite armature significantly suppresses ablation damage at the tail and throat edges.The incorporation of graphene notably reduces the temperature rise during the armature emission process,increases the muzzle velocity under identical current excitation,and mitigates directional deformation of the armature.The 1 wt.% graphene-reinforced aluminum matrix composite armature demonstrates better agreement with experimental results at a strain rate of 2000 s^(-1),while simultaneously improving stress-strain response,reducing temperature rise,and improving velocity performance.展开更多
Hydraulic asphalt concrete(HAC)has been increasingly employed as an appropriate impervious structure in hydraulic and hydropower engineering.However,asphalt mortar,usually seen as the matrix of HAC composite,is partic...Hydraulic asphalt concrete(HAC)has been increasingly employed as an appropriate impervious structure in hydraulic and hydropower engineering.However,asphalt mortar,usually seen as the matrix of HAC composite,is particularly prone to damage under combined stress and seepage interactions,and the mesoscale investigations on the damage-seepage coupling behavior of HAC under complex stress states remain limited.This research develops a numerical three-dimensional mesoscale model composed of asphalt mortar and polyhedral aggregate to investigate the stress-damage-seepage coupling behavior in HAC.In this model,asphalt mortar yields the viscoelastic continuum damage law and aggregate obeys the Mazars’elastic-brittle damage law;simultaneously,the effective permeability coefficient of asphalt mortar is assumed to follow an exponential function of damage.The predicted deviatoric stress-strain and hydraulic gradient-seepage curves both are in good agreement with the reported experimental results,which shows the proposed model is valid and reasonable.The simulated results indicate that the damaged asphalt mortar can induce localized areas of high permeability,which in turn affects the overall impervious performance of HAC.展开更多
基金supported by the National Natural Science Foundation of China(No.52204126)the Shandong Provincial Natural Science Foundation(Nos.ZR2022ME077,ZR2022QE060,and ZR2023ME119).
文摘Focusing on the conversion of pressure energy and internal energy under viscous dissipation,a heat-fluid-solid coupling method is established to study the flow and stress fields of 100 MPa submerged water jets.Results indicate that pressure energy to internal energy conversion primarily occurs at three locations:the nozzle wall,the potential core edge,and the impact wall,with the most intense conversion occurring at the impact wall.The impact temperature of the jet can reach 200℃,and the high-temperature region covers an area more than 4 times that of the high-pressure.Thermal stress can especially amplify erosion stress by more than 100%and expand the erosion area by more than 400%.Therefore,it serves as a dominant factor determining the optimal spray distance and jet angle in hard rock(E≥40 GPa).With increased spray distance or jet angle,impact pressure decreases,while the high-temperature zone moves toward the high-pressure region,thus increasing the overlap between the two regions.This extended overlap enhances the temperature-pressure coupling effect,consequently reducing the threshold pressure for jet-breaking rock.Therefore,the maximum erosion stress increases first and then decreases,and an optimal spray distance and jet angle exist.The optimal jet angle,defined by the maximum tensile stress,decreases with the dimensionless spray distance increase,ranging between 0°and 40°.This temperature-pressure coupling reduces rock-breaking threshold pressure by 15%-75%for elastic moduli of 40-80 GPa,with maximum erosion stress peaking at a dimensionless spray distance of 9 and jet angles of 15°-20°.When the overlap region decreases,the area affected by the temperature and pressure fields increases,leading to an increase in the rock-breaking area.It is important to note that reducing the rock-breaking threshold pressure and increasing the rock-breaking area are mutually exclusive objectives.It is necessary to optimize the design of the spray distance and jet angle according to the on-site rock-breaking requirements.
基金Supposed by National Natural Science Foundation of China(Grant No.51075348)Hebei Provincial Natural Science Foundation of China(Grant No.E2011203151)Research Fund for Doctoral Program of Higher Education of China(Grant No.20101333110002)
文摘The double flapper-nozzle servo valve is widely used to launch and guide the equipment. Due to the large instantaneous flow rate of servo valve working under specific operating conditions, the temperature of servo valve would reach 120℃ and the valve core and valve sleeve deform in a short amount of time. So the control precision of servo valve significantly decreases and the clamping stagnation phenomenon of valve core appears. In order to solve the problem of degraded control accuracy and clamping stagnation of servo valve under large temperature difference circumstance, the numerical simulation of heat-fluid-solid coupling by using finite element method is done. The simulation result shows that zero position leakage of servo valve is basically impacted by oil temperature and change of fit clearance. The clamping stagnation is caused by warpage-deformation and fit clearance reduction of the valve core and valve sleeve. The distribution roles of the temperature and thermal-deformation of shell, valve core and valve sleeve and the pressure, velocity and temperature field of flow channel are also analyzed. Zero position leakage and electromagnet＇s current when valve core moves in full-stroke are tested using Electro-hydraulic Servo-valve Characteristic Test-bed of an aerospace sciences and technology corporation. The experimental results show that the change law of experimental current at different oil temperatures is roughly identical to simulation current. The current curve of the electromagnet is smooth when oil temperature is below 80℃, but the amplitude of current significantly increases and the hairy appears when oil temperature is above 80℃. The current becomes smooth again after the warped valve core and valve sleeve are reground. It indicates that clamping stagnation is caused by warpage-deformation and fit clearance reduction of valve core and valve sleeve. This paper simulates and tests the heat-fluid-solid coupling of double flapper-nozzle servo valve, and the obtained results provide the reference value for the design of double flapper-nozzle force feedback servo valve.
基金Supported by the National Natural Science Foundation of China(51674158,51704324,51934004)。
文摘Aiming at the synergistic rock-breaking mechanism of supercritical carbon dioxide(SC-CO_(2))jet pressure and tem-perature difference,a heat-fluid-solid calculation model of rock-breaking stress was established and verified to be effective,and the variations of jet flow field and rock stress with jet standoff distance of SC-CO_(2),water and nitrogen were studied.With the increase of jet standoff distance,the jet pressure of SC-CO_(2) decreases and the jet temperature difference increases.The SC-CO_(2) jet is higher in pressure than the nitrogen jet and differs little from the water jet.Temperature difference of SC-CO_(2) jet is 5 times that of water jet and more than 2.5 ti mes that of nitrogen jet when the jet standoff distance is larger than 10.The tem-perature stress is the main reason why SC-CO_(2) jet is superior to water and nitrogen jets in rock-breaking.The rock under the SC-CO_(2) jet has greater rock stress,effective rock-breaking jet standoff distance and rock-breaking area.The jet pressure plays a major role in rock-breaking when the jet standoff distance is small,while the jet temperature difference plays a major role in rock-breaking when the jet standoff distance is large.The SC-CO_(2) jet is an efficient volume rock-breaking method,which results in tensile and shear failure on the rock surface under short time jet and large area tensile failure inside the rock simultaneously under long time jet.
基金The authors acknowledge the financial support from the Natural Science Foundation of China(U1704131)Program for Science&Technology Innovation Talents in Universities of Henan Province(18HASTIT018)the Program for Changjiang Scholars and Innovative Research Team in University(IRT_16R22).
文摘Improving the absorbed gas to active desorption and seepage and delaying gas drainage attenuation are considered as key methods for increasing drainage efficiency and gas output.According to the solid mechanics theory,the nonlinear Darcy seepage theory and thermodynamics,the heat-fluid-solid coupling model for gassy coal has been improved.The numerical model was founded from the improved multi-field coupling model by COMSOL Multiphysics and gas drainage by borehole down the coal seam enhanced by heat injection was modelled.The results show that the heatfluid-solid model with adsorption effects for gassy coal was well simulated by the improved multi-field model.The mechanism of coal seam gas desorption seepage under the combined action of temperature,stress and adsorption can be well described.Gas desorption and seepage can be enhanced by heat injection into coal seams.The gas drainage rate was directly proportional to the temperature of injected heat in the scope of 30-150 ℃ and increasing in the whole modelleddrainage process (0-1000 d).The increased level was maximum in the initial drainage time and decreasing gradually along with drainage time.The increasing ratio of drainage rate was maximum when the temperature raised from 30 to 60 ℃.Although the drainage rate would increase along with increasing temperature,when exceeding 60 ℃,the increasing ratio of drainage rate with rising temperature would decrease.Gas drainage promotion was more effective in coal seams with lower permeability than with higher permeability.The coal seam temperature in a 5 m distance surrounding the heat injection borehole would rise to around 60 ℃ in 3 months.That was much less than the time of gas drainage in the coal mines in sites with low permeability coal seams.Therefore,it is valuable and feasible to inject heat into coal seams to promote gas drainage,and this has strong feasibility for coal seams with low permeability which are widespread in China.
基金Supported by National Natural Science Foundation of China(21991093)。
文摘The coupling reactions of methanol and long-chain alkanes(n-dodecane,n-tetradecane and n-hexadecane)over CHA-type molecular sieves were studied in a fixed bed reactor.Over SAPO-34 and SSZ-13,it was found that the induction period of methanol conversion was shortened by the introduction of long-chain alkanes.However,the addition of long-chain alkanes had little influence on the product distribution.Polymethylbenzenes and the derivatives were the main retained species on spent SSZ-13 catalyst,while adamantanes were the main retained species on SAPO-34.This indicates that coking species formation was mainly related to the further transformation of long-chain alkane/methanol coupling products at acid sites of the molecular sieve.These findings provide valuable information of long chain alkanes conversion and methanol reaction behavior of induction period over small pore CHA molecular sieves.
基金National Key Research and Development Program of China(2022YFB4600902)Shandong Provincial Science Foundation for Outstanding Young Scholars(ZR2024YQ020)。
文摘Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing additive-induced defects,and alleviating residual stress and deformation,all of which are critical for enhancing the mechanical performance of the manufactured parts.Integrating interlayer friction stir processing(FSP)into WAAM significantly enhances the quality of deposited materials.However,numerical simulation research focusing on elucidating the associated thermomechanical coupling mechanisms remains insufficient.A comprehensive numerical model was developed to simulate the thermomechanical coupling behavior in friction stir-assisted WAAM.The influence of post-deposition FSP on the coupled thermomechanical response of the WAAM process was analyzed quantitatively.Moreover,the residual stress distribution and deformation behavior under both single-layer and multilayer deposition conditions were investigated.Thermal analysis of different deposition layers in WAAM and friction stir-assisted WAAM was conducted.Results show that subsequent layer deposition induces partial remelting of the previously solidified layer,whereas FSP does not cause such remelting.Furthermore,thermal stress and deformation analysis confirm that interlayer FSP effectively mitigates residual stresses and distortion in WAAM components,thereby improving their structural integrity and mechanical properties.
基金Project supported by the Basic Research Support Program for Outstanding Young Teachers in Provincial Undergraduate Colleges and Universities in Heilongjiang Province(No.YQJH2024096)the Heilongjiang Province Natural Joint Guidance Cultivation Project(No.PL2024H198)。
文摘Transition metal-catalyzed C—C coupling reactions are a core strategy for the construction of carbon-carbon bonds in organic synthesis.Their development has not only promoted the synthesis of drugs,materials,and natural products,but also promoted the development of new synthetic methods,and has also made breakthroughs in mechanism innovation and catalyst design.On this basis,a copper-catalyzed radical reaction between ketones is reported,enabling the synthesis of 2-carbonyl-1,4-diones.The method exhibits excellent applicability to multiple structural types of ketones,including aliphatic ketones with diverse substituents,aromatic ketones,and various simple ketones not limited to acetone,with wide applications,easy implementation,low catalyst toxicity,and low cost,cost-effective,and the product is easy to separate and purify.
基金Youth project under the National Social Science Foundation of China(15CJY054)key project in Philosophy and Social Sciences funded by the Chongqing Municipal Education Commission(22SKGH091)。
文摘This study aims to promote the optimization and upgrading of the economic structure in rural areas of China by focusing on the coupling coordination mechanism between digital economy–agriculture integration and rural revitalization.By examining panel data from 30 Chinese provinces,autonomous regions,and municipalities between 2011 and 2022,the research constructs a weight-based evaluation system that integrates subjective and objective methods and a coupling coordination model to reveal its dynamic evolution patterns.Key findings indicate that digital economy–agriculture integration and rural revitalization achieve cross-coupling through critical activities.The impact of digital-agriculture integration on advancing rural revitalization lags by 2–3 years.Although the coupling development degree between the two systems continues to improve,it remains at the stage of primary coordination.Regional disparities are significant,showing a gradient pattern of“high degree of coupling development in the east and low degree of coupling development in the west.”
基金Project supported by the National Natural Science Foun-dation of China(Grant No.62373197)the Natural Science Foundation of the Higher Education Institutions of Jiangsu Province,China(Grant No.23KJB120010)+1 种基金the Industry-University-Research Cooperation Project of Jiangsu Province,China(Grant No.BY20251038)the Cultivation and In-cubation Project of the College of Automation,Nanjing Uni-versity of Posts and Telecommunications.
文摘Multilayer complex dynamical networks,characterized by the intricate topological connections and diverse hierarchical structures,present significant challenges in determining complete structural configurations due to the unique functional attributes and interaction patterns inherent to different layers.This paper addresses the critical question of whether structural information from a known layer can be used to reconstruct the unknown intralayer structure of a target layer within general weighted output-coupling multilayer networks.Building upon the generalized synchronization principle,we propose an innovative reconstruction method that incorporates two essential components in the design of structure observers,the cross-layer coupling modulator and the structural divergence term.A key advantage of the proposed reconstruction method lies in its flexibility to freely designate both the unknown target layer and the known reference layer from the general weighted output-coupling multilayer network.The reduced dependency on full-state observability enables more deployment in engineering applications with partial measurements.Numerical simulations are conducted to validate the effectiveness of the proposed structure reconstruction method.
文摘A series of new chiral amide ligands were prepared from natural amino acids and applied to the copper-catalyzed asymmetric oxidative homocoupling reaction of 3-hydroxy-2-naphthoates.By optimizing the reaction conditions,it was found that when using L3(5 mol%)as the ligand,CuCl(5 mol%)as the catalyst,dichloromethane as the solvent,2,2,6,6-tetramethylpiperidine 1-oxyl(TEMPO)/O2 as the oxidant,and under the reaction condition of 40℃,this method exhibited good substrate tolerance.Under these conditions,a series of chiral 1,1'-bi-2-naphthol(BINOL)derivatives were synthesized with yields of 45%~90%and enantioselectivities ranging from 50∶50 to 97∶3.
基金supported by the National Natural Science Foundation of China(Grant Nos.22193032 and 32401033)the Research Fund of Wenzhou Institute,Chinese Academy of Sciences(Grant Nos.WIUCASQD2020009,WIUCASQD2023005,XSZD2024004,2021HZSY0061,and WIUCASICTP2022)。
文摘The F_(1)-ATPase and V_(1)-ATPase are rotary biomotors.Alignment of their amino acid sequences,which originate from bovine heart mitochondria(1BMF)and Enterococcus hirae(3VR6),respectively,demonstrates that the segment forming the ATP catalytic pocket is highly conserved.Single-molecule experiments,however,have revealed subtle differences in efficiency between the F_(1) and V_(1) motors.Here,we perform both atomistic and coarse-grained molecular dynamics simulations to investigate the mechanochemical coupling and coordination in F_(1) and V_(1) ATPase.Our results show that the correlation between conformational changes in F_(1) is stronger than that in V_(1),indicating that the mechanochemical coupling in F_(1) is tighter than in V_(1).Moreover,the unidirectional rotation of F_(1) is more processive than that of V_(1),which accounts for the higher efficiency observed in F_(1) and explains the occasional backward steps detected in single-molecule experiments on V_(1).
基金supported by the National Science and Tech-nology Major Project,China(No.J2019-II-0012-0032)。
文摘The coupling effects among the flow field,temperature distribution and structural deformation in a turbine cannot be ignored,particularly during flight cycles when the turbine experiences varied operational states.Relying solely on steady-state solutions cannot predict the detrimental effects caused by hysteresis.Consequently,this paper employs a quasi-steady-state fluid-thermalstructure multidisciplinary coupling solution method,integrating transient solid heat conduction with steady-state flow field and static structural deformation solutions.After conducting a numerical simulation of a three-dimensional,five-stage,low-pressure turbine air system,the following conclusions are drawn:when boundary conditions attain high-power states through processes that are numerically identical but in opposite directions,slight variations in solid deformation significantly impact the flow field;when boundary conditions attain high-power states through processes that are directionally consistent but have different numerical values,the influence of the boundary condition change rate on the flow field surpasses that of solid deformation.In terms of turbine design parameters,a large difference in stage-reaction between adjacent stages at the lower radius of the turbine can lead to significant changes in the disc cavity flow field during flight cycles.The difference in the stage-reaction of 0.23 at 10%blade height in adjacent stages may induce severe gas ingress in the stator disc cavity.Thus,it is crucial to minimize this difference and to appropriately extend the duration of the deceleration phase to ensure the turbine's safe operation.
基金supported by the National Key Research and Development Program of China (MOST)(Grant No.2022YFA1402800)the Chinese Academy of Sciences (CAS) Presidents International Fellowship Initiative (PIFI)(Grant No.2025PG0006)+3 种基金the National Natural Science Foundation of China (NSFC)(Grant Nos.51831012,12274437,and 52161160334)the CAS Project for Young Scientists in Basic Research (Grant No.YSBR-084)the CAS Youth Interdisciplinary Teamthe China Postdoctoral Science Foundation (Grant No.2025M773402)。
文摘Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling the automatic derivation of analytical expressions for the eigenmatrix elements via symbolic computation,eliminating the need for tedious manual calculations.Using this approach,we investigate the impact of magnetic hysteresis on magnon-magnon coupling in a system with interlayer Dzyaloshinskii-Moriya interaction(DMI).The magnetic hysteresis leads to an asymmetric magnetic field dependence of the resonance frequency and alters the number of degeneracy points between the pure optical and acoustic modes.Moreover,it can result in the coupling strength at the gap of the f–H phase diagram being nearly vanishing,contrary to the conventionally expected maximum.These results deepen the understanding of the effect of interlayer DMI on magnon–magnon coupling and the proposed universal method significantly streamlines the solving process of magnon–magnon coupling problems.
基金supported in part by the Mining Hydraulic Technology and Equipment Engineering Research Center,Liaoning Technical University,Fuxin,China(Grant No.MHTE23-R04)the Fundamental Research Funds for the Central Universities(ID N25BSS068).
文摘This study presents an implicit multiphysics coupling method integrating Computational Fluid Dynamics(CFD),the Multiphase Particle-in-Cell(MPPIC)model,and the Finite Element Method(FEM),implemented with OpenFOAM,CalculiX,and preCICE to simulate fluid-particle-structure interactions with large deformations.Mesh motion in the fluid field is handled using the radial basis function(RBF)method.The particle phase is modeled by MPPIC,where fluid-particle interaction is described through momentum exchange,and inter-particle collisions are characterized by collision stress.The structural field is solved by nonlinear FEM to capture large deformations induced by geometric nonlinearity.Coupling among fields is realized through a partitioned,parallel,and non-intrusive iterative strategy,ensuring stable transfer and convergence of interface forces and displacements.Notably,the influence of particles on the structure is not direct but mediated by the fluid,while structural motion directly affects particle dynamics.The results demonstrate that the proposed approach effectively captures multiphysics interaction processes and provides a valuable reference for numerical modeling of coupled fluid-particle-structure systems.
基金NASA(National Aeronautics and Space Administration)grant 81NSSC19K0306NASA prime contract NAS5-01072+6 种基金AFOSR(Air Force Office of Scientific Research)grant FA9559-16-1-0364NSF(National Science Foundation)grant AGS-2055192NASA grants 80NSSC20K1314,80NSSC20K1316,and 80NSSC21K1407NASA Contract NAS5-02099NASA grants:80NSSC18K1220 and 80NSSC18K0570NASA contracts 80GSFC17C0018,and NAS5-02099NASA award 80NSSC18K122。
文摘Global-and meso-scale dipolarizations are well-known features of Earth’s magnetosphere,but their coupling remains poorly understood.Here,using a new approach that combines two-dimentional(2D)ionospheric field-aligned current(FAC)maps with coordinated observations from a network of magnetospheric satellites,we directly show that individual global-scale dipolarizations can expand from the nightside to,or even into,the dayside.These expansions are enduring(20–30 minutes),slow(2–4 deg/min),and global in extent(up to 12 h in local time),consistent with previous statistical inferences but now explicitly observed.The expanding FACs form a two-sheet current system as described by the Boström II model.In contrast,meso-scale dipolarizations are bursty(a few minutes),fast(several tens deg/min),and localized(several hours in local time),as evidenced by auroral expansions and satellite data.They are associated with the line-current system as described by the Boström I model(i.e.,the substorm current wedge).Notably,meso-scale dipolarizations often emerge near the expanding edge of a global-scale dipolarization,suggesting a dynamic coupling between the two scales.These observations provide a complementary scenario to the simulation-based interpretation that global-scale dipolarizations result from the accumulation of meso-scale dipolarizations.Here,meso-scale dipolarizations appear far less frequently than in simulations and occur around the edge of global-scale dipolarizations.This result implies that meso-scale dipolarizations may be sporadically triggered during the azimuthal expansion of global-scale dipolarizations.
基金Project supported by the National Natural Science Foundation of China(No.12472062)。
文摘In this paper,a theoretical model is established for locally resonant plates with general resonators,and the corresponding governing equation is derived.The model provides a mathematical demonstration of the locally resonant effect,which contains two parts:the first part is induced by translation coupling,and the second part is induced by rotation coupling.The second part cannot be reflected by most existing theoretical models.The analytical solutions of the dynamic response are compared with the direct numerical simulation(DNS)results for two locally resonant plates with different resonator types,thereby validating the general applicability of the present model.The rotation coupling effect leads to the frequency-dependent effective rotational inertia density and anisotropic dispersion relation of the locally resonant plate,as well as the enhancement of the structural vibration suppression ability.
基金Supported by the National Natural Science Foundation of China(11971475)。
文摘An efficient scheme is applied to generate a nonisospectral Botie-Pempinelli-Tu(BPT)integrable hierarchy under the case whereλ_(t)=n∑j=0 k_(j)(t)λ^(-j).Based on an expanding higherdimensional Lie algebra,we obtain a nonisospectral BPT integrable coupling hieararchy.It follws that some new nonisospectral nonlinear systems are obtained by reducing these two nonisospectral BPT hierarchies.Actually,these nonisospectral integrable models that we obtained can enrich the existing integrable models and possibly describe new nonlinear phenomena.
基金supported by the NSFC(52522314,52473200,52450063,52120105006,51925306)the National Key R&D Program of China(2018FYA 0305800)+2 种基金the Key Research Program of Chinese Academy of Sciences(XDPB08-2)the Youth Innovation Promotion Asso-ciation of Chinese Academy of Sciences(2022165)the Fundamental Research Funds for the Central Universities(E3ET1803).
文摘The strong electron-phonon coupling in organic photovoltaic materials significantly impedes exciton transport and promotes charge recombination,thereby exerting a detrimental effect on the overall performance of organic solar cells(OSCs).Mitigating electron-phonon coupling is therefore essential for developing high-performance OSCs.In this work,we introduce two solid additives,1-bromo-3-chloronaphthalene(BCN-1)and 1-chloro-3-bromonaphthalene(BCN-2),into the bulk heterojunction active layer to address this fundamental challenge.We demonstrate that BCN-2 effectively suppresses high-frequency lattice vibrations,which minimizes electron-phonon scattering and thereby promotes efficient and long-range exciton diffusion.As a result,the BCN-2 processed devices exhibit prolonged exciton lifetime and superior charge carrier mobility compared to the control devices.These synergistic improvements in photophysical properties such as charge transport,contribute to a remarkable power conversion efficiency of 19.72%in the PM6:L8-BO-based OSCs.This work underscores the suppression of electron-phonon coupling as a critical and general strategy for advancing the performance of organic photovoltaic devices.
基金funded Basic Research Projects of Higher Education Institutions in Liaoning Province(JYTZD20230004)Future Industry Frontier Technology Project in Liaoning Province in 2025(2025JH2/101330141)Key Research and Development Program of Liaoning Province in 2025.
文摘With the rapid advancement of electromagnetic launch technology,enhancing the structural stability and thermal resistance of armatures has become essential for improving the overall efficiency and reliability of railgun systems.Traditional aluminum alloy armatures often suffer from severe ablation,deformation,and uneven current distribution under high pulsed currents,which limit their performance and service life.To address these challenges,this study employs the Johnson–Cook constitutive model and the finite element method to develop armature models of aluminum matrix composites with varying heterogeneous graphene volume fractions.The temperature,stress,and strain of the armatures during operation were analyzed to investigate the effects of different graphene volume fractions on the deformation and damage behavior of aluminum matrix composite armatures under the multi-field coupling of electromagnetic,thermal,and structural interactions.The results indicate that,compared to the 6061 aluminum alloy matrix,the graphene-reinforced aluminum matrix composite armature significantly suppresses ablation damage at the tail and throat edges.The incorporation of graphene notably reduces the temperature rise during the armature emission process,increases the muzzle velocity under identical current excitation,and mitigates directional deformation of the armature.The 1 wt.% graphene-reinforced aluminum matrix composite armature demonstrates better agreement with experimental results at a strain rate of 2000 s^(-1),while simultaneously improving stress-strain response,reducing temperature rise,and improving velocity performance.
基金supported by the National Key Research and Development Program of China(Grant No.2022YFC3005603-01)the Natural Science Foundation Science of Anhui Province(Grant No.2308085US02).
文摘Hydraulic asphalt concrete(HAC)has been increasingly employed as an appropriate impervious structure in hydraulic and hydropower engineering.However,asphalt mortar,usually seen as the matrix of HAC composite,is particularly prone to damage under combined stress and seepage interactions,and the mesoscale investigations on the damage-seepage coupling behavior of HAC under complex stress states remain limited.This research develops a numerical three-dimensional mesoscale model composed of asphalt mortar and polyhedral aggregate to investigate the stress-damage-seepage coupling behavior in HAC.In this model,asphalt mortar yields the viscoelastic continuum damage law and aggregate obeys the Mazars’elastic-brittle damage law;simultaneously,the effective permeability coefficient of asphalt mortar is assumed to follow an exponential function of damage.The predicted deviatoric stress-strain and hydraulic gradient-seepage curves both are in good agreement with the reported experimental results,which shows the proposed model is valid and reasonable.The simulated results indicate that the damaged asphalt mortar can induce localized areas of high permeability,which in turn affects the overall impervious performance of HAC.
