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Recent advances in directing group assisted transition metal catalyzed para-selective C-H functionalization
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作者 Wei-Bin Li Xiao-Chao Huang +2 位作者 Pei Liu Jie Kong Guo-Ping Yang 《Chinese Chemical Letters》 2025年第6期68-77,共10页
The transition metal-catalyzed C–H activation have been considered as increasingly useful approach for installing new functional groups onto organic small molecules due to their high step-and atom-economy,the abundan... The transition metal-catalyzed C–H activation have been considered as increasingly useful approach for installing new functional groups onto organic small molecules due to their high step-and atom-economy,the abundance of hydrocarbon compounds,and the potential for late-stage functionalization of complex organic molecules.The ortho-and meta-C-H activation and functionalization of aromatic compounds have been widely explored in recent years,however the distal para-C-H activation and functionalization has remained a significant challenge because of the difficulty in forming energetically favorable metallacyclic transition states.The utilization of appropriate directing groups or templates as well as the meticulous design of catalysts and ligands has proven to be effective in transition-metal-catalyzed remote para-C-H bonds activation and functionalization of aromatic compounds.This review aims to summarize the strategies for controlling para-selective C–H functionalization using the directing group,template engineering,and catalyst/ligand design under transition metals catalysis in recent years. 展开更多
关键词 C-H activation Transition metal catalysis SELECTIVITY Remote functionalization directing group
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Formation mechanism of defects in Invar 36/MnCu functionally graded material fabricated by directed energy deposition
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作者 Yijie Peng Wei Fan +6 位作者 Dapeng Hao Zhe Feng Mingji Dang Zhiwei Hao Hua Tan Fengying Zhang Xin Lin 《Journal of Materials Science & Technology》 2025年第15期95-107,共13页
The fabrication of Invar/MnCu functionally graded material(FGM)through directed energy deposition(DED)can satisfy the demands for precision devices in aerospace,providing lightweight properties and integrating thermal... The fabrication of Invar/MnCu functionally graded material(FGM)through directed energy deposition(DED)can satisfy the demands for precision devices in aerospace,providing lightweight properties and integrating thermal stability and vibration damping capabilities.However,basic research on Invar/MnCu FGM is still lacking,hindering its potential applications.To address this gap,this study was conducted using mixed powders and consistent process parameters to print experiments for Invar/MnCu FGM and homogeneous samples.Phases,microstructures,compositions,and thermal expansion properties were thoroughly examined.Three types of defects were detected in the Invar/MnCu FGM sample:unmelted Invar 36 powders,cracks,and pores.The mechanism of unmelted powders was deeply discussed,attributing it to material properties influencing laser absorptivity,the required time for melting powder,and effects on solidus temperature.The mechanism of cracks was also discussed,attributing it to theγ-Fe dendritic structure causing low melting point metal to form an intergranular liquid film,harmful secondary phases mismatched with the terminal alloy,and obvious tensile stresses during the DED process.Additionally,an effective strategy was proposed to reduce defects in Invar/MnCu FGM.After optimization,the specimens exhibited excellent tensile properties,with a yield strength of 262±5 MPa,an ultimate tensile strength of 316±7 MPa,and an elongation of 3%±1%.This research provides valuable references and insights for subsequent work,offering robust support for better understanding and designing other FGM. 展开更多
关键词 Additive manufacturing directed energy deposition functionally graded materials Invar alloy MnCu alloy
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Energy flow control of nanofluid-based direct absorption solar collectors with functional optical coatings for efficient solar harvesting
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作者 XU Bing ZENG Rui-jing +1 位作者 ZHENG Nian-ben SUN Zhi-qiang 《Journal of Central South University》 2025年第8期3124-3135,共12页
The nanofluid-based direct absorption solar collector(NDASC)ensures that solar radiation passing through the tube wall is directly absorbed by the nanofluid,reducing thermal resistance in the energy transfer process.H... The nanofluid-based direct absorption solar collector(NDASC)ensures that solar radiation passing through the tube wall is directly absorbed by the nanofluid,reducing thermal resistance in the energy transfer process.However,further exploration is required to suppress the outward thermal losses from the nanofluid at high temperatures.Herein,this paper proposes a novel NDASC in which the outer surface of the collector tube is covered with functional coatings and a three-dimensional computational fluid dynamics model is established to study the energy flow distributions on the collector within the temperature range of 400-600 K.When the nanofluid’s absorption coefficient reaches 80 m^(-1),the NDASC shows the optimal thermal performance,and the NDASC with local Sn-In_(2)O_(3) coating achieves a 7.8% improvement in thermal efficiency at 400 K compared to the original NDASC.Furthermore,hybrid coatings with Sn In_(2)O_(3)/WTi-Al_(2)O_(3) are explored,and the optimal coverage angles are determined.The NDASC with such coatings shows a 10.22%-17.9% increase in thermal efficiency compared to the original NDASC and a 7.6%-19.5% increase compared to the traditional surface-type solar collectors,demonstrating the effectiveness of the proposed energy flow control strategy for DASCs. 展开更多
关键词 direct absorption solar collector NANOFLUID functional optical coatings energy flow control
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Correction:Impact of twice-a-day transcranial direct current stimulation interuention on cognitive function and motor cortex plasticity in patients with Alzheimer's disease
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《General Psychiatry》 2025年第5期415-415,共1页
An unauthorised version of the Chinese MMSE was used in this article by the authors without permission from the copyright owner,PAR.Necessary permission has now been retrospectively obtained from PAR.The MMSE is a cop... An unauthorised version of the Chinese MMSE was used in this article by the authors without permission from the copyright owner,PAR.Necessary permission has now been retrospectively obtained from PAR.The MMSE is a copyrighted instrument and may not be used or reproduced in whole or in part,in any form or language,or by any means without the written permission of PAR(www.parinc.com). 展开更多
关键词 transcranial direct current stimulation motor cortex plasticity COPYRIGHT cognitive function retrospective permission unauthorized version alzheimer's disease
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The Precise Order and Singular Directions of Meromorphic Functions 被引量:2
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作者 张学莲 《Journal of Beijing Institute of Technology》 EI CAS 1997年第1期14-18,共5页
The rnemmorphic functions of positive order(both finite positive order and infinite order) are discussed.First,the precise order and type function are given by using the characteristic function.Then some singular dire... The rnemmorphic functions of positive order(both finite positive order and infinite order) are discussed.First,the precise order and type function are given by using the characteristic function.Then some singular directions are defined and their existence is proved. 展开更多
关键词 metamorphic function singular direction precise order
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The Deficiency and Nevanlinna Direction of the Meromorphic Functions *L
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作者 张学莲 《Journal of Beijing Institute of Technology》 EI CAS 1999年第1期15-19,共5页
Aim To study the value distribution of meromorphic functions in angular domains, the deficiency, the deficient value, the Nevanlinna direction and other singular directions. Methods A fundamental inequality of Nevan... Aim To study the value distribution of meromorphic functions in angular domains, the deficiency, the deficient value, the Nevanlinna direction and other singular directions. Methods A fundamental inequality of Nevanlinna characteristic functions in the angular domain was used, which is similar with the Nevanlinna secondary fundamental theorem. Results The deficiency and deficient value of meromorphic functions about an angular domain and a direction were defined. The definition of Nevanlinna direction was improved. Conclusion For a family of meromorphic functions, it is proved that the number of deficient values is at most countable and the sum of deficiencies isnt greater than 2. The existence of the Nevanlinna direction is obtained. The existence of Borel and Julia directions and the relation between them are found. 展开更多
关键词 meromorphic functions DEFICIENCY deficient value Nevanlinna direction sigular direction
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ON NEVANLINNA DIRECTIONS OF ALGEBROID FUNCTIONS 被引量:5
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作者 卢谦 顾永兴 《Acta Mathematica Scientia》 SCIE CSCD 2005年第2期367-375,共9页
In this paper, a notation delta(x)(w) is derived from the counting function N-x(r, w) of branch points of algebriod functions. With this notation, the authors give the definition of the Nevanlinna direction for algebr... In this paper, a notation delta(x)(w) is derived from the counting function N-x(r, w) of branch points of algebriod functions. With this notation, the authors give the definition of the Nevanlinna direction for algebriod functions and discuss its existence in certain condition. By this notation the authors also obtain the numbers of exceptional value of the Julia direction and Borel direction of algebriod functions are not more than 2 + [delta(x) (w)] here [x] implies an maximum integer number which does not exceed x. 展开更多
关键词 Algebriod functions deficient relations Nevanlinna directions
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A proposed directional function and wind-wave directional spectrum 被引量:4
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作者 Wen Shengchang Wu Kejian +1 位作者 Guan Changlong Sun Shicai and Zhang Dacuo (Institute of Physical Oceanography, Ocean University of Oingdao, Oingdao 266003, China) 《Acta Oceanologica Sinica》 SCIE CAS CSCD 1995年第2期155-166,共12页
A directional function for frequencies equal to and larger than the peak frequency of a wind-wave frequency spectrum is constructed by fitting the angular spreading based on the analytically derived directional spectr... A directional function for frequencies equal to and larger than the peak frequency of a wind-wave frequency spectrum is constructed by fitting the angular spreading based on the analytically derived directional spectrum of Wen et al. (1993, Journal of Oceanography, 49(2), 131~147, 149~172). For frequencies smaller than the peak frequency, the directional function is obtained by comparing and analyzing existing formulas. The nondimensional wind-wave frequency spectrum of Wen et al. (1994, Progress in Natural Seience, 4(4). 407~427;4 (5), 586~596) has been used together with the directional function just mentioned to obtain the directional spectrum for easier application. 展开更多
关键词 Wind-wave directional function directional spectrum
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DIRECT AND ADAPTIVE SLICING ON CAD MODEL OF IDEAL FUNCTIONAL MATERIAL COMPONENTS (IFMC) 被引量:3
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作者 XuDaoming JiaZhenyuan GuoDongming 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2005年第1期139-144,共6页
A brand new direct and adaptive slicing approach is proposed, which canapparently improve the part accuracy and reduce the building time. At least two stages are includedin this operation: getting the crossing contour... A brand new direct and adaptive slicing approach is proposed, which canapparently improve the part accuracy and reduce the building time. At least two stages are includedin this operation: getting the crossing contour of the cutting plane with the solid part anddetermining the layer thickness. Apart from usual SPI algorithm, slicing of the solid model has itsspecial requirements. Enabling the contour line segments of the cross-section as long as possible isone of them, which is for improving manufacturing efficiency and is reached by adaptively adjustingthe step direction and the step size at every crossing point to obtain optimized secant height. Thelayer thickness determination can be divided into two phases: the geometry-based thicknessestimation and the material-based thickness verifying. During the former phase, the geometrytolerance is divided into two parts: a variety of curves are approximated by a circular arc, whichintroduces the first part, and the deviation error between the contour line in LM process and thecircular arc generates the second part. The latter phase is mainly verifying the layer thicknessestimated in the former stage and determining a new one if necessary. In addition, an example usingthis slicing algorithm is also illustrated. 展开更多
关键词 Rapid prototyping Ideal functional material components direct and adaptiveslicing Surface/plane intersection MARCHING
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THE BOREL DIRECTIONS OF ALGEBROIDAL FUNCTION AND ITS COEFFICIENT FUNCTIONS 被引量:2
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作者 张少华 张晓梅 孙道椿 《Acta Mathematica Scientia》 SCIE CSCD 2014年第2期241-251,共11页
In this article, the relationship between the Borel direction of algebroidal function and its coefficient functions is studied for the first time. To begin with, several theorems of algebroidal functions in unit disk ... In this article, the relationship between the Borel direction of algebroidal function and its coefficient functions is studied for the first time. To begin with, several theorems of algebroidal functions in unit disk are proved. By these theorems, some interesting conclusions are obtained. 展开更多
关键词 Algebroidal function coefficient function Borel direction.
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Direct Multiscale Analysis of Stability of an Axially Moving Functionally Graded Beam with Time-Dependent Velocity 被引量:4
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作者 Ting Yan Tianzhi Yang Liqun Chen 《Acta Mechanica Solida Sinica》 SCIE EI CSCD 2020年第2期150-163,共14页
In this study,the transverse vibration of a traveling beam made of functionally graded material was analyzed.The material gradation was assumed to vary continuously along the thickness direction of the beam in the for... In this study,the transverse vibration of a traveling beam made of functionally graded material was analyzed.The material gradation was assumed to vary continuously along the thickness direction of the beam in the form of power law exponent.The effect of the longitudinally varying tension due to axial acceleration was highlighted,and the dependence of the tension on the finite support rigidity was also considered.A complex governing equation of the functionally graded beam was derived by the Hamilton principle,in which the geometric nonlinearity,material properties and axial load were incorporated.The direct multiscale method was applied to the analysis process of an axially moving functionally graded beam with timedependent velocity,and the natural frequency and solvability conditions were obtained.Based on the conditions,the stability boundaries of subharmonic resonance and combination resonance were obtained.It was found that the dynamic behavior of axial moving beams could be tuned by using the distribution law of the functional gradient parameters. 展开更多
关键词 Axial motion functionally graded beam direct multiscale method Support rigidity Stability boundary
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Well production optimization using streamline features-based objective function and Bayesian adaptive direct search algorithm 被引量:4
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作者 Qi-Hong Feng Shan-Shan Li +2 位作者 Xian-Min Zhang Xiao-Fei Gao Ji-Hui Ni 《Petroleum Science》 SCIE CAS CSCD 2022年第6期2879-2894,共16页
Well production optimization is a complex and time-consuming task in the oilfield development.The combination of reservoir numerical simulator with optimization algorithms is usually used to optimize well production.T... Well production optimization is a complex and time-consuming task in the oilfield development.The combination of reservoir numerical simulator with optimization algorithms is usually used to optimize well production.This method spends most of computing time in objective function evaluation by reservoir numerical simulator which limits its optimization efficiency.To improve optimization efficiency,a well production optimization method using streamline features-based objective function and Bayesian adaptive direct search optimization(BADS)algorithm is established.This new objective function,which represents the water flooding potential,is extracted from streamline features.It only needs to call the streamline simulator to run one time step,instead of calling the simulator to calculate the target value at the end of development,which greatly reduces the running time of the simulator.Then the well production optimization model is established and solved by the BADS algorithm.The feasibility of the new objective function and the efficiency of this optimization method are verified by three examples.Results demonstrate that the new objective function is positively correlated with the cumulative oil production.And the BADS algorithm is superior to other common algorithms in convergence speed,solution stability and optimization accuracy.Besides,this method can significantly accelerate the speed of well production optimization process compared with the objective function calculated by other conventional methods.It can provide a more effective basis for determining the optimal well production for actual oilfield development. 展开更多
关键词 Well production Optimization efficiency Streamline simulation Streamline feature Objective function Bayesian adaptive direct search algorithm
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Decellularized optic nerve functional scaffold transplant facilitates directional axon regeneration and remyelination in the injured white matter of the rat spinal cord 被引量:7
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作者 Yu-Rong Bai Bi-Qin Lai +6 位作者 Wei-Tao Han Jia-Hui Sun Ge Li Ying Ding Xiang Zeng Yuan-Huan Ma Yuan-Shan Zeng 《Neural Regeneration Research》 SCIE CAS CSCD 2021年第11期2276-2283,共8页
Axon regeneration and remyelination of the damaged region is the most common repair strategy for spinal cord injury.However,achieving good outcome remains difficult.Our previous study showed that porcine decellularize... Axon regeneration and remyelination of the damaged region is the most common repair strategy for spinal cord injury.However,achieving good outcome remains difficult.Our previous study showed that porcine decellularized optic nerve better mimics the extracellular matrix of the embryonic porcine optic nerve and promotes the directional growth of dorsal root ganglion neurites.However,it has not been reported whether this material promotes axonal regeneration in vivo.In the present study,a porcine decellularized optic nerve was seeded with neurotrophin-3-overexpressing Schwann cells.This functional scaffold promoted the directional growth and remyelination of regenerating axons.In vitro,the porcine decellularized optic nerve contained many straight,longitudinal channels with a uniform distribution,and microscopic pores were present in the channel wall.The spatial micro topological structure and extracellular matrix were conducive to the adhesion,survival and migration of neural stem cells.The scaffold promoted the directional growth of dorsal root ganglion neurites,and showed strong potential for myelin regeneration.Furthermore,we transplanted the porcine decellularized optic nerve containing neurotrophin-3-overexpressing Schwann cells in a rat model of T10 spinal cord defect in vivo.Four weeks later,the regenerating axons grew straight,the myelin sheath in the injured/transplanted area recovered its structure,and simultaneously,the number of inflammatory cells and the expression of chondroitin sulfate proteoglycans were reduced.Together,these findings suggest that porcine decellularized optic nerve loaded with Schwann cells overexpressing neurotrophin-3 promotes the directional growth of regenerating spinal cord axons as well as myelin regeneration.All procedures involving animals were conducted in accordance with the ethical standards of the Institutional Animal Care and Use Committee of Sun Yat-sen University(approval No.SYSU-IACUC-2019-B034)on February 28,2019. 展开更多
关键词 axonal regeneration decellularized optic nerve directional regeneration functional scaffold microenvironment NEUROTROPHIN-3 optic nerve REMYELINATION Schwann cells tissue engineering white matter injury
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Radial Basis Function Interpolation and Galerkin Projection for Direct Trajectory Optimization and Costate Estimation 被引量:1
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作者 Hossein Mirinejad Tamer Inanc Jacek M.Zurada 《IEEE/CAA Journal of Automatica Sinica》 SCIE EI CSCD 2021年第8期1380-1388,共9页
This work presents a novel approach combining radial basis function(RBF)interpolation with Galerkin projection to efficiently solve general optimal control problems.The goal is to develop a highly flexible solution to... This work presents a novel approach combining radial basis function(RBF)interpolation with Galerkin projection to efficiently solve general optimal control problems.The goal is to develop a highly flexible solution to optimal control problems,especially nonsmooth problems involving discontinuities,while accounting for trajectory accuracy and computational efficiency simultaneously.The proposed solution,called the RBF-Galerkin method,offers a highly flexible framework for direct transcription by using any interpolant functions from the broad class of global RBFs and any arbitrary discretization points that do not necessarily need to be on a mesh of points.The RBF-Galerkin costate mapping theorem is developed that describes an exact equivalency between the Karush-Kuhn-Tucker(KKT)conditions of the nonlinear programming problem resulted from the RBF-Galerkin method and the discretized form of the first-order necessary conditions of the optimal control problem,if a set of discrete conditions holds.The efficacy of the proposed method along with the accuracy of the RBF-Galerkin costate mapping theorem is confirmed against an analytical solution for a bang-bang optimal control problem.In addition,the proposed approach is compared against both local and global polynomial methods for a robot motion planning problem to verify its accuracy and computational efficiency. 展开更多
关键词 Costate estimation direct trajectory optimization Galerkin projection numerical optimal control radial basis function interpolation
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Three-dimensional free vibration analysis of multi-directional functionally graded piezoelectric annular plates on elastic foundations via state space based differential quadrature method 被引量:3
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作者 M.H.YAS N.MOLOUDI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2015年第4期439-464,共26页
The three-dimensional free vibration analysis of a multi-directional func- tionally graded piezoelectric (FGP) annular plate resting on two parameter (Pasternak) elastic foundations is investigated under different... The three-dimensional free vibration analysis of a multi-directional func- tionally graded piezoelectric (FGP) annular plate resting on two parameter (Pasternak) elastic foundations is investigated under different boundary conditions. The material properties are assumed to vary continuously along the radial and thickness directions and have exponent-law distribution. A semi-analytical approach named the state space based differential quadrature method (SSDQM) is used to provide an analytical solution along the thickness using the state space method (SSM) and an approximate solution along the radial direction using the one-dimensional differential quadrature method (DQM). The influence of the Winkler and shear stiffness of the foundation~ the material property graded variations, and the circumferential wave number on the nomdimensional natural frequency of multi-directional FGP annular plates is studied. 展开更多
关键词 multi-directional functionally graded PIEZOELECTRIC annular plate freevibration
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ON THE NEVANLINNA DIRECTION OF ALGEBROID FUNCTIONS
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作者 张洪申 孙道椿 《Acta Mathematica Scientia》 SCIE CSCD 2012年第4期1441-1448,共8页
In this paper, we prove that for an algebroid function w(z), the singular direction argz = φ0, satisfying that for arbitrary ε(0 〈 ε 〈 2/π) and any given α ∈ C^^,limr→+∞ log τ/n(τ,φ0-ε,φ0+ε,w=a... In this paper, we prove that for an algebroid function w(z), the singular direction argz = φ0, satisfying that for arbitrary ε(0 〈 ε 〈 2/π) and any given α ∈ C^^,limr→+∞ log τ/n(τ,φ0-ε,φ0+ε,w=a)=+∞ holds with at most; 2v possible exceptional values of a, is the Ncvanlinna direction of w(z). 展开更多
关键词 algebroid function Nevanlinna direction algebroid function Nevanlinna direction
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Onsite-effects of dual-hemisphere versus conventional single-hemisphere transcranial direct current stimulation A functional MRI study
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作者 Yong Hyun Kwon Sung Ho Jang 《Neural Regeneration Research》 SCIE CAS CSCD 2012年第24期1889-1894,共6页
We performed functional MRI examinations in six right-handed healthy subjects.During functional MRI scanning,transcranial direct current stimulation was delivered with the anode over the right primary sensorimotor cor... We performed functional MRI examinations in six right-handed healthy subjects.During functional MRI scanning,transcranial direct current stimulation was delivered with the anode over the right primary sensorimotor cortex and the cathode over the left primary sensorimotor cortex using dual-hemispheric transcranial direct current stimulation.This was compared to a cathode over the left supraorbital area using conventional single-hemispheric transcranial direct current stimulation. Voxel counts and blood oxygenation level-dependent signal intensities in the right primary sensorimotor cortex regions were estimated and compared between the two transcranial direct current stimulation conditions.Our results showed that dual-hemispheric transcranial direct current stimulation induced greater cortical activities than single-hemispheric transcranial direct current stimulation.These findings suggest that dual-hemispheric transcranial direct current stimulation may provide more effective cortical stimulation than single-hemispheric transcranial direct current stimulation. 展开更多
关键词 transcranial direct current stimulation dual-hemispheric stimulation cortical activation functional MRI primary sensorimotor cortex NEUROIMAGING regeneration neural regeneration
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AXISYMMETRIC BENDING OF TWO-DIRECTIONAL FUNCTIONALLY GRADED CIRCULAR AND ANNULAR PLATES 被引量:6
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作者 Guojun Nie Zheng Zhong 《Acta Mechanica Solida Sinica》 SCIE EI 2007年第4期289-295,共7页
Assuming the material properties varying with an exponential law both in the thick- ness and radial directions, axisymmetric bending of two-directional functionally graded circular and annular plates is studied using ... Assuming the material properties varying with an exponential law both in the thick- ness and radial directions, axisymmetric bending of two-directional functionally graded circular and annular plates is studied using the semi-analytical numerical method in this paper. The deflections and stresses of the plates are presented. Numerical results show the well accuracy and convergence of the method. Compared with the finite element method, the semi-analytical nu- merical method is with great advantage in the computational efficiency. Moreover, study on ax- isymmetric bending of two-directional functionally graded annular plate shows that such plates have better performance than those made of isotropic homogeneous materials or one-directional functionally graded materials. Two-directional functionally graded material is a potential alternative to the one-directional functionally graded material. And the integrated design of materials and structures can really be achieved in two-directional functionally graded materials. 展开更多
关键词 two-directional functionally graded materials circular and annular plates axisym-metric bending semi-analytical numerical method integrated design
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3D printing of poly(ethyleneimine)-functionalized Mg-Al mixed metal oxide monoliths for direct air capture of CO_(2)
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作者 Qingyang Shao Zhuozhen Gan +4 位作者 Bingyao Ge Xuyi Liu Chunping Chen Dermot O’Hare Xuancan Zhu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期491-500,共10页
Direct air capture(DAC)of CO_(2)plays an indispensable role in achieving carbon-neutral goals as one of the key negative emission technologies.Since large air flows are required to capture the ultradilute CO_(2)from t... Direct air capture(DAC)of CO_(2)plays an indispensable role in achieving carbon-neutral goals as one of the key negative emission technologies.Since large air flows are required to capture the ultradilute CO_(2)from the air,lab-synthesized adsorbents in powder form may cause unacceptable gas pressure drops and poor heat and mass transfer efficiencies.A structured adsorbent is essential for the implementation of gas-solid contactors for cost-and energy-efficient DAC systems.In this study,efficient adsorbent poly(ethyleneimine)(PEI)-functionalized Mg-Al-CO_(3)layered double hydroxide(LDH)-derived mixed metal oxides(MMOs)are three-dimensional(3D)printed into monoliths for the first time with more than 90%adsorbent loadings.The printing process has been optimized by initially printing the LDH powder into monoliths followed by calcination into MMO monoliths.This structure exhibits a 32.7%higher specific surface area and a 46.1%higher pore volume,as compared to the direct printing of the MMO powder into a monolith.After impregnation of PEI,the monolith demonstrates a large adsorption capacity(1.82 mmol/g)and fast kinetics(0.7 mmol/g/h)using a CO_(2)feed gas at 400 ppm at 25℃,one of the highest values among the shaped DAC adsorbents.Smearing of the amino-polymers during the post-printing process affects the diffusion of CO_(2),resulting in slower adsorption kinetics of pre-impregnation monoliths compared to post-impregnation monoliths.The optimal PEI/MeOH ratio for the post-impregnation solution prevents pores clogging that would affect both adsorption capacity and kinetics. 展开更多
关键词 3D printing Mixed metal oxides Amine functionalization Structured adsorbent direct air capture
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On Singular Directions of Entire and Meromorphic Functions
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作者 常建明 宋国栋 任福尧 《Northeastern Mathematical Journal》 CSCD 2000年第4期379-382,共4页
关键词 entire and meromorphic function Martys direction GROWTH
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