The smallest borafullerene U@C_(27)B has been synthesized using a laser vaporization cluster source and detected as the most abundant species in the U@C_(2n-1)B family.Density functional theory(DFT)calculations show t...The smallest borafullerene U@C_(27)B has been synthesized using a laser vaporization cluster source and detected as the most abundant species in the U@C_(2n-1)B family.Density functional theory(DFT)calculations show that the U atom is placed just at the center of the cage interacting almost in the same way with all its atoms as if the cage were a 28-hapto ligand.展开更多
基金Spanish Ministry of Science(grants PID2020-112762GB-I00 and PID2020-113187GB-I00)the Generalitat de Catalunya(grant 2017SGR629)the URV for support.
文摘The smallest borafullerene U@C_(27)B has been synthesized using a laser vaporization cluster source and detected as the most abundant species in the U@C_(2n-1)B family.Density functional theory(DFT)calculations show that the U atom is placed just at the center of the cage interacting almost in the same way with all its atoms as if the cage were a 28-hapto ligand.
