Two series of lanthanide compounds, namely, chlorides containing different numbers of both 1,10-phenanthroline （Phen） molecules and chloride anions in the first coordination sphere, and Schiff Bases （SBs） derived ...Two series of lanthanide compounds, namely, chlorides containing different numbers of both 1,10-phenanthroline （Phen） molecules and chloride anions in the first coordination sphere, and Schiff Bases （SBs） derived from Pyridoxal （PL） and amino acids, were characterized by single crystal X-ray diffraction and luminescence techniques. The combined use of these techniques for the analysis of long-distance europium non-covalent interactions was performed for the first time. As a result, the correlation between supramolecular organization and the features of the Eum electronic transitions was found for the compounds of the first series. Strong non-covalent interactions between pyridoxal tings of SBs （the second series of compotmd） led to the formation of 1：2 species and four-dentate coordination function of these SBs in aqueous solution.展开更多
基金Russian Science Support Foundation, Russian Foundation of Basic Research (07-03-12196 and grant MK-6026.2008.9)
文摘Two series of lanthanide compounds, namely, chlorides containing different numbers of both 1,10-phenanthroline （Phen） molecules and chloride anions in the first coordination sphere, and Schiff Bases （SBs） derived from Pyridoxal （PL） and amino acids, were characterized by single crystal X-ray diffraction and luminescence techniques. The combined use of these techniques for the analysis of long-distance europium non-covalent interactions was performed for the first time. As a result, the correlation between supramolecular organization and the features of the Eum electronic transitions was found for the compounds of the first series. Strong non-covalent interactions between pyridoxal tings of SBs （the second series of compotmd） led to the formation of 1：2 species and four-dentate coordination function of these SBs in aqueous solution.
