A novel bat-like ZnO nanostructure was synthesized on the silicon substrate by simple ther- mal evaporation of zinc powders without any catalyst. Each bat-like nanorod （＂nanobat＂） is composed of a hexagonal head, ...A novel bat-like ZnO nanostructure was synthesized on the silicon substrate by simple ther- mal evaporation of zinc powders without any catalyst. Each bat-like nanorod （＂nanobat＂） is composed of a hexagonal head, a continuous neck and a thin handle. High-resolution transmission electron microscopy and selected area electron diffraction results reveal the single-crystalline feature and the growing direction along [0001] of the nanobat. The vapor- solid mechanism was found suitable to explain the growth process of the nanobat and a schematic model was proposed in detail based on the experimental results.展开更多
A Mg-6Zn-3Gd(mass fraction,%) alloy,noted as ZG63,was coated by different micro-arc oxidation(MAO) processes,and the coating structure and corrosion resistance of the alloy were studied using scanning electron microsc...A Mg-6Zn-3Gd(mass fraction,%) alloy,noted as ZG63,was coated by different micro-arc oxidation(MAO) processes,and the coating structure and corrosion resistance of the alloy were studied using scanning electron microscopy(SEM),glancing angle X-ray diffractometry(GAXRD) and various electrochemical methods.The micro-arc oxidation process consists of three stages and corresponds with different coating structures.In the initial stage,the coating thickness is linearly increased and is controlled by electrochemical polarization.In the second stage,the coating grows mainly inward and accords with parabolic regularity.In the third stage,the loose coating forms and is controlled by local arc light.The looser coating is mainly composed of MgSiO3 and the compact coating is mainly composed of MgO.From micro-arc oxidation stage to local arc light stage,the corrosion resistance of the coated alloy firstly increases and then decreases.The satisfied corrosion resistance corresponds to the coating time ranging from 6 to10 min.展开更多
A crop growth model of WOFOST was calibrated and validated through rice field experiments from 2001 to 2004 in Jinhua and Hangzhou, Zhejiang Province. For late rice variety Xiushui 11 and hybrid Xieyou 46, the model w...A crop growth model of WOFOST was calibrated and validated through rice field experiments from 2001 to 2004 in Jinhua and Hangzhou, Zhejiang Province. For late rice variety Xiushui 11 and hybrid Xieyou 46, the model was calibrated to obtain parameter values using the experimental data of years 2001 and 2002, then the parameters were validated by the data obtained during 2003. For single hybrid rice Liangyoupeijiu, the data recorded in 2004 and 2003 were used for calibration and validation, respectively. The main focus of the study was as follows： the WOFOST model is good in simulating rice potential growth in Zhejiang and can be used to analyze the process of rice growth and yield potential. The potential yield obtained from the WOFOST model was about 8100 kg/ha for late rice and 9300 kg/ha for single rice. The current average yield in Jinhua is only about 78% （late rice） and 70% （single rice） of their potential yield. The results of the simulation also showed that the currant practice of management at the middle and late growth stages of rice should be reexamined and improved to reach optimal rice growth.展开更多
Growth process of the NaY zeolite membranes was investigated by fluoride-containing precursor synthesis gel.Compared with the fluoride-free precursor synthesis gel,the irregular NaY zeolite crystals were dissolved int...Growth process of the NaY zeolite membranes was investigated by fluoride-containing precursor synthesis gel.Compared with the fluoride-free precursor synthesis gel,the irregular NaY zeolite crystals were dissolved into amorphous by the fluoride-containing precursor synthesis gel initially,the amorphous contained the Y-type zeolite characteristic bands by the IR characterization.The fine square NaY zeolite crystals arose from the amorphous,which were accumulated and gradually grew into a dense NaY zeolite layer on the support surface after 6.5 h.Because the excessive NaY zeolites were dissolved by the strong alkaline and fluoride-containing precursor synthesis gel,there was plenty of amorphous on NaY zeolites layer for prolonging the crystallization time.The assynthesized NaY zeolite membranes had a good separation performance and repeatability for separation of 10 wt%methanol(MeOH)/methyl methacrylate(MMA) mixture by pervaporation,the flux and separation factor were(1.27 ± 0.07) kg·M^(-2)·h^(-1) and(4900 ± 1500) at 323 K,respectively.Besides,the NaY zeolite membranes were applied to separate the other short chain alcohol from the various alcohol/organic ester and alcohol/organic ether mixtures,the NaY zeolite membranes showed high short chain alcohol perm-selectivity.展开更多
Three kinds of tetrapod-like ZnO nanostructures have been synthesized simultaneously via pure Zn chemical vapor deposition on silicon wafers with （111） orientation （Si （111）） at 920 ℃. X-ray diffraction indicat...Three kinds of tetrapod-like ZnO nanostructures have been synthesized simultaneously via pure Zn chemical vapor deposition on silicon wafers with （111） orientation （Si （111）） at 920 ℃. X-ray diffraction indicates that the nanotetrapods are of wurtzite structure. The morphology and the microstructure of the nanotetrapods are investigated by the scanning electron microscopy. Selected area electron diffraction shows the growth direction, and energy dispersive X-ray spectroscopy reveals the atomic composition ratio of Zn/O. The growth process is briefly discussed. The optical property of the products was also recorded by means of photoluminescence spectroscopy.展开更多
Analysis on the deposition behavior of spray on deposition surface was made and an optimization method for the movement parameters （u, ω） of substrate was obtained. Simultaneously, a mathematical model of growth of...Analysis on the deposition behavior of spray on deposition surface was made and an optimization method for the movement parameters （u, ω） of substrate was obtained. Simultaneously, a mathematical model of growth of tubular preform, specifically aimed at the kind of atomizer that is fixed and with a tilt angle was established. By in- tegrating the optimization method and the mathematical model, the growth process and shape of preform were simu- lated. The results show that the tilt angle of atomizer plays an important role on the dimensions and shapes of tubular preforms and it can provide a guidance for the development of spray forming equipment.展开更多
With advantages of low costs and high energy density,Li–S batteries are considered as one of the most promising energy storage devices.However,Li_(2)S_(2) with a high dissociation energy and insulative properties is ...With advantages of low costs and high energy density,Li–S batteries are considered as one of the most promising energy storage devices.However,Li_(2)S_(2) with a high dissociation energy and insulative properties is hard to convert into Li_(2)S,resulting in underutilization of sulfur capacity.Herein,Co-Mo_(2)C@C yolk–shell spheres as nanoreactors were designed to confront this challenge rationally.The Co-Mo_(2)C@C-induced Li_(2)S_(1/2) nucleation and growth in the three-dimensional process and the cathode produced more Li_(2)S after full discharge.Experimental studies and theoretical calculations reveal that the conversion barrier from Li_(2)S_(2) into Li_(2)S was lowered while the diffusion of lithium ions and electron transfer accelerated when using the Co-Mo_(2)C@C catalyst.Based on the above advantages,the Co-Mo_(2)C@C/S cathode exhibits a high reversible capacity and excellent cyclic stability,such as an initial specific capacity of 1200 mAh g^(−1) at 0.1 C with 709 mAh g^(−1) at 1.0 C after 1000 cycles with a low capacity fading rate of 0.04%per cycle.Even at high densities of 3.0 C and 5.0 C,the specific capacities are 647.6 and 557.7 mAh g^(−1) after 400 cycles,respectively.Impressively,it also shows ca.770 and 900 mAh g^(−1) at 0.2 C after 50 cycles with high sulfur loadings of 4.2 and 5.1 mg cm−2,respectively.The present work may provide new insights into the design of nanoreactors to promote Li_(2)S_(1/2) growth in a three-dimensional process and accelerate conversion from solid Li_(2)S_(2) to solid Li_(2)S in high performance Li–S batteries.展开更多
Purpose The purpose of this study is to explore deep learning methods for processing high-throughput small-angle X-ray scattering(SAXS)experimental data.Methods The deep learning algorithm was trained and validated us...Purpose The purpose of this study is to explore deep learning methods for processing high-throughput small-angle X-ray scattering(SAXS)experimental data.Methods The deep learning algorithm was trained and validated using simulated SAXS data,which were generated in batches based on the theoretical SAXS formula using Python code.Our self-developed SAXSNET,a convolutional neural network based on PyTorch,was employed to classify SAXS data for various shapes of nanoparticles.Additionally,we conducted comparative analysis of classification algorithms including ResNet-18,ResNet-34 and Vision Transformer.Random Forest and XGboost regression algorithms were used for the nanoparticle size prediction.Finally,we evaluated the aforementioned shape classification and numerical regression methods using actual experimental data.A pipeline segment is established for the processing of SAXS data,incorporating deep learning classification algorithms and numerical regression algorithms.Results After being trained with simulated data,the four deep learning algorithms achieved a prediction accuracy of over 96%on the validation set.The fine-tuned deep learning model demonstrated robust generalization capabilities for predicting the shapes of experimental data,enabling rapid and accurate identification of morphological changes in nanoparticles during experiments.The Random Forest and XGboost regression algorithms can simultaneously provide faster and more accurate predictions of nanoparticle size.Conclusion The pipeline segment constructed in this study,integrating deep learning classification and regression algorithms,enables real-time processing of high-throughput SAXS data.It aims to effectively mitigates the impact of human factors on data processing results and enhances the standardization,automation,and intelligence of synchrotron radiation experiments.展开更多
The microphysical structure of snow clouds and the growth process of snow crystals were observed by means of instrumented aircraft, weather radar, snow crystal observations etc. in Urumqi region during the winter of 1...The microphysical structure of snow clouds and the growth process of snow crystals were observed by means of instrumented aircraft, weather radar, snow crystal observations etc. in Urumqi region during the winter of 1982. The analysis of three cases show that about 70% of snow mass growth is produced in the lower layer below 2000 m under the cold front, and that the concentration of ice crystals is as high as 60 L^(-1) and the supercooled water is absent in lower clouds. We may infer that the deposition of ice crystals and the aggregation of snow crystals are important processes for the snow development. The microphysical structure of the snow band near the front aloft and its characteristics as a seeder cloud are also described in this paper.展开更多
The growth of LaBrs：Ce^3＋ crystal by the vertical Bridgman process in a nonvacuum atmosphere was reported. According to the dehydration procedure of LaBr3·7H2O and CeBr3·7H2O investigated by differential t...The growth of LaBrs：Ce^3＋ crystal by the vertical Bridgman process in a nonvacuum atmosphere was reported. According to the dehydration procedure of LaBr3·7H2O and CeBr3·7H2O investigated by differential thermal analysis/thermogravimetry （DTA/TG）, anhydrous LaBr3 and CeBr3 were prepared by heating LaBr3·7H2O and CeBr3·7H2O at 240-260℃ for 5-6 h in dried HBr atmosphere. Using the feed materials prepared from the anhydrous lanthanon bromides, a 0.5 mole fraction Ce^3＋ doped LaBr3 crystal with size ofФ25 mm×50 mm had been grown by vertical Bridgman process successfully. By sealing the feed material in a platinum crucible, the crystal could be grown in a nonvacuum atmosphere as the oxidization and volatilization of the melt could be avoided. The crystal was grown with the optimum conditions such as a growth rate of 0.5-1.0 mm/h and a temperature gradient of around 30℃/cm across solid-liquid interface under a furnace temperature of 850-880℃. The crystal was characterized by DTA/TG, X-ray diffraction （XRD）, optical transmission, photoluminescence and X-ray stimulated luminescence measurement. The Bridgman process was confirmed to be promising for growing transparent LaBr3：Ce^3＋ crystal with high optical quality.展开更多
We reported the development of a Ф100 cm growth apparatus for skull melting growth of yttria-stabilized cubic zirconia(YSZ) crystals and more than 1000 kg crystals have been grown in the furnace each time.The growth ...We reported the development of a Ф100 cm growth apparatus for skull melting growth of yttria-stabilized cubic zirconia(YSZ) crystals and more than 1000 kg crystals have been grown in the furnace each time.The growth conditions were optimized and the structure of the as-grown crystals was characterized by X-ray diffraction.The transmittance of 15 mol.% yttria-stabilized cubic zirconia crystal was nearly 80% in the range of 400–1600 nm.The refractive indices were measured and fitted the Sellmeier equation whi...展开更多
A new meso-mechanical testing scheme based on SEM was developed to carry out the experiment of microfracturing process of rocks. The microfracturing process of the pre-crack marble sample on surrounding rock in the im...A new meso-mechanical testing scheme based on SEM was developed to carry out the experiment of microfracturing process of rocks. The microfracturing process of the pre-crack marble sample on surrounding rock in the immerged Long-big tunnel in Jinping Cascade II Hydropower Station under uniaxial compression was recorded by using the testing scheme. According to the stereology theory, the propagation and coalescent of cracks at meso-scale were quantitatively investigated with digital technology. Therefore, the basic geometric information of rock microcracks such as area, angle, length, width, perimeter, was obtained from binary images after segmentation. The failure mechanism of specimen under uniaxial compression with the quantitative information was studied from macro and microscopic point of view. The results show that the image of microfracturing process of the specimen can be observed and recorded digitally. During the damage of the specimen, the distribution of microcracks in the specimen is still subjected to exponential distribution with some microcracks concentrated in certain regions. Finally, the change law of the fractal dimension of the local element in marble sample under different external load conditions is obtained by means of the statistical calculation of the fractal dimension.展开更多
The effect of vanadium on the DIFT (Deformation Induced Ferrite Transformation) microstructure coarsening in low carbon steel during the continuous cooling processes and isothermal processes at different temperatures ...The effect of vanadium on the DIFT (Deformation Induced Ferrite Transformation) microstructure coarsening in low carbon steel during the continuous cooling processes and isothermal processes at different temperatures were investigated using thermo-simulator.The results showed that the steel containing a small amount of vanadium had the similar velocity of grain growth with the vanadium free steel during the continuous cooling process,but a lower velocity of grain growth than that of vanadium free steel during isothermal processes at high temperatures.On the other hand,the vanadium remarkably inhibited grain growth in the steel containing a high amount of vanadium during both the continuous cooling and isothermal processes.Vanadium dissolved in matrix is indicated as an important factor on restraining grain growth through estimating the driving force of normal grain growth and the resistance of precipitation particles of vanadium on grain growth.The influencing mechanism of vanadium dissolved in matrix on the grain growth during the controlled cooling process is discussed.展开更多
China’s foreign trade from January to August According to Customs figures,China’s total import and export in August reached 2.04 trillion yuan,down 9.7%year on year(the same below).Export was 1.2 trillion yuan,down ...China’s foreign trade from January to August According to Customs figures,China’s total import and export in August reached 2.04 trillion yuan,down 9.7%year on year(the same below).Export was 1.2 trillion yuan,down 6.1%,and import 0.84 trillion yuan,down 14.3%.Trade surplus was 368 billion yuan,an increase of 20.1%.In terms of the U.S.dollar,the total import and export in August reached US$333.5 billion,展开更多
In this work, TiO2 nanorods with uniform diameter of about 100 nm and a length of several micrometers were successfully prepared by the sol-gel template method. Also the influence of molar ratios of precursor on the m...In this work, TiO2 nanorods with uniform diameter of about 100 nm and a length of several micrometers were successfully prepared by the sol-gel template method. Also the influence of molar ratios of precursor on the morphology and structure of TiO2 nanorods has been investigated. The prepared samples were characterized by Fourier transform infrared spectroscopy （FTIR）, X-ray diffraction （XRD） and scanning electron microscopy （SEM）. The XRD results indicated that the TiO2 nanorods were crystallized in the anatase and rutile phases, after annealing to 400-700℃ up to 2 h.展开更多
New armament systems are subjected to the method for dealing with multi-stage system reliability-growth statistical problems of diverse population in order to improve reliability before starting mass production. Aimin...New armament systems are subjected to the method for dealing with multi-stage system reliability-growth statistical problems of diverse population in order to improve reliability before starting mass production. Aiming at the test process which is high expense and small sample-size in the development of complex system, the specific methods are studied on how to process the statistical information of Bayesian reliability growth regarding diverse populations. Firstly, according to the characteristics of reliability growth during product development, the Bayesian method is used to integrate the testing information of multi-stage and the order relations of distribution parameters. And then a Gamma-Beta prior distribution is proposed based on non-homogeneous Poisson process（NHPP） corresponding to the reliability growth process. The posterior distribution of reliability parameters is obtained regarding different stages of product, and the reliability parameters are evaluated based on the posterior distribution. Finally, Bayesian approach proposed in this paper for multi-stage reliability growth test is applied to the test process which is small sample-size in the astronautics filed. The results of a numerical example show that the presented model can make use of the diverse information synthetically, and pave the way for the application of the Bayesian model for multi-stage reliability growth test evaluation with small sample-size. The method is useful for evaluating multi-stage system reliability and making reliability growth plan rationally.展开更多
The transition from middle-income to high-income stage is fraught with risks of growth divergence. Economic transition is clouded by the following possibilities： （1）falling share of industrial seetor through indust...The transition from middle-income to high-income stage is fraught with risks of growth divergence. Economic transition is clouded by the following possibilities： （1）falling share of industrial seetor through industrial depression and weakening growth momentum caused by the large urbanization costs; （2） the subordination of service sector as a result of nearly irreversibly industrial professional, which falters the process of service sector transition and upgrading,＂ （3） inefficient knowledge production allocation and human capital upgrade due to the absence of incentivized compensation of knowledge consumption. We suggest that a country should reshape its efficiency model by upgrading knowledge factor and human capital as the pre-requisite. Given the dilemmas of transition, China should take the faetorization trend of service sector and reshape efficiency model through institutional reform, ensuring that service sector will develop in tandem with industrial sector.展开更多
The regional climate model RegCM3 incorporating the crop model CERES,called the RegCM3CERES model,was used to study the efects of crop growth and development on regional climate and hydrological processes over seven r...The regional climate model RegCM3 incorporating the crop model CERES,called the RegCM3CERES model,was used to study the efects of crop growth and development on regional climate and hydrological processes over seven river basins in China.A 20-year numerical simulation showed that incorporating the crop growth and development processes improved the simulation of precipitation over the Haihe River Basin,Songhuajiang River Basin and Pearl River Basin.When compared with the RegCM3 control run,RegCM3CERES reduced the negative biases of monthly mean temperature over most of the seven basins in summer,especially the Haihe River Basin and Huaihe River Basin.The simulated maximum monthly evapotranspiration for summer(JJA)was around 100 mm in the basins of the Yangtze,Haihe,Huaihe and Pearl Rivers.The seasonal and annual variations of water balance components(runof,evapotranspiration and total precipitation)over all seven basins indicate that changes of evapotranspiration agree well with total precipitation.Compared to the RegCM3,RegCM3CERES simulations indicate reduced local water recycling rate over most of the seven basins due to lower evapotranspiration and greater water flux into these basins and an increased precipitation in the Heihe River Basin and Yellow River Basin,but reduced precipitation in the other five basins.Furthermore,a lower summer leaf area index(1.20 m2m 2),greater root soil moisture(0.01 m3m 3),lower latent heat flux(1.34 W m 2),and greater sensible heat flux(2.04 W m 2)are simulated for the Yangtze River Basin.展开更多
We studied the formation of heartwood in Ery- throphleumfordii Oliv., an endangered rosewood species, by cross-section analysis on 52 stumps aged 28-57 years and arbitrarily sampled from natural forests in South China...We studied the formation of heartwood in Ery- throphleumfordii Oliv., an endangered rosewood species, by cross-section analysis on 52 stumps aged 28-57 years and arbitrarily sampled from natural forests in South China. Width and area of heartwood were positively correlated with age and xylem width （XW）, and were independent of annual radial growth. The proportions of heartwood and sapwood areas were equal at about 40 years. The heartwood formation pro- cess was simulated by linear regression of age and XW.展开更多
Fault attributes generally display a consistent power–law-scaling relationship.Based on new 3 D seismic data,however,we found some exceptional fault attribute relationships of lengths(L)–throw(T)(vertical component ...Fault attributes generally display a consistent power–law-scaling relationship.Based on new 3 D seismic data,however,we found some exceptional fault attribute relationships of lengths(L)–throw(T)(vertical component of displacement),overlap zone length(Lo)–width(Wo)from a strike-slip fault system of the Ordovician carbonates in the Tarim Basin.The L–T relationship shows two linear segments with breakup at^40 km in fault length.This presents an exceptional throw increase in the second stage,which is attributed to a localization of vertical displacement and deformation in overlapping zones other than the different fault scales in a mature fault zone.The Lo–Wo relationship in the overlapping zones shows multiply stepped-shape patterns,suggesting multiple fault differential growth and periodic increase in fault size.Therefore,we propose a new alternative growth model of fault attributes in strike-slip fault zones,in which the overlapping zones accumulated localized displacement and deformation in the intracratonic strike-slip fault zone.展开更多
文摘A novel bat-like ZnO nanostructure was synthesized on the silicon substrate by simple ther- mal evaporation of zinc powders without any catalyst. Each bat-like nanorod （＂nanobat＂） is composed of a hexagonal head, a continuous neck and a thin handle. High-resolution transmission electron microscopy and selected area electron diffraction results reveal the single-crystalline feature and the growing direction along [0001] of the nanobat. The vapor- solid mechanism was found suitable to explain the growth process of the nanobat and a schematic model was proposed in detail based on the experimental results.
文摘A Mg-6Zn-3Gd(mass fraction,%) alloy,noted as ZG63,was coated by different micro-arc oxidation(MAO) processes,and the coating structure and corrosion resistance of the alloy were studied using scanning electron microscopy(SEM),glancing angle X-ray diffractometry(GAXRD) and various electrochemical methods.The micro-arc oxidation process consists of three stages and corresponds with different coating structures.In the initial stage,the coating thickness is linearly increased and is controlled by electrochemical polarization.In the second stage,the coating grows mainly inward and accords with parabolic regularity.In the third stage,the loose coating forms and is controlled by local arc light.The looser coating is mainly composed of MgSiO3 and the compact coating is mainly composed of MgO.From micro-arc oxidation stage to local arc light stage,the corrosion resistance of the coated alloy firstly increases and then decreases.The satisfied corrosion resistance corresponds to the coating time ranging from 6 to10 min.
文摘A crop growth model of WOFOST was calibrated and validated through rice field experiments from 2001 to 2004 in Jinhua and Hangzhou, Zhejiang Province. For late rice variety Xiushui 11 and hybrid Xieyou 46, the model was calibrated to obtain parameter values using the experimental data of years 2001 and 2002, then the parameters were validated by the data obtained during 2003. For single hybrid rice Liangyoupeijiu, the data recorded in 2004 and 2003 were used for calibration and validation, respectively. The main focus of the study was as follows： the WOFOST model is good in simulating rice potential growth in Zhejiang and can be used to analyze the process of rice growth and yield potential. The potential yield obtained from the WOFOST model was about 8100 kg/ha for late rice and 9300 kg/ha for single rice. The current average yield in Jinhua is only about 78% （late rice） and 70% （single rice） of their potential yield. The results of the simulation also showed that the currant practice of management at the middle and late growth stages of rice should be reexamined and improved to reach optimal rice growth.
基金supported by the National Natural Science Foundation of China (Grant No. 21868012 and 21968009)Jiangxi Provincial Department of Science and Technology (20171BCB24005, 20181ACH80003, 20192ACB80003 and 20192BBH80024)。
文摘Growth process of the NaY zeolite membranes was investigated by fluoride-containing precursor synthesis gel.Compared with the fluoride-free precursor synthesis gel,the irregular NaY zeolite crystals were dissolved into amorphous by the fluoride-containing precursor synthesis gel initially,the amorphous contained the Y-type zeolite characteristic bands by the IR characterization.The fine square NaY zeolite crystals arose from the amorphous,which were accumulated and gradually grew into a dense NaY zeolite layer on the support surface after 6.5 h.Because the excessive NaY zeolites were dissolved by the strong alkaline and fluoride-containing precursor synthesis gel,there was plenty of amorphous on NaY zeolites layer for prolonging the crystallization time.The assynthesized NaY zeolite membranes had a good separation performance and repeatability for separation of 10 wt%methanol(MeOH)/methyl methacrylate(MMA) mixture by pervaporation,the flux and separation factor were(1.27 ± 0.07) kg·M^(-2)·h^(-1) and(4900 ± 1500) at 323 K,respectively.Besides,the NaY zeolite membranes were applied to separate the other short chain alcohol from the various alcohol/organic ester and alcohol/organic ether mixtures,the NaY zeolite membranes showed high short chain alcohol perm-selectivity.
文摘Three kinds of tetrapod-like ZnO nanostructures have been synthesized simultaneously via pure Zn chemical vapor deposition on silicon wafers with （111） orientation （Si （111）） at 920 ℃. X-ray diffraction indicates that the nanotetrapods are of wurtzite structure. The morphology and the microstructure of the nanotetrapods are investigated by the scanning electron microscopy. Selected area electron diffraction shows the growth direction, and energy dispersive X-ray spectroscopy reveals the atomic composition ratio of Zn/O. The growth process is briefly discussed. The optical property of the products was also recorded by means of photoluminescence spectroscopy.
基金Sponsored by National Natural Science Foundation of China (50474082)
文摘Analysis on the deposition behavior of spray on deposition surface was made and an optimization method for the movement parameters （u, ω） of substrate was obtained. Simultaneously, a mathematical model of growth of tubular preform, specifically aimed at the kind of atomizer that is fixed and with a tilt angle was established. By in- tegrating the optimization method and the mathematical model, the growth process and shape of preform were simu- lated. The results show that the tilt angle of atomizer plays an important role on the dimensions and shapes of tubular preforms and it can provide a guidance for the development of spray forming equipment.
基金supported by the Key-Area Research and Development Program of Guangdong Province(grant no.2020B0909-19005)the National Natural Science Foundation of China(grant nos.21975056 and 22179025)+1 种基金The Major and Special Project in the Field of Intelligent Manufacturing of the Universities in Guangdong Province(grant no.2020ZDZX2067)the Natural Science Foundation of Huizhou University(grant no.HZU202004).
文摘With advantages of low costs and high energy density,Li–S batteries are considered as one of the most promising energy storage devices.However,Li_(2)S_(2) with a high dissociation energy and insulative properties is hard to convert into Li_(2)S,resulting in underutilization of sulfur capacity.Herein,Co-Mo_(2)C@C yolk–shell spheres as nanoreactors were designed to confront this challenge rationally.The Co-Mo_(2)C@C-induced Li_(2)S_(1/2) nucleation and growth in the three-dimensional process and the cathode produced more Li_(2)S after full discharge.Experimental studies and theoretical calculations reveal that the conversion barrier from Li_(2)S_(2) into Li_(2)S was lowered while the diffusion of lithium ions and electron transfer accelerated when using the Co-Mo_(2)C@C catalyst.Based on the above advantages,the Co-Mo_(2)C@C/S cathode exhibits a high reversible capacity and excellent cyclic stability,such as an initial specific capacity of 1200 mAh g^(−1) at 0.1 C with 709 mAh g^(−1) at 1.0 C after 1000 cycles with a low capacity fading rate of 0.04%per cycle.Even at high densities of 3.0 C and 5.0 C,the specific capacities are 647.6 and 557.7 mAh g^(−1) after 400 cycles,respectively.Impressively,it also shows ca.770 and 900 mAh g^(−1) at 0.2 C after 50 cycles with high sulfur loadings of 4.2 and 5.1 mg cm−2,respectively.The present work may provide new insights into the design of nanoreactors to promote Li_(2)S_(1/2) growth in a three-dimensional process and accelerate conversion from solid Li_(2)S_(2) to solid Li_(2)S in high performance Li–S batteries.
基金supported by the Innovation Program of the Institute of High Energy Physics,CAS(Grant Number 2023000034)the National Natural Science Foundation of China(Grant Numbers 22273013,12275300)National Key R&D Program of China(Grant Numbers 2022YFA1603802,2017YFA0403000).
文摘Purpose The purpose of this study is to explore deep learning methods for processing high-throughput small-angle X-ray scattering(SAXS)experimental data.Methods The deep learning algorithm was trained and validated using simulated SAXS data,which were generated in batches based on the theoretical SAXS formula using Python code.Our self-developed SAXSNET,a convolutional neural network based on PyTorch,was employed to classify SAXS data for various shapes of nanoparticles.Additionally,we conducted comparative analysis of classification algorithms including ResNet-18,ResNet-34 and Vision Transformer.Random Forest and XGboost regression algorithms were used for the nanoparticle size prediction.Finally,we evaluated the aforementioned shape classification and numerical regression methods using actual experimental data.A pipeline segment is established for the processing of SAXS data,incorporating deep learning classification algorithms and numerical regression algorithms.Results After being trained with simulated data,the four deep learning algorithms achieved a prediction accuracy of over 96%on the validation set.The fine-tuned deep learning model demonstrated robust generalization capabilities for predicting the shapes of experimental data,enabling rapid and accurate identification of morphological changes in nanoparticles during experiments.The Random Forest and XGboost regression algorithms can simultaneously provide faster and more accurate predictions of nanoparticle size.Conclusion The pipeline segment constructed in this study,integrating deep learning classification and regression algorithms,enables real-time processing of high-throughput SAXS data.It aims to effectively mitigates the impact of human factors on data processing results and enhances the standardization,automation,and intelligence of synchrotron radiation experiments.
文摘The microphysical structure of snow clouds and the growth process of snow crystals were observed by means of instrumented aircraft, weather radar, snow crystal observations etc. in Urumqi region during the winter of 1982. The analysis of three cases show that about 70% of snow mass growth is produced in the lower layer below 2000 m under the cold front, and that the concentration of ice crystals is as high as 60 L^(-1) and the supercooled water is absent in lower clouds. We may infer that the deposition of ice crystals and the aggregation of snow crystals are important processes for the snow development. The microphysical structure of the snow band near the front aloft and its characteristics as a seeder cloud are also described in this paper.
基金supported by the Scientific & Techni-cal Project of Zhejiang Province, China (No 2005C31029)the Doctor Science Foundation of Ningbo City, China(No 2005A610021)
文摘The growth of LaBrs：Ce^3＋ crystal by the vertical Bridgman process in a nonvacuum atmosphere was reported. According to the dehydration procedure of LaBr3·7H2O and CeBr3·7H2O investigated by differential thermal analysis/thermogravimetry （DTA/TG）, anhydrous LaBr3 and CeBr3 were prepared by heating LaBr3·7H2O and CeBr3·7H2O at 240-260℃ for 5-6 h in dried HBr atmosphere. Using the feed materials prepared from the anhydrous lanthanon bromides, a 0.5 mole fraction Ce^3＋ doped LaBr3 crystal with size ofФ25 mm×50 mm had been grown by vertical Bridgman process successfully. By sealing the feed material in a platinum crucible, the crystal could be grown in a nonvacuum atmosphere as the oxidization and volatilization of the melt could be avoided. The crystal was grown with the optimum conditions such as a growth rate of 0.5-1.0 mm/h and a temperature gradient of around 30℃/cm across solid-liquid interface under a furnace temperature of 850-880℃. The crystal was characterized by DTA/TG, X-ray diffraction （XRD）, optical transmission, photoluminescence and X-ray stimulated luminescence measurement. The Bridgman process was confirmed to be promising for growing transparent LaBr3：Ce^3＋ crystal with high optical quality.
基金supported by the National Natural Science Foundation of China (50672111)Shanghai Science and Technology Committee (08520513100)
文摘We reported the development of a Ф100 cm growth apparatus for skull melting growth of yttria-stabilized cubic zirconia(YSZ) crystals and more than 1000 kg crystals have been grown in the furnace each time.The growth conditions were optimized and the structure of the as-grown crystals was characterized by X-ray diffraction.The transmittance of 15 mol.% yttria-stabilized cubic zirconia crystal was nearly 80% in the range of 400–1600 nm.The refractive indices were measured and fitted the Sellmeier equation whi...
基金Projects(50674040, 50539090) supported by the National Natural Science Foundation of ChinaProject(CX07B_128z) supported by the Cultivate Creative Postgraduate Foundation of Jiangsu Province, China
文摘A new meso-mechanical testing scheme based on SEM was developed to carry out the experiment of microfracturing process of rocks. The microfracturing process of the pre-crack marble sample on surrounding rock in the immerged Long-big tunnel in Jinping Cascade II Hydropower Station under uniaxial compression was recorded by using the testing scheme. According to the stereology theory, the propagation and coalescent of cracks at meso-scale were quantitatively investigated with digital technology. Therefore, the basic geometric information of rock microcracks such as area, angle, length, width, perimeter, was obtained from binary images after segmentation. The failure mechanism of specimen under uniaxial compression with the quantitative information was studied from macro and microscopic point of view. The results show that the image of microfracturing process of the specimen can be observed and recorded digitally. During the damage of the specimen, the distribution of microcracks in the specimen is still subjected to exponential distribution with some microcracks concentrated in certain regions. Finally, the change law of the fractal dimension of the local element in marble sample under different external load conditions is obtained by means of the statistical calculation of the fractal dimension.
基金financial support by Chinese Society for Metals and Vanadium International Technical CommitteeTalent foundation over Century of Ministry of Education of ChinaChina Postdoctoral Science Foundation
文摘The effect of vanadium on the DIFT (Deformation Induced Ferrite Transformation) microstructure coarsening in low carbon steel during the continuous cooling processes and isothermal processes at different temperatures were investigated using thermo-simulator.The results showed that the steel containing a small amount of vanadium had the similar velocity of grain growth with the vanadium free steel during the continuous cooling process,but a lower velocity of grain growth than that of vanadium free steel during isothermal processes at high temperatures.On the other hand,the vanadium remarkably inhibited grain growth in the steel containing a high amount of vanadium during both the continuous cooling and isothermal processes.Vanadium dissolved in matrix is indicated as an important factor on restraining grain growth through estimating the driving force of normal grain growth and the resistance of precipitation particles of vanadium on grain growth.The influencing mechanism of vanadium dissolved in matrix on the grain growth during the controlled cooling process is discussed.
文摘China’s foreign trade from January to August According to Customs figures,China’s total import and export in August reached 2.04 trillion yuan,down 9.7%year on year(the same below).Export was 1.2 trillion yuan,down 6.1%,and import 0.84 trillion yuan,down 14.3%.Trade surplus was 368 billion yuan,an increase of 20.1%.In terms of the U.S.dollar,the total import and export in August reached US$333.5 billion,
文摘In this work, TiO2 nanorods with uniform diameter of about 100 nm and a length of several micrometers were successfully prepared by the sol-gel template method. Also the influence of molar ratios of precursor on the morphology and structure of TiO2 nanorods has been investigated. The prepared samples were characterized by Fourier transform infrared spectroscopy （FTIR）, X-ray diffraction （XRD） and scanning electron microscopy （SEM）. The XRD results indicated that the TiO2 nanorods were crystallized in the anatase and rutile phases, after annealing to 400-700℃ up to 2 h.
基金supported by Sustentation Program of National Ministries and Commissions of China (Grant No. 51319030302 and Grant No. 9140A19030506KG0166)
文摘New armament systems are subjected to the method for dealing with multi-stage system reliability-growth statistical problems of diverse population in order to improve reliability before starting mass production. Aiming at the test process which is high expense and small sample-size in the development of complex system, the specific methods are studied on how to process the statistical information of Bayesian reliability growth regarding diverse populations. Firstly, according to the characteristics of reliability growth during product development, the Bayesian method is used to integrate the testing information of multi-stage and the order relations of distribution parameters. And then a Gamma-Beta prior distribution is proposed based on non-homogeneous Poisson process（NHPP） corresponding to the reliability growth process. The posterior distribution of reliability parameters is obtained regarding different stages of product, and the reliability parameters are evaluated based on the posterior distribution. Finally, Bayesian approach proposed in this paper for multi-stage reliability growth test is applied to the test process which is small sample-size in the astronautics filed. The results of a numerical example show that the presented model can make use of the diverse information synthetically, and pave the way for the application of the Bayesian model for multi-stage reliability growth test evaluation with small sample-size. The method is useful for evaluating multi-stage system reliability and making reliability growth plan rationally.
基金sponsored by major tendering projects of National Social Sciences Foundation "Study on Accelerating Economic Adjustment and Coordinated Development"(Grant No.12&ZD084) and "Study on Contribution of Consumption to Economic Growth under Shifting Demand Structure"(Grant No.15ZDC011)projects of National Social Sciences Foundation "Study on China's Structural Growth Deceleration,Transition Risks and Efficiency Improvement Path"(Grant No.14AJL006) and "Study on the Scale,Spatial Clustering and Management Model of Chinese Cities"(Grant No.15ZDC011)
文摘The transition from middle-income to high-income stage is fraught with risks of growth divergence. Economic transition is clouded by the following possibilities： （1）falling share of industrial seetor through industrial depression and weakening growth momentum caused by the large urbanization costs; （2） the subordination of service sector as a result of nearly irreversibly industrial professional, which falters the process of service sector transition and upgrading,＂ （3） inefficient knowledge production allocation and human capital upgrade due to the absence of incentivized compensation of knowledge consumption. We suggest that a country should reshape its efficiency model by upgrading knowledge factor and human capital as the pre-requisite. Given the dilemmas of transition, China should take the faetorization trend of service sector and reshape efficiency model through institutional reform, ensuring that service sector will develop in tandem with industrial sector.
基金supported by the National Basic Research Program of China(Nos.2010CB428403 and 2010CB951001)the National Natural Science Foundation of China(No.91125016)
文摘The regional climate model RegCM3 incorporating the crop model CERES,called the RegCM3CERES model,was used to study the efects of crop growth and development on regional climate and hydrological processes over seven river basins in China.A 20-year numerical simulation showed that incorporating the crop growth and development processes improved the simulation of precipitation over the Haihe River Basin,Songhuajiang River Basin and Pearl River Basin.When compared with the RegCM3 control run,RegCM3CERES reduced the negative biases of monthly mean temperature over most of the seven basins in summer,especially the Haihe River Basin and Huaihe River Basin.The simulated maximum monthly evapotranspiration for summer(JJA)was around 100 mm in the basins of the Yangtze,Haihe,Huaihe and Pearl Rivers.The seasonal and annual variations of water balance components(runof,evapotranspiration and total precipitation)over all seven basins indicate that changes of evapotranspiration agree well with total precipitation.Compared to the RegCM3,RegCM3CERES simulations indicate reduced local water recycling rate over most of the seven basins due to lower evapotranspiration and greater water flux into these basins and an increased precipitation in the Heihe River Basin and Yellow River Basin,but reduced precipitation in the other five basins.Furthermore,a lower summer leaf area index(1.20 m2m 2),greater root soil moisture(0.01 m3m 3),lower latent heat flux(1.34 W m 2),and greater sensible heat flux(2.04 W m 2)are simulated for the Yangtze River Basin.
基金financially supported by the Special Research Program for Public-welfare Forestry(No.201204301-2)National Nonprofit Institute Research Grant of RITF(No.RITFKYYW2010-05)
文摘We studied the formation of heartwood in Ery- throphleumfordii Oliv., an endangered rosewood species, by cross-section analysis on 52 stumps aged 28-57 years and arbitrarily sampled from natural forests in South China. Width and area of heartwood were positively correlated with age and xylem width （XW）, and were independent of annual radial growth. The proportions of heartwood and sapwood areas were equal at about 40 years. The heartwood formation pro- cess was simulated by linear regression of age and XW.
基金partly supported by the National Natural Science Foundation of China(Grant No.91955204)Science and Technology Cooperation Project of the CNPC-SWPU Innovation Alliance(Grant No.2020CX010300)。
文摘Fault attributes generally display a consistent power–law-scaling relationship.Based on new 3 D seismic data,however,we found some exceptional fault attribute relationships of lengths(L)–throw(T)(vertical component of displacement),overlap zone length(Lo)–width(Wo)from a strike-slip fault system of the Ordovician carbonates in the Tarim Basin.The L–T relationship shows two linear segments with breakup at^40 km in fault length.This presents an exceptional throw increase in the second stage,which is attributed to a localization of vertical displacement and deformation in overlapping zones other than the different fault scales in a mature fault zone.The Lo–Wo relationship in the overlapping zones shows multiply stepped-shape patterns,suggesting multiple fault differential growth and periodic increase in fault size.Therefore,we propose a new alternative growth model of fault attributes in strike-slip fault zones,in which the overlapping zones accumulated localized displacement and deformation in the intracratonic strike-slip fault zone.
