A general strategy forβ-selective silylcarbonylation of styrenes with CO_(2) via electrochemical reduction has been reported.A series of styrenes have been simultaneously introduced with silyl and carboxyl groups,and...A general strategy forβ-selective silylcarbonylation of styrenes with CO_(2) via electrochemical reduction has been reported.A series of styrenes have been simultaneously introduced with silyl and carboxyl groups,and these groups have been further converted to high-value functional groups.Detailed mechanistic experiments have proven that the single-electron reduction of CO_(2) is the key to this unique regioselectivity.展开更多
基金supported by the National Key R&D Program of China(2023YFA1507203)the National Natural Science Foundation of China(22371149,22301144,and 22188101)+3 种基金the Natural Science Foundation of Tianjin(24JCJQJC00210)the Fundamental Research Funds for the Central Universities(63223015)Frontiers Science Center for New Organic Matter,Nankai University(63181206)Nankai University are gratefully acknowledged.
文摘A general strategy forβ-selective silylcarbonylation of styrenes with CO_(2) via electrochemical reduction has been reported.A series of styrenes have been simultaneously introduced with silyl and carboxyl groups,and these groups have been further converted to high-value functional groups.Detailed mechanistic experiments have proven that the single-electron reduction of CO_(2) is the key to this unique regioselectivity.
