In this paper,we introduce the set of maximal subgroups with non-trivial core and their corresponding second maximal subgroups.A correlation characterization of the group class J_(pr)is presented by establishing the r...In this paper,we introduce the set of maximal subgroups with non-trivial core and their corresponding second maximal subgroups.A correlation characterization of the group class J_(pr)is presented by establishing the relationship between the core and the second maximal subgroups in these classifications.展开更多
During the initial impoundment period of a canyon-shaped reservoir,the water body fluctuated violently regarding water level,hydrological condition,and thermal stratification.These variations may alter the structure o...During the initial impoundment period of a canyon-shaped reservoir,the water body fluctuated violently regarding water level,hydrological condition,and thermal stratification.These variations may alter the structure of phytoplankton community,resulting in algal blooms and seriously threatening the ecological security of the reservoir.It is of great significance to understand the continuous changes of phytoplankton in the initial impoundment period for the protection of reservoir water quality.Therefore,a two-year in-situ monitoring study was conducted on water quality and phytoplankton in a representative canyonshaped reservoir named Sanhekou and the interannual changes of phytoplankton community and its response to environmental changes during the initial impoundment period were discussed at taxonomic versus functional classification levels.The results showed that the total nitrogen and permanganate index levels were relatively high in the first year due to rapid water storage and heavy rainfall input,and the more stable hydrological conditions in the second year promoted the increase of algae density and the transformation of community,and the proportion of cyanobacteria increased significantly.The succession order of phytoplankton in the first year of the initial impoundment periodwas Chlorophyta-Bacillariophyta-Chlorophyta,or J/F/X1-P/MP/W1-A/X1/MP,respectively.And the succession order in the second year was Cyanobacteria/Chlorophyta-Bacillariophyta-Chlorophyta,or L_(M)/G/P-P/A/X1-X1/J/G.Water temperature,relativewater column stability,mixing depth,and pHwere crucial factors affecting phytoplankton community succession.This study revealed the interannual succession law and driving factors of phytoplankton in the initial impoundment period and provided an important reference for the operation management and ecological protection of canyon-shaped reservoirs.展开更多
Acceptor-donor-acceptor(A-D-A)type molecules,of which the novel non-fused azacyclic end-group pyrazoli-nones were modified with chlorine substitution on the phenyl ring,were synthesized.The non-fused azacyclic end-gro...Acceptor-donor-acceptor(A-D-A)type molecules,of which the novel non-fused azacyclic end-group pyrazoli-nones were modified with chlorine substitution on the phenyl ring,were synthesized.The non-fused azacyclic end-group py-razolinones have the advantages of simple synthesis steps,low cost and environmental friendliness,compared to the classical end-group dicyanomethyleneindianone.The properties of the synthesized A-D-A type molecules with non-fused azacyclic end groups were characterized by theoretical calculation,UV-vis absorption,cyclic voltammetry,X-ray diffraction and space charge limited current.It is shown that the strong UV-vis absorptions of the synthesized A-D-A type molecules are located in the wavelength range of 500~700 nm,with a moderate band gap of nearly 1.7 eV.At the same time,the influence of end-group chlorination on the properties of A-D-A type molecules was compared and explored.It is proven that this kind of A-D-A type molecule with non-fused azacyclic end groups has the potential to be applied as interfacial modified layer of the active layer in perovskite solar cell devices.展开更多
The photocatalytic hydrogen peroxide(H_(2)O_(2))production by graphitic carbon nitride is a sustainable and environment-benign alternative approach of conventional anthraquinone autoxidation technology,but it is great...The photocatalytic hydrogen peroxide(H_(2)O_(2))production by graphitic carbon nitride is a sustainable and environment-benign alternative approach of conventional anthraquinone autoxidation technology,but it is great challenges to promote two-electron O_(2)reduction and water oxidation.Herein,we present the well-dispersed graphitic carbon nitride quantum dots decorated with cyano groups(Na-CNQD and K-CNQD)by thermal polymerization of melamine in the presence of metal fluoride.The quantum confinement and edge effect have endowed the photocatalysts with rich active sites,wide light absorption range and the inhibited charge recombination.The cyano moieties function as O_(2)reduction centers to accept the photogenerated electrons and facilitate their rapid transfer to O_(2)molecules.This process enables the selective two-electron reduction of O_(2),leading to the production of H_(2)O_(2).Concurrently,the valence band holes on the heptazine moiety oxidize water into H_(2)O_(2).These synergistic effects promote photocatalytic H_(2)O_(2)production from O_(2)and H_(2)O without the need for additional photosensitizers,organic scavengers and co-catalysts.In contrast,pristine carbon nitride nanosheets remain inactive under the same conditions.This study offers new strategies for rational design of carbon-based materials for solar-to-chemical energy conversion.展开更多
As a new electrochemical technology,capacitive deionization(CDI)has been increasingly applied in environmental water treatment and seawater desalination.In this study,functional groups modified porous hollow carbon(HC...As a new electrochemical technology,capacitive deionization(CDI)has been increasingly applied in environmental water treatment and seawater desalination.In this study,functional groups modified porous hollow carbon(HC)were synthesized as CDI electrode material for removing Na^(+)and Cl^(−)in salty water.Results showed that the average diameter of HC was approximately 180 nm,and the infrared spectrum showed that its surface was successfully modified with sulfonic and amino groups,respectively.The sulfonic acid functionalized HC(HC-S)showed better electrochemical and desalting performance than the amino-functionalized HC(HC–N),with a maximum Faradic capacity of 287.4 F/g and an adsorptive capacity of 112.97 mg/g for NaCl.Additionally,92.63%capacity retention after 100 adsorption/desorption cycles demonstrates the excellent stability of HC-S.The main findings prove that HC-S is viable as an electrodematerial for desalination by high-performance CDI applications.展开更多
Introducing functional polar groups into polyolefins can significantly improve the material properties,but there are still challenges in achieving this goal,with the core difficulty being that polar groups are prone t...Introducing functional polar groups into polyolefins can significantly improve the material properties,but there are still challenges in achieving this goal,with the core difficulty being that polar groups are prone to interact with metal active species,affecting the efficiency of the copolymerization.With the rapid advancement in catalyst,a variety of copolymerization strategies are developed aimed at producing more versatile polyolefin materials.Although early transition metal catalysts play an indispensable role in the traditional polyolefin industry,their inherent strong oxophilicity becomes a significant constraint in copolymerization involving polar olefins,limiting their application scope.This review summarizes the progress made in recent years in the efficient copolymerization of non-polar olefins with polar comonomers catalyzed by groups 3 and 4 single-site catalysts.We classify the catalysts into four categories,Sc-,Ti-,Zr-,Hf-,based on the type of metal centers,and provide insights into the influence of catalyst structures and the type of comonomers on the copolymerization behavior.The introduction of polar monomers fundamentally improves the comprehensive performance of the products,greatly broadens the application scope of polyolefin materials,and meets the growing market demand for multifunctional and high-performance materials.展开更多
Because the grinding temperature is high when grinding using conventional disordered grinding wheels,the grinding quality improvement is limited when using single abrasive ordered grinding wheels,and the wheel prepara...Because the grinding temperature is high when grinding using conventional disordered grinding wheels,the grinding quality improvement is limited when using single abrasive ordered grinding wheels,and the wheel preparation process is complex and costly when using microstructured grinding wheels,abrasive groups ordered grinding wheels are widely investigated.However,there is a paucity of systematic analyses and comprehensive reviews focused on abrasive groups ordered grinding wheels.Therefore,this paper defines abrasive groups ordered grinding wheels and classifies them,based on their unique characteristics,into groups such as abrasive blocks ordered grinding wheel,fine grain structured grinding wheel,abrasive clusters ordered grinding wheel,and abrasive fibers ordered grinding wheel.We provide an overview of the latest advances in wheel structures,preparation methods,and abrasive selection for various types of abrasive groups ordered grinding wheels.Furthermore,we conduct a comparative analysis of the existing types,significant advantages,and challenges associated with the four types of abrasive groups ordered grinding wheels.Looking ahead,given the potential of abrasive groups ordered grinding wheels in reducing grinding force and temperature,we recommend further exploration of their application in combination with special processing techniques.This could pave the way for the development of machining processes that are more environmentally friendly,energy-efficient,and precise.展开更多
Along the ancient Tea-Horse Road of thousands of miles between Sichuan and Xizang in Southwest China lies a centuries old courtyard.Commonly called the"Jiang Family Compound"or"Yu Xing Tea Store",t...Along the ancient Tea-Horse Road of thousands of miles between Sichuan and Xizang in Southwest China lies a centuries old courtyard.Commonly called the"Jiang Family Compound"or"Yu Xing Tea Store",this architecture situated in the old downtown area of Yingjing County in Ya'an City,Sichuan Province,was once the residence of the local tea merchants-the Jiang family.展开更多
Based on deep realization in relationship between human beings and environment,Yi people gradually formed high level ecological wisdom,which not only protects the environment very well where they are living in,but als...Based on deep realization in relationship between human beings and environment,Yi people gradually formed high level ecological wisdom,which not only protects the environment very well where they are living in,but also maintains their survival and development.Importantly,such traditional ecological wisdom will be very helpful for environmental protection and sustainable development of human beings,especially in the background of modern industrial civilization.展开更多
In this paper,the synchronizable system by groups and the generalized synchronizable system are studied for a coupled system of wave equations.Moreover,situations possessing different groupings are also discussed.
Taking the Lower Silurian Longmaxi Formation shale in the Sichuan Basin as an example,this study employs atomic force microscopy-based infrared(AFM-IR)spectroscopy to analyze the submicron-scale molecular functional g...Taking the Lower Silurian Longmaxi Formation shale in the Sichuan Basin as an example,this study employs atomic force microscopy-based infrared(AFM-IR)spectroscopy to analyze the submicron-scale molecular functional groups of different types and occurrences of organic matter.Combined with the quantitative evaluation of pore development via scanning electron microscopy(SEM),the response of organic pore formation and evolution mechanisms to chemical composition and structural evolution of organic matter in overmature marine shale is investigated.The results indicate that the AFM-IR spectra of graptolite periderms and pyrobitumen in shale are dominated by the stretching vibrations of conjugated C=C bonds in aromatic compounds at approximately 1600 cm-1,with weak absorption peaks near 1375,1450 and 1720 cm-1,corresponding to aliphatic chains and carbonyl/carboxyl functional groups.Overall,the AFM-IR structural indices(A and C factors)of organic matter show a strong correlation with visible porosity in shales of equivalent maturity.Lower A and C factor values correlate with enhanced development of organic pores,which is associated with the detachment of more aliphatic chains and oxygen-containing functional groups during thermal evolution.Pyrobitumen-clay mineral composites generally exhibit superior pore development,likely attributable to clay mineral dehydration participating in hydrocarbon generation reactions that promote the removal of more functional groups.Additionally,hydrocarbon generation within organic-clay composites during high-over mature stages may induce volumetric expansion,resulting in microfracturing and hydrocarbon expulsion.The associated higher hydrocarbon expulsion rates promote the formation of larger pores and fracture-shaped pores along the flake-shaped clay minerals.This study highlights that the research of submicron-scale molecular functional groups provides a deeper understanding of organic matter evolution and pores development mechanisms in overmature shales,thereby offering critical theoretical parameters for reservoir evaluation in shale oil and gas exploration.展开更多
ı-quantum groups,arising from quantum symmetric pairs,are coideal subalgebras of quantum groups.ı-quantum groups are a vast generalization of quantum groups,as quantum groups can be viewed asıquantum groups of diagona...ı-quantum groups,arising from quantum symmetric pairs,are coideal subalgebras of quantum groups.ı-quantum groups are a vast generalization of quantum groups,as quantum groups can be viewed asıquantum groups of diagonal type.Recently,the braid group symmetries and Drinfeld new presentations of quantum groups have been generalized to affineı-quantum groups.In this paper,we construct PBW type bases for splitı-quantum groups of type ADE,based on their braid group symmetries and Drinfeld new presentations.This can be viewed as anı-analogue of the PBW-basis for affine quantum groups,and it generalizes the PBW-basis ofı-quantum groups of finite type.展开更多
Let G be a finite group.A subgroup H of G is said to be σ-c-propermutable in G if G has a subgroup B such that G=N_(G)(H)B and for every Hall σ_(i)-subgroup B_(i) of B,there exists an element x∈B such that HB_(i)^(...Let G be a finite group.A subgroup H of G is said to be σ-c-propermutable in G if G has a subgroup B such that G=N_(G)(H)B and for every Hall σ_(i)-subgroup B_(i) of B,there exists an element x∈B such that HB_(i)^(x)=B_(i)^(x) H.In this paper,the influence of σ-c-propermutable subgroups on the structure of finite groups is investigated,and some criteria for a normal subgroup of G to be hypercyclically embedded in G are derived.展开更多
In this work,we compute the Grothendieck groups of finite 2-Calabi-Yau triangulated categories with maximal rigid objects which are not cluster tilting.These finite 2-Calabi-Yau triangulated categories are divided int...In this work,we compute the Grothendieck groups of finite 2-Calabi-Yau triangulated categories with maximal rigid objects which are not cluster tilting.These finite 2-Calabi-Yau triangulated categories are divided into,by the work of Amiot[Bull.Soc.Math.France,2007,135(3):435-474](see also[Adv.Math.,2008,217(6):2443-2484]and[J.Algebra,2016,446:426-449]),three classes:type A,type D and type E.展开更多
Solar-driven CO_(2)conversion and pollutant removal with an S-scheme heterojunction provides promising approach to alleviate energy shortage and environmental crisis,yet the comprehensive regulation of the charge sepa...Solar-driven CO_(2)conversion and pollutant removal with an S-scheme heterojunction provides promising approach to alleviate energy shortage and environmental crisis,yet the comprehensive regulation of the charge separation and the activation sites of reactant molecules remains challenging.Herein,a dual-active groups regulated S-scheme heterojunction for hydroxy-regulated BiOBr modified amino-functionalized g-C_(3)N_(4)(labeled as HBOB/ACN)was designed by spatially separated dual sites with hydroxyl group(OH)and amino group(NH_(2))toward simultaneously photocatalytic CO_(2)reduction and ciprofloxacin(CIP)oxidation.The optimized HBOB/ACN delivers around 2.74-fold CO yield rate and 1.61-times CIP removal rate in comparison to BiOBr/g-C_(3)N_(4)(BOB/CN)without surface groups,which chiefly ascribed the synergistic effect of OH and NH_(2)group.A series of experiments and theoretical calculation unveiled that the OH and NH_(2)group trapped holes and electrons to participate in CIP oxidation and CO_(2)reduction,respectively.Besides,dual-functional coupled reaction system realized the complete utilization of carriers.This work affords deep insights for dual-group modified S-scheme heterojunctions with redox active sites toward dual-functional coupled reaction system for environment purification and solar fuel production.展开更多
Let G be a finite group.A generating set X of G is said to be minimal if no proper subset of X generates G.Let d(G)and m(G)denote the smallest size and the largest size of a minimal generating set of G,respectively.In...Let G be a finite group.A generating set X of G is said to be minimal if no proper subset of X generates G.Let d(G)and m(G)denote the smallest size and the largest size of a minimal generating set of G,respectively.In this paper we present a characterization for finite solvable groups G such that m(G)-d(G)=1 and m(G)≥m(G/N)+m(N)for any non-trivial normal subgroup N of G.展开更多
Na_(3)V_(2)(PO_(4))_(2)O_(2)F (VP) is recognized as a promising cathode material for sodium-ion batteries due to its stable structural framework and high specific capacity.Density functional theory (DFT) and finite el...Na_(3)V_(2)(PO_(4))_(2)O_(2)F (VP) is recognized as a promising cathode material for sodium-ion batteries due to its stable structural framework and high specific capacity.Density functional theory (DFT) and finite element simulations show that incorporating SO_(4)^(2-)into VP decreases its band gap,lowers the migration energy barrier,and ensures a uniform Na+concentration gradient and stress distribution during charge and discharge cycles.Consequently,the average Na+diffusion coefficient of Na_(3)V_(2)(PO_(4))_(1.95)(SO_(4))_(0.05)O_(2)F(VPS-1) is roughly double that of VP,leading to enhanced rate capability (80 C,75.5 mAh g^(-1)) and cycling stability (111.0 mAh g^(-1)capacity after 1000 cycles at 10 C current density) for VPS-1.VPS-1 exhibits outstanding fast-charging capabilities,achieving an 80%state of charge in just 8.1 min.The assembled VPS-1//SbSn/NPC full cell demonstrated stable cycling over 200 cycles at a high 5 C current,maintaining an average coulombic efficiency of 95.35%.展开更多
A simplified analytical approach is proposed for predicting the load-displacement behavior of single piles in unsaturated soils considering the contribution from the nonlinear shear strength and soil stiffness influen...A simplified analytical approach is proposed for predicting the load-displacement behavior of single piles in unsaturated soils considering the contribution from the nonlinear shear strength and soil stiffness influenced by matric suction.This approach includes a Modified Load Transfer Model(MLTM)that can predict the nonlinear relationships between the shear stress and pile-soil relative displacement along the pile shaft,and between the pile base resistance and base settlement.The proposed model is also extended for pile groups to incorporate the interaction effects between individual piles.The analytical approach is validated through a comparative analysis with the measurements from two single pile tests and one pile group test.In addition,a finite element analysis using 3D modeling is carried out to investigate the behavior of pile groups in various unsaturated conditions.This is accomplished with a user-defined subroutine that is written and implemented in ABAQUS to simulate the nonlinear mechanical behavior of unsaturated soils.The predictions derived from the proposed analytical and numerical methods compare well with the measurements of a published experimental study.The proposed methodologies have the potential to be applied in geotechnical engineering practice for the rational design of single piles and pile groups in unsaturated soils.展开更多
It is urgent to develop high-performance polyimide(PI)films that simultaneously exhibit high transparency,exceptional thermal stability,mechanical robustness,and low dielectric to fulfil the requirements of flexible d...It is urgent to develop high-performance polyimide(PI)films that simultaneously exhibit high transparency,exceptional thermal stability,mechanical robustness,and low dielectric to fulfil the requirements of flexible display technologies.Herein,a series of fluorinated polyimide films(FPIs)were fabricated by the condensation of 5,5′-(perfluoropropane-2,2-diyl)bis(isobenzofuran-1,3-dione)(6FDA)and the fluorinated triphenylmethane diamine monomer(EDA,MEDA and DMEDA)with heat-crosslinkable tetrafluorostyrene side groups,which was incorporated by different numbers of methyl groups pendant in the ortho position of amino groups.Subsequently,the FPI films underwent heating to produce crosslinking FPIs(C-FPIs)through the self-crosslinking of double bonds in the tetrafluorostyrene.The transparency,solvent resistance,thermal stability,mechanical robustness and dielectric properties of FPI and C-FPI films can be tuned by the number of methyl groups and crosslinking,which were deeply investigated by virtue of molecular dynamics(MD)simulations and density functional theory(DFT).As a result,all the films exhibited exceptional optically colorless and transparent,with transmittance in the visible region of 450-700 nm exceeding 79.9%,and the cut-off wavelengths(λ_(off))were nearly 350 nm.The thermal decomposition temperatures at 5% weight loss(T_(d5%))for all samples exceeded 504℃.These films exhibited a wide range of tunable tensile strength(46.5-75.1 MPa).Significantly,they showed exceptional dielectric properties with the dielectric constant of 2.3-2.5 at full frequency(10^(7)-20 Hz).This study not only highlights the relationship between the polymer molecular structure and properties,but offer insights for balancing optical transparency,heat resistance and low dielectric constant in PI films.展开更多
This paper explores the phenomenon of fluid resonance occurring within a narrow gap between a vessel and a vertical wharf, taking ships berthing in front of a gravity wharf as the research background. Using the open-s...This paper explores the phenomenon of fluid resonance occurring within a narrow gap between a vessel and a vertical wharf, taking ships berthing in front of a gravity wharf as the research background. Using the open-source software Open FOAM~?, a two-dimensional viscous-flow numerical wave flume was developed to simulate the fluid resonant motions induced by transient focused wave groups with different spectral peak periods and wave amplitudes. The results indicate that for all the incident focused wave amplitudes considered, the amplitudes of the free surface elevation in the gap, horizontal wave force and moment all exhibit a bimodal variation trend with increasing spectral peak period. The peak values of the above amplitude-period curve appear near the resonant period of the first and second harmonic components of the free surface elevation. However, the variation in the vertical wave force versus the spectral peak period presents different patterns. In addition, the first-to fourth-order harmonic components in the wave surface and forces are further examined via the four-phase combination method. The results show that the first-to secondorder harmonic components play a dominant role in the overall amplitude.展开更多
基金Supported by the National Natural Science Foundation of China(Grant Nos.1237101812201236)+1 种基金the Fundamental Research Funds for the Central Universities(Grant No.B240201093/2013)the Natural Science Foundation of the Anhui Higher Education Institutions(Grant No.2022AH051907)。
文摘In this paper,we introduce the set of maximal subgroups with non-trivial core and their corresponding second maximal subgroups.A correlation characterization of the group class J_(pr)is presented by establishing the relationship between the core and the second maximal subgroups in these classifications.
基金supported by the National Key R&D Program of China(No.2022YFC3203602)the Natural Science Foundation of China(No.52370018)+1 种基金Shaanxi Provincial Youth Innovation Team Project(No.22JP040)Shaanxi Provincial Key Scientific and Technological Innovation Team(No.2023-CX-TD-32).
文摘During the initial impoundment period of a canyon-shaped reservoir,the water body fluctuated violently regarding water level,hydrological condition,and thermal stratification.These variations may alter the structure of phytoplankton community,resulting in algal blooms and seriously threatening the ecological security of the reservoir.It is of great significance to understand the continuous changes of phytoplankton in the initial impoundment period for the protection of reservoir water quality.Therefore,a two-year in-situ monitoring study was conducted on water quality and phytoplankton in a representative canyonshaped reservoir named Sanhekou and the interannual changes of phytoplankton community and its response to environmental changes during the initial impoundment period were discussed at taxonomic versus functional classification levels.The results showed that the total nitrogen and permanganate index levels were relatively high in the first year due to rapid water storage and heavy rainfall input,and the more stable hydrological conditions in the second year promoted the increase of algae density and the transformation of community,and the proportion of cyanobacteria increased significantly.The succession order of phytoplankton in the first year of the initial impoundment periodwas Chlorophyta-Bacillariophyta-Chlorophyta,or J/F/X1-P/MP/W1-A/X1/MP,respectively.And the succession order in the second year was Cyanobacteria/Chlorophyta-Bacillariophyta-Chlorophyta,or L_(M)/G/P-P/A/X1-X1/J/G.Water temperature,relativewater column stability,mixing depth,and pHwere crucial factors affecting phytoplankton community succession.This study revealed the interannual succession law and driving factors of phytoplankton in the initial impoundment period and provided an important reference for the operation management and ecological protection of canyon-shaped reservoirs.
文摘Acceptor-donor-acceptor(A-D-A)type molecules,of which the novel non-fused azacyclic end-group pyrazoli-nones were modified with chlorine substitution on the phenyl ring,were synthesized.The non-fused azacyclic end-group py-razolinones have the advantages of simple synthesis steps,low cost and environmental friendliness,compared to the classical end-group dicyanomethyleneindianone.The properties of the synthesized A-D-A type molecules with non-fused azacyclic end groups were characterized by theoretical calculation,UV-vis absorption,cyclic voltammetry,X-ray diffraction and space charge limited current.It is shown that the strong UV-vis absorptions of the synthesized A-D-A type molecules are located in the wavelength range of 500~700 nm,with a moderate band gap of nearly 1.7 eV.At the same time,the influence of end-group chlorination on the properties of A-D-A type molecules was compared and explored.It is proven that this kind of A-D-A type molecule with non-fused azacyclic end groups has the potential to be applied as interfacial modified layer of the active layer in perovskite solar cell devices.
基金supported by the National Natural Science Foundation of China(22361024 and 22471055)Natural Science Foundation of Jiangxi Province(20232ACB203001)+1 种基金Natural Science Foundation of Hebei Province(B2024202021,B2022202039)S&T Program of Hebei(236Z4308G)。
文摘The photocatalytic hydrogen peroxide(H_(2)O_(2))production by graphitic carbon nitride is a sustainable and environment-benign alternative approach of conventional anthraquinone autoxidation technology,but it is great challenges to promote two-electron O_(2)reduction and water oxidation.Herein,we present the well-dispersed graphitic carbon nitride quantum dots decorated with cyano groups(Na-CNQD and K-CNQD)by thermal polymerization of melamine in the presence of metal fluoride.The quantum confinement and edge effect have endowed the photocatalysts with rich active sites,wide light absorption range and the inhibited charge recombination.The cyano moieties function as O_(2)reduction centers to accept the photogenerated electrons and facilitate their rapid transfer to O_(2)molecules.This process enables the selective two-electron reduction of O_(2),leading to the production of H_(2)O_(2).Concurrently,the valence band holes on the heptazine moiety oxidize water into H_(2)O_(2).These synergistic effects promote photocatalytic H_(2)O_(2)production from O_(2)and H_(2)O without the need for additional photosensitizers,organic scavengers and co-catalysts.In contrast,pristine carbon nitride nanosheets remain inactive under the same conditions.This study offers new strategies for rational design of carbon-based materials for solar-to-chemical energy conversion.
基金supported by the National Science Foundation of China(No.21606191)the Natural Science Foundation of Shandong Province(No.ZR2020ME024).
文摘As a new electrochemical technology,capacitive deionization(CDI)has been increasingly applied in environmental water treatment and seawater desalination.In this study,functional groups modified porous hollow carbon(HC)were synthesized as CDI electrode material for removing Na^(+)and Cl^(−)in salty water.Results showed that the average diameter of HC was approximately 180 nm,and the infrared spectrum showed that its surface was successfully modified with sulfonic and amino groups,respectively.The sulfonic acid functionalized HC(HC-S)showed better electrochemical and desalting performance than the amino-functionalized HC(HC–N),with a maximum Faradic capacity of 287.4 F/g and an adsorptive capacity of 112.97 mg/g for NaCl.Additionally,92.63%capacity retention after 100 adsorption/desorption cycles demonstrates the excellent stability of HC-S.The main findings prove that HC-S is viable as an electrodematerial for desalination by high-performance CDI applications.
基金supported by the National Natural Science Foundation of China(No.U23B6011)。
文摘Introducing functional polar groups into polyolefins can significantly improve the material properties,but there are still challenges in achieving this goal,with the core difficulty being that polar groups are prone to interact with metal active species,affecting the efficiency of the copolymerization.With the rapid advancement in catalyst,a variety of copolymerization strategies are developed aimed at producing more versatile polyolefin materials.Although early transition metal catalysts play an indispensable role in the traditional polyolefin industry,their inherent strong oxophilicity becomes a significant constraint in copolymerization involving polar olefins,limiting their application scope.This review summarizes the progress made in recent years in the efficient copolymerization of non-polar olefins with polar comonomers catalyzed by groups 3 and 4 single-site catalysts.We classify the catalysts into four categories,Sc-,Ti-,Zr-,Hf-,based on the type of metal centers,and provide insights into the influence of catalyst structures and the type of comonomers on the copolymerization behavior.The introduction of polar monomers fundamentally improves the comprehensive performance of the products,greatly broadens the application scope of polyolefin materials,and meets the growing market demand for multifunctional and high-performance materials.
基金Supported by National Natural Science Foundation of China(Grant No.52175401)Hunan Provincial Postgraduate Scientific Research Innovation Project(Grant No.QL20230244)+1 种基金Enterprise Innovation and Development Joint Program of National Natural Science Foundation of China(Grant No.U20B2032)Hunan Provincial Science and Technology Innovation Program(Grant No.2022RC1050).
文摘Because the grinding temperature is high when grinding using conventional disordered grinding wheels,the grinding quality improvement is limited when using single abrasive ordered grinding wheels,and the wheel preparation process is complex and costly when using microstructured grinding wheels,abrasive groups ordered grinding wheels are widely investigated.However,there is a paucity of systematic analyses and comprehensive reviews focused on abrasive groups ordered grinding wheels.Therefore,this paper defines abrasive groups ordered grinding wheels and classifies them,based on their unique characteristics,into groups such as abrasive blocks ordered grinding wheel,fine grain structured grinding wheel,abrasive clusters ordered grinding wheel,and abrasive fibers ordered grinding wheel.We provide an overview of the latest advances in wheel structures,preparation methods,and abrasive selection for various types of abrasive groups ordered grinding wheels.Furthermore,we conduct a comparative analysis of the existing types,significant advantages,and challenges associated with the four types of abrasive groups ordered grinding wheels.Looking ahead,given the potential of abrasive groups ordered grinding wheels in reducing grinding force and temperature,we recommend further exploration of their application in combination with special processing techniques.This could pave the way for the development of machining processes that are more environmentally friendly,energy-efficient,and precise.
文摘Along the ancient Tea-Horse Road of thousands of miles between Sichuan and Xizang in Southwest China lies a centuries old courtyard.Commonly called the"Jiang Family Compound"or"Yu Xing Tea Store",this architecture situated in the old downtown area of Yingjing County in Ya'an City,Sichuan Province,was once the residence of the local tea merchants-the Jiang family.
文摘Based on deep realization in relationship between human beings and environment,Yi people gradually formed high level ecological wisdom,which not only protects the environment very well where they are living in,but also maintains their survival and development.Importantly,such traditional ecological wisdom will be very helpful for environmental protection and sustainable development of human beings,especially in the background of modern industrial civilization.
基金Supported by the National Natural Science Foundation of China(12301577)Sichuan Science and Technology Program(2023NSFSC1346).
文摘In this paper,the synchronizable system by groups and the generalized synchronizable system are studied for a coupled system of wave equations.Moreover,situations possessing different groupings are also discussed.
基金Supported by the National Natural Science Foundation of China(42172148,42172142)。
文摘Taking the Lower Silurian Longmaxi Formation shale in the Sichuan Basin as an example,this study employs atomic force microscopy-based infrared(AFM-IR)spectroscopy to analyze the submicron-scale molecular functional groups of different types and occurrences of organic matter.Combined with the quantitative evaluation of pore development via scanning electron microscopy(SEM),the response of organic pore formation and evolution mechanisms to chemical composition and structural evolution of organic matter in overmature marine shale is investigated.The results indicate that the AFM-IR spectra of graptolite periderms and pyrobitumen in shale are dominated by the stretching vibrations of conjugated C=C bonds in aromatic compounds at approximately 1600 cm-1,with weak absorption peaks near 1375,1450 and 1720 cm-1,corresponding to aliphatic chains and carbonyl/carboxyl functional groups.Overall,the AFM-IR structural indices(A and C factors)of organic matter show a strong correlation with visible porosity in shales of equivalent maturity.Lower A and C factor values correlate with enhanced development of organic pores,which is associated with the detachment of more aliphatic chains and oxygen-containing functional groups during thermal evolution.Pyrobitumen-clay mineral composites generally exhibit superior pore development,likely attributable to clay mineral dehydration participating in hydrocarbon generation reactions that promote the removal of more functional groups.Additionally,hydrocarbon generation within organic-clay composites during high-over mature stages may induce volumetric expansion,resulting in microfracturing and hydrocarbon expulsion.The associated higher hydrocarbon expulsion rates promote the formation of larger pores and fracture-shaped pores along the flake-shaped clay minerals.This study highlights that the research of submicron-scale molecular functional groups provides a deeper understanding of organic matter evolution and pores development mechanisms in overmature shales,thereby offering critical theoretical parameters for reservoir evaluation in shale oil and gas exploration.
文摘ı-quantum groups,arising from quantum symmetric pairs,are coideal subalgebras of quantum groups.ı-quantum groups are a vast generalization of quantum groups,as quantum groups can be viewed asıquantum groups of diagonal type.Recently,the braid group symmetries and Drinfeld new presentations of quantum groups have been generalized to affineı-quantum groups.In this paper,we construct PBW type bases for splitı-quantum groups of type ADE,based on their braid group symmetries and Drinfeld new presentations.This can be viewed as anı-analogue of the PBW-basis for affine quantum groups,and it generalizes the PBW-basis ofı-quantum groups of finite type.
文摘Let G be a finite group.A subgroup H of G is said to be σ-c-propermutable in G if G has a subgroup B such that G=N_(G)(H)B and for every Hall σ_(i)-subgroup B_(i) of B,there exists an element x∈B such that HB_(i)^(x)=B_(i)^(x) H.In this paper,the influence of σ-c-propermutable subgroups on the structure of finite groups is investigated,and some criteria for a normal subgroup of G to be hypercyclically embedded in G are derived.
文摘In this work,we compute the Grothendieck groups of finite 2-Calabi-Yau triangulated categories with maximal rigid objects which are not cluster tilting.These finite 2-Calabi-Yau triangulated categories are divided into,by the work of Amiot[Bull.Soc.Math.France,2007,135(3):435-474](see also[Adv.Math.,2008,217(6):2443-2484]and[J.Algebra,2016,446:426-449]),three classes:type A,type D and type E.
文摘Solar-driven CO_(2)conversion and pollutant removal with an S-scheme heterojunction provides promising approach to alleviate energy shortage and environmental crisis,yet the comprehensive regulation of the charge separation and the activation sites of reactant molecules remains challenging.Herein,a dual-active groups regulated S-scheme heterojunction for hydroxy-regulated BiOBr modified amino-functionalized g-C_(3)N_(4)(labeled as HBOB/ACN)was designed by spatially separated dual sites with hydroxyl group(OH)and amino group(NH_(2))toward simultaneously photocatalytic CO_(2)reduction and ciprofloxacin(CIP)oxidation.The optimized HBOB/ACN delivers around 2.74-fold CO yield rate and 1.61-times CIP removal rate in comparison to BiOBr/g-C_(3)N_(4)(BOB/CN)without surface groups,which chiefly ascribed the synergistic effect of OH and NH_(2)group.A series of experiments and theoretical calculation unveiled that the OH and NH_(2)group trapped holes and electrons to participate in CIP oxidation and CO_(2)reduction,respectively.Besides,dual-functional coupled reaction system realized the complete utilization of carriers.This work affords deep insights for dual-group modified S-scheme heterojunctions with redox active sites toward dual-functional coupled reaction system for environment purification and solar fuel production.
基金Supported by China Scholarship Council(Grant No.202208360148)the National Natural Science Foundation of China(Grant Nos.12126415,12261042,12301026)the Natural Science Foundation of Jiangxi Province(Grant No.20232BAB211006).
文摘Let G be a finite group.A generating set X of G is said to be minimal if no proper subset of X generates G.Let d(G)and m(G)denote the smallest size and the largest size of a minimal generating set of G,respectively.In this paper we present a characterization for finite solvable groups G such that m(G)-d(G)=1 and m(G)≥m(G/N)+m(N)for any non-trivial normal subgroup N of G.
基金National Natural Science Foundation of China (52372224 and 52072299)Major Project of Shaanxi Coal Joint Fund of Shaanxi Provincial Science and Technology Department (2019JLZ-07)。
文摘Na_(3)V_(2)(PO_(4))_(2)O_(2)F (VP) is recognized as a promising cathode material for sodium-ion batteries due to its stable structural framework and high specific capacity.Density functional theory (DFT) and finite element simulations show that incorporating SO_(4)^(2-)into VP decreases its band gap,lowers the migration energy barrier,and ensures a uniform Na+concentration gradient and stress distribution during charge and discharge cycles.Consequently,the average Na+diffusion coefficient of Na_(3)V_(2)(PO_(4))_(1.95)(SO_(4))_(0.05)O_(2)F(VPS-1) is roughly double that of VP,leading to enhanced rate capability (80 C,75.5 mAh g^(-1)) and cycling stability (111.0 mAh g^(-1)capacity after 1000 cycles at 10 C current density) for VPS-1.VPS-1 exhibits outstanding fast-charging capabilities,achieving an 80%state of charge in just 8.1 min.The assembled VPS-1//SbSn/NPC full cell demonstrated stable cycling over 200 cycles at a high 5 C current,maintaining an average coulombic efficiency of 95.35%.
基金financially supported by NSERC,CanadaDiscovery Grant 2020(Grant No.5808).
文摘A simplified analytical approach is proposed for predicting the load-displacement behavior of single piles in unsaturated soils considering the contribution from the nonlinear shear strength and soil stiffness influenced by matric suction.This approach includes a Modified Load Transfer Model(MLTM)that can predict the nonlinear relationships between the shear stress and pile-soil relative displacement along the pile shaft,and between the pile base resistance and base settlement.The proposed model is also extended for pile groups to incorporate the interaction effects between individual piles.The analytical approach is validated through a comparative analysis with the measurements from two single pile tests and one pile group test.In addition,a finite element analysis using 3D modeling is carried out to investigate the behavior of pile groups in various unsaturated conditions.This is accomplished with a user-defined subroutine that is written and implemented in ABAQUS to simulate the nonlinear mechanical behavior of unsaturated soils.The predictions derived from the proposed analytical and numerical methods compare well with the measurements of a published experimental study.The proposed methodologies have the potential to be applied in geotechnical engineering practice for the rational design of single piles and pile groups in unsaturated soils.
基金financially supported by the Natural Science Foundation of Shandong Province(Nos.ZR2021ME055,ZR2022QB170 and ZR2022MB034)the Foundation(No.GZKF202128)of State Key Laboratory of Biobased Material and Green Papermaking,Qilu University of Technology,Shandong Academy of Sciencesthe Development Program Project of Young Innovation Team of Institutions of Higher Learning in Shandong Province.
文摘It is urgent to develop high-performance polyimide(PI)films that simultaneously exhibit high transparency,exceptional thermal stability,mechanical robustness,and low dielectric to fulfil the requirements of flexible display technologies.Herein,a series of fluorinated polyimide films(FPIs)were fabricated by the condensation of 5,5′-(perfluoropropane-2,2-diyl)bis(isobenzofuran-1,3-dione)(6FDA)and the fluorinated triphenylmethane diamine monomer(EDA,MEDA and DMEDA)with heat-crosslinkable tetrafluorostyrene side groups,which was incorporated by different numbers of methyl groups pendant in the ortho position of amino groups.Subsequently,the FPI films underwent heating to produce crosslinking FPIs(C-FPIs)through the self-crosslinking of double bonds in the tetrafluorostyrene.The transparency,solvent resistance,thermal stability,mechanical robustness and dielectric properties of FPI and C-FPI films can be tuned by the number of methyl groups and crosslinking,which were deeply investigated by virtue of molecular dynamics(MD)simulations and density functional theory(DFT).As a result,all the films exhibited exceptional optically colorless and transparent,with transmittance in the visible region of 450-700 nm exceeding 79.9%,and the cut-off wavelengths(λ_(off))were nearly 350 nm.The thermal decomposition temperatures at 5% weight loss(T_(d5%))for all samples exceeded 504℃.These films exhibited a wide range of tunable tensile strength(46.5-75.1 MPa).Significantly,they showed exceptional dielectric properties with the dielectric constant of 2.3-2.5 at full frequency(10^(7)-20 Hz).This study not only highlights the relationship between the polymer molecular structure and properties,but offer insights for balancing optical transparency,heat resistance and low dielectric constant in PI films.
基金financially supported by the National Natural Science Foundation of China (Grant No. 52371277)the State Key Laboratory of Hydraulic Engineering Intelligent Construction and Operation (Tianjin University)(Grant No. HESS-2323)+2 种基金the Postgraduate Research&Practice Innovation Program of Jiangsu Province (Grant No. KYCX24_4071)the Guangdong Basic and Applied Basic Research Foundation (Grant No. 2023A1515010890)the Open foundation of Key Laboratory of Port.Waterway&Sedimentation Engineering (Grant No. Yk224001-1)。
文摘This paper explores the phenomenon of fluid resonance occurring within a narrow gap between a vessel and a vertical wharf, taking ships berthing in front of a gravity wharf as the research background. Using the open-source software Open FOAM~?, a two-dimensional viscous-flow numerical wave flume was developed to simulate the fluid resonant motions induced by transient focused wave groups with different spectral peak periods and wave amplitudes. The results indicate that for all the incident focused wave amplitudes considered, the amplitudes of the free surface elevation in the gap, horizontal wave force and moment all exhibit a bimodal variation trend with increasing spectral peak period. The peak values of the above amplitude-period curve appear near the resonant period of the first and second harmonic components of the free surface elevation. However, the variation in the vertical wave force versus the spectral peak period presents different patterns. In addition, the first-to fourth-order harmonic components in the wave surface and forces are further examined via the four-phase combination method. The results show that the first-to secondorder harmonic components play a dominant role in the overall amplitude.
