In the paper, an estimating method for critical properties in group-contribution method is presented.For eliminating the influence of adjacent group and distinguishing isomers, the new method including first-level gro...In the paper, an estimating method for critical properties in group-contribution method is presented.For eliminating the influence of adjacent group and distinguishing isomers, the new method including first-level group-contribution method and second-level group-contribution method is proposed. The new method demonstrates significant improvement in accuracy.展开更多
The vaporization ratios of the slurry at various temperature and partial pressure were calculated with the group-contribution method,and then the phase state of the slurry in the residue fluid catalytic cracking(RFCC)...The vaporization ratios of the slurry at various temperature and partial pressure were calculated with the group-contribution method,and then the phase state of the slurry in the residue fluid catalytic cracking(RFCC) disengager was determined.This research could provide some advices on how to select the technological conditions to decrease the coking in the RFCC disengager.The oil gas temperature and the slurry partial pressure had signifi- cant effects on the vaporization ratio of the slurry.Increasing the oil gas temperature and reducing the slurry partial pressure could effectively slow down the coking speed in the RFCC disengager.According to the calculation results, a correlation was established to predict the vaporization ratio of the slurry under different operating conditions.展开更多
基金Supported by Tianjin Natural Scientific Foundation(No.973602911).
文摘In the paper, an estimating method for critical properties in group-contribution method is presented.For eliminating the influence of adjacent group and distinguishing isomers, the new method including first-level group-contribution method and second-level group-contribution method is proposed. The new method demonstrates significant improvement in accuracy.
基金Supported by the National-Natural Science Foundation of China （No.20406013） and Program for New Century Excellent Talents in University （No.NCET-04-0107）.
文摘The vaporization ratios of the slurry at various temperature and partial pressure were calculated with the group-contribution method,and then the phase state of the slurry in the residue fluid catalytic cracking(RFCC) disengager was determined.This research could provide some advices on how to select the technological conditions to decrease the coking in the RFCC disengager.The oil gas temperature and the slurry partial pressure had signifi- cant effects on the vaporization ratio of the slurry.Increasing the oil gas temperature and reducing the slurry partial pressure could effectively slow down the coking speed in the RFCC disengager.According to the calculation results, a correlation was established to predict the vaporization ratio of the slurry under different operating conditions.
