In order to apply grinding method for degradation of pentachlorophenol(PCP) to an industrial scale,the proportion of different materials[CaO,SiO_2 and CO(NH_2)_2]and the size of grinding balls were examined.For saving...In order to apply grinding method for degradation of pentachlorophenol(PCP) to an industrial scale,the proportion of different materials[CaO,SiO_2 and CO(NH_2)_2]and the size of grinding balls were examined.For saving energy and increasing dechlorination efficiency,the rotation speed and grinding time were maintained at relatively low values.At a mass ratio of grinding balls to materials(40:1),PCP was added into a big steel jar(300 ml) with other materials to grind at 300 r ·min^(-1)for 5 h.The results indicated that when PCP was mixed with CaO and SiO_2in a molar ratio of 1:60:60,the best dechlorination of 58.4%was achieved.CO(NH_2)_2 could not be used as hydrogen donor in the dehalogenation by mechanochemical reaction,since it restrained the dechlorination process.The size of grinding balls has significant effect on the reaction.The experiment with 5 mm steel balls indicates that the weight is too light to provide appropriate energy for the reaction,while steel balls of 10 and 15 mm could give better dechlorination reaction.It indicates that dechlorination depends on the mass of balls and fill rate.展开更多
The present work discusses a systematic approach to model grinding parameters of coal in a ball mill. A three level Box-Behnken design combined with response surface methodology using second order model was applied to...The present work discusses a systematic approach to model grinding parameters of coal in a ball mill. A three level Box-Behnken design combined with response surface methodology using second order model was applied to the experiments done according to the model requirement. Three parameters ball charge （numbers 10-20）, coal content （100-200 g） and the grinding time （4-8 rain） were chosen for the experiments as well as for the modeling work. Coal fineness is defined as the dso （80 % passing size）. A quadratic model was developed to show the effect of parameters and their interaction with fineness of the product. Three different sizes （4, 1 and 0.65 mm） of Indian coal were used. The model equations for each fraction were developed and different sets of experiments were performed. The predicted values of the fineness of coal were in good agreement with the experimental results （R2 values of dso varies between 0.97 and 0.99）. Fine size of three different coal sizes were obtained with larger ball charge with less grinding time and less solid content. This work represents the efficient use of response surface methodology and the Box-Behnken design use for grinding of Indian coal.展开更多
Gold ore processing is often ineffective in obtaining gold metal. Various methods have been successfully developed on an industrial scale, but small-scale gold mines are often problematic. The problem of inefficiency ...Gold ore processing is often ineffective in obtaining gold metal. Various methods have been successfully developed on an industrial scale, but small-scale gold mines are often problematic. The problem of inefficiency of processing is caused by gold ore characterization and evaluation of gold ore preparation process is not implemented. In this study, the conditions of gold ore deposits have a thin thickness （vein）. These gold ore deposits have an economic value if they are developed by traditional gold mining. The objective of the research is to identify and characterize gold ore as well as to analyze the optimum condition to obtain the perfect gold mineral liberation degree. Research methods include characterization of gold ore geology, sampling for test preparation using rod mill （amalgamation）, gold mineral liberation using time variables and number of rods. After the grinding process, grain size analysis is performed with various mesh sizes, and the analysis of each fraction uses a polarization microscope. The results show that gold ore minerals are associated with pyrite, chalcopyrite, galena and gangue minerals. Gold minerals are fully liberated at a certain size. The results of this research are very useful for the gold ore grinding process to obtain an efficient gold processing.展开更多
文摘In order to apply grinding method for degradation of pentachlorophenol(PCP) to an industrial scale,the proportion of different materials[CaO,SiO_2 and CO(NH_2)_2]and the size of grinding balls were examined.For saving energy and increasing dechlorination efficiency,the rotation speed and grinding time were maintained at relatively low values.At a mass ratio of grinding balls to materials(40:1),PCP was added into a big steel jar(300 ml) with other materials to grind at 300 r ·min^(-1)for 5 h.The results indicated that when PCP was mixed with CaO and SiO_2in a molar ratio of 1:60:60,the best dechlorination of 58.4%was achieved.CO(NH_2)_2 could not be used as hydrogen donor in the dehalogenation by mechanochemical reaction,since it restrained the dechlorination process.The size of grinding balls has significant effect on the reaction.The experiment with 5 mm steel balls indicates that the weight is too light to provide appropriate energy for the reaction,while steel balls of 10 and 15 mm could give better dechlorination reaction.It indicates that dechlorination depends on the mass of balls and fill rate.
文摘The present work discusses a systematic approach to model grinding parameters of coal in a ball mill. A three level Box-Behnken design combined with response surface methodology using second order model was applied to the experiments done according to the model requirement. Three parameters ball charge （numbers 10-20）, coal content （100-200 g） and the grinding time （4-8 rain） were chosen for the experiments as well as for the modeling work. Coal fineness is defined as the dso （80 % passing size）. A quadratic model was developed to show the effect of parameters and their interaction with fineness of the product. Three different sizes （4, 1 and 0.65 mm） of Indian coal were used. The model equations for each fraction were developed and different sets of experiments were performed. The predicted values of the fineness of coal were in good agreement with the experimental results （R2 values of dso varies between 0.97 and 0.99）. Fine size of three different coal sizes were obtained with larger ball charge with less grinding time and less solid content. This work represents the efficient use of response surface methodology and the Box-Behnken design use for grinding of Indian coal.
文摘Gold ore processing is often ineffective in obtaining gold metal. Various methods have been successfully developed on an industrial scale, but small-scale gold mines are often problematic. The problem of inefficiency of processing is caused by gold ore characterization and evaluation of gold ore preparation process is not implemented. In this study, the conditions of gold ore deposits have a thin thickness （vein）. These gold ore deposits have an economic value if they are developed by traditional gold mining. The objective of the research is to identify and characterize gold ore as well as to analyze the optimum condition to obtain the perfect gold mineral liberation degree. Research methods include characterization of gold ore geology, sampling for test preparation using rod mill （amalgamation）, gold mineral liberation using time variables and number of rods. After the grinding process, grain size analysis is performed with various mesh sizes, and the analysis of each fraction uses a polarization microscope. The results show that gold ore minerals are associated with pyrite, chalcopyrite, galena and gangue minerals. Gold minerals are fully liberated at a certain size. The results of this research are very useful for the gold ore grinding process to obtain an efficient gold processing.
