The simulation of the coordination geometry and environment of the active metal center in metalloenzymes is highly valuable for activating O_(2)to oxidize inexpensive bulk chemicals into high-value-added fine chemical...The simulation of the coordination geometry and environment of the active metal center in metalloenzymes is highly valuable for activating O_(2)to oxidize inexpensive bulk chemicals into high-value-added fine chemicals.In this study,we have selected the inorganic ligand phosphovanadomolybdate(PMoV)and the auxiliary ligand N-butylimidazole(bIM),which possess a long flexible alkyl chain,to jointly stabilize two types of triangular bipyramidal cobalt-based enzymatic complexes(PMoV-Co).展开更多
基金financially supported by the National Natural Science Foundation of China(22171122 and 22201123)the Liaoning Revitalization Talents Program(XLYC2007130)the Talent Scientific Research Fund of Liaoning Petrochemical University(2016XJJL–019).
文摘The simulation of the coordination geometry and environment of the active metal center in metalloenzymes is highly valuable for activating O_(2)to oxidize inexpensive bulk chemicals into high-value-added fine chemicals.In this study,we have selected the inorganic ligand phosphovanadomolybdate(PMoV)and the auxiliary ligand N-butylimidazole(bIM),which possess a long flexible alkyl chain,to jointly stabilize two types of triangular bipyramidal cobalt-based enzymatic complexes(PMoV-Co).
