Hemipelagic to pelagic(H/P)marls,representing pelitic deposits,accumulated within the foredeep sub-basin of the Dinaric Foreland Basin(northern Neotethyan margin,present-day Croatia)during the Middle to Late Eocene.Sy...Hemipelagic to pelagic(H/P)marls,representing pelitic deposits,accumulated within the foredeep sub-basin of the Dinaric Foreland Basin(northern Neotethyan margin,present-day Croatia)during the Middle to Late Eocene.Syn-sedimentary tectonic movements,paleogeographic position and exchanges of short-lived hyperthermal episodes affected the sedimentation and related mineral and geochemical record of these deposits.Mineral(clay)assemblages bear signature of prevailing physical weathering with significant illite and chlorite content,but climatic seasonality is suggested by smectite-interlayered phases and sporadical increase of kaolinite content.Illite crystallinity varies significantly,and the lowest crystallinity is recorded by the Lutetian samples.Illite chemistry index is always bellow 0.5,being characteristic for Fe-Mg-rich illite.The geochemical records are the most prominent(CIA up to 76,CIW up to 91)for the Istrian Lutetian(42.3-40.5 Ma),but also for Priabonian(35.8-34.3 Ma)samples of Hvar Island.The ICV values(the lowest 1.40 and the highest 10.85)of all studied samples fall above PAAS(ICV=0.85)and point to their chemical immaturity.The Ga/Rb ratios are lower than 0.2 and K_(2)O/Al_(2)O_(3) ratios are also low(0.16-0.22),implying transition between cold and dry,and warm and humid climate,obviously trending among several warming episodes.展开更多
Research on changes in the redox conditions of bottom waters is essential for understanding deep water circulation,global ocean currents,climate change,and ecosystem health.Through sedimentary geological methods,a dee...Research on changes in the redox conditions of bottom waters is essential for understanding deep water circulation,global ocean currents,climate change,and ecosystem health.Through sedimentary geological methods,a deeper understanding of the complex relationships between various environmental changes can be achieved,providing detailed evidence and theoretical support for global climate change research.The Ross Sea in Antarctica plays a key role in the formation of Antarctic bottom water(AABW),and the complex climate changes since the last glacial maximum(LGM)make it particularly significant for study.This research analyzes core ANT32-RB16C from the Ross Sea using geochemical proxies such as major and trace elements,grain size,and redox-sensitive indicators like Mn/Ti,Co/Ti,Mo/Ti,Cd/Ti,U/Th,and Ni/Co molar concentration ratios.Combining this data with a previously established chronological framework,the study explores the evolution of redox conditions in the Ross Sea’s deep waters since the LGM.The results show that the deep waters have remained oxygen-rich since the LGM,with significant changes in four stages.Stage 1(24.7–15.7 cal ka BP):Strong oxidizing conditions,likely due to enhanced formation of Ross Sea bottom water(RSBW),increasing oxygen levels.Stage 2(15.7–4.5 cal ka BP):Weakened oxidizing conditions as temperatures rose and ice shelves retreated,increasing primary productivity and depleting oxygen.Stage 3(4.5–1.5 cal ka BP):Continued decline in oxidizing conditions,possibly linked to high primary productivity and oxygen consumption.Stage 4(1.5 cal ka BP to present):A rapid recovery of oxidizing conditions,likely driven by temperature drops,increased RSBW formation,and decreased productivity.展开更多
This paper examines the relationship among organic geochemical proxies （TOC, C/N ratio and ~13C） and pollen assemblages in Zhuye Lake sediments since the Late Glacial. Results show that the reaction extent of organi...This paper examines the relationship among organic geochemical proxies （TOC, C/N ratio and ~13C） and pollen assemblages in Zhuye Lake sediments since the Late Glacial. Results show that the reaction extent of organic geochemical proxies and pollen as- semblages to environment changes are different. Organic geochemical proxies are sensitive to overall environmental change, while pollen assemblages indicate detailed information of environmental change. For the entire sedimentary section （except the sand layer fi＇om the bottom of the section）, when values of TOC, C/N ratio and total pollen concentrations are high, 813C values are low, and vice versa. The different responses of organic geochemical proxies and pollen records in Zhuye Lake are mainly due to their different sensitivity and diverse influencing factors in different environmental conditions.展开更多
Sedimentary TOC （total organic carbon）, TN （total nitrogen） and C/N （carbon/nitrogen） at selected sites of Lake Victoria basin have provided evidence of phytoplankton productivity, input of nitrates and allochth...Sedimentary TOC （total organic carbon）, TN （total nitrogen） and C/N （carbon/nitrogen） at selected sites of Lake Victoria basin have provided evidence of phytoplankton productivity, input of nitrates and allochthonous （land） plant materials/catchment destruction in the basin during the late Holocene period （last 4,000 years to present）. TOC and TN in the sediment cores were determined using EuroEA3000 Series Elemental Analyser and radiocarbon dating done using AMS （accelerator mass spectrometry） standard method. Results showed that TOC （13.45%-20.78%） and TN （1.07%-1.92%） values were higher at Napoleon Gulf from about 4,186 years before present （ca. 4,186 yr. BP） to present than at inlet of river Kagera （TOC： 3.27%-6.32% and TN： 0.30%-0.59%） from about 190 years before present （ca. 190 yr. BP） to present. Generally TOC and TN had a negative correlation （r = -0.37, p = 0.04, n = 32） at Napoleon Gulf in the last 4,186 years to present signifying that C/N ratios were governed mostly by phytoplankton productivity which markedly increased during some periods in the last 370 years to present possibly as a result of increased input of nitrates. However, the periods from about 4,186 years to 1,684 years before present （ca. 4,186 yr. BP to 1,684 yr. BP） and some periods between the last 370 years to present indicated increased input of allochthonous plant materials/catchment destruction. On overall, there was a positive correlation between C/N and TOC at inlet of river Kagera （r = 0.57, p = 0.01, n = 20） in the last 190 years to present possibly signifying that C/N ratios were governed mainly by input of allochthonous plant materials hence increased catchment destruction. Input of land plant materials （catchment destruction） along Kagera basin declined during some period after 1950 AD. However the most recent years have shown increased input of land plant materials （catchment destruction） in Kagera basin.展开更多
The Cenomanian-Turonian boundary oceanic anoxic event(OAE-2;Bonarelli event;~94 Ma)is associated with a species turnover in the marine calcareous microfossil record,widespread marine anoxia,black shale deposition and ...The Cenomanian-Turonian boundary oceanic anoxic event(OAE-2;Bonarelli event;~94 Ma)is associated with a species turnover in the marine calcareous microfossil record,widespread marine anoxia,black shale deposition and positiveδ13C excursions.This study reviews 141 CTBE sites globally,aiming to understand micropaleontological,geochemical,and sedimentological expressions of OAE-2.There is a clear palaeogeographic and palaeobathymetric heterogeneity in the development of OAE-2 marine anoxia.A majority of the documented OAE-2 sites are from deep marine environments.The calcareous nannoplankton and benthic foraminifera record a diversity decline,while planktic foraminifera shows community level shifts and no major mass extinction.The variability of total organic carbon in OAE-2 sediments across sites(<1 to>10 wt.%)and theδ13C profiles(diachronous)have been attributed to different mechanisms of anoxia development.The increased primary“productivity model”gains support from productivity proxies(e.g.,Ba,P,Cu,Ni),redox-sensitive elements(e.g.,Mn,Mo,U,V,As),and eutrophic genera(e.g.,benthic foraminifera Gabonita spp.,calcareous nannofossils Biscutum spp.and Zeugrhabdotus erectus).The enhanced organic carbon“preservation model”in stratified(semi)restricted basins gains support from sites with lower enrichment of redox-sensitive elements and oligotrophic flora and fauna in the OAE-2 records.Geochronology of the Caribbean and the High Atlantic Large Igneous Province events(CLIP and HALIP)mark them as likely triggers of the OAE-2 related global perturbation of marine biogeochemistry.Volcanic triggers may have caused climate warming,altered hydrological cycles,enhanced continental weathering,shifts in ocean circulation,and nutrient flows.Addressing knowledge gaps,further research is urged,utilizing innovative proxies,and exploring underrepresented depositional systems to comprehensively understand OAE-2 onset and biotic crisis.展开更多
The change of the primary productivity across the Permian-Triassic boundary （PTB） remains controversial. In this study, records from two deep-water sections in South China （Xiakou and Xinmin sections） show the pri...The change of the primary productivity across the Permian-Triassic boundary （PTB） remains controversial. In this study, records from two deep-water sections in South China （Xiakou and Xinmin sections） show the primary productivity decreased gradually from the latest Permian to the earliest Triassic, and five evolutionary stages Increase-Decrease-Recovery-Recession- Stagnation） can be observed from Clarkina changxingensis-C, deflecta to Hindeodus parvus-lsarcicella isarcica zones. Pri- mary productivity decreased abruptly from the base of C. meishanensis zone. Besides, for adjusting to the deterioration of the oceanic environment, the primary producers in the oceanic surface had changed to acritarch and cyanobacteria, which were more tolerant of stressful environment. Then the producers were under huge stagnation in the H. parvus-L isarcica zone. The values of quantitative calculation of the primary productivity from the black rock series in the Dalong Formation were very high, corresponding to that of an upwelling area in modern ocean, which shows that the strata of the Dalong Formation in the study region are potential hydrocarbon source-rocks. This result may come from the fact that South China craton was located at the equatorial upwelling area during the Permian-Triassic transitions. But organic matter contents were different in various sections because they could be affected by redox conditions and diagenesis process after burial.展开更多
基金supported by Croatian Science Foundation Research Project Dinaridic Foreland Basin between Two Eocene Thermal Optima:A Possible Scenario for the Northern Adriatic BREEMECO(No.2019-04-5775)。
文摘Hemipelagic to pelagic(H/P)marls,representing pelitic deposits,accumulated within the foredeep sub-basin of the Dinaric Foreland Basin(northern Neotethyan margin,present-day Croatia)during the Middle to Late Eocene.Syn-sedimentary tectonic movements,paleogeographic position and exchanges of short-lived hyperthermal episodes affected the sedimentation and related mineral and geochemical record of these deposits.Mineral(clay)assemblages bear signature of prevailing physical weathering with significant illite and chlorite content,but climatic seasonality is suggested by smectite-interlayered phases and sporadical increase of kaolinite content.Illite crystallinity varies significantly,and the lowest crystallinity is recorded by the Lutetian samples.Illite chemistry index is always bellow 0.5,being characteristic for Fe-Mg-rich illite.The geochemical records are the most prominent(CIA up to 76,CIW up to 91)for the Istrian Lutetian(42.3-40.5 Ma),but also for Priabonian(35.8-34.3 Ma)samples of Hvar Island.The ICV values(the lowest 1.40 and the highest 10.85)of all studied samples fall above PAAS(ICV=0.85)and point to their chemical immaturity.The Ga/Rb ratios are lower than 0.2 and K_(2)O/Al_(2)O_(3) ratios are also low(0.16-0.22),implying transition between cold and dry,and warm and humid climate,obviously trending among several warming episodes.
基金The National Key R&D Program of China under contract No. 2023YFC28 11305the Scientific Research Fund of the Second Institute of Oceanography,MNR under contract No. SZ2405the Impact and Response of Antarctic Seas to Climate Change under contract No. IRASCC
文摘Research on changes in the redox conditions of bottom waters is essential for understanding deep water circulation,global ocean currents,climate change,and ecosystem health.Through sedimentary geological methods,a deeper understanding of the complex relationships between various environmental changes can be achieved,providing detailed evidence and theoretical support for global climate change research.The Ross Sea in Antarctica plays a key role in the formation of Antarctic bottom water(AABW),and the complex climate changes since the last glacial maximum(LGM)make it particularly significant for study.This research analyzes core ANT32-RB16C from the Ross Sea using geochemical proxies such as major and trace elements,grain size,and redox-sensitive indicators like Mn/Ti,Co/Ti,Mo/Ti,Cd/Ti,U/Th,and Ni/Co molar concentration ratios.Combining this data with a previously established chronological framework,the study explores the evolution of redox conditions in the Ross Sea’s deep waters since the LGM.The results show that the deep waters have remained oxygen-rich since the LGM,with significant changes in four stages.Stage 1(24.7–15.7 cal ka BP):Strong oxidizing conditions,likely due to enhanced formation of Ross Sea bottom water(RSBW),increasing oxygen levels.Stage 2(15.7–4.5 cal ka BP):Weakened oxidizing conditions as temperatures rose and ice shelves retreated,increasing primary productivity and depleting oxygen.Stage 3(4.5–1.5 cal ka BP):Continued decline in oxidizing conditions,possibly linked to high primary productivity and oxygen consumption.Stage 4(1.5 cal ka BP to present):A rapid recovery of oxidizing conditions,likely driven by temperature drops,increased RSBW formation,and decreased productivity.
基金supported by the National Natural Science Foundation of China(Grant Nos.41371009 and 41001116)the Fundamental Research Fund for the Central Universities(Grant Nos.lzujbky-2013-127 and lzujbky-2013-129)
文摘This paper examines the relationship among organic geochemical proxies （TOC, C/N ratio and ~13C） and pollen assemblages in Zhuye Lake sediments since the Late Glacial. Results show that the reaction extent of organic geochemical proxies and pollen as- semblages to environment changes are different. Organic geochemical proxies are sensitive to overall environmental change, while pollen assemblages indicate detailed information of environmental change. For the entire sedimentary section （except the sand layer fi＇om the bottom of the section）, when values of TOC, C/N ratio and total pollen concentrations are high, 813C values are low, and vice versa. The different responses of organic geochemical proxies and pollen records in Zhuye Lake are mainly due to their different sensitivity and diverse influencing factors in different environmental conditions.
文摘Sedimentary TOC （total organic carbon）, TN （total nitrogen） and C/N （carbon/nitrogen） at selected sites of Lake Victoria basin have provided evidence of phytoplankton productivity, input of nitrates and allochthonous （land） plant materials/catchment destruction in the basin during the late Holocene period （last 4,000 years to present）. TOC and TN in the sediment cores were determined using EuroEA3000 Series Elemental Analyser and radiocarbon dating done using AMS （accelerator mass spectrometry） standard method. Results showed that TOC （13.45%-20.78%） and TN （1.07%-1.92%） values were higher at Napoleon Gulf from about 4,186 years before present （ca. 4,186 yr. BP） to present than at inlet of river Kagera （TOC： 3.27%-6.32% and TN： 0.30%-0.59%） from about 190 years before present （ca. 190 yr. BP） to present. Generally TOC and TN had a negative correlation （r = -0.37, p = 0.04, n = 32） at Napoleon Gulf in the last 4,186 years to present signifying that C/N ratios were governed mostly by phytoplankton productivity which markedly increased during some periods in the last 370 years to present possibly as a result of increased input of nitrates. However, the periods from about 4,186 years to 1,684 years before present （ca. 4,186 yr. BP to 1,684 yr. BP） and some periods between the last 370 years to present indicated increased input of allochthonous plant materials/catchment destruction. On overall, there was a positive correlation between C/N and TOC at inlet of river Kagera （r = 0.57, p = 0.01, n = 20） in the last 190 years to present possibly signifying that C/N ratios were governed mainly by input of allochthonous plant materials hence increased catchment destruction. Input of land plant materials （catchment destruction） along Kagera basin declined during some period after 1950 AD. However the most recent years have shown increased input of land plant materials （catchment destruction） in Kagera basin.
基金supported by The Department of Science and Technology (DST,India)SERB Grant CRG/2018/002202。
文摘The Cenomanian-Turonian boundary oceanic anoxic event(OAE-2;Bonarelli event;~94 Ma)is associated with a species turnover in the marine calcareous microfossil record,widespread marine anoxia,black shale deposition and positiveδ13C excursions.This study reviews 141 CTBE sites globally,aiming to understand micropaleontological,geochemical,and sedimentological expressions of OAE-2.There is a clear palaeogeographic and palaeobathymetric heterogeneity in the development of OAE-2 marine anoxia.A majority of the documented OAE-2 sites are from deep marine environments.The calcareous nannoplankton and benthic foraminifera record a diversity decline,while planktic foraminifera shows community level shifts and no major mass extinction.The variability of total organic carbon in OAE-2 sediments across sites(<1 to>10 wt.%)and theδ13C profiles(diachronous)have been attributed to different mechanisms of anoxia development.The increased primary“productivity model”gains support from productivity proxies(e.g.,Ba,P,Cu,Ni),redox-sensitive elements(e.g.,Mn,Mo,U,V,As),and eutrophic genera(e.g.,benthic foraminifera Gabonita spp.,calcareous nannofossils Biscutum spp.and Zeugrhabdotus erectus).The enhanced organic carbon“preservation model”in stratified(semi)restricted basins gains support from sites with lower enrichment of redox-sensitive elements and oligotrophic flora and fauna in the OAE-2 records.Geochronology of the Caribbean and the High Atlantic Large Igneous Province events(CLIP and HALIP)mark them as likely triggers of the OAE-2 related global perturbation of marine biogeochemistry.Volcanic triggers may have caused climate warming,altered hydrological cycles,enhanced continental weathering,shifts in ocean circulation,and nutrient flows.Addressing knowledge gaps,further research is urged,utilizing innovative proxies,and exploring underrepresented depositional systems to comprehensively understand OAE-2 onset and biotic crisis.
基金was supported by National Natural Science Foundation of China (Grant Nos. 41073007 and 41273005)National Basic Research Program of China (Grant No. 2011CB808800)+3 种基金the 111 Project (Grant No. B08030)Research Fund for the Doctoral Program of Higher Education (Grant No. 20110145130001)special funding from the State Key Laboratory of Geological Processes and Mineral Resourcesa contribution to IGCP Project 572 (Grant No. GPMR201301)
文摘The change of the primary productivity across the Permian-Triassic boundary （PTB） remains controversial. In this study, records from two deep-water sections in South China （Xiakou and Xinmin sections） show the primary productivity decreased gradually from the latest Permian to the earliest Triassic, and five evolutionary stages Increase-Decrease-Recovery-Recession- Stagnation） can be observed from Clarkina changxingensis-C, deflecta to Hindeodus parvus-lsarcicella isarcica zones. Pri- mary productivity decreased abruptly from the base of C. meishanensis zone. Besides, for adjusting to the deterioration of the oceanic environment, the primary producers in the oceanic surface had changed to acritarch and cyanobacteria, which were more tolerant of stressful environment. Then the producers were under huge stagnation in the H. parvus-L isarcica zone. The values of quantitative calculation of the primary productivity from the black rock series in the Dalong Formation were very high, corresponding to that of an upwelling area in modern ocean, which shows that the strata of the Dalong Formation in the study region are potential hydrocarbon source-rocks. This result may come from the fact that South China craton was located at the equatorial upwelling area during the Permian-Triassic transitions. But organic matter contents were different in various sections because they could be affected by redox conditions and diagenesis process after burial.
