CO_(2)reduction reaction(CO_(2)RR)electrolyzers based on gas diffusion electrode(GDE)enable the direct mass transfer of CO_(2)to the catalyst surface for participation in the reaction,thereby establishing an efficient...CO_(2)reduction reaction(CO_(2)RR)electrolyzers based on gas diffusion electrode(GDE)enable the direct mass transfer of CO_(2)to the catalyst surface for participation in the reaction,thereby establishing an efficient three-phase reaction interface that significantly enhances current density.However,current hydrophobic modification methods face difficulties in achieving precise and substantial control over wettability,and the hydrophobic modifiers tend to significantly impair the conductivity of the electrode and ion transport capabilities.This study employs Nafion ionomers to hydrophobically modify the threedimensional catalyst layer,revealing the bifunctionality of Nafion.The fluorinated backbone of Nafion ensures the hydrophobicity of the entire catalyst layer,while its sulfonic acid groups promote ion transport,without significantly affecting the conductivity of the electrode.Furthermore,by employing modifiers with distinct wettability characteristics,a highly efficient and large-scale manipulation of the hydrophilic/hydrophobic properties of the catalyst layer was successfully realized.The electrode,constructed with silver nanopowder as a representative catalyst and modified with the hydrophobic ionomer Nafion,exhibits a substantial enhancement in both catalytic activity and durability.The optimized electrode exhibited exceptional electrocatalytic performance in both flow cell and membrane electrode assembly(MEA)configurations.Notably,in the MEA,the electrode achieved a remarkable CO Faradaic efficiency(FE)of 93.3%at a total current density of 200 mA cm^(-2),while maintaining stable operation for over 62 h.展开更多
实际变压器局部放电定位过程中放电源数目是未知的,常利用传统高分辨波达方向(direction of arrival,DOA)估计算法解决放电定位问题,但在信源数欠估计、过估计情况下存在定位精度低、误差大的问题。为此,本文提出了一种基于改进盖氏圆(g...实际变压器局部放电定位过程中放电源数目是未知的,常利用传统高分辨波达方向(direction of arrival,DOA)估计算法解决放电定位问题,但在信源数欠估计、过估计情况下存在定位精度低、误差大的问题。为此,本文提出了一种基于改进盖氏圆(geschgorin disk estimator,GDE)准则联合多重信号分类(multiple signal classification,MUSIC)算法的变压器局部放电多目标定位方法。首先,利用改进盖氏圆准则确定真实放电源数目;然后,在信源数确定的情况下利用MUSIC算法对多个局部放电源的波达方向进行估计。仿真结果表明,本方法定位精度高,且在白噪声和空间色噪声的情况下仍能对放电源的俯仰角和方位角进行准确估计,能够满足实际工程需求。展开更多
The development of active yet stable catalysts for oxygen reduction reaction(ORR)is still a major issue for the extensive permeation of fuel cells into everyday technology.While nanostructured Pt catalysts are to date...The development of active yet stable catalysts for oxygen reduction reaction(ORR)is still a major issue for the extensive permeation of fuel cells into everyday technology.While nanostructured Pt catalysts are to date the best available systems in terms of activity,the same is not true for stability,particularly under operating conditions.In this work,Pt_(Х)Y alloy nanoparticles are proposed as active and durable electrocatalysts for ORR.Pt_(Х)Y nanoalloys are synthesized and further optimized by laser ablation in liquid followed by laser fragmentation in liquid.The novel integrated laser-assisted methodology succeeded in producing Pt_(Х)Y nanoparticles with the ideal size(<10 nm)of commercial Pt catalysts,yet resulting remarkably more active with E_(1/2)=0.943 V vs.RHE,specific activity=1095μA cm^(-2) and mass activity>1000 A g^(-1).At the same time,the nanoalloys are embedded in a fine Pt oxide matrix,which allows a greater stability of the catalyst than the commercial Pt reference,as directly verified on a gas diffusion electrode.展开更多
Groundwater-Dependent Ecosystems(GDEs)in the arid region of northwest China are crucial for maintaining ecological balance and biodiversity.However,the ongoing decline in groundwater levels caused by excessive groundw...Groundwater-Dependent Ecosystems(GDEs)in the arid region of northwest China are crucial for maintaining ecological balance and biodiversity.However,the ongoing decline in groundwater levels caused by excessive groundwater exploitation poses a potential threat to GDEs.This paper reviews the current developments and future challenges associated with defining groundwater level thresholds for maintaining GDEs in arid regions.It focuses on methods for identifying and investigating these thresholds,with particular attention to recent advances in northwest China.Additionally,this paper highlights the limitations and future challenges in determining these thresholds,including the complexities of ecological processes,groundwater systems,data availability,and methodological constraints.To address these issues,a multidisciplinary approach that incorporates new technologies,such as multi-source data fusion,machine learning models,and big data and cloud computing,will be essential.By overcoming these challenges and utilizing effective methods,appropriate groundwater level thresholds can be established to ensure the longterm sustainability of GDEs.展开更多
基金National Key R&D Program of China(2023YFA1507902,2021YFA1500804)the National Natural Science Foundation of China(22121004,22038009,22250008)+2 种基金the Haihe Laboratory of Sustainable Chemical Transformations(CYZC202107)the Program of Introducing Talents of Discipline to Universities,China(No.BP0618007)the Xplorer Prize,China,for their financial support。
文摘CO_(2)reduction reaction(CO_(2)RR)electrolyzers based on gas diffusion electrode(GDE)enable the direct mass transfer of CO_(2)to the catalyst surface for participation in the reaction,thereby establishing an efficient three-phase reaction interface that significantly enhances current density.However,current hydrophobic modification methods face difficulties in achieving precise and substantial control over wettability,and the hydrophobic modifiers tend to significantly impair the conductivity of the electrode and ion transport capabilities.This study employs Nafion ionomers to hydrophobically modify the threedimensional catalyst layer,revealing the bifunctionality of Nafion.The fluorinated backbone of Nafion ensures the hydrophobicity of the entire catalyst layer,while its sulfonic acid groups promote ion transport,without significantly affecting the conductivity of the electrode.Furthermore,by employing modifiers with distinct wettability characteristics,a highly efficient and large-scale manipulation of the hydrophilic/hydrophobic properties of the catalyst layer was successfully realized.The electrode,constructed with silver nanopowder as a representative catalyst and modified with the hydrophobic ionomer Nafion,exhibits a substantial enhancement in both catalytic activity and durability.The optimized electrode exhibited exceptional electrocatalytic performance in both flow cell and membrane electrode assembly(MEA)configurations.Notably,in the MEA,the electrode achieved a remarkable CO Faradaic efficiency(FE)of 93.3%at a total current density of 200 mA cm^(-2),while maintaining stable operation for over 62 h.
文摘实际变压器局部放电定位过程中放电源数目是未知的,常利用传统高分辨波达方向(direction of arrival,DOA)估计算法解决放电定位问题,但在信源数欠估计、过估计情况下存在定位精度低、误差大的问题。为此,本文提出了一种基于改进盖氏圆(geschgorin disk estimator,GDE)准则联合多重信号分类(multiple signal classification,MUSIC)算法的变压器局部放电多目标定位方法。首先,利用改进盖氏圆准则确定真实放电源数目;然后,在信源数确定的情况下利用MUSIC算法对多个局部放电源的波达方向进行估计。仿真结果表明,本方法定位精度高,且在白噪声和空间色噪声的情况下仍能对放电源的俯仰角和方位角进行准确估计,能够满足实际工程需求。
基金the P-DISC Grant PROMETEO(project number:P-DiSC#03NExuS_BIRD2021-UNIPD)DYNAMO(project number:P-P-DiSC#01BIRD2020-UNIPD)the financial support of the Fellowship in Applied Electrochemistry 2020。
文摘The development of active yet stable catalysts for oxygen reduction reaction(ORR)is still a major issue for the extensive permeation of fuel cells into everyday technology.While nanostructured Pt catalysts are to date the best available systems in terms of activity,the same is not true for stability,particularly under operating conditions.In this work,Pt_(Х)Y alloy nanoparticles are proposed as active and durable electrocatalysts for ORR.Pt_(Х)Y nanoalloys are synthesized and further optimized by laser ablation in liquid followed by laser fragmentation in liquid.The novel integrated laser-assisted methodology succeeded in producing Pt_(Х)Y nanoparticles with the ideal size(<10 nm)of commercial Pt catalysts,yet resulting remarkably more active with E_(1/2)=0.943 V vs.RHE,specific activity=1095μA cm^(-2) and mass activity>1000 A g^(-1).At the same time,the nanoalloys are embedded in a fine Pt oxide matrix,which allows a greater stability of the catalyst than the commercial Pt reference,as directly verified on a gas diffusion electrode.
基金financially supported by the China Geological Survey Project(No.DD20230472).
文摘Groundwater-Dependent Ecosystems(GDEs)in the arid region of northwest China are crucial for maintaining ecological balance and biodiversity.However,the ongoing decline in groundwater levels caused by excessive groundwater exploitation poses a potential threat to GDEs.This paper reviews the current developments and future challenges associated with defining groundwater level thresholds for maintaining GDEs in arid regions.It focuses on methods for identifying and investigating these thresholds,with particular attention to recent advances in northwest China.Additionally,this paper highlights the limitations and future challenges in determining these thresholds,including the complexities of ecological processes,groundwater systems,data availability,and methodological constraints.To address these issues,a multidisciplinary approach that incorporates new technologies,such as multi-source data fusion,machine learning models,and big data and cloud computing,will be essential.By overcoming these challenges and utilizing effective methods,appropriate groundwater level thresholds can be established to ensure the longterm sustainability of GDEs.
