Gas-liquid flow(GLF),especially slug and annular flows in oil and gas gathering and transportation pipelines,become particularly complex inside elbows and can easily exacerbate pipeline corrosion and damage.In thisstu...Gas-liquid flow(GLF),especially slug and annular flows in oil and gas gathering and transportation pipelines,become particularly complex inside elbows and can easily exacerbate pipeline corrosion and damage.In thisstudy,FLUENT was used to conduct 3D simulations of slug and annular flow in elbows for different velocitiesto assess the ensuing changes in terms of pressure.In particular,the multifluid VOF(Volume of Fraction)modelwas chosen.The results indicate that under both slug and annular flow conditions,the pressure inside the elbow islower than the outside.As the superficial velocity of liquid and gas increase,the pressure and liquid flow velocityat different positions of the elbow also increase,while the secondary flow weakens.Under annular flow conditions,the liquid film on the outer side of the elbow is thicker than that on the inner side,and the liquid velocityin the main liquid film zone is the lowest.展开更多
Gas–liquid two-phase jets exhibit markedly enhanced impact performance due to the violent collapse of entrained bubbles,which generates transient microjets and shock waves.The geometry of the nozzle is a decisive fac...Gas–liquid two-phase jets exhibit markedly enhanced impact performance due to the violent collapse of entrained bubbles,which generates transient microjets and shock waves.The geometry of the nozzle is a decisive factor in controlling jet formation,flow modulation,and impact efficiency.In this work,the structural optimization of gas–liquid two-phase nozzles was investigated numerically using the Volume of Fluid(VOF).Simulation results show that the aero-shaped nozzle delivers a significantly stronger impact on the target surface than conventional geometries.Specifically,its impact pressure is 21%higher than that of a conical straight nozzle and 37%higher than that of a conical nozzle.The aero nozzle not only increases peak impact pressure but also sustains it over a longer duration,leading to an overall improvement in energy transfer efficiency.Parametric analyses further reveal the key geometric conditions governing performance.When the nozzle curvature is set to 0.01,the jet achieves a higher and more stable surface pressure profile,maintaining elevated impact for a prolonged period.At an aspect ratio of 15,the jet exhibits pronounced pulsation under high pressure,thereby enhancing impact intensity.The contraction ratio exerts a non-monotonic influence:as it increases,impact pressure initially rises and subsequently declines,with an optimal value of 4 yielding the highest and most persistent impact pressure.Likewise,when the ratio of inlet length to outlet diameter is 2.5,the jet demonstrates the strongest impact on the target surface.展开更多
Sulfide precipitation is an effective method for treating acidic heavy metal wastewater.However,the process often generates tiny particles with poor settling performance.The factors and mechanisms influencing particle...Sulfide precipitation is an effective method for treating acidic heavy metal wastewater.However,the process often generates tiny particles with poor settling performance.The factors and mechanisms influencing particle size and settling performance remain unclear.In this study,the growth behavior of CuS particles generated by two sulfide precipitation methods,gas-liquid and liquid-liquid sulfidation,was investigated.The effects of acidity,sulfur-to-copper molar ratio,and temperature on particle size were analyzed.The results showed that increasing the temperature had an adverse effect on CuS particle growth.Additionally,we found that acidity and sulfur-to-copper molar ratio had a more significant impact on particle growth in the liquid-liquid sulfidation system than in the gas-liquid sulfidation system.Based on supersaturation calculations and XPS analysis,it is found that particle growth in gas-liquid sulfidation systems is mainly influenced by supersaturation,while particle growth in liquid-liquid sulfidation systems is mainly affected by surface charge.This study provides valuable insights into the factors that influence particle growth in sulfide precipitation and can inform the development of strategies to improve the effective precipitation of sulfide nanoparticles in acidic wastewater.展开更多
The structural and operational optimization of gas-liquid stirred bioreactors presents both complexity and critical importance for enhancing mass transfer performance. This study proposes a machine learning (ML)-drive...The structural and operational optimization of gas-liquid stirred bioreactors presents both complexity and critical importance for enhancing mass transfer performance. This study proposes a machine learning (ML)-driven approach to identify key features and predict the volumetric mass transfer coefficient (kLa). Four ML models were adopted and compared for kLa prediction in Newtonian and non-Newtonian fluids by evaluative indices, with CatBoost and XGBoost emerging as the optimal models, respectively. Specifically, it is demonstrated that Catboost has higher prediction accuracy (AARD = 18.84%) than empirical equations by effectively incorporating multidimensional features (structural, impeller, and operational), while simultaneously extending applicability to diverse Newtonian fluids. For non-Newtonian fluids, XGBoost outperforms empirical equations by effectively incorporating fluid rheological parameters (consistency coefficient, power-law index), thereby better capturing shear-thinning behavior. Feature importance analysis further identified rotational speed (for Newtonian fluids) and liquid height (for non-Newtonian fluids) as the key features, while 2D partial dependence analysis establishes quantitative optimization ranges. This ML approach provides an efficient predictive tool for gas-liquid stirred bioreactor design and optimization.展开更多
The Casimir pressure plays an important role in the adhesion stability of nanofilms at submicro scales.In this work,the Casimir pressure of peptide films deposited on a layered substrate is investigated.Three types of...The Casimir pressure plays an important role in the adhesion stability of nanofilms at submicro scales.In this work,the Casimir pressure of peptide films deposited on a layered substrate is investigated.Three types of semi-infinite substrates,i.e.,silica,silicon and gold,are considered.The buffer layer between the peptide film and substrate consists of silicon or silica.The switching sign of the Casimir pressure can be controlled in a region ranging from about 130 nm to 1000 nm,depending on the thickness of the buffer layer and the substrate.The results suggest that the critical thickness of peptide films for Casimir equilibrium increases(or decreases)by increasing the thickness of the silicon(or silica)buffer film.The influences of wetting and electrolyte screening on the Casimir pressure are also investigated.Our finding provides a theoretical guide for the adhesion stability of peptide films in organic electronics.展开更多
Stochastic optical reconstruction microscopy(STORM),as a typical technique of single-molecule localization microscopy(SMLM),has overcome the diffraction limit by randomly switching fluorophores between fluorescent and...Stochastic optical reconstruction microscopy(STORM),as a typical technique of single-molecule localization microscopy(SMLM),has overcome the diffraction limit by randomly switching fluorophores between fluorescent and dark states,allowing for the precise localization of isolated emission patterns and the super-resolution reconstruction from millions of localized positions of single fluorophores.A critical factor influencing localization precision is the photo-switching behavior of fluorophores,which is affected by the imaging buffer.The imaging buffer typically comprises oxygen scavengers,photo-switching reagents,and refractive index regulators.Oxygen scavengers help prevent photobleaching,photo-switching reagents assist in facilitating the conversion of fluorophores,and refractive index regulators are used to adjust the refractive index of the solution.The synergistic interaction of these components promotes stable blinking of fluorophores,reduces irreversible photobleaching,and thereby ensures high-quality super-resolution imaging.This review provides a comprehensive overview of the essential compositions and functionalities of imaging buffers used in STORM,serving as a valuable resource for researchers seeking to select appropriate imaging buffers for their experiments.展开更多
Metal-organic framework materials exhibit considerable potential as molecularly selective surfaceenhanced Raman spectroscopy(SERS)substrates because of their microporous structures,which enrich small molecules while e...Metal-organic framework materials exhibit considerable potential as molecularly selective surfaceenhanced Raman spectroscopy(SERS)substrates because of their microporous structures,which enrich small molecules while excluding larger ones.In this study,we develop a template-assisted chemical-etching strategy to prepare layered tuneable SERS substrates based on hierarchical porous zeolitic imidazolate framework-67(HP-ZIF-67)with a rhombic dodecahedral structure.The synergistic SERS enhancement mechanisms of HP-ZIF-67,which combine electromagnetic(EM)and chemical(CM)effects,were systematically studied through numerical simulations and experiments.Calculations revealed that under 633-nm laser excitation,the contributions of the EM and CM effects to the total SERS enhancement factor of HP-ZIF-67 were 60%and 40%,respectively.The hierarchical porous structure enhanced the fluid-flow flux over the microporous ZIF-67 because the increased pore radius reduced the viscous resistance and facilitated rapid molecular transport through the interconnected macro-meso-channels.Precise modulation of the CM and EM effects,combined with enhanced mass transfer,facilitated the development of HP-ZIF-67and HP-ZIF-67@Au as efficient SERS sensors.An investigation of the relationship between pore-size distribution and EM effects revealed the pivotal role of light confinement by whispering-gallery-mode microcavities in enhancing the SERS performance.The optimised HPZIF-67@Au composites functioned as flexible and highly sensitive in situ SERS sensors for gases and liquids,including volatile organic-compound gas and liquid-pesticide residues.This study introduces a novel design concept and provides a robust theoretical foundation for the future development of exhaled-breath point-of-care diagnostic devices and sweat-based wearable biomedical sensors.展开更多
Man-made superheavy elements(SHE)are produced as energetic recoils in complete-fusion reactions and need to be thermalized in a gas-filled chamber for chemical studies.The ever-shorter half-lives and decreasing produc...Man-made superheavy elements(SHE)are produced as energetic recoils in complete-fusion reactions and need to be thermalized in a gas-filled chamber for chemical studies.The ever-shorter half-lives and decreasing production rates of the elements beyond Fl(atomic number Z=114)-the heaviest element chemically studied today-require the development of novel techniques for quantitative thermalization and fast extraction efficiency.The Universal high-density gas stopping Cell(UniCell),currently under construction,was proposed to achieve this.Within this work,we propose an Ion Transfer by Gas Flow(ITGF)device,which serves as a UniCell ejector to interface with a gas chromatography detector array for chemical studies.Detailed parameter optimizations,using gas dynamics and Monte Carlo ion-trajectory simulations,promise fast(within a few ms)and highly efficient(up to 100%)ion extraction across a wide mass range.These ions can then be transmitted quantitatively through the ITGF into the high-pressure environment needed for further chemical studies.展开更多
The squeezing deformation of surrounding rock is an important factor restricting the safe construction and long-term operation of tunnels when a tunnel passes through soft strata with high ground stress.Under such sof...The squeezing deformation of surrounding rock is an important factor restricting the safe construction and long-term operation of tunnels when a tunnel passes through soft strata with high ground stress.Under such soft rock geological conditions,the large deformation of the surrounding rock can easily lead to the failure of supporting structures,including shotcrete cracks,spalling,and steel arch distortion.To improve the lining support performance during the large deformation of squeezed surrounding rock,this work selects aluminum foam with densities of 0.25 g/cm3,0.42 g/cm3 and 0.61 g/cm3 as the buffer layer material and carries out uniaxial confined compression tests.Through the evaluation and analysis of energy absorption and the comparison of the yield pressure of aluminum foam with those of other cushioning materials and yield pressure support systems,the strength,deformation and energy absorption of aluminum foam with a density of 0.25 g/cm3 meet the yield pressure performance requirements.The numerical model of the buffer layer yielding support system is then established via the finite element analysis software ABAQUS,and the influence of the buffer layer setting on the lining support is analyzed.Compared with the conventional support scheme,the addition of an aluminum foam buffer layer can reduce the stress and deformation of the primary support and secondary lining.The maximum and minimum principal stresses of the primary support are reduced by 13%and 15%,respectively.The maximum and minimum principal stresses of the secondary lining are reduced by 15%and 12%,respectively,and the displacement deformation of the secondary lining position is reduced by 15%.In summary,the application of aluminum foam buffer layer can reduce the stress and deformation of the primary support and secondary lining,improve the stress safety of the support and reduce the deformation of the support.展开更多
The gas-liquid countercurrent flow pattern is complex and the bubble migration velocity is difficult to predict in the process of bullheading well killing.The experiment on bubble migration in gas-liquid countercurren...The gas-liquid countercurrent flow pattern is complex and the bubble migration velocity is difficult to predict in the process of bullheading well killing.The experiment on bubble migration in gas-liquid countercurrent flow in annulus is carried out under different working conditions to reveal how the wellbore inclination angle,liquid phase property and countercurrent liquid velocity affect the bubble deformation and bubble migration trajectory/velocity,and to establish a bubble migration velocity prediction model.The bubbles in the countercurrent flow mainly migrate in two modes:free rising of isolated bubbles,and interactive rising of multiple bubbles.The bubbles migrate by an S-shaped trajectory in the countercurrent flow.With the increase of countercurrent liquid velocity,the lateral oscillation of bubbles is intensified.The increases of wellbore inclination angle,liquid density and liquid viscosity make the bubble migration trajectory gradually to be linear.The bubble is generally ellipsoidal during its rising.The wellbore inclination angle has little effect on the degree of bubble deformation.The bubbles are ellipsoidal during rising,with little influence of wellbore inclination angle on bubble deformation.With the increase of liquid viscosity and density,the aspect ratio of the bubble decreases.As the wellbore inclination angle increases,the bubble migration velocity gradually decreases.As the liquid viscosity increases,the bubble migration velocity decreases.As the liquid density increases,the bubble migration velocity increases slightly.The established bubble migration velocity prediction model yields errors within±15%,and demonstrates broad applicability across a wide range of operating conditions.展开更多
The shop scheduling problem with limited buffers has broad applications in real-world production scenarios,so this research direction is of great practical significance.However,there is currently little research on th...The shop scheduling problem with limited buffers has broad applications in real-world production scenarios,so this research direction is of great practical significance.However,there is currently little research on the hybrid flow shop scheduling problem with limited buffers(LBHFSP).This paper deeply investigates the LBHFSP to optimize the goal of the total completion time.To better solve the LBHFSP,a multi-level subpopulation-based particle swarm optimization algorithm(MLPSO)is proposed,which is founded on the attributes of the LBHFSP and the shortcomings of the basic PSO(particle swarm optimization)algorithm.In MLPSO,firstly,considering the impact of the limited buffers on the process of subsequent operations,a specific circular decoding strategy is developed to accommodate the characteristics of limited buffers.Secondly,an initialization strategy based on blocking time is designed to enhance the quality and diversity of the initial population.Afterward,a multi-level subpopulation collaborative search is developed to prevent being trapped in a local optimum and improve the global exploration capability.Additionally,a local search strategy based on the first blocked job is designed to enhance the MLPSO algorithm’s exploitation capability.Lastly,numerous experiments are carried out to test the performance of the proposed MLPSO by comparing it with classical intelligent optimization and popular algorithms in recent years.The results confirm that the proposed MLPSO has an outstanding performance when compared to other algorithms when solving LBHFSP.展开更多
Aqueous zinc-ion batteries(AZIBs)have developed rapidly in recent years but still face several challenges,including zinc dendrites growth,hydrogen evolution reaction,passivation and corrosion.The pH of the electrolyte...Aqueous zinc-ion batteries(AZIBs)have developed rapidly in recent years but still face several challenges,including zinc dendrites growth,hydrogen evolution reaction,passivation and corrosion.The pH of the electrolyte plays a crucial role in these processes,significantly impacting the stability and reversibility of Zn^(2+)deposition.Therefore,pH-buffer tris(hydroxymethyl)amino methane(tris)is chosen as a versatile electrolyte additive to address these issues.Tris can buffer electrolyte pH at Zn/electrolyte interface by protonated/deprotonated nature of amino group,optimize the coordination environment of zinc solvate ions by its strong interaction with zinc ions,and simultaneously create an in-situ stable solid electrolyte interface membrane on the zinc anode surface.These synergistic effects effectively restrain dendrite formation and side reactions,resulting in a highly stable and reversible Zn anode,thereby enhancing the electrochemical performance of AZIBs.The Zn||Zn battery with 0.15 wt%tris additives maintains stable cycling for 1500 h at 4 mA·cm^(−2) and 1120 h at 10 mA·cm^(−2).Furthermore,the Coulombic efficiency reaches~99.2%at 4 mA·cm^(−2)@1 mAh·cm^(−2).The Zn||NVO full batteries also demonstrated a stable specific capacity and exceptional capacity retention.展开更多
Photocatalytic hydrogen peroxide(H_(2)O_(2))production offers a sustainable route to convert water and oxygen into H_(2)O_(2)using solar energy.However,achieving long-term stability in photocatalysts remains a critica...Photocatalytic hydrogen peroxide(H_(2)O_(2))production offers a sustainable route to convert water and oxygen into H_(2)O_(2)using solar energy.However,achieving long-term stability in photocatalysts remains a critical challenge due to mismatched kinetics between oxygen reduction(ORR)and water oxidation(WOR),which leads to hole accumulation and oxidative degradation.Here,we report a redox-mediated strategy to address this bottleneck by designing a hydroquinone-embedded covalent organic framework(Tz-QH-COF)that enables reversible hole buffering and kinetic balance.The hydroquinone(QH)units act as dynamic hole reservoirs,capturing excess holes during ORR and converting to benzoquinone(Q),which is regenerated to QH via WOR,thereby preventing oxidative decomposition.This reversible QH/Q cycle,directly visualized through in situ attenuated total reflection surface-enhanced infrared absorption spectroscopy,ensures unmatched stability,achieving continuous H_(2)O_(2) production for 528 h(22 d)with an accumulated yield of 18.6 mmol L^(–1)—the highest reported duration for organic photocatalysts.Density functional theory calculations reveal that the QH units exhibit a strong oxygen adsorption energy and favorable two-electron ORR/WOR pathways with low energy barriers.The synergy between experimental and theoretical insights elucidates a redox-mediated charge-balance mechanism,advancing the design of robust photocatalysts for solar-driven H_(2)O_(2) synthesis.展开更多
The buffer zone of a World Natural Heritage Site constitutes a critical element of the heritage site protection system.It not only functions as an ecological security barrier,but also significantly influences the visu...The buffer zone of a World Natural Heritage Site constitutes a critical element of the heritage site protection system.It not only functions as an ecological security barrier,but also significantly influences the visual integrity and aesthetic value of the core area’s landscape.Given the rapid development of transportation infrastructure,particularly the growing number of high-speed railways traversing ecologically sensitive regions,the scientific assessment of their impact on the landscape environment of heritage sites has emerged as a pivotal concern in heritage conservation and regional development.This study focused on the section of the Guiyang-Nanning High-Speed Railway that traverses the buffer zone of the Libo World Natural Heritage Site in Guizhou Province.Beginning with five primary indicators,including natural landscape and aesthetic value,geological geomorphology and Earth history value,biodiversity value,integrity and protection management,and impact on ecological environment,a visual landscape impact assessment system for high-speed railways was developed based on the analytic hierarchy process(AHP)and the fuzzy comprehensive evaluation method(FCE).Through expert scoring,hierarchical weight calculation,and fuzzy membership degree analysis,a comprehensive assessment was conducted on the landscape ecological quality,visual coordination,and aesthetic perception within the buffer zone following the construction of high-speed railways.The findings indicate that the construction of the Guiyang-Nanning High-Speed Railway generally harmonizes well with the landscape environment of the heritage site.The level of visual disturbance remains within an acceptable range and has not significantly damaged the overall aesthetic value or authenticity of the heritage site.Although the integrity of the landscape in certain local areas has experienced a slight decline due to the exposure of bridge and slope structures,the adverse effects have been effectively mitigated through engineering interventions such as vegetation restoration and color coordination.This study innovatively integrates the AHP with fuzzy mathematics methods to achieve a comprehensive evaluation that combines both qualitative and quantitative approaches.This integration provides a scientifically grounded analytical path and a practical technical framework for assessing the visual impact of linear infrastructure projects,such as high-speed railways,within the buffer zones of World Heritage Sites.The findings offer valuable insights for the protection of landscapes and the sustainable development of infrastructure in heritage sites.展开更多
Optimizing the orientation of β-Ga_(2)O_(3) has emerged as an effective strategy to design high-performance β-Ga_(2)O_(3) device,but the orientation growth mechanism and approach have not been revealed yet.Herein,by...Optimizing the orientation of β-Ga_(2)O_(3) has emerged as an effective strategy to design high-performance β-Ga_(2)O_(3) device,but the orientation growth mechanism and approach have not been revealed yet.Herein,by employing AlN buffer layer,the highly preferred orientation of β-Ga_(2)O_(3)(100)film rather than(-201)film is realized on 4H-SiC substrate at low sputtering power and temperature.Because β-Ga_(2)O_(3)(100)film exhibits a slower growth speed than(-201)film,the former possesses the higher dangling bond density and the lower nucleation energy,and a large conversion barrier exists between these two ori-entations.Moreover,the AlN buffer layer can suppress the surface oxidation of the 4H-SiC substrate and eliminate the strain of β-Ga_(2)O_(3)(100)film,which further reduces the nucleation energy and en-larges the conversion barrier.Meanwhile,the AlN buffer layer can increase the oxygen vacancy formation energy and decrease the oxygen vacancy concentration of β-Ga_(2)O_(3)(100)film.Consequently,the solar-blind photodetector based on the oriented film exhibits the outstanding detectivity of 1.22×10^(12) Jones and photo-to-dark current ratio of 1.11×10^(5),which are the highest among the reported β-Ga_(2)O_(3) solar-blind photodetector on the SiC substrate.Our results offer in-depth insights into the preferred orientation growth mechanism,and provide an effective way to design high-quality β-Ga_(2)O_(3)(100)orientation film and high-performance solar-blind photodetector.展开更多
Attempts to remove environmentally harmful materials in mass production industries are always a major issue and draw attention if the substitution guarantees a chance to lower fabrication cost and to improve device pe...Attempts to remove environmentally harmful materials in mass production industries are always a major issue and draw attention if the substitution guarantees a chance to lower fabrication cost and to improve device performance,as in a wide bandgap Zn_(1-x)Mg_(x)O(ZMO)to replace the CdS buffer in Cu(In_(1-x),Ga_(x))Se_(2)(CIGSe)thin-film solar cell structure.ZMO is one of the candidates for the buffer material in CIGSe thin-film solar cells with a wide and controllable bandgap depending on the Mg content,which can be helpful in attaining a suitable conduction band offset.Hence,compared to the fixed and limited bandgap of a CdS buffer,a ZMO buffer may provide advantages in V_(oc) and J_(sc) based on its controllable and wide bandgap,even with a relatively wider bandgap CIGSe thin-film solar cell.In addition,to solve problems with the defect sites at the ZMO/CIGSe junction interface,a few-nanometer ZnS layer is employed for heterojunction interface passivation,forming a ZMO/ZnS buffer structure by atomic layer deposition(ALD).Finally,a Cd-free all-dry-processed CIGSe solar cell with a wider bandgap(1.25 eV)and ALD-grown buffer structure exhibited the best power conversion efficiency of 19.1%,which exhibited a higher performance than the CdS counterpart.展开更多
基金supported by the Ministry of Industry and Information Technology High Tech Ship Special Project(Grant No.CBG3N21-2-6).
文摘Gas-liquid flow(GLF),especially slug and annular flows in oil and gas gathering and transportation pipelines,become particularly complex inside elbows and can easily exacerbate pipeline corrosion and damage.In thisstudy,FLUENT was used to conduct 3D simulations of slug and annular flow in elbows for different velocitiesto assess the ensuing changes in terms of pressure.In particular,the multifluid VOF(Volume of Fraction)modelwas chosen.The results indicate that under both slug and annular flow conditions,the pressure inside the elbow islower than the outside.As the superficial velocity of liquid and gas increase,the pressure and liquid flow velocityat different positions of the elbow also increase,while the secondary flow weakens.Under annular flow conditions,the liquid film on the outer side of the elbow is thicker than that on the inner side,and the liquid velocityin the main liquid film zone is the lowest.
基金funded by the National Natural Science Foundation of China,grant number 52204022Natural Science Foundation of Shandong Province,grant number ZR2022ME152+3 种基金Youth Innovation and Technology Support Program for Shandong Provincial Universities,grant number 2022KJ066National Key Research and Development Program of China,grant number 2021YFE0111400Shandong Provincial Key Research and Development Program(2025TSGCCZZB0419)The Major Special Project for Scientific and Technological Innovation of Dongying City(Science and Technology Development Guidance Plan),grant number 2023ZDJH110.
文摘Gas–liquid two-phase jets exhibit markedly enhanced impact performance due to the violent collapse of entrained bubbles,which generates transient microjets and shock waves.The geometry of the nozzle is a decisive factor in controlling jet formation,flow modulation,and impact efficiency.In this work,the structural optimization of gas–liquid two-phase nozzles was investigated numerically using the Volume of Fluid(VOF).Simulation results show that the aero-shaped nozzle delivers a significantly stronger impact on the target surface than conventional geometries.Specifically,its impact pressure is 21%higher than that of a conical straight nozzle and 37%higher than that of a conical nozzle.The aero nozzle not only increases peak impact pressure but also sustains it over a longer duration,leading to an overall improvement in energy transfer efficiency.Parametric analyses further reveal the key geometric conditions governing performance.When the nozzle curvature is set to 0.01,the jet achieves a higher and more stable surface pressure profile,maintaining elevated impact for a prolonged period.At an aspect ratio of 15,the jet exhibits pronounced pulsation under high pressure,thereby enhancing impact intensity.The contraction ratio exerts a non-monotonic influence:as it increases,impact pressure initially rises and subsequently declines,with an optimal value of 4 yielding the highest and most persistent impact pressure.Likewise,when the ratio of inlet length to outlet diameter is 2.5,the jet demonstrates the strongest impact on the target surface.
基金supported by the Foundation for Innovative Research Groups of the National Natural Science Foundation of China(No.52121004)the National Natural Science Foundation of China(No.52274414).
文摘Sulfide precipitation is an effective method for treating acidic heavy metal wastewater.However,the process often generates tiny particles with poor settling performance.The factors and mechanisms influencing particle size and settling performance remain unclear.In this study,the growth behavior of CuS particles generated by two sulfide precipitation methods,gas-liquid and liquid-liquid sulfidation,was investigated.The effects of acidity,sulfur-to-copper molar ratio,and temperature on particle size were analyzed.The results showed that increasing the temperature had an adverse effect on CuS particle growth.Additionally,we found that acidity and sulfur-to-copper molar ratio had a more significant impact on particle growth in the liquid-liquid sulfidation system than in the gas-liquid sulfidation system.Based on supersaturation calculations and XPS analysis,it is found that particle growth in gas-liquid sulfidation systems is mainly influenced by supersaturation,while particle growth in liquid-liquid sulfidation systems is mainly affected by surface charge.This study provides valuable insights into the factors that influence particle growth in sulfide precipitation and can inform the development of strategies to improve the effective precipitation of sulfide nanoparticles in acidic wastewater.
基金supported by the National Natural Science Foundation of China(22494713,22178160,22327809 and 22208141)Natural Science Foundation of Jiangsu Province,China(BK20220349).
文摘The structural and operational optimization of gas-liquid stirred bioreactors presents both complexity and critical importance for enhancing mass transfer performance. This study proposes a machine learning (ML)-driven approach to identify key features and predict the volumetric mass transfer coefficient (kLa). Four ML models were adopted and compared for kLa prediction in Newtonian and non-Newtonian fluids by evaluative indices, with CatBoost and XGBoost emerging as the optimal models, respectively. Specifically, it is demonstrated that Catboost has higher prediction accuracy (AARD = 18.84%) than empirical equations by effectively incorporating multidimensional features (structural, impeller, and operational), while simultaneously extending applicability to diverse Newtonian fluids. For non-Newtonian fluids, XGBoost outperforms empirical equations by effectively incorporating fluid rheological parameters (consistency coefficient, power-law index), thereby better capturing shear-thinning behavior. Feature importance analysis further identified rotational speed (for Newtonian fluids) and liquid height (for non-Newtonian fluids) as the key features, while 2D partial dependence analysis establishes quantitative optimization ranges. This ML approach provides an efficient predictive tool for gas-liquid stirred bioreactor design and optimization.
基金supported by the National Natural Science Foundation of China(Grant No.11804288)the Natural Science Foundation of Henan(Grant No.232300420120)。
文摘The Casimir pressure plays an important role in the adhesion stability of nanofilms at submicro scales.In this work,the Casimir pressure of peptide films deposited on a layered substrate is investigated.Three types of semi-infinite substrates,i.e.,silica,silicon and gold,are considered.The buffer layer between the peptide film and substrate consists of silicon or silica.The switching sign of the Casimir pressure can be controlled in a region ranging from about 130 nm to 1000 nm,depending on the thickness of the buffer layer and the substrate.The results suggest that the critical thickness of peptide films for Casimir equilibrium increases(or decreases)by increasing the thickness of the silicon(or silica)buffer film.The influences of wetting and electrolyte screening on the Casimir pressure are also investigated.Our finding provides a theoretical guide for the adhesion stability of peptide films in organic electronics.
基金funded by the National Natural Science Foundation of China(No.62305041)the Natural Science Foundation of Liaoning Province(No.2023-MS-103)。
文摘Stochastic optical reconstruction microscopy(STORM),as a typical technique of single-molecule localization microscopy(SMLM),has overcome the diffraction limit by randomly switching fluorophores between fluorescent and dark states,allowing for the precise localization of isolated emission patterns and the super-resolution reconstruction from millions of localized positions of single fluorophores.A critical factor influencing localization precision is the photo-switching behavior of fluorophores,which is affected by the imaging buffer.The imaging buffer typically comprises oxygen scavengers,photo-switching reagents,and refractive index regulators.Oxygen scavengers help prevent photobleaching,photo-switching reagents assist in facilitating the conversion of fluorophores,and refractive index regulators are used to adjust the refractive index of the solution.The synergistic interaction of these components promotes stable blinking of fluorophores,reduces irreversible photobleaching,and thereby ensures high-quality super-resolution imaging.This review provides a comprehensive overview of the essential compositions and functionalities of imaging buffers used in STORM,serving as a valuable resource for researchers seeking to select appropriate imaging buffers for their experiments.
基金supported by the National Natural Science Foundation of China(Nos.62475128 and 12274055)Youth Innovation Team Program of Shandong Higher Education Institution(No.2024KJN016)+1 种基金Research Grants Council of Hong Kong through an ANR/RGC Joint Research Scheme grant(No.A-CityUl01/20)Centre for Functional Photonics of City University of Hong Kong,and Hong Kong Branch of National Precious Metals Material Engineering Research Center(ITC Fund)
文摘Metal-organic framework materials exhibit considerable potential as molecularly selective surfaceenhanced Raman spectroscopy(SERS)substrates because of their microporous structures,which enrich small molecules while excluding larger ones.In this study,we develop a template-assisted chemical-etching strategy to prepare layered tuneable SERS substrates based on hierarchical porous zeolitic imidazolate framework-67(HP-ZIF-67)with a rhombic dodecahedral structure.The synergistic SERS enhancement mechanisms of HP-ZIF-67,which combine electromagnetic(EM)and chemical(CM)effects,were systematically studied through numerical simulations and experiments.Calculations revealed that under 633-nm laser excitation,the contributions of the EM and CM effects to the total SERS enhancement factor of HP-ZIF-67 were 60%and 40%,respectively.The hierarchical porous structure enhanced the fluid-flow flux over the microporous ZIF-67 because the increased pore radius reduced the viscous resistance and facilitated rapid molecular transport through the interconnected macro-meso-channels.Precise modulation of the CM and EM effects,combined with enhanced mass transfer,facilitated the development of HP-ZIF-67and HP-ZIF-67@Au as efficient SERS sensors.An investigation of the relationship between pore-size distribution and EM effects revealed the pivotal role of light confinement by whispering-gallery-mode microcavities in enhancing the SERS performance.The optimised HPZIF-67@Au composites functioned as flexible and highly sensitive in situ SERS sensors for gases and liquids,including volatile organic-compound gas and liquid-pesticide residues.This study introduces a novel design concept and provides a robust theoretical foundation for the future development of exhaled-breath point-of-care diagnostic devices and sweat-based wearable biomedical sensors.
基金This work was supported by the German BMBF (No.05P21UMFN2)
文摘Man-made superheavy elements(SHE)are produced as energetic recoils in complete-fusion reactions and need to be thermalized in a gas-filled chamber for chemical studies.The ever-shorter half-lives and decreasing production rates of the elements beyond Fl(atomic number Z=114)-the heaviest element chemically studied today-require the development of novel techniques for quantitative thermalization and fast extraction efficiency.The Universal high-density gas stopping Cell(UniCell),currently under construction,was proposed to achieve this.Within this work,we propose an Ion Transfer by Gas Flow(ITGF)device,which serves as a UniCell ejector to interface with a gas chromatography detector array for chemical studies.Detailed parameter optimizations,using gas dynamics and Monte Carlo ion-trajectory simulations,promise fast(within a few ms)and highly efficient(up to 100%)ion extraction across a wide mass range.These ions can then be transmitted quantitatively through the ITGF into the high-pressure environment needed for further chemical studies.
基金the support of the National Natural Science Foundation of China(Grant No.42207199)Scientific Research Project of Education of Zhejiang Province(No.Y202351343)+1 种基金Zhejiang Postdoctoral Scientific Research Project(Grant Nos.ZJ2022155,ZJ2022156)Zhejiang Province International Science and Technology Cooperation Base Open Fund Project(IBGDP-2023-01)。
文摘The squeezing deformation of surrounding rock is an important factor restricting the safe construction and long-term operation of tunnels when a tunnel passes through soft strata with high ground stress.Under such soft rock geological conditions,the large deformation of the surrounding rock can easily lead to the failure of supporting structures,including shotcrete cracks,spalling,and steel arch distortion.To improve the lining support performance during the large deformation of squeezed surrounding rock,this work selects aluminum foam with densities of 0.25 g/cm3,0.42 g/cm3 and 0.61 g/cm3 as the buffer layer material and carries out uniaxial confined compression tests.Through the evaluation and analysis of energy absorption and the comparison of the yield pressure of aluminum foam with those of other cushioning materials and yield pressure support systems,the strength,deformation and energy absorption of aluminum foam with a density of 0.25 g/cm3 meet the yield pressure performance requirements.The numerical model of the buffer layer yielding support system is then established via the finite element analysis software ABAQUS,and the influence of the buffer layer setting on the lining support is analyzed.Compared with the conventional support scheme,the addition of an aluminum foam buffer layer can reduce the stress and deformation of the primary support and secondary lining.The maximum and minimum principal stresses of the primary support are reduced by 13%and 15%,respectively.The maximum and minimum principal stresses of the secondary lining are reduced by 15%and 12%,respectively,and the displacement deformation of the secondary lining position is reduced by 15%.In summary,the application of aluminum foam buffer layer can reduce the stress and deformation of the primary support and secondary lining,improve the stress safety of the support and reduce the deformation of the support.
基金Supported by the National Natural Science Foundation of China(U21B2069,52274020,52288101,52274022)National Key Research and Development Program of China(2022YFC2806504)。
文摘The gas-liquid countercurrent flow pattern is complex and the bubble migration velocity is difficult to predict in the process of bullheading well killing.The experiment on bubble migration in gas-liquid countercurrent flow in annulus is carried out under different working conditions to reveal how the wellbore inclination angle,liquid phase property and countercurrent liquid velocity affect the bubble deformation and bubble migration trajectory/velocity,and to establish a bubble migration velocity prediction model.The bubbles in the countercurrent flow mainly migrate in two modes:free rising of isolated bubbles,and interactive rising of multiple bubbles.The bubbles migrate by an S-shaped trajectory in the countercurrent flow.With the increase of countercurrent liquid velocity,the lateral oscillation of bubbles is intensified.The increases of wellbore inclination angle,liquid density and liquid viscosity make the bubble migration trajectory gradually to be linear.The bubble is generally ellipsoidal during its rising.The wellbore inclination angle has little effect on the degree of bubble deformation.The bubbles are ellipsoidal during rising,with little influence of wellbore inclination angle on bubble deformation.With the increase of liquid viscosity and density,the aspect ratio of the bubble decreases.As the wellbore inclination angle increases,the bubble migration velocity gradually decreases.As the liquid viscosity increases,the bubble migration velocity decreases.As the liquid density increases,the bubble migration velocity increases slightly.The established bubble migration velocity prediction model yields errors within±15%,and demonstrates broad applicability across a wide range of operating conditions.
基金supported in part by the National Natural Science Foundation of China under Grant No.52175490.
文摘The shop scheduling problem with limited buffers has broad applications in real-world production scenarios,so this research direction is of great practical significance.However,there is currently little research on the hybrid flow shop scheduling problem with limited buffers(LBHFSP).This paper deeply investigates the LBHFSP to optimize the goal of the total completion time.To better solve the LBHFSP,a multi-level subpopulation-based particle swarm optimization algorithm(MLPSO)is proposed,which is founded on the attributes of the LBHFSP and the shortcomings of the basic PSO(particle swarm optimization)algorithm.In MLPSO,firstly,considering the impact of the limited buffers on the process of subsequent operations,a specific circular decoding strategy is developed to accommodate the characteristics of limited buffers.Secondly,an initialization strategy based on blocking time is designed to enhance the quality and diversity of the initial population.Afterward,a multi-level subpopulation collaborative search is developed to prevent being trapped in a local optimum and improve the global exploration capability.Additionally,a local search strategy based on the first blocked job is designed to enhance the MLPSO algorithm’s exploitation capability.Lastly,numerous experiments are carried out to test the performance of the proposed MLPSO by comparing it with classical intelligent optimization and popular algorithms in recent years.The results confirm that the proposed MLPSO has an outstanding performance when compared to other algorithms when solving LBHFSP.
基金supported by the Fund of Xuzhou Science and Technology Key R&D Program(Social Development)Project(No.KC22289)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX22_2783).
文摘Aqueous zinc-ion batteries(AZIBs)have developed rapidly in recent years but still face several challenges,including zinc dendrites growth,hydrogen evolution reaction,passivation and corrosion.The pH of the electrolyte plays a crucial role in these processes,significantly impacting the stability and reversibility of Zn^(2+)deposition.Therefore,pH-buffer tris(hydroxymethyl)amino methane(tris)is chosen as a versatile electrolyte additive to address these issues.Tris can buffer electrolyte pH at Zn/electrolyte interface by protonated/deprotonated nature of amino group,optimize the coordination environment of zinc solvate ions by its strong interaction with zinc ions,and simultaneously create an in-situ stable solid electrolyte interface membrane on the zinc anode surface.These synergistic effects effectively restrain dendrite formation and side reactions,resulting in a highly stable and reversible Zn anode,thereby enhancing the electrochemical performance of AZIBs.The Zn||Zn battery with 0.15 wt%tris additives maintains stable cycling for 1500 h at 4 mA·cm^(−2) and 1120 h at 10 mA·cm^(−2).Furthermore,the Coulombic efficiency reaches~99.2%at 4 mA·cm^(−2)@1 mAh·cm^(−2).The Zn||NVO full batteries also demonstrated a stable specific capacity and exceptional capacity retention.
文摘Photocatalytic hydrogen peroxide(H_(2)O_(2))production offers a sustainable route to convert water and oxygen into H_(2)O_(2)using solar energy.However,achieving long-term stability in photocatalysts remains a critical challenge due to mismatched kinetics between oxygen reduction(ORR)and water oxidation(WOR),which leads to hole accumulation and oxidative degradation.Here,we report a redox-mediated strategy to address this bottleneck by designing a hydroquinone-embedded covalent organic framework(Tz-QH-COF)that enables reversible hole buffering and kinetic balance.The hydroquinone(QH)units act as dynamic hole reservoirs,capturing excess holes during ORR and converting to benzoquinone(Q),which is regenerated to QH via WOR,thereby preventing oxidative decomposition.This reversible QH/Q cycle,directly visualized through in situ attenuated total reflection surface-enhanced infrared absorption spectroscopy,ensures unmatched stability,achieving continuous H_(2)O_(2) production for 528 h(22 d)with an accumulated yield of 18.6 mmol L^(–1)—the highest reported duration for organic photocatalysts.Density functional theory calculations reveal that the QH units exhibit a strong oxygen adsorption energy and favorable two-electron ORR/WOR pathways with low energy barriers.The synergy between experimental and theoretical insights elucidates a redox-mediated charge-balance mechanism,advancing the design of robust photocatalysts for solar-driven H_(2)O_(2) synthesis.
基金Sponsored by Guizhou Provincial Key Technology R&D Program“A Study on the Conservation Model with Technology and Sustainable Development Demonstration of the World Natural Heritages in Guizhou”(2202023 QKHZC)the China Overseas Expertise Introduction Project for Discipline Innovation(China 111 Project)(D17016).
文摘The buffer zone of a World Natural Heritage Site constitutes a critical element of the heritage site protection system.It not only functions as an ecological security barrier,but also significantly influences the visual integrity and aesthetic value of the core area’s landscape.Given the rapid development of transportation infrastructure,particularly the growing number of high-speed railways traversing ecologically sensitive regions,the scientific assessment of their impact on the landscape environment of heritage sites has emerged as a pivotal concern in heritage conservation and regional development.This study focused on the section of the Guiyang-Nanning High-Speed Railway that traverses the buffer zone of the Libo World Natural Heritage Site in Guizhou Province.Beginning with five primary indicators,including natural landscape and aesthetic value,geological geomorphology and Earth history value,biodiversity value,integrity and protection management,and impact on ecological environment,a visual landscape impact assessment system for high-speed railways was developed based on the analytic hierarchy process(AHP)and the fuzzy comprehensive evaluation method(FCE).Through expert scoring,hierarchical weight calculation,and fuzzy membership degree analysis,a comprehensive assessment was conducted on the landscape ecological quality,visual coordination,and aesthetic perception within the buffer zone following the construction of high-speed railways.The findings indicate that the construction of the Guiyang-Nanning High-Speed Railway generally harmonizes well with the landscape environment of the heritage site.The level of visual disturbance remains within an acceptable range and has not significantly damaged the overall aesthetic value or authenticity of the heritage site.Although the integrity of the landscape in certain local areas has experienced a slight decline due to the exposure of bridge and slope structures,the adverse effects have been effectively mitigated through engineering interventions such as vegetation restoration and color coordination.This study innovatively integrates the AHP with fuzzy mathematics methods to achieve a comprehensive evaluation that combines both qualitative and quantitative approaches.This integration provides a scientifically grounded analytical path and a practical technical framework for assessing the visual impact of linear infrastructure projects,such as high-speed railways,within the buffer zones of World Heritage Sites.The findings offer valuable insights for the protection of landscapes and the sustainable development of infrastructure in heritage sites.
基金supported by the National Key Research and Development Program of China(No.2021YFA0715600)the National Natural Science Foundation of China(Nos.62274125,52192611)+2 种基金the Guangdong Basic and Applied Basic Research Fund(No.2023A1515030084)the Key Research and Development Program of Shaanxi Province(Grant No.2024GX-YBXM-410)the fund of the State Key Laboratory of Solidification Processing in NWPU(No.SKLSP202220).
文摘Optimizing the orientation of β-Ga_(2)O_(3) has emerged as an effective strategy to design high-performance β-Ga_(2)O_(3) device,but the orientation growth mechanism and approach have not been revealed yet.Herein,by employing AlN buffer layer,the highly preferred orientation of β-Ga_(2)O_(3)(100)film rather than(-201)film is realized on 4H-SiC substrate at low sputtering power and temperature.Because β-Ga_(2)O_(3)(100)film exhibits a slower growth speed than(-201)film,the former possesses the higher dangling bond density and the lower nucleation energy,and a large conversion barrier exists between these two ori-entations.Moreover,the AlN buffer layer can suppress the surface oxidation of the 4H-SiC substrate and eliminate the strain of β-Ga_(2)O_(3)(100)film,which further reduces the nucleation energy and en-larges the conversion barrier.Meanwhile,the AlN buffer layer can increase the oxygen vacancy formation energy and decrease the oxygen vacancy concentration of β-Ga_(2)O_(3)(100)film.Consequently,the solar-blind photodetector based on the oriented film exhibits the outstanding detectivity of 1.22×10^(12) Jones and photo-to-dark current ratio of 1.11×10^(5),which are the highest among the reported β-Ga_(2)O_(3) solar-blind photodetector on the SiC substrate.Our results offer in-depth insights into the preferred orientation growth mechanism,and provide an effective way to design high-quality β-Ga_(2)O_(3)(100)orientation film and high-performance solar-blind photodetector.
基金conducted under the framework of the research and development program of the Korea Institute of Energy Research(C4-2412 and C4-2413)supported by the National Research Foundation of Korea(grant number 2022M3J1A1063019)funded by the Ministry of Science and ICT.
文摘Attempts to remove environmentally harmful materials in mass production industries are always a major issue and draw attention if the substitution guarantees a chance to lower fabrication cost and to improve device performance,as in a wide bandgap Zn_(1-x)Mg_(x)O(ZMO)to replace the CdS buffer in Cu(In_(1-x),Ga_(x))Se_(2)(CIGSe)thin-film solar cell structure.ZMO is one of the candidates for the buffer material in CIGSe thin-film solar cells with a wide and controllable bandgap depending on the Mg content,which can be helpful in attaining a suitable conduction band offset.Hence,compared to the fixed and limited bandgap of a CdS buffer,a ZMO buffer may provide advantages in V_(oc) and J_(sc) based on its controllable and wide bandgap,even with a relatively wider bandgap CIGSe thin-film solar cell.In addition,to solve problems with the defect sites at the ZMO/CIGSe junction interface,a few-nanometer ZnS layer is employed for heterojunction interface passivation,forming a ZMO/ZnS buffer structure by atomic layer deposition(ALD).Finally,a Cd-free all-dry-processed CIGSe solar cell with a wider bandgap(1.25 eV)and ALD-grown buffer structure exhibited the best power conversion efficiency of 19.1%,which exhibited a higher performance than the CdS counterpart.
