This paper extends the SPH method to gas simulation. The SPH （Smoothed Particles Hydrodynamics） method is the most popular method of flow simulation, which is widely used in large-scale liquid simulation. However, i...This paper extends the SPH method to gas simulation. The SPH （Smoothed Particles Hydrodynamics） method is the most popular method of flow simulation, which is widely used in large-scale liquid simulation. However, it is not found to apply to gas simulation, since those methods based on SPH can＇t be used in real-time simulation due to their enormous particles and huge computation. This paper proposes a method for gas simulation based on SPH with a small number of particles. Firstly, the method computes the position and density of each particle in each point-in-time, and outlines the shape of the simulated gas based on those particles. Secondly the method uses the grid technique to refine the shape with the diffusion of particle＇s density under the control of grid, and get more lifelike simulation result. Each grid will be assigned density according to the particles in it. The density determines the final appearance of the grid. For ensuring the natural transition of the color between adjacent grids, we give a diffuse process of density between these grids and assign appropriate values to vertexes of these grids. The experimental results show that the proposed method can give better gas simulation and meet the request of real-time.展开更多
A gas migration controlling equation was formulated based on the characteristics of the dual pore–fracture media of coal mass and in consideration of the matrix exchange between pores and fractures.A model of permeab...A gas migration controlling equation was formulated based on the characteristics of the dual pore–fracture media of coal mass and in consideration of the matrix exchange between pores and fractures.A model of permeability dynamic evolution was established by analyzing the variation in effective stress during gas drainage and the action mechanism of the effect of coal matrix desorption on porosity and fracture in the coal body.A coupling model can then be obtained to characterize gas compressibility and coal deformability under the gas–solid coupling of loading coal.In addition,a 3D model of boreholes was established and solved for gas drainage based on the relevant physical parameters of real mines.The comparison and analysis results for the law of gas migration and the evolution of coal body permeability around the boreholes before and after gas extraction between the dual media and the single-seepage field models can provide a theoretical basis for further research on the action mechanism of gas drainage.展开更多
In order to simulate field distribution rules,mathematical models for 3-D air flows and gas transfer in the goaf of the coal mining are established,based on theories of permeability and dynamic dispersion through poro...In order to simulate field distribution rules,mathematical models for 3-D air flows and gas transfer in the goaf of the coal mining are established,based on theories of permeability and dynamic dispersion through porous media. A gas dispersion equation in a 3-D field is calculated by use of numerical method on a weighted upstream multi-element balance. Based on data of an example with a U type ventilation mode,surface charts of air pressure distribution and gas concentration are drawn by Graphtool software. Finally,a comparison between actually measured results in the model test and the numerical simulation results is made to proves the numerical implementation feasible.展开更多
Tracer gas technique is a method to analyze the airflow path, measure the airflow quantity, and detect any recirculation or leakages in underground mine. In addition, it is also possible to evaluate the axial gas diff...Tracer gas technique is a method to analyze the airflow path, measure the airflow quantity, and detect any recirculation or leakages in underground mine. In addition, it is also possible to evaluate the axial gas diffusion of gas in turbulent bulk flow by utilizing the tracer gas data. This paper discussed about the measurement using tracer gas technique in Cibaliung Underground Mine, Indonesia and the evaluation of effective axial diffusion coefficient, E, by numerical simulation. In addition, a scheme to treat network flow in mine ventilation system was also proposed. The effective axial diffusion coefficient for each airway was evaluated based on Taylor's theoretical equation. It is found that the evaluated diffusion coefficient agrees well with Taylor's equation by considering that the wall friction factor, f, is higher than those for smooth pipe flow. It also shows that the value of effective diffusion coefficient can be inherently determined and the value is constant when matching with other measurements. Furthermore, there are possibilities to utilize the tracer gas measurement data to evaluate the airway friction factors.展开更多
Background Petrochemical products possess a high risk of flammability,explosivity,and toxicity,making petrochemical accidents exceedingly destructive.Therefore,disaster analysis,prediction,and real-time simulations ha...Background Petrochemical products possess a high risk of flammability,explosivity,and toxicity,making petrochemical accidents exceedingly destructive.Therefore,disaster analysis,prediction,and real-time simulations have become important means of controlling and reducing accident hazards.Methods This study proposes a complete real-time simulation solution of gas diffusion with coordinate and concentration data,which was mainly aimed at simulating the types of harmful gas leakage and diffusion accidents in the petrochemical industry.The rendering effect was more continuous and accurate through grid homogenization and trilinear interpolation.This study presents a data processing and rendering parallelization process to enhance simulation efficiency.Gas concentration and fragment transparency were combined to synthesize transparent pixels in a scene.To ensure the approximate accuracy of the rendering effect,improve the efficiency of real-time rendering,and meet the requirement of intuitive perception using concentration data,a weighted blended order-independent transparency(OIT)with enhanced alpha weight is presented,which can provide a more intuitive perception of the hierarchical information of concentration data while preserving depth information.This study compares and analyzes three OIT algorithms-depth peeling,weighted blended OIT,and weighted blended OIT with enhanced alpha weight-in terms of rendering image quality,rendering time,required memory,and hierarchical information.Results Using weighted blended OIT with an enhanced alpha weight technique,the rendering time was shortened by 53.2%compared with that of the depth peeling algorithm,and the texture memory required was significantly smaller than that of the depth peeling algorithm.The rendering results of weighted blended OIT with an enhanced alpha weight were approximately accurate compared with those of the depth peeling algorithm as the ground truth,and there was no popping when surfaces passed through one another.Simultaneously,compared with weighted blended OIT,weighted blended OIT with an enhanced alpha weight achieved an intuitive perception of the hierarchical information of concentration data.展开更多
The personnel in refuge chamber absorb O_2 and exhale CO_2 all the time. Supplying O_2 and removing CO_2 are the basic function of refuge chamber. After disaster occurs, the supply of the compressed air or oxygen for ...The personnel in refuge chamber absorb O_2 and exhale CO_2 all the time. Supplying O_2 and removing CO_2 are the basic function of refuge chamber. After disaster occurs, the supply of the compressed air or oxygen for personnel in refuge chamber is limited. Thus, how to effectively use the compressed air and oxygen and try to improve the time of supply has a great significance. Supplying more oxygen will result in waste, while supplying less oxygen will cause its concentration to be lower, and harm life safety. This research uses the theoretical calculation and numerical simulation, finds critical gas supply for refuge chamber, and illuminates the change law of gas concentration with critical gas supply in refuge chamber,which provides theoretical guidance for effective use of compressed air and oxygen in refuge chamber.展开更多
Adsorption of FCC dry gas components, hydrogen(H_2), nitrogen(N_2), methane(CH_4), ethane(C_2H_6) and ethylene(C_2H_4) in zeolite Y was studied by performing the Grant Canonical Monte Carlo(GCMC) simulations at 298K a...Adsorption of FCC dry gas components, hydrogen(H_2), nitrogen(N_2), methane(CH_4), ethane(C_2H_6) and ethylene(C_2H_4) in zeolite Y was studied by performing the Grant Canonical Monte Carlo(GCMC) simulations at 298K and 823K and under a pressure range up to 10 MPa. Simulation results were analyzed using the Langmuir model, which presented fitting of dry gas components adsorption to be suggested as the monolayer adsorption. C_2H_4 presented most single adsorption amount, which reached 7.63 mol/kg at 298K under a pressure of 200kPa. Thermodynamic parameters of the Gibbs free energy change, enthalpy change and entropy change were analyzed based on adsorption equilibrium constant obtained from the GCMC simulations. The results suggested that it was more favorable for C_2H_4 to be adsorbed in zeolite Y. Adsorption molecules were in ordered arrangement in the zeolite, and C_2H_4 exhibited a more orderly arrangement than other components. Additionally, a competition in the adsorption of a mixture of dry gas components was found, and supercages were the priority adsorption space. The competition was favorable to CH_4 and C_2H_6, and the competitive power was affected by temperature.展开更多
Numerical simulations of gas–liquid two-phase flow and alumina transport process in an aluminum reduction cell were conducted to investigate the effects of anode configurations on the bath flow, gas volume fraction a...Numerical simulations of gas–liquid two-phase flow and alumina transport process in an aluminum reduction cell were conducted to investigate the effects of anode configurations on the bath flow, gas volume fraction and alumina content distributions. An Euler–Euler two-fluid model was employed coupled with a species transport equation for alumina content. Three different anode configurations such as anode without a slot, anode with a longitudinal slot and anode with a transversal slot were studied in the simulation. The simulation results clearly show that the slots can reduce the bath velocity and promote the releasing of the anode gas, but can not contribute to the uniformity of the alumina content. Comparisons of the effects between the longitudinal and transversal slots indicate that the longitudinal slot is better in terms of gas–liquid flow but is disadvantageous for alumina mixing and transport process due to a decrease of anode gas under the anode bottom surface. It is demonstrated from the simulations that the mixing and transfer characteristics of alumina are controlled to great extent by the anode gas forces while the electromagnetic forces(EMFs) play the second role.展开更多
Gas release and its dispersion is a major concern in chemical industries.In order to manage and mitigate the risk of gas dispersion and its consequences,it is necessary to predict gas dispersion behavior and its conce...Gas release and its dispersion is a major concern in chemical industries.In order to manage and mitigate the risk of gas dispersion and its consequences,it is necessary to predict gas dispersion behavior and its concentration at various locations upon emission.Therefore,models and commercial packages such as Phast and ALOHA have been developed.Computational fluid dynamics(CFD)can be a useful tool to simulate gas dispersion in complex areas and conditions.The validation of the models requires the employment of the experimental data from filed and wind tunnel experiments.It appears that the use of the experimental data to validate the CFD method that only includes certain monitor points and not the entire domain can lead to unreliable results for the intended areas of concern.In this work,some of the trials of the Kit Fox field experiment,which provided a wide-range database for gas dispersion,were simulated by CFD.Various scenarios were considered with different mesh sizes,physical conditions,and types of release.The results of the simulations were surveyed in the whole domain.The data matching each scenario was varied by the influence of the dominant displacement force(wind or diffusivity).Furthermore,the statistical parameters suggested for the heavy gas dispersion showed a dependency on the lower band of gas concentration.Therefore,they should be used with precaution.Finally,the results and computation cost of the simulation could be affected by the chosen scenario,the location of the intended points,and the release type.展开更多
A three-dimensional mathematical model,based on differential balances of mass and momentum,hasbeen developed to describe the two-phase flow of gas and liquid through the dropping zone of the blast fur-nace.Agreement b...A three-dimensional mathematical model,based on differential balances of mass and momentum,hasbeen developed to describe the two-phase flow of gas and liquid through the dropping zone of the blast fur-nace.Agreement between observed and calculated values verifies the validity of this model.On the basis of this model,various parameters for the surrounding of the dry zone of Blast FurnaceNo.I-BF of the Beijing Iron and Steel Company have been computed,from which a diagram for demar-cation of fluidization of coke and flooding of slag has been proposed.展开更多
Simulation has proven to be an effective tool for analyzing pipeline network systems （PNS） in order to determine the design and operational variables which are essential for evaluating the performance of the system....Simulation has proven to be an effective tool for analyzing pipeline network systems （PNS） in order to determine the design and operational variables which are essential for evaluating the performance of the system. This paper discusses the use of simulation for performance analysis of transmission PNS. A simulation model was developed for determining flow and pressure variables for different configuration of PNS. The mathematical formulation for the simulation model was derived based on the principles of energy conservation, mass balance, and compressor characteristics. For the determination of the pressure and flow variables, solution procedure was developed based on iterative Newton Raphson scheme and implemented using visual C＋＋6. Evaluations of the simulation model with the existing pipeline network system showed that the model enabled to determine the operational variables with less than ten iterations. The performances of the compressor working in the pipeline network system xvhich includes energy consumption, compression ratio and discharge pressure were evaluated to meet pressure requirements ranging from 4000-5000 kPa at various speed. Results of the analyses from the simulation indicated that the model could be used for performance analysis to assist decisions regarding the design and optimal operations of transmission PNS.展开更多
The high melting point element W and the rare earth element Ce were added to 18Cr-Mo(444-type)ferritic stainless steel to improve its high-temperature oxidation resistance in exhaust gas.A simulated exhaust gas was fi...The high melting point element W and the rare earth element Ce were added to 18Cr-Mo(444-type)ferritic stainless steel to improve its high-temperature oxidation resistance in exhaust gas.A simulated exhaust gas was filled in the simultaneous thermal analyzer to simulate the service environment,and the oxidation behavior in high-temperature exhaust gas environment of 444-type ferritic stainless steel alloyed with W and Ce was investigated.The oxide structure and composition formed in this process were analyzed and characterized by scanning electron microscopy/energy-dispersive spectroscopy and electron probe analysis,and the mechanism of W and Ce in the oxidation process was revealed.The results show that 18Cr-Mo ferritic stainless steel containing W and Ce has better oxidation resistance in high-temperature exhaust gas.The element W can promote the precipitation of Laves phase at the matrix/interface,inhibit the interface diffusion of oxidizing elements and prevent the inward growth of the oxide film.The element Ce can suppress the volume of SiO_(2)at the oxide film/interface,reducing the breakaway oxidation caused by cracking of the oxide film.The CeO_(2)provides nucleation sites for oxide particles,promoting the healing of cracks and voids within the oxide film.展开更多
A gas–solid coupling model involving coal seam deformation,gas diffusion and seepage,gas adsorption and desorption was built to study the gas transport rule under the effect of protective coal seam mining.The researc...A gas–solid coupling model involving coal seam deformation,gas diffusion and seepage,gas adsorption and desorption was built to study the gas transport rule under the effect of protective coal seam mining.The research results indicate:(1) The depressurization effect changes the stress state of an overlying coal seam and causes its permeability to increase,thus gas in the protected coal seam will be desorbed and transported under the effect of a gas pressure gradient,which will cause a decrease in gas pressure.(2) Gas pressure can be further decreased by setting out gas extraction boreholes in the overlying coal seam,which can effectively reduce the coal and gas outburst risk.The research is of important engineering significance for studying the gas transport rule in protected coal seam and providing important reference for controlling coal and gas outbursts in deep mining in China.展开更多
The influence of CO2 content and presence of SO2 on the sequestration of CO2 by municipal solid waste incinerator （MSWI） fly ash was studied by investigating the carbonation reaction of MSWI fly ash with different c...The influence of CO2 content and presence of SO2 on the sequestration of CO2 by municipal solid waste incinerator （MSWI） fly ash was studied by investigating the carbonation reaction of MSWI fly ash with different combinations of simulated flue gas. The reaction between fly ash and 100% CO2 was relatively fast; the uptake of CO2 reached 87 g CO2/kg ash, and the sequestered CO2 could be entirely released at high temperatures. When CO2 content was reduced to 12%, the reaction rate decreased; the uptake fell to 41 g CO2/kg ash, and 70.7% of the sequestered CO2 could be released. With 12% CO2 in the presence of SO2, the reaction rate significantly decreased; the uptake was just 17 g CO2/kg ash, and only 52.9% of the sequestered CO2 could be released. SO2 in the simulated gas restricted the ability of fly ash to sequester CO2 because it blocked the pores of the ash.展开更多
To understand the influence of the diagenetic water medium on the isotopic compositions of thermogenic coalbed gas,both hydrous and anhydrous closed-system pyrolyses were performed at temperatures of 250°C to 650...To understand the influence of the diagenetic water medium on the isotopic compositions of thermogenic coalbed gas,both hydrous and anhydrous closed-system pyrolyses were performed at temperatures of 250°C to 650°C on an herbaceous marsh peat.Compared to the results of anhydrous pyrolysis,the hydrocarbon gases generated from hydrous pyrolyses have very different hydrogen isotopic compositions.However,the carbon isotopic compositions of the hydrocarbon gases became only slightly heavier in hydrous pyrolysis,compared to that from anhydrous pyrolysis.With the progress of thermal evolution from peat to a more advanced thermal maturity of vitrinite reflectance values(Ro)of 5.5%during the pyrolysis,the difference in the averageδD value increased from 52‰to 64‰between the hydrous pyrolysis with saltwater and anhydrous pyrolysis and increased from 18‰to 29‰between the hydrous pyrolysis with freshwater and anhydrous pyrolysis,respectively.The difference in the averageδ^(13)C value was only 1‰–2‰between the hydrous and anhydrous pyrolysis.The relationships between theδD values of the generated hydrocarbon gases and Ro values as well as amongδD values of the hydrocarbon gas species are established.The close relationships among these parameters suggest that the water medium had a significant effect on the hydrogen isotopic composition and a minimal effect on the carbon isotopic composition of the hydrocarbon gases.The results of these pyrolyses may provide information for the understanding of the genesis of coalbed gas from herbaceous marsh material with the participation of different diagenetic water media.展开更多
The corrosion behaviors of pure titanium and its weldment welded by tungsten inert gas （TIG） welding in simulated desulfurized flue gas condensates in thermal power plant chimney were investigated using potentiodyna...The corrosion behaviors of pure titanium and its weldment welded by tungsten inert gas （TIG） welding in simulated desulfurized flue gas condensates in thermal power plant chimney were investigated using potentiodynamic polarization, electrochemical impedance spectroscopy （EIS） and immersion tests. The effects of heat input and shielding gases on the corrosion behavior of the welded titanium were also studied. Grain coarsening and Widmanst^itten structure were found in both the fusion zone and the heat-affected zone. The welded titanium exhibited active-passive behavior in the simulated condensates. Both the polarization curves and EIS measurements confirmed that TIG welding process with different parameters had few effects on the corrosion behavior. It was proved that the microstructure changes were not the key material factors affecting the corrosion behavior of pure titanium under the test conditions, while the oxide film had remarkable effect on improving the corrosion resistance.展开更多
In order to investigate the influence on shale gas well productivity caused by gas transport in nanometer- size pores, a mathematical model of multi-stage fractured horizontal wells in shale gas reservoirs is built, w...In order to investigate the influence on shale gas well productivity caused by gas transport in nanometer- size pores, a mathematical model of multi-stage fractured horizontal wells in shale gas reservoirs is built, which considers the influence of viscous flow, Knudsen diffusion, surface diffusion, and adsorption layer thickness. A dis- crete-fracture model is used to simplify the fracture mod- cling, and a finite element method is applied to solve the model. The numerical simulation results indicate that with a decrease in the intrinsic matrix permeability, Knudsen diffusion and surface diffusion contributions to production become large and cannot be ignored. The existence of an adsorption layer on the nanopore surfaces reduces the effective pore radius and the effective porosity, resulting in low production from fractured horizontal wells. With a decrease in the pore radius, considering the adsorption layer, the production reduction rate increases. When the pore radius is less than 10 nm, because of the combined impacts of Knudsen diffusion, surface diffusion, and adsorption layers, the production of multi-stage fractured horizontal wells increases with a decrease in the pore pressure. When the pore pressure is lower than 30 MPa, the rate of production increase becomes larger with a decrease in pore pressure.展开更多
By combining 5,10,15,20-tetra(4-chlorine)phenylporphyrin(TClPP)andα-Keggin polyoxometalate H_(5)PV_(2)Mo_(10)O_(40)(H 5 PVMo)via a simple ion-exchange method,an organic-inorganic hybrid material[C_(44)H_(28)N_(4)Cl_(...By combining 5,10,15,20-tetra(4-chlorine)phenylporphyrin(TClPP)andα-Keggin polyoxometalate H_(5)PV_(2)Mo_(10)O_(40)(H 5 PVMo)via a simple ion-exchange method,an organic-inorganic hybrid material[C_(44)H_(28)N_(4)Cl_(4)]_(1.5)[H_(2)PMo_(10)V_(2)O_(40)]·2C_(2)H_(6)O(H_(2 )TClPP-H_(2) PVMo)was prepared and thoroughly characterized by a variety of techniques.The homogeneous photocatalytic degradation of 2-chloroethyl ethyl sulfide(CEES)(5μL)by H_(2) TClPP-H_(2) PVMo(1×10^(−6)mol/L)was studied in methanol and methanol-water mixed solvent(v/v=1:1),in which the degradation rate of CEES reached 99.52%and 99.14%,respectively.The reaction followed first-order reaction kinetics,and the half-life and kinetic constant in methanol and the mixed solvent were respectively 33.0min,−0.021 min−1 and 15.7min,−0.043 min−1.Mechanism analysis indicated that under visible light irradiation in the air,CEES was degraded via oxidation and alcoholysis/hydrolysis in methanol and the mixed solvent.O_(2)·−and ^(1)O_(2) generated by H_(2) TClPP-H_(2) PVMo selectively oxidized CEES into a nontoxic sulfoxide.Singlet oxygen capture experiments showed that H_(2) TClPP-H_(2) PVMo(φ=0.73)had a higher quantum yield of singlet oxygen than TClPP(φ=0.35)under an air atmosphere and visible light irradiation.展开更多
In order to present a retrospective analysis of exposition accidents using input data from investigation processes,data from a specific accident was examined,in which we analyzed possible involved gas species（ liquef...In order to present a retrospective analysis of exposition accidents using input data from investigation processes,data from a specific accident was examined,in which we analyzed possible involved gas species（ liquefied petroleum gas; nature gas） and computed their concentrations and distributions based on the interactions between the structures and the effects of the explosion. In this study,5 scenarios were created to analyze the impact effect. Moreover,a coupling algorithm was put into practice,with a practical outflow boundary and joint strength are applied. Finally,the damage effects of each scenario were simulated. Our experimental results showed significant differences in the 5 scenarios concerning the damage effects on the building structures. The results from scenario 3 agree with the accident characteristics,demonstrating the effectiveness of our proposed modeling method. Our proposed method reflects gas properties,species and the concentration and distribution,and the simulated results validates the root cause,process,and consequences of accidental explosions. Furthermore,this method describes the evolution process of explosions in different building structures. Significantly,our model demonstrates the quantatative explosion effect of factors like gas species,gas volumes,and distributions of gases on explosion results. In this study,a feasible,effective,and quantitative method for structure safety is defined,which is helpful to accelerate the development of safer site regulations.展开更多
As one of the main reasons causing leakage heat load in a refrigerator,mass and heat transfer through refrigerator door seal is of great importance to be studied.In this paper,a model is presented for numerical simula...As one of the main reasons causing leakage heat load in a refrigerator,mass and heat transfer through refrigerator door seal is of great importance to be studied.In this paper,a model is presented for numerical simulation of mass and heat transfer process through refrigerator door seal,and an experiment apparatus is designed and set up as well for comparison.A two-dimensional model and tracer gas method are used in simulation and experiment,respectively.It can be found that the relative deviations of air infiltration rate between the simulated results and experimental results were less than 1%,and the temperature difference errors at two special points of the door seal were less than 2.03℃.In conclusion,the simulated results are in good agreement with the experimental results.This paper initially sets up a model that can accurately simulate the heat and mass transfer through the refrigerator door seal,and the model can be used in refrigerator door seal optimization research in the follow-up study.展开更多
基金Supported by National Natural Science Foundation of China(No.61272024)
文摘This paper extends the SPH method to gas simulation. The SPH （Smoothed Particles Hydrodynamics） method is the most popular method of flow simulation, which is widely used in large-scale liquid simulation. However, it is not found to apply to gas simulation, since those methods based on SPH can＇t be used in real-time simulation due to their enormous particles and huge computation. This paper proposes a method for gas simulation based on SPH with a small number of particles. Firstly, the method computes the position and density of each particle in each point-in-time, and outlines the shape of the simulated gas based on those particles. Secondly the method uses the grid technique to refine the shape with the diffusion of particle＇s density under the control of grid, and get more lifelike simulation result. Each grid will be assigned density according to the particles in it. The density determines the final appearance of the grid. For ensuring the natural transition of the color between adjacent grids, we give a diffuse process of density between these grids and assign appropriate values to vertexes of these grids. The experimental results show that the proposed method can give better gas simulation and meet the request of real-time.
基金supported by Chinese Ministry of Education (No.213022A)the National Natural Science Foundation of China (No.51574112)+4 种基金Henan Key Laboratory of Biogenic Traces and Sedimentary Minerals (No.OTMP1410)the Key Research Project of Higher Education Institution of Henan Province in 2015 (No.15A440001)the Doctor Funds of Henan Polytechnic University (No.B2015-05)the Basic and Advanced Technology Research Projects of Henan Province (No.162300410031)the Science and Technology Innovation Funds for Distinguished Young Scholar in Henan Province (No.164100510013)
文摘A gas migration controlling equation was formulated based on the characteristics of the dual pore–fracture media of coal mass and in consideration of the matrix exchange between pores and fractures.A model of permeability dynamic evolution was established by analyzing the variation in effective stress during gas drainage and the action mechanism of the effect of coal matrix desorption on porosity and fracture in the coal body.A coupling model can then be obtained to characterize gas compressibility and coal deformability under the gas–solid coupling of loading coal.In addition,a 3D model of boreholes was established and solved for gas drainage based on the relevant physical parameters of real mines.The comparison and analysis results for the law of gas migration and the evolution of coal body permeability around the boreholes before and after gas extraction between the dual media and the single-seepage field models can provide a theoretical basis for further research on the action mechanism of gas drainage.
基金Projects 50534090 and 50674090 supported by the National Natural Science Foundation of China2005CB221503 by the National Key Basic ResearchDevelopment Program (973 Program)
文摘In order to simulate field distribution rules,mathematical models for 3-D air flows and gas transfer in the goaf of the coal mining are established,based on theories of permeability and dynamic dispersion through porous media. A gas dispersion equation in a 3-D field is calculated by use of numerical method on a weighted upstream multi-element balance. Based on data of an example with a U type ventilation mode,surface charts of air pressure distribution and gas concentration are drawn by Graphtool software. Finally,a comparison between actually measured results in the model test and the numerical simulation results is made to proves the numerical implementation feasible.
基金the financial support of this work by Japan Ministry of Education, Culture, Sport, Science and Technology and Kyushu University’s Global COE program
文摘Tracer gas technique is a method to analyze the airflow path, measure the airflow quantity, and detect any recirculation or leakages in underground mine. In addition, it is also possible to evaluate the axial gas diffusion of gas in turbulent bulk flow by utilizing the tracer gas data. This paper discussed about the measurement using tracer gas technique in Cibaliung Underground Mine, Indonesia and the evaluation of effective axial diffusion coefficient, E, by numerical simulation. In addition, a scheme to treat network flow in mine ventilation system was also proposed. The effective axial diffusion coefficient for each airway was evaluated based on Taylor's theoretical equation. It is found that the evaluated diffusion coefficient agrees well with Taylor's equation by considering that the wall friction factor, f, is higher than those for smooth pipe flow. It also shows that the value of effective diffusion coefficient can be inherently determined and the value is constant when matching with other measurements. Furthermore, there are possibilities to utilize the tracer gas measurement data to evaluate the airway friction factors.
基金Supported by National Key R&D Program of China (2020YFB1710400)。
文摘Background Petrochemical products possess a high risk of flammability,explosivity,and toxicity,making petrochemical accidents exceedingly destructive.Therefore,disaster analysis,prediction,and real-time simulations have become important means of controlling and reducing accident hazards.Methods This study proposes a complete real-time simulation solution of gas diffusion with coordinate and concentration data,which was mainly aimed at simulating the types of harmful gas leakage and diffusion accidents in the petrochemical industry.The rendering effect was more continuous and accurate through grid homogenization and trilinear interpolation.This study presents a data processing and rendering parallelization process to enhance simulation efficiency.Gas concentration and fragment transparency were combined to synthesize transparent pixels in a scene.To ensure the approximate accuracy of the rendering effect,improve the efficiency of real-time rendering,and meet the requirement of intuitive perception using concentration data,a weighted blended order-independent transparency(OIT)with enhanced alpha weight is presented,which can provide a more intuitive perception of the hierarchical information of concentration data while preserving depth information.This study compares and analyzes three OIT algorithms-depth peeling,weighted blended OIT,and weighted blended OIT with enhanced alpha weight-in terms of rendering image quality,rendering time,required memory,and hierarchical information.Results Using weighted blended OIT with an enhanced alpha weight technique,the rendering time was shortened by 53.2%compared with that of the depth peeling algorithm,and the texture memory required was significantly smaller than that of the depth peeling algorithm.The rendering results of weighted blended OIT with an enhanced alpha weight were approximately accurate compared with those of the depth peeling algorithm as the ground truth,and there was no popping when surfaces passed through one another.Simultaneously,compared with weighted blended OIT,weighted blended OIT with an enhanced alpha weight achieved an intuitive perception of the hierarchical information of concentration data.
基金supported by the National Natural Science Foundation of China(Grant Nos.51504251,51404263)the National Natural Science Foundation of Jiangsu of China(Nos.BK20140187,BK20130203)+4 种基金the Fundamental Research Funds for the Central Universities(2015QNB01)the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the Central Universities Special Funds for Fundamental Research Funds of the China University of Mining and Technology(No.2014ZDPY04)the Innovation Team of CUMT(2014QN001)the Natural Science Foundation of Jiangsu Province(No.BK2012571)
文摘The personnel in refuge chamber absorb O_2 and exhale CO_2 all the time. Supplying O_2 and removing CO_2 are the basic function of refuge chamber. After disaster occurs, the supply of the compressed air or oxygen for personnel in refuge chamber is limited. Thus, how to effectively use the compressed air and oxygen and try to improve the time of supply has a great significance. Supplying more oxygen will result in waste, while supplying less oxygen will cause its concentration to be lower, and harm life safety. This research uses the theoretical calculation and numerical simulation, finds critical gas supply for refuge chamber, and illuminates the change law of gas concentration with critical gas supply in refuge chamber,which provides theoretical guidance for effective use of compressed air and oxygen in refuge chamber.
基金financial support from the National Natural Science Foundation of China (No. 41302101 and No. 21476263)
文摘Adsorption of FCC dry gas components, hydrogen(H_2), nitrogen(N_2), methane(CH_4), ethane(C_2H_6) and ethylene(C_2H_4) in zeolite Y was studied by performing the Grant Canonical Monte Carlo(GCMC) simulations at 298K and 823K and under a pressure range up to 10 MPa. Simulation results were analyzed using the Langmuir model, which presented fitting of dry gas components adsorption to be suggested as the monolayer adsorption. C_2H_4 presented most single adsorption amount, which reached 7.63 mol/kg at 298K under a pressure of 200kPa. Thermodynamic parameters of the Gibbs free energy change, enthalpy change and entropy change were analyzed based on adsorption equilibrium constant obtained from the GCMC simulations. The results suggested that it was more favorable for C_2H_4 to be adsorbed in zeolite Y. Adsorption molecules were in ordered arrangement in the zeolite, and C_2H_4 exhibited a more orderly arrangement than other components. Additionally, a competition in the adsorption of a mixture of dry gas components was found, and supercages were the priority adsorption space. The competition was favorable to CH_4 and C_2H_6, and the competitive power was affected by temperature.
基金Project(2010AA065201)supported by the High Technology Research and Development Program of ChinaProject(2013zzts038)supported by the Fundamental Research Funds for the Central Universities of ChinaProject(ZB2011CBBCe1)supported by the Major Program for Aluminum Corporation of China Limited,China
文摘Numerical simulations of gas–liquid two-phase flow and alumina transport process in an aluminum reduction cell were conducted to investigate the effects of anode configurations on the bath flow, gas volume fraction and alumina content distributions. An Euler–Euler two-fluid model was employed coupled with a species transport equation for alumina content. Three different anode configurations such as anode without a slot, anode with a longitudinal slot and anode with a transversal slot were studied in the simulation. The simulation results clearly show that the slots can reduce the bath velocity and promote the releasing of the anode gas, but can not contribute to the uniformity of the alumina content. Comparisons of the effects between the longitudinal and transversal slots indicate that the longitudinal slot is better in terms of gas–liquid flow but is disadvantageous for alumina mixing and transport process due to a decrease of anode gas under the anode bottom surface. It is demonstrated from the simulations that the mixing and transfer characteristics of alumina are controlled to great extent by the anode gas forces while the electromagnetic forces(EMFs) play the second role.
基金the support provided by the Iranian Research Organization for Scientific and Technology(IROST)in conducting this research。
文摘Gas release and its dispersion is a major concern in chemical industries.In order to manage and mitigate the risk of gas dispersion and its consequences,it is necessary to predict gas dispersion behavior and its concentration at various locations upon emission.Therefore,models and commercial packages such as Phast and ALOHA have been developed.Computational fluid dynamics(CFD)can be a useful tool to simulate gas dispersion in complex areas and conditions.The validation of the models requires the employment of the experimental data from filed and wind tunnel experiments.It appears that the use of the experimental data to validate the CFD method that only includes certain monitor points and not the entire domain can lead to unreliable results for the intended areas of concern.In this work,some of the trials of the Kit Fox field experiment,which provided a wide-range database for gas dispersion,were simulated by CFD.Various scenarios were considered with different mesh sizes,physical conditions,and types of release.The results of the simulations were surveyed in the whole domain.The data matching each scenario was varied by the influence of the dominant displacement force(wind or diffusivity).Furthermore,the statistical parameters suggested for the heavy gas dispersion showed a dependency on the lower band of gas concentration.Therefore,they should be used with precaution.Finally,the results and computation cost of the simulation could be affected by the chosen scenario,the location of the intended points,and the release type.
文摘A three-dimensional mathematical model,based on differential balances of mass and momentum,hasbeen developed to describe the two-phase flow of gas and liquid through the dropping zone of the blast fur-nace.Agreement between observed and calculated values verifies the validity of this model.On the basis of this model,various parameters for the surrounding of the dry zone of Blast FurnaceNo.I-BF of the Beijing Iron and Steel Company have been computed,from which a diagram for demar-cation of fluidization of coke and flooding of slag has been proposed.
文摘Simulation has proven to be an effective tool for analyzing pipeline network systems （PNS） in order to determine the design and operational variables which are essential for evaluating the performance of the system. This paper discusses the use of simulation for performance analysis of transmission PNS. A simulation model was developed for determining flow and pressure variables for different configuration of PNS. The mathematical formulation for the simulation model was derived based on the principles of energy conservation, mass balance, and compressor characteristics. For the determination of the pressure and flow variables, solution procedure was developed based on iterative Newton Raphson scheme and implemented using visual C＋＋6. Evaluations of the simulation model with the existing pipeline network system showed that the model enabled to determine the operational variables with less than ten iterations. The performances of the compressor working in the pipeline network system xvhich includes energy consumption, compression ratio and discharge pressure were evaluated to meet pressure requirements ranging from 4000-5000 kPa at various speed. Results of the analyses from the simulation indicated that the model could be used for performance analysis to assist decisions regarding the design and optimal operations of transmission PNS.
基金the joint financial support from the National Natural Science Foundation of China and Baowu Group Co.,Ltd.(Grant No.U1660205)the Fundamental Research Funds for the Central Universities(Grant No.N2007001).
文摘The high melting point element W and the rare earth element Ce were added to 18Cr-Mo(444-type)ferritic stainless steel to improve its high-temperature oxidation resistance in exhaust gas.A simulated exhaust gas was filled in the simultaneous thermal analyzer to simulate the service environment,and the oxidation behavior in high-temperature exhaust gas environment of 444-type ferritic stainless steel alloyed with W and Ce was investigated.The oxide structure and composition formed in this process were analyzed and characterized by scanning electron microscopy/energy-dispersive spectroscopy and electron probe analysis,and the mechanism of W and Ce in the oxidation process was revealed.The results show that 18Cr-Mo ferritic stainless steel containing W and Ce has better oxidation resistance in high-temperature exhaust gas.The element W can promote the precipitation of Laves phase at the matrix/interface,inhibit the interface diffusion of oxidizing elements and prevent the inward growth of the oxide film.The element Ce can suppress the volume of SiO_(2)at the oxide film/interface,reducing the breakaway oxidation caused by cracking of the oxide film.The CeO_(2)provides nucleation sites for oxide particles,promoting the healing of cracks and voids within the oxide film.
基金supported by the National Natural Science Foundation of China (Nos.51304072,51574112 and 51404100)the Excellent Youth Foundation of Henan Scientific Committee (No.164100510013)+2 种基金the Key Scientific Research Project of Colleges and Universities of Henan Province (No.15A440010)the Chinese Ministry of Education Science and Technology Research Project (No.213022A)the Doctoral Foundation of Henan Polytechnic University (No.B2013-007)
文摘A gas–solid coupling model involving coal seam deformation,gas diffusion and seepage,gas adsorption and desorption was built to study the gas transport rule under the effect of protective coal seam mining.The research results indicate:(1) The depressurization effect changes the stress state of an overlying coal seam and causes its permeability to increase,thus gas in the protected coal seam will be desorbed and transported under the effect of a gas pressure gradient,which will cause a decrease in gas pressure.(2) Gas pressure can be further decreased by setting out gas extraction boreholes in the overlying coal seam,which can effectively reduce the coal and gas outburst risk.The research is of important engineering significance for studying the gas transport rule in protected coal seam and providing important reference for controlling coal and gas outbursts in deep mining in China.
基金supported by the Hi-Tech Research and Development Program (863) of China (No. 2012AA06A116)
文摘The influence of CO2 content and presence of SO2 on the sequestration of CO2 by municipal solid waste incinerator （MSWI） fly ash was studied by investigating the carbonation reaction of MSWI fly ash with different combinations of simulated flue gas. The reaction between fly ash and 100% CO2 was relatively fast; the uptake of CO2 reached 87 g CO2/kg ash, and the sequestered CO2 could be entirely released at high temperatures. When CO2 content was reduced to 12%, the reaction rate decreased; the uptake fell to 41 g CO2/kg ash, and 70.7% of the sequestered CO2 could be released. With 12% CO2 in the presence of SO2, the reaction rate significantly decreased; the uptake was just 17 g CO2/kg ash, and only 52.9% of the sequestered CO2 could be released. SO2 in the simulated gas restricted the ability of fly ash to sequester CO2 because it blocked the pores of the ash.
基金supported by the National Natural Science Foundation of China(Grant nos.41772108 and 41472121)
文摘To understand the influence of the diagenetic water medium on the isotopic compositions of thermogenic coalbed gas,both hydrous and anhydrous closed-system pyrolyses were performed at temperatures of 250°C to 650°C on an herbaceous marsh peat.Compared to the results of anhydrous pyrolysis,the hydrocarbon gases generated from hydrous pyrolyses have very different hydrogen isotopic compositions.However,the carbon isotopic compositions of the hydrocarbon gases became only slightly heavier in hydrous pyrolysis,compared to that from anhydrous pyrolysis.With the progress of thermal evolution from peat to a more advanced thermal maturity of vitrinite reflectance values(Ro)of 5.5%during the pyrolysis,the difference in the averageδD value increased from 52‰to 64‰between the hydrous pyrolysis with saltwater and anhydrous pyrolysis and increased from 18‰to 29‰between the hydrous pyrolysis with freshwater and anhydrous pyrolysis,respectively.The difference in the averageδ^(13)C value was only 1‰–2‰between the hydrous and anhydrous pyrolysis.The relationships between theδD values of the generated hydrocarbon gases and Ro values as well as amongδD values of the hydrocarbon gas species are established.The close relationships among these parameters suggest that the water medium had a significant effect on the hydrogen isotopic composition and a minimal effect on the carbon isotopic composition of the hydrocarbon gases.The results of these pyrolyses may provide information for the understanding of the genesis of coalbed gas from herbaceous marsh material with the participation of different diagenetic water media.
基金supported by the National Natural Science Foundation of China (No.51131008)
文摘The corrosion behaviors of pure titanium and its weldment welded by tungsten inert gas （TIG） welding in simulated desulfurized flue gas condensates in thermal power plant chimney were investigated using potentiodynamic polarization, electrochemical impedance spectroscopy （EIS） and immersion tests. The effects of heat input and shielding gases on the corrosion behavior of the welded titanium were also studied. Grain coarsening and Widmanst^itten structure were found in both the fusion zone and the heat-affected zone. The welded titanium exhibited active-passive behavior in the simulated condensates. Both the polarization curves and EIS measurements confirmed that TIG welding process with different parameters had few effects on the corrosion behavior. It was proved that the microstructure changes were not the key material factors affecting the corrosion behavior of pure titanium under the test conditions, while the oxide film had remarkable effect on improving the corrosion resistance.
基金supported by the National Natural Science Foundation of China (No. 51234007, No. 51490654, No. 51504276, and No. 51504277)Program for Changjiang Scholars and Innovative Research Team in University (IRT1294)+3 种基金the Natural Science Foundation of Shandong Province (ZR2014EL016, ZR2014EEP018)China Postdoctoral Science Foundation (No. 2014M551989 and No. 2015T80762)the Major Programs of Ministry of Education of China (No. 311009)Introducing Talents of Discipline to Universities (B08028)
文摘In order to investigate the influence on shale gas well productivity caused by gas transport in nanometer- size pores, a mathematical model of multi-stage fractured horizontal wells in shale gas reservoirs is built, which considers the influence of viscous flow, Knudsen diffusion, surface diffusion, and adsorption layer thickness. A dis- crete-fracture model is used to simplify the fracture mod- cling, and a finite element method is applied to solve the model. The numerical simulation results indicate that with a decrease in the intrinsic matrix permeability, Knudsen diffusion and surface diffusion contributions to production become large and cannot be ignored. The existence of an adsorption layer on the nanopore surfaces reduces the effective pore radius and the effective porosity, resulting in low production from fractured horizontal wells. With a decrease in the pore radius, considering the adsorption layer, the production reduction rate increases. When the pore radius is less than 10 nm, because of the combined impacts of Knudsen diffusion, surface diffusion, and adsorption layers, the production of multi-stage fractured horizontal wells increases with a decrease in the pore pressure. When the pore pressure is lower than 30 MPa, the rate of production increase becomes larger with a decrease in pore pressure.
基金The financial support from the Natural Science Foundation of China (No. 21976013)
文摘By combining 5,10,15,20-tetra(4-chlorine)phenylporphyrin(TClPP)andα-Keggin polyoxometalate H_(5)PV_(2)Mo_(10)O_(40)(H 5 PVMo)via a simple ion-exchange method,an organic-inorganic hybrid material[C_(44)H_(28)N_(4)Cl_(4)]_(1.5)[H_(2)PMo_(10)V_(2)O_(40)]·2C_(2)H_(6)O(H_(2 )TClPP-H_(2) PVMo)was prepared and thoroughly characterized by a variety of techniques.The homogeneous photocatalytic degradation of 2-chloroethyl ethyl sulfide(CEES)(5μL)by H_(2) TClPP-H_(2) PVMo(1×10^(−6)mol/L)was studied in methanol and methanol-water mixed solvent(v/v=1:1),in which the degradation rate of CEES reached 99.52%and 99.14%,respectively.The reaction followed first-order reaction kinetics,and the half-life and kinetic constant in methanol and the mixed solvent were respectively 33.0min,−0.021 min−1 and 15.7min,−0.043 min−1.Mechanism analysis indicated that under visible light irradiation in the air,CEES was degraded via oxidation and alcoholysis/hydrolysis in methanol and the mixed solvent.O_(2)·−and ^(1)O_(2) generated by H_(2) TClPP-H_(2) PVMo selectively oxidized CEES into a nontoxic sulfoxide.Singlet oxygen capture experiments showed that H_(2) TClPP-H_(2) PVMo(φ=0.73)had a higher quantum yield of singlet oxygen than TClPP(φ=0.35)under an air atmosphere and visible light irradiation.
基金Supported by the National Natural Science Foundation of China(E041003)the Fundamental Research Funds for the Central Universities(FRF-TP-15-105A1)the Postdoctoral Science Foundation of China(2015M580049)
文摘In order to present a retrospective analysis of exposition accidents using input data from investigation processes,data from a specific accident was examined,in which we analyzed possible involved gas species（ liquefied petroleum gas; nature gas） and computed their concentrations and distributions based on the interactions between the structures and the effects of the explosion. In this study,5 scenarios were created to analyze the impact effect. Moreover,a coupling algorithm was put into practice,with a practical outflow boundary and joint strength are applied. Finally,the damage effects of each scenario were simulated. Our experimental results showed significant differences in the 5 scenarios concerning the damage effects on the building structures. The results from scenario 3 agree with the accident characteristics,demonstrating the effectiveness of our proposed modeling method. Our proposed method reflects gas properties,species and the concentration and distribution,and the simulated results validates the root cause,process,and consequences of accidental explosions. Furthermore,this method describes the evolution process of explosions in different building structures. Significantly,our model demonstrates the quantatative explosion effect of factors like gas species,gas volumes,and distributions of gases on explosion results. In this study,a feasible,effective,and quantitative method for structure safety is defined,which is helpful to accelerate the development of safer site regulations.
基金Supported by the National Science Fund for Distinguished Young Scholar(51525604)111 project B16038
文摘As one of the main reasons causing leakage heat load in a refrigerator,mass and heat transfer through refrigerator door seal is of great importance to be studied.In this paper,a model is presented for numerical simulation of mass and heat transfer process through refrigerator door seal,and an experiment apparatus is designed and set up as well for comparison.A two-dimensional model and tracer gas method are used in simulation and experiment,respectively.It can be found that the relative deviations of air infiltration rate between the simulated results and experimental results were less than 1%,and the temperature difference errors at two special points of the door seal were less than 2.03℃.In conclusion,the simulated results are in good agreement with the experimental results.This paper initially sets up a model that can accurately simulate the heat and mass transfer through the refrigerator door seal,and the model can be used in refrigerator door seal optimization research in the follow-up study.
