Anchoring molecular cocatalysts on semiconductors has been recognized as a general strategy to boost the charge separation efficiency required for efficient photocatalysis.However,the effect of molecular cocatalysts o...Anchoring molecular cocatalysts on semiconductors has been recognized as a general strategy to boost the charge separation efficiency required for efficient photocatalysis.However,the effect of molecular cocatalysts on energy funneling(i.e.,directional energy transfer)inside semiconductor photocatalysts has not been demonstrated yet.Here we prepared CdS nanorods with both thin and thick rods and anchored the conjugated molecules 2‐mercaptobenzimidazole(MBI)and cobalt molecular catalysts(MCoA)sequentially onto the surface of nanorods.Transient absorption measurements revealed that MBI molecules facilitated energy funneling from thin to thick rods by the electronic coupling between thin and thick nanorods,which is essentially a light‐harvesting antenna approach to enhance the charge generation efficiency in the reaction center(here the thick rods).Moreover,MBI and MCoA molecules selectively extracted photogenerated holes and electrons of CdS nanorods rapidly,leading to efficient charge separation.Consequently,CdS/MBI/MCoA displayed 15 times enhanced photocatalytic H_(2) evolution(1.65 mL)than pure CdS(0.11 mL)over 3 h of illumination.The amount of H_(2) evolution reached 60 mL over 48 h of illumination with a high turnover number of 26294 and an apparent quantum efficiency of 71%at 420 nm.This study demonstrates a novel design principle for next‐generation photocatalysts.展开更多
Devices operating with excitons exhibit promising prospects for overcoming the dilemma of response time and integration in electron or/and photon based system.Strain engineering has emerged as an effective approach to...Devices operating with excitons exhibit promising prospects for overcoming the dilemma of response time and integration in electron or/and photon based system.Strain engineering has emerged as an effective approach to modulate exciton transport and dynamics,with bubbles induced biaxial strain attracting particular attention for nanoscopic manipulation of exciton flux.However,the unintentionally produced bubbles are completely stochastic in dimensions and morphology,thereby the active and controllable bubbles formation still remain challenge,which is imperative for modulating excitonic and opt-electric performance on demand.Here,we propose the annealing-driven reassembly of micro-bubbles to create the controllable artificial potential landscapes in atomically thin semiconductor,facilitating the active manipulation of exciton flux at room temperature.Correlating micro PL mappings with strain maps calculated from AFM topography and strain modeling,demonstrates the efficient localized exciton emission and exciton funneling in spectral.The imaging of exciton transport and emission provide more intuitive evidence in spatial that excitons flow towards bubble center from excitation location driven by the conventional diffusion and strain gradient induced drift effect,supported by drift-diffusion model.These findings demonstrate the great potential to control exciton dynamics on-demand through annealing driven reassembled micro-bubbles,and lay the foundation for promising applications in high-performance sensing,energy harvesting,and quantum information processing.展开更多
Due to the characteristics of the underwater acoustic channel, such as long propagation delay and low available bandwidth, the media access control (MAC) protocol designed for underwater acoustic sensor networks (UWAS...Due to the characteristics of the underwater acoustic channel, such as long propagation delay and low available bandwidth, the media access control (MAC) protocol designed for underwater acoustic sensor networks (UWASNs) is quite different from that for terrestrial wireless sensor networks. In this paper, we propose a MAC protocol for the UWASNs, named the funneling MAC (FMAC-U), which is a contention-based MAC protocol with a three-way handshake. The FMAC-U protocol uses an improved three-way handshake mechanism and code division multiple access (CDMA) based technology for request-to-send (RTS) signals transmitting to the sink in order that the sink can receive packets from multiple neighbors in a fixed order during each round of handshakes. The mechanism reduces the packet collisions and alleviates the funneling effect, especially alleviating the choke point of the UWASNs. Simulation results show that the proposed FMAC-U protocol achieves higher throughput, smaller packet drop ratio, lower end-to-end delay, and lower overhead of the control packet compared to the existing MAC protocols for UWASNs.展开更多
Engineering lattice models with tailored inter-site tunnelings and onsite energies could synthesize essentially arbitrary Riemannian surfaces with highly tunable local curvatures.Here,we point out that discrete synthe...Engineering lattice models with tailored inter-site tunnelings and onsite energies could synthesize essentially arbitrary Riemannian surfaces with highly tunable local curvatures.Here,we point out that discrete synthetic Poincaréhalf-planes and Poincarédisks,which are created by lattices in flat planes,support infinitely degenerate eigenstates for any nonzero eigenenergies.Such Efimov-like states exhibit a discrete scaling symmetry and imply an unprecedented apparatus for studying quantum anomaly using hyperbolic surfaces.Furthermore,all eigenstates are exponentially localized in the hyperbolic coordinates,signifying the first example of quantum funneling effects in Hermitian systems.As such,any initial wave packet travels towards the edge of the Poincaréhalf-plane or its equivalent on the Poincarédisk,delivering an efficient scheme to harvest light and atoms in two dimensions.Our findings unfold the intriguing properties of hyperbolic spaces and suggest that Efimov states may be regarded as a projection from a curved space with an extra dimension.展开更多
Man-made superheavy elements(SHE)are produced as energetic recoils in complete-fusion reactions and need to be thermalized in a gas-filled chamber for chemical studies.The ever-shorter half-lives and decreasing produc...Man-made superheavy elements(SHE)are produced as energetic recoils in complete-fusion reactions and need to be thermalized in a gas-filled chamber for chemical studies.The ever-shorter half-lives and decreasing production rates of the elements beyond Fl(atomic number Z=114)-the heaviest element chemically studied today-require the development of novel techniques for quantitative thermalization and fast extraction efficiency.The Universal high-density gas stopping Cell(UniCell),currently under construction,was proposed to achieve this.Within this work,we propose an Ion Transfer by Gas Flow(ITGF)device,which serves as a UniCell ejector to interface with a gas chromatography detector array for chemical studies.Detailed parameter optimizations,using gas dynamics and Monte Carlo ion-trajectory simulations,promise fast(within a few ms)and highly efficient(up to 100%)ion extraction across a wide mass range.These ions can then be transmitted quantitatively through the ITGF into the high-pressure environment needed for further chemical studies.展开更多
This study examines the Carolina Bays and Nebraska Rainwater Basins,using high-resolution LiDAR elevation models to analyze their unique shapes.The research reveals that well-preserved Bays exhibit precise elliptical ...This study examines the Carolina Bays and Nebraska Rainwater Basins,using high-resolution LiDAR elevation models to analyze their unique shapes.The research reveals that well-preserved Bays exhibit precise elliptical geometry,distinguishing them from various oriented lakes they are often compared to.While the timing of their formation is discussed,the primary goal of this paper is to establish a repeatable method for quantifying the elliptical nature of these dominant geomorphic landforms.By applying the least squares method to points selected along the perimeters of these extraordinary basins,the study confirms their elliptical geometry with an error margin of less than 3%.This rigorous mathematical approach sets a high standard for any hypothesis attempting to explain the origin of these depressions using natural environmental conditions.Notably,the long axes of these elliptical basins converge near the Great Lakes region,and since ellipses can be described as conic sections,this finding supports the plausibility of a cosmic impact origin.The study suggests that these basins may be secondary impact features formed during a past glacial cycle of the Laurentide Ice Sheet.This research establishes a strong mathematical foundation to support future studies on the possible impact origin of the Carolina Bays and Nebraska Rainwater Basins.展开更多
In this paper, the multi-agent systems(MASs) typically with heterogeneous unknown nonlinearities and nonidentical unknown control coefficients are studied. Although the model information of MASs is coarse, the leader-...In this paper, the multi-agent systems(MASs) typically with heterogeneous unknown nonlinearities and nonidentical unknown control coefficients are studied. Although the model information of MASs is coarse, the leader-following consensus is still pursued, with a prescribed performance and zero consensus errors. Leveraging a powerful funnel control strategy, a fully distributed and completely relative-state-dependent protocol is designed. Distinctively, the time-varying function characterizing the performance boundary is introduced, not only to construct the funnel gains but also as an indispensable part of the protocol,enhancing the control ability and enabling the consensus errors to converge to zero(rather than a residual set). Remark that when control directions are unknown, coexisting with inherent system nonlinearities, it is essential to incorporate an additional compensation mechanism while imposing a hierarchical structure of communication topology for the control design and analysis. Simulation examples are given to illustrate the effectiveness of the theoretical results.展开更多
Stemflow of xerophytic shrubs represents a significant component of water replenishment to the soil-root system and influences water utilization of plant roots at the stand scale,especially in water-scarce semi-arid e...Stemflow of xerophytic shrubs represents a significant component of water replenishment to the soil-root system and influences water utilization of plant roots at the stand scale,especially in water-scarce semi-arid ecosystems.The stemflow of two semi-arid shrubs(Caragana korshinskii and Hippophae rhamnoides)and its effect on soil moisture enhancement were evaluated during the growing season of 2011 in the semi-arid loess region of China.The results indicated that stemflow averaged 12.3%and 8.4%of the bulk precipitation for C.korshinskii and H.rhamnoides,respectively.Individual stemflow increased in a linear function with increasing rainfall depth.The relationship between funneling ratios and rainfall suggested that there existed a rainfall depth threshold of 11 mm for both C.korshinskii and H.rhamnoides.Averaged funneling ratios were 156.6±57.1 and49.5±30.8 for C.korshinskii and H.rhamnoides,respectively,indicating that the canopy architecture of the two shrubs was an effective funnel to channel stemflow to the root area,and C.korshinskii showed a greater potential to use stemflow water in the semi-arid conditions.For individual rainfall events,the wetting front depths were approximately 2 times deeper in the rooting zone around the stems than in the bare area outside canopy for both C.korshinskii and H.rhamnoides.Correspondingly,soil water content was also significantly higher in the root area around the shrub stem than in the area outside the shrub canopy.This confirms that shrub stemflow conserved in the deep soil layers may be an available moisture source for plant growth under semi-arid conditions.展开更多
Ectoparasites and other invertebrates are known to play a role in bird behavior and in evolutionary adaptations such as preening and foraging strategies. We conducted an exploratory study by macro- and microscopically...Ectoparasites and other invertebrates are known to play a role in bird behavior and in evolutionary adaptations such as preening and foraging strategies. We conducted an exploratory study by macro- and microscopically evaluating the nests of Hair-crested Drongos(Dicrurus hottentottus) at Dongzhai National Nature Reserve, Henan Province, China in 2011 to determine if there was a presence of invertebrates. We developed a modified funneling technique to collect invertebrate samples and reduce contamination from outside sources in a field setting. We found several species of ectoparasites(lice and ticks) and other invertebrates(springtails and rove beetles) within the nests. Our findings warrant further investigation as to whether or not the presence of invertebrates in the nests of Hair-crested Drongos plays a role in the adaptation of the unique nest dismantling behavior exhibited by this species.展开更多
Due to long-term over-exploitation of groundwater in Beijing Municipality, regional groundwater funnels have formed and land subsidence has been induced. By combining a groundwater monitoring network, GPS monitor- ing...Due to long-term over-exploitation of groundwater in Beijing Municipality, regional groundwater funnels have formed and land subsidence has been induced. By combining a groundwater monitoring network, GPS monitor- ing network data, radar satellite SAR data, GIS and other new technologies, a coupled process model based on the dy- namic variation of groundwater and the deformation response of land subsidence has been established. The dynamic variation of groundwater fimnels and the land subsidence response process were analyzed systematically in Beijing. Study results indicate that current groundwater funnel areas are distributed mainly in the southwest of Shunyi District, the northeast of Chaoyang District and the northwest of Tongzhou District, with an average decline rate of groundwa- ter level of 2.66 rn/yr and a maximum of 3.82 m/yr in the center of the funnels. Seasonal and interannual differences exist in the response model of land subsidence to groundwater funnels with uneven spatial and temporal distribution, where the maximum land subsidence rate was about --41.08 mm/yr and the area with a subsidence rate greater than 30 mm/yr was about 1637.29 km2. Although a consistency was revealed to exist between a groundwater funnel and the spatial distribution characteristics of the corresponding land subsidence funnel, this consistency was not perfect. The results showed that the response model of land subsidence to the dynamic variation of groundwater was more revealing when combining conventional technologies with InSAR, GIS, GPS, providing a new strategy for environmental and hydrogeological research and a scientific basis for regional land subsidence control.展开更多
The recycled cathode ray tube(CRT)funnel glass was used as replacement of magnetite sand in the concrete,and its mass replacement rates were 0,20%,40%and 60%,respectively.The flowability,apparent density and mechanica...The recycled cathode ray tube(CRT)funnel glass was used as replacement of magnetite sand in the concrete,and its mass replacement rates were 0,20%,40%and 60%,respectively.The flowability,apparent density and mechanical properties of the radiation shielding concrete were investigated,while itsγ-ray radiation shielding parameters such as linear and mass attenuation coefficients(μandμm,respectively),thickness values of half-value layer(hHVL)and tenth-value layer(hTVL)were obtained by theoretical calculation,experiment and Monte.Carlo N-Particle(MCNP)simulation code.The experimental results show that the flowability of the concrete increases significantly,whilst its apparent density,compressive strength and static elastic modulus decrease slightly.The calculated,simulated and experimentalμm,μ,hHVL and hTVL values of all concrete samples are very consistent at the sameγ-ray photon energy,and it is feasible to use MCNP code to simulateγ-ray radiation shielding parameters of materials.The calculated results show that in a wide range ofγ-ray photon energy,theμm value of the concrete with CRT funnel glass replacing magnetite sand is improved effectively,and its radiation shielding performances are the same as those of the control concrete(M.1).By comprehensively comparing the flowability,mechanical properties andγ-ray radiation shielding properties,the concrete samples with 20%.40%funnel glass as fine aggregate have good performances.展开更多
文摘Anchoring molecular cocatalysts on semiconductors has been recognized as a general strategy to boost the charge separation efficiency required for efficient photocatalysis.However,the effect of molecular cocatalysts on energy funneling(i.e.,directional energy transfer)inside semiconductor photocatalysts has not been demonstrated yet.Here we prepared CdS nanorods with both thin and thick rods and anchored the conjugated molecules 2‐mercaptobenzimidazole(MBI)and cobalt molecular catalysts(MCoA)sequentially onto the surface of nanorods.Transient absorption measurements revealed that MBI molecules facilitated energy funneling from thin to thick rods by the electronic coupling between thin and thick nanorods,which is essentially a light‐harvesting antenna approach to enhance the charge generation efficiency in the reaction center(here the thick rods).Moreover,MBI and MCoA molecules selectively extracted photogenerated holes and electrons of CdS nanorods rapidly,leading to efficient charge separation.Consequently,CdS/MBI/MCoA displayed 15 times enhanced photocatalytic H_(2) evolution(1.65 mL)than pure CdS(0.11 mL)over 3 h of illumination.The amount of H_(2) evolution reached 60 mL over 48 h of illumination with a high turnover number of 26294 and an apparent quantum efficiency of 71%at 420 nm.This study demonstrates a novel design principle for next‐generation photocatalysts.
基金supported by the National Science Foundation of China(Grant Nos.12027807,12104241,62225501)Fundamental Research Funds for the Central Universities(Grant No.075-63253216).
文摘Devices operating with excitons exhibit promising prospects for overcoming the dilemma of response time and integration in electron or/and photon based system.Strain engineering has emerged as an effective approach to modulate exciton transport and dynamics,with bubbles induced biaxial strain attracting particular attention for nanoscopic manipulation of exciton flux.However,the unintentionally produced bubbles are completely stochastic in dimensions and morphology,thereby the active and controllable bubbles formation still remain challenge,which is imperative for modulating excitonic and opt-electric performance on demand.Here,we propose the annealing-driven reassembly of micro-bubbles to create the controllable artificial potential landscapes in atomically thin semiconductor,facilitating the active manipulation of exciton flux at room temperature.Correlating micro PL mappings with strain maps calculated from AFM topography and strain modeling,demonstrates the efficient localized exciton emission and exciton funneling in spectral.The imaging of exciton transport and emission provide more intuitive evidence in spatial that excitons flow towards bubble center from excitation location driven by the conventional diffusion and strain gradient induced drift effect,supported by drift-diffusion model.These findings demonstrate the great potential to control exciton dynamics on-demand through annealing driven reassembled micro-bubbles,and lay the foundation for promising applications in high-performance sensing,energy harvesting,and quantum information processing.
基金(No. 2009AA093601-3) supported by the National High-Tech R & D Program (863) of China
文摘Due to the characteristics of the underwater acoustic channel, such as long propagation delay and low available bandwidth, the media access control (MAC) protocol designed for underwater acoustic sensor networks (UWASNs) is quite different from that for terrestrial wireless sensor networks. In this paper, we propose a MAC protocol for the UWASNs, named the funneling MAC (FMAC-U), which is a contention-based MAC protocol with a three-way handshake. The FMAC-U protocol uses an improved three-way handshake mechanism and code division multiple access (CDMA) based technology for request-to-send (RTS) signals transmitting to the sink in order that the sink can receive packets from multiple neighbors in a fixed order during each round of handshakes. The mechanism reduces the packet collisions and alleviates the funneling effect, especially alleviating the choke point of the UWASNs. Simulation results show that the proposed FMAC-U protocol achieves higher throughput, smaller packet drop ratio, lower end-to-end delay, and lower overhead of the control packet compared to the existing MAC protocols for UWASNs.
基金supported by the National Natural Science Foundation of China(11804268)the National Key R&D Program of China(2018YFA0307601)。
文摘Engineering lattice models with tailored inter-site tunnelings and onsite energies could synthesize essentially arbitrary Riemannian surfaces with highly tunable local curvatures.Here,we point out that discrete synthetic Poincaréhalf-planes and Poincarédisks,which are created by lattices in flat planes,support infinitely degenerate eigenstates for any nonzero eigenenergies.Such Efimov-like states exhibit a discrete scaling symmetry and imply an unprecedented apparatus for studying quantum anomaly using hyperbolic surfaces.Furthermore,all eigenstates are exponentially localized in the hyperbolic coordinates,signifying the first example of quantum funneling effects in Hermitian systems.As such,any initial wave packet travels towards the edge of the Poincaréhalf-plane or its equivalent on the Poincarédisk,delivering an efficient scheme to harvest light and atoms in two dimensions.Our findings unfold the intriguing properties of hyperbolic spaces and suggest that Efimov states may be regarded as a projection from a curved space with an extra dimension.
基金This work was supported by the German BMBF (No.05P21UMFN2)
文摘Man-made superheavy elements(SHE)are produced as energetic recoils in complete-fusion reactions and need to be thermalized in a gas-filled chamber for chemical studies.The ever-shorter half-lives and decreasing production rates of the elements beyond Fl(atomic number Z=114)-the heaviest element chemically studied today-require the development of novel techniques for quantitative thermalization and fast extraction efficiency.The Universal high-density gas stopping Cell(UniCell),currently under construction,was proposed to achieve this.Within this work,we propose an Ion Transfer by Gas Flow(ITGF)device,which serves as a UniCell ejector to interface with a gas chromatography detector array for chemical studies.Detailed parameter optimizations,using gas dynamics and Monte Carlo ion-trajectory simulations,promise fast(within a few ms)and highly efficient(up to 100%)ion extraction across a wide mass range.These ions can then be transmitted quantitatively through the ITGF into the high-pressure environment needed for further chemical studies.
文摘This study examines the Carolina Bays and Nebraska Rainwater Basins,using high-resolution LiDAR elevation models to analyze their unique shapes.The research reveals that well-preserved Bays exhibit precise elliptical geometry,distinguishing them from various oriented lakes they are often compared to.While the timing of their formation is discussed,the primary goal of this paper is to establish a repeatable method for quantifying the elliptical nature of these dominant geomorphic landforms.By applying the least squares method to points selected along the perimeters of these extraordinary basins,the study confirms their elliptical geometry with an error margin of less than 3%.This rigorous mathematical approach sets a high standard for any hypothesis attempting to explain the origin of these depressions using natural environmental conditions.Notably,the long axes of these elliptical basins converge near the Great Lakes region,and since ellipses can be described as conic sections,this finding supports the plausibility of a cosmic impact origin.The study suggests that these basins may be secondary impact features formed during a past glacial cycle of the Laurentide Ice Sheet.This research establishes a strong mathematical foundation to support future studies on the possible impact origin of the Carolina Bays and Nebraska Rainwater Basins.
基金supported in part by the National Natural Science Foundation of China(61821004,62033007)Major Fundamental Research Program of Shandong Province(ZR2023ZD37)
文摘In this paper, the multi-agent systems(MASs) typically with heterogeneous unknown nonlinearities and nonidentical unknown control coefficients are studied. Although the model information of MASs is coarse, the leader-following consensus is still pursued, with a prescribed performance and zero consensus errors. Leveraging a powerful funnel control strategy, a fully distributed and completely relative-state-dependent protocol is designed. Distinctively, the time-varying function characterizing the performance boundary is introduced, not only to construct the funnel gains but also as an indispensable part of the protocol,enhancing the control ability and enabling the consensus errors to converge to zero(rather than a residual set). Remark that when control directions are unknown, coexisting with inherent system nonlinearities, it is essential to incorporate an additional compensation mechanism while imposing a hierarchical structure of communication topology for the control design and analysis. Simulation examples are given to illustrate the effectiveness of the theoretical results.
基金supported by the National Natural Science Foundation of China(91025015,51178209)
文摘Stemflow of xerophytic shrubs represents a significant component of water replenishment to the soil-root system and influences water utilization of plant roots at the stand scale,especially in water-scarce semi-arid ecosystems.The stemflow of two semi-arid shrubs(Caragana korshinskii and Hippophae rhamnoides)and its effect on soil moisture enhancement were evaluated during the growing season of 2011 in the semi-arid loess region of China.The results indicated that stemflow averaged 12.3%and 8.4%of the bulk precipitation for C.korshinskii and H.rhamnoides,respectively.Individual stemflow increased in a linear function with increasing rainfall depth.The relationship between funneling ratios and rainfall suggested that there existed a rainfall depth threshold of 11 mm for both C.korshinskii and H.rhamnoides.Averaged funneling ratios were 156.6±57.1 and49.5±30.8 for C.korshinskii and H.rhamnoides,respectively,indicating that the canopy architecture of the two shrubs was an effective funnel to channel stemflow to the root area,and C.korshinskii showed a greater potential to use stemflow water in the semi-arid conditions.For individual rainfall events,the wetting front depths were approximately 2 times deeper in the rooting zone around the stems than in the bare area outside canopy for both C.korshinskii and H.rhamnoides.Correspondingly,soil water content was also significantly higher in the root area around the shrub stem than in the area outside the shrub canopy.This confirms that shrub stemflow conserved in the deep soil layers may be an available moisture source for plant growth under semi-arid conditions.
基金support by Dongzhai National Nature Reserve for conducting this studyprovided by National Science Foundation East Asia Pacific Summer Institute(EAPSI)+1 种基金Chinese Ministry of Science and Technology,and China Science and Technology Exchange Centerprovided by Alabama A&M University and Beijing Normal University
文摘Ectoparasites and other invertebrates are known to play a role in bird behavior and in evolutionary adaptations such as preening and foraging strategies. We conducted an exploratory study by macro- and microscopically evaluating the nests of Hair-crested Drongos(Dicrurus hottentottus) at Dongzhai National Nature Reserve, Henan Province, China in 2011 to determine if there was a presence of invertebrates. We developed a modified funneling technique to collect invertebrate samples and reduce contamination from outside sources in a field setting. We found several species of ectoparasites(lice and ticks) and other invertebrates(springtails and rove beetles) within the nests. Our findings warrant further investigation as to whether or not the presence of invertebrates in the nests of Hair-crested Drongos plays a role in the adaptation of the unique nest dismantling behavior exhibited by this species.
基金Supported by National Natural Science Foundation of China(61403343)Scientific Research Foundation of the Education Department of Zhejiang Province,China(Y201329260)Natural Science Foundation of Zhejiang University of Technology(1301103053408)
基金Under the auspices of Program of International S&T Cooperation(No.2010DFA92400)Non-profit Industry Financial Program of the Ministry of Water Resources(No.200901091)+2 种基金Beijing Municipal Natural Science Foundation(No.8101002)Beijing Municipal Education Commission Plans to Focus Science and Technology Projects(No.KZ201010028030)National Natural Science Foundation of China(No.41130744,41171335)
文摘Due to long-term over-exploitation of groundwater in Beijing Municipality, regional groundwater funnels have formed and land subsidence has been induced. By combining a groundwater monitoring network, GPS monitor- ing network data, radar satellite SAR data, GIS and other new technologies, a coupled process model based on the dy- namic variation of groundwater and the deformation response of land subsidence has been established. The dynamic variation of groundwater fimnels and the land subsidence response process were analyzed systematically in Beijing. Study results indicate that current groundwater funnel areas are distributed mainly in the southwest of Shunyi District, the northeast of Chaoyang District and the northwest of Tongzhou District, with an average decline rate of groundwa- ter level of 2.66 rn/yr and a maximum of 3.82 m/yr in the center of the funnels. Seasonal and interannual differences exist in the response model of land subsidence to groundwater funnels with uneven spatial and temporal distribution, where the maximum land subsidence rate was about --41.08 mm/yr and the area with a subsidence rate greater than 30 mm/yr was about 1637.29 km2. Although a consistency was revealed to exist between a groundwater funnel and the spatial distribution characteristics of the corresponding land subsidence funnel, this consistency was not perfect. The results showed that the response model of land subsidence to the dynamic variation of groundwater was more revealing when combining conventional technologies with InSAR, GIS, GPS, providing a new strategy for environmental and hydrogeological research and a scientific basis for regional land subsidence control.
基金Project(14JJ2083)supported by the Natural Science Foundation of Hunan Province,ChinaProject(2015JC3090)supported by the Science and Technology Department of Hunan Province,China
文摘The recycled cathode ray tube(CRT)funnel glass was used as replacement of magnetite sand in the concrete,and its mass replacement rates were 0,20%,40%and 60%,respectively.The flowability,apparent density and mechanical properties of the radiation shielding concrete were investigated,while itsγ-ray radiation shielding parameters such as linear and mass attenuation coefficients(μandμm,respectively),thickness values of half-value layer(hHVL)and tenth-value layer(hTVL)were obtained by theoretical calculation,experiment and Monte.Carlo N-Particle(MCNP)simulation code.The experimental results show that the flowability of the concrete increases significantly,whilst its apparent density,compressive strength and static elastic modulus decrease slightly.The calculated,simulated and experimentalμm,μ,hHVL and hTVL values of all concrete samples are very consistent at the sameγ-ray photon energy,and it is feasible to use MCNP code to simulateγ-ray radiation shielding parameters of materials.The calculated results show that in a wide range ofγ-ray photon energy,theμm value of the concrete with CRT funnel glass replacing magnetite sand is improved effectively,and its radiation shielding performances are the same as those of the control concrete(M.1).By comprehensively comparing the flowability,mechanical properties andγ-ray radiation shielding properties,the concrete samples with 20%.40%funnel glass as fine aggregate have good performances.
