Integrated CO_(2)capture and utilization(ICCU)technology requires dual functional materials(DFMs)to carry out the process in a single reaction system.The influence of the calcination atmosphere on efficiency of 4%Ru-8...Integrated CO_(2)capture and utilization(ICCU)technology requires dual functional materials(DFMs)to carry out the process in a single reaction system.The influence of the calcination atmosphere on efficiency of 4%Ru-8%Na_(2)CO_(3)-8%CaO/γ-Al_(2)O_(3)DFM is studied.The adsorbent precursors are first co-impregnated onto alumina and calcined in air.Then,Ru precursor is impregnated and four aliquotes are subjected to different calcination protocols:static air in muffle or under different mixtures(10%H_(2)/N_(2),50%H_(2)/N_(2)and N_(2))streams.Samples are characterized by XRD,N_(2)adsorption-desorption,H_(2)chemisorption,TEM,XPS,H_(2)-TPD,H_(2)-TPR,CO_(2)-TPD and TPSR.The catalytic behavior is evaluated,in cycles of CO_(2)adsorption and hydrogenation to CH_(4),and temporal evolution of reactants and products concentrations is analyzed.The calcination atmosphere influences the physicochemical properties and,ultimately,activity of DFMs.Characterization data and catalytic performance discover the acccomodation of Ru nanoparticles disposition and basic sites is mostly influencing the catalytic activity.DFM calcined under N_(2)flow(RuNaCa-N_(2))shows the highest CH_(4)production(449μmol/g at 370℃),because a well-controlled decomposition of precursors which favors the better accomodation of adsorbent and Ru phases,maximizing the specific surface area,the Ru-basic sites interface and the participation of different basic sites in the CO_(2)methanation reaction.Thus,the calcination in a N_(2)flow is revealed as the optimal calcination protocol to achieve highly efficient DFM for integrated CO_(2)adsorption and hydrogenation applications.展开更多
It is difficult to determine the effective reservoir rock compressibility,aquifer volume and water influx of high pressure and ultra-high pressure gas reservoirs,so when the traditional apparent reservoir pressure and...It is difficult to determine the effective reservoir rock compressibility,aquifer volume and water influx of high pressure and ultra-high pressure gas reservoirs,so when the traditional apparent reservoir pressure and cumulative gas production curve extrapolation method and its modified version are used to calculate the initial gas in-place of such gas reservoirs,the calculation accuracy is lower.The material balance equation in the form of power function for such gas reservoirs was established based on Gonzalez method to improve the accuracy and reliability of reserve evaluation.Then,based on 20 high pressure and ultra-high pressure reservoirs that had been developed abroad,the empirical value of the power exponent was defined,and the influences of the depletion degree of apparent reservoir pressure and the degree of reserve recovery on the reliability of reserve calculation were analyzed.Besides,the critical value of the key parameter affecting the reliability of reserve evaluation(depletion degree of apparent reservoir pressure)was determined and compared with the critical value of the two-linear trends.Finally,an example calculation was carried out.And the following research results were obtained.First,the empirical value of the power exponent calculated using the material balance method in the form of power function is 1.02847,with an upper limit of 1.11567.Second,the depletion degree of apparent reservoir pressure corresponding to the inflection point of the classical two-linear trends ranges from 0.14 to 0.38 with an average of 0.23,while that corresponding to the extrapolation point of the second straight line is between 0.23 and 0.50 with an average of 0.33,and the corresponding degree of reserve recovery is in the range of 33%-65%with an average of 45%.Third,the reserves of such high pressure gas reservoirs calculated with this new method has an error rate less than 10%if the depletion degree of apparent reservoir pressure is greater than 0.33.In conclusion,for such high pressure gas reservoirs and the stress-sensitive fractured gas reservoirs,the material balance method in the form of power function proposed in this paper can avoid the uncertainty parameters(e.g.effective reservoir rock compressibility,aquifer volume and water influx)and it is advantageous with simple calculation process,better practicability and small error.展开更多
Calcium ferrite(CF)is recognized as a potential green and efficient functional material because of its advantages of magnetism,electrochemistry,catalysis,and biocompatibility in the fields of materials chemistry,envir...Calcium ferrite(CF)is recognized as a potential green and efficient functional material because of its advantages of magnetism,electrochemistry,catalysis,and biocompatibility in the fields of materials chemistry,environmental engineering,and biomedicine.There-fore,the obtained research results need to be systematically summarized,and new perspectives on CF and its composite materials need to be analyzed.Based on the presented studies of CF and its composite materials,the types and structures of the crystal are summarized.In addition,the current application technologies and theoretical mechanisms with various properties in different fields are elucidated.Moreover,the various preparation methods of CF and its composite materials are elaborated in detail.Most importantly,the advantages and disadvantages of the synthesis methods of CF and its composite materials are discussed,and the existing problems and emerging challenges in practical production are identified.Furthermore,the key future research directions of CF and its composite materials have been prospected from the potential application technologies to provide references for its synthesis and efficient utilization.展开更多
Fe-Mo functionally graded materials(FGMs)with different composition-change rates from 100%304 stainless steel to 100%Mo along the composition gradient direction were prepared by electron beam-directed energy depositio...Fe-Mo functionally graded materials(FGMs)with different composition-change rates from 100%304 stainless steel to 100%Mo along the composition gradient direction were prepared by electron beam-directed energy deposition(EB-DED)technique,including three samples with composition mutation of 100%,composition change rate of 10%and 30%.Results show that the composition-change rate significantly affects the microstructure and mechanical properties of the samples.In the sample with abrupt change of composition,the sharp shift in composition between 304 stainless steel and Mo leads to a great difference in the microstructure and hardness near the interface between the two materials.With the increase in the number of gradient layers,the composition changes continuously along the direction of deposition height,and the microstructure morphology shows a smooth transition from 304 stainless steel to Mo,which is gradually transformed from columnar crystal to dendritic crystal.Elements Fe,Mo,and other major elements transform linearly along the gradient direction,with sufficient interlayer diffusion between the deposited layers,leading to good metallurgical bonding.The smaller the change in composition gradient,the greater the microhardness value along the deposition direction.When the composition gradient is 10%,the gradient layer exhibits higher hardness(940 HV)and excellent resistance to surface abrasion,and the overall compressive properties of the samples are better,with the compressive fracture stress in the top region reaching 750.05±14 MPa.展开更多
SS316L alloy coupled with Inconel625 alloy were combined with Ti6Al4V or Inconel718 alloy through wire arc additive manufacturing technique to manufacture functionally graded materials(FGMs).Two FGMs,namely 60%SS316L+...SS316L alloy coupled with Inconel625 alloy were combined with Ti6Al4V or Inconel718 alloy through wire arc additive manufacturing technique to manufacture functionally graded materials(FGMs).Two FGMs,namely 60%SS316L+20%Inconel625+20%Ti6Al4V composite and 60%SS316L+20%Inconel625+20%Inconel718 composite,were prepared.The tensile strength,elongation,yield strength,hardness,cross section area of the parent material,and composition were analysed.Results illustrate that the 60%SS316L+20%Inconel625+20%Inconel718 composite has better mechanical properties than 60%SS316L+20%Inconel625+20%Ti6Al4V composite,and the comprehensive properties of 60%SS316L+20%Inconel 625+20%Ti6Al4V composite are better than those of the parent material SS316L.Hence,the composite of 60%SS316L+20%Inconel625+20%Inconel718 is optimal.Due to its high strength,the 60%SS316L+20%Inconel625+20%Inconel718 composite has great application potential in the field of high pressure pneumatic tool and defence tool.展开更多
Intracellular polymerization is an emerging field,showcasing high diversity and efficiency of chemistry.Motivated by the principles of natural biomolecular synthesis,polymerization within living cells is believed to b...Intracellular polymerization is an emerging field,showcasing high diversity and efficiency of chemistry.Motivated by the principles of natural biomolecular synthesis,polymerization within living cells is believed to be a powerful and versatile tool to modulate cell behavior.In this review,we summarized recent advances and future trends in the field of intracellular polymerization,specifically focusing on covalent and supramolecular polymerization.This discussion comprehensively covers the diverse chemical designs,reaction mechanisms,responsive features,and functional applications.Furthermore,we also clarified the connection between preliminary design of polymer synthesis and their subsequent biological applications.We hope this review will serve as an innovative platform for chemists and biologists to regulate biological functions in practical applications and clinical trials.展开更多
The fabrication of Invar/MnCu functionally graded material(FGM)through directed energy deposition(DED)can satisfy the demands for precision devices in aerospace,providing lightweight properties and integrating thermal...The fabrication of Invar/MnCu functionally graded material(FGM)through directed energy deposition(DED)can satisfy the demands for precision devices in aerospace,providing lightweight properties and integrating thermal stability and vibration damping capabilities.However,basic research on Invar/MnCu FGM is still lacking,hindering its potential applications.To address this gap,this study was conducted using mixed powders and consistent process parameters to print experiments for Invar/MnCu FGM and homogeneous samples.Phases,microstructures,compositions,and thermal expansion properties were thoroughly examined.Three types of defects were detected in the Invar/MnCu FGM sample:unmelted Invar 36 powders,cracks,and pores.The mechanism of unmelted powders was deeply discussed,attributing it to material properties influencing laser absorptivity,the required time for melting powder,and effects on solidus temperature.The mechanism of cracks was also discussed,attributing it to theγ-Fe dendritic structure causing low melting point metal to form an intergranular liquid film,harmful secondary phases mismatched with the terminal alloy,and obvious tensile stresses during the DED process.Additionally,an effective strategy was proposed to reduce defects in Invar/MnCu FGM.After optimization,the specimens exhibited excellent tensile properties,with a yield strength of 262±5 MPa,an ultimate tensile strength of 316±7 MPa,and an elongation of 3%±1%.This research provides valuable references and insights for subsequent work,offering robust support for better understanding and designing other FGM.展开更多
Functionally graded materials (FGMs) are innovative materials distinguished by gradual variations in composition and structure, offering exceptional properties for diverse applications. Poly(ionic liquid)s (PILs), mer...Functionally graded materials (FGMs) are innovative materials distinguished by gradual variations in composition and structure, offering exceptional properties for diverse applications. Poly(ionic liquid)s (PILs), merging the characteristics of polymers and ionic liquids, have emerged as viable options for the development of FGMs given their tunable skeleton, ionic conductivity, and compatibility with various functional materials. This review highlights the latest advancements in the design strategies of FGMs based on porous PILs, focusing on single and multi-gradient structures. Furthermore, we also highlight their emerging applications in molecular recognition, sensing, adsorption, separation, and catalysis. By exploring the interplay between porosity, ionic functionality, and gradient architecture, this review offers perspectives on the prospects of PIL-based FGMs for tackling global challenges in energy, environment, and healthcare.展开更多
Given the significant potential of multi-directional functionally graded materials(MFGMs)for customizable performance,it is crucial to develop versatile material models to enhance design optimization in engineering ap...Given the significant potential of multi-directional functionally graded materials(MFGMs)for customizable performance,it is crucial to develop versatile material models to enhance design optimization in engineering applications.This paper introduces a material model for an MFGM plate described by trigonometric functions,equipped with four parameters to control diverse material distributions effectively.The bending and vibration analysis of MFGM rectangular and cutout plates is carried out utilizing isogeometric analysis,which is based on a novel third-order shear deformation theory(TSDT)to account for transverse shear deformation.The present TSDT,founded on rigorous kinematics of displacements,is demonstrated to surpass other preceding theories.It is derived from an elasticity formulation,rather than relying on the hypothesis of displacements.The effectiveness of the proposed method is verified by comparing its numerical results with those of other methods reported in the relevant literature.Numerical results indicate that the structure,boundary conditions,and gradient parameters of the MFGM plate significantly influence its deflection,stress,and vibration frequency.As the periodic parameter exceeds four,the model complexity increases,causing result fluctuations.Additionally,MFGM cutout plates,when clamped on all sides,display almost identical first four vibration frequencies.展开更多
The stable sub-angstrom resolution of the aberration-corrected scanning transmission electron microscope(ACSTEM)makes it an advanced and practical characterization technique for all materials.Owing to the prosperous a...The stable sub-angstrom resolution of the aberration-corrected scanning transmission electron microscope(ACSTEM)makes it an advanced and practical characterization technique for all materials.Owing to the prosperous advancement in computational technology,specialized software and programs have emerged as potent facilitators across the entirety of electron microscopy characterization process.Utilizing advanced image processing algorithms promotes the rectification of image distortions,concurrently elevating the overall image quality to superior standards.Extracting high-resolution,pixel-level discrete information and converting it into atomic-scale,followed by performing statistical calculations on the physical matters of interest through quantitative analysis,represent an effective strategy to maximize the value of electron microscope images.The efficacious utilization of quantitative analysis of electron microscope images has become a progressively prominent consideration for materials scientists and electron microscopy researchers.This article offers a concise overview of the pivotal procedures in quantitative analysis and summarizes the computational methodologies involved from three perspectives:contrast,lattice and strain,as well as atomic displacements and polarization.It further elaborates on practical applications of these methods in electronic functional materials,notably in piezoelectrics/ferroelectrics and thermoelectrics.It emphasizes the indispensable role of quantitative analysis in fundamental theoretical research,elucidating the structure–property correlations in high-performance systems,and guiding synthesis strategies.展开更多
In this paper, the wave propagation in functionally graded materials (FGM) is studied by the elastic wave theory based on thewave problems in homogeneous media. The auxiliary function and modulus function are introduc...In this paper, the wave propagation in functionally graded materials (FGM) is studied by the elastic wave theory based on thewave problems in homogeneous media. The auxiliary function and modulus function are introduced to construct the displacementfield and density function. The displacement field, modulus function, and density function are connected to proposea design theory of special FGM. An analytical method for elastic wave propagation in inhomogeneous media with varyingmodulus and density is derived to provide theoretical references for material design and dynamic stress analysis under elasticwaves. Taking the problem of dynamic stress concentration caused by shallow buried elliptical cavity in half space designedunder SH waves as an example, the calculation results are obtained and analyzed. The results show that the dynamic stressconcentration is sensitive to the change of the inhomogeneity of the medium.展开更多
Rechargeable lithium batteries with high-capacity cathodes/anodes promise high energy densities for nextgeneration electrochemical energy storage.However,the associated limitations at various scales greatly hinder the...Rechargeable lithium batteries with high-capacity cathodes/anodes promise high energy densities for nextgeneration electrochemical energy storage.However,the associated limitations at various scales greatly hinder their practical applications.Functional gradient material(FGM)design endows the electrode materials with property gradient,thus providing great opportunities to address the kinetics and stability obstacles.To date,still no review or perspective has covered recent advancements in gradient design at multiple scales for boosting lithium battery performances.To fill this void,this work provides a timely and comprehensive overview of this exciting and sustainable research field.We begin by overviewing the fundamental features of FGM and the rationales of gradient design for improved electrochemical performance.Then,we comprehensively review FGM design for rechargeable lithium batteries at various scales,including natural or artificial solid electrolyte interphase(SEI)at the nanoscale,micrometer-scale electrode particles,and macroscale electrode films.The link between gradient structure design and improved electrochemical performance is particularly highlighted.The most recent research into constructing novel functional gradients,such as valence and temperature gradients,has also been explored.Finally,we discussed the current constraints and future scope of FGM in rechargeable lithium batteries,aiming to inspire the development of novel FGM for next-generation high-performance lithium batteries.展开更多
Functionally graded materials(FGMs)are a novel class of composite materials that have attracted significant attention in the field of engineering due to their unique mechanical properties.This study aims to explore th...Functionally graded materials(FGMs)are a novel class of composite materials that have attracted significant attention in the field of engineering due to their unique mechanical properties.This study aims to explore the dynamic behaviors of an FGM stepped beam with different boundary conditions based on an efficient solving method.Under the assumptions of the Euler-Bernoulli beam theory,the governing differential equations of an individual FGM beam are derived with Hamilton’s principle and decoupled via the separation-of-variable approach.Then,the free and forced vibrations of the FGM stepped beam are solved with the transfer matrix method(TMM).Two models,i.e.,a three-level FGM stepped beam and a five-level FGM stepped beam,are considered,and their natural frequencies and mode shapes are presented.To demonstrate the validity of the method in this paper,the simulation results by ABAQUS are also given.On this basis,the detailed parametric analyses on the frequencies and dynamic responses of the three-level FGM stepped beam are carried out.The results show the accuracy and efficiency of the TMM.展开更多
In this paper, the isogeometric analysis (IGA) is employed to develop an acoustic radiation model for a double plate-acoustic cavity coupling system, with a focus on analyzing the sound transmission loss (STL). The fu...In this paper, the isogeometric analysis (IGA) is employed to develop an acoustic radiation model for a double plate-acoustic cavity coupling system, with a focus on analyzing the sound transmission loss (STL). The functionally graded (FG) plate exhibits a different material properties in-plane, and the power-law rule is adopted as the governing principle for material mixing. To validate the harmonic response and demonstrate the accuracy and convergence of the isogeometric modeling, ANASYS is utilized to compare with numerical examples. A plane wave serves as the acoustic excitation, and the Rayleigh integral is applied to discretize the radiated plate. The STL results are compared with the literature, confirming the reliability of the coupling system. Finally, the investigation is conducted to study impact of cavity depth and power-law parameter on the STL.展开更多
Cellulosic materials are attracting increasing research interest because of their abundance,biocompatibility,and biodegradability,making them suitable in multiple industrial and medical applications.Functionalization ...Cellulosic materials are attracting increasing research interest because of their abundance,biocompatibility,and biodegradability,making them suitable in multiple industrial and medical applications.Functionalization of cellulose is usually required to improve or expand its properties to meet the requirements of different applications.Cellulose-binding domains(CBDs)found in various proteins have been shown to be powerful tools in the functionalization of cellulose materials.In this review,we firstly introduce the structural characteristics of commonly used CBDs belonging to carbohydrate-binding module families 1,2 and 3.Then,we summarize four main kinds of methodologies for employing CBDs to modify cellulosic materials(i.e.,CBD only,genetic fusion,non-covalent linkage and covalent linkage).Via different approaches,CBDs have been used to improve the material properties of cellulose,immobilize enzymes for biocatalysis,and design various detection tools.To achieve industrial applications,researches for lowering the production cost of CBDs,improving their performance(e.g.,stability),and expanding their application scenarios are still in need.展开更多
With the growing importance of wearable and portable electronics in modern society and industry,researchers from all over the world have reported on advances in energy harvesting and self-powered sensing technologies....With the growing importance of wearable and portable electronics in modern society and industry,researchers from all over the world have reported on advances in energy harvesting and self-powered sensing technologies.The current review discusses recent developments in triboelectric platforms from a manufacturing perspective,including material,design,application,and industrialization.Manufacturing is an essential component of both industry and technology.The use of a proper manufacturing process enables cutting-edge technology in a lab-scale stage to progress to commercialization and popularization with scalability,availability,commercial advantage,and consistent quality.Furthermore,much literature has emphasized that the most powerful advantage of the triboelectric platform is its wide range of available materials and simple working mechanism,both of which are important characteristics in manufacturing engineering.As a result,different manufacturing processes can be implemented as needed.Because the practical process can have a synergetic effect on the fundamental development,resulting in the growth of both,the development of the triboelectric platform from the standpoint of manufacturing engineering can be further advanced.However,research into the development of a productive manufacturing process is still in its early stages in the field of triboelectric platforms.This review looks at the various manufacturing technologies used in previous studies and discusses the potential benefits of the appropriate process for triboelectric platforms.Given its unique strength,which includes a diverse material selection and a simple working mechanism,the triboelectric platform can use a variety of manufacturing technologies and the process can be optimized as needed.Numerous research groups have clearly demonstrated the triboelectric platform's advantages.As a result,using appropriate manufacturing processes can accelerate the technological advancement of triboelectric platforms in a variety of research and industrial fields by allowing them to move beyond the lab-scale fabrication stage.展开更多
This study investigates the nonlinear dynamic properties of rotating functionally graded sandwich rectangular plates in a thermal environment.The nonlinear vibration equations for a rotating metal-ceramic functionally...This study investigates the nonlinear dynamic properties of rotating functionally graded sandwich rectangular plates in a thermal environment.The nonlinear vibration equations for a rotating metal-ceramic functionally graded sandwich rectangular plate in a thermal environment are derived using classical thin plate theory and Hamilton’s principle,considering geometric nonlinearity,temperature-dependent material properties,and power law distribution of components through the thickness.With cantilever boundary conditions,the flexural nonlinear differential equations of the rectangular sandwich plate are obtained via the Galerkin method.Since the natural vibration differential equations exhibit nonlinear characteristics,the multiscale method is employed to derive the expression for nonlinear natural frequency.An example analysis reveals how the natural frequency of a functionally graded sandwich rectangular plate varies with rotational speed and temperature.Results show that the nonlinear/linear frequency ratio increases with rotational angular velocity Ω and thickness-to-length ratio h/a,follows a cosine-like periodic pattern with the setting angle,and shows a sharp decrease followed by a rapid increase with increasing width-to-length ratio b/a.The derived analytical solutions for nonlinear frequency provide valuable insights for assessing the dynamic characteristics of functionally graded structures.展开更多
In this study,an improved integrated radial basis function with nonuniform shape parameter is introduced.The proposed shape parameter varies in each support domain and is defined byθ=1/d_(max),where d_(max)is the max...In this study,an improved integrated radial basis function with nonuniform shape parameter is introduced.The proposed shape parameter varies in each support domain and is defined byθ=1/d_(max),where d_(max)is the maximum distance of any pair of nodes in the support domain.The proposed method is verified and shows good performance.The results are stable and accurate with any number of nodes and an arbitrary nodal distribution.Notably,the support domain should be large enough to obtain accurate results.This method is then applied for transient analysis of curved shell structures made from functionally graded materials with complex geometries.Through several numerical examples,the accuracy of the proposed approach is demonstrated and discussed.Additionally,the influence of various factors on the dynamic behavior of the structures,including the power-law index,different materials,loading conditions,and geometrical parameters of the structures,was investigated.展开更多
This paper proposes a new step-by-step Chebyshev space-time spectral method to analyze the force vibration of functionally graded material structures.Although traditional space-time spectral methods can reduce the acc...This paper proposes a new step-by-step Chebyshev space-time spectral method to analyze the force vibration of functionally graded material structures.Although traditional space-time spectral methods can reduce the accuracy mismatch between tem-poral low-order finite difference and spatial high-order discre tization,the ir time collocation points must increase dramatically to solve highly oscillatory solutions of structural vibration,which results in a surge in computing time and a decrease in accuracy.To address this problem,we introduced the step-by-step idea in the space-time spectral method.The Chebyshev polynomials and Lagrange's equation were applied to derive discrete spatial goverming equations,and a matrix projection method was used to map the calculation results of prev ious steps as the initial conditions of the subsequent steps.A series of numerical experiments were carried out.The results of the proposed method were compared with those obtained by traditional space-time spectral methods,which showed that higher accuracy could be achieved in a shorter computation time than the latter in highly oscillatory cases.展开更多
Based on the Timoshenko beam theory,this paper proposes a nonlocal bi-gyroscopic model for spinning functionally graded(FG)nanotubes conveying fluid,and the thermal–mechanical vibration and stability of such composit...Based on the Timoshenko beam theory,this paper proposes a nonlocal bi-gyroscopic model for spinning functionally graded(FG)nanotubes conveying fluid,and the thermal–mechanical vibration and stability of such composite nanostructures under small scale,rotor,and temperature coupling effects are investigated.The nanotube is composed of functionally graded materials(FGMs),and different volume fraction functions are utilized to control the distribution of material properties.Eringen’s nonlocal elasticity theory and Hamilton’s principle are applied for dynamical modeling,and the forward and backward precession frequencies as well as 3D mode configurations of the nanotube are obtained.By conducting dimensionless analysis,it is found that compared to the Timoshenko nano-beam model,the conventional Euler–Bernoulli(E-B)model holds the same flutter frequency in the supercritical region,while it usually overestimates the higher-order precession frequencies.The nonlocal,thermal,and flowing effects all can lead to buckling or different kinds of coupled flutter in the system.The material distribution of the P-type FGM nanotube can also induce coupled flutter,while that of the S-type FGM nanotube has no impact on the stability of the system.This paper is expected to provide a theoretical foundation for the design of motional composite nanodevices.展开更多
基金supported by Ministry of Science and InnovationNational Research Agency(Project PID2019-105960RBC21)+1 种基金by the Basque Government(Project IT1509-2022)One of the authors(JAOC)acknowledges the post-doctoral research grant(DOCREC20/49)provided by the University of the Basque Country。
文摘Integrated CO_(2)capture and utilization(ICCU)technology requires dual functional materials(DFMs)to carry out the process in a single reaction system.The influence of the calcination atmosphere on efficiency of 4%Ru-8%Na_(2)CO_(3)-8%CaO/γ-Al_(2)O_(3)DFM is studied.The adsorbent precursors are first co-impregnated onto alumina and calcined in air.Then,Ru precursor is impregnated and four aliquotes are subjected to different calcination protocols:static air in muffle or under different mixtures(10%H_(2)/N_(2),50%H_(2)/N_(2)and N_(2))streams.Samples are characterized by XRD,N_(2)adsorption-desorption,H_(2)chemisorption,TEM,XPS,H_(2)-TPD,H_(2)-TPR,CO_(2)-TPD and TPSR.The catalytic behavior is evaluated,in cycles of CO_(2)adsorption and hydrogenation to CH_(4),and temporal evolution of reactants and products concentrations is analyzed.The calcination atmosphere influences the physicochemical properties and,ultimately,activity of DFMs.Characterization data and catalytic performance discover the acccomodation of Ru nanoparticles disposition and basic sites is mostly influencing the catalytic activity.DFM calcined under N_(2)flow(RuNaCa-N_(2))shows the highest CH_(4)production(449μmol/g at 370℃),because a well-controlled decomposition of precursors which favors the better accomodation of adsorbent and Ru phases,maximizing the specific surface area,the Ru-basic sites interface and the participation of different basic sites in the CO_(2)methanation reaction.Thus,the calcination in a N_(2)flow is revealed as the optimal calcination protocol to achieve highly efficient DFM for integrated CO_(2)adsorption and hydrogenation applications.
基金Project supported by Major Special Science and Technology Project of PetroChina Company Limited“Study and application of key technologies for developing deepeultra-deep gas in Kuqa depression”(No.:2018E-1803).
文摘It is difficult to determine the effective reservoir rock compressibility,aquifer volume and water influx of high pressure and ultra-high pressure gas reservoirs,so when the traditional apparent reservoir pressure and cumulative gas production curve extrapolation method and its modified version are used to calculate the initial gas in-place of such gas reservoirs,the calculation accuracy is lower.The material balance equation in the form of power function for such gas reservoirs was established based on Gonzalez method to improve the accuracy and reliability of reserve evaluation.Then,based on 20 high pressure and ultra-high pressure reservoirs that had been developed abroad,the empirical value of the power exponent was defined,and the influences of the depletion degree of apparent reservoir pressure and the degree of reserve recovery on the reliability of reserve calculation were analyzed.Besides,the critical value of the key parameter affecting the reliability of reserve evaluation(depletion degree of apparent reservoir pressure)was determined and compared with the critical value of the two-linear trends.Finally,an example calculation was carried out.And the following research results were obtained.First,the empirical value of the power exponent calculated using the material balance method in the form of power function is 1.02847,with an upper limit of 1.11567.Second,the depletion degree of apparent reservoir pressure corresponding to the inflection point of the classical two-linear trends ranges from 0.14 to 0.38 with an average of 0.23,while that corresponding to the extrapolation point of the second straight line is between 0.23 and 0.50 with an average of 0.33,and the corresponding degree of reserve recovery is in the range of 33%-65%with an average of 45%.Third,the reserves of such high pressure gas reservoirs calculated with this new method has an error rate less than 10%if the depletion degree of apparent reservoir pressure is greater than 0.33.In conclusion,for such high pressure gas reservoirs and the stress-sensitive fractured gas reservoirs,the material balance method in the form of power function proposed in this paper can avoid the uncertainty parameters(e.g.effective reservoir rock compressibility,aquifer volume and water influx)and it is advantageous with simple calculation process,better practicability and small error.
基金supported by the National Natural Science Foundation of China(No.51574105)the Science and Technology Program of Hebei Province,China(No.23564101D)+2 种基金the Natural Science Foundation of Hebei Province,China(No.E2021209147)the Key Research Project of North China University of Science and Technology(No.ZD-ST-202308)the Postgraduate Innovation Funding Project of Hebei Province,China(No.CXZZBS2024135).
文摘Calcium ferrite(CF)is recognized as a potential green and efficient functional material because of its advantages of magnetism,electrochemistry,catalysis,and biocompatibility in the fields of materials chemistry,environmental engineering,and biomedicine.There-fore,the obtained research results need to be systematically summarized,and new perspectives on CF and its composite materials need to be analyzed.Based on the presented studies of CF and its composite materials,the types and structures of the crystal are summarized.In addition,the current application technologies and theoretical mechanisms with various properties in different fields are elucidated.Moreover,the various preparation methods of CF and its composite materials are elaborated in detail.Most importantly,the advantages and disadvantages of the synthesis methods of CF and its composite materials are discussed,and the existing problems and emerging challenges in practical production are identified.Furthermore,the key future research directions of CF and its composite materials have been prospected from the potential application technologies to provide references for its synthesis and efficient utilization.
基金National Natural Science Foundation of China(51975286)。
文摘Fe-Mo functionally graded materials(FGMs)with different composition-change rates from 100%304 stainless steel to 100%Mo along the composition gradient direction were prepared by electron beam-directed energy deposition(EB-DED)technique,including three samples with composition mutation of 100%,composition change rate of 10%and 30%.Results show that the composition-change rate significantly affects the microstructure and mechanical properties of the samples.In the sample with abrupt change of composition,the sharp shift in composition between 304 stainless steel and Mo leads to a great difference in the microstructure and hardness near the interface between the two materials.With the increase in the number of gradient layers,the composition changes continuously along the direction of deposition height,and the microstructure morphology shows a smooth transition from 304 stainless steel to Mo,which is gradually transformed from columnar crystal to dendritic crystal.Elements Fe,Mo,and other major elements transform linearly along the gradient direction,with sufficient interlayer diffusion between the deposited layers,leading to good metallurgical bonding.The smaller the change in composition gradient,the greater the microhardness value along the deposition direction.When the composition gradient is 10%,the gradient layer exhibits higher hardness(940 HV)and excellent resistance to surface abrasion,and the overall compressive properties of the samples are better,with the compressive fracture stress in the top region reaching 750.05±14 MPa.
文摘SS316L alloy coupled with Inconel625 alloy were combined with Ti6Al4V or Inconel718 alloy through wire arc additive manufacturing technique to manufacture functionally graded materials(FGMs).Two FGMs,namely 60%SS316L+20%Inconel625+20%Ti6Al4V composite and 60%SS316L+20%Inconel625+20%Inconel718 composite,were prepared.The tensile strength,elongation,yield strength,hardness,cross section area of the parent material,and composition were analysed.Results illustrate that the 60%SS316L+20%Inconel625+20%Inconel718 composite has better mechanical properties than 60%SS316L+20%Inconel625+20%Ti6Al4V composite,and the comprehensive properties of 60%SS316L+20%Inconel 625+20%Ti6Al4V composite are better than those of the parent material SS316L.Hence,the composite of 60%SS316L+20%Inconel625+20%Inconel718 is optimal.Due to its high strength,the 60%SS316L+20%Inconel625+20%Inconel718 composite has great application potential in the field of high pressure pneumatic tool and defence tool.
基金financially supported by the National Key R&D Program of China(No.2023YFA0915300)the National Natural Science Foundation of China(Nos.52233012,22405212 and22471219)the Funds for Creative Research Groups of China of the National Natural Science Foundation of China(No.21821001)。
文摘Intracellular polymerization is an emerging field,showcasing high diversity and efficiency of chemistry.Motivated by the principles of natural biomolecular synthesis,polymerization within living cells is believed to be a powerful and versatile tool to modulate cell behavior.In this review,we summarized recent advances and future trends in the field of intracellular polymerization,specifically focusing on covalent and supramolecular polymerization.This discussion comprehensively covers the diverse chemical designs,reaction mechanisms,responsive features,and functional applications.Furthermore,we also clarified the connection between preliminary design of polymer synthesis and their subsequent biological applications.We hope this review will serve as an innovative platform for chemists and biologists to regulate biological functions in practical applications and clinical trials.
基金supported by the National Key Research and Development Program of China(Nos.2022YFB4600300 and 2022YFB4600301)the National Natural Science Foundation of China(No.52175364)+1 种基金the ND Basic Research Funds of NPU(G2022WD)the Research Fund of the State Key Laboratory of Solidification Processing(NPU),China(No.2023-QZ-04).
文摘The fabrication of Invar/MnCu functionally graded material(FGM)through directed energy deposition(DED)can satisfy the demands for precision devices in aerospace,providing lightweight properties and integrating thermal stability and vibration damping capabilities.However,basic research on Invar/MnCu FGM is still lacking,hindering its potential applications.To address this gap,this study was conducted using mixed powders and consistent process parameters to print experiments for Invar/MnCu FGM and homogeneous samples.Phases,microstructures,compositions,and thermal expansion properties were thoroughly examined.Three types of defects were detected in the Invar/MnCu FGM sample:unmelted Invar 36 powders,cracks,and pores.The mechanism of unmelted powders was deeply discussed,attributing it to material properties influencing laser absorptivity,the required time for melting powder,and effects on solidus temperature.The mechanism of cracks was also discussed,attributing it to theγ-Fe dendritic structure causing low melting point metal to form an intergranular liquid film,harmful secondary phases mismatched with the terminal alloy,and obvious tensile stresses during the DED process.Additionally,an effective strategy was proposed to reduce defects in Invar/MnCu FGM.After optimization,the specimens exhibited excellent tensile properties,with a yield strength of 262±5 MPa,an ultimate tensile strength of 316±7 MPa,and an elongation of 3%±1%.This research provides valuable references and insights for subsequent work,offering robust support for better understanding and designing other FGM.
基金support provided by National Natural Science Foundation of China(22471018,22071008,22208018)support provided by the Shenzhen Science and Technology Program(JCYJ20220818100012025).
文摘Functionally graded materials (FGMs) are innovative materials distinguished by gradual variations in composition and structure, offering exceptional properties for diverse applications. Poly(ionic liquid)s (PILs), merging the characteristics of polymers and ionic liquids, have emerged as viable options for the development of FGMs given their tunable skeleton, ionic conductivity, and compatibility with various functional materials. This review highlights the latest advancements in the design strategies of FGMs based on porous PILs, focusing on single and multi-gradient structures. Furthermore, we also highlight their emerging applications in molecular recognition, sensing, adsorption, separation, and catalysis. By exploring the interplay between porosity, ionic functionality, and gradient architecture, this review offers perspectives on the prospects of PIL-based FGMs for tackling global challenges in energy, environment, and healthcare.
基金supported by the Guangdong Major Project of Basic and Applied Basic Research(2021B0301030001)the National Key Research and Development Program of China(2021YFA0716304)+3 种基金the project supported by the Space Utilization System of China Manned Space Engineering(KJZ-YY-WCL03)the National Key Laboratory Foundation of Science and Technology on Materials under Shock and Impact(6142902210109)Independent Innovation Projects of the Hubei Longzhong Laboratory(2022ZZ-32)the National Natural Science Foundation of China(Nos.11902232,51972246,and 51521001).
文摘Given the significant potential of multi-directional functionally graded materials(MFGMs)for customizable performance,it is crucial to develop versatile material models to enhance design optimization in engineering applications.This paper introduces a material model for an MFGM plate described by trigonometric functions,equipped with four parameters to control diverse material distributions effectively.The bending and vibration analysis of MFGM rectangular and cutout plates is carried out utilizing isogeometric analysis,which is based on a novel third-order shear deformation theory(TSDT)to account for transverse shear deformation.The present TSDT,founded on rigorous kinematics of displacements,is demonstrated to surpass other preceding theories.It is derived from an elasticity formulation,rather than relying on the hypothesis of displacements.The effectiveness of the proposed method is verified by comparing its numerical results with those of other methods reported in the relevant literature.Numerical results indicate that the structure,boundary conditions,and gradient parameters of the MFGM plate significantly influence its deflection,stress,and vibration frequency.As the periodic parameter exceeds four,the model complexity increases,causing result fluctuations.Additionally,MFGM cutout plates,when clamped on all sides,display almost identical first four vibration frequencies.
基金Project supported by the financial support from the National Key R&D Program of China(Grant No.2021YFB3201100)the National Natural Science Foundation of China(Grant No.52172128)the Top Young Talents Programme of Xi’an Jiaotong University.
文摘The stable sub-angstrom resolution of the aberration-corrected scanning transmission electron microscope(ACSTEM)makes it an advanced and practical characterization technique for all materials.Owing to the prosperous advancement in computational technology,specialized software and programs have emerged as potent facilitators across the entirety of electron microscopy characterization process.Utilizing advanced image processing algorithms promotes the rectification of image distortions,concurrently elevating the overall image quality to superior standards.Extracting high-resolution,pixel-level discrete information and converting it into atomic-scale,followed by performing statistical calculations on the physical matters of interest through quantitative analysis,represent an effective strategy to maximize the value of electron microscope images.The efficacious utilization of quantitative analysis of electron microscope images has become a progressively prominent consideration for materials scientists and electron microscopy researchers.This article offers a concise overview of the pivotal procedures in quantitative analysis and summarizes the computational methodologies involved from three perspectives:contrast,lattice and strain,as well as atomic displacements and polarization.It further elaborates on practical applications of these methods in electronic functional materials,notably in piezoelectrics/ferroelectrics and thermoelectrics.It emphasizes the indispensable role of quantitative analysis in fundamental theoretical research,elucidating the structure–property correlations in high-performance systems,and guiding synthesis strategies.
基金supported by the National Natural Science Foundation of China(Grant No.12072085)the Natural Science Foundation of Heilongjiang Province of China(Grant No.ZD2021A001)the program for Innovative Research Team in China Earthquake Administration.
文摘In this paper, the wave propagation in functionally graded materials (FGM) is studied by the elastic wave theory based on thewave problems in homogeneous media. The auxiliary function and modulus function are introduced to construct the displacementfield and density function. The displacement field, modulus function, and density function are connected to proposea design theory of special FGM. An analytical method for elastic wave propagation in inhomogeneous media with varyingmodulus and density is derived to provide theoretical references for material design and dynamic stress analysis under elasticwaves. Taking the problem of dynamic stress concentration caused by shallow buried elliptical cavity in half space designedunder SH waves as an example, the calculation results are obtained and analyzed. The results show that the dynamic stressconcentration is sensitive to the change of the inhomogeneity of the medium.
基金financial support from the National Natural Science Foundation of China(Nos.52261160384 and 52072208)the Project of Department of Education of Guangdong Province(No.2022ZDZX3018)+2 种基金the Natural Science Foundation of Guangdong(No.2023A1515010020)the Innovation and Technology Fund(No.ITS-325-22FP)the Shenzhen Science and Technology Program(No.KJZD20230923114107014)。
文摘Rechargeable lithium batteries with high-capacity cathodes/anodes promise high energy densities for nextgeneration electrochemical energy storage.However,the associated limitations at various scales greatly hinder their practical applications.Functional gradient material(FGM)design endows the electrode materials with property gradient,thus providing great opportunities to address the kinetics and stability obstacles.To date,still no review or perspective has covered recent advancements in gradient design at multiple scales for boosting lithium battery performances.To fill this void,this work provides a timely and comprehensive overview of this exciting and sustainable research field.We begin by overviewing the fundamental features of FGM and the rationales of gradient design for improved electrochemical performance.Then,we comprehensively review FGM design for rechargeable lithium batteries at various scales,including natural or artificial solid electrolyte interphase(SEI)at the nanoscale,micrometer-scale electrode particles,and macroscale electrode films.The link between gradient structure design and improved electrochemical performance is particularly highlighted.The most recent research into constructing novel functional gradients,such as valence and temperature gradients,has also been explored.Finally,we discussed the current constraints and future scope of FGM in rechargeable lithium batteries,aiming to inspire the development of novel FGM for next-generation high-performance lithium batteries.
基金the National Natural Science Foundation of China(Nos.12302007,12372006,and 12202109)the Specific Research Project of Guangxi for Research Bases and Talents(No.AD23026051)。
文摘Functionally graded materials(FGMs)are a novel class of composite materials that have attracted significant attention in the field of engineering due to their unique mechanical properties.This study aims to explore the dynamic behaviors of an FGM stepped beam with different boundary conditions based on an efficient solving method.Under the assumptions of the Euler-Bernoulli beam theory,the governing differential equations of an individual FGM beam are derived with Hamilton’s principle and decoupled via the separation-of-variable approach.Then,the free and forced vibrations of the FGM stepped beam are solved with the transfer matrix method(TMM).Two models,i.e.,a three-level FGM stepped beam and a five-level FGM stepped beam,are considered,and their natural frequencies and mode shapes are presented.To demonstrate the validity of the method in this paper,the simulation results by ABAQUS are also given.On this basis,the detailed parametric analyses on the frequencies and dynamic responses of the three-level FGM stepped beam are carried out.The results show the accuracy and efficiency of the TMM.
文摘In this paper, the isogeometric analysis (IGA) is employed to develop an acoustic radiation model for a double plate-acoustic cavity coupling system, with a focus on analyzing the sound transmission loss (STL). The functionally graded (FG) plate exhibits a different material properties in-plane, and the power-law rule is adopted as the governing principle for material mixing. To validate the harmonic response and demonstrate the accuracy and convergence of the isogeometric modeling, ANASYS is utilized to compare with numerical examples. A plane wave serves as the acoustic excitation, and the Rayleigh integral is applied to discretize the radiated plate. The STL results are compared with the literature, confirming the reliability of the coupling system. Finally, the investigation is conducted to study impact of cavity depth and power-law parameter on the STL.
基金supported by the National Natural Science Foundation of China(32170037)and SKLMT Frontiers and Challenges Project(SKLMTFCP-2023-04).
文摘Cellulosic materials are attracting increasing research interest because of their abundance,biocompatibility,and biodegradability,making them suitable in multiple industrial and medical applications.Functionalization of cellulose is usually required to improve or expand its properties to meet the requirements of different applications.Cellulose-binding domains(CBDs)found in various proteins have been shown to be powerful tools in the functionalization of cellulose materials.In this review,we firstly introduce the structural characteristics of commonly used CBDs belonging to carbohydrate-binding module families 1,2 and 3.Then,we summarize four main kinds of methodologies for employing CBDs to modify cellulosic materials(i.e.,CBD only,genetic fusion,non-covalent linkage and covalent linkage).Via different approaches,CBDs have been used to improve the material properties of cellulose,immobilize enzymes for biocatalysis,and design various detection tools.To achieve industrial applications,researches for lowering the production cost of CBDs,improving their performance(e.g.,stability),and expanding their application scenarios are still in need.
基金supported by the National Research Foundation of Korea(NRF)(No.2021R1C1C2009703)supported by the National Research Foundation of Korea(NRF)Grant funded by the Korea government(MSIT)(RS-2024-00344920)supported by the Human Resources Development of the Korea Institute of Energy Technology Evaluation and Planning(KETEP)Grant funded by the Ministry of Trade,Industry and Energy of Korea(No.RS2023-00244330)。
文摘With the growing importance of wearable and portable electronics in modern society and industry,researchers from all over the world have reported on advances in energy harvesting and self-powered sensing technologies.The current review discusses recent developments in triboelectric platforms from a manufacturing perspective,including material,design,application,and industrialization.Manufacturing is an essential component of both industry and technology.The use of a proper manufacturing process enables cutting-edge technology in a lab-scale stage to progress to commercialization and popularization with scalability,availability,commercial advantage,and consistent quality.Furthermore,much literature has emphasized that the most powerful advantage of the triboelectric platform is its wide range of available materials and simple working mechanism,both of which are important characteristics in manufacturing engineering.As a result,different manufacturing processes can be implemented as needed.Because the practical process can have a synergetic effect on the fundamental development,resulting in the growth of both,the development of the triboelectric platform from the standpoint of manufacturing engineering can be further advanced.However,research into the development of a productive manufacturing process is still in its early stages in the field of triboelectric platforms.This review looks at the various manufacturing technologies used in previous studies and discusses the potential benefits of the appropriate process for triboelectric platforms.Given its unique strength,which includes a diverse material selection and a simple working mechanism,the triboelectric platform can use a variety of manufacturing technologies and the process can be optimized as needed.Numerous research groups have clearly demonstrated the triboelectric platform's advantages.As a result,using appropriate manufacturing processes can accelerate the technological advancement of triboelectric platforms in a variety of research and industrial fields by allowing them to move beyond the lab-scale fabrication stage.
基金supported by the National Natural Science Foundation of China(No.11772090).
文摘This study investigates the nonlinear dynamic properties of rotating functionally graded sandwich rectangular plates in a thermal environment.The nonlinear vibration equations for a rotating metal-ceramic functionally graded sandwich rectangular plate in a thermal environment are derived using classical thin plate theory and Hamilton’s principle,considering geometric nonlinearity,temperature-dependent material properties,and power law distribution of components through the thickness.With cantilever boundary conditions,the flexural nonlinear differential equations of the rectangular sandwich plate are obtained via the Galerkin method.Since the natural vibration differential equations exhibit nonlinear characteristics,the multiscale method is employed to derive the expression for nonlinear natural frequency.An example analysis reveals how the natural frequency of a functionally graded sandwich rectangular plate varies with rotational speed and temperature.Results show that the nonlinear/linear frequency ratio increases with rotational angular velocity Ω and thickness-to-length ratio h/a,follows a cosine-like periodic pattern with the setting angle,and shows a sharp decrease followed by a rapid increase with increasing width-to-length ratio b/a.The derived analytical solutions for nonlinear frequency provide valuable insights for assessing the dynamic characteristics of functionally graded structures.
基金Ho Chi Minh City University of Technology (HCMUT), VNU-HCM for supporting this study
文摘In this study,an improved integrated radial basis function with nonuniform shape parameter is introduced.The proposed shape parameter varies in each support domain and is defined byθ=1/d_(max),where d_(max)is the maximum distance of any pair of nodes in the support domain.The proposed method is verified and shows good performance.The results are stable and accurate with any number of nodes and an arbitrary nodal distribution.Notably,the support domain should be large enough to obtain accurate results.This method is then applied for transient analysis of curved shell structures made from functionally graded materials with complex geometries.Through several numerical examples,the accuracy of the proposed approach is demonstrated and discussed.Additionally,the influence of various factors on the dynamic behavior of the structures,including the power-law index,different materials,loading conditions,and geometrical parameters of the structures,was investigated.
基金supported by the Advance Research Project of Civil Aerospace Technology(Grant No.D020304)National Nat-ural Science Foundation of China(Grant Nos.52205257 and U22B2083).
文摘This paper proposes a new step-by-step Chebyshev space-time spectral method to analyze the force vibration of functionally graded material structures.Although traditional space-time spectral methods can reduce the accuracy mismatch between tem-poral low-order finite difference and spatial high-order discre tization,the ir time collocation points must increase dramatically to solve highly oscillatory solutions of structural vibration,which results in a surge in computing time and a decrease in accuracy.To address this problem,we introduced the step-by-step idea in the space-time spectral method.The Chebyshev polynomials and Lagrange's equation were applied to derive discrete spatial goverming equations,and a matrix projection method was used to map the calculation results of prev ious steps as the initial conditions of the subsequent steps.A series of numerical experiments were carried out.The results of the proposed method were compared with those obtained by traditional space-time spectral methods,which showed that higher accuracy could be achieved in a shorter computation time than the latter in highly oscillatory cases.
基金National Natural Science Foundation of China,12372025,Feng Liang,12072311,Feng Liang.
文摘Based on the Timoshenko beam theory,this paper proposes a nonlocal bi-gyroscopic model for spinning functionally graded(FG)nanotubes conveying fluid,and the thermal–mechanical vibration and stability of such composite nanostructures under small scale,rotor,and temperature coupling effects are investigated.The nanotube is composed of functionally graded materials(FGMs),and different volume fraction functions are utilized to control the distribution of material properties.Eringen’s nonlocal elasticity theory and Hamilton’s principle are applied for dynamical modeling,and the forward and backward precession frequencies as well as 3D mode configurations of the nanotube are obtained.By conducting dimensionless analysis,it is found that compared to the Timoshenko nano-beam model,the conventional Euler–Bernoulli(E-B)model holds the same flutter frequency in the supercritical region,while it usually overestimates the higher-order precession frequencies.The nonlocal,thermal,and flowing effects all can lead to buckling or different kinds of coupled flutter in the system.The material distribution of the P-type FGM nanotube can also induce coupled flutter,while that of the S-type FGM nanotube has no impact on the stability of the system.This paper is expected to provide a theoretical foundation for the design of motional composite nanodevices.
