Carbon dioxide(CO_(2)),resulting from the combustion of fossil fuels,is widely recognized as one of the main contributors to global warming.However,the existing carbon capture methods lack stability and cost-effective...Carbon dioxide(CO_(2)),resulting from the combustion of fossil fuels,is widely recognized as one of the main contributors to global warming.However,the existing carbon capture methods lack stability and cost-effectiveness.In order to tackle this issue,lithium-carbon dioxide batteries(LCBs)have emerged as a promising solution due to their high energy density and environmentally friendly nature.Nevertheless,the development of LCBs is still in its early stages,facing challenges such as low catalyst efficiency,electrolyte system instability,and an unclear mechanism.This review focuses on the reaction mechanism and cathodic catalysts of various types of LCBs,which include aprotic LCBs,photo-assisted LCBs,and allsolid-state LCBs.Lastly,the review paper summarizes the current problems and challenges associated with LCBs,providing suggestions and solutions to further advance the development and research of the LCB system.展开更多
基金support for this work from the Fund Project for the National Defense Technology Innovation Special Zone Spark Project(2016300TS00911901)a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)+1 种基金the Postgraduate Research&Practice Innovation Program of NUAA(xcxjh20230608 and xcxjh20230614)the Project of Zhongyuan Critical Metals Laboratory(GJJSGFYQ202422).
文摘Carbon dioxide(CO_(2)),resulting from the combustion of fossil fuels,is widely recognized as one of the main contributors to global warming.However,the existing carbon capture methods lack stability and cost-effectiveness.In order to tackle this issue,lithium-carbon dioxide batteries(LCBs)have emerged as a promising solution due to their high energy density and environmentally friendly nature.Nevertheless,the development of LCBs is still in its early stages,facing challenges such as low catalyst efficiency,electrolyte system instability,and an unclear mechanism.This review focuses on the reaction mechanism and cathodic catalysts of various types of LCBs,which include aprotic LCBs,photo-assisted LCBs,and allsolid-state LCBs.Lastly,the review paper summarizes the current problems and challenges associated with LCBs,providing suggestions and solutions to further advance the development and research of the LCB system.
