Modern chromatography is increasingly focused on miniaturization and integration. Compared to conventional liquid chromatography, microfluidic chip liquid chromatography(microchip-LC) has the potential due to its zero...Modern chromatography is increasingly focused on miniaturization and integration. Compared to conventional liquid chromatography, microfluidic chip liquid chromatography(microchip-LC) has the potential due to its zero-dead volume connection and ease of integration. Nano-sized packings have the potential to significantly enhance separation performance in microchip-LC. However, their application has been hindered by packing difficulties. This study presents a method for packing nano-sized silica particles into a microchannel as the stationary phase. The microchip-LC packed column was prepared by combining the weir and the porous silica single-particle as frit to retain the packing particles. A surface tensionbased single-particle picking technique was established to insert porous single-particle frit into glass microchannels. Additionally, we developed a slurry packing method that utilizes air pressure to inject nano-sized packing into the microchannel. Pressure-driven chromatographic separation was performed using this nano-packed column integrated into a glass microchip. The mixture of four PAHs was successfully separated within just 8 min using a 5 mm separation channel length, achieving high theoretical plates(10~6plates/m). Overall, these findings demonstrate the potential of utilizing nano-sized packings for enhancing chromatographic performance in microchip systems.展开更多
Conventional four-probe methods for measuring the resistance of Josephson junctions can damage superconducting thin films,making them unsuitable for frequency measurements of superconducting qubits.In this study,we pr...Conventional four-probe methods for measuring the resistance of Josephson junctions can damage superconducting thin films,making them unsuitable for frequency measurements of superconducting qubits.In this study,we present a custom probe station measurement system that employs the fritting contact technique to achieve in situ,non-destructive measurements of Josephson junction resistance.Our experimental results demonstrate that this method allows for accurate prediction of qubit frequency with an error margin of 17.2 MHz.Moreover,the fritting contact technique does not significantly affect qubit coherence time or the integrity of the superconducting film,confirming its non-destructive nature.This innovative approach provides a dependable foundation for frequency tuning and addressing frequency collision issues,thus supporting the advancement and practical deployment of superconducting quantum computing.展开更多
Bright long afterglow phosphorescence glasses were prepared by using SrAl2O4： Eu^2＋, Dy^3＋ phosphors and suitable glass frits together. The SrAl2O4： Eu^2＋, Dy^3＋ phosphors were initially prepared by the solid re...Bright long afterglow phosphorescence glasses were prepared by using SrAl2O4： Eu^2＋, Dy^3＋ phosphors and suitable glass frits together. The SrAl2O4： Eu^2＋, Dy^3＋ phosphors were initially prepared by the solid reaction method. Three kinds of glass frits were prepared to match the SrAl2O4： Eu^2＋, Dy^3＋ phosphors. Effects of the compositions of the glass frits, the ratios of the phosphors to the frits us well us the firing temperature and firing times on the properties of the samples were discussed. XRD analysis indicated the samples exhibited the typical diffraction peaks of SrAlwO4： Eu^2＋, Dy^3＋. The emission spectra of the samples showed broad bands peaking at 510nm.The excitation spectra of the samples showed broad bands ranging from 300 to 480hm. These are believed due to the 5d4f-4f transitions of Eu^2＋ in the SrAl2O4： Eu^2＋, Dy^3＋ phosphors. The afterglow luminescence of the samples excited by a 40W fluorescence lamp for 30min can be observed in the dark for more lOh with the naked eyes. It can find wide applications in many fields.展开更多
A simple electroless plating process was employed to prepare silver-coated glass frits for solar cells. The surface of the glass frits was modified with polyvinyl-pyrrolidone（PVP） before the electroless plating proc...A simple electroless plating process was employed to prepare silver-coated glass frits for solar cells. The surface of the glass frits was modified with polyvinyl-pyrrolidone（PVP） before the electroless plating process. Infrared（IR） spectroscopy,field emission scanning electron microscopy（FESEM）, and x-ray diffraction（XRD） were used to characterize the PVP modified glass frits and investigate the mechanism of the modification process. It was found that the PVP molecules adsorbed on the glass frit surface and reduced the silver ions to the silver nanoparticles. Through epitaxial growth, these nanoparticles were uniformly deposited onto the surface of the glass frit. Silicon solar cells with this novel silver coating exhibited a photoelectric conversion efficiency increase of 0.33%. Compared with the electroless plating processes, this method provides a simple route to prepare silver-coated glass frits without introducing impurity ions.展开更多
In this investigation, an attempt has been made to develop Al6061-Frit particulate metal matrix composites through stir casting technique using metal molds and to study the corrosion behaviour. Pre heated frit particl...In this investigation, an attempt has been made to develop Al6061-Frit particulate metal matrix composites through stir casting technique using metal molds and to study the corrosion behaviour. Pre heated frit particles were added to matrix as reinforcement. Al6061 containing 2 wt% to 8 wt % in steps of 2 wt % of frit particulate composites were prepared. Corrosion tests were conducted by using Potentiostat model SEP238C where 3.5% NaCl solution was used as corrodent. The corrosion rate of metal matrix composites was lower than that of matrix material Al6061 under the corrosive atmosphere for both un-heat treated and heat treated conditions.展开更多
In this work,a novel kind of particulate capillary precolumns with double-end polymer monolithic frits has been developed.Firstly,the polymer monolithic frit at one end was prepared via photo-initiated polymerization ...In this work,a novel kind of particulate capillary precolumns with double-end polymer monolithic frits has been developed.Firstly,the polymer monolithic frit at one end was prepared via photo-initiated polymerization of a mixture of lauryl methacrylate and ethyleneglycol dimethacrylate with 1-propanol and 1,4-butanediol as porogens and 2,2-dimethoxy-2-phenylacetophenone as a photo-initiator in UV transparent coating capillary（100 μm i.d.）.Subsequently,C18 particles（5 μm,100 A） were packed into the capillary,and sealed with the polymer monolithic frit at another end.To prevent the reaction of monomers and C18 particles,the packed C18 particles were masked during UV exposure.The loading capacity of such a precolumn was determined to be about 9 μg by frontal analysis with a synthetic peptide APGDR1 YVHPF as a model sample.Furthermore,two parallel precolumns were incorporated into a two-dimensional nano-liquid chromatography（2D nano-LC） system with dual capillary trap columns for peptide trapping and concentration.Compared to 2D nano-LC system with a single trap column,such two dimensional separations could be operated simultaneously to improve the analysis throughput.All these results demonstrated that such capillary precolumns with double frits would be promising for high-throughput proteome analysis.展开更多
The role of using frits in developing glazes for ceramics has increasingly received attention across a number of industrial ceramics fields in recent years. Over the past decade, the link between using frits for devel...The role of using frits in developing glazes for ceramics has increasingly received attention across a number of industrial ceramics fields in recent years. Over the past decade, the link between using frits for developing ceramics glazes and the reduction of financial costs has been at the center of much attention. Determining the impact of using frits in the local ceramics industry in Oman is important for the future study of this creative field. Using imported ready-made glazes, despite their long commercial success, is associated with a number of problems, including a shortage of suppliers, high costs, and logistical difficulties. Consequently, there is an urgent need to address the importance of developing glazes locally to help establish some workable solutions for the aforementioned problems. To date, no research studies have investigated using local Omani earthenware clays to make glazes by combining them with commercial frits using empirical laboratory methodologies. By developing low temperature chemical glaze recipes, the main aim of this study is to explore the possibilities of using Omani earthenware clays (OECs) and frits to create glazes that are suitable for local Omani ceramic works.展开更多
Efficient representation of linear singularities is discussed in this paper. We analyzed the relationship between the ＂wrap around＂ effect and the distribution of FRAT （Finite Radon Transform） coefficients first, ...Efficient representation of linear singularities is discussed in this paper. We analyzed the relationship between the ＂wrap around＂ effect and the distribution of FRAT （Finite Radon Transform） coefficients first, and then based on study of some properties of the columnwisely FRAT reconstruction procedure, we proposed an energy-based adaptive orthogonal FRIT scheme （EFRIT）. Experiments using nonlinear approximation show its superiority in energy concentration over both Discrete Wavelet Transform （DWT） and Finite Ridgelet Transform （FRIT）. Furthermore, we have modeled the denoising problem and proposed a novel threshold selecting method. Experiments carried out on images containing strong linear singularities and texture components with varying levels of addictive white Gaussian noise show that our method achieves prominent improvement in terms of both SNR and visual quality as compared with that of DWT and FRIT.展开更多
基金supported by the National Natural Science Foundation of China (No.21936001)the Beijing Outstanding Young Scientist Program (No.BJJWZYJH01201910005017)。
文摘Modern chromatography is increasingly focused on miniaturization and integration. Compared to conventional liquid chromatography, microfluidic chip liquid chromatography(microchip-LC) has the potential due to its zero-dead volume connection and ease of integration. Nano-sized packings have the potential to significantly enhance separation performance in microchip-LC. However, their application has been hindered by packing difficulties. This study presents a method for packing nano-sized silica particles into a microchannel as the stationary phase. The microchip-LC packed column was prepared by combining the weir and the porous silica single-particle as frit to retain the packing particles. A surface tensionbased single-particle picking technique was established to insert porous single-particle frit into glass microchannels. Additionally, we developed a slurry packing method that utilizes air pressure to inject nano-sized packing into the microchannel. Pressure-driven chromatographic separation was performed using this nano-packed column integrated into a glass microchip. The mixture of four PAHs was successfully separated within just 8 min using a 5 mm separation channel length, achieving high theoretical plates(10~6plates/m). Overall, these findings demonstrate the potential of utilizing nano-sized packings for enhancing chromatographic performance in microchip systems.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12034018 and 11625419).
文摘Conventional four-probe methods for measuring the resistance of Josephson junctions can damage superconducting thin films,making them unsuitable for frequency measurements of superconducting qubits.In this study,we present a custom probe station measurement system that employs the fritting contact technique to achieve in situ,non-destructive measurements of Josephson junction resistance.Our experimental results demonstrate that this method allows for accurate prediction of qubit frequency with an error margin of 17.2 MHz.Moreover,the fritting contact technique does not significantly affect qubit coherence time or the integrity of the superconducting film,confirming its non-destructive nature.This innovative approach provides a dependable foundation for frequency tuning and addressing frequency collision issues,thus supporting the advancement and practical deployment of superconducting quantum computing.
基金supported by the Jilin Provincial Natural Science Foundation of China(No.20040506-1).
文摘Bright long afterglow phosphorescence glasses were prepared by using SrAl2O4： Eu^2＋, Dy^3＋ phosphors and suitable glass frits together. The SrAl2O4： Eu^2＋, Dy^3＋ phosphors were initially prepared by the solid reaction method. Three kinds of glass frits were prepared to match the SrAl2O4： Eu^2＋, Dy^3＋ phosphors. Effects of the compositions of the glass frits, the ratios of the phosphors to the frits us well us the firing temperature and firing times on the properties of the samples were discussed. XRD analysis indicated the samples exhibited the typical diffraction peaks of SrAlwO4： Eu^2＋, Dy^3＋. The emission spectra of the samples showed broad bands peaking at 510nm.The excitation spectra of the samples showed broad bands ranging from 300 to 480hm. These are believed due to the 5d4f-4f transitions of Eu^2＋ in the SrAl2O4： Eu^2＋, Dy^3＋ phosphors. The afterglow luminescence of the samples excited by a 40W fluorescence lamp for 30min can be observed in the dark for more lOh with the naked eyes. It can find wide applications in many fields.
文摘A simple electroless plating process was employed to prepare silver-coated glass frits for solar cells. The surface of the glass frits was modified with polyvinyl-pyrrolidone（PVP） before the electroless plating process. Infrared（IR） spectroscopy,field emission scanning electron microscopy（FESEM）, and x-ray diffraction（XRD） were used to characterize the PVP modified glass frits and investigate the mechanism of the modification process. It was found that the PVP molecules adsorbed on the glass frit surface and reduced the silver ions to the silver nanoparticles. Through epitaxial growth, these nanoparticles were uniformly deposited onto the surface of the glass frit. Silicon solar cells with this novel silver coating exhibited a photoelectric conversion efficiency increase of 0.33%. Compared with the electroless plating processes, this method provides a simple route to prepare silver-coated glass frits without introducing impurity ions.
文摘In this investigation, an attempt has been made to develop Al6061-Frit particulate metal matrix composites through stir casting technique using metal molds and to study the corrosion behaviour. Pre heated frit particles were added to matrix as reinforcement. Al6061 containing 2 wt% to 8 wt % in steps of 2 wt % of frit particulate composites were prepared. Corrosion tests were conducted by using Potentiostat model SEP238C where 3.5% NaCl solution was used as corrodent. The corrosion rate of metal matrix composites was lower than that of matrix material Al6061 under the corrosive atmosphere for both un-heat treated and heat treated conditions.
基金the financial support from National Basic Research Program of China(No.2012CB910604)National Natural Science Foundation of China(No.20935004)+1 种基金the Creative Research Group Project by NSFC(No.21321064)National High Technology Research and Development Program of China (No.2012AA020202)
文摘In this work,a novel kind of particulate capillary precolumns with double-end polymer monolithic frits has been developed.Firstly,the polymer monolithic frit at one end was prepared via photo-initiated polymerization of a mixture of lauryl methacrylate and ethyleneglycol dimethacrylate with 1-propanol and 1,4-butanediol as porogens and 2,2-dimethoxy-2-phenylacetophenone as a photo-initiator in UV transparent coating capillary（100 μm i.d.）.Subsequently,C18 particles（5 μm,100 A） were packed into the capillary,and sealed with the polymer monolithic frit at another end.To prevent the reaction of monomers and C18 particles,the packed C18 particles were masked during UV exposure.The loading capacity of such a precolumn was determined to be about 9 μg by frontal analysis with a synthetic peptide APGDR1 YVHPF as a model sample.Furthermore,two parallel precolumns were incorporated into a two-dimensional nano-liquid chromatography（2D nano-LC） system with dual capillary trap columns for peptide trapping and concentration.Compared to 2D nano-LC system with a single trap column,such two dimensional separations could be operated simultaneously to improve the analysis throughput.All these results demonstrated that such capillary precolumns with double frits would be promising for high-throughput proteome analysis.
文摘The role of using frits in developing glazes for ceramics has increasingly received attention across a number of industrial ceramics fields in recent years. Over the past decade, the link between using frits for developing ceramics glazes and the reduction of financial costs has been at the center of much attention. Determining the impact of using frits in the local ceramics industry in Oman is important for the future study of this creative field. Using imported ready-made glazes, despite their long commercial success, is associated with a number of problems, including a shortage of suppliers, high costs, and logistical difficulties. Consequently, there is an urgent need to address the importance of developing glazes locally to help establish some workable solutions for the aforementioned problems. To date, no research studies have investigated using local Omani earthenware clays to make glazes by combining them with commercial frits using empirical laboratory methodologies. By developing low temperature chemical glaze recipes, the main aim of this study is to explore the possibilities of using Omani earthenware clays (OECs) and frits to create glazes that are suitable for local Omani ceramic works.
基金Scientific Research Foundation for the Returned Overseas Chinese Scholarsthe Ministry of Education (Grant No. 2004.176.4)the Natural Science Foundation of Shandong Province (Grant Nos. Z2004G01 and 2004ZRC03016)
文摘Efficient representation of linear singularities is discussed in this paper. We analyzed the relationship between the ＂wrap around＂ effect and the distribution of FRAT （Finite Radon Transform） coefficients first, and then based on study of some properties of the columnwisely FRAT reconstruction procedure, we proposed an energy-based adaptive orthogonal FRIT scheme （EFRIT）. Experiments using nonlinear approximation show its superiority in energy concentration over both Discrete Wavelet Transform （DWT） and Finite Ridgelet Transform （FRIT）. Furthermore, we have modeled the denoising problem and proposed a novel threshold selecting method. Experiments carried out on images containing strong linear singularities and texture components with varying levels of addictive white Gaussian noise show that our method achieves prominent improvement in terms of both SNR and visual quality as compared with that of DWT and FRIT.
