Environmental conditions determining the timing of the lifetime maximum intensities of tropical cyclones(TCs)are investigated for the TCs over the western North Pacific during the period 2008-2017.The results show tha...Environmental conditions determining the timing of the lifetime maximum intensities of tropical cyclones(TCs)are investigated for the TCs over the western North Pacific during the period 2008-2017.The results show that the land controls the timings of the lifetime maximum intensities in 42% of the TCs over this basin,indicating that accurate track forecasts are beneficial for TC intensity forecasts.With respect to other TCs that are not affected by the land(i.e.,Ocean-TCs),the timings of their lifetime maximum intensities are determined by multiple oceanic factors.In particular,interactions between TCs and cold-core eddies occur in a large proportion(nearly 60%)of Ocean-TCs at or shortly after the times of their lifetime maximum intensities,especially in strong TCs(categories 4 and 5),suggesting that a consideration of the above interactions is necessary for improving TC intensity forecasting skills.In addition,unfavorable oceanic heat content conditions become common as the latitude increases over 25°N,influencing half of the Ocean-TCs.Strong vertical wind shear contributes detrimentally to the atmospheric environment in 17% of the TCs over this basin,especially in moderate and weak TCs.In contrast,neither the maximum potential intensity nor the humidity in the middle level of the atmosphere plays dominant roles when TCs turn from their peak intensities to weakening.展开更多
Considerable interest in hydrogen bonding involving chalcogen has been growing since the IUPAC committee has redefined hydrogen bonding. Not only the focus is on unconventional acceptors, but also on donors not discus...Considerable interest in hydrogen bonding involving chalcogen has been growing since the IUPAC committee has redefined hydrogen bonding. Not only the focus is on unconventional acceptors, but also on donors not discussed before. It has been mentioned in previous studies that the proton of the H-C group could be involved in hydrogen bonding, but with conventional acceptors. In this study, we explored the ability of hydrogen bond formation of Se, S and Te acceptors with the H-C donor using Cambridge Structural Database in conjunction with Ab Initio calculations. In the CSD, there are respectively 256, 6249 and 11 R1,R2,-C=Se, R1,R2,-C=S and R1,R2,-C=Te structures that form hydrogen bonds, in which the N,N groups are majority. Except for C=S acceptor which can form a hydrogen bond with its C, C group, both C=Se and C=Te acceptors could form a hydrogen bond only with N,C and N,N groups. CSD analysis shows very similar d (norm) around -0.04 Å, while DFT-calculated interaction for N,C and N,N groups are also similar. Both interaction distances derived from CSD analysis and DFT-calculated interaction energies demonstrate that the acceptors form stable complexes with H-CF3. Besides hydrogen bonds, dispersion interactions are forces stabilizing the complexes since their contribution can reach 50%. Analysis of intra-molecular geometries and Ab Initio partial charges show that this bonding stems from resonance induced C<sup>δ+</sup>=X<sup>δ-</sup> dipoles. In many respects, both C=Se, C=S and C=Te are similar to C=S, with similar d (norm) and calculated interaction strengths.展开更多
The Kuroshio frontal instable processes （KFIP） in the East China Sea （ECS） not only have a great impact on the hydrologic characteristics,the pollutants drift,the distribution of seafloor sediment and the ships na...The Kuroshio frontal instable processes （KFIP） in the East China Sea （ECS） not only have a great impact on the hydrologic characteristics,the pollutants drift,the distribution of seafloor sediment and the ships navigation of the ECS,but also are closely related to the climate changes of the coastal areas of the ECS.However the frequency and area of occurrence of the KFIP have not been studied fully and detailedly.Because of its high spatial and temporal resolution,MODIS data is a kind of very good data source for surveying and researching the KFIP in the ECS.The aim of this study is to detect the KFIP in the ECS by using MODIS data,and to study the frequency and region of occurrence of the KFIP in the ECS.The selection has coverage of level 2 data of MODIS SST and Kd490 ranging from July 1,2002 to June 30,2009 of the ECS when there was no cloud impact or little.By using of the data,the minimum standard of the Kuroshio temperature fronts and the diffuse attenuation coefficient （Kd490） fronts of the ECS are given.Based on these standards and the curvature distinguish methods,the standard of curvature distinguish for the KFIP in the ECS are put forward.By making use of this standard,we study a total of 2073 satellite-derived images,and discover that as long as there is no cloud impact from January to May and October to December,the KFIP in the ECS are surely found in MODIS satellite images.From June to September,the frequency of occurrence can also reach to 82.9% at least.Moreover,it is obtained that there are three source regions of these instability processes,namely,（26°N,121.5°E） nearby,（27°N,125°E） nearby and （30°N,128°E） nearby.The differences of the characteristics of these instability processes which are generated in different regions are analyzed in the present study.展开更多
基金National Key Research and Development Program of China(2018YFC1506402)National Natural Scientific Foundations of China(41575061,41775061)JSPS KAKENHI(JP18H01283)。
文摘Environmental conditions determining the timing of the lifetime maximum intensities of tropical cyclones(TCs)are investigated for the TCs over the western North Pacific during the period 2008-2017.The results show that the land controls the timings of the lifetime maximum intensities in 42% of the TCs over this basin,indicating that accurate track forecasts are beneficial for TC intensity forecasts.With respect to other TCs that are not affected by the land(i.e.,Ocean-TCs),the timings of their lifetime maximum intensities are determined by multiple oceanic factors.In particular,interactions between TCs and cold-core eddies occur in a large proportion(nearly 60%)of Ocean-TCs at or shortly after the times of their lifetime maximum intensities,especially in strong TCs(categories 4 and 5),suggesting that a consideration of the above interactions is necessary for improving TC intensity forecasting skills.In addition,unfavorable oceanic heat content conditions become common as the latitude increases over 25°N,influencing half of the Ocean-TCs.Strong vertical wind shear contributes detrimentally to the atmospheric environment in 17% of the TCs over this basin,especially in moderate and weak TCs.In contrast,neither the maximum potential intensity nor the humidity in the middle level of the atmosphere plays dominant roles when TCs turn from their peak intensities to weakening.
文摘Considerable interest in hydrogen bonding involving chalcogen has been growing since the IUPAC committee has redefined hydrogen bonding. Not only the focus is on unconventional acceptors, but also on donors not discussed before. It has been mentioned in previous studies that the proton of the H-C group could be involved in hydrogen bonding, but with conventional acceptors. In this study, we explored the ability of hydrogen bond formation of Se, S and Te acceptors with the H-C donor using Cambridge Structural Database in conjunction with Ab Initio calculations. In the CSD, there are respectively 256, 6249 and 11 R1,R2,-C=Se, R1,R2,-C=S and R1,R2,-C=Te structures that form hydrogen bonds, in which the N,N groups are majority. Except for C=S acceptor which can form a hydrogen bond with its C, C group, both C=Se and C=Te acceptors could form a hydrogen bond only with N,C and N,N groups. CSD analysis shows very similar d (norm) around -0.04 Å, while DFT-calculated interaction for N,C and N,N groups are also similar. Both interaction distances derived from CSD analysis and DFT-calculated interaction energies demonstrate that the acceptors form stable complexes with H-CF3. Besides hydrogen bonds, dispersion interactions are forces stabilizing the complexes since their contribution can reach 50%. Analysis of intra-molecular geometries and Ab Initio partial charges show that this bonding stems from resonance induced C<sup>δ+</sup>=X<sup>δ-</sup> dipoles. In many respects, both C=Se, C=S and C=Te are similar to C=S, with similar d (norm) and calculated interaction strengths.
基金the special funds for marine commonweal research under contract No.200705027variability of the subtropical gyre in North Pacific and its impacts on dynamic environment of China marginal seas under contract No.2007CB411800defense industrial technology development program and the special funds for basic scientific research project of the First Institute of Oceanography,SOA under contract No.2010G12
文摘The Kuroshio frontal instable processes （KFIP） in the East China Sea （ECS） not only have a great impact on the hydrologic characteristics,the pollutants drift,the distribution of seafloor sediment and the ships navigation of the ECS,but also are closely related to the climate changes of the coastal areas of the ECS.However the frequency and area of occurrence of the KFIP have not been studied fully and detailedly.Because of its high spatial and temporal resolution,MODIS data is a kind of very good data source for surveying and researching the KFIP in the ECS.The aim of this study is to detect the KFIP in the ECS by using MODIS data,and to study the frequency and region of occurrence of the KFIP in the ECS.The selection has coverage of level 2 data of MODIS SST and Kd490 ranging from July 1,2002 to June 30,2009 of the ECS when there was no cloud impact or little.By using of the data,the minimum standard of the Kuroshio temperature fronts and the diffuse attenuation coefficient （Kd490） fronts of the ECS are given.Based on these standards and the curvature distinguish methods,the standard of curvature distinguish for the KFIP in the ECS are put forward.By making use of this standard,we study a total of 2073 satellite-derived images,and discover that as long as there is no cloud impact from January to May and October to December,the KFIP in the ECS are surely found in MODIS satellite images.From June to September,the frequency of occurrence can also reach to 82.9% at least.Moreover,it is obtained that there are three source regions of these instability processes,namely,（26°N,121.5°E） nearby,（27°N,125°E） nearby and （30°N,128°E） nearby.The differences of the characteristics of these instability processes which are generated in different regions are analyzed in the present study.
