LiMnxFe1-xPO_(4) is a promising cathode candidate due to its high security and the availability of a high 4.1 V operating voltage and high energy density.However,the poor electrochemical kinetics and structural instab...LiMnxFe1-xPO_(4) is a promising cathode candidate due to its high security and the availability of a high 4.1 V operating voltage and high energy density.However,the poor electrochemical kinetics and structural instability currently hinder its broader application.Herein,inspired by the hydrogen-bonded cross-linking and steric hindrance effect between short-chain polymer molecules(polyethylene glycol-400,PEG-400),the pomegranate-type LiMn_(0.5)Fe_(0.5)PO_(4)-0.5@C(P-LMFP@C)cathode materials with 3D ion/electron dual-conductive network structure were constructed through ball mill-assisted spray-drying method.The intermolecular effects of PEG-400 promote the spheroidization and uniform PEG coating of LMFP precursor,which prevents agglomeration during sintering.The 3D ion/electron dual-conductive network structure in P-LMFP@C accelerates the Li^(+)transport kinetics,improving the rate performance and cycling stability.As a result,the designed P-LMFP@C has remarkable electrochemical behavior,boasting excellent capacity retention(98%after 100 cycles at the 1C rate)and rate capability(91 mAh·g^(-1)at 20C).Such strategy introduces a novel window for designing high-performance olivine cathodes and offers compatibility with a range of energy storage materials for diverse applications.展开更多
Cold air is one key factor affecting the freezing process of ice tanks.The volume of fluid method is employed to simulate the freezing process of water in an ice tank with cold air inlets.The temperature field distrib...Cold air is one key factor affecting the freezing process of ice tanks.The volume of fluid method is employed to simulate the freezing process of water in an ice tank with cold air inlets.The temperature field distribution in the ice tank is calculated.The temperature field at different typical instants are compared.The main characteristics of the freezing process in an ice tank driven by cold air are analyzed.The influence of the number of cold air inlets on the freezing process is investigated.The numerical results show that with increasing the number of cold air inlets,the temperature field becomes more uniform.The inlet velocity of cold air has a great influence on the generation of ice.This work can serve for the design of the ice tank and control of the freezing process.展开更多
Frost heave in water-bearing rock masses poses significant threats to geotechnical engineering.This paper developed a novel three-dimensional(3D)frost model,based on the combined finite-discrete element method(FDEM),t...Frost heave in water-bearing rock masses poses significant threats to geotechnical engineering.This paper developed a novel three-dimensional(3D)frost model,based on the combined finite-discrete element method(FDEM),to investigate the frost heave process in rock masses where thermal transfer,water migration,water-ice phase transition(ice growth)and ice-rock interaction are explicitly simulated.The proposed model is first validated against existing experimental and analytical solutions,and further applied to investigate path-dependent frost heave behavior under various freezing conditions.Results show that freezing direction plays a vital role in the dynamic ice growth and ice-rock interaction,thus affecting the frost heave behavior.In the top-down freezing regime,ice plugs form first at the crack's top surface,sealing the crack and preventing water migration,which can amplify ice pressure.Parametric studies,including rock Young's modulus,ice-rock friction,and rock hydraulic conductivity,further reveal that the temporal aspects of ice development and rock mechanical response strongly affect ice-rock interaction and hence the frost heave mechanism.Furthermore,some typical phenomena(e.g.water/ice extrusion and frost cracking)can also be well captured in this model.This novel numerical framework sheds new light on frost heave behavior and enriches our understanding of frost heave mechanisms and ice-rock interaction processes within cold environment engineering projects.展开更多
The coupled heat and moisture transfer in a freezing process of wood particle material was mathematically modeled in the paper. The models were interactively solved by using the numerical method(the finite element met...The coupled heat and moisture transfer in a freezing process of wood particle material was mathematically modeled in the paper. The models were interactively solved by using the numerical method(the finite element method and the finite difference method). By matching the theoretical calculation to an experiment, the nonlinear problem was analyzed and the variable thermophysical parameters concerned was evaluated. The analysis procedure and the evaluation of the parameters were presented in detail. The result of the study showed that by using the method as described in the paper, it was possible to determine the variable (with respect to temperature, moisture content and freezing state) thermophysical parameters which were unknown or difficult to measure as long as the governing equations for a considered process were available. The method can significantly reduces the experiment efforts for determining thermophysical parameters which arc very complicated to measure. The determined variable of the effective heat conductivity of wood particle material was given in the paper. The error of the numerical calculation was also estimated by the comparison with a matched experiment.展开更多
Heavy metal pollution of soil has become one of the most common hazards in human development.The artificial freezing method,especially the progressive freezing method,can reduce heavy metal pollutants in the soil and ...Heavy metal pollution of soil has become one of the most common hazards in human development.The artificial freezing method,especially the progressive freezing method,can reduce heavy metal pollutants in the soil and promises to be an effective in-situ treatment of contaminated sites.This study analyzes the freezing purification mechanism of heavy metal contaminants in saturated sand and identifies three main factors that impact the effects of purification:freezing rate,initial concentration,and diffusion coefficient.Moreover,one-dimensional freezing tests are carried out by different freezing modes.The experimental results show that the heavy metal chromium could only be removed effectively with a slow freezing rate.By optimizing the freezing mode and freezing rate,a long section of soil was frozen and purified,with the maximum purification rate reaching 65.8%.This study shows that it is feasible to treat contaminated saturated sand by a gradual-cooling freezing method.展开更多
The objective was to investigate the major effect of freezing rate and freezing methods on physical properties of fish balls made with various flour contents. The fish balls were observed to be almost in temperature a...The objective was to investigate the major effect of freezing rate and freezing methods on physical properties of fish balls made with various flour contents. The fish balls were observed to be almost in temperature at -28℃ for air-blast freezer, at -100 ℃ in the liquid nitrogen and the standard house freezing were done at -18℃. The air-blast had the freezing rate of 11.82-20.84 cm h1 while those frozen by liquid nitrogen had the freezing rate of 13.36-22.38 cm/h and standard house freezer held lower freezing rate （7. ! 5-8.02 cm hl）. Texture profile analysis results showed that ubi badak＇s flour gel was harder, sticky, gummy and chewy than that of wheat and banana＇s flour gels. The proximate analysis revealed that wheat flour had higher protein and moisture content compared to banana and ubi badak flours.展开更多
The mean activity coefficient of 5, 10,15 , 20-tetrakis (P-methoxyl-O-sulfophenyl)porphyrin sodium in dilute aqueous solution has been determined in the modality range 0. 00547-0. 08871 mol · kg-1at 273. 2 K by t...The mean activity coefficient of 5, 10,15 , 20-tetrakis (P-methoxyl-O-sulfophenyl)porphyrin sodium in dilute aqueous solution has been determined in the modality range 0. 00547-0. 08871 mol · kg-1at 273. 2 K by the freezing-point depression method . The results of γ± are 0. 9945-0. 7695, it is in close agreement with that by isopiestic method.展开更多
Freezing in ice rubble is a common phenomenon in cold regions,which can consolidate loose blocks and change their mechanical properties.To model the cohesive effect in frozen ice rubble,and to describe the fragmentati...Freezing in ice rubble is a common phenomenon in cold regions,which can consolidate loose blocks and change their mechanical properties.To model the cohesive effect in frozen ice rubble,and to describe the fragmentation behavior with a large external forces exerted,a freeze-bond model based on the dilated polyhedral discrete element method(DEM)is proposed.Herein,imaginary bonding is initialized at the contact points to transmit forces and moments,and the initiation of the damage is detected using the hybrid fracture model.The model is validated through the qualitative agreement between the simulation results and the analytical solution of two bonding particles.To study the effect of freeze-bond on the floating ice rubble,punch-through tests were simulated on the ice rubble under freezing and nonfreezing conditions.The deformation and resistance of the ice rubble are investigated during indenter penetration.The influence of the internal friction coefficient on the strength of the ice rubble is determined.The results indicate that the proposed model can properly describe the consolidated ice rubble,and the freeze-bond effect is of great significance to the ice rubble properties.展开更多
In order to prolong semen preservation and improve pregnancy rate, semen freezing was studied with German shepherd dogs for experimental animals. The semen of four dogs was collected 40 times in four dilution frozen i...In order to prolong semen preservation and improve pregnancy rate, semen freezing was studied with German shepherd dogs for experimental animals. The semen of four dogs was collected 40 times in four dilution frozen into two formulations, according to the sperm motility to compare the advantages and disadvantages. The result indicated that the sperm motility of the pellet frozen semen in dilute 2 was significantly higher than that in dilution 1, 3, and 4 （P0.01）. The sperm motility of dogs semen with fried smoked method was notablely higher than that of frozen semen of program method （P0.01）. The dilution which contained yolk-Tris mainly was the best; the pellet semen frozen with fried smoked method was superior to tuble semen frozen with program freezing method; sperm motility of pellet semen was higher than that of tuble semen in the same dilution. The conception rate and litter size of the natural matting were higher than AI.展开更多
In this study, the Single Factor Test（SFT） was used to optimize the pre-freezing conditions of L. plantarum KLDS1.0391（KLDS1.0391）. Further, the Freeze-Drying Protective Agents（FDPA） of KLDS1.0391 was optimized ...In this study, the Single Factor Test（SFT） was used to optimize the pre-freezing conditions of L. plantarum KLDS1.0391（KLDS1.0391）. Further, the Freeze-Drying Protective Agents（FDPA） of KLDS1.0391 was optimized by Response Surface Methodology（RSM）. The optimum pretreatment conditions were as the follows： initial concentration of KLDS1.0391 was 1011 CFU · m L-1 and KLDS1.0391 was pre-freezed at –80℃ for 8 h to achieve the survival rate of 46.21%. The main components of FDPA were skim milk, sucrose, sodium glutamate and Tween-80. And the influence of four factors on the survival rate of KLDS1.0391 in freeze-drying was in order as the follows： skim milk〉sucrose〉Tween-80〉sodium glutamate. The optimal FDPA composition was skim milk 11.3%, sucrose 9.8%, sodium glutamate 5.1% and Tween-80 0.2%. Under the above conditions, the survival rate of the cells was 82.98%. Comparing the predicted values, the relative error was 0.37% and the difference was not significant, which indicated that the established model could effectively reflect the actual protection of FDPA to KLDS1.0391.展开更多
Purpose–This study purposes to study the influence of artificial freezing on the liquefaction characteristics of Nanjing sand,as well as its mechanism.Design/methodology/approach–was studied through dynamic triaxial...Purpose–This study purposes to study the influence of artificial freezing on the liquefaction characteristics of Nanjing sand,as well as its mechanism.Design/methodology/approach–was studied through dynamic triaxial tests by means of the GDS dynamic triaxial system on Nanjing sand extensively discovered in the middle and lower reaches of the Yangtze River under seismic load and metro train vibration load,respectively,and potential hazards of the two loads to the freezing construction of Nanjing sand were also identified in the tests.Findings–The results show that under both seismic load and metro train vibration load,freeze-thaw cycles will significantly reduce the stiffness and liquefaction resistance of Nanjing sand,especially in the first freezethaw cycle;the more freeze-thaw cycles,the worse structural behaviors of silty-fine sand,and the easier to liquefy;freeze-thaw cycles will increase the sensitivity of Nanjing sand’s dynamic pore pressure to dynamic load response;the lower the freezing temperature and the effective confining pressure,the worse the liquefaction resistance of Nanjing sand after freeze-thaw cycles;compared to the metro train vibration load,the seismic load in Nanjing is potentially less dangerous to freezing construction of Nanjing sand.Originality/value–The research results are helpful to the construction of the artificial ground freezing of the subway crossing passage in the lower reaches of the Yangtze River and to ensure the construction safety of the subway tunnel and its crossing passage.展开更多
Freeze-sealing pipe roof method is applied in the Gongbei tunnel,which causes the ground surface uplift induced by frost heave.A frost heaving prediction approach based on the coefficient of cold expansion is proposed...Freeze-sealing pipe roof method is applied in the Gongbei tunnel,which causes the ground surface uplift induced by frost heave.A frost heaving prediction approach based on the coefficient of cold expansion is proposed to simulate the ground deformation of the Gongbei tunnel.The coefficient of cold expansion in the model and the frost heaving rate from the frost heave test under the hydration condition can achieve a good correspondence making the calculation result closer to the actual engineering.The ground surface uplift along the lateral and longitudinal direction are respectively analyzed and compared with the field measured data to validate the model.The results show that a good agreement between the frost heaving prediction model and the field measured data verifies the rationality and applicability of the proposed model.The maximum uplift of the Gongbei tunnel appears at the center of the model,gradually decreasing along with the lateral and longitudinal directions.The curve in the lateral direction presents a normal distribution due to the influence of the constraint of two sides,while the one along the lateral direction shapes like a parabola with the opening downward due to the temperature field distribution.The model provides a reference for frost heaving engineering calculation.展开更多
In-situ characterization of non-aqueous nano-dispersion systems（NANDS） by freeze-etching transmission electron microscope（FETEM） was reported.To improve just-for-once successive rate of specimen preparation and ge...In-situ characterization of non-aqueous nano-dispersion systems（NANDS） by freeze-etching transmission electron microscope（FETEM） was reported.To improve just-for-once successive rate of specimen preparation and get good characterization results,an improving specimen preparation method of freezing etching was developed.Size,distribution and morphology of NANDS were directly visualized.Some information of particle dispersion feature and particle density can also be obtained.Reproductivity of the FETEM characterization is excellent.Comparing with laser scattering method,which is liable to give positive error especially for small size particle anchoring disperser,FETEM characterization can give more accurate measurement of particle size.Moreover,FETEM can give dispersion feature of nanoparticle in non-aqueous medium.展开更多
In this paper,we use gambit and fluent to study the time needed and the temperature distribution of the plasma in the three frozen methods of air-cooled,plate-contact and alcohol-immersion quick freezing,this numerica...In this paper,we use gambit and fluent to study the time needed and the temperature distribution of the plasma in the three frozen methods of air-cooled,plate-contact and alcohol-immersion quick freezing,this numerical simulation was used to solve the limitation of the equipment in the actual experiment,so as to guide the experimental work.展开更多
Cadmium telluride(CdTe),which has a high average atomic number and a unique band structure,is a leading material for room-temperature X/γ-ray detectors.Resistivity and mobility are the two most important properties o...Cadmium telluride(CdTe),which has a high average atomic number and a unique band structure,is a leading material for room-temperature X/γ-ray detectors.Resistivity and mobility are the two most important properties of detector-grade CdTe single crystals.However,despite decades of research,the fabrication of high-resistivity and high-mobility CdTe single crystals faces persistent challenges,primarily because the stoichiometric composition cannot be well controlled owing to the high volatility of Cd under high-temperature conditions.This volatility introduces Te inclusions and cadmium vacancies(V_(Cd))into the as-grown CdTe ingot,which significantly degrades the device performance.In this study,we successfully obtained detector-grade CdTe single crystals by simultaneously employing a Cd reservoir and chlorine(Cl)dopants via a vertical gradient freeze(VGF)method.By installing a Cd reservoir,we can maintain the Cd pressure under the crystal growth conditions,thereby preventing the accumulation of Te in the CdTe ingot.Additionally,the existence of the Cl dopant helps improve the CdTe resistivity by minimizing V_(Cd)density through the formation of an acceptor complex(Cl_(Te)-V_(Cd))^(-1).The crystalline quality of the obtained CdTe(Cl)was evidenced by a reduction in large Te inclusions,high optical transmission(60%),and a sharp absorption edge(1.456 eV).The presence of substitutional Cl dopants,known as Cl_(Te)^(+),simultaneously supports the record high resistivity of 1.5×10^(10)Ω·cm and remarkable electron mobility of 1075±88 cm^(2)V^(-1)s^(-1)simultaneously,has been confirmed by photoluminescence spectroscopy.Moreover,using our crystals,we fabricated a planar detector withμτ_(e)of(1.11±0.04)×10^(-4)cm^(2)∕V,which performed with a decent radiation-detection feature.This study demonstrates that the vapor-pressure-controlled VGF method is a viable technical route for fabricating detector-grade CdTe crystals.展开更多
基金supported by the Key Technologies R&D Program of Xiamen(No.3502Z20231057)Industry Leading Key Projects of Fujian Province(No.2022H0057)+2 种基金the National Natural Science Foundation of China(No.21975212)High-Level Talent Start-Up Foundation of Xiamen Institute of Technology for financial support(No.YKJ23017R)Graduate Science and Technology Innovation Program of Xiamen University of Technology(No.YKJCX2023194).
文摘LiMnxFe1-xPO_(4) is a promising cathode candidate due to its high security and the availability of a high 4.1 V operating voltage and high energy density.However,the poor electrochemical kinetics and structural instability currently hinder its broader application.Herein,inspired by the hydrogen-bonded cross-linking and steric hindrance effect between short-chain polymer molecules(polyethylene glycol-400,PEG-400),the pomegranate-type LiMn_(0.5)Fe_(0.5)PO_(4)-0.5@C(P-LMFP@C)cathode materials with 3D ion/electron dual-conductive network structure were constructed through ball mill-assisted spray-drying method.The intermolecular effects of PEG-400 promote the spheroidization and uniform PEG coating of LMFP precursor,which prevents agglomeration during sintering.The 3D ion/electron dual-conductive network structure in P-LMFP@C accelerates the Li^(+)transport kinetics,improving the rate performance and cycling stability.As a result,the designed P-LMFP@C has remarkable electrochemical behavior,boasting excellent capacity retention(98%after 100 cycles at the 1C rate)and rate capability(91 mAh·g^(-1)at 20C).Such strategy introduces a novel window for designing high-performance olivine cathodes and offers compatibility with a range of energy storage materials for diverse applications.
基金the Key Technologies Research and Development Program(No.2022YFE0107000)the National Natural Science Foundation of China(No.52171259)。
文摘Cold air is one key factor affecting the freezing process of ice tanks.The volume of fluid method is employed to simulate the freezing process of water in an ice tank with cold air inlets.The temperature field distribution in the ice tank is calculated.The temperature field at different typical instants are compared.The main characteristics of the freezing process in an ice tank driven by cold air are analyzed.The influence of the number of cold air inlets on the freezing process is investigated.The numerical results show that with increasing the number of cold air inlets,the temperature field becomes more uniform.The inlet velocity of cold air has a great influence on the generation of ice.This work can serve for the design of the ice tank and control of the freezing process.
基金supported by the Natural Sciences and Engineering Research Council of Canada(Grant Nos.Discovery 341275,and CRDPJ 543894-19)NSERC/Energi Simulation Industrial Research Chair programState Key Laboratory of Geohazard Prevention and Geoenvironment Protection Open Fund(Grant No.SKLGP2024K001).
文摘Frost heave in water-bearing rock masses poses significant threats to geotechnical engineering.This paper developed a novel three-dimensional(3D)frost model,based on the combined finite-discrete element method(FDEM),to investigate the frost heave process in rock masses where thermal transfer,water migration,water-ice phase transition(ice growth)and ice-rock interaction are explicitly simulated.The proposed model is first validated against existing experimental and analytical solutions,and further applied to investigate path-dependent frost heave behavior under various freezing conditions.Results show that freezing direction plays a vital role in the dynamic ice growth and ice-rock interaction,thus affecting the frost heave behavior.In the top-down freezing regime,ice plugs form first at the crack's top surface,sealing the crack and preventing water migration,which can amplify ice pressure.Parametric studies,including rock Young's modulus,ice-rock friction,and rock hydraulic conductivity,further reveal that the temporal aspects of ice development and rock mechanical response strongly affect ice-rock interaction and hence the frost heave mechanism.Furthermore,some typical phenomena(e.g.water/ice extrusion and frost cracking)can also be well captured in this model.This novel numerical framework sheds new light on frost heave behavior and enriches our understanding of frost heave mechanisms and ice-rock interaction processes within cold environment engineering projects.
文摘The coupled heat and moisture transfer in a freezing process of wood particle material was mathematically modeled in the paper. The models were interactively solved by using the numerical method(the finite element method and the finite difference method). By matching the theoretical calculation to an experiment, the nonlinear problem was analyzed and the variable thermophysical parameters concerned was evaluated. The analysis procedure and the evaluation of the parameters were presented in detail. The result of the study showed that by using the method as described in the paper, it was possible to determine the variable (with respect to temperature, moisture content and freezing state) thermophysical parameters which were unknown or difficult to measure as long as the governing equations for a considered process were available. The method can significantly reduces the experiment efforts for determining thermophysical parameters which arc very complicated to measure. The determined variable of the effective heat conductivity of wood particle material was given in the paper. The error of the numerical calculation was also estimated by the comparison with a matched experiment.
基金supported by Major State Basic Research Development Program(Grant No.2012CB026103)111 Project of China(Grant No.B14021)+1 种基金National Natural Science Foundation of China(Grant No.51104146,Grant No.41271096)Open Fund of State Key Laboratory of Frozen Soil Engineering(Grant No.SKLFSE201704)。
文摘Heavy metal pollution of soil has become one of the most common hazards in human development.The artificial freezing method,especially the progressive freezing method,can reduce heavy metal pollutants in the soil and promises to be an effective in-situ treatment of contaminated sites.This study analyzes the freezing purification mechanism of heavy metal contaminants in saturated sand and identifies three main factors that impact the effects of purification:freezing rate,initial concentration,and diffusion coefficient.Moreover,one-dimensional freezing tests are carried out by different freezing modes.The experimental results show that the heavy metal chromium could only be removed effectively with a slow freezing rate.By optimizing the freezing mode and freezing rate,a long section of soil was frozen and purified,with the maximum purification rate reaching 65.8%.This study shows that it is feasible to treat contaminated saturated sand by a gradual-cooling freezing method.
文摘The objective was to investigate the major effect of freezing rate and freezing methods on physical properties of fish balls made with various flour contents. The fish balls were observed to be almost in temperature at -28℃ for air-blast freezer, at -100 ℃ in the liquid nitrogen and the standard house freezing were done at -18℃. The air-blast had the freezing rate of 11.82-20.84 cm h1 while those frozen by liquid nitrogen had the freezing rate of 13.36-22.38 cm/h and standard house freezer held lower freezing rate （7. ! 5-8.02 cm hl）. Texture profile analysis results showed that ubi badak＇s flour gel was harder, sticky, gummy and chewy than that of wheat and banana＇s flour gels. The proximate analysis revealed that wheat flour had higher protein and moisture content compared to banana and ubi badak flours.
文摘The mean activity coefficient of 5, 10,15 , 20-tetrakis (P-methoxyl-O-sulfophenyl)porphyrin sodium in dilute aqueous solution has been determined in the modality range 0. 00547-0. 08871 mol · kg-1at 273. 2 K by the freezing-point depression method . The results of γ± are 0. 9945-0. 7695, it is in close agreement with that by isopiestic method.
基金the National Key Research and Devel-opment Program of China(Grant No.2018YFA0605902)the National Natural Science Foun-dation of China(Grant Nos.20212024,11872136)China Postdoctoral Science Foundation(Grant No.2020M670746).
文摘Freezing in ice rubble is a common phenomenon in cold regions,which can consolidate loose blocks and change their mechanical properties.To model the cohesive effect in frozen ice rubble,and to describe the fragmentation behavior with a large external forces exerted,a freeze-bond model based on the dilated polyhedral discrete element method(DEM)is proposed.Herein,imaginary bonding is initialized at the contact points to transmit forces and moments,and the initiation of the damage is detected using the hybrid fracture model.The model is validated through the qualitative agreement between the simulation results and the analytical solution of two bonding particles.To study the effect of freeze-bond on the floating ice rubble,punch-through tests were simulated on the ice rubble under freezing and nonfreezing conditions.The deformation and resistance of the ice rubble are investigated during indenter penetration.The influence of the internal friction coefficient on the strength of the ice rubble is determined.The results indicate that the proposed model can properly describe the consolidated ice rubble,and the freeze-bond effect is of great significance to the ice rubble properties.
文摘In order to prolong semen preservation and improve pregnancy rate, semen freezing was studied with German shepherd dogs for experimental animals. The semen of four dogs was collected 40 times in four dilution frozen into two formulations, according to the sperm motility to compare the advantages and disadvantages. The result indicated that the sperm motility of the pellet frozen semen in dilute 2 was significantly higher than that in dilution 1, 3, and 4 （P0.01）. The sperm motility of dogs semen with fried smoked method was notablely higher than that of frozen semen of program method （P0.01）. The dilution which contained yolk-Tris mainly was the best; the pellet semen frozen with fried smoked method was superior to tuble semen frozen with program freezing method; sperm motility of pellet semen was higher than that of tuble semen in the same dilution. The conception rate and litter size of the natural matting were higher than AI.
基金Supported by the Outstanding Youth Scientists Foundation of Harbin City(2014RFYXJ006)
文摘In this study, the Single Factor Test（SFT） was used to optimize the pre-freezing conditions of L. plantarum KLDS1.0391（KLDS1.0391）. Further, the Freeze-Drying Protective Agents（FDPA） of KLDS1.0391 was optimized by Response Surface Methodology（RSM）. The optimum pretreatment conditions were as the follows： initial concentration of KLDS1.0391 was 1011 CFU · m L-1 and KLDS1.0391 was pre-freezed at –80℃ for 8 h to achieve the survival rate of 46.21%. The main components of FDPA were skim milk, sucrose, sodium glutamate and Tween-80. And the influence of four factors on the survival rate of KLDS1.0391 in freeze-drying was in order as the follows： skim milk〉sucrose〉Tween-80〉sodium glutamate. The optimal FDPA composition was skim milk 11.3%, sucrose 9.8%, sodium glutamate 5.1% and Tween-80 0.2%. Under the above conditions, the survival rate of the cells was 82.98%. Comparing the predicted values, the relative error was 0.37% and the difference was not significant, which indicated that the established model could effectively reflect the actual protection of FDPA to KLDS1.0391.
基金supported by the National Natural Science Foundation of China(Grant No.U41702299).
文摘Purpose–This study purposes to study the influence of artificial freezing on the liquefaction characteristics of Nanjing sand,as well as its mechanism.Design/methodology/approach–was studied through dynamic triaxial tests by means of the GDS dynamic triaxial system on Nanjing sand extensively discovered in the middle and lower reaches of the Yangtze River under seismic load and metro train vibration load,respectively,and potential hazards of the two loads to the freezing construction of Nanjing sand were also identified in the tests.Findings–The results show that under both seismic load and metro train vibration load,freeze-thaw cycles will significantly reduce the stiffness and liquefaction resistance of Nanjing sand,especially in the first freezethaw cycle;the more freeze-thaw cycles,the worse structural behaviors of silty-fine sand,and the easier to liquefy;freeze-thaw cycles will increase the sensitivity of Nanjing sand’s dynamic pore pressure to dynamic load response;the lower the freezing temperature and the effective confining pressure,the worse the liquefaction resistance of Nanjing sand after freeze-thaw cycles;compared to the metro train vibration load,the seismic load in Nanjing is potentially less dangerous to freezing construction of Nanjing sand.Originality/value–The research results are helpful to the construction of the artificial ground freezing of the subway crossing passage in the lower reaches of the Yangtze River and to ensure the construction safety of the subway tunnel and its crossing passage.
基金supported by the financial support from National Natural Science Foundation of China(No.51478340)Natural Science Foundation of Jiangsu Province(No.BK20200707)+4 种基金The Natural Science Foundation of the Jiangsu Higher Education Institutions of China(No.20KJB560029)China Postdoctoral Science Foundation(No.2020M671670)Key Laboratory of Soft Soils and Geoenvironmental Engineering(Zhejiang University)Ministry of Education(No.2020P04)the support above is gratefully acknowledged.
文摘Freeze-sealing pipe roof method is applied in the Gongbei tunnel,which causes the ground surface uplift induced by frost heave.A frost heaving prediction approach based on the coefficient of cold expansion is proposed to simulate the ground deformation of the Gongbei tunnel.The coefficient of cold expansion in the model and the frost heaving rate from the frost heave test under the hydration condition can achieve a good correspondence making the calculation result closer to the actual engineering.The ground surface uplift along the lateral and longitudinal direction are respectively analyzed and compared with the field measured data to validate the model.The results show that a good agreement between the frost heaving prediction model and the field measured data verifies the rationality and applicability of the proposed model.The maximum uplift of the Gongbei tunnel appears at the center of the model,gradually decreasing along with the lateral and longitudinal directions.The curve in the lateral direction presents a normal distribution due to the influence of the constraint of two sides,while the one along the lateral direction shapes like a parabola with the opening downward due to the temperature field distribution.The model provides a reference for frost heaving engineering calculation.
基金Funded by National Natural Science Foundation of China(No.50572121) Key Pre-research Foundation of Weapon and Equipment(No. 9140A27010206JB35)
文摘In-situ characterization of non-aqueous nano-dispersion systems（NANDS） by freeze-etching transmission electron microscope（FETEM） was reported.To improve just-for-once successive rate of specimen preparation and get good characterization results,an improving specimen preparation method of freezing etching was developed.Size,distribution and morphology of NANDS were directly visualized.Some information of particle dispersion feature and particle density can also be obtained.Reproductivity of the FETEM characterization is excellent.Comparing with laser scattering method,which is liable to give positive error especially for small size particle anchoring disperser,FETEM characterization can give more accurate measurement of particle size.Moreover,FETEM can give dispersion feature of nanoparticle in non-aqueous medium.
文摘In this paper,we use gambit and fluent to study the time needed and the temperature distribution of the plasma in the three frozen methods of air-cooled,plate-contact and alcohol-immersion quick freezing,this numerical simulation was used to solve the limitation of the equipment in the actual experiment,so as to guide the experimental work.
基金supported by the National Key R&D Program(Nos.2023YFE0108500 and 2023YFF0719500)the National Natural Science Foundation of China(Nos.52072300 and 52302199)+2 种基金the Guangdong Basic and Applied Basic Research Foundation(No.2022A1515110538)Key Research and Development Program of Shaanxi(No.2023-GHZD-48)the Fundamental Research Funds for the Central Universities.
文摘Cadmium telluride(CdTe),which has a high average atomic number and a unique band structure,is a leading material for room-temperature X/γ-ray detectors.Resistivity and mobility are the two most important properties of detector-grade CdTe single crystals.However,despite decades of research,the fabrication of high-resistivity and high-mobility CdTe single crystals faces persistent challenges,primarily because the stoichiometric composition cannot be well controlled owing to the high volatility of Cd under high-temperature conditions.This volatility introduces Te inclusions and cadmium vacancies(V_(Cd))into the as-grown CdTe ingot,which significantly degrades the device performance.In this study,we successfully obtained detector-grade CdTe single crystals by simultaneously employing a Cd reservoir and chlorine(Cl)dopants via a vertical gradient freeze(VGF)method.By installing a Cd reservoir,we can maintain the Cd pressure under the crystal growth conditions,thereby preventing the accumulation of Te in the CdTe ingot.Additionally,the existence of the Cl dopant helps improve the CdTe resistivity by minimizing V_(Cd)density through the formation of an acceptor complex(Cl_(Te)-V_(Cd))^(-1).The crystalline quality of the obtained CdTe(Cl)was evidenced by a reduction in large Te inclusions,high optical transmission(60%),and a sharp absorption edge(1.456 eV).The presence of substitutional Cl dopants,known as Cl_(Te)^(+),simultaneously supports the record high resistivity of 1.5×10^(10)Ω·cm and remarkable electron mobility of 1075±88 cm^(2)V^(-1)s^(-1)simultaneously,has been confirmed by photoluminescence spectroscopy.Moreover,using our crystals,we fabricated a planar detector withμτ_(e)of(1.11±0.04)×10^(-4)cm^(2)∕V,which performed with a decent radiation-detection feature.This study demonstrates that the vapor-pressure-controlled VGF method is a viable technical route for fabricating detector-grade CdTe crystals.
