We propose a rigid-flexible synergistic strategy for the syntheses of ferrocene-functionalized indiumbased metal-organic frameworks(In-MOFs)through introducing rigid carboxylic acids as auxiliary ligands,where the lar...We propose a rigid-flexible synergistic strategy for the syntheses of ferrocene-functionalized indiumbased metal-organic frameworks(In-MOFs)through introducing rigid carboxylic acids as auxiliary ligands,where the large cations are used to induce flexible 1,1’-ferrocene dicarboxylic acid(H_(2)FcDCA)in a controllable coordination mode to construct target frameworks.As an illustration of this strategy,a series of In-MOFs based on the H_(2)FcDCA ligand have been successfully synthesized.The introduction of rigid OX^(2)-ligands and large cation template leads to the syntheses of various In-MOFs.Furthermore,introducing functional cations and a ferrocene unit endows them with good third order nonlinear optical properties and redox activity.展开更多
基金the financial support from NSFC(21971241 and 21871050).
文摘We propose a rigid-flexible synergistic strategy for the syntheses of ferrocene-functionalized indiumbased metal-organic frameworks(In-MOFs)through introducing rigid carboxylic acids as auxiliary ligands,where the large cations are used to induce flexible 1,1’-ferrocene dicarboxylic acid(H_(2)FcDCA)in a controllable coordination mode to construct target frameworks.As an illustration of this strategy,a series of In-MOFs based on the H_(2)FcDCA ligand have been successfully synthesized.The introduction of rigid OX^(2)-ligands and large cation template leads to the syntheses of various In-MOFs.Furthermore,introducing functional cations and a ferrocene unit endows them with good third order nonlinear optical properties and redox activity.
