Efficient selective adsorption and separation using porous frameworks are critical in many industrial processes,where adsorption energy and dynamic diffusion rate are predominant factors governing selectivity.They are...Efficient selective adsorption and separation using porous frameworks are critical in many industrial processes,where adsorption energy and dynamic diffusion rate are predominant factors governing selectivity.They are highly susceptible to framework charge,which plays a significant role in selective adsorption.Currently,ionic porous frameworks can be divided into two types.One of them is composed of a charged backbone and counter ions.The framework with zwitterionic channels is another type.It is composed of regular and alternating arrangements of cationic and anionic building units.Herein,we report a hydrogen-bonded ionic framework(HIF)of{(CN_(3)H_(6))_(2)[Ti(μ_(2)-O)(SO_(4))_(2)]}_nwith 1D channel exhibits unique adsorption selectivity for Ar against N_(2)and CO_(2).Density functional theory(DFT)results suggest that CO_(2)cannot be adsorbed by HIF at the experimental temperature due to a positive adsorption free energy.In addition,due to a relatively large diffusion barrier at 77 K,N_(2)molecules hardly diffuse in HIF channels,while Ar has a negligible diffusion barrier.The unique net positively-charged space in the channel is the key to the unusual phenomena,based on DFT simulations and structural analysis.The findings in this work proposes the new adsorption mechanism and provides unique perspective for special separation applications,such as isotope and noble gasses separations.展开更多
Complex Field Theory (CFT) proposes that dark matter (DM) and dark energy (DE) are pervasive, complex fields of charged complex masses of equally positive and negative complex charges, respectively. It proposes that e...Complex Field Theory (CFT) proposes that dark matter (DM) and dark energy (DE) are pervasive, complex fields of charged complex masses of equally positive and negative complex charges, respectively. It proposes that each material object, including living creatures, is concomitant with a fraction of the charged complex masses of DM and DE in proportion to its mass. This perception provides new insights into the physics of nature and its constituents from subatomic to cosmic scales. This complex nature of DM and DE explains our inability to see DM or harvest DE for the last several decades. The positive complex DM is responsible for preserving the integrity of galaxies and all material systems. The negative complex charged DE induces a positive repelling force with the positively charged DM and contributes to the universe’s expansion. Both fields are Lorentz invariants in all directions and entangle the whole universe. The paper uses CFT to investigate zero-point energy, particle-wave duality, relativistic mass increase, and entanglement phenomenon and unifies Coulomb’s and Newton’s laws. The paper also verifies the existence of tachyons and explains the spooky action of quantum mechanics at a distance. The paper encourages further research into how CFT might resolve several physical mysteries in physics.展开更多
The deteriorated continuous rigid frame bridge is strengthened by external prestressing. Static loading tests wereconducted before and after the bridge rehabilitation to verify the effectiveness of the rehabilitation ...The deteriorated continuous rigid frame bridge is strengthened by external prestressing. Static loading tests wereconducted before and after the bridge rehabilitation to verify the effectiveness of the rehabilitation process. Thestiffness of the repaired bridge is improved, and the maximum deflection of the load test is reduced from 37.9 to27.6 mm. A bridge health monitoring system is installed after the bridge is reinforced. To achieve an easy assessmentof the bridge’s safety status by directly using transferred data, a real-time safety warning system is createdbased on a five-level safety standard. The threshold for each safety level will be determined by theoretical calculationsand the outcomes of static loading tests. The highest risk threshold will be set at the ultimate limit statevalue. The remaining levels, namely middle risk, low risk, and very low risk, will be determined usingreduction coefficients of 0.95, 0.9, and 0.8, respectively.展开更多
Covalent organic frameworks(COFs)are promising materials for converting solar energy into green hydrogen.However,limited charge separation and transport in COFs impede their application in the photocatalytic hydrogen ...Covalent organic frameworks(COFs)are promising materials for converting solar energy into green hydrogen.However,limited charge separation and transport in COFs impede their application in the photocatalytic hydrogen evolution reaction(HER).In this study,the intrinsically tunable internal bond electric field(IBEF)at the imine bonds of COFs was manipulated to cooperate with the internal molecular electric field(IMEF)induced by the donor-acceptor(D-A)structure for an efficient HER.The aligned orientation of IBEF and IMEF resulted in a remarkable H_(2) evolution rate of 57.3 mmol·g^(-1)·h^(-1)on TNCA,which was approximately 520 times higher than that of TCNA(0.11 mmol·g^(-1)·h^(-1))with the opposing electric field orientation.The superposition of the dual electric fields enables the IBEF to function as an accelerating field for electron transfer,kinetically facilitat-ing the migration of photogenerated electrons from D to A.Furthermore,theoretical calculations indicate that the inhomogeneous charge distribution at the C and N atoms in TNCA not only pro-vides a strong driving force for carrier transfer but also effectively hinders the return of free elec-trons to the valence band,improving the utilization of photoelectrons.This strategy of fabricating dual electric fields in COFs offers a novel approach to designing photocatalysts for clean energy synthesis.展开更多
Earth’s internal core and crustal magnetic fields,as measured by geomagnetic satellites like MSS-1(Macao Science Satellite-1)and Swarm,are vital for understanding core dynamics and tectonic evolution.To model these i...Earth’s internal core and crustal magnetic fields,as measured by geomagnetic satellites like MSS-1(Macao Science Satellite-1)and Swarm,are vital for understanding core dynamics and tectonic evolution.To model these internal magnetic fields accurately,data selection based on specific criteria is often employed to minimize the influence of rapidly changing current systems in the ionosphere and magnetosphere.However,the quantitative impact of various data selection criteria on internal geomagnetic field modeling is not well understood.This study aims to address this issue and provide a reference for constructing and applying geomagnetic field models.First,we collect the latest MSS-1 and Swarm satellite magnetic data and summarize widely used data selection criteria in geomagnetic field modeling.Second,we briefly describe the method to co-estimate the core,crustal,and large-scale magnetospheric fields using satellite magnetic data.Finally,we conduct a series of field modeling experiments with different data selection criteria to quantitatively estimate their influence.Our numerical experiments confirm that without selecting data from dark regions and geomagnetically quiet times,the resulting internal field differences at the Earth’s surface can range from tens to hundreds of nanotesla(nT).Additionally,we find that the uncertainties introduced into field models by different data selection criteria are significantly larger than the measurement accuracy of modern geomagnetic satellites.These uncertainties should be considered when utilizing constructed magnetic field models for scientific research and applications.展开更多
We present a formalism of charge self-consistent dynamical mean field theory(DMFT)in combination with densityfunctional theory(DFT)within the linear combination of numerical atomic orbitals(LCNAO)framework.We implemen...We present a formalism of charge self-consistent dynamical mean field theory(DMFT)in combination with densityfunctional theory(DFT)within the linear combination of numerical atomic orbitals(LCNAO)framework.We implementedthe charge self-consistent DFT+DMFT formalism by interfacing a full-potential all-electron DFT code with threehybridization expansion-based continuous-time quantum Monte Carlo impurity solvers.The benchmarks on several 3d,4fand 5f strongly correlated electron systems validated our formalism and implementation.Furthermore,within the LCANOframework,our formalism is general and the code architecture is extensible,so it can work as a bridge merging differentLCNAO DFT packages and impurity solvers to do charge self-consistent DFT+DMFT calculations.展开更多
This study presents preliminary results of tidal-induced magnetic field signals extracted from 9 months of data collected by the Macao Science Satellite-1(MSS-1) from November 2023 to July 2024. Tidal signals were iso...This study presents preliminary results of tidal-induced magnetic field signals extracted from 9 months of data collected by the Macao Science Satellite-1(MSS-1) from November 2023 to July 2024. Tidal signals were isolated using sequential modeling techniques by subtracting non-tidal field model predictions from observed magnetic data. The extracted MSS-1 results show strong agreement with those from the Swarm and CryoSat satellites. MSS-1 effectively captures key large-scale tidal-induced magnetic anomalies, mainly due to its unique 41-degree low-inclination orbit, which provides wide coverage of local times. This finding underscores the strong potential of MSS-1 to recover high-resolution global tidal magnetic field models as more MSS-1 data become available.展开更多
With the approval of more and more genetically modified(GM)crops in our country,GM safety management has become more important.Transgenic detection is a major approach for transgenic safety management.Nevertheless,a c...With the approval of more and more genetically modified(GM)crops in our country,GM safety management has become more important.Transgenic detection is a major approach for transgenic safety management.Nevertheless,a convenient and visual technique with low equipment requirements and high sensitivity for the field detection of GM plants is still lacking.On the basis of the existing recombinase polymerase amplification(RPA)technique,we developed a multiplex RPA(multi-RPA)method that can simultaneously detect three transgenic elements,including the cauliflower mosaic virus 35S gene(CaMV35S)promoter,neomycin phosphotransferaseⅡgene(NptⅡ)and hygromycin B phosphotransferase gene(Hyg),thus improving the detection rate.Moreover,we coupled this multi-RPA technique with the CRISPR/Cas12a reporter system,which enabled the detection results to be clearly observed by naked eyes under ultraviolet(UV)light(254 nm;which could be achieved by a portable UV flashlight),therefore establishing a multi-RPA visual detection technique.Compared with the traditional test strip detection method,this multi-RPA-CRISPR/Cas12a technique has the higher specificity,higher sensitivity,wider application range and lower cost.Compared with other polymerase chain reaction(PCR)techniques,it also has the advantages of low equipment requirements and visualization,making it a potentially feasible method for the field detection of GM plants.展开更多
The movement of global ocean circulation in the Earth’s main magnetic field generates a measurable induced magnetic field(about 2 nT at geomagnetic satellite altitudes).However,this ocean circulation-induced magnetic...The movement of global ocean circulation in the Earth’s main magnetic field generates a measurable induced magnetic field(about 2 nT at geomagnetic satellite altitudes).However,this ocean circulation-induced magnetic field has not been previously estimated or incorporated into geomagnetic field models,potentially causing leakage into the core field model.Here,we present a method to account for the circulation-induced magnetic field during geomagnetic field modeling.First,a forward model of the circulation-induced magnetic field is constructed by numerically solving electromagnetic induction equations based on a realistic ocean circulation model.Then,this forward model is subtracted from the observed data.Finally,the core and lithospheric fields,magnetospheric and Earth’s mantle-induced fields,and the ocean tide-induced magnetic field are co-estimated.Applying our method to over 20 years of MSS-1,Swarm,CryoSat-2,and CHAMP satellite magnetic data,we derive a new multisource geomagnetic field model(MGFM).We find that incorporating a forward model of the circulation-induced magnetic field marginally improves the fit to the data.Furthermore,we demonstrate that neglecting the circulation-induced magnetic field in geomagnetic field modeling results in leakage into the core field model.The highlights of the MGFM model include:(i)a good agreement with the widely used CHAOS model series;(ii)the incorporation of magnetic fields induced by both ocean tides and circulation;and(iii)the suppression of leakage of the circulation-induced magnetic field into the core field model.展开更多
By combining data from the Challenging Minisatellite Payload(CHAMP),Swarm-A,and newest Macao Science Satellite-1(MSS-1) missions,we constructed a lithospheric magnetic field model up to spherical harmonic degree N = 1...By combining data from the Challenging Minisatellite Payload(CHAMP),Swarm-A,and newest Macao Science Satellite-1(MSS-1) missions,we constructed a lithospheric magnetic field model up to spherical harmonic degree N = 100.To isolate the lithospheric magnetic field signals,we utilized the latest CHAOS-8(CHAMP,Φrsted,and SAC-C 8) model and MGFM(Multisource Geomagnetic Field Model) to remove nonlithospheric sources,including the core field,magnetospheric field,ocean tidal field,and ocean circulation field.Subsequently,orbit-by-orbit processing was applied to both scalar and vector data,such as spherical harmonic high-pass filtering,singular spectrum analysis,and line leveling,to suppress noise and residual signals along the satellite tracks.With an orbital inclination of only 41°,MSS-1 effectively captures fine-scale lithospheric magnetic field signals in mid-to low-latitude regions.Its data exhibit a root mean square error of only 0.77 nT relative to the final model,confirming the high quality and utility of lithospheric field modeling.The resulting model exhibits excellent consistency with the MF7(Magnetic Field Model 7),maintaining a high correlation up to N = 90 and still exceeding 0.65 at N = 100.These results demonstrate the reliability and value of MSS-1 data in global lithospheric magnetic field modeling.展开更多
The generalized rheological tests on sandstone were conducted under both dynamic stress and seepage fields.The results demonstrate that the rheological strain of the specimen under increased stress conditions is great...The generalized rheological tests on sandstone were conducted under both dynamic stress and seepage fields.The results demonstrate that the rheological strain of the specimen under increased stress conditions is greater than that under creep conditions,indicating that the dynamic stress field significantly influences the rheological behaviours of sandstone.Following the rheological tests,the number of small pores in the sandstone decreased,while the number of medium-sized pores increased,forming new seepage channels.The high initial rheological stress accelerated fracture compression and the closure of seepage channels,resulting in reduction in the permeability of sandstone.Based on the principles of generalized rheology and the experimental findings,a novel rock rheological constitutive model incorporating both the dynamic stress field and seepage properties has been developed.Numerical simulations of surrounding rock deformation in geotechnical engineering were carried out using a secondary development version of this model,which confirmed the applicability of the generalized rheological numerical simulation method.These results provide theoretical support for the long-term stability evaluation of engineering rock masses and for predicting the deformation of surrounding rock.展开更多
Understanding the evolution of microstructures in nuclear fuels under high-burn-up conditions is critical for extending fuel refueling cycles and enhancing nuclear reactor safety.In this study,a phase-field model is p...Understanding the evolution of microstructures in nuclear fuels under high-burn-up conditions is critical for extending fuel refueling cycles and enhancing nuclear reactor safety.In this study,a phase-field model is proposed to examine the evolution of high-burn-up structures in polycrystalline UO_(2).The formation and growth of recrystallized grains were initially investigated.It was demonstrated that recrystallization kinetics adhere to the Kolmogorov–Johnson–Mehl–Avrami(KJMA)equation,and that recrystallization represents a process of free-energy reduction.Subsequently,the microstructural evolution in UO_(2) was analyzed as the burn up increased.Gas bubbles acted as additional nucleation sites,thereby augmenting the recrystallization kinetics,whereas the presence of recrystallized grains accelerated bubble growth by increasing the number of grain boundaries.The observed variations in the recrystallization kinetics and porosity with burn-up closely align with experimental findings.Furthermore,the influence of grain size on microstructure evolution was investigated.Larger grain sizes were found to decrease porosity and the occurrence of high-burn-up structures.展开更多
It is well known that coarse-grained super-elastic NiTi shape memory alloys(SMAs)exhibit localized rather than homogeneous martensite transformation(MT),which,however,can be strongly influenced by either internal size...It is well known that coarse-grained super-elastic NiTi shape memory alloys(SMAs)exhibit localized rather than homogeneous martensite transformation(MT),which,however,can be strongly influenced by either internal size(grain size,GS)or the external size(geometric size).The coupled effect of GS and geometric size on the functional properties has not been clearly understood yet.In this work,the super-elasticity,one-way,and stress-assisted two-way shape memory effects of the polycrystalline NiTi SMAs with different aspect ratios(length/width for the gauge section)and different GSs are investigated based on the phase field method.The coupled effect of the aspect ratio and GS on the functional properties is adequately revealed.The simulated results indicate that when the aspect ratio is lower than about 4:1,the stress biaxiality and stress heterogeneity in the gauge section of the sample become more and more obvious with decreasing the aspect ratio,which can significantly influence the microstructure evolution in the process involving external stress.Therefore,the corresponding functional property is strongly dependent on the aspect ratio.With decreasing the GS and the aspect ratio(to be lower than 4:1),both the aspect ratio and GS can affect the MT or martensite reorientation in each grain and the interaction among grains.Thus,due to the strong internal constraint(i.e.,the constraint of grain boundary)and the external constraint(i.e.,the constraint of geometric boundary),the capabilities of the functional properties of NiTi SMAs are gradually weakened and highly dependent on these two factors.展开更多
The Sq(solar quiet)geomagnetic field is generated by the electric currents in the E-region of the ionosphere,driven by the atmospheric tides.It is a critical part of high-precision geomagnetic field modeling.Based on ...The Sq(solar quiet)geomagnetic field is generated by the electric currents in the E-region of the ionosphere,driven by the atmospheric tides.It is a critical part of high-precision geomagnetic field modeling.Based on the classic thermal tide theory and atmospheric electrodynamics,this research,for the first time,developed an Sq geomagnetic field model that is directly built on the physical mechanism of the ionospheric dynamo,which is responsible for daily variations of the geomagnetic field.The performance in Sq geomagnetic field modeling was investigated using the Macao Science Satellite-1(MSS-1)data.Our model can enhance the physics-based framework of comprehensive geomagnetic field modeling for the MSS-1 and ensuing missions.展开更多
In this study,we present a comprehensive evaluation of the magnetic field measurements from the Vector Field Magnetometer(VFM)aboard the recently launched Macao Science Satellite-1(MSS-1).One-year data from November 2...In this study,we present a comprehensive evaluation of the magnetic field measurements from the Vector Field Magnetometer(VFM)aboard the recently launched Macao Science Satellite-1(MSS-1).One-year data from November 2,2023,to November 1,2024,are considered.The MSS-1 flies with a low inclination(41°)and is designed to provide high-resolution magnetic field measurements,especially for monitoring the evolution of the South Atlantic Anomaly.Earlier studies confirmed the possibility of using MSS-1A data to model the Earth’s main magnetic field(e.g.,Jiang Y et al.,2024).Therefore,in this study we focus on the magnetic signatures related to the external field,which are primarily associated with magnetospheric and ionospheric currents.The global distributions of the magnetic residuals from MSS-1A show a pattern consistent with that derived from the European Space Agency’s Swarm A satellite.A statistical survey of the conjugated observations(withΔt<5 min andΔR<150 km)between the two satellites showed that the difference between their magnetic residuals is within±3 nanoteslas.By separating the magnetic residuals at the noon and midnight hours,we see that the MSS-1A data can effectively capture features of the magnetospheric and ionospheric currents,such as the magnetospheric ring current and ionospheric equatorial electrojet.Moreover,the magnetic residuals from MSS-1A show a diamagnetic effect caused by post-sunset equatorial plasma bubbles,which also suggests that the MSS-1A data have the potential to reveal the ionospheric structures.The comprehensive evaluations performed within this study demonstrate that the MSS-1A provides high-quality magnetic field data reaching the level of the Swarm satellite,which enables a deeper understanding of the modeling of Earth’s magnetic field as well as monitoring of the magnetic environment.展开更多
The kitchen-oil wastewater is characterized by a high concentration of organicmatter,complex composition and refractory pollutants,which make wastewater treatment more difficult.Based on the study of using micro-elect...The kitchen-oil wastewater is characterized by a high concentration of organicmatter,complex composition and refractory pollutants,which make wastewater treatment more difficult.Based on the study of using micro-electric field characteristic catalyst HCLL-S8-M to enhance the electron transfer between microorganisms in kitchen-oil wastewater which further improved the COD removal rate,we focus on themicrobial community,intracellular metabolism and extracellular respiration,and make an in-depth analysis of the molecular biological mechanisms to microbial treatment in wastewater.It is found that electroactive microorganisms are enriched on the material surface,and the expression levels of cytochrome c and riboflavin genes related to electron transfer are up-regulated,confirming that the surface micro-electric field structure could enhance the electron transfer between microbial species and improve the efficiency ofwastewater degradation.This study provides a new idea for the treatment of refractory organic wastewater.展开更多
We combine gradient data from the Macao Science Satellite-1(MSS-1),CHAllenging Minisatellite Payload(CHAMP),Swarm-A,and Swarm-C satellites to develop a 110-degree lithospheric magnetic field model.We then comprehensiv...We combine gradient data from the Macao Science Satellite-1(MSS-1),CHAllenging Minisatellite Payload(CHAMP),Swarm-A,and Swarm-C satellites to develop a 110-degree lithospheric magnetic field model.We then comprehensively evaluate the performance of the model by power spectral comparisons,correlation analyses,sensitivity matrix assessments,and comparisons with existing lithospheric field models.Results showed that using near east–west gradient data from MSS-1 significantly enhances the model correlation in the spherical harmonic degree(N) range of 45–60 while also mitigating the decline in correlation at higher degrees(N > 60).Furthermore,the unique orbital characteristics of MSS-1 enable its gradient data to provide substantial contributions to modeling in the mid-to low-latitude regions.With continued data acquisition from MSS-1 and further optimization of data processing methods,the performance of the model is expected to improve.展开更多
Aircraft disturbs the adjacent atmospheric environment in flight,forming spatial distribution features of atmospheric density that differ from the natural background,which may potentially be utilized as tracer charact...Aircraft disturbs the adjacent atmospheric environment in flight,forming spatial distribution features of atmospheric density that differ from the natural background,which may potentially be utilized as tracer characteristics to introduce new technologies for indirectly sensing the presence of aircraft.In this paper,the concept of a long-range aircraft detection based on the atmospheric disturbance density field is proposed,and the detection mode of tomographic imaging of the scattering light of an atmospheric disturbance flow field is designed.By modeling the spatial distribution of the disturbance density field,the scattered echo signal images of active light towards the disturbance field at long distance are simulated.On this basis,the characteristics of the disturbance optical signal at the optimal detection resolution are analyzed.The results show that the atmospheric disturbance flow field of the supersonic aircraft presents circular in the light-scattering echo images.The disturbance signal can be further highlighted by differential processing of the adjacent scattering images.As the distance behind the aircraft increases,the diffusion range of the disturbance signal increases,and the signal intensity and contrast with the background decrease.Under the ground-based observation conditions of the aircraft at a height of 10000 m,a Mach number of1.6,and a detection distance of 100 km,the contrast between the disturbance signal and the back-ground was 30 d B at a distance of one time from the rear of the fuselage,and the diffusion diameter of the disturbance signal was 50 m.At a distance eight times the length of the aircraft,the contrast decreased to 10 dB,and the diameter increased to 290 m.The contrast was reduced to 3 dB at a distance nine times the length of the aircraft,and the diameter was diffused to 310 m.These results indicate the possibility of long-range aircraft detection based on the characteristics of the atmospheric density field.展开更多
The present study focuses on the flow of a yield-stress(Bingham)nanofluid,consisting of suspended Fe3O4 nanoparticles,subjected to a magnetic field in a backward-facing step duct(BFS)configuration.The duct is equipped...The present study focuses on the flow of a yield-stress(Bingham)nanofluid,consisting of suspended Fe3O4 nanoparticles,subjected to a magnetic field in a backward-facing step duct(BFS)configuration.The duct is equipped with a cylindrical obstacle,where the lower wall is kept at a constant temperature.The yield-stress nanofluid enters this duct at a cold temperature with fully developed velocity.The aim of the present investigation is to explore the influence of flow velocity(Re=10 to 200),nanoparticle concentration(ϕ=0 to 0.1),magnetic field intensity(Ha=0 to 100),and its inclination angle(γ=0 to 90)and nanofluid yield stress(Bn=0 to 20)on the thermal and hydrodynamic efficiency inside the backward-facing step.The numerical results have been obtained by resolving the momentum and energy balance equations using the Galerkin finite element method.The obtained results have indicated that an increase in Reynolds number and nanoparticle volume fraction enhances heat transfer.In contrast,a significant reduction is observed with an increase in Hartmann and Bingham numbers,resulting in quasi-immobilization of the fluid under the magnetic influence and radical solidification of this type of fluid,accompanied by the suppression of the vortex zone downstream of the cylindrical obstacle.This study sheds light on the complexity of this magnetically influenced fluid,with potential implications in various engineering and materials science fields.展开更多
基金support from the Chinese Academy of Sciences and University of Science and Technology of China,National Key Research and Development Program of China(No.2021YFA1500402)National Natural Science Foundation of China(Nos.21571167,51502282 and 22075266)Fundamental Research Funds for the Central Universities(Nos.WK2060190053 and WK2060190100)。
文摘Efficient selective adsorption and separation using porous frameworks are critical in many industrial processes,where adsorption energy and dynamic diffusion rate are predominant factors governing selectivity.They are highly susceptible to framework charge,which plays a significant role in selective adsorption.Currently,ionic porous frameworks can be divided into two types.One of them is composed of a charged backbone and counter ions.The framework with zwitterionic channels is another type.It is composed of regular and alternating arrangements of cationic and anionic building units.Herein,we report a hydrogen-bonded ionic framework(HIF)of{(CN_(3)H_(6))_(2)[Ti(μ_(2)-O)(SO_(4))_(2)]}_nwith 1D channel exhibits unique adsorption selectivity for Ar against N_(2)and CO_(2).Density functional theory(DFT)results suggest that CO_(2)cannot be adsorbed by HIF at the experimental temperature due to a positive adsorption free energy.In addition,due to a relatively large diffusion barrier at 77 K,N_(2)molecules hardly diffuse in HIF channels,while Ar has a negligible diffusion barrier.The unique net positively-charged space in the channel is the key to the unusual phenomena,based on DFT simulations and structural analysis.The findings in this work proposes the new adsorption mechanism and provides unique perspective for special separation applications,such as isotope and noble gasses separations.
文摘Complex Field Theory (CFT) proposes that dark matter (DM) and dark energy (DE) are pervasive, complex fields of charged complex masses of equally positive and negative complex charges, respectively. It proposes that each material object, including living creatures, is concomitant with a fraction of the charged complex masses of DM and DE in proportion to its mass. This perception provides new insights into the physics of nature and its constituents from subatomic to cosmic scales. This complex nature of DM and DE explains our inability to see DM or harvest DE for the last several decades. The positive complex DM is responsible for preserving the integrity of galaxies and all material systems. The negative complex charged DE induces a positive repelling force with the positively charged DM and contributes to the universe’s expansion. Both fields are Lorentz invariants in all directions and entangle the whole universe. The paper uses CFT to investigate zero-point energy, particle-wave duality, relativistic mass increase, and entanglement phenomenon and unifies Coulomb’s and Newton’s laws. The paper also verifies the existence of tachyons and explains the spooky action of quantum mechanics at a distance. The paper encourages further research into how CFT might resolve several physical mysteries in physics.
文摘The deteriorated continuous rigid frame bridge is strengthened by external prestressing. Static loading tests wereconducted before and after the bridge rehabilitation to verify the effectiveness of the rehabilitation process. Thestiffness of the repaired bridge is improved, and the maximum deflection of the load test is reduced from 37.9 to27.6 mm. A bridge health monitoring system is installed after the bridge is reinforced. To achieve an easy assessmentof the bridge’s safety status by directly using transferred data, a real-time safety warning system is createdbased on a five-level safety standard. The threshold for each safety level will be determined by theoretical calculationsand the outcomes of static loading tests. The highest risk threshold will be set at the ultimate limit statevalue. The remaining levels, namely middle risk, low risk, and very low risk, will be determined usingreduction coefficients of 0.95, 0.9, and 0.8, respectively.
文摘Covalent organic frameworks(COFs)are promising materials for converting solar energy into green hydrogen.However,limited charge separation and transport in COFs impede their application in the photocatalytic hydrogen evolution reaction(HER).In this study,the intrinsically tunable internal bond electric field(IBEF)at the imine bonds of COFs was manipulated to cooperate with the internal molecular electric field(IMEF)induced by the donor-acceptor(D-A)structure for an efficient HER.The aligned orientation of IBEF and IMEF resulted in a remarkable H_(2) evolution rate of 57.3 mmol·g^(-1)·h^(-1)on TNCA,which was approximately 520 times higher than that of TCNA(0.11 mmol·g^(-1)·h^(-1))with the opposing electric field orientation.The superposition of the dual electric fields enables the IBEF to function as an accelerating field for electron transfer,kinetically facilitat-ing the migration of photogenerated electrons from D to A.Furthermore,theoretical calculations indicate that the inhomogeneous charge distribution at the C and N atoms in TNCA not only pro-vides a strong driving force for carrier transfer but also effectively hinders the return of free elec-trons to the valence band,improving the utilization of photoelectrons.This strategy of fabricating dual electric fields in COFs offers a novel approach to designing photocatalysts for clean energy synthesis.
基金supported by the National Natural Science Foundation of China(42250101)the Macao Foundation。
文摘Earth’s internal core and crustal magnetic fields,as measured by geomagnetic satellites like MSS-1(Macao Science Satellite-1)and Swarm,are vital for understanding core dynamics and tectonic evolution.To model these internal magnetic fields accurately,data selection based on specific criteria is often employed to minimize the influence of rapidly changing current systems in the ionosphere and magnetosphere.However,the quantitative impact of various data selection criteria on internal geomagnetic field modeling is not well understood.This study aims to address this issue and provide a reference for constructing and applying geomagnetic field models.First,we collect the latest MSS-1 and Swarm satellite magnetic data and summarize widely used data selection criteria in geomagnetic field modeling.Second,we briefly describe the method to co-estimate the core,crustal,and large-scale magnetospheric fields using satellite magnetic data.Finally,we conduct a series of field modeling experiments with different data selection criteria to quantitatively estimate their influence.Our numerical experiments confirm that without selecting data from dark regions and geomagnetically quiet times,the resulting internal field differences at the Earth’s surface can range from tens to hundreds of nanotesla(nT).Additionally,we find that the uncertainties introduced into field models by different data selection criteria are significantly larger than the measurement accuracy of modern geomagnetic satellites.These uncertainties should be considered when utilizing constructed magnetic field models for scientific research and applications.
文摘We present a formalism of charge self-consistent dynamical mean field theory(DMFT)in combination with densityfunctional theory(DFT)within the linear combination of numerical atomic orbitals(LCNAO)framework.We implementedthe charge self-consistent DFT+DMFT formalism by interfacing a full-potential all-electron DFT code with threehybridization expansion-based continuous-time quantum Monte Carlo impurity solvers.The benchmarks on several 3d,4fand 5f strongly correlated electron systems validated our formalism and implementation.Furthermore,within the LCANOframework,our formalism is general and the code architecture is extensible,so it can work as a bridge merging differentLCNAO DFT packages and impurity solvers to do charge self-consistent DFT+DMFT calculations.
基金financially supported by the National Natural Science Foundation of China(42250102,42250101)the Macao Foundation and Macao Science and Technology Development Fund(0001/2019/A1)the Pre-research Project on Civil Aerospace Technologies funded by China National Space Administration(D020303)。
文摘This study presents preliminary results of tidal-induced magnetic field signals extracted from 9 months of data collected by the Macao Science Satellite-1(MSS-1) from November 2023 to July 2024. Tidal signals were isolated using sequential modeling techniques by subtracting non-tidal field model predictions from observed magnetic data. The extracted MSS-1 results show strong agreement with those from the Swarm and CryoSat satellites. MSS-1 effectively captures key large-scale tidal-induced magnetic anomalies, mainly due to its unique 41-degree low-inclination orbit, which provides wide coverage of local times. This finding underscores the strong potential of MSS-1 to recover high-resolution global tidal magnetic field models as more MSS-1 data become available.
基金the Experimental Technology Research Project of Zhejiang University(SYB202138)National Natural Science Foundation of China(32000195)。
文摘With the approval of more and more genetically modified(GM)crops in our country,GM safety management has become more important.Transgenic detection is a major approach for transgenic safety management.Nevertheless,a convenient and visual technique with low equipment requirements and high sensitivity for the field detection of GM plants is still lacking.On the basis of the existing recombinase polymerase amplification(RPA)technique,we developed a multiplex RPA(multi-RPA)method that can simultaneously detect three transgenic elements,including the cauliflower mosaic virus 35S gene(CaMV35S)promoter,neomycin phosphotransferaseⅡgene(NptⅡ)and hygromycin B phosphotransferase gene(Hyg),thus improving the detection rate.Moreover,we coupled this multi-RPA technique with the CRISPR/Cas12a reporter system,which enabled the detection results to be clearly observed by naked eyes under ultraviolet(UV)light(254 nm;which could be achieved by a portable UV flashlight),therefore establishing a multi-RPA visual detection technique.Compared with the traditional test strip detection method,this multi-RPA-CRISPR/Cas12a technique has the higher specificity,higher sensitivity,wider application range and lower cost.Compared with other polymerase chain reaction(PCR)techniques,it also has the advantages of low equipment requirements and visualization,making it a potentially feasible method for the field detection of GM plants.
基金supported by the National Natural Science Foundation of China(42250101,42250102)the Macao Foundation.
文摘The movement of global ocean circulation in the Earth’s main magnetic field generates a measurable induced magnetic field(about 2 nT at geomagnetic satellite altitudes).However,this ocean circulation-induced magnetic field has not been previously estimated or incorporated into geomagnetic field models,potentially causing leakage into the core field model.Here,we present a method to account for the circulation-induced magnetic field during geomagnetic field modeling.First,a forward model of the circulation-induced magnetic field is constructed by numerically solving electromagnetic induction equations based on a realistic ocean circulation model.Then,this forward model is subtracted from the observed data.Finally,the core and lithospheric fields,magnetospheric and Earth’s mantle-induced fields,and the ocean tide-induced magnetic field are co-estimated.Applying our method to over 20 years of MSS-1,Swarm,CryoSat-2,and CHAMP satellite magnetic data,we derive a new multisource geomagnetic field model(MGFM).We find that incorporating a forward model of the circulation-induced magnetic field marginally improves the fit to the data.Furthermore,we demonstrate that neglecting the circulation-induced magnetic field in geomagnetic field modeling results in leakage into the core field model.The highlights of the MGFM model include:(i)a good agreement with the widely used CHAOS model series;(ii)the incorporation of magnetic fields induced by both ocean tides and circulation;and(iii)the suppression of leakage of the circulation-induced magnetic field into the core field model.
基金the support of the National Natural Science Foundation of China (Nos. 42250103, 41974073, and 41404053)the Macao Foundation and the preresearch project of Civil Aerospace Technologies (Nos. D020308 and D020303)funded by China’s National Space Administration, and the Specialized Research Fund for State Key Laboratories。
文摘By combining data from the Challenging Minisatellite Payload(CHAMP),Swarm-A,and newest Macao Science Satellite-1(MSS-1) missions,we constructed a lithospheric magnetic field model up to spherical harmonic degree N = 100.To isolate the lithospheric magnetic field signals,we utilized the latest CHAOS-8(CHAMP,Φrsted,and SAC-C 8) model and MGFM(Multisource Geomagnetic Field Model) to remove nonlithospheric sources,including the core field,magnetospheric field,ocean tidal field,and ocean circulation field.Subsequently,orbit-by-orbit processing was applied to both scalar and vector data,such as spherical harmonic high-pass filtering,singular spectrum analysis,and line leveling,to suppress noise and residual signals along the satellite tracks.With an orbital inclination of only 41°,MSS-1 effectively captures fine-scale lithospheric magnetic field signals in mid-to low-latitude regions.Its data exhibit a root mean square error of only 0.77 nT relative to the final model,confirming the high quality and utility of lithospheric field modeling.The resulting model exhibits excellent consistency with the MF7(Magnetic Field Model 7),maintaining a high correlation up to N = 90 and still exceeding 0.65 at N = 100.These results demonstrate the reliability and value of MSS-1 data in global lithospheric magnetic field modeling.
基金supported and financed by Scientific Research Foundation for High-level Talents of Anhui University of Science and Technology (No.2024yjrc96)Anhui Provincial University Excellent Research and Innovation Team Support Project (No.2022AH010053)+2 种基金National Key Research and Development Program of China (Nos.2023YFC2907602 and 2022YFF1303302)Anhui Provincial Major Science and Technology Project (No.202203a07020011)Open Foundation of Joint National-Local Engineering Research Centre for Safe and Precise Coal Mining (No.EC2023020)。
文摘The generalized rheological tests on sandstone were conducted under both dynamic stress and seepage fields.The results demonstrate that the rheological strain of the specimen under increased stress conditions is greater than that under creep conditions,indicating that the dynamic stress field significantly influences the rheological behaviours of sandstone.Following the rheological tests,the number of small pores in the sandstone decreased,while the number of medium-sized pores increased,forming new seepage channels.The high initial rheological stress accelerated fracture compression and the closure of seepage channels,resulting in reduction in the permeability of sandstone.Based on the principles of generalized rheology and the experimental findings,a novel rock rheological constitutive model incorporating both the dynamic stress field and seepage properties has been developed.Numerical simulations of surrounding rock deformation in geotechnical engineering were carried out using a secondary development version of this model,which confirmed the applicability of the generalized rheological numerical simulation method.These results provide theoretical support for the long-term stability evaluation of engineering rock masses and for predicting the deformation of surrounding rock.
基金supported by the National Natural Science Foundation of China(Grant Nos.U20B2013 and 12205286)the National Key Research and Development Program of China(Grant No.2022YFB1902401)。
文摘Understanding the evolution of microstructures in nuclear fuels under high-burn-up conditions is critical for extending fuel refueling cycles and enhancing nuclear reactor safety.In this study,a phase-field model is proposed to examine the evolution of high-burn-up structures in polycrystalline UO_(2).The formation and growth of recrystallized grains were initially investigated.It was demonstrated that recrystallization kinetics adhere to the Kolmogorov–Johnson–Mehl–Avrami(KJMA)equation,and that recrystallization represents a process of free-energy reduction.Subsequently,the microstructural evolution in UO_(2) was analyzed as the burn up increased.Gas bubbles acted as additional nucleation sites,thereby augmenting the recrystallization kinetics,whereas the presence of recrystallized grains accelerated bubble growth by increasing the number of grain boundaries.The observed variations in the recrystallization kinetics and porosity with burn-up closely align with experimental findings.Furthermore,the influence of grain size on microstructure evolution was investigated.Larger grain sizes were found to decrease porosity and the occurrence of high-burn-up structures.
基金supported by the National Natural Science Foundation of China (Grant Nos.12202294 and 12022208)the Project funded by China Postdoctoral Science Foundation (Grant No.2022M712243)the Fundamental Research Funds for the Central Universities (Grant No.2023SCU12098).
文摘It is well known that coarse-grained super-elastic NiTi shape memory alloys(SMAs)exhibit localized rather than homogeneous martensite transformation(MT),which,however,can be strongly influenced by either internal size(grain size,GS)or the external size(geometric size).The coupled effect of GS and geometric size on the functional properties has not been clearly understood yet.In this work,the super-elasticity,one-way,and stress-assisted two-way shape memory effects of the polycrystalline NiTi SMAs with different aspect ratios(length/width for the gauge section)and different GSs are investigated based on the phase field method.The coupled effect of the aspect ratio and GS on the functional properties is adequately revealed.The simulated results indicate that when the aspect ratio is lower than about 4:1,the stress biaxiality and stress heterogeneity in the gauge section of the sample become more and more obvious with decreasing the aspect ratio,which can significantly influence the microstructure evolution in the process involving external stress.Therefore,the corresponding functional property is strongly dependent on the aspect ratio.With decreasing the GS and the aspect ratio(to be lower than 4:1),both the aspect ratio and GS can affect the MT or martensite reorientation in each grain and the interaction among grains.Thus,due to the strong internal constraint(i.e.,the constraint of grain boundary)and the external constraint(i.e.,the constraint of geometric boundary),the capabilities of the functional properties of NiTi SMAs are gradually weakened and highly dependent on these two factors.
基金supported by the National Natural Science Foundation of China(Grant Nos.12250013,12403070,12425306,42250101,12273092)the Macao Foundation,and Shanghai Post-doctoral Excellence Program(Grant No.2023000137)。
文摘The Sq(solar quiet)geomagnetic field is generated by the electric currents in the E-region of the ionosphere,driven by the atmospheric tides.It is a critical part of high-precision geomagnetic field modeling.Based on the classic thermal tide theory and atmospheric electrodynamics,this research,for the first time,developed an Sq geomagnetic field model that is directly built on the physical mechanism of the ionospheric dynamo,which is responsible for daily variations of the geomagnetic field.The performance in Sq geomagnetic field modeling was investigated using the Macao Science Satellite-1(MSS-1)data.Our model can enhance the physics-based framework of comprehensive geomagnetic field modeling for the MSS-1 and ensuing missions.
基金supported by the National Natural Science Foundation of China(Grant Nos.42474200 and 42174186)Chao Xiong is supported by the Dragon 6 cooperation 2024-2028(Project No.95437).
文摘In this study,we present a comprehensive evaluation of the magnetic field measurements from the Vector Field Magnetometer(VFM)aboard the recently launched Macao Science Satellite-1(MSS-1).One-year data from November 2,2023,to November 1,2024,are considered.The MSS-1 flies with a low inclination(41°)and is designed to provide high-resolution magnetic field measurements,especially for monitoring the evolution of the South Atlantic Anomaly.Earlier studies confirmed the possibility of using MSS-1A data to model the Earth’s main magnetic field(e.g.,Jiang Y et al.,2024).Therefore,in this study we focus on the magnetic signatures related to the external field,which are primarily associated with magnetospheric and ionospheric currents.The global distributions of the magnetic residuals from MSS-1A show a pattern consistent with that derived from the European Space Agency’s Swarm A satellite.A statistical survey of the conjugated observations(withΔt<5 min andΔR<150 km)between the two satellites showed that the difference between their magnetic residuals is within±3 nanoteslas.By separating the magnetic residuals at the noon and midnight hours,we see that the MSS-1A data can effectively capture features of the magnetospheric and ionospheric currents,such as the magnetospheric ring current and ionospheric equatorial electrojet.Moreover,the magnetic residuals from MSS-1A show a diamagnetic effect caused by post-sunset equatorial plasma bubbles,which also suggests that the MSS-1A data have the potential to reveal the ionospheric structures.The comprehensive evaluations performed within this study demonstrate that the MSS-1A provides high-quality magnetic field data reaching the level of the Swarm satellite,which enables a deeper understanding of the modeling of Earth’s magnetic field as well as monitoring of the magnetic environment.
基金supported by the National Natural Science Foundation of China(Nos.52150056 and 51838005)the Basic and Applied Basic Research Foundation of Guangdong Province(No.2023A1515111061).
文摘The kitchen-oil wastewater is characterized by a high concentration of organicmatter,complex composition and refractory pollutants,which make wastewater treatment more difficult.Based on the study of using micro-electric field characteristic catalyst HCLL-S8-M to enhance the electron transfer between microorganisms in kitchen-oil wastewater which further improved the COD removal rate,we focus on themicrobial community,intracellular metabolism and extracellular respiration,and make an in-depth analysis of the molecular biological mechanisms to microbial treatment in wastewater.It is found that electroactive microorganisms are enriched on the material surface,and the expression levels of cytochrome c and riboflavin genes related to electron transfer are up-regulated,confirming that the surface micro-electric field structure could enhance the electron transfer between microbial species and improve the efficiency ofwastewater degradation.This study provides a new idea for the treatment of refractory organic wastewater.
基金the support of the National Natural Science Foundation of China (Nos. 42250103, 41974073, and 41404053)the Macao Foundation and the preresearch project of Civil Aerospace Technologies (Nos. D020308 and D020303)funded by China’s National Space Administration, the Specialized Research Fund for State Key Laboratories。
文摘We combine gradient data from the Macao Science Satellite-1(MSS-1),CHAllenging Minisatellite Payload(CHAMP),Swarm-A,and Swarm-C satellites to develop a 110-degree lithospheric magnetic field model.We then comprehensively evaluate the performance of the model by power spectral comparisons,correlation analyses,sensitivity matrix assessments,and comparisons with existing lithospheric field models.Results showed that using near east–west gradient data from MSS-1 significantly enhances the model correlation in the spherical harmonic degree(N) range of 45–60 while also mitigating the decline in correlation at higher degrees(N > 60).Furthermore,the unique orbital characteristics of MSS-1 enable its gradient data to provide substantial contributions to modeling in the mid-to low-latitude regions.With continued data acquisition from MSS-1 and further optimization of data processing methods,the performance of the model is expected to improve.
文摘Aircraft disturbs the adjacent atmospheric environment in flight,forming spatial distribution features of atmospheric density that differ from the natural background,which may potentially be utilized as tracer characteristics to introduce new technologies for indirectly sensing the presence of aircraft.In this paper,the concept of a long-range aircraft detection based on the atmospheric disturbance density field is proposed,and the detection mode of tomographic imaging of the scattering light of an atmospheric disturbance flow field is designed.By modeling the spatial distribution of the disturbance density field,the scattered echo signal images of active light towards the disturbance field at long distance are simulated.On this basis,the characteristics of the disturbance optical signal at the optimal detection resolution are analyzed.The results show that the atmospheric disturbance flow field of the supersonic aircraft presents circular in the light-scattering echo images.The disturbance signal can be further highlighted by differential processing of the adjacent scattering images.As the distance behind the aircraft increases,the diffusion range of the disturbance signal increases,and the signal intensity and contrast with the background decrease.Under the ground-based observation conditions of the aircraft at a height of 10000 m,a Mach number of1.6,and a detection distance of 100 km,the contrast between the disturbance signal and the back-ground was 30 d B at a distance of one time from the rear of the fuselage,and the diffusion diameter of the disturbance signal was 50 m.At a distance eight times the length of the aircraft,the contrast decreased to 10 dB,and the diameter increased to 290 m.The contrast was reduced to 3 dB at a distance nine times the length of the aircraft,and the diameter was diffused to 310 m.These results indicate the possibility of long-range aircraft detection based on the characteristics of the atmospheric density field.
文摘The present study focuses on the flow of a yield-stress(Bingham)nanofluid,consisting of suspended Fe3O4 nanoparticles,subjected to a magnetic field in a backward-facing step duct(BFS)configuration.The duct is equipped with a cylindrical obstacle,where the lower wall is kept at a constant temperature.The yield-stress nanofluid enters this duct at a cold temperature with fully developed velocity.The aim of the present investigation is to explore the influence of flow velocity(Re=10 to 200),nanoparticle concentration(ϕ=0 to 0.1),magnetic field intensity(Ha=0 to 100),and its inclination angle(γ=0 to 90)and nanofluid yield stress(Bn=0 to 20)on the thermal and hydrodynamic efficiency inside the backward-facing step.The numerical results have been obtained by resolving the momentum and energy balance equations using the Galerkin finite element method.The obtained results have indicated that an increase in Reynolds number and nanoparticle volume fraction enhances heat transfer.In contrast,a significant reduction is observed with an increase in Hartmann and Bingham numbers,resulting in quasi-immobilization of the fluid under the magnetic influence and radical solidification of this type of fluid,accompanied by the suppression of the vortex zone downstream of the cylindrical obstacle.This study sheds light on the complexity of this magnetically influenced fluid,with potential implications in various engineering and materials science fields.
