Pyrite framboids were found in the Permian-Triassic boundary at Meishan Section,while their sulfur isotopes were determined.The majority of framboids is less than 5μm in diameter,with some large-sized framboids.Also,...Pyrite framboids were found in the Permian-Triassic boundary at Meishan Section,while their sulfur isotopes were determined.The majority of framboids is less than 5μm in diameter,with some large-sized framboids.Also,euhedral gypsums were observed in the boundary clay.The authors suppose that most of the pyrite framboids formed just below the redox boundary and stopped growing after entering the lower water column.The result indicates that it was probably lower dysoxia condition in the temporal ocean.Moreover,the authors also presume that some pyrite was oxidated to sulfates accompanying the fluctuation of redox condition,which would probably be the origin of the negative sulfur isotopes of gypsum and CAS reported before.In addition,sulfur isotope of framboidal pyrite suggests that sulfur is originated from bacterial sulfate reduction in anoxic condition.Therefore, this study confirms that the ocean was widely anoxic during the Permian-Triassic transitional period. However,the redox condition in temporal ocean was probably not stable,with short-term fluctuations.展开更多
Authigenic carbonate samples were collected from the northern Okinawa Trough.Based on their carbon and oxygen isotopes,these samples were found to be methane-related carbonates precipitated by the anaerobic oxidation ...Authigenic carbonate samples were collected from the northern Okinawa Trough.Based on their carbon and oxygen isotopes,these samples were found to be methane-related carbonates precipitated by the anaerobic oxidation of methane(AOM).Petrological analysis revealed numerous framboidal pyrites that had been partly oxidized.In order to trace the variation and diagenetic information of these framboidal pyrites,their diameters and geochemical components were studied using an electron probe.The results showed that their diameters varied from 4μm to 17μm(n=60;geometric mean of 9.9μm)and were of a normal distribution.The diameters of single pyrite that formed the framboidal pyrites varied from 1μm to 2μm.The framboidal pyrites with diameters of 6–14μm accounted for~80%of the total.The geometric mean of 9.9μm indicates that they are probably diagenetic pyrites that were precipitated in a lower dysoxic environment(weakly oxygenated bottom waters).The S/Fe ratio of the framboidal minerals ranged from 0 to 1.67,and the pyrite content of single framboid varied between 0%and 86.4%.Therefore,numerous pyrites were oxygenated to iron oxides or oxyhydroxides,and were retained as pseudomorphism pyrites.The size of framboidal pyrites precipitated in cold seeps can be used to trace the redox environment;however,acquisition of additional data via investigation of different cold seeps is necessary to obtain more persuasive results.展开更多
为研究卡尼期雨幕事件在鄂尔多斯盆地南部的响应,对该盆地ZH2钻孔延长组进行孢粉化石、有机碳同位素、草莓状黄铁矿和主量元素分析。孢粉化石由下至上划分出Punctatisporites-Verrucosisporites-Osmundacidites组合Ⅰ和Asseretospora-Ap...为研究卡尼期雨幕事件在鄂尔多斯盆地南部的响应,对该盆地ZH2钻孔延长组进行孢粉化石、有机碳同位素、草莓状黄铁矿和主量元素分析。孢粉化石由下至上划分出Punctatisporites-Verrucosisporites-Osmundacidites组合Ⅰ和Asseretospora-Apiculatisporis组合Ⅱ,地质年代分别为中三叠世拉丁期和晚三叠世卡尼期。在孢粉组合Ⅱ下部张家滩页岩中总有机碳富集、有机碳同位素发生负漂移,漂移量为4.88‰,同时草莓状黄铁矿指标指示着该层位形成于贫氧的环境,Al_(2)O_(3)/MgO比值和化学蚀变指数(chemical index of alteration,CIA)值在该层位均处于高值,指示着高温、湿润、强化学风化的环境。以上特征表明卡尼期雨幕事件在鄂尔多斯盆地造成了显著影响。进一步分析显示这些指标在张家滩页岩中可划分为4个独立的高温、湿润、缺氧、有机碳富集片段,指示了卡尼期雨幕事件(Carnian pluvial event,CPE)在鄂尔多斯盆地的4次气候波动,分别命名为:CPEⅠ、CPEⅡ、CPEⅢ、CPEⅣ。展开更多
基金supported by China Scholarship Council,National Natural Science Foundation of China(No40572020)Doctoral Program of Higher Education(No20040290005)
文摘Pyrite framboids were found in the Permian-Triassic boundary at Meishan Section,while their sulfur isotopes were determined.The majority of framboids is less than 5μm in diameter,with some large-sized framboids.Also,euhedral gypsums were observed in the boundary clay.The authors suppose that most of the pyrite framboids formed just below the redox boundary and stopped growing after entering the lower water column.The result indicates that it was probably lower dysoxia condition in the temporal ocean.Moreover,the authors also presume that some pyrite was oxidated to sulfates accompanying the fluctuation of redox condition,which would probably be the origin of the negative sulfur isotopes of gypsum and CAS reported before.In addition,sulfur isotope of framboidal pyrite suggests that sulfur is originated from bacterial sulfate reduction in anoxic condition.Therefore, this study confirms that the ocean was widely anoxic during the Permian-Triassic transitional period. However,the redox condition in temporal ocean was probably not stable,with short-term fluctuations.
基金The National Natural Science Foundation of China under contract Nos 41476050,41106047,and 41506073
文摘Authigenic carbonate samples were collected from the northern Okinawa Trough.Based on their carbon and oxygen isotopes,these samples were found to be methane-related carbonates precipitated by the anaerobic oxidation of methane(AOM).Petrological analysis revealed numerous framboidal pyrites that had been partly oxidized.In order to trace the variation and diagenetic information of these framboidal pyrites,their diameters and geochemical components were studied using an electron probe.The results showed that their diameters varied from 4μm to 17μm(n=60;geometric mean of 9.9μm)and were of a normal distribution.The diameters of single pyrite that formed the framboidal pyrites varied from 1μm to 2μm.The framboidal pyrites with diameters of 6–14μm accounted for~80%of the total.The geometric mean of 9.9μm indicates that they are probably diagenetic pyrites that were precipitated in a lower dysoxic environment(weakly oxygenated bottom waters).The S/Fe ratio of the framboidal minerals ranged from 0 to 1.67,and the pyrite content of single framboid varied between 0%and 86.4%.Therefore,numerous pyrites were oxygenated to iron oxides or oxyhydroxides,and were retained as pseudomorphism pyrites.The size of framboidal pyrites precipitated in cold seeps can be used to trace the redox environment;however,acquisition of additional data via investigation of different cold seeps is necessary to obtain more persuasive results.
文摘为研究卡尼期雨幕事件在鄂尔多斯盆地南部的响应,对该盆地ZH2钻孔延长组进行孢粉化石、有机碳同位素、草莓状黄铁矿和主量元素分析。孢粉化石由下至上划分出Punctatisporites-Verrucosisporites-Osmundacidites组合Ⅰ和Asseretospora-Apiculatisporis组合Ⅱ,地质年代分别为中三叠世拉丁期和晚三叠世卡尼期。在孢粉组合Ⅱ下部张家滩页岩中总有机碳富集、有机碳同位素发生负漂移,漂移量为4.88‰,同时草莓状黄铁矿指标指示着该层位形成于贫氧的环境,Al_(2)O_(3)/MgO比值和化学蚀变指数(chemical index of alteration,CIA)值在该层位均处于高值,指示着高温、湿润、强化学风化的环境。以上特征表明卡尼期雨幕事件在鄂尔多斯盆地造成了显著影响。进一步分析显示这些指标在张家滩页岩中可划分为4个独立的高温、湿润、缺氧、有机碳富集片段,指示了卡尼期雨幕事件(Carnian pluvial event,CPE)在鄂尔多斯盆地的4次气候波动,分别命名为:CPEⅠ、CPEⅡ、CPEⅢ、CPEⅣ。
