Complex trimalleolar ankle fractures are a major orthopaedic challenge,with an incidence of 4.22 per 10000 person-years in the United States and an annual cost of 3.4 billion dollars.This review synthesizes current ev...Complex trimalleolar ankle fractures are a major orthopaedic challenge,with an incidence of 4.22 per 10000 person-years in the United States and an annual cost of 3.4 billion dollars.This review synthesizes current evidence on diagnostic protocols and management strategies,highlighting optimal approaches and emerging trends.Initial care emphasizes soft tissue assessment,often guided by the Tscherne classification,and fracture classification systems.External fixation may be required in open injuries,while early open reduction and internal fixation within six days is linked to improved outcomes.Minimally invasive techniques for the lateral malleolus,including intramedullary nailing and locking plates,are effective,while medial malleolus fractures are commonly managed with screw fixation or tension-band wiring.Posterior malleolus fragments involving more than 25%of the articular surface usually warrant fixation.Alternatives to syndesmotic screws,such as cortical buttons or high-strength sutures,reduce the need for secondary procedures.Arthroscopic-assisted open reduction and internal fixation benefits younger,active patients by enabling concurrent management of intra-articular and ligamentous injuries.Postoperative care prioritizes early weight-bearing and validated functional scores.Despite advances,complications remain common,and further research is needed to refine surgical strategies and improve outcomes.展开更多
The migration,accumulation,and high yield of hydrocarbons in tight sandstone reservoirs are closely tied to the natural fracture systems within the reservoirs.Large-scale fracture networks not only enhance reservoir s...The migration,accumulation,and high yield of hydrocarbons in tight sandstone reservoirs are closely tied to the natural fracture systems within the reservoirs.Large-scale fracture networks not only enhance reservoir seepage capacity but also influence effective productivity and subsequent fracturing reconstruction.Given the diverse mechanical behaviors,such as migration,penetration,or fracture arrest,traditional assumptions about fracture interaction criteria fail to address this complexity.To resolve these issues,a global cohesive element method is proposed to model random natural fractures.This approach verifies intersection models based on real-time stress conditions rather than pre-set criteria,enabling better characterization of interactions between hydraulic and natural fractures.Research has shown that the elastic modulus,horizontal stress difference,and fracturing fluid pumping rate significantly promote the expansion of hydraulic fractures.The use of low viscosity fracturing fluid can observe a decrease in the width of fractures near the wellbore,which may cause fractures to deflect when interacting with natural fractures.However,simulations under these conditions did not form a“complex network of fractures”.It is worth noting that when the local stress difference is zero,the result is close to the formation of this network.Excessive spacing will reduce the interaction between fractures,resulting in a decrease in the total length of fractures.By comprehensively analyzing these factors,an optimal combination can be identified,increasing the likelihood of achieving a“complex fracture network”.This paper thoroughly investigates hydraulic fracture propagation in naturally fractured reservoirs under various conditions,offering insights for developing efficient fracturing methods.展开更多
Self-suspended proppants,which enable clear-water fracturing,represent a promising new class of materials for reservoir stimulation.Given the economic limitations associated with their exclusive use,this study investi...Self-suspended proppants,which enable clear-water fracturing,represent a promising new class of materials for reservoir stimulation.Given the economic limitations associated with their exclusive use,this study investigates proppant transport behavior in hybrid systems combining self-suspended proppants with conventional 40/70 mesh quartz sand at various mixing ratios.A dedicated experimental apparatus was developed to replicate field-relevant complex fracture networks,consisting of a main fracture and two branching fractures with different deflection angles.Using this system,sand bank formation and proppant distribution were examined for both conventional quartz sand fracturing and fracturing augmented with self-suspended proppants.The effects of slurry discharge volume,proppant mixing ratio,sand ratio,and injection location of the self-suspended proppant on transport and placement behavior were systematically analyzed.According to the results,the incorporation of self-suspended proppants markedly enhances the proppant-carrying capacity of the slurry and substantially modifies sand bank morphology.Increasing the discharge volume raises the inlet slope angle and promotes greater proppant penetration into branch fractures.The proportion of self-suspended proppant governs slurry viscoelasticity and,consequently,proppant settling behavior.As the fraction of self-suspended proppant decreases,the equilibrium height of the sand bank increases,while the proppant mass fraction within branch fractures exhibits a non-monotonic response,initially decreasing and then increasing.Variations in sand ratio alter both overall proppant concentration and the self-suspended proppant-to-water ratio,thereby modulating slurry rheology and influencing proppant placement.In addition,changes in injection location affect near-wellbore vortex structures,leading to distinct sand bank morphologies.展开更多
A three-dimensional multiphase particle-in-cell(MP-PIC)method was adopted to establish a liquid-solid two-phase flow model accounting for complex fracture networks.The model was validated using physical experimental d...A three-dimensional multiphase particle-in-cell(MP-PIC)method was adopted to establish a liquid-solid two-phase flow model accounting for complex fracture networks.The model was validated using physical experimental data.On this basis,the main factors influencing proppant transport in fracture network were analyzed.The study shows that proppant transport in fracture network can be divided into three stages:initial filling,dominant channel formation and fracture network extension.These correspond to three transport patterns:patch-like accumulation near the wellbore,preferential placement along main fractures,and improved the coverage of planar placement as fluid flows into branch fractures.Higher proppant density,lower fracturing fluid viscosity,lower injection rate,and larger proppant grain size result in shorter proppant transport distance and smaller planar placement coefficient.The use of low-density,small-diameter proppant combined with high-viscosity fracturing fluid and appropriately increased injection rate can effectively enlarge the stimulated volume.A smaller angle between the main fracture and branch fractures leads to longer proppant banks,broader coverage,more uniform distribution,and better stimulation performance in branch fractures.In contrast,a larger angle increases the likelihood of proppant accumulation near the branch fracture entrance and reduces the planar placement coefficient.展开更多
Three copper(Ⅱ),nickel and cadmium(Ⅱ)complexes,namely[Cu_(2)(μ-H2dbda)2(phen)2]·2H_(2)O(1),[Ni(μ-H2dbda)(μ-bpb)(H_(2)O)2]n(2),and[Cd(μ-H2dbda)(μ-bpa)]n(3),have been constructed hydrothermally using H4dbda(...Three copper(Ⅱ),nickel and cadmium(Ⅱ)complexes,namely[Cu_(2)(μ-H2dbda)2(phen)2]·2H_(2)O(1),[Ni(μ-H2dbda)(μ-bpb)(H_(2)O)2]n(2),and[Cd(μ-H2dbda)(μ-bpa)]n(3),have been constructed hydrothermally using H4dbda(4,4'-dihydroxy-[1,1'-biphenyl]-3,3'-dicarboxylic acid),phen(1,10-phenanthroline),bpb(1,4-bis(pyrid-4-yl)benzene),bpa(bis(4-pyridyl)amine),and copper,nickel and cadmium chlorides at 160℃.The products were isolated as stable crystalline solids and were characterized by IR spectra,elemental analyses,thermogravimetric analyses,and singlecrystal X-ray diffraction analyses.Single-crystal X-ray diffraction analyses revealed that three complexes crystallize in the monoclinic P21/n,tetragonal I42d,and orthorhombic P21212 space groups.The complexes exhibit molecular dimers(1)or 2D metal-organic networks(2 and 3).The catalytic performances in the Knoevenagel reaction of these complexes were investigated.Complex 1 exhibits an effective catalytic activity and excellent reusability as a heterogeneous catalyst in the Knoevenagel reaction at room temperature.CCDC:2463800,1;2463801,2;2463802,3.展开更多
Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'...Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'-bipyridine]were successfully synthesized by the volatilization of the solution at room temperature.The crystal structures of six complexes were determined by single-crystal X-ray diffraction technology.The results showed that the complexes all have a binuclear structure,and the structures contain free ethanol molecules.Moreover,the coordination number of the central metal of each structural unit is eight.Adjacent structural units interact with each other through hydrogen bonds and further expand to form 1D chain-like and 2D planar structures.After conducting a systematic study on the luminescence properties of complexes 1-4,their emission and excitation spectra were obtained.Experimental results indicated that the fluorescence lifetimes of complexes 2 and 3 were 0.807 and 0.845 ms,respectively.The emission spectral data of complexes 1-4 were imported into the CIE chromaticity coordinate system,and their corre sponding luminescent regions cover the yellow light,red light,green light,and orange-red light bands,respectively.Within the temperature range of 299.15-1300 K,the thermal decomposition processes of the six complexes were comprehensively analyzed by using TG-DSC/FTIR/MS technology.The hypothesis of the gradual loss of ligand groups during the decomposition process was verified by detecting the escaped gas,3D infrared spectroscopy,and ion fragment information detected by mass spectrometry.The specific decomposition path is as follows:firstly,free ethanol molecules and neutral ligands are removed,and finally,acidic ligands are released;the final product is the corresponding metal oxide.CCDC:2430420,1;2430422,2;2430419,3;2430424,4;2430421,5;2430423,6.展开更多
To investigate the fracture initiation and propagation behavior of fractures in tight sandstone under the supercritical CO_(2)(SCCO_(2))shock fracturing,laboratory fracturing experiments were conducted using a true-tr...To investigate the fracture initiation and propagation behavior of fractures in tight sandstone under the supercritical CO_(2)(SCCO_(2))shock fracturing,laboratory fracturing experiments were conducted using a true-triaxial-like SCCO_(2)shock fracturing system.Computed tomography(CT)scanning and three-dimensional fracture reconstruction were employed to elucidate the effects of shock pressure,pore pressure,and in-situ stress on fracture characteristics.In addition,nuclear magnetic resonance(NMR)transverse relaxation time spectra were used to assess the internal damage induced by SCCO_(2)shock fracturing.The results indicate that,compared with conventional hydraulic fracturing and SCCO_(2)quasi-static fracturing,SCCO_(2)shock fracturing facilitates multidirectional fracture initiation and the formation of complex fracture networks.Increasing shock pressure more readily activates bedding-plane weaknesses,with main and subsidiary fractures interweaving into a dense fracture network.Under the same impulse intensity,elevated pore pressure reduces the effective normal stress and alters stress-wave scattering paths,thereby inducing more branch fractures and enhancing fracture complexity.An increase in differential in-situ stress promotes fracture propagation along the direction of the maximum principal stress,reduces branching,and simplifies fracture morphology.With increasing SCCO_(2)shock pressure,pore volume and connectivity generally increase:small-to-medium pores primarily respond through increased number and enhanced connectivity;when the shock pressure rises to 40-45 MPa,crack coalescence generates larger pores and fissures,which play a dominant role in improving flow pathways and effective storage space,ultimately forming a multiscale pore-fracture network.展开更多
Three zinc(Ⅱ),nickel(Ⅱ),and cadmium(Ⅱ)complexes,namely[Zn(μ-Htpta)(py)_(2)]n(1),[Ni(H_(2)biim)2(H_(2)O)2][Ni(tpta)(H_(2)biim)2(H_(2)O)]2·3H_(2)O(2),and[Cd_(3)(μ4-tpta)2(μ-dpe)_(3)]_(n)(3),have been construc...Three zinc(Ⅱ),nickel(Ⅱ),and cadmium(Ⅱ)complexes,namely[Zn(μ-Htpta)(py)_(2)]n(1),[Ni(H_(2)biim)2(H_(2)O)2][Ni(tpta)(H_(2)biim)2(H_(2)O)]2·3H_(2)O(2),and[Cd_(3)(μ4-tpta)2(μ-dpe)_(3)]_(n)(3),have been constructed hydrothermally at 160℃ using H_(3)tpta([1,1':3',1″-terphenyl]-4,4',5'-tricarboxylic acid),py(pyridine),H_(2)biim(2,2'-biimidazole),dpe(1,2-di(4-pyridyl)ethylene),and zinc,nickel and cadmium chlorides,resulting in the formation of stable crystalline solids which were subsequently analyzed using infrared spectroscopy,element analysis,thermogravimetric analysis,as well as structural analyses conducted via single-crystal X-ray diffraction.The findings from these single-crystal Xray diffraction studies indicate that complexes 1-3 form crystals within the monoclinic system P2_(1)/c space group(1)or triclinic system P1 space group(2 and 3),and possess 1D,0D,and 3D structures,respectively.Complex 1 demonstrated substantial catalytic efficiency and excellent reusability as a heterogeneous catalyst in the reaction of Knoevenagel condensation under ambient temperature conditions.In addition,complex 1 also showcased notable anti-wear performance when used in polyalphaolefin synthetic lubricants.CCDC:2449810,1;2449811,2;2449812,3.展开更多
This paper reports the preparation of three di‑iron complexes containing a thiazole moiety.Esterification of complex[Fe_(2)(CO)_(6)(μ‑SCH_(2)CH(CH_(2)OH)S)](1)with 4‑methylthiazole‑5‑carboxylic acid gave the correspo...This paper reports the preparation of three di‑iron complexes containing a thiazole moiety.Esterification of complex[Fe_(2)(CO)_(6)(μ‑SCH_(2)CH(CH_(2)OH)S)](1)with 4‑methylthiazole‑5‑carboxylic acid gave the corresponding ester[Fe_(2)(CO)_(6)(μ‑tedt)](2),where tedt=SCH_(2)CH(CH_(2)OOC(5‑C_(3)HNSCH_(3)))S.Further reactions of complex 2 with tri(ptolyl)phosphine(tp)or tris(4‑fluorophenyl)phosphine(fp)gave the phosphine‑substituted derivatives[Fe_(2)(CO)_(5)(tp)(μ‑tedt)](3)and[Fe_(2)(CO)_(5)(fp)(μ‑tedt)](4).The structures of the newly prepared complexes were elucidated by elemental analysis,NMR,IR,and X‑ray photoelectron spectroscopy.Moreover,single‑crystal X‑ray diffraction analysis confirmed their molecular structures,showing that they contain a di‑iron core ligated by a bridged dithiolate bearing a thiazole moiety and terminal carbonyls.The electrochemical and electrocatalytic proton reduction were probed by cyclic voltammetry,revealing that three complexes can catalyze the reduction of protons to H_(2) under the electrochemical conditions.For comparison,complex 4 possessed the best efficiency with a turnover frequency of 23.5 s^(-1)at 10 mmol·L^(-1)HOAc concentration.In addition,the fungicidal activity of these complexes was also investigated in this study.CCDC:2477511,2;2477512,3;2477513,4.展开更多
Re-fracturing horizontal wells is a critical strategy for enhancing recovery from tight oil reservoirs,but its success depends on the evaluation of candidate wells and locations.This process is complicated by producti...Re-fracturing horizontal wells is a critical strategy for enhancing recovery from tight oil reservoirs,but its success depends on the evaluation of candidate wells and locations.This process is complicated by production-induced alterations in reservoir pressure and geomechanical responses.This study introduces a workflow to evaluate re-fracturing potential by integrating coupled fluid flow and geomechanical modeling for the production of initial hydraulic fractures.We developed a numerical model that simulates the poroelastic response of a tight oil reservoir to depletion from an initial set of hydraulic fractures.To quantify the re-fracturing potential along the horizontal wellbore,a novel composite re-fracturing potential index is proposed where fracture shape,stress,and pressure are considered.This index considers four key physical factors:current reservoir pressure,fracture initiation ease,fracture geometry favorability,and fracture propagation efficiency considering tortuosity.Numerical simulations were conducted for scenarios with both uniform and non-uniform initial hydraulic fractures.The results consistently demonstrate that the optimal locations for re-fracturing are the midpoints between existing fractures,where a favorable balance of high reservoir pressure and altered stress conditions exists.The analysis reveals that the overall re-fracturing potential tends to increase with production time,suggesting that a period of depletion can enhance the geomechanical conditions for subsequent stimulation.Furthermore,a sensitivity analysis on the index weighting factors shows that the optimum re-fracturing strategy is highly dependent on the primary field objective,whether it is maximizing resource contact,ensuring geomechanical feasibility,or avoiding operational complexity.The study concludes that heterogeneity in the initial fracture network creates complex and asymmetric potential profiles,which implies the necessity of case-specific and integrated analysis over simplified assumptions.The proposed methodology provides a framework for optimizing re-fracturing designs in tight oil reservoirs.展开更多
The hydrated tricyclohexyltin theophylline-7-acetic acid(tpH)complex[Sn(C_(6)H_(11))_(3)(tp)(H_(2)O)]was synthesized via an ethanol solvothermal method using tricyclohexyltin hydroxide and tpH in a 1∶1 molar ratio.Th...The hydrated tricyclohexyltin theophylline-7-acetic acid(tpH)complex[Sn(C_(6)H_(11))_(3)(tp)(H_(2)O)]was synthesized via an ethanol solvothermal method using tricyclohexyltin hydroxide and tpH in a 1∶1 molar ratio.The complex was characterized by IR,^(1)H(^(13)C)NMR,elemental analysis,and powder X-ray diffraction,and the crystal structure was determined by single-crystal X-ray diffraction.The crystal belongs to the orthorhombic system with space group Iba2,and the central tin atom is in a five-coordinated trigonal bipyramidal configuration.Quantum chemistry ab initio calculations were performed to investigate the stability,molecular orbital energy,and frontier molecular orbital characteristics of the complex.Additionally,its thermal stability,electrochemical properties,and in vitro anticancer activity were evaluated.CCDC:2380308.展开更多
The increase in CO_(2)injectivity and shifting of CO_(2)-absorbing layers in multilayered geological CO_(2)sequestration(GCS)reservoirs in Ordos,China indicate significantpermeability variations in certain layers.To c...The increase in CO_(2)injectivity and shifting of CO_(2)-absorbing layers in multilayered geological CO_(2)sequestration(GCS)reservoirs in Ordos,China indicate significantpermeability variations in certain layers.To capture these system changes,a numerical model incorporating all 21 aquifers and internal aquitards was developed.The monitored pressure was well matched through multiphase and thermalhydraulic-mechanical(THM)coupling numerical simulations by introducing permeability variations.The results revealed that the permeability in the second layer increased on approximately day 13 due to the abrupt pressure buildup and temperature decrease.Even such a low rate of CO_(2)(2.8 kg/s)injected into the low permeability system initiated some fractures and the permeability in the second layer around the wellbore increased by 722 times.The second critical system change occurred on approximately day 386.As demonstrated in the numerical simulation,the substantial injection of cold CO_(2)induced strong thermal stress,leading to rock contraction and the initiation of several cracks.The permeability of the firstlayer around the wellbore unexpectedly increased by 4 orders of magnitude.Since no additional pressure could drive the CO_(2)into the remaining 17 layers,the total storage capability of the multilayered system was reduced.A whole picture of the system variation is fully presented and the underlying mechanisms are analyzed.It is believed that the phenomenon of thermal-hydraulic fracturing observed in this fieldand the simulation procedures will benefitother fluidinjection and production works in various geotechnical settings.展开更多
Fractures are typically characterized by roughness that significantlyaffects the mechanical and hydraulic characteristics of reservoirs.However,hydraulic fracturing mechanisms under the influenceof fracture morphology...Fractures are typically characterized by roughness that significantlyaffects the mechanical and hydraulic characteristics of reservoirs.However,hydraulic fracturing mechanisms under the influenceof fracture morphology remain largely unexplored.Leveraging the advantages of the finite-discrete element method(FDEM)for explicitly simulating fracture propagation and the strengths of the unifiedpipe model(UPM)for efficientlymodeling dual-permeability seepage,we propose a new hydromechanical(HM)coupling approach for modeling hydraulic fracturing.Validated against benchmark examples,the proposed FDEM-UPM model is further augmented by incorporating a Fourier-based methodology for reconstructing non-planar fractures,enabling quantitative analysis of hydraulic fracturing behavior within rough discrete fracture networks(DFNs).The FDEM-UPM model demonstrates computational advantages in accurately capturing transient hydraulic seepage phenomena,while the asynchronous time-stepping schemes between hydraulic and mechanical analyses substantially enhanced computational efficiencywithout compromising computational accuracy.Our results show that fracture morphology can affect both macroscopic fracture networks and microscopic interaction types between hydraulic fractures(HFs)and natural fractures(NFs).In an isotropic stress field,the initiation azimuth,propagation direction and microcracking mechanism are significantly influencedby fracture roughness.In an anisotropic stress field,HFs invariably propagate parallel to the direction of the maximum principal stress,reducing the overall complexity of the stimulated fracture networks.Additionally,stress concentration and perturbation attributed to fracture morphology tend to be compromised as the leak-off increases,while the breakdown and propagation pressures remain insensitive to fracture morphology.These findingsprovide new insights into the hydraulic fracturing mechanisms of fractured reservoirs containing complex rough DFNs.展开更多
To address the key scientific challenge of monitoring the dynamic fracturing of surrounding rock in deep roadways,this study systematically investigates the quantitative relationship between stress and charge signals ...To address the key scientific challenge of monitoring the dynamic fracturing of surrounding rock in deep roadways,this study systematically investigates the quantitative relationship between stress and charge signals during coal mass loading.By integrating innovative analytical approaches,introducing quantitative evaluation indices,and developing a charge–stress inversion model,and incorporating underground monitoring practices,significant progress has been achieved in elucidating the correlation between stress variations and charge signals throughout the entire coal mass fracturing process.First,in the field of stress–charge correlation analysis,empirical mode decomposition(EMD)was combined with wavelet coherence analysis for the first time,enabling the removal of slow-varying stress trends while retaining high-frequency fluctuations.This approach allowed for the quantitative characterization of the evolution of coherence between stress variations and charge fluctuations across multiple time scales.Second,coherence skewness and the proportion of high-coherence intervals were innovatively introduced to examine the influence of time scale selection on correlation results.On this basis,a criterion for determining the near-optimal observation scale of charge signals was proposed,providing a quantitative reference for time scale selection in similar signal analyses.Finally,by correlating charge signals with coal damage factors and stress states,a charge-based damage evolution equation was established to achieve effective stress inversion.Combined with in situ monitoring of stress and charge in roadway surrounding rock,this approach revealed the correlation characteristics of stress and charge intensity responses during the dynamic fracturing process.The results indicate,first,that charge signals are not significantly correlated with the absolute stress level of coal but are directly associated with stress variations following coal damage and failure,with the amplitude of charge fluctuations increasing alongside stress fluctuations.Second,coherence between stress and charge signals varies markedly across time scales,with excessively small or large scales leading to distortion,and the scale corresponding to the peak proportion of intervals with coherence>0.8 was identified as the near-optimal observation scale.Third,charge signals can effectively characterize coal damage factors,and the established damage evolution equation can effectively invert stress variation trends.Fourth,in underground roadways,zones of dynamic fracturing in surrounding rock are commonly located in areas where stress concentration overlaps with regions of high charge intensity,further confirming the strong consistency between charge and stress variations.These findings improve the theoretical framework of charge signal responses in loaded coal and provide a scientific basis for precise“stress-charge”monitoring of dynamic disasters,offering practical potential for engineering applications.展开更多
In the development of coalbed methane(CBM)reservoirs using multistage fractured horizontal wells,there often exist areas that are either repeatedly stimulated or completely unstimulated between fracturing stages,leadi...In the development of coalbed methane(CBM)reservoirs using multistage fractured horizontal wells,there often exist areas that are either repeatedly stimulated or completely unstimulated between fracturing stages,leading to suboptimal reservoir performance.Currently,there is no well-established method for accurately evaluating the effectiveness of such stimulation.This study introduces,for the first time,the concept of the Fracture Network Bridging Coefficient(FNBC)as a novel metric to assess stimulation performance.By quantitatively coupling the proportions of unstimulated and overstimulated volumes,the FNBC effectively characterizes the connectivity and efficiency of the fracture network.A background grid calibration method is developed to quantify the stage-controlled volume,effectively stimulated volume,unstimulated volume,and repeatedly stimulated volume among different stages of horizontal wells.Furthermore,an optimization model is constructed by taking the FNBC as the objective function and the fracturing injection rate and fluid volume as optimization variables.The Simultaneous Perturbation Stochastic Approximation(SPSA)algorithm is employed to iteratively perturb and optimize these variables,progressively improving the FNBC until the optimal displacement rate and fluid volume corresponding to the maximum FNBC are obtained.Field application in a typical CBM multistage fractured horizontal well in China demonstrates that the FNBC increased from 0.358 to 0.539(a 50.6% improvement),with the injection rate rising from 16 m^(3)/min to 24 m^(3)/min and the average fluid volume per stage increasing from 2490 m^(3) to 3192 m^(3),significantly enhancing the stimulation effectiveness.This research provides theoretical support for designing high-efficiency stimulation strategies in unconventional reservoirs under dynamic limits.展开更多
Abstract:Microwave-based destressing is regarded as a promising approach for proactively preventing and controlling rockbursts in deep hard rock.As the fracturing degree of microwave-induced boreholes is affected by b...Abstract:Microwave-based destressing is regarded as a promising approach for proactively preventing and controlling rockbursts in deep hard rock.As the fracturing degree of microwave-induced boreholes is affected by borehole diameter,water content,mineral content,etc.,it is difficult to establish relationships between them.The research aims to unify various factors with heating rate and temperature,and establish a microwave parameter design method based thereon.Tests on microwave-induced borehole fracturing in hard rock with different or similar heating rates and temperatures under true triaxial stress were conducted.The test results show that both heating rate and temperature promote radial fracture of the rock,but have little effect on the development of axial fractures.Compared with heating rate,temperature is a more critical factor influencing microwave-induced fracturing.The effects of the heating rate on rock fracturing become noticeable only at higher temperatures.When the heating rate and temperature are similar but the diameter of the boreholes is different,the crack distribution,total length,wave velocity attenuation,and fracture process are similar.It is feasible to reverse-design microwave parameters under different borehole diameters based on the heating rate and temperature.Thermal fracturing of basalt shows a distinct threshold effect between 150℃ and 195℃(with an average of about 175℃),and the heating rate and borehole diameter exert minor influences thereon.The results provide guidance for the design of microwave parameters in practice.展开更多
Single-pixel imaging(SPI)receives widespread attention due to its superior anti-interference capabilities,and image segmentation technology can effectively facilitate its recognition and information extraction.However...Single-pixel imaging(SPI)receives widespread attention due to its superior anti-interference capabilities,and image segmentation technology can effectively facilitate its recognition and information extraction.However,the complexity of the target scene and plenty of imaging time in SPI make it challenging to achieve high-quality and concise segmentation.In this paper,we investigate the image-free intricate scene semantic segmentation in SPI.Using“learned”illumination patterns allows for the full extraction of the object's spatial information,thereby enabling pixel-level segmentation results through the decoding of the received measurements.Simulation and experimentation show that,in the absence of image reconstruction,the mean intersection over union(MIoU)of segmented image can reach higher than 85%,and the Dice coefficient(DICE)close to 90%even at the sampling ratio of 5%.Our approach may be favorable to applications in medical image segmentation and autonomous driving field.展开更多
High-voltage electric pulse(HVEP)rock fragmentation has demonstrated substantial potential for sustainable fracturing of hard rocks owing to its energy efficiency.The transient nature and highly disruptive characteris...High-voltage electric pulse(HVEP)rock fragmentation has demonstrated substantial potential for sustainable fracturing of hard rocks owing to its energy efficiency.The transient nature and highly disruptive characteristics of its physical fracturing process render experimental investigation of the underlying rock-breaking mechanisms challenging.However,existing numerical studies lack comprehensive models that precisely link electrical breakdown phenomena with mechanical disintegration processes.This study combines COMSOL electrical breakdown simulations with four-dimension lattice spring model(4D-LSM)mechanical analysis to establish a coupled HVEP rock fragmentation model.The core concept of the model construction is to import the temperature field of the plasma channel obtained from the electrical breakdown into the mechanical solver to realize the precise connection between the two stages.The validated numerical model elucidates the full process of HVEP-induced fragmentation under varying electrical parameters.Furthermore,the effects of confining pressure and mineral grain size on fragmentation behavior have been investigated.Finally,parametric simulations across 25 electrical parameter combinations demonstrate the critical role of electrode spacing optimization in achieving energy-efficient rock fragmentation.These findings provide a predictive tool for designing efficient HVEP systems in deep resource extraction and mineral processing engineering.展开更多
Dear Editor,We present a case of acute zonal occult outer retinopathy(AZOOR)complex in a myopic patient with angioid streaks(ASs).A 19-year-old female has been experiencing visual field defects in her left eye for mor...Dear Editor,We present a case of acute zonal occult outer retinopathy(AZOOR)complex in a myopic patient with angioid streaks(ASs).A 19-year-old female has been experiencing visual field defects in her left eye for more than 3y.She was diagnosed with ASs and choroiditis at a local hospital.She has a seven-year history of bilateral high myopia.A fundus examination confirmed the presence of ASs and myopic fundus changes in both eyes.Multimodal imaging revealed an AZOOR complex in the left eye.展开更多
The complexes 1-4 of cyclobutanocucurbit[5]uril(CyB5Q[5])with Na^(+)/K^(+)have been synthesized and characterized by single-crystal X-ray diffraction.The results show that although the inorganic salts are used when th...The complexes 1-4 of cyclobutanocucurbit[5]uril(CyB5Q[5])with Na^(+)/K^(+)have been synthesized and characterized by single-crystal X-ray diffraction.The results show that although the inorganic salts are used when the cations are the same and the anions are different,in complex 1,Na^(+)closes one port of CyB5Q[5]through Na—O seven coordination bonds to form a molecular bowl;in complex 3,Na^(+)completely closes the two ports of CyB5Q[5]to form a molecular capsule with six Na—O coordination bonds;in complexes 2 and 4,the two ports of CyB5Q[5]are completely closed to form K—O coordinated molecular capsules,but the K^(+)of complex 2 is six-coordinated and that of complex 4 is eight-/nine-coordinated.and complex 4 are connected by three oxygen bridges to form a 1D molecular chain.CCDC:2457122,1;2457121,2;2457400,3;2457120,4.展开更多
文摘Complex trimalleolar ankle fractures are a major orthopaedic challenge,with an incidence of 4.22 per 10000 person-years in the United States and an annual cost of 3.4 billion dollars.This review synthesizes current evidence on diagnostic protocols and management strategies,highlighting optimal approaches and emerging trends.Initial care emphasizes soft tissue assessment,often guided by the Tscherne classification,and fracture classification systems.External fixation may be required in open injuries,while early open reduction and internal fixation within six days is linked to improved outcomes.Minimally invasive techniques for the lateral malleolus,including intramedullary nailing and locking plates,are effective,while medial malleolus fractures are commonly managed with screw fixation or tension-band wiring.Posterior malleolus fragments involving more than 25%of the articular surface usually warrant fixation.Alternatives to syndesmotic screws,such as cortical buttons or high-strength sutures,reduce the need for secondary procedures.Arthroscopic-assisted open reduction and internal fixation benefits younger,active patients by enabling concurrent management of intra-articular and ligamentous injuries.Postoperative care prioritizes early weight-bearing and validated functional scores.Despite advances,complications remain common,and further research is needed to refine surgical strategies and improve outcomes.
基金supported by the National Natural Science Foundation of China(52074313).
文摘The migration,accumulation,and high yield of hydrocarbons in tight sandstone reservoirs are closely tied to the natural fracture systems within the reservoirs.Large-scale fracture networks not only enhance reservoir seepage capacity but also influence effective productivity and subsequent fracturing reconstruction.Given the diverse mechanical behaviors,such as migration,penetration,or fracture arrest,traditional assumptions about fracture interaction criteria fail to address this complexity.To resolve these issues,a global cohesive element method is proposed to model random natural fractures.This approach verifies intersection models based on real-time stress conditions rather than pre-set criteria,enabling better characterization of interactions between hydraulic and natural fractures.Research has shown that the elastic modulus,horizontal stress difference,and fracturing fluid pumping rate significantly promote the expansion of hydraulic fractures.The use of low viscosity fracturing fluid can observe a decrease in the width of fractures near the wellbore,which may cause fractures to deflect when interacting with natural fractures.However,simulations under these conditions did not form a“complex network of fractures”.It is worth noting that when the local stress difference is zero,the result is close to the formation of this network.Excessive spacing will reduce the interaction between fractures,resulting in a decrease in the total length of fractures.By comprehensively analyzing these factors,an optimal combination can be identified,increasing the likelihood of achieving a“complex fracture network”.This paper thoroughly investigates hydraulic fracture propagation in naturally fractured reservoirs under various conditions,offering insights for developing efficient fracturing methods.
基金the China National Petroleum Corporation’s Forward-Looking Fundamental Technology Breakthrough Project(2021DJ2305).
文摘Self-suspended proppants,which enable clear-water fracturing,represent a promising new class of materials for reservoir stimulation.Given the economic limitations associated with their exclusive use,this study investigates proppant transport behavior in hybrid systems combining self-suspended proppants with conventional 40/70 mesh quartz sand at various mixing ratios.A dedicated experimental apparatus was developed to replicate field-relevant complex fracture networks,consisting of a main fracture and two branching fractures with different deflection angles.Using this system,sand bank formation and proppant distribution were examined for both conventional quartz sand fracturing and fracturing augmented with self-suspended proppants.The effects of slurry discharge volume,proppant mixing ratio,sand ratio,and injection location of the self-suspended proppant on transport and placement behavior were systematically analyzed.According to the results,the incorporation of self-suspended proppants markedly enhances the proppant-carrying capacity of the slurry and substantially modifies sand bank morphology.Increasing the discharge volume raises the inlet slope angle and promotes greater proppant penetration into branch fractures.The proportion of self-suspended proppant governs slurry viscoelasticity and,consequently,proppant settling behavior.As the fraction of self-suspended proppant decreases,the equilibrium height of the sand bank increases,while the proppant mass fraction within branch fractures exhibits a non-monotonic response,initially decreasing and then increasing.Variations in sand ratio alter both overall proppant concentration and the self-suspended proppant-to-water ratio,thereby modulating slurry rheology and influencing proppant placement.In addition,changes in injection location affect near-wellbore vortex structures,leading to distinct sand bank morphologies.
基金Supported by the National Natural Science Foundation of China(U21B2071,U23B20156)。
文摘A three-dimensional multiphase particle-in-cell(MP-PIC)method was adopted to establish a liquid-solid two-phase flow model accounting for complex fracture networks.The model was validated using physical experimental data.On this basis,the main factors influencing proppant transport in fracture network were analyzed.The study shows that proppant transport in fracture network can be divided into three stages:initial filling,dominant channel formation and fracture network extension.These correspond to three transport patterns:patch-like accumulation near the wellbore,preferential placement along main fractures,and improved the coverage of planar placement as fluid flows into branch fractures.Higher proppant density,lower fracturing fluid viscosity,lower injection rate,and larger proppant grain size result in shorter proppant transport distance and smaller planar placement coefficient.The use of low-density,small-diameter proppant combined with high-viscosity fracturing fluid and appropriately increased injection rate can effectively enlarge the stimulated volume.A smaller angle between the main fracture and branch fractures leads to longer proppant banks,broader coverage,more uniform distribution,and better stimulation performance in branch fractures.In contrast,a larger angle increases the likelihood of proppant accumulation near the branch fracture entrance and reduces the planar placement coefficient.
文摘Three copper(Ⅱ),nickel and cadmium(Ⅱ)complexes,namely[Cu_(2)(μ-H2dbda)2(phen)2]·2H_(2)O(1),[Ni(μ-H2dbda)(μ-bpb)(H_(2)O)2]n(2),and[Cd(μ-H2dbda)(μ-bpa)]n(3),have been constructed hydrothermally using H4dbda(4,4'-dihydroxy-[1,1'-biphenyl]-3,3'-dicarboxylic acid),phen(1,10-phenanthroline),bpb(1,4-bis(pyrid-4-yl)benzene),bpa(bis(4-pyridyl)amine),and copper,nickel and cadmium chlorides at 160℃.The products were isolated as stable crystalline solids and were characterized by IR spectra,elemental analyses,thermogravimetric analyses,and singlecrystal X-ray diffraction analyses.Single-crystal X-ray diffraction analyses revealed that three complexes crystallize in the monoclinic P21/n,tetragonal I42d,and orthorhombic P21212 space groups.The complexes exhibit molecular dimers(1)or 2D metal-organic networks(2 and 3).The catalytic performances in the Knoevenagel reaction of these complexes were investigated.Complex 1 exhibits an effective catalytic activity and excellent reusability as a heterogeneous catalyst in the Knoevenagel reaction at room temperature.CCDC:2463800,1;2463801,2;2463802,3.
文摘Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'-bipyridine]were successfully synthesized by the volatilization of the solution at room temperature.The crystal structures of six complexes were determined by single-crystal X-ray diffraction technology.The results showed that the complexes all have a binuclear structure,and the structures contain free ethanol molecules.Moreover,the coordination number of the central metal of each structural unit is eight.Adjacent structural units interact with each other through hydrogen bonds and further expand to form 1D chain-like and 2D planar structures.After conducting a systematic study on the luminescence properties of complexes 1-4,their emission and excitation spectra were obtained.Experimental results indicated that the fluorescence lifetimes of complexes 2 and 3 were 0.807 and 0.845 ms,respectively.The emission spectral data of complexes 1-4 were imported into the CIE chromaticity coordinate system,and their corre sponding luminescent regions cover the yellow light,red light,green light,and orange-red light bands,respectively.Within the temperature range of 299.15-1300 K,the thermal decomposition processes of the six complexes were comprehensively analyzed by using TG-DSC/FTIR/MS technology.The hypothesis of the gradual loss of ligand groups during the decomposition process was verified by detecting the escaped gas,3D infrared spectroscopy,and ion fragment information detected by mass spectrometry.The specific decomposition path is as follows:firstly,free ethanol molecules and neutral ligands are removed,and finally,acidic ligands are released;the final product is the corresponding metal oxide.CCDC:2430420,1;2430422,2;2430419,3;2430424,4;2430421,5;2430423,6.
基金Supported by the National Natural Science Foundation for Outstanding Young Scholars(52425402)National Natural Science Foundation of China(52341401)International(Regional)Cooperation and Exchange Program of the National Natural Science Foundation of China(W2412078)。
文摘To investigate the fracture initiation and propagation behavior of fractures in tight sandstone under the supercritical CO_(2)(SCCO_(2))shock fracturing,laboratory fracturing experiments were conducted using a true-triaxial-like SCCO_(2)shock fracturing system.Computed tomography(CT)scanning and three-dimensional fracture reconstruction were employed to elucidate the effects of shock pressure,pore pressure,and in-situ stress on fracture characteristics.In addition,nuclear magnetic resonance(NMR)transverse relaxation time spectra were used to assess the internal damage induced by SCCO_(2)shock fracturing.The results indicate that,compared with conventional hydraulic fracturing and SCCO_(2)quasi-static fracturing,SCCO_(2)shock fracturing facilitates multidirectional fracture initiation and the formation of complex fracture networks.Increasing shock pressure more readily activates bedding-plane weaknesses,with main and subsidiary fractures interweaving into a dense fracture network.Under the same impulse intensity,elevated pore pressure reduces the effective normal stress and alters stress-wave scattering paths,thereby inducing more branch fractures and enhancing fracture complexity.An increase in differential in-situ stress promotes fracture propagation along the direction of the maximum principal stress,reduces branching,and simplifies fracture morphology.With increasing SCCO_(2)shock pressure,pore volume and connectivity generally increase:small-to-medium pores primarily respond through increased number and enhanced connectivity;when the shock pressure rises to 40-45 MPa,crack coalescence generates larger pores and fissures,which play a dominant role in improving flow pathways and effective storage space,ultimately forming a multiscale pore-fracture network.
文摘Three zinc(Ⅱ),nickel(Ⅱ),and cadmium(Ⅱ)complexes,namely[Zn(μ-Htpta)(py)_(2)]n(1),[Ni(H_(2)biim)2(H_(2)O)2][Ni(tpta)(H_(2)biim)2(H_(2)O)]2·3H_(2)O(2),and[Cd_(3)(μ4-tpta)2(μ-dpe)_(3)]_(n)(3),have been constructed hydrothermally at 160℃ using H_(3)tpta([1,1':3',1″-terphenyl]-4,4',5'-tricarboxylic acid),py(pyridine),H_(2)biim(2,2'-biimidazole),dpe(1,2-di(4-pyridyl)ethylene),and zinc,nickel and cadmium chlorides,resulting in the formation of stable crystalline solids which were subsequently analyzed using infrared spectroscopy,element analysis,thermogravimetric analysis,as well as structural analyses conducted via single-crystal X-ray diffraction.The findings from these single-crystal Xray diffraction studies indicate that complexes 1-3 form crystals within the monoclinic system P2_(1)/c space group(1)or triclinic system P1 space group(2 and 3),and possess 1D,0D,and 3D structures,respectively.Complex 1 demonstrated substantial catalytic efficiency and excellent reusability as a heterogeneous catalyst in the reaction of Knoevenagel condensation under ambient temperature conditions.In addition,complex 1 also showcased notable anti-wear performance when used in polyalphaolefin synthetic lubricants.CCDC:2449810,1;2449811,2;2449812,3.
文摘This paper reports the preparation of three di‑iron complexes containing a thiazole moiety.Esterification of complex[Fe_(2)(CO)_(6)(μ‑SCH_(2)CH(CH_(2)OH)S)](1)with 4‑methylthiazole‑5‑carboxylic acid gave the corresponding ester[Fe_(2)(CO)_(6)(μ‑tedt)](2),where tedt=SCH_(2)CH(CH_(2)OOC(5‑C_(3)HNSCH_(3)))S.Further reactions of complex 2 with tri(ptolyl)phosphine(tp)or tris(4‑fluorophenyl)phosphine(fp)gave the phosphine‑substituted derivatives[Fe_(2)(CO)_(5)(tp)(μ‑tedt)](3)and[Fe_(2)(CO)_(5)(fp)(μ‑tedt)](4).The structures of the newly prepared complexes were elucidated by elemental analysis,NMR,IR,and X‑ray photoelectron spectroscopy.Moreover,single‑crystal X‑ray diffraction analysis confirmed their molecular structures,showing that they contain a di‑iron core ligated by a bridged dithiolate bearing a thiazole moiety and terminal carbonyls.The electrochemical and electrocatalytic proton reduction were probed by cyclic voltammetry,revealing that three complexes can catalyze the reduction of protons to H_(2) under the electrochemical conditions.For comparison,complex 4 possessed the best efficiency with a turnover frequency of 23.5 s^(-1)at 10 mmol·L^(-1)HOAc concentration.In addition,the fungicidal activity of these complexes was also investigated in this study.CCDC:2477511,2;2477512,3;2477513,4.
基金funding from the National Natural Science Foundation of China(No.U24B6001)the CNPC Innovation Fund(No.2021DQ02-0502).
文摘Re-fracturing horizontal wells is a critical strategy for enhancing recovery from tight oil reservoirs,but its success depends on the evaluation of candidate wells and locations.This process is complicated by production-induced alterations in reservoir pressure and geomechanical responses.This study introduces a workflow to evaluate re-fracturing potential by integrating coupled fluid flow and geomechanical modeling for the production of initial hydraulic fractures.We developed a numerical model that simulates the poroelastic response of a tight oil reservoir to depletion from an initial set of hydraulic fractures.To quantify the re-fracturing potential along the horizontal wellbore,a novel composite re-fracturing potential index is proposed where fracture shape,stress,and pressure are considered.This index considers four key physical factors:current reservoir pressure,fracture initiation ease,fracture geometry favorability,and fracture propagation efficiency considering tortuosity.Numerical simulations were conducted for scenarios with both uniform and non-uniform initial hydraulic fractures.The results consistently demonstrate that the optimal locations for re-fracturing are the midpoints between existing fractures,where a favorable balance of high reservoir pressure and altered stress conditions exists.The analysis reveals that the overall re-fracturing potential tends to increase with production time,suggesting that a period of depletion can enhance the geomechanical conditions for subsequent stimulation.Furthermore,a sensitivity analysis on the index weighting factors shows that the optimum re-fracturing strategy is highly dependent on the primary field objective,whether it is maximizing resource contact,ensuring geomechanical feasibility,or avoiding operational complexity.The study concludes that heterogeneity in the initial fracture network creates complex and asymmetric potential profiles,which implies the necessity of case-specific and integrated analysis over simplified assumptions.The proposed methodology provides a framework for optimizing re-fracturing designs in tight oil reservoirs.
文摘The hydrated tricyclohexyltin theophylline-7-acetic acid(tpH)complex[Sn(C_(6)H_(11))_(3)(tp)(H_(2)O)]was synthesized via an ethanol solvothermal method using tricyclohexyltin hydroxide and tpH in a 1∶1 molar ratio.The complex was characterized by IR,^(1)H(^(13)C)NMR,elemental analysis,and powder X-ray diffraction,and the crystal structure was determined by single-crystal X-ray diffraction.The crystal belongs to the orthorhombic system with space group Iba2,and the central tin atom is in a five-coordinated trigonal bipyramidal configuration.Quantum chemistry ab initio calculations were performed to investigate the stability,molecular orbital energy,and frontier molecular orbital characteristics of the complex.Additionally,its thermal stability,electrochemical properties,and in vitro anticancer activity were evaluated.CCDC:2380308.
基金supports from the National Natural Science Foundation of China(Grant Nos.52179095,52378323,and 42407216)are gratefully acknowledged.
文摘The increase in CO_(2)injectivity and shifting of CO_(2)-absorbing layers in multilayered geological CO_(2)sequestration(GCS)reservoirs in Ordos,China indicate significantpermeability variations in certain layers.To capture these system changes,a numerical model incorporating all 21 aquifers and internal aquitards was developed.The monitored pressure was well matched through multiphase and thermalhydraulic-mechanical(THM)coupling numerical simulations by introducing permeability variations.The results revealed that the permeability in the second layer increased on approximately day 13 due to the abrupt pressure buildup and temperature decrease.Even such a low rate of CO_(2)(2.8 kg/s)injected into the low permeability system initiated some fractures and the permeability in the second layer around the wellbore increased by 722 times.The second critical system change occurred on approximately day 386.As demonstrated in the numerical simulation,the substantial injection of cold CO_(2)induced strong thermal stress,leading to rock contraction and the initiation of several cracks.The permeability of the firstlayer around the wellbore unexpectedly increased by 4 orders of magnitude.Since no additional pressure could drive the CO_(2)into the remaining 17 layers,the total storage capability of the multilayered system was reduced.A whole picture of the system variation is fully presented and the underlying mechanisms are analyzed.It is believed that the phenomenon of thermal-hydraulic fracturing observed in this fieldand the simulation procedures will benefitother fluidinjection and production works in various geotechnical settings.
基金supported by the National Natural Science Foundation of China(Grant Nos.52574103 and 42277150).
文摘Fractures are typically characterized by roughness that significantlyaffects the mechanical and hydraulic characteristics of reservoirs.However,hydraulic fracturing mechanisms under the influenceof fracture morphology remain largely unexplored.Leveraging the advantages of the finite-discrete element method(FDEM)for explicitly simulating fracture propagation and the strengths of the unifiedpipe model(UPM)for efficientlymodeling dual-permeability seepage,we propose a new hydromechanical(HM)coupling approach for modeling hydraulic fracturing.Validated against benchmark examples,the proposed FDEM-UPM model is further augmented by incorporating a Fourier-based methodology for reconstructing non-planar fractures,enabling quantitative analysis of hydraulic fracturing behavior within rough discrete fracture networks(DFNs).The FDEM-UPM model demonstrates computational advantages in accurately capturing transient hydraulic seepage phenomena,while the asynchronous time-stepping schemes between hydraulic and mechanical analyses substantially enhanced computational efficiencywithout compromising computational accuracy.Our results show that fracture morphology can affect both macroscopic fracture networks and microscopic interaction types between hydraulic fractures(HFs)and natural fractures(NFs).In an isotropic stress field,the initiation azimuth,propagation direction and microcracking mechanism are significantly influencedby fracture roughness.In an anisotropic stress field,HFs invariably propagate parallel to the direction of the maximum principal stress,reducing the overall complexity of the stimulated fracture networks.Additionally,stress concentration and perturbation attributed to fracture morphology tend to be compromised as the leak-off increases,while the breakdown and propagation pressures remain insensitive to fracture morphology.These findingsprovide new insights into the hydraulic fracturing mechanisms of fractured reservoirs containing complex rough DFNs.
基金supported by the Research Fund of the National Natural Science Foundation of China(No.52374205)the Fundamental Research Project of the Educational Department of Liaoning Province(No.JYTMS20230793)the Research Fund of the State Key Laboratory of Coal Resources and Safe Mining,CUMT(No.YJY-XD-2024-A-016).
文摘To address the key scientific challenge of monitoring the dynamic fracturing of surrounding rock in deep roadways,this study systematically investigates the quantitative relationship between stress and charge signals during coal mass loading.By integrating innovative analytical approaches,introducing quantitative evaluation indices,and developing a charge–stress inversion model,and incorporating underground monitoring practices,significant progress has been achieved in elucidating the correlation between stress variations and charge signals throughout the entire coal mass fracturing process.First,in the field of stress–charge correlation analysis,empirical mode decomposition(EMD)was combined with wavelet coherence analysis for the first time,enabling the removal of slow-varying stress trends while retaining high-frequency fluctuations.This approach allowed for the quantitative characterization of the evolution of coherence between stress variations and charge fluctuations across multiple time scales.Second,coherence skewness and the proportion of high-coherence intervals were innovatively introduced to examine the influence of time scale selection on correlation results.On this basis,a criterion for determining the near-optimal observation scale of charge signals was proposed,providing a quantitative reference for time scale selection in similar signal analyses.Finally,by correlating charge signals with coal damage factors and stress states,a charge-based damage evolution equation was established to achieve effective stress inversion.Combined with in situ monitoring of stress and charge in roadway surrounding rock,this approach revealed the correlation characteristics of stress and charge intensity responses during the dynamic fracturing process.The results indicate,first,that charge signals are not significantly correlated with the absolute stress level of coal but are directly associated with stress variations following coal damage and failure,with the amplitude of charge fluctuations increasing alongside stress fluctuations.Second,coherence between stress and charge signals varies markedly across time scales,with excessively small or large scales leading to distortion,and the scale corresponding to the peak proportion of intervals with coherence>0.8 was identified as the near-optimal observation scale.Third,charge signals can effectively characterize coal damage factors,and the established damage evolution equation can effectively invert stress variation trends.Fourth,in underground roadways,zones of dynamic fracturing in surrounding rock are commonly located in areas where stress concentration overlaps with regions of high charge intensity,further confirming the strong consistency between charge and stress variations.These findings improve the theoretical framework of charge signal responses in loaded coal and provide a scientific basis for precise“stress-charge”monitoring of dynamic disasters,offering practical potential for engineering applications.
基金the financial support from National Natural Science Foundation of China(No.52474029)Strategic and Applied Scientific Research Project of PetroChina Company Limited(2023ZZ18,2023ZZ18YJ04).
文摘In the development of coalbed methane(CBM)reservoirs using multistage fractured horizontal wells,there often exist areas that are either repeatedly stimulated or completely unstimulated between fracturing stages,leading to suboptimal reservoir performance.Currently,there is no well-established method for accurately evaluating the effectiveness of such stimulation.This study introduces,for the first time,the concept of the Fracture Network Bridging Coefficient(FNBC)as a novel metric to assess stimulation performance.By quantitatively coupling the proportions of unstimulated and overstimulated volumes,the FNBC effectively characterizes the connectivity and efficiency of the fracture network.A background grid calibration method is developed to quantify the stage-controlled volume,effectively stimulated volume,unstimulated volume,and repeatedly stimulated volume among different stages of horizontal wells.Furthermore,an optimization model is constructed by taking the FNBC as the objective function and the fracturing injection rate and fluid volume as optimization variables.The Simultaneous Perturbation Stochastic Approximation(SPSA)algorithm is employed to iteratively perturb and optimize these variables,progressively improving the FNBC until the optimal displacement rate and fluid volume corresponding to the maximum FNBC are obtained.Field application in a typical CBM multistage fractured horizontal well in China demonstrates that the FNBC increased from 0.358 to 0.539(a 50.6% improvement),with the injection rate rising from 16 m^(3)/min to 24 m^(3)/min and the average fluid volume per stage increasing from 2490 m^(3) to 3192 m^(3),significantly enhancing the stimulation effectiveness.This research provides theoretical support for designing high-efficiency stimulation strategies in unconventional reservoirs under dynamic limits.
基金the financial support from the Na-tional Key Research and Development Program of China(Grant No.2023YFC2907202)the Postdoctoral Fellowship Program of CPSF(Grant No.GZB20240129).
文摘Abstract:Microwave-based destressing is regarded as a promising approach for proactively preventing and controlling rockbursts in deep hard rock.As the fracturing degree of microwave-induced boreholes is affected by borehole diameter,water content,mineral content,etc.,it is difficult to establish relationships between them.The research aims to unify various factors with heating rate and temperature,and establish a microwave parameter design method based thereon.Tests on microwave-induced borehole fracturing in hard rock with different or similar heating rates and temperatures under true triaxial stress were conducted.The test results show that both heating rate and temperature promote radial fracture of the rock,but have little effect on the development of axial fractures.Compared with heating rate,temperature is a more critical factor influencing microwave-induced fracturing.The effects of the heating rate on rock fracturing become noticeable only at higher temperatures.When the heating rate and temperature are similar but the diameter of the boreholes is different,the crack distribution,total length,wave velocity attenuation,and fracture process are similar.It is feasible to reverse-design microwave parameters under different borehole diameters based on the heating rate and temperature.Thermal fracturing of basalt shows a distinct threshold effect between 150℃ and 195℃(with an average of about 175℃),and the heating rate and borehole diameter exert minor influences thereon.The results provide guidance for the design of microwave parameters in practice.
基金Project supported by the Fundamental Research Funds for the Central Universities of China(Grant No.531118010757)。
文摘Single-pixel imaging(SPI)receives widespread attention due to its superior anti-interference capabilities,and image segmentation technology can effectively facilitate its recognition and information extraction.However,the complexity of the target scene and plenty of imaging time in SPI make it challenging to achieve high-quality and concise segmentation.In this paper,we investigate the image-free intricate scene semantic segmentation in SPI.Using“learned”illumination patterns allows for the full extraction of the object's spatial information,thereby enabling pixel-level segmentation results through the decoding of the received measurements.Simulation and experimentation show that,in the absence of image reconstruction,the mean intersection over union(MIoU)of segmented image can reach higher than 85%,and the Dice coefficient(DICE)close to 90%even at the sampling ratio of 5%.Our approach may be favorable to applications in medical image segmentation and autonomous driving field.
基金financial support from the National Natural Science Foundation of China(Nos.52209144 and 12472405).
文摘High-voltage electric pulse(HVEP)rock fragmentation has demonstrated substantial potential for sustainable fracturing of hard rocks owing to its energy efficiency.The transient nature and highly disruptive characteristics of its physical fracturing process render experimental investigation of the underlying rock-breaking mechanisms challenging.However,existing numerical studies lack comprehensive models that precisely link electrical breakdown phenomena with mechanical disintegration processes.This study combines COMSOL electrical breakdown simulations with four-dimension lattice spring model(4D-LSM)mechanical analysis to establish a coupled HVEP rock fragmentation model.The core concept of the model construction is to import the temperature field of the plasma channel obtained from the electrical breakdown into the mechanical solver to realize the precise connection between the two stages.The validated numerical model elucidates the full process of HVEP-induced fragmentation under varying electrical parameters.Furthermore,the effects of confining pressure and mineral grain size on fragmentation behavior have been investigated.Finally,parametric simulations across 25 electrical parameter combinations demonstrate the critical role of electrode spacing optimization in achieving energy-efficient rock fragmentation.These findings provide a predictive tool for designing efficient HVEP systems in deep resource extraction and mineral processing engineering.
基金Supported by the National Natural Science Foundation of China(No.82171073).
文摘Dear Editor,We present a case of acute zonal occult outer retinopathy(AZOOR)complex in a myopic patient with angioid streaks(ASs).A 19-year-old female has been experiencing visual field defects in her left eye for more than 3y.She was diagnosed with ASs and choroiditis at a local hospital.She has a seven-year history of bilateral high myopia.A fundus examination confirmed the presence of ASs and myopic fundus changes in both eyes.Multimodal imaging revealed an AZOOR complex in the left eye.
文摘The complexes 1-4 of cyclobutanocucurbit[5]uril(CyB5Q[5])with Na^(+)/K^(+)have been synthesized and characterized by single-crystal X-ray diffraction.The results show that although the inorganic salts are used when the cations are the same and the anions are different,in complex 1,Na^(+)closes one port of CyB5Q[5]through Na—O seven coordination bonds to form a molecular bowl;in complex 3,Na^(+)completely closes the two ports of CyB5Q[5]to form a molecular capsule with six Na—O coordination bonds;in complexes 2 and 4,the two ports of CyB5Q[5]are completely closed to form K—O coordinated molecular capsules,but the K^(+)of complex 2 is six-coordinated and that of complex 4 is eight-/nine-coordinated.and complex 4 are connected by three oxygen bridges to form a 1D molecular chain.CCDC:2457122,1;2457121,2;2457400,3;2457120,4.
