Previous studies on post-fracturing flowback fluids focus primarily on their cleaning and discharge,high salinity sources,and damage to gas reservoirs.An analysis of the geochemical characteristics of these fluids hel...Previous studies on post-fracturing flowback fluids focus primarily on their cleaning and discharge,high salinity sources,and damage to gas reservoirs.An analysis of the geochemical characteristics of these fluids helps develop an improved understanding of the preservation condition and fracturing performance of shale gas reservoirs.This study analyzed the ion,total dissolved solids(TDS)concentration,and stable isotope characteristics of post-fracturing flowback fluids from five horizontal shale gas wells in the Luzhou area.Among these wells,two were subjected to hydraulic fracturing using fresh water,and three using reused flowback fluids.The results indicate that with increasing flowback time,the post-fracturing flowback fluids from wells subjected to hydraulic fracturing using fresh water showed increased TDS concentration,heavier stable isotopes,and the presence of new ion components.These results indicate the mixing of a large volume of formation water into the fluids.In contrast,postfracturing flowback fluids from wells subjected to hydraulic fracturing using reused flowback fluids exhibited a slow increase in the TDS concentration and stable isotopes.As the flowback time increased,the trends in TDS concentration and stable isotope ratios of post-fracturing flowback fluids from shale gas wells subjected to fracturing using fresh water evolved toward those of post-fracturing flowback fluids from shale gas wells undergoing fracturing using reused flowback fluids.Measurements show that post-fracturing flowback fluids from both well types exhibited roughly the same properties after one year of shale gas production.This result suggests that post-fracturing flowback fluids from wells using reused flowback fluids progressively took on the formation water properties.In particular,postfracturing flowback fluids from well Lu 211—a well subjected to hydraulic fracturing using fresh water—showed a low sodium-chloride coefficient,a low coefficient of variation,high TDS concentration,heavy stable isotopes,and a high nitrate ion concentration.This indicates a formation water source of the fluids and the poor sealing of the formation water,which hinders shale gas enrichment.The quantification of the fracturing fluid and formation water contents in the post-fracturing flowback fluids reveals that higher TDS concentration and heavier stable isotopes in the fluids appear to correspond to higher formation water content and lower fracturing fluid content,as well as higher fracturing performance.A systematic analysis of the geochemical characteristics and flowback pattern of fracturing fluids indirectly provides insights into the flow path of formation water,water body mixing,rock-water interactions,and fluid sources.Besides,the analysis offers a new perspective for understanding the preservation conditions and fracturing performance of shale gas reservoirs.展开更多
Microbial polysaccharides,due to their unique physicochemical properties,have been shown to effec-tively enhance the stability of foam fracturing fluids.However,the combined application of microbial polysaccharides an...Microbial polysaccharides,due to their unique physicochemical properties,have been shown to effec-tively enhance the stability of foam fracturing fluids.However,the combined application of microbial polysaccharides and surfactants under high-temperature and high-salinity conditions remain poorly understood.In this study,we innovatively investigate this problem with a particular focus on foam stabilization mechanisms.By employing the Waring blender method,the optimal surfactant-microbial polysaccharide blends are identified,and the foam stability,rheological properties,and decay behavior in different systems under varying conditions are systematically analyzed for the first time.The results reveal that microbial polysaccharides significantly enhance foam stability by improving the viscoelasticity of the liquid films,particularly under high-salinity and high-temperature conditions,leading to notable improvements in both foam stability and sand-carrying capacity.Additionally,scanning electron microscopy(SEM)is used to observe the microstructure of the foam liquid films,demonstrating that the network structure formed by the foam stabilizer within the liquid film effectively inhibits foam coarsening.The Lauryl betaine and Diutan gum blend exhibits outstanding foam stability,superior sand-carrying capacity,and minimal core damage,making(LAB+MPS04)it ideal for applications in enhanced production and reservoir stimulation of unconventional reservoirs.展开更多
Spontaneous imbibition of water-based frac- turing fluids into the shale matrix is considered to be the main mechanism responsible for the high volume of water loss during the flowback period. Understanding the matrix...Spontaneous imbibition of water-based frac- turing fluids into the shale matrix is considered to be the main mechanism responsible for the high volume of water loss during the flowback period. Understanding the matrix imbibition capacity and rate helps to determine the frac- turing fluid volume, optimize the flowback design, and to analyze the influences on the production of shale gas. Imbibition experiments were conducted on shale samples from the Sichuan Basin, and some tight sandstone samples from the Ordos Basin. Tight volcanic samples from the Songliao Basin were also investigated for comparison. The effects of porosity, clay minerals, surfactants, and KC1 solutions on the matrix imbibition capacity and rate were systematically investigated. The results show that the imbibition characteristic of tight rocks can be characterized by the imbibition curve shape, the imbibition capacity, the imbibition rate, and the diffusion rate. The driving forces of water imbibition are the capillary pressure and the clay absorption force. For the tight rocks with low clay contents, the imbibition capacity and rate are positively correlated with the porosity. For tight rocks with high clay content, the type and content of clay minerals are the most impor- tant factors affecting the imbibition capacity. The imbibed water volume normalized by the porosity increases with an increasing total clay content. Smectite and illite/smectite tend to greatly enhance the water imbibition capacity. Furthermore, clay-rich tight rocks can imbibe a volume of water greater than their measured pore volume. The aver- age ratio of the imbibed water volume to the pore volume is approximately 1.1 in the Niutitang shale, 1.9 in the Lujiaping shale, 2.8 in the Longmaxi shale, and 4.0 in the Yingcheng volcanic rock, and this ratio can be regarded as a parameter that indicates the influence of clay. In addition, surfactants can change the imbibition capacity due to alteration of the capillary pressure and wettability. A 10 wt% KC1 solution can inhibit clay absorption to reduce the imbibition capacity.展开更多
Chinaʼs continental shale exhibits favorable geological characteristics and substantial resource potential,yet oil recovery for natural energy extraction remains critically low.Investigating the mechanisms of hydrauli...Chinaʼs continental shale exhibits favorable geological characteristics and substantial resource potential,yet oil recovery for natural energy extraction remains critically low.Investigating the mechanisms of hydraulically induced bedding fracture to generate complex fracture networks in continental shale,and establishing effective flow systems,is of utmost importance.This study employs laboratory experiments and numerical simulations to investigate the flow capacity and percolation behavior of hydraulically induced bedding fractures by different fluids in full-diameter shale cores.Hydraulic stimulation using different fluids generates bedding plane fracture networks,establishing effective flow systems.Eroded and detached shale fragments support localized fractures,thereby increasing their opening and enhancing flow capacity.Cetyltrimethylammonium bromide(CTAB)solution and SiO2 solution reduce the hydration of the shale surface,preventing shale fragments from swelling and disintegrating,leading to more stable percolation behavior.Eroded and spalled shale fragments near the injection point are transported to farther locations,where they help support localized fractures.This process differs from conventional hydraulic fracturing.Under a constant injection rate,the velocity in the smaller flow paths near the closure is significantly higher than that in the main flow paths,leading to pronounced bypass flow behavior.This restricts the percolation of fluid during imbibition in shale cores.The results provide valuable insights into the mechanism of hydraulically induced bedding fracture in continental shale,offering guidance for the effective development of shale reservoirs.展开更多
This study investigated the micro-sliding frictional behavior of shale in fracturing fluids under varying operational conditions using Chang 7 shale oil reservoir core samples.Through systematic micro-sliding friction...This study investigated the micro-sliding frictional behavior of shale in fracturing fluids under varying operational conditions using Chang 7 shale oil reservoir core samples.Through systematic micro-sliding friction experiments,the characteristics and governing mechanisms of shale friction were elucidated.Complementary analyses were conducted to characterize the mineral composition,petrophysical properties,and micromorphology of the shale samples,providing insights into the relationship between microscopic structure and frictional response.In this paper,the characteristics and variation law of shale micro-sliding friction under different types of graphite materials as additives in LGF-80(Low-damage Guar Fluid)oil flooding recoverable fracturing fluid system were mainly studied.In addition,the finite element numerical simulation experiment of hydraulic fracturing was adopted to study the influence of the friction coefficient of natural fracture surfaces on fracture propagation and formation of the fracture network.The geometric complexity of fracture networks was systematically quantified under varying frictional coefficients of natural fracture surfaces through multi-parametric characterization and morphometric analysis.The research results show that graphite micro-particles reduce friction and drag.Based on this,this paper proposes a new idea of graphite micro-particles as an additive in the LGF-80 oil flooding recoverable fracturing fluid system to reduce friction on the fracture surface.展开更多
The combination of ultrasonic and acid fracturing fluid can strengthen the modification effect on the micropore structure of the coal matrix,thereby enhancing the efficiency of the acid fracturing process.In this rese...The combination of ultrasonic and acid fracturing fluid can strengthen the modification effect on the micropore structure of the coal matrix,thereby enhancing the efficiency of the acid fracturing process.In this research,acetic acid was utilized to formulate acid fracturing fluids with varying concentrations,and the evolutionary traits of both the acid fracturing fluids and ultrasonic waves in relation to coal samples were investigated.The functional group structure,mineral composition,micropore structure and surface morphology of coal samples were characterized by FTIR,XRD,N_(2)adsorption at low temperature and SEM-EDS.The results showed that aromatics(I)and branching parameters(CH_(2)/CH_(3))were reduced by 81.58%and 88.67%,respectively,after 9%acetic acid treatment.Acetic acid can dissolve carbonates and clay minerals in coal,create new pores,and increase porosity,pore volume and pore fractal dimension.After modification by 7%acetic acid,the pore volume increased by 5.7 times.SEM observation shows that the diameter of coal surface holes increases,EDS scanning shows that the content of mineral elements in coal decreases,the connectivity of coal holes increases,and the holes expand.The findings of this research offer theoretical direction for optimizing ultrasonic-enhanced acid fracturing fluid modification.展开更多
Injection rate is crucial for determining the hydraulic fracturing effectiveness;however,the effects of the injection rate on the pore and fracture structure(PFS)and fluid infiltration during injection pressurization ...Injection rate is crucial for determining the hydraulic fracturing effectiveness;however,the effects of the injection rate on the pore and fracture structure(PFS)and fluid infiltration during injection pressurization have rarely been explored.In this study,the cylindrical sandstone samples were hydraulically fractured at various injection rates on a self-developed integrated nuclear magnetic resonance(NMR)and hydraulic fracturing experimental system.The results show that low injection rates predominantly resulted in macropore-scale damage by creating intergranular cracks,whereas high injection rates facilitated micropore-scale damage,probably owing to the adsorption swelling effect of clay minerals within pores.Additionally,the water contents of the samples with low injection rates exhibited a continuous increase,whereas those of the samples with high injection rates initially increased and subsequently stabilized.Magnetic resonance imaging(MRI)indicated that fluid infiltration during the fracturing process exhibited high anisotropy owing to the inherent heterogeneous PFS distributions around the wellbore.Moreover,a primary fluid infiltration path exists that aligns with the initiation direction of the hydraulic fractures.However,the fluid infiltration damage distance along the hydraulic fracture direction decreased with increasing injection rate,whereas the fluid infiltration damage distance perpendicular to the hydraulic fracture direction was approximately equal to the characteristic length,regardless of the injection rate.Finally,we recommend using the pore damage during fluid pressurization as the basis for selecting the proppant size and employing a primary fluid infiltration path to predict hydraulic fracture initiation.These findings provide valuable insights into the design of hydraulic fracturing in tight gas reservoirs.展开更多
As oil and gas development increasingly targets unconventional reservoirs,the limitations of conventional hydraulic fracturing,namely high water consumption and significant reservoir damage,have become more pronounced...As oil and gas development increasingly targets unconventional reservoirs,the limitations of conventional hydraulic fracturing,namely high water consumption and significant reservoir damage,have become more pronounced.This has driven growing interest in the development of clean fracturing fluids that minimize both water usage and formation impairment.In this study,a low-liquid-content viscoelastic surfactant(VES)foam fracturing fluid system was formulated and evaluated through laboratory experiments.The optimized formulation comprises 0.2%foaming agent CTAB(cetyltrimethylammonium bromide)and 2%foam stabilizer EAPB(erucamidopropyl betaine).Laboratory tests demonstrated that the VES foam system achieved a composite foam value of 56,700 mL・s,reflecting excellent foaming performance.Proppant transport experiments revealed minimal variation in suspended sand volume over 120 min across different sand ratios,indicating robust sand-carrying capacity even at high proppant concentrations.Rheological measurements showed that the fluid maintained a viscosity above 120 mPa・s after 120 min of shearing at 70℃ and a shear rate of 170 s−1,with the elastic modulus exceeding the viscous modulus,confirming the system’s exceptional stability and resilience.Furthermore,core damage tests indicated that the VES foam caused only 4.42%formation damage,highlighting its potential for efficient and low-damage stimulation of tight reservoirs.Overall,the findings demonstrate that this low-liquid-content VES foam provides a highly effective,environmentally considerate alternative for hydraulic fracturing in unconventional formations,combining superior proppant transport,rheological stability,and minimal reservoir impairment.展开更多
To elucidate the adsorption characteristics and retention mechanisms of fracturing fluids in diverse clay minerals,we conducted on-line nuclear magnetic resonance(NMR)and atomic force microscopy(AFM)experiments.The de...To elucidate the adsorption characteristics and retention mechanisms of fracturing fluids in diverse clay minerals,we conducted on-line nuclear magnetic resonance(NMR)and atomic force microscopy(AFM)experiments.The depth and extent of solid phase damage are determined by the ratio between the size of fine fractions in fracturing fluid residue and the pore-throat size in experiments.Poor physical properties(K<0.5 mD)result in a more preferential flow pathway effect during flowback,and the stepwise incremental pressure differential proves to be more effective for the discharge of fracturing fluid in submicron pore throats.The permeability is significantly influenced by the differential distri-bution of retained fracturing fluid,as supported by direct experimental evidence.The presence of good physical properties(K>0.5 mD)combined with a scattered distribution of retained fracturing fluid is associated with high gas phase recovery permeability,whereas a continuous sheet-like distribution results in low recovery permeability.The expansive surface area and presence of filamentous illite minerals facilitate the multiple winding and adsorption of fracturing fluids,demonstrating strong hydrogen-bonding,multi-layering and multiple adsorption properties.The geological characteristics of the main gas formations exhibit significant variation,and the severity of damage caused by fracturing fluids occurs in diverse sequences.To address this issue,a differentiated strategy for optimizing frac-turing fluids has been proposed.展开更多
With the widespread adoption of hydraulic fracturing technology in oil and gas resource development,improving the accuracy and efficiency of fracturing simulations has become a critical research focus.This paper propo...With the widespread adoption of hydraulic fracturing technology in oil and gas resource development,improving the accuracy and efficiency of fracturing simulations has become a critical research focus.This paper proposes an improved fluid flow algorithm,aiming to enhance the computational efficiency of hydraulic fracturing simulations while ensuring computational accuracy.The algorithm optimizes the aperture law and iteration criteria,focusing on improving the domain volume and crack pressure update strategy,thereby enabling precise capture of dynamic borehole pressure variations during injection tests.The effectiveness of the algorithm is verified through three flow-solid coupling cases.The study also analyzes the effects of borehole size,domain volume,and crack pressure update strategy on fracturing behavior.Furthermore,the performance of the improved algorithm in terms of crack propagation rate,micro-crack formation,and fluid pressure distribution was further evaluated.The results indicate that while large-size boreholes delay crack initiation,the cracks propagate more rapidly once formed.Additionally,the optimized domain volume calculation and crack pressure update strategy significantly shorten the pressure propagation stage,promote crack propagation,and improve computational efficiency.展开更多
Static adsorption and dynamic damage experiments were carried out on typical 8#deep coal rock of the Carboniferous Benxi Formation in the Ordos Basin,NW China,to evaluate the adsorption capacity of hydroxypropyl guar ...Static adsorption and dynamic damage experiments were carried out on typical 8#deep coal rock of the Carboniferous Benxi Formation in the Ordos Basin,NW China,to evaluate the adsorption capacity of hydroxypropyl guar gum and polyacrylamide as fracturing fluid thickeners on deep coal rock surface and the permeability damage caused by adsorption.The adsorption morphology of the thickener was quantitatively characterized by atomic force microscopy,and the main controlling factors of the thickener adsorption were analyzed.Meanwhile,the adsorption mechanism of the thickener was revealed by Zeta potential,Fourier infrared spectroscopy and X-ray photoelectron spectroscopy.The results show that the adsorption capacity of hydroxypropyl guar gum on deep coal surface is 3.86 mg/g,and the permeability of coal rock after adsorption decreases by 35.24%–37.01%.The adsorption capacity of polyacrylamide is 3.29 mg/g,and the permeability of coal rock after adsorption decreases by 14.31%–21.93%.The thickness of the thickener adsorption layer is positively correlated with the mass fraction of thickener and negatively correlated with temperature,and a decrease in pH will reduce the thickness of the hydroxypropyl guar gum adsorption layer and make the distribution frequency of the thickness of polyacrylamide adsorption layer more concentrated.Functional group condensation and intermolecular force are chemical and physical forces for adsorbing fracturing fluid thickener in deep coal rock.Optimization of thickener mass fraction,chemical modification of thickener molecular,oxidative thermal degradation of polymer and addition of desorption agent can reduce the potential damages on micro-nano pores and cracks in coal rock.展开更多
CO_(2) foam fracturing fluid can effectively integrate CCUS technology into oil and gas field development,and its core advantages include low water consumption,excellent flowback performance,and strong sand-carrying c...CO_(2) foam fracturing fluid can effectively integrate CCUS technology into oil and gas field development,and its core advantages include low water consumption,excellent flowback performance,and strong sand-carrying capacity.For these reasons,it has received increasing attention in the oil and gas field development field.However,this type of fracturing fluid still has some prominent problems:The residue from gel breaking can easily cause formation pollution,the system cost is relatively high,and the utilization rate is low,which forms a significant technical bottleneck.In response to these issues,this study,based on the theory of clean fracturing fluid gel breaking without residue and the reusability of CO_(2)-responsive wormlike micelles,innovatively combines CO_(2)-responsive wormlike micelles with different types of surfactant-based foaming agents to construct a new CO_(2)-responsive foam fracturing fluid system.A systematic performance evaluation of the system was conducted to clarify its defoaming rules under different temperature conditions.Compared with the traditional guar gum CO_(2) foam fracturing fluid,the new system has significant performance advantages.At 90℃,its foam comprehensive value reached 19720 mL·min,6150 mL·min higher than the guar gum fluid.After a 5400 s high-temperature and high-shear test at the same temperature,the residual viscosity of the new system was 67 mPa·s,which is higher than the guar gum fluid.This CO_(2)-responsive foam fracturing fluid simultaneously possesses the application potential of both clean fracturing fluid and foam fracturing fluid.It can effectively solve key problems such as formation pollution and low system utilization rates,and laboratory evaluation experiments confirmed its excellent foaming and rheological properties.These results are of great significance for promoting CO_(2) foam fracturing technology to reach an advanced international level and supporting the low-carbon and highefficiency development of unconventional oil and gas resources in China.展开更多
The Linxing area within the Ordos Basin exhibits pronounced reservoir heterogeneity and intricate micro-pore structures,rendering it susceptible to water-blocking damage during imbibition extraction.This study delved ...The Linxing area within the Ordos Basin exhibits pronounced reservoir heterogeneity and intricate micro-pore structures,rendering it susceptible to water-blocking damage during imbibition extraction.This study delved into the traits of tight sandstone reservoirs in the 8th member of the Shihezi Formation(also referred to as the He 8 Member)in the study area,as well as their effects on fracturing fluid imbibition.Utilizing experimental techniques such as nuclear magnetic resonance(NMR),high-pressure mercury intrusion(HPMI),and gas adsorption,this study elucidated the reservoir characteristics and examined the factors affecting the imbibition through imbibition experiments.The findings reveal that:①The reservoir,with average porosity of 8.40%and average permeability of 0.642×10^(-3)μm^(2),consists principally of quartz,feldspar,and lithic fragments,with feldspathic litharenite serving as the primary rock type and illite as the chief clay mineral;②Nano-scale micro-pores and throats dominate the reservoir,with dissolution pores and intercrystalline pores serving as predominant pore types,exhibiting relatively high pore connectivity;③Imbibition efficiency is influenced by petrophysical properties,clay mineral content,and microscopic pore structure.Due to the heterogeneity of the tight sandstone reservoir,microscopic factors have a more significant impact on the imbibition efficiency of fracturing fluids;④A comparative analysis shows that average pore size correlates most strongly with imbibition efficiency,followed by petrophysical properties and clay mineral content.In contrast,the pore type has minimal impact.Micropores are vital in the imbibition process,while meso-pores and macro-pores offer primary spaces for imbibition.This study offers theoretical insights and guidance for enhancing the post-fracturing production of tight sandstone reservoirs by examining the effects of these factors on the imbibition efficiency of fracturing fluids in tight sandstones.展开更多
Fracturing operations can effectively improve the production of low-permeable reservoirs. The performance of fracturing fluids directly affects the fracturing efficiency and back flow capacity. As polymerbased fractur...Fracturing operations can effectively improve the production of low-permeable reservoirs. The performance of fracturing fluids directly affects the fracturing efficiency and back flow capacity. As polymerbased fracturing fluids(such as guar gum(GG), polyacrylamide(HPAM), etc.) are high-viscosity fluids formed by viscosifiers and crosslinking agents, the degree of gel breakage after the fracturing operation directly influences the damage degree to the reservoir matrix and the mobility of oil angd gas produced from the reservoir into the wellbore. This study compared the viscosity, molecular weight, and particle size of the fracturing fluid after gel breakage prepared by GG and HPAM as viscosifiers, as well as evaluate their damage to the core. Results show that the viscosities of the gel-breaking fluid increased with the concentration of the viscosifier for both the HPAM-based and GG-based fracturing fluids. For the breaking fluid with the same viscosity, the molecular weight in the HPAM-based gel-breaking fluid was much larger than that in the GG-based system. Moreover, for the gel-breaking fluid with the same viscosity, the molecular particle size of the residual polymers in the HPAM-based system was smaller than that in the GG-based system. The damage to the core with the permeability of 1 × 10^(-3)μm^(2) caused by both the HPAM-based and GG-based gel-breaking fluids decreased with the increase in the solution viscosity. For the gel-breaking fluid systems with the same viscosity(i.e., 2-4 mPa s), the damage of HPAM-based fracturing fluid to low-permeability cores was greater than the GG-based fracturing fluid(45.6%-80.2%) since it had a smaller molecular particle size, ranging from 66.2% to 77.0%. This paper proposed that the damage caused by hydraulic fracturing in rock cores was related to the partilce size of residual polymers in gel-breaking solution, rather than its molecular weight. It was helpful for screening and optimizing viscosifiers used in hydraulic fracturing process.展开更多
The variable-density flow model-SEAWAT Version 4, was used to evaluate the hydrogeological conditions associatedwith hydraulic fracturing （fracking） the limestone oil reservoir in the Lower Cretaceous Sunniland Form...The variable-density flow model-SEAWAT Version 4, was used to evaluate the hydrogeological conditions associatedwith hydraulic fracturing （fracking） the limestone oil reservoir in the Lower Cretaceous Sunniland Formation of Southwest Florida.This research contributes to the understanding of the controls on fluid and potential contaminant migration, following high pressurehydraulic fracturing. A hydraulic fracturing treatment used recently in this formation at the Collier-Hogan 20-3H well represents thebase case simulation. Multiple stage fracturing using typical stress periods, a modelled fracture zone radius, and various injectionrates were tested to evaluate the potential for horizontal and vertical fluid migration in and from the reservoir under dynamicconditions, with TDS used as a tracer. Hypothetical scenarios including preferential vertical pathways between the SunnilandFormation and the Lower Floridan aquifer Boulder Zone were also simulated. Results indicate that injected fluids do not migratesignificantly in the lateral and vertical directions beyond the design fractured zone, unless a preferential pathway exists within closeproximity to the fractured zone. In a worst-case scenario under the simulated conditions, vertical heads are approximately 580 metersgreater than static conditions and fluids associated with hydraulic fracturing vertically migrate approximately 500 meters; therefore,the quality of the deepest sources of drinking water is not compromised. Analytical results from a monitoring well installed in theimmediate vicinity of the Collier-Hogan 20-3H well and at the base of the deepest source of drinking water support the conclusionthat impacts from hydraulic fracturing fluids have not migrated into the deepest sources of drinking water.展开更多
Hydrogeochemical processes that would occur in polluted groundwater and aquifer system,may reduce the sensitivity of Sr isotope being the indicator of hydraulic fracturing flowback fluids(HFFF)in groundwater.In this p...Hydrogeochemical processes that would occur in polluted groundwater and aquifer system,may reduce the sensitivity of Sr isotope being the indicator of hydraulic fracturing flowback fluids(HFFF)in groundwater.In this paper,the Dameigou shale gas field in the northern Qaidam Basin was taken as the study area,where the hydrogeochemical processes affecting Sr isotope was analysed.Then,the model for Sr isotope in HFFF-polluted groundwater was constructed to assess the sensitivity of Sr isotope as HFFF indicator.The results show that the dissolution can release little Sr to polluted groundwater and cannot affect the εSr(the deviation of the 87Sr/86Sr ratio)of polluted groundwater.In the meantime,cation exchange can considerably affect Sr composition in the polluted groundwater.The Sr with low εSr is constantly released to groundwater from the solid phase of aquifer media by cation exchange with pollution of Quaternary groundwater by the HFFF and it accounts for 4.6% and 11.0% of Sr in polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater,respectively.However,the Sr from cation exchange has limited impact on Sr isotope in polluted groundwater.Addition of Sr from cation exchange would only cause a 0.2%and 1.2% decrease in εSr of the polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater,respectively.These results demonstrate that hydrogeochemical processes have little effect on the sensitivity of Sr isotope being the HFFF indicator in groundwater of the study area.For the scenario of groundwater pollution by HFFF,when the HFFF accounts for 5%(in volume percentage)of the polluted groundwater,the HFFF can result in detectable shifts of εSr(Δ_(εSr)=0.86)in natural groundwater.Therefore,after consideration of hydrogeochemical processes occurred in aquifer with input of the HFFF,Sr isotope is still a sensitive indicator of the Quaternary groundwater pollution by the HFFF produced in the Dameigou shale of Qaidam Basin.展开更多
Centralized and group well deployment and factory-like fracturing techniques are adopted for low-permeability tight sandstone reservoirs in the Sulige Gasfield,Ordos Basin,so as to realize its efficient and economic d...Centralized and group well deployment and factory-like fracturing techniques are adopted for low-permeability tight sandstone reservoirs in the Sulige Gasfield,Ordos Basin,so as to realize its efficient and economic development.However,environmental protection is faced with grim situations because fluid delivery rises abruptly on site in a short time due to centralized fracturing of the well group.Based on the characteristics of gas testing after fracturing in this gas field,a fracturing flowback fluid recovery and treatment method suitable for the Sulige Gasfield has been developed with the landform features of this area taken into account.Firstly,a high-efficiency well-to-well fracturing flowback fluid recovery and reutilization technique was developed with multi-effect surfactant polymer recoverable fracturing fluid system as the core,and in virtue of this technique,the treatment efficiency of conventional guar gum fracturing fluid system is increased.Secondly,for recovering and treating the end fluids on the well sites,a fine fracturing flowback fluid recovery and treatment technique has been worked out with“coagulation and precipitation,filtration and disinfection,and sludge dewatering”as the main part.Owing to the application of this method,the on-site water resource utilization ratio has been increased and environmental protection pressure concerned with fracturing operation has been relieved.In 2014,field tests were performed in 62 wells of 10 well groups,with 32980 m3 cumulative treated flowback fluid,17160 m3 reutilization volume and reutilization ratio over 70%.Obviously,remarkable social and economical benefits are thus realized.展开更多
In this paper,marine shale cores taken from Zhaotong,Changning and Weiyuan Blocks in South China were used as samples to investigate the interaction between fracturing fluids and shale and the retention mechanisms.Fir...In this paper,marine shale cores taken from Zhaotong,Changning and Weiyuan Blocks in South China were used as samples to investigate the interaction between fracturing fluids and shale and the retention mechanisms.Firstly,adsorption,swelling,dissolution pore,dissolution fluid mineralization degree and ionic composition were experimentally studied to reveal the occurrence of water in shale and the reason for a high mineralization degree.Then,the mechanisms of water retention and mineralization degree increase were simulated and calculated.The scanning electron microscopy(SEM)analysis shows that there are a large number of micro fractures originated from clay minerals in the shale.Mineral dissolution rates of shale immersed in ultrasonic is around 0.5-0.7%.The ionic composition is in accordance with that of formation water.The clay minerals in core samples are mainly composed of chlorites and illites with a small amount of illites/smectites,but no montmorillonites(SS),and its content is between 18%and 20%.It is verified by XRD and infrared spectroscopy that the fracturing fluid doesn't flow into the space between clay mineral layers,so it can't lead to shale swelling.Thus,the retention of fracturing fluids is mainly caused by the adsorption at the surface of the newly fractured micro fractures in shale in a mode of successive permeation,and its adsorptive saturation rates is proportional to the pore diameters.It is concluded that the step-by-step extraction of fracturing fluids to shale and the repulsion of nano-cracks to ion are the main reasons for the abrupt increase of mineralization degree in the late stage of flowing back.In addition,the liquid carrying effect of methane during the formation of a gas reservoir is also a possible reason.Based on the experimental and field data,fracturing fluid flowback rates and gas production rates of 9 wells were analyzed.It is indicated that the same block follows an overall trend,namely,the lower the flowback rates,the more developed the micro fractures,the better the volume simulation effect and the higher the gas production rates.展开更多
Particle-fluid two-phase flows in rock fractures and fracture networks play a pivotal role in determining the efficiency and effectiveness of hydraulic fracturing operations,a vital component in unconventional oil and...Particle-fluid two-phase flows in rock fractures and fracture networks play a pivotal role in determining the efficiency and effectiveness of hydraulic fracturing operations,a vital component in unconventional oil and gas extraction.Central to this phenomenon is the transport of proppants,tiny solid particles injected into the fractures to prevent them from closing once the injection is stopped.However,effective transport and deposition of proppant is critical in keeping fracture pathways open,especially in lowpermeability reservoirs.This review explores,then quantifies,the important role of fluid inertia and turbulent flows in governing proppant transport.While traditional models predominantly assume and then characterise flow as laminar,this may not accurately capture the complexities inherent in realworld hydraulic fracturing and proppant emplacement.Recent investigations highlight the paramount importance of fluid inertia,especially at the high Reynolds numbers typically associated with fracturing operations.Fluid inertia,often overlooked,introduces crucial forces that influence particle settling velocities,particle-particle interactions,and the eventual deposition of proppants within fractures.With their inherent eddies and transient and chaotic nature,turbulent flows introduce additional complexities to proppant transport,crucially altering proppant settling velocities and dispersion patterns.The following comprehensive survey of experimental,numerical,and analytical studies elucidates controls on the intricate dynamics of proppant transport under fluid inertia and turbulence-towards providing a holistic understanding of the current state-of-the-art,guiding future research directions,and optimising hydraulic fracturing practices.展开更多
A deep understanding of the geometric impacts of fracture on fracturing fluid flowback efficiency is essential for unconventional oil development. Using nuclear magnetic resonance and 2.5-dimensional matrix-fracture v...A deep understanding of the geometric impacts of fracture on fracturing fluid flowback efficiency is essential for unconventional oil development. Using nuclear magnetic resonance and 2.5-dimensional matrix-fracture visualization microfluidic models, qualitative and quantitative descriptions of the influences of connectivity between primary fracture and secondary fracture on flowback were given from core scale to pore network scale. The flow patterns of oil-gel breaking fluid two-phase flow during flowback under different fracture connectivity were analyzed. We found some counterintuitive results that non-connected secondary fracture (NCSF, not connect with artificial primary fracture and embedded in the matrix) is detrimental to flowbackefficiency. The NCSF accelerates the formation of oil channeling during flowback, resulting in a large amount of fracturing fluid trapped in the matrix, which is not beneficial for flowback. Whereas the connected secondary fracture (CSF, connected with the artificial primary fracture) is conducive to flowback. The walls of CSF become part of primary fracture, which expands the drainage area with low resistance, and delays the formation of the oil flow channel. Thus, CSF increases the high-speed flowback stage duration, thereby enhancing the flowback efficiency. The fracturing fluid flowback efficiency investigated here follows the sequence of the connected secondary fracture model (72%) > the matrix model (66%) > the non-connected secondary fracture model (38%). Our results contribute to hydraulic fracturing design and the prediction of flowback efficiency.展开更多
基金supported by China National Petroleum Corporation(NO:2023ZZ21)。
文摘Previous studies on post-fracturing flowback fluids focus primarily on their cleaning and discharge,high salinity sources,and damage to gas reservoirs.An analysis of the geochemical characteristics of these fluids helps develop an improved understanding of the preservation condition and fracturing performance of shale gas reservoirs.This study analyzed the ion,total dissolved solids(TDS)concentration,and stable isotope characteristics of post-fracturing flowback fluids from five horizontal shale gas wells in the Luzhou area.Among these wells,two were subjected to hydraulic fracturing using fresh water,and three using reused flowback fluids.The results indicate that with increasing flowback time,the post-fracturing flowback fluids from wells subjected to hydraulic fracturing using fresh water showed increased TDS concentration,heavier stable isotopes,and the presence of new ion components.These results indicate the mixing of a large volume of formation water into the fluids.In contrast,postfracturing flowback fluids from wells subjected to hydraulic fracturing using reused flowback fluids exhibited a slow increase in the TDS concentration and stable isotopes.As the flowback time increased,the trends in TDS concentration and stable isotope ratios of post-fracturing flowback fluids from shale gas wells subjected to fracturing using fresh water evolved toward those of post-fracturing flowback fluids from shale gas wells undergoing fracturing using reused flowback fluids.Measurements show that post-fracturing flowback fluids from both well types exhibited roughly the same properties after one year of shale gas production.This result suggests that post-fracturing flowback fluids from wells using reused flowback fluids progressively took on the formation water properties.In particular,postfracturing flowback fluids from well Lu 211—a well subjected to hydraulic fracturing using fresh water—showed a low sodium-chloride coefficient,a low coefficient of variation,high TDS concentration,heavy stable isotopes,and a high nitrate ion concentration.This indicates a formation water source of the fluids and the poor sealing of the formation water,which hinders shale gas enrichment.The quantification of the fracturing fluid and formation water contents in the post-fracturing flowback fluids reveals that higher TDS concentration and heavier stable isotopes in the fluids appear to correspond to higher formation water content and lower fracturing fluid content,as well as higher fracturing performance.A systematic analysis of the geochemical characteristics and flowback pattern of fracturing fluids indirectly provides insights into the flow path of formation water,water body mixing,rock-water interactions,and fluid sources.Besides,the analysis offers a new perspective for understanding the preservation conditions and fracturing performance of shale gas reservoirs.
基金supported by the Key Technology Research on Increasing Recovery Rate in Tight Sandstone Gas Reservoirs,a Major Scientific and Technological Special Project of China National Petroleum Corporation(Project No.2023ZZ25).
文摘Microbial polysaccharides,due to their unique physicochemical properties,have been shown to effec-tively enhance the stability of foam fracturing fluids.However,the combined application of microbial polysaccharides and surfactants under high-temperature and high-salinity conditions remain poorly understood.In this study,we innovatively investigate this problem with a particular focus on foam stabilization mechanisms.By employing the Waring blender method,the optimal surfactant-microbial polysaccharide blends are identified,and the foam stability,rheological properties,and decay behavior in different systems under varying conditions are systematically analyzed for the first time.The results reveal that microbial polysaccharides significantly enhance foam stability by improving the viscoelasticity of the liquid films,particularly under high-salinity and high-temperature conditions,leading to notable improvements in both foam stability and sand-carrying capacity.Additionally,scanning electron microscopy(SEM)is used to observe the microstructure of the foam liquid films,demonstrating that the network structure formed by the foam stabilizer within the liquid film effectively inhibits foam coarsening.The Lauryl betaine and Diutan gum blend exhibits outstanding foam stability,superior sand-carrying capacity,and minimal core damage,making(LAB+MPS04)it ideal for applications in enhanced production and reservoir stimulation of unconventional reservoirs.
基金financially supported by the National Basic Research Program of China (973 Program) Granted No. 2015CB250903the National Natural Science Foundation of China Granted No. 51490652The Chongqing Institute of Geology and Mineral Resources supported this field work
文摘Spontaneous imbibition of water-based frac- turing fluids into the shale matrix is considered to be the main mechanism responsible for the high volume of water loss during the flowback period. Understanding the matrix imbibition capacity and rate helps to determine the frac- turing fluid volume, optimize the flowback design, and to analyze the influences on the production of shale gas. Imbibition experiments were conducted on shale samples from the Sichuan Basin, and some tight sandstone samples from the Ordos Basin. Tight volcanic samples from the Songliao Basin were also investigated for comparison. The effects of porosity, clay minerals, surfactants, and KC1 solutions on the matrix imbibition capacity and rate were systematically investigated. The results show that the imbibition characteristic of tight rocks can be characterized by the imbibition curve shape, the imbibition capacity, the imbibition rate, and the diffusion rate. The driving forces of water imbibition are the capillary pressure and the clay absorption force. For the tight rocks with low clay contents, the imbibition capacity and rate are positively correlated with the porosity. For tight rocks with high clay content, the type and content of clay minerals are the most impor- tant factors affecting the imbibition capacity. The imbibed water volume normalized by the porosity increases with an increasing total clay content. Smectite and illite/smectite tend to greatly enhance the water imbibition capacity. Furthermore, clay-rich tight rocks can imbibe a volume of water greater than their measured pore volume. The aver- age ratio of the imbibed water volume to the pore volume is approximately 1.1 in the Niutitang shale, 1.9 in the Lujiaping shale, 2.8 in the Longmaxi shale, and 4.0 in the Yingcheng volcanic rock, and this ratio can be regarded as a parameter that indicates the influence of clay. In addition, surfactants can change the imbibition capacity due to alteration of the capillary pressure and wettability. A 10 wt% KC1 solution can inhibit clay absorption to reduce the imbibition capacity.
基金supported by the Frontier and Fundamental Research of Active Nanofluids Flooding for Enhanced Oil Recovery through Discontinuous and Variable-circle Modes in High Temperature and High Salinity Offshore Oilfields(U22B6005)National Natural Science Foundation of China(No.52274037)Study on Key Issues of Enhanced Oil Recovery of Gulong Shale Oil(DQYT-2022-JS-761).
文摘Chinaʼs continental shale exhibits favorable geological characteristics and substantial resource potential,yet oil recovery for natural energy extraction remains critically low.Investigating the mechanisms of hydraulically induced bedding fracture to generate complex fracture networks in continental shale,and establishing effective flow systems,is of utmost importance.This study employs laboratory experiments and numerical simulations to investigate the flow capacity and percolation behavior of hydraulically induced bedding fractures by different fluids in full-diameter shale cores.Hydraulic stimulation using different fluids generates bedding plane fracture networks,establishing effective flow systems.Eroded and detached shale fragments support localized fractures,thereby increasing their opening and enhancing flow capacity.Cetyltrimethylammonium bromide(CTAB)solution and SiO2 solution reduce the hydration of the shale surface,preventing shale fragments from swelling and disintegrating,leading to more stable percolation behavior.Eroded and spalled shale fragments near the injection point are transported to farther locations,where they help support localized fractures.This process differs from conventional hydraulic fracturing.Under a constant injection rate,the velocity in the smaller flow paths near the closure is significantly higher than that in the main flow paths,leading to pronounced bypass flow behavior.This restricts the percolation of fluid during imbibition in shale cores.The results provide valuable insights into the mechanism of hydraulically induced bedding fracture in continental shale,offering guidance for the effective development of shale reservoirs.
文摘This study investigated the micro-sliding frictional behavior of shale in fracturing fluids under varying operational conditions using Chang 7 shale oil reservoir core samples.Through systematic micro-sliding friction experiments,the characteristics and governing mechanisms of shale friction were elucidated.Complementary analyses were conducted to characterize the mineral composition,petrophysical properties,and micromorphology of the shale samples,providing insights into the relationship between microscopic structure and frictional response.In this paper,the characteristics and variation law of shale micro-sliding friction under different types of graphite materials as additives in LGF-80(Low-damage Guar Fluid)oil flooding recoverable fracturing fluid system were mainly studied.In addition,the finite element numerical simulation experiment of hydraulic fracturing was adopted to study the influence of the friction coefficient of natural fracture surfaces on fracture propagation and formation of the fracture network.The geometric complexity of fracture networks was systematically quantified under varying frictional coefficients of natural fracture surfaces through multi-parametric characterization and morphometric analysis.The research results show that graphite micro-particles reduce friction and drag.Based on this,this paper proposes a new idea of graphite micro-particles as an additive in the LGF-80 oil flooding recoverable fracturing fluid system to reduce friction on the fracture surface.
基金financially supported by the National Natural Science Foundation of China(Nos.52304129 and 52274130)Natural Science Foundation of Sichuan Province(No.2024NSFSC0971)+1 种基金Guizhou Provincial Basic Research Program(Natural Science)(No.ZK[2023]general 070)Shandong Key Laboratory of Mining Disaster Prevention and Control,Shandong University of Science and Technology(No.SMDPC202403)。
文摘The combination of ultrasonic and acid fracturing fluid can strengthen the modification effect on the micropore structure of the coal matrix,thereby enhancing the efficiency of the acid fracturing process.In this research,acetic acid was utilized to formulate acid fracturing fluids with varying concentrations,and the evolutionary traits of both the acid fracturing fluids and ultrasonic waves in relation to coal samples were investigated.The functional group structure,mineral composition,micropore structure and surface morphology of coal samples were characterized by FTIR,XRD,N_(2)adsorption at low temperature and SEM-EDS.The results showed that aromatics(I)and branching parameters(CH_(2)/CH_(3))were reduced by 81.58%and 88.67%,respectively,after 9%acetic acid treatment.Acetic acid can dissolve carbonates and clay minerals in coal,create new pores,and increase porosity,pore volume and pore fractal dimension.After modification by 7%acetic acid,the pore volume increased by 5.7 times.SEM observation shows that the diameter of coal surface holes increases,EDS scanning shows that the content of mineral elements in coal decreases,the connectivity of coal holes increases,and the holes expand.The findings of this research offer theoretical direction for optimizing ultrasonic-enhanced acid fracturing fluid modification.
基金supported by the National Natural Science Foundation of China(Grant.Nos.52364004,52464005)the Youth Talent Growth Project of Guizhou Provincial Department of Education(Grant No.QianJiaoJi[2024]18).
文摘Injection rate is crucial for determining the hydraulic fracturing effectiveness;however,the effects of the injection rate on the pore and fracture structure(PFS)and fluid infiltration during injection pressurization have rarely been explored.In this study,the cylindrical sandstone samples were hydraulically fractured at various injection rates on a self-developed integrated nuclear magnetic resonance(NMR)and hydraulic fracturing experimental system.The results show that low injection rates predominantly resulted in macropore-scale damage by creating intergranular cracks,whereas high injection rates facilitated micropore-scale damage,probably owing to the adsorption swelling effect of clay minerals within pores.Additionally,the water contents of the samples with low injection rates exhibited a continuous increase,whereas those of the samples with high injection rates initially increased and subsequently stabilized.Magnetic resonance imaging(MRI)indicated that fluid infiltration during the fracturing process exhibited high anisotropy owing to the inherent heterogeneous PFS distributions around the wellbore.Moreover,a primary fluid infiltration path exists that aligns with the initiation direction of the hydraulic fractures.However,the fluid infiltration damage distance along the hydraulic fracture direction decreased with increasing injection rate,whereas the fluid infiltration damage distance perpendicular to the hydraulic fracture direction was approximately equal to the characteristic length,regardless of the injection rate.Finally,we recommend using the pore damage during fluid pressurization as the basis for selecting the proppant size and employing a primary fluid infiltration path to predict hydraulic fracture initiation.These findings provide valuable insights into the design of hydraulic fracturing in tight gas reservoirs.
文摘As oil and gas development increasingly targets unconventional reservoirs,the limitations of conventional hydraulic fracturing,namely high water consumption and significant reservoir damage,have become more pronounced.This has driven growing interest in the development of clean fracturing fluids that minimize both water usage and formation impairment.In this study,a low-liquid-content viscoelastic surfactant(VES)foam fracturing fluid system was formulated and evaluated through laboratory experiments.The optimized formulation comprises 0.2%foaming agent CTAB(cetyltrimethylammonium bromide)and 2%foam stabilizer EAPB(erucamidopropyl betaine).Laboratory tests demonstrated that the VES foam system achieved a composite foam value of 56,700 mL・s,reflecting excellent foaming performance.Proppant transport experiments revealed minimal variation in suspended sand volume over 120 min across different sand ratios,indicating robust sand-carrying capacity even at high proppant concentrations.Rheological measurements showed that the fluid maintained a viscosity above 120 mPa・s after 120 min of shearing at 70℃ and a shear rate of 170 s−1,with the elastic modulus exceeding the viscous modulus,confirming the system’s exceptional stability and resilience.Furthermore,core damage tests indicated that the VES foam caused only 4.42%formation damage,highlighting its potential for efficient and low-damage stimulation of tight reservoirs.Overall,the findings demonstrate that this low-liquid-content VES foam provides a highly effective,environmentally considerate alternative for hydraulic fracturing in unconventional formations,combining superior proppant transport,rheological stability,and minimal reservoir impairment.
基金supported by the Sichuan Youth Science and Technology Innovation Research Team Project(No.2021JDTDO017)the open Fund(PLN2022-11)of State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation(Southwest Petroleum University)+1 种基金Southwest Petroleum University Graduate Innovation Fund(No.2022KYCX021)Jian Tian would like to acknowledge the funding from the National Natural Science Foundation of China(52404023).
文摘To elucidate the adsorption characteristics and retention mechanisms of fracturing fluids in diverse clay minerals,we conducted on-line nuclear magnetic resonance(NMR)and atomic force microscopy(AFM)experiments.The depth and extent of solid phase damage are determined by the ratio between the size of fine fractions in fracturing fluid residue and the pore-throat size in experiments.Poor physical properties(K<0.5 mD)result in a more preferential flow pathway effect during flowback,and the stepwise incremental pressure differential proves to be more effective for the discharge of fracturing fluid in submicron pore throats.The permeability is significantly influenced by the differential distri-bution of retained fracturing fluid,as supported by direct experimental evidence.The presence of good physical properties(K>0.5 mD)combined with a scattered distribution of retained fracturing fluid is associated with high gas phase recovery permeability,whereas a continuous sheet-like distribution results in low recovery permeability.The expansive surface area and presence of filamentous illite minerals facilitate the multiple winding and adsorption of fracturing fluids,demonstrating strong hydrogen-bonding,multi-layering and multiple adsorption properties.The geological characteristics of the main gas formations exhibit significant variation,and the severity of damage caused by fracturing fluids occurs in diverse sequences.To address this issue,a differentiated strategy for optimizing frac-turing fluids has been proposed.
基金supported by the National Natural Science Foundation of China(Nos.52164001,52064006,52004072 and 52364004)the Science and Technology Support Project of Guizhou(Nos.[2020]4Y044,[2021]N404 and[2021]N511)+1 种基金the Guizhou Provincial Science and Technology Foundation(No.GCC[2022]005-1),Talents of Guizhou University(No.201901)the Special Research Funds of Guizhou University(Nos.201903,202011,and 202012).
文摘With the widespread adoption of hydraulic fracturing technology in oil and gas resource development,improving the accuracy and efficiency of fracturing simulations has become a critical research focus.This paper proposes an improved fluid flow algorithm,aiming to enhance the computational efficiency of hydraulic fracturing simulations while ensuring computational accuracy.The algorithm optimizes the aperture law and iteration criteria,focusing on improving the domain volume and crack pressure update strategy,thereby enabling precise capture of dynamic borehole pressure variations during injection tests.The effectiveness of the algorithm is verified through three flow-solid coupling cases.The study also analyzes the effects of borehole size,domain volume,and crack pressure update strategy on fracturing behavior.Furthermore,the performance of the improved algorithm in terms of crack propagation rate,micro-crack formation,and fluid pressure distribution was further evaluated.The results indicate that while large-size boreholes delay crack initiation,the cracks propagate more rapidly once formed.Additionally,the optimized domain volume calculation and crack pressure update strategy significantly shorten the pressure propagation stage,promote crack propagation,and improve computational efficiency.
基金Supported by National Natural Science Foundation of China(51674209)Sichuan Province Youth Science and Technology Innovation Team(2021JDTD0017).
文摘Static adsorption and dynamic damage experiments were carried out on typical 8#deep coal rock of the Carboniferous Benxi Formation in the Ordos Basin,NW China,to evaluate the adsorption capacity of hydroxypropyl guar gum and polyacrylamide as fracturing fluid thickeners on deep coal rock surface and the permeability damage caused by adsorption.The adsorption morphology of the thickener was quantitatively characterized by atomic force microscopy,and the main controlling factors of the thickener adsorption were analyzed.Meanwhile,the adsorption mechanism of the thickener was revealed by Zeta potential,Fourier infrared spectroscopy and X-ray photoelectron spectroscopy.The results show that the adsorption capacity of hydroxypropyl guar gum on deep coal surface is 3.86 mg/g,and the permeability of coal rock after adsorption decreases by 35.24%–37.01%.The adsorption capacity of polyacrylamide is 3.29 mg/g,and the permeability of coal rock after adsorption decreases by 14.31%–21.93%.The thickness of the thickener adsorption layer is positively correlated with the mass fraction of thickener and negatively correlated with temperature,and a decrease in pH will reduce the thickness of the hydroxypropyl guar gum adsorption layer and make the distribution frequency of the thickness of polyacrylamide adsorption layer more concentrated.Functional group condensation and intermolecular force are chemical and physical forces for adsorbing fracturing fluid thickener in deep coal rock.Optimization of thickener mass fraction,chemical modification of thickener molecular,oxidative thermal degradation of polymer and addition of desorption agent can reduce the potential damages on micro-nano pores and cracks in coal rock.
基金supported by the National Natural Science Foundation of China(Grant No.52222403 and U24B2033)Taishan Scholar Program,China(Grant No.tsqn202211079)State Key Laboratory of Deep Oil and Gas,China(Grant No.SKLDOG2024-ZYTS-15).
文摘CO_(2) foam fracturing fluid can effectively integrate CCUS technology into oil and gas field development,and its core advantages include low water consumption,excellent flowback performance,and strong sand-carrying capacity.For these reasons,it has received increasing attention in the oil and gas field development field.However,this type of fracturing fluid still has some prominent problems:The residue from gel breaking can easily cause formation pollution,the system cost is relatively high,and the utilization rate is low,which forms a significant technical bottleneck.In response to these issues,this study,based on the theory of clean fracturing fluid gel breaking without residue and the reusability of CO_(2)-responsive wormlike micelles,innovatively combines CO_(2)-responsive wormlike micelles with different types of surfactant-based foaming agents to construct a new CO_(2)-responsive foam fracturing fluid system.A systematic performance evaluation of the system was conducted to clarify its defoaming rules under different temperature conditions.Compared with the traditional guar gum CO_(2) foam fracturing fluid,the new system has significant performance advantages.At 90℃,its foam comprehensive value reached 19720 mL·min,6150 mL·min higher than the guar gum fluid.After a 5400 s high-temperature and high-shear test at the same temperature,the residual viscosity of the new system was 67 mPa·s,which is higher than the guar gum fluid.This CO_(2)-responsive foam fracturing fluid simultaneously possesses the application potential of both clean fracturing fluid and foam fracturing fluid.It can effectively solve key problems such as formation pollution and low system utilization rates,and laboratory evaluation experiments confirmed its excellent foaming and rheological properties.These results are of great significance for promoting CO_(2) foam fracturing technology to reach an advanced international level and supporting the low-carbon and highefficiency development of unconventional oil and gas resources in China.
基金funded by the National key R&D Program of China(No.2023YFE0120700)the National Natural Science Foundation of China(No.51934005)+2 种基金the Shaanxi Province 2023 Innovation Capability Support Plan(No.2023KJXX-122)the Technology Innovation Leading Program of Shaanxi(No.2022 PT-08)the Project of Youth Innovation Team of Shaanxi Universities(No.22JP063).
文摘The Linxing area within the Ordos Basin exhibits pronounced reservoir heterogeneity and intricate micro-pore structures,rendering it susceptible to water-blocking damage during imbibition extraction.This study delved into the traits of tight sandstone reservoirs in the 8th member of the Shihezi Formation(also referred to as the He 8 Member)in the study area,as well as their effects on fracturing fluid imbibition.Utilizing experimental techniques such as nuclear magnetic resonance(NMR),high-pressure mercury intrusion(HPMI),and gas adsorption,this study elucidated the reservoir characteristics and examined the factors affecting the imbibition through imbibition experiments.The findings reveal that:①The reservoir,with average porosity of 8.40%and average permeability of 0.642×10^(-3)μm^(2),consists principally of quartz,feldspar,and lithic fragments,with feldspathic litharenite serving as the primary rock type and illite as the chief clay mineral;②Nano-scale micro-pores and throats dominate the reservoir,with dissolution pores and intercrystalline pores serving as predominant pore types,exhibiting relatively high pore connectivity;③Imbibition efficiency is influenced by petrophysical properties,clay mineral content,and microscopic pore structure.Due to the heterogeneity of the tight sandstone reservoir,microscopic factors have a more significant impact on the imbibition efficiency of fracturing fluids;④A comparative analysis shows that average pore size correlates most strongly with imbibition efficiency,followed by petrophysical properties and clay mineral content.In contrast,the pore type has minimal impact.Micropores are vital in the imbibition process,while meso-pores and macro-pores offer primary spaces for imbibition.This study offers theoretical insights and guidance for enhancing the post-fracturing production of tight sandstone reservoirs by examining the effects of these factors on the imbibition efficiency of fracturing fluids in tight sandstones.
文摘Fracturing operations can effectively improve the production of low-permeable reservoirs. The performance of fracturing fluids directly affects the fracturing efficiency and back flow capacity. As polymerbased fracturing fluids(such as guar gum(GG), polyacrylamide(HPAM), etc.) are high-viscosity fluids formed by viscosifiers and crosslinking agents, the degree of gel breakage after the fracturing operation directly influences the damage degree to the reservoir matrix and the mobility of oil angd gas produced from the reservoir into the wellbore. This study compared the viscosity, molecular weight, and particle size of the fracturing fluid after gel breakage prepared by GG and HPAM as viscosifiers, as well as evaluate their damage to the core. Results show that the viscosities of the gel-breaking fluid increased with the concentration of the viscosifier for both the HPAM-based and GG-based fracturing fluids. For the breaking fluid with the same viscosity, the molecular weight in the HPAM-based gel-breaking fluid was much larger than that in the GG-based system. Moreover, for the gel-breaking fluid with the same viscosity, the molecular particle size of the residual polymers in the HPAM-based system was smaller than that in the GG-based system. The damage to the core with the permeability of 1 × 10^(-3)μm^(2) caused by both the HPAM-based and GG-based gel-breaking fluids decreased with the increase in the solution viscosity. For the gel-breaking fluid systems with the same viscosity(i.e., 2-4 mPa s), the damage of HPAM-based fracturing fluid to low-permeability cores was greater than the GG-based fracturing fluid(45.6%-80.2%) since it had a smaller molecular particle size, ranging from 66.2% to 77.0%. This paper proposed that the damage caused by hydraulic fracturing in rock cores was related to the partilce size of residual polymers in gel-breaking solution, rather than its molecular weight. It was helpful for screening and optimizing viscosifiers used in hydraulic fracturing process.
文摘The variable-density flow model-SEAWAT Version 4, was used to evaluate the hydrogeological conditions associatedwith hydraulic fracturing （fracking） the limestone oil reservoir in the Lower Cretaceous Sunniland Formation of Southwest Florida.This research contributes to the understanding of the controls on fluid and potential contaminant migration, following high pressurehydraulic fracturing. A hydraulic fracturing treatment used recently in this formation at the Collier-Hogan 20-3H well represents thebase case simulation. Multiple stage fracturing using typical stress periods, a modelled fracture zone radius, and various injectionrates were tested to evaluate the potential for horizontal and vertical fluid migration in and from the reservoir under dynamicconditions, with TDS used as a tracer. Hypothetical scenarios including preferential vertical pathways between the SunnilandFormation and the Lower Floridan aquifer Boulder Zone were also simulated. Results indicate that injected fluids do not migratesignificantly in the lateral and vertical directions beyond the design fractured zone, unless a preferential pathway exists within closeproximity to the fractured zone. In a worst-case scenario under the simulated conditions, vertical heads are approximately 580 metersgreater than static conditions and fluids associated with hydraulic fracturing vertically migrate approximately 500 meters; therefore,the quality of the deepest sources of drinking water is not compromised. Analytical results from a monitoring well installed in theimmediate vicinity of the Collier-Hogan 20-3H well and at the base of the deepest source of drinking water support the conclusionthat impacts from hydraulic fracturing fluids have not migrated into the deepest sources of drinking water.
基金This study was supported by the National Natural Science Foundation of China(No.41302192)Natural Science Foundation of Hebei Province of China(No.D2018504011)+1 种基金China Geological Survey(No.DD20190555)the Ministry of land and resources of the People’s Republic of China(No.201411052).
文摘Hydrogeochemical processes that would occur in polluted groundwater and aquifer system,may reduce the sensitivity of Sr isotope being the indicator of hydraulic fracturing flowback fluids(HFFF)in groundwater.In this paper,the Dameigou shale gas field in the northern Qaidam Basin was taken as the study area,where the hydrogeochemical processes affecting Sr isotope was analysed.Then,the model for Sr isotope in HFFF-polluted groundwater was constructed to assess the sensitivity of Sr isotope as HFFF indicator.The results show that the dissolution can release little Sr to polluted groundwater and cannot affect the εSr(the deviation of the 87Sr/86Sr ratio)of polluted groundwater.In the meantime,cation exchange can considerably affect Sr composition in the polluted groundwater.The Sr with low εSr is constantly released to groundwater from the solid phase of aquifer media by cation exchange with pollution of Quaternary groundwater by the HFFF and it accounts for 4.6% and 11.0% of Sr in polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater,respectively.However,the Sr from cation exchange has limited impact on Sr isotope in polluted groundwater.Addition of Sr from cation exchange would only cause a 0.2%and 1.2% decrease in εSr of the polluted groundwater when the HFFF flux reaches 10% and 30% of the polluted groundwater,respectively.These results demonstrate that hydrogeochemical processes have little effect on the sensitivity of Sr isotope being the HFFF indicator in groundwater of the study area.For the scenario of groundwater pollution by HFFF,when the HFFF accounts for 5%(in volume percentage)of the polluted groundwater,the HFFF can result in detectable shifts of εSr(Δ_(εSr)=0.86)in natural groundwater.Therefore,after consideration of hydrogeochemical processes occurred in aquifer with input of the HFFF,Sr isotope is still a sensitive indicator of the Quaternary groundwater pollution by the HFFF produced in the Dameigou shale of Qaidam Basin.
文摘Centralized and group well deployment and factory-like fracturing techniques are adopted for low-permeability tight sandstone reservoirs in the Sulige Gasfield,Ordos Basin,so as to realize its efficient and economic development.However,environmental protection is faced with grim situations because fluid delivery rises abruptly on site in a short time due to centralized fracturing of the well group.Based on the characteristics of gas testing after fracturing in this gas field,a fracturing flowback fluid recovery and treatment method suitable for the Sulige Gasfield has been developed with the landform features of this area taken into account.Firstly,a high-efficiency well-to-well fracturing flowback fluid recovery and reutilization technique was developed with multi-effect surfactant polymer recoverable fracturing fluid system as the core,and in virtue of this technique,the treatment efficiency of conventional guar gum fracturing fluid system is increased.Secondly,for recovering and treating the end fluids on the well sites,a fine fracturing flowback fluid recovery and treatment technique has been worked out with“coagulation and precipitation,filtration and disinfection,and sludge dewatering”as the main part.Owing to the application of this method,the on-site water resource utilization ratio has been increased and environmental protection pressure concerned with fracturing operation has been relieved.In 2014,field tests were performed in 62 wells of 10 well groups,with 32980 m3 cumulative treated flowback fluid,17160 m3 reutilization volume and reutilization ratio over 70%.Obviously,remarkable social and economical benefits are thus realized.
基金Project supported by National Key Basic Research Program of China(937 program)“Basic research of high-efficiency marine shale gas development in South China”(No.2013CB228000).
文摘In this paper,marine shale cores taken from Zhaotong,Changning and Weiyuan Blocks in South China were used as samples to investigate the interaction between fracturing fluids and shale and the retention mechanisms.Firstly,adsorption,swelling,dissolution pore,dissolution fluid mineralization degree and ionic composition were experimentally studied to reveal the occurrence of water in shale and the reason for a high mineralization degree.Then,the mechanisms of water retention and mineralization degree increase were simulated and calculated.The scanning electron microscopy(SEM)analysis shows that there are a large number of micro fractures originated from clay minerals in the shale.Mineral dissolution rates of shale immersed in ultrasonic is around 0.5-0.7%.The ionic composition is in accordance with that of formation water.The clay minerals in core samples are mainly composed of chlorites and illites with a small amount of illites/smectites,but no montmorillonites(SS),and its content is between 18%and 20%.It is verified by XRD and infrared spectroscopy that the fracturing fluid doesn't flow into the space between clay mineral layers,so it can't lead to shale swelling.Thus,the retention of fracturing fluids is mainly caused by the adsorption at the surface of the newly fractured micro fractures in shale in a mode of successive permeation,and its adsorptive saturation rates is proportional to the pore diameters.It is concluded that the step-by-step extraction of fracturing fluids to shale and the repulsion of nano-cracks to ion are the main reasons for the abrupt increase of mineralization degree in the late stage of flowing back.In addition,the liquid carrying effect of methane during the formation of a gas reservoir is also a possible reason.Based on the experimental and field data,fracturing fluid flowback rates and gas production rates of 9 wells were analyzed.It is indicated that the same block follows an overall trend,namely,the lower the flowback rates,the more developed the micro fractures,the better the volume simulation effect and the higher the gas production rates.
基金the Australian Research Council Discovery Project(ARC DP 220100851)scheme and would acknowledge that.
文摘Particle-fluid two-phase flows in rock fractures and fracture networks play a pivotal role in determining the efficiency and effectiveness of hydraulic fracturing operations,a vital component in unconventional oil and gas extraction.Central to this phenomenon is the transport of proppants,tiny solid particles injected into the fractures to prevent them from closing once the injection is stopped.However,effective transport and deposition of proppant is critical in keeping fracture pathways open,especially in lowpermeability reservoirs.This review explores,then quantifies,the important role of fluid inertia and turbulent flows in governing proppant transport.While traditional models predominantly assume and then characterise flow as laminar,this may not accurately capture the complexities inherent in realworld hydraulic fracturing and proppant emplacement.Recent investigations highlight the paramount importance of fluid inertia,especially at the high Reynolds numbers typically associated with fracturing operations.Fluid inertia,often overlooked,introduces crucial forces that influence particle settling velocities,particle-particle interactions,and the eventual deposition of proppants within fractures.With their inherent eddies and transient and chaotic nature,turbulent flows introduce additional complexities to proppant transport,crucially altering proppant settling velocities and dispersion patterns.The following comprehensive survey of experimental,numerical,and analytical studies elucidates controls on the intricate dynamics of proppant transport under fluid inertia and turbulence-towards providing a holistic understanding of the current state-of-the-art,guiding future research directions,and optimising hydraulic fracturing practices.
基金supported by the National Key Research and Development Program of China(Grant No.2019YFA0708700).
文摘A deep understanding of the geometric impacts of fracture on fracturing fluid flowback efficiency is essential for unconventional oil development. Using nuclear magnetic resonance and 2.5-dimensional matrix-fracture visualization microfluidic models, qualitative and quantitative descriptions of the influences of connectivity between primary fracture and secondary fracture on flowback were given from core scale to pore network scale. The flow patterns of oil-gel breaking fluid two-phase flow during flowback under different fracture connectivity were analyzed. We found some counterintuitive results that non-connected secondary fracture (NCSF, not connect with artificial primary fracture and embedded in the matrix) is detrimental to flowbackefficiency. The NCSF accelerates the formation of oil channeling during flowback, resulting in a large amount of fracturing fluid trapped in the matrix, which is not beneficial for flowback. Whereas the connected secondary fracture (CSF, connected with the artificial primary fracture) is conducive to flowback. The walls of CSF become part of primary fracture, which expands the drainage area with low resistance, and delays the formation of the oil flow channel. Thus, CSF increases the high-speed flowback stage duration, thereby enhancing the flowback efficiency. The fracturing fluid flowback efficiency investigated here follows the sequence of the connected secondary fracture model (72%) > the matrix model (66%) > the non-connected secondary fracture model (38%). Our results contribute to hydraulic fracturing design and the prediction of flowback efficiency.
