In order to reduce the torque ripple,increase the average torque and optimize the drive performance of the switched reluctance motor (SRM),the nonlinear dynamic model of SRM is established in the MATLAB /Simulink envi...In order to reduce the torque ripple,increase the average torque and optimize the drive performance of the switched reluctance motor (SRM),the nonlinear dynamic model of SRM is established in the MATLAB /Simulink environment.The effects of the turn-on and turn-off angles are investigated by the simulation results of the dynamic model,and the function is made among the rotor speed,turn-on angle and turn-off angle.To optimize the torque dynamic performance,the two-objective simultaneous optimization function is proposed by two weight factors.And the optimized turn-on and turn-off angles as functions of rotor speed are developed by using the simultaneous optimization method.Then the optimized torque controller is designed based on the optimized turn-on and turn-off angles.The simulation results show that the optimized torque controller designed in this paper can effectively reduce the torque ripple and increase the average torque,and optimize the torque dynamic performance of the SRM.展开更多
A novel temperature fluctuation synthesis/simultaneous densification process was developed for the preparation of Ti3SiC2 bulk ceramics. In this process. Si is used as an in-situ liquid forming phase and it is favorab...A novel temperature fluctuation synthesis/simultaneous densification process was developed for the preparation of Ti3SiC2 bulk ceramics. In this process. Si is used as an in-situ liquid forming phase and it is favorable for both the solid-liquid synthesis and the densification of Ti3SiC2 rainies. The present work demonstrated that the temperature fluctuation synthesis/simultaneous densification process is one of the most effective and simple methods for the preparation of Ti3SiC2 bulk materials providing relatively low synthesis temperature. short reaction time; and simultaneous synthesis and densification. This work also showed the capability to control the microstructure, e.g., the preferred orientation, of the bulk Ti3SiC2 materials simply by applying the hot pressing pressure at different Stages of the temperature fluctuation process. And textured Ti3SiC2 bulk materials with {002} faces of laminated Ti3SiC2 grains normal to the hot pressing axis were prepared.展开更多
This paper deal with optimal control problems for a non-stationary Stokes system. We study a simultaneous distributed-boundary optimal control problem with distributed observation. We prove the existence and uniquenes...This paper deal with optimal control problems for a non-stationary Stokes system. We study a simultaneous distributed-boundary optimal control problem with distributed observation. We prove the existence and uniqueness of a simultaneous optimal control and we give the first order optimality condition for this problem. We also consider a distributed optimal control problem and a boundary optimal control problem and we obtain estimations between the simultaneous optimal control and the optimal controls of these last ones. Finally, some regularity results are presented.展开更多
The application of a closed-loop specification oriented feedback control design method, which addresses the design of controllers to satisfy multiple simultaneous conflicting closed-loop performance specifications is ...The application of a closed-loop specification oriented feedback control design method, which addresses the design of controllers to satisfy multiple simultaneous conflicting closed-loop performance specifications is presented. The proposed approach is well suited to the design of controllers which must meet a set of conflicting performance specifications. Gain tuning is central to the design process, however, the tuning process is greatly simplified over that presented by the problem of tuning a PID controller for example. The proposed control method is applied to an AC induction motor, with an inner-loop flux vector controller applied to design a position control system. Experimental results verify the effectiveness of this method.展开更多
On the tasis of study in the mathematical model of 3-dimensional ruled surface (RS),this paper introduces a new concept of distance paramcter (DP) and also puts forward that themethod of modeling a RS depends on not o...On the tasis of study in the mathematical model of 3-dimensional ruled surface (RS),this paper introduces a new concept of distance paramcter (DP) and also puts forward that themethod of modeling a RS depends on not only two boundary curves but also DP. According toabove theory, the formulas to calculate corresponding point coordinates to any kind of top and bot-tom profile of a workpiece and formulas to calcuate the maximum inclination angle of ruling linehave been obtained. Then a different top and bottom RS mathining method including profile withline-are combination as well as parametric curves has been achieved by 4-axes simultancous con-trol programming proposed.展开更多
The configuration and the reference frame of the four-axis wire-electric discharge machining （WEDM） machine tool are introduced. Based on the motion analysis of the four-axis WEDM machine tool, an algorithm for cont...The configuration and the reference frame of the four-axis wire-electric discharge machining （WEDM） machine tool are introduced. Based on the motion analysis of the four-axis WEDM machine tool, an algorithm for controlling the four-axis motion is proposed. The algorithm is applicable to both the invariable and variable taper machining. Motion loci of the machining platform and the wire guiding head are deduced by the algorithm according to the bottom surface locus of the workpiece and the taper angle. The algorithm is used in the CNC system of the four-axis WEDM machine tool and confirmed to be effective.展开更多
Mining operation, especially underground coal mining, always has the remarkable risks of ground control. Passive seismic velocity tomography based on simultaneous iterative reconstructive technique （SIRT） inversion ...Mining operation, especially underground coal mining, always has the remarkable risks of ground control. Passive seismic velocity tomography based on simultaneous iterative reconstructive technique （SIRT） inversion is used to deduce the stress redistribution around the longwall mining panel. The mining-induced microseismic events were recorded by mounting an array of receivers on the surface, above the active panel. After processing and filtering the seismic data, the three-dimensional tomography images of the p-wave velocity variations by SIRT passive seismic velocity tomography were provided. To display the velocity changes on coal seam level and subsequently to infer the stress redistribution, these three-dimensional tomograms into the coal seam level were sliced. In addition, the boundary element method （BEM） was used to simulate the stress redistribution. The results show that the inferred stresses from the passive seismic tomograms are conformed to numerical models and theoretical concept of the stress redistribution around the longwall panel. In velocity tomograms, the main zones of the stress redistribution arotmd the panel, including front and side abutment pressures, and gob stress are obvious and also the movement of stress zones along the face advancement is evident. Moreover, the effect of the advance rate of the face on the stress redistribution is demonstrated in tomography images. The research result proves that the SIRT passive seismic velocity tomography has an ultimate potential for monitoring the changes of stress redistribution around the longwall mining panel continuously and subsequently to improve safety of mining operations.展开更多
An approach of simultaneous strategies with two novel techniques is proposed to improve the solution accuracy of chemical dynamic optimization problems. The first technique is to handle constraints on control vari- ab...An approach of simultaneous strategies with two novel techniques is proposed to improve the solution accuracy of chemical dynamic optimization problems. The first technique is to handle constraints on control vari- ables based on the finite-element collocation so as to control the approximation error for discrete optimal problems, where a set of control constraints at dement knots are integrated with the procedure for optimization leading to a significant gain in the accuracy of the simultaneous strategies. The second technique is to make the mesh refine- ment more feasible and reliable by introducing length constraints and guideline in designing appropriate element length boundaries, so that the proposed approach becomes more efficient in adjusting dements to track optimal control profile breakpoints and ensure accurate state and centrol profiles. Four classic benchmarks of dynamic op- timization problems are used as illustrations, and the proposed approach is compared with literature reports. The research results reveal that the proposed approach is preferz,ble in improving the solution accuracy of chemical dy- namic optimization problem.展开更多
Chinese rice wine making is a typical simultaneous saccharification and fermentation （SSF） process. During the fermentation process, temperature is one of the key parameters which decide the quality of Chinese rice ...Chinese rice wine making is a typical simultaneous saccharification and fermentation （SSF） process. During the fermentation process, temperature is one of the key parameters which decide the quality of Chinese rice wine. To optimize the SSF process for Chinese rice wine brewing, the effects of temperature on the kinetic parameters of yeast growth and ethanol production at various temperatures were determined in batch cultures using a mathematical model. The kinetic parameters as a function of temperature were evaluated using the software Origin8.0. Combing these functions with the mathematical model, an appropriate form of the model equations for the SSF considering the effects of temperature were developed. The kinetic parameters were found to fit the experimental data satisfactorily with the developed temperature-dependent model. The temperature profile for maximizing the ethanol production for rice wine fermentation was determined by genetic algorithm. The optimum temperature profile began at a low temperature of 26℃ up to 30 h. The operating temperature increased rapidly to 31.9 ℃, and then decreased slowly to 18℃ at 65 h. Thereafter, the temperature was maintained at 18 ℃ until the end of fermentation. A maximum ethanol production of 89.3 g.L 1 was attained. Conceivably, our model would facilitate the improvement of Chinese rice wine production at the industrial scale.展开更多
This paper proposes an adaptive sliding mode observer(ASMO)-based approach for wind turbines subject to simultaneous faults in sensors and actuators.The proposed approach enables the simultaneous detection of actuator...This paper proposes an adaptive sliding mode observer(ASMO)-based approach for wind turbines subject to simultaneous faults in sensors and actuators.The proposed approach enables the simultaneous detection of actuator and sensor faults without the need for any redundant hardware components.Additionally,wind speed variations are considered as unknown disturbances,thus eliminating the need for accurate measurement or estimation.The proposed ASMO enables the accurate estimation and reconstruction of the descriptor states and disturbances.The proposed design implements the principle of separation to enable the use of the nominal controller during faulty conditions.Fault tolerance is achieved by implementing a signal correction scheme to recover the nominal behavior.The performance of the proposed approach is validated using a 4.8 MW wind turbine benchmark model subject to various faults.Monte-Carlo analysis is also carried out to further evaluate the reliability and robustness of the proposed approach in the presence of measurement errors.Simplicity,ease of implementation and the decoupling property are among the positive features of the proposed approach.展开更多
[Objectives] To establish a high performance liquid chromatography (HPLC) wavelength switching method for the simultaneous determination of content of six constituents (phellodendrine chloride, gentiopicrin, paeoniflo...[Objectives] To establish a high performance liquid chromatography (HPLC) wavelength switching method for the simultaneous determination of content of six constituents (phellodendrine chloride, gentiopicrin, paeoniflorin, tetrandrine, berberine hydrochloride and paeonol) in Cangbaiqutong capsules, and provide a scientific basis for the comprehensive evaluation of the quality of Cangbaiqutong capsule.[Methods] The chromatographic column of Waters XSELECT CSH-C 18 (4.6 mm × 150 mm, 5 μm), the mobile phase of acetonitrile-0.1% phosphate solution, gradient elution (0-15 min,10%-18% A;15-30 min,18%-50% A;30-35 min, 50%-10% A);the flow rate of 1.0 mL/min, wavelength switching of 284 (0-7 min, phellodendrine), 274 (7-10 min, gentiopicrin), 230 (10-14 min, paeoniflorin) and 274 nm (14-35 min, tetrandrine, berberine hydrochloride, paeonol), the injection volume of 10 μL.[Results] There was a good linear relationship between the area of chromatographic peak and the injection volume of phellodendrine chloride, gentiopicrin, paeoniflorin, tetrandrine, berberine hydrochloride and paeonol in the range of 0.150-1.504, 0.768-7.680, 1.096-10.960, 0.220-2.200, 0.296-2.956, 0.0345-0.345 μg, respectively;the average recovery rates ( n =6) were 98.3%, 99.2%, 98.8%, 98.8%, 99.1% and 98.2%, respectively;the RSD value was 1.32%, 1.46%, 1.08%, 1.31%, 1.26% and 1.21%, respectively.[Conclusions] The method can be used to determine many kinds of constituents at the same time, and the operation is simple, accurate and reproducible, and can be used for the quality control of compound Cangbaiqutong capsules.展开更多
This paper presents a simultaneous H2/H∞ stabilization problem for the chemical reaction systems which can be modeled as a finite collection of subsystems. A single dynamic output feedback controller which simultaneo...This paper presents a simultaneous H2/H∞ stabilization problem for the chemical reaction systems which can be modeled as a finite collection of subsystems. A single dynamic output feedback controller which simultaneously stabilizes the multiple subsystems and captures the mixed H2/H∞ control performance is designed. To ensure that the stability condition, the H2 characterization and the H∞ characterization can be enforced within a unified matrix inequality framework, a novel technique based on orthogonal complement space is developed. Within such a framework, the controller gain is parameterized by the introduction of a common free positive definite matrix, which is independent of the multiple Lyapunov matrices. An iterative linear matrix inequality （ILMI） algorithm using Matlab Yalmip toolbox is established to deal with the proposed framework. Simulation results of a typical chemical reaction system are exploited to show the validity of the proposed methodology.展开更多
In this paper,the adaptive robust simultaneous stabilization problem of uncertain multiple n-degree-of-freedom(n-DOF)robot systems is studied using the Hamiltonian function method,and the corresponding adaptive L2 con...In this paper,the adaptive robust simultaneous stabilization problem of uncertain multiple n-degree-of-freedom(n-DOF)robot systems is studied using the Hamiltonian function method,and the corresponding adaptive L2 controller is designed.First,we investigate the adaptive simultaneous stabilization problem of uncertain multiple n-DOF robot systems without external disturbance.Namely,the single uncertain n-DOF robot system is transformed into an equivalent Hamiltonian form using the unified partial derivative operator(UP-DO)and potential energy shaping method,and then a high dimensional Hamiltonian system for multiple uncertain robot systems is obtained by applying augmented dimension technology,and a single output feedback controller is designed to ensure the simultaneous stabilization for the higher dimensional Hamiltonian system.On this basis,we further study the adaptive robust simultaneous stabilization control problem for the uncertain multiple n-DOF robot systems with external disturbances,and design an adaptive robust simultaneous stabilization controller.Finally,the simulation results show that the adaptive robust simultaneous stabilization controller designed in this paper is very effective in stabilizing multi-robot systems at the same time.展开更多
The origins and main control methods of gas in coal seams were introduced cursorily, and the processes that need to be done in controlling gas, which includes prediction of gas emissions, drainage systems, the means o...The origins and main control methods of gas in coal seams were introduced cursorily, and the processes that need to be done in controlling gas, which includes prediction of gas emissions, drainage systems, the means of prevention of gas outbursts, and some suggestions were put forward. The characteristic of different gas emissions and the corresponding counter measures were presented, and ＆ case study of simultaneous extraction of coal and gas in Xieyi Coal Mine was carried out by coal mining and gas extraction without coal-pillar. The field application shows that gas drainage ratio in panel 5121（0） averages about 90% and reaches as high as 95~/0, which will give beneficial references to gas control in coal mines.展开更多
Coal bed methane control with low permeability is a hot issue at present. The current status of coal bed methane control in China is introduced. The government-support policies on coal bed methane control are presente...Coal bed methane control with low permeability is a hot issue at present. The current status of coal bed methane control in China is introduced. The government-support policies on coal bed methane control are presented. This paper proposes the theories of methane control in depressurized mining, including methane extraction in depressurized mining, simultaneous mining technique of coal and methane without coal pillar, and circular overlying zone for high-efficiency methane extraction in coal seams with low permeability. The techniques of methane control and related instruments and equipments in China are introduced. On this basis, the problems related to coal bed methane control are addressed and further studies are pointed out.展开更多
Chiral molecules, which may contain one or more different type（s） of stereocentres, such as central, axial, planar, and helical chiralities, etc., are indispensable in chemistry, pharmaceutical industry, and life sc...Chiral molecules, which may contain one or more different type（s） of stereocentres, such as central, axial, planar, and helical chiralities, etc., are indispensable in chemistry, pharmaceutical industry, and life science. Despite many advances for the preparation of chiral molecules usually with a single type of chirality have been realized, simultaneous construction of different types of chiralities is still a significant challenge. Here, we wish to report a protocol for preparation of chiral allenes with both central and axial chiralities via a catalytic asymmetric allenylation of different biologically or syn- thetically useful fluorinated or non-fluorinated nucleophiles with readily available racemic allenes by using a single chiral ligand. An echoing between the central chirality and axial chirality for the enantioselectivity was observed. This strategy provides a general and practical approach to functionalized optically active allenes bearing both central and axial chiralities with an excellent enantioselectivity under mild conditions.展开更多
基金Sponsored by the Ph.D.Program Foundation of Ministry of Education of China(Grant No.20092302120)
文摘In order to reduce the torque ripple,increase the average torque and optimize the drive performance of the switched reluctance motor (SRM),the nonlinear dynamic model of SRM is established in the MATLAB /Simulink environment.The effects of the turn-on and turn-off angles are investigated by the simulation results of the dynamic model,and the function is made among the rotor speed,turn-on angle and turn-off angle.To optimize the torque dynamic performance,the two-objective simultaneous optimization function is proposed by two weight factors.And the optimized turn-on and turn-off angles as functions of rotor speed are developed by using the simultaneous optimization method.Then the optimized torque controller is designed based on the optimized turn-on and turn-off angles.The simulation results show that the optimized torque controller designed in this paper can effectively reduce the torque ripple and increase the average torque,and optimize the torque dynamic performance of the SRM.
基金the National Outstanding YOung Scientist Foundation Under Grant !No.59925208 the National Natural Science Foundation of China
文摘A novel temperature fluctuation synthesis/simultaneous densification process was developed for the preparation of Ti3SiC2 bulk ceramics. In this process. Si is used as an in-situ liquid forming phase and it is favorable for both the solid-liquid synthesis and the densification of Ti3SiC2 rainies. The present work demonstrated that the temperature fluctuation synthesis/simultaneous densification process is one of the most effective and simple methods for the preparation of Ti3SiC2 bulk materials providing relatively low synthesis temperature. short reaction time; and simultaneous synthesis and densification. This work also showed the capability to control the microstructure, e.g., the preferred orientation, of the bulk Ti3SiC2 materials simply by applying the hot pressing pressure at different Stages of the temperature fluctuation process. And textured Ti3SiC2 bulk materials with {002} faces of laminated Ti3SiC2 grains normal to the hot pressing axis were prepared.
基金partially supported by PIP No.0534 from CONICET-Univ.AustralPPI No.18C417 from SECy T-UNRCpartially supported by AVENTURES-ANR-12-BLAN-BS01-0001-01
文摘This paper deal with optimal control problems for a non-stationary Stokes system. We study a simultaneous distributed-boundary optimal control problem with distributed observation. We prove the existence and uniqueness of a simultaneous optimal control and we give the first order optimality condition for this problem. We also consider a distributed optimal control problem and a boundary optimal control problem and we obtain estimations between the simultaneous optimal control and the optimal controls of these last ones. Finally, some regularity results are presented.
文摘The application of a closed-loop specification oriented feedback control design method, which addresses the design of controllers to satisfy multiple simultaneous conflicting closed-loop performance specifications is presented. The proposed approach is well suited to the design of controllers which must meet a set of conflicting performance specifications. Gain tuning is central to the design process, however, the tuning process is greatly simplified over that presented by the problem of tuning a PID controller for example. The proposed control method is applied to an AC induction motor, with an inner-loop flux vector controller applied to design a position control system. Experimental results verify the effectiveness of this method.
文摘On the tasis of study in the mathematical model of 3-dimensional ruled surface (RS),this paper introduces a new concept of distance paramcter (DP) and also puts forward that themethod of modeling a RS depends on not only two boundary curves but also DP. According toabove theory, the formulas to calculate corresponding point coordinates to any kind of top and bot-tom profile of a workpiece and formulas to calcuate the maximum inclination angle of ruling linehave been obtained. Then a different top and bottom RS mathining method including profile withline-are combination as well as parametric curves has been achieved by 4-axes simultancous con-trol programming proposed.
文摘The configuration and the reference frame of the four-axis wire-electric discharge machining （WEDM） machine tool are introduced. Based on the motion analysis of the four-axis WEDM machine tool, an algorithm for controlling the four-axis motion is proposed. The algorithm is applicable to both the invariable and variable taper machining. Motion loci of the machining platform and the wire guiding head are deduced by the algorithm according to the bottom surface locus of the workpiece and the taper angle. The algorithm is used in the CNC system of the four-axis WEDM machine tool and confirmed to be effective.
文摘Mining operation, especially underground coal mining, always has the remarkable risks of ground control. Passive seismic velocity tomography based on simultaneous iterative reconstructive technique （SIRT） inversion is used to deduce the stress redistribution around the longwall mining panel. The mining-induced microseismic events were recorded by mounting an array of receivers on the surface, above the active panel. After processing and filtering the seismic data, the three-dimensional tomography images of the p-wave velocity variations by SIRT passive seismic velocity tomography were provided. To display the velocity changes on coal seam level and subsequently to infer the stress redistribution, these three-dimensional tomograms into the coal seam level were sliced. In addition, the boundary element method （BEM） was used to simulate the stress redistribution. The results show that the inferred stresses from the passive seismic tomograms are conformed to numerical models and theoretical concept of the stress redistribution around the longwall panel. In velocity tomograms, the main zones of the stress redistribution arotmd the panel, including front and side abutment pressures, and gob stress are obvious and also the movement of stress zones along the face advancement is evident. Moreover, the effect of the advance rate of the face on the stress redistribution is demonstrated in tomography images. The research result proves that the SIRT passive seismic velocity tomography has an ultimate potential for monitoring the changes of stress redistribution around the longwall mining panel continuously and subsequently to improve safety of mining operations.
基金Supported by the Joint Funds of NSFC-CNPC of China(U1162130)the International Cooperation and Exchange Project of Science and Technology Department of Zhejiang Province(2009C34008)+1 种基金the National High Technology Research and Development Program of China(2006AA05Z226)the Zhejiang Provincial Natural Science Foundation for Distinguished Young Scientists(R4100133)
文摘An approach of simultaneous strategies with two novel techniques is proposed to improve the solution accuracy of chemical dynamic optimization problems. The first technique is to handle constraints on control vari- ables based on the finite-element collocation so as to control the approximation error for discrete optimal problems, where a set of control constraints at dement knots are integrated with the procedure for optimization leading to a significant gain in the accuracy of the simultaneous strategies. The second technique is to make the mesh refine- ment more feasible and reliable by introducing length constraints and guideline in designing appropriate element length boundaries, so that the proposed approach becomes more efficient in adjusting dements to track optimal control profile breakpoints and ensure accurate state and centrol profiles. Four classic benchmarks of dynamic op- timization problems are used as illustrations, and the proposed approach is compared with literature reports. The research results reveal that the proposed approach is preferz,ble in improving the solution accuracy of chemical dy- namic optimization problem.
基金Supported by the National Natural Science Foundation of China(21276111,21206053,61305017)the Programme of Introducing Talents of Discipline to Universities(B12018)+2 种基金Fundamental Research Funds for the Central Universities(JUSRP11558)the Natural Science Foundation of Jiangsu Province(no.BK20160162)the Fundamental Research Funds for the Central Universities(JUSRP51510)
文摘Chinese rice wine making is a typical simultaneous saccharification and fermentation （SSF） process. During the fermentation process, temperature is one of the key parameters which decide the quality of Chinese rice wine. To optimize the SSF process for Chinese rice wine brewing, the effects of temperature on the kinetic parameters of yeast growth and ethanol production at various temperatures were determined in batch cultures using a mathematical model. The kinetic parameters as a function of temperature were evaluated using the software Origin8.0. Combing these functions with the mathematical model, an appropriate form of the model equations for the SSF considering the effects of temperature were developed. The kinetic parameters were found to fit the experimental data satisfactorily with the developed temperature-dependent model. The temperature profile for maximizing the ethanol production for rice wine fermentation was determined by genetic algorithm. The optimum temperature profile began at a low temperature of 26℃ up to 30 h. The operating temperature increased rapidly to 31.9 ℃, and then decreased slowly to 18℃ at 65 h. Thereafter, the temperature was maintained at 18 ℃ until the end of fermentation. A maximum ethanol production of 89.3 g.L 1 was attained. Conceivably, our model would facilitate the improvement of Chinese rice wine production at the industrial scale.
文摘This paper proposes an adaptive sliding mode observer(ASMO)-based approach for wind turbines subject to simultaneous faults in sensors and actuators.The proposed approach enables the simultaneous detection of actuator and sensor faults without the need for any redundant hardware components.Additionally,wind speed variations are considered as unknown disturbances,thus eliminating the need for accurate measurement or estimation.The proposed ASMO enables the accurate estimation and reconstruction of the descriptor states and disturbances.The proposed design implements the principle of separation to enable the use of the nominal controller during faulty conditions.Fault tolerance is achieved by implementing a signal correction scheme to recover the nominal behavior.The performance of the proposed approach is validated using a 4.8 MW wind turbine benchmark model subject to various faults.Monte-Carlo analysis is also carried out to further evaluate the reliability and robustness of the proposed approach in the presence of measurement errors.Simplicity,ease of implementation and the decoupling property are among the positive features of the proposed approach.
基金Supported by Lanzhou Talent Innovation and Entrepreneurship Science and Technology Plan Project(2015-RC-22)
文摘[Objectives] To establish a high performance liquid chromatography (HPLC) wavelength switching method for the simultaneous determination of content of six constituents (phellodendrine chloride, gentiopicrin, paeoniflorin, tetrandrine, berberine hydrochloride and paeonol) in Cangbaiqutong capsules, and provide a scientific basis for the comprehensive evaluation of the quality of Cangbaiqutong capsule.[Methods] The chromatographic column of Waters XSELECT CSH-C 18 (4.6 mm × 150 mm, 5 μm), the mobile phase of acetonitrile-0.1% phosphate solution, gradient elution (0-15 min,10%-18% A;15-30 min,18%-50% A;30-35 min, 50%-10% A);the flow rate of 1.0 mL/min, wavelength switching of 284 (0-7 min, phellodendrine), 274 (7-10 min, gentiopicrin), 230 (10-14 min, paeoniflorin) and 274 nm (14-35 min, tetrandrine, berberine hydrochloride, paeonol), the injection volume of 10 μL.[Results] There was a good linear relationship between the area of chromatographic peak and the injection volume of phellodendrine chloride, gentiopicrin, paeoniflorin, tetrandrine, berberine hydrochloride and paeonol in the range of 0.150-1.504, 0.768-7.680, 1.096-10.960, 0.220-2.200, 0.296-2.956, 0.0345-0.345 μg, respectively;the average recovery rates ( n =6) were 98.3%, 99.2%, 98.8%, 98.8%, 99.1% and 98.2%, respectively;the RSD value was 1.32%, 1.46%, 1.08%, 1.31%, 1.26% and 1.21%, respectively.[Conclusions] The method can be used to determine many kinds of constituents at the same time, and the operation is simple, accurate and reproducible, and can be used for the quality control of compound Cangbaiqutong capsules.
基金supported by National Natural Science Foundation of China(No.61174064)National Basic Research Program of China(973 Program)(No.2012CB720502)
文摘This paper presents a simultaneous H2/H∞ stabilization problem for the chemical reaction systems which can be modeled as a finite collection of subsystems. A single dynamic output feedback controller which simultaneously stabilizes the multiple subsystems and captures the mixed H2/H∞ control performance is designed. To ensure that the stability condition, the H2 characterization and the H∞ characterization can be enforced within a unified matrix inequality framework, a novel technique based on orthogonal complement space is developed. Within such a framework, the controller gain is parameterized by the introduction of a common free positive definite matrix, which is independent of the multiple Lyapunov matrices. An iterative linear matrix inequality （ILMI） algorithm using Matlab Yalmip toolbox is established to deal with the proposed framework. Simulation results of a typical chemical reaction system are exploited to show the validity of the proposed methodology.
基金Supported by National Natural Science Foundation of China （60774011, 60674024）, Natural Science Foundation of Zhejiang Province （Y105141）, and Natural Science Foundation of Fujian Province （2008J0026）
文摘In this paper,the adaptive robust simultaneous stabilization problem of uncertain multiple n-degree-of-freedom(n-DOF)robot systems is studied using the Hamiltonian function method,and the corresponding adaptive L2 controller is designed.First,we investigate the adaptive simultaneous stabilization problem of uncertain multiple n-DOF robot systems without external disturbance.Namely,the single uncertain n-DOF robot system is transformed into an equivalent Hamiltonian form using the unified partial derivative operator(UP-DO)and potential energy shaping method,and then a high dimensional Hamiltonian system for multiple uncertain robot systems is obtained by applying augmented dimension technology,and a single output feedback controller is designed to ensure the simultaneous stabilization for the higher dimensional Hamiltonian system.On this basis,we further study the adaptive robust simultaneous stabilization control problem for the uncertain multiple n-DOF robot systems with external disturbances,and design an adaptive robust simultaneous stabilization controller.Finally,the simulation results show that the adaptive robust simultaneous stabilization controller designed in this paper is very effective in stabilizing multi-robot systems at the same time.
文摘The origins and main control methods of gas in coal seams were introduced cursorily, and the processes that need to be done in controlling gas, which includes prediction of gas emissions, drainage systems, the means of prevention of gas outbursts, and some suggestions were put forward. The characteristic of different gas emissions and the corresponding counter measures were presented, and ＆ case study of simultaneous extraction of coal and gas in Xieyi Coal Mine was carried out by coal mining and gas extraction without coal-pillar. The field application shows that gas drainage ratio in panel 5121（0） averages about 90% and reaches as high as 95~/0, which will give beneficial references to gas control in coal mines.
文摘Coal bed methane control with low permeability is a hot issue at present. The current status of coal bed methane control in China is introduced. The government-support policies on coal bed methane control are presented. This paper proposes the theories of methane control in depressurized mining, including methane extraction in depressurized mining, simultaneous mining technique of coal and methane without coal pillar, and circular overlying zone for high-efficiency methane extraction in coal seams with low permeability. The techniques of methane control and related instruments and equipments in China are introduced. On this basis, the problems related to coal bed methane control are addressed and further studies are pointed out.
文摘Chiral molecules, which may contain one or more different type（s） of stereocentres, such as central, axial, planar, and helical chiralities, etc., are indispensable in chemistry, pharmaceutical industry, and life science. Despite many advances for the preparation of chiral molecules usually with a single type of chirality have been realized, simultaneous construction of different types of chiralities is still a significant challenge. Here, we wish to report a protocol for preparation of chiral allenes with both central and axial chiralities via a catalytic asymmetric allenylation of different biologically or syn- thetically useful fluorinated or non-fluorinated nucleophiles with readily available racemic allenes by using a single chiral ligand. An echoing between the central chirality and axial chirality for the enantioselectivity was observed. This strategy provides a general and practical approach to functionalized optically active allenes bearing both central and axial chiralities with an excellent enantioselectivity under mild conditions.
