Samples of the Cambrian microbial dolomites were collected from Penglaiba section,a well-exposed stratigraphic section in the northwestern area of the Tarim Basin.This study provides an analogue for mediated dolomites...Samples of the Cambrian microbial dolomites were collected from Penglaiba section,a well-exposed stratigraphic section in the northwestern area of the Tarim Basin.This study provides an analogue for mediated dolomites that can precipitate in microbial mats and biofilms.The Cambrian stromatolitic dolomites were studied using high-resolution scanning electron microscopy.The results are as follows:(1)dolomites with 50 nm to 100 nm spherical nanostructures are aggregated into minerals of larger sphericities;(2)nanospherical dolomites of 50 nm to 170 nm diameter are densely arranged as dumbbell-shaped or chained aggregates;(3)silicified filaments,as well as dumbbell-shaped and chain arrangements,are preserved as important microstructures.On the basis of sedimentological,compositional,geochemical,and petrographic data,the microstructures were interpreted as nanoglobules that function as bacteria in the nucleation and filament mineralization stages.The microstructures function as such because they are wrapped in extracellular polymeric substance(EPS)or mucus and mineralized fossils.Silicification accounts for the exceptional preservation of microbial mat structures,including biofilms,as well as filamentous and coccoid microbes.In addition,EPS process is capable of binding different elements,with preference for Si,Mg,and Ca.Such suitable composition favors microbe mineralization and dolomite nucleation on organic substrates.These microscopic structures suggest bacterial mineralization and provide visual evidence for the origin of microbial dolomites.展开更多
IN zoology, the developmental stage of individual from zygote to hatching was called embryo. The modem embryology is a branch of study on the organism’ s embryos. The palaeoembryology is a new field in palaeontology,...IN zoology, the developmental stage of individual from zygote to hatching was called embryo. The modem embryology is a branch of study on the organism’ s embryos. The palaeoembryology is a new field in palaeontology, and it has not been considered an important field before, because the invertebrate’s eggs or embryos are minute size and without mineralized envelope. Until now, fossilized eggs of invertebrates in Cambrian have been rarely reported and most of them are small globular structures without recognizable features. Other reported fossilized embryos found from Middle Cambrian are spherical with a展开更多
This report is about the first record of non-avian dinosaur eggs in the Hefei Basin,Anhui Province,China.Based on the combination of elongated egg body,linear ridges on the outer surface and two structure layer,the eg...This report is about the first record of non-avian dinosaur eggs in the Hefei Basin,Anhui Province,China.Based on the combination of elongated egg body,linear ridges on the outer surface and two structure layer,the eggs can be referred to Elongatoolithidae.The gradual boundary between the cone and the column layers as well as the relative thin eggshell(less than 1 mm)indicates its affinity within Elongatoolithus.The eggs are identified as Elongatoolithus oosp.,as they were severely compressed and experienced erosion on both inner and outer surfaces.The discovery of egg fossil in the Hefei Basin offers evidence for stratum comparison in this region and supplements the diversity of egg fossils in Anhui.Meanwhile,this discovery also enriches the paleogeographic distribution of elongatoolithids.展开更多
The micromammal fossils collected from the Shangzhuang Formation of the Linxia Basin,Gansu,are described here.The assemblage consists of 16 species of 13 genera belonging to 7 families,including one new species and on...The micromammal fossils collected from the Shangzhuang Formation of the Linxia Basin,Gansu,are described here.The assemblage consists of 16 species of 13 genera belonging to 7 families,including one new species and one taxon previously unknown from China.Among them 5 genera are Oligocene holdovers and 11 genera/species are known to make their first appearances in Early Miocene,indicating an Early Miocene age for the Gucheng Fauna.The absence of Oligocene survivors such as Tataromys,Yindirtemys,Eucricetodon and Tachyoryctoides,which usually occur in the Xiejian age of Early Miocene,and the presence of newcomers Protalactaga,Megacricetodon and Gobicricetodon,that made their first appearance only in the Shanwangian age of late Early Miocene,suggest that the Gucheng Fauna is of a later age of Early Miocene.The new species,Sinolagomys guchengensis,showing more derived morphology than in S.ulunguensis,seems to support an assessment of the fauna in Shanwangian age.Thus,the Gucheng Fauna may belong to late Early Miocene Shanwangian,partially equivalent to MN 3/4 of the European land mammal zonation.Ecological analysis of the fauna indicates that the palaeoecological condition of the Gucheng area might still be a predominantly arid shrub-steppe in late Early Miocene.展开更多
Beginning from the industrial revolution,non-renewable fossil fuels have powered the population growth and economic expansion.However,the overdependence of such energy sources leads to serious eco-crisis and energy se...Beginning from the industrial revolution,non-renewable fossil fuels have powered the population growth and economic expansion.However,the overdependence of such energy sources leads to serious eco-crisis and energy security issues.As shown in Fig.1,the emissions of CO_(2) greenhouse gas are rising year by year because of the significant amount consumption of fossil energy[1].Searching sustainable energy technologies to achieve carbon neutrality has thus become an urgent task for the future of human society[2].As the most abundant and inexhaustible energy source,sunlight has brought dawn to the opportunities for a sustainable society.Owing to the diurnal and seasonal cycles,the solar energy has the intermittent character,which limits its applications.展开更多
The fossil shells on the sedimentary rocks were collected from The Historical Park,Ban Sap Noi Geopark,Phetchabun Province,Thailand.However,the fossils remained in this area were investigated on the characteristic spe...The fossil shells on the sedimentary rocks were collected from The Historical Park,Ban Sap Noi Geopark,Phetchabun Province,Thailand.However,the fossils remained in this area were investigated on the characteristic species only in geological studies with taxonomy for fossil age predicting.To fill up the gap of these studies,the material characterization techniques were used to study the chemical composition and structure of fossil shells I,II and III.The results clearly showed that the morphologies of all fossil shells were Brachiopod fossils with different species.The functional group and elemental composition of all fossil shells showed that the high content of calcium carbonate was a major composition.In addition,the high content of quartz indicated the silica precipitation phenomenon in all fossil shells.The element composition of cross-sectional morphology and energy dispersive spectroscope (EDS mapping) were used to confirm the presence of Si element in each zone of fossil shells.The crystal structures of all fossil shells were investigated and indicated that the calcium carbonate compound was a calcite phase and silicon dioxide compound was a quartz phase.Moreover,the crystal structure of quartz phase was used to calculate the crystallinity index.The crystallinity index values in all fossil shells indicated a well-crystallized quartz.The age of fossil shells was estimated and found to be brachiopod fossil in carboniferous period with the age of about 359.2 to 299.0 million years.展开更多
In the past century,industrial and economic growth relied heavily on fossil fuels such as coal,oil,and natural gas.As the society energy demands continue to grow,these fossil fuel reserves are depleted,leading to sign...In the past century,industrial and economic growth relied heavily on fossil fuels such as coal,oil,and natural gas.As the society energy demands continue to grow,these fossil fuel reserves are depleted,leading to significant environmental issues[1].Currently,sustainable biomass resources have attracted much attention as potential substitutes to fossil fuels for producing biofuels and commodity chemicals[2].展开更多
The Late Cretaceous global transgression is one of the best documented episodes of continental submergence events.The extent of transgression of the Neotethys Ocean into the African continent is generally thought to b...The Late Cretaceous global transgression is one of the best documented episodes of continental submergence events.The extent of transgression of the Neotethys Ocean into the African continent is generally thought to be limited to north Africa.Here,we describe transgression traces in the Muglad Basin in central Africa that indicate a greater spatial extend of the Neotethys during the late Cretaceous.A series of molecular markers detected in the Upper Cretaceous Santonian-Maastrichtian sediments of the Muglad Basin are typical for marine depositional conditions and differ from those in the typical lacustrine sediments of the Lower Cretaceous Barremian-Aptian.Combining the geological-geochemical implications of these markers with the paleogeographic,paleontological and lithological records,we propose that the Muglad Basin received intermittent marine inundations during the Santonian-Maastrichtian stages(86.3-66.0 Ma)and these special molecular markers are therefore the products of seawater incursion.Consequently,this study proposes that the transgression extent of the Neotethys Ocean into the African continent southern extended to the central Africa during the Late Cretaceous.展开更多
Evergreen broad-leaved forests(EBLFs) are widely distributed in East Asia and play a vital role in ecosystem stability. The occurrence of these forests in East Asia has been a subject of debate across various discipli...Evergreen broad-leaved forests(EBLFs) are widely distributed in East Asia and play a vital role in ecosystem stability. The occurrence of these forests in East Asia has been a subject of debate across various disciplines. In this study, we explored the occurrence of East Asian EBLFs from a paleobotanical perspective. By collecting plant fossils from four regions in East Asia, we have established the evolutionary history of EBLFs. Through floral similarity analysis and paleoclimatic reconstruction, we have revealed a diverse spatio-temporal pattern for the occurrence of EBLFs in East Asia. The earliest occurrence of EBLFs in southern China can be traced back to the middle Eocene, followed by southwestern China during the late Eocene-early Oligocene. Subsequently, EBLFs emerged in Japan during the early Oligocene and eventually appeared in central-eastern China around the Miocene. Paleoclimate simulation results suggest that the precipitation of wettest quarter(PWet Q, mm) exceeding 600 mm is crucial for the occurrence of EBLFs. Furthermore, the heterogeneous occurrence of EBLFs in East Asia is closely associated with the evolution of the Asian Monsoon. This study provides new insights into the occurrence of EBLFs in East Asia.展开更多
Carbon Capture,Utilization,and Storage(CCUS)is a crucial technology for achieving carbon neutrality,but it faces significant challenges.Despite substantial investments and policy support,CCUS projects have underperfor...Carbon Capture,Utilization,and Storage(CCUS)is a crucial technology for achieving carbon neutrality,but it faces significant challenges.Despite substantial investments and policy support,CCUS projects have underperformed due to technical difficulties,high costs,and controversies surrounding the fossil fuel industry's involvement.The effectiveness and feasibility of CCUS in reducing carbon emissions remain uncertain.This viewpoint provides a comprehensive analysis of the current state of CCUS technology,examining its potential to reduce carbon emissions,the challenges hindering its deployment,and the strategies needed to overcome these barriers.We discuss the need for a combinatorial approach to unlock CCUS's full potential,and also emphasize the importance of selecting optimal CO_(2)utilization pathways to maximize economic benefits and CO_(2)absorption.Although CCUS faces technical,economic,and social barriers,it can still play a valuable role in mitigating emissions from hard-to-abate sectors when supported by comprehensive strategies and collaborative efforts among governments,industries,and research institutions.By addressing these challenges and investing in innovation,CCUS can contribute to achieving carbon neutrality and building a sustainable,low-carbon future.展开更多
The increasing dependence on fossil fuels and the consequent CO_(2)emissions have prompted urgent energy and environmental challenges[1,2].Solar-driven CO_(2)conversion into value-added fuels offers a sustainable and ...The increasing dependence on fossil fuels and the consequent CO_(2)emissions have prompted urgent energy and environmental challenges[1,2].Solar-driven CO_(2)conversion into value-added fuels offers a sustainable and promising solution to these issues[3].However,the practical implementation of CO_(2)photoreduction is constrained by low efficiency,primarily due to the rapid recombination of photogenerated electron-hole pairs[4].展开更多
The challenge of establishing top-down constraints for regional emissions of fossil fuel CO_(2)(FFCO_(2))arises from the difficulty in distinguishing between atmospheric CO_(2)concentrations released from fossil fuels...The challenge of establishing top-down constraints for regional emissions of fossil fuel CO_(2)(FFCO_(2))arises from the difficulty in distinguishing between atmospheric CO_(2)concentrations released from fossil fuels and background variability,particularly owing to the influence of terrestrial biospheric fluxes.This necessitates the development of a regional inversion methodology based on atmospheric CO_(2)observations to verify bottom-up estimations independently.This study presents a promising approach for estimating China's FFCO_(2)emissions by incorporating the model residual errors(MREs)of the column-averaged dry-air mole fractions of CO_(2)(XCO_(2))from FFCO_(2)emissions(MREff)retained in the analysis of natural flux optimization.China's FFCO_(2)emissions during the COVID-19 lockdown in 2020 are estimated using the GEOS-Chem adjoint model.The relationship between the MREff and FFCO_(2)is determined using the model based on a regional FFCO_(2)anomaly suggested by posterior NOx emissions from air-quality data assimilation.The MREff is typically one-tenth in magnitude,but some positively skewed outliers exceed 1 ppm because the prior emissions lack lockdown impacts,thereby exerting considerable observation forcing given the satellite retrieval uncertainties.We initialize the FFCO_(2)with posterior NOx emissions and optimize the colinear emission ratio.Synthetic data experiments demonstrate that this approach reduces the FFCO_(2)bias to less than 10%.The real-data experiments estimate 19%lower FFCO_(2)with GOSAT XCO_(2)and 26%lower with OCO-2 XCO_(2)than the bottom-up estimations.This study proves the feasibility of our regional FFCO_(2)inversion,highlighting the importance of addressing the outlier behaviors observed in satellite XCO_(2)retrievals.展开更多
The ultra-deep(deeper than 8000 m)petroleum in the platform-basin zones of the Tarim Basin has been found mainly in the Lower Paleozoic reservoirs located to the east of the strike-slip fault F5 in the north depressio...The ultra-deep(deeper than 8000 m)petroleum in the platform-basin zones of the Tarim Basin has been found mainly in the Lower Paleozoic reservoirs located to the east of the strike-slip fault F5 in the north depression.However,the source and exploration potential of the ultra-deep petroleum in the Cambrian on the west of F5 are still unclear.Through the analysis of lithofacies and biomarkers,it is revealed that there are at least three kinds of isochronous source rocks(SRs)in the Cambrian Newfoundland Series in Tarim Basin,which were deposited in three sedimentary environments,i.e.sulfide slope,deep-water shelf and restricted bay.In 2024,Well XT-1 in the western part of northern Tarim Basin has yielded a high production of condensate from the Cambrian.In the produced oil,entire aryl-isoprenoid alkane biomarkers were detected,but triaromatic dinosterane was absent.This finding is well consistent with the geochemical characteristics of the Newfoundland sulfidized slope SRs represented by those in wells LT-1 and QT-1,suggesting that the Newfoundland SRs are the main source of the Cambrian petroleum discovered in Well XT-1.Cambrian crude oil of Well XT-1 also presents the predominance of C29 steranes and is rich in long-chain tricyclic terpanes(up to C39),which can be the indicators for effectively distinguishing lithofacies such as siliceous mudstone and carbonate rock.Combined with the analysis of hydrocarbon accumulation in respect of conduction systems including thrust fault and strike-slip fault,it is found that the area to the west of F5 is possible to receive effective supply of hydrocarbons from the Cambrian Newfoundland SRs in Manxi hydrocarbon-generation center.This finding suggests that the area to the west of F5 will be a new target of exploration in the Cambrian ultra-deep structural-lithologic reservoirs in the Tarim Basin,in addition to the Cambrian ultra-deep platform-margin facies-controlled reservoirs in the eastern part of the basin.展开更多
While the significant role of technological innovation in promoting renewable energy has been extensively explored in the literature,limited attention has been paid to the impact of energy patents,particularly clean e...While the significant role of technological innovation in promoting renewable energy has been extensively explored in the literature,limited attention has been paid to the impact of energy patents,particularly clean energy patents and fossil fuel patents.This study pioneers an investigation into the effects of energy patents and energy prices on renewable energy consumption.The study utilizes data from 2000Q1 to 2023Q4 and,due to the nonlinear nature of the series,applies wavelet quantile-based methods.Specifically,it introduces the wavelet quantile cointegration approach to evaluate cointegration across different quantiles and time horizons,along with the wavelet quantile-on-quantile regression method.The results confirm cointegration across different periods and quantiles,highlighting the significant relationships between energy patents,economic factors,and renewable energy consumption.Furthermore,we found that fossil energy patents negatively affect renewable energy consumption,while clean energy patents have a similar but weaker effect,especially in the short term.In addition,higher energy prices promote renewable energy adoption while economic growth positively influences renewable energy consumption,particularly in the short term.The study formulates specific policies based on these findings.展开更多
Global climate change has become one of the most pressing challenges of the 21st century.As anthropogenic CO_(2) emissions from fossil fuel consumption and industrial processes continue to disrupt Earth’s carbon cycl...Global climate change has become one of the most pressing challenges of the 21st century.As anthropogenic CO_(2) emissions from fossil fuel consumption and industrial processes continue to disrupt Earth’s carbon cycle,atmospheric CO_(2) concentrations have reached unprecedented levels-exceeding 420 parts per million(ppm)in 2023 compared to pre-industrial 280 ppm.This rapid accumulation of greenhouse gases has resulted in measurable con-sequences including rising global temperatures,ocean acidifica-tion,and increased frequency of extreme weather events.展开更多
Small shelly fossils(SSFs)have long been recognized as important to the studies of both metazoan evolution and the onset of biomineralization during the Cambrian radiation.The marked decline in the occurrence,diversit...Small shelly fossils(SSFs)have long been recognized as important to the studies of both metazoan evolution and the onset of biomineralization during the Cambrian radiation.The marked decline in the occurrence,diversity and abundance of SSFs in the middle to late Cambrian,when compared with the early Cambrian,has often been regarded as a result of the closure of a phosphatization window.Despite this,there have been numerous and consistent reports of SSFs from the middle Cambrian and younger deposits.To identify possible factors influencing SSF preservation,five microfacies including bioclastic limestone,flat-pebble conglomerates with bioclasts,hummocky cross-stratified grainstone with bioclasts,bioclastic grainstone in hardgrounds and glauconite bioclastic wackstone-packstone,from Cambrian Series 2 to Miaolingian in North China are compared to assess how differences in lithology impact the preservation potential of SSFs.Our results,based on 35,161 SSF specimens from deposits across six sections,suggest that there are still abundant and diverse SSFs in the middle Cambrian of North China preserved in ways not exclusively reliant on the presence of phosphate and that SSF preservation can be linked to the differences in microfacies in the early to middle Cambrian of North China.展开更多
基金financially supported by the National Natural Science Foundation of China(Grant No.41402102)Fundamental Research Funds for the Central Universities(Grant No.2652014001)+1 种基金the National Science and Technology Major Project of the Ministry of Science and Technology of China(Grant No.2011ZX05005–002–008HZ)National Basic Research Program of China(Grant No.2011CB201100–03)
文摘Samples of the Cambrian microbial dolomites were collected from Penglaiba section,a well-exposed stratigraphic section in the northwestern area of the Tarim Basin.This study provides an analogue for mediated dolomites that can precipitate in microbial mats and biofilms.The Cambrian stromatolitic dolomites were studied using high-resolution scanning electron microscopy.The results are as follows:(1)dolomites with 50 nm to 100 nm spherical nanostructures are aggregated into minerals of larger sphericities;(2)nanospherical dolomites of 50 nm to 170 nm diameter are densely arranged as dumbbell-shaped or chained aggregates;(3)silicified filaments,as well as dumbbell-shaped and chain arrangements,are preserved as important microstructures.On the basis of sedimentological,compositional,geochemical,and petrographic data,the microstructures were interpreted as nanoglobules that function as bacteria in the nucleation and filament mineralization stages.The microstructures function as such because they are wrapped in extracellular polymeric substance(EPS)or mucus and mineralized fossils.Silicification accounts for the exceptional preservation of microbial mat structures,including biofilms,as well as filamentous and coccoid microbes.In addition,EPS process is capable of binding different elements,with preference for Si,Mg,and Ca.Such suitable composition favors microbe mineralization and dolomite nucleation on organic substrates.These microscopic structures suggest bacterial mineralization and provide visual evidence for the origin of microbial dolomites.
文摘IN zoology, the developmental stage of individual from zygote to hatching was called embryo. The modem embryology is a branch of study on the organism’ s embryos. The palaeoembryology is a new field in palaeontology, and it has not been considered an important field before, because the invertebrate’s eggs or embryos are minute size and without mineralized envelope. Until now, fossilized eggs of invertebrates in Cambrian have been rarely reported and most of them are small globular structures without recognizable features. Other reported fossilized embryos found from Middle Cambrian are spherical with a
文摘This report is about the first record of non-avian dinosaur eggs in the Hefei Basin,Anhui Province,China.Based on the combination of elongated egg body,linear ridges on the outer surface and two structure layer,the eggs can be referred to Elongatoolithidae.The gradual boundary between the cone and the column layers as well as the relative thin eggshell(less than 1 mm)indicates its affinity within Elongatoolithus.The eggs are identified as Elongatoolithus oosp.,as they were severely compressed and experienced erosion on both inner and outer surfaces.The discovery of egg fossil in the Hefei Basin offers evidence for stratum comparison in this region and supplements the diversity of egg fossils in Anhui.Meanwhile,this discovery also enriches the paleogeographic distribution of elongatoolithids.
文摘The micromammal fossils collected from the Shangzhuang Formation of the Linxia Basin,Gansu,are described here.The assemblage consists of 16 species of 13 genera belonging to 7 families,including one new species and one taxon previously unknown from China.Among them 5 genera are Oligocene holdovers and 11 genera/species are known to make their first appearances in Early Miocene,indicating an Early Miocene age for the Gucheng Fauna.The absence of Oligocene survivors such as Tataromys,Yindirtemys,Eucricetodon and Tachyoryctoides,which usually occur in the Xiejian age of Early Miocene,and the presence of newcomers Protalactaga,Megacricetodon and Gobicricetodon,that made their first appearance only in the Shanwangian age of late Early Miocene,suggest that the Gucheng Fauna is of a later age of Early Miocene.The new species,Sinolagomys guchengensis,showing more derived morphology than in S.ulunguensis,seems to support an assessment of the fauna in Shanwangian age.Thus,the Gucheng Fauna may belong to late Early Miocene Shanwangian,partially equivalent to MN 3/4 of the European land mammal zonation.Ecological analysis of the fauna indicates that the palaeoecological condition of the Gucheng area might still be a predominantly arid shrub-steppe in late Early Miocene.
基金supported by the National Natural Science Foundation of China(No.52202321)the Starting Research Funds of Hefei University of Technology.
文摘Beginning from the industrial revolution,non-renewable fossil fuels have powered the population growth and economic expansion.However,the overdependence of such energy sources leads to serious eco-crisis and energy security issues.As shown in Fig.1,the emissions of CO_(2) greenhouse gas are rising year by year because of the significant amount consumption of fossil energy[1].Searching sustainable energy technologies to achieve carbon neutrality has thus become an urgent task for the future of human society[2].As the most abundant and inexhaustible energy source,sunlight has brought dawn to the opportunities for a sustainable society.Owing to the diurnal and seasonal cycles,the solar energy has the intermittent character,which limits its applications.
基金supported by the Science Achievement Scholarship of Thailand (SAST)the support of Office of Atom for Peace,Thailand and Thailand Institute of Nuclear Technology (a public organization) for providing facilities for some experiment in this work。
文摘The fossil shells on the sedimentary rocks were collected from The Historical Park,Ban Sap Noi Geopark,Phetchabun Province,Thailand.However,the fossils remained in this area were investigated on the characteristic species only in geological studies with taxonomy for fossil age predicting.To fill up the gap of these studies,the material characterization techniques were used to study the chemical composition and structure of fossil shells I,II and III.The results clearly showed that the morphologies of all fossil shells were Brachiopod fossils with different species.The functional group and elemental composition of all fossil shells showed that the high content of calcium carbonate was a major composition.In addition,the high content of quartz indicated the silica precipitation phenomenon in all fossil shells.The element composition of cross-sectional morphology and energy dispersive spectroscope (EDS mapping) were used to confirm the presence of Si element in each zone of fossil shells.The crystal structures of all fossil shells were investigated and indicated that the calcium carbonate compound was a calcite phase and silicon dioxide compound was a quartz phase.Moreover,the crystal structure of quartz phase was used to calculate the crystallinity index.The crystallinity index values in all fossil shells indicated a well-crystallized quartz.The age of fossil shells was estimated and found to be brachiopod fossil in carboniferous period with the age of about 359.2 to 299.0 million years.
基金funded by the Master,PhD Scholarship Programme of Vingroup Innovation Foundation(VINIF),code VINIF.2024.TS.035funded by Vietnam National University,Ho Chi Minh City(VNUHCM)under grant number NCM2024-18-01。
文摘In the past century,industrial and economic growth relied heavily on fossil fuels such as coal,oil,and natural gas.As the society energy demands continue to grow,these fossil fuel reserves are depleted,leading to significant environmental issues[1].Currently,sustainable biomass resources have attracted much attention as potential substitutes to fossil fuels for producing biofuels and commodity chemicals[2].
基金supported by the National Natural Science Foundation of China(No.42202134)Science Foundation of China University of Petroleum,Beijing(No.2462023YJRC010)the postdoctoral fellowship by the Central Research and Development Fund of the University of Bremen.The authors would like to thank the editor and the two anonymous reviewers for their constructive comments and suggestions which significantly improved the quality of the manuscript.
文摘The Late Cretaceous global transgression is one of the best documented episodes of continental submergence events.The extent of transgression of the Neotethys Ocean into the African continent is generally thought to be limited to north Africa.Here,we describe transgression traces in the Muglad Basin in central Africa that indicate a greater spatial extend of the Neotethys during the late Cretaceous.A series of molecular markers detected in the Upper Cretaceous Santonian-Maastrichtian sediments of the Muglad Basin are typical for marine depositional conditions and differ from those in the typical lacustrine sediments of the Lower Cretaceous Barremian-Aptian.Combining the geological-geochemical implications of these markers with the paleogeographic,paleontological and lithological records,we propose that the Muglad Basin received intermittent marine inundations during the Santonian-Maastrichtian stages(86.3-66.0 Ma)and these special molecular markers are therefore the products of seawater incursion.Consequently,this study proposes that the transgression extent of the Neotethys Ocean into the African continent southern extended to the central Africa during the Late Cretaceous.
基金supported by National Key R&D Program of China(No.2022YFF0800800)National Science Fund for Distinguished Young Scholars(No.32225005)+3 种基金National Natural Science Foundation of China(NSFC)(Nos.42072024,42320104005,42372033)the Young and Middle-aged Academic and Technical Leaders of Yunnan(No.202305AC160051)Basic Research Project of Yunnan Province(No.202401AT070222)the 14th Five-Year Plan of the Xishuangbanna Tropical Botanical Garden,Chinese Academy of Sciences(Nos.XTBG-1450101,E3ZKFF7B).
文摘Evergreen broad-leaved forests(EBLFs) are widely distributed in East Asia and play a vital role in ecosystem stability. The occurrence of these forests in East Asia has been a subject of debate across various disciplines. In this study, we explored the occurrence of East Asian EBLFs from a paleobotanical perspective. By collecting plant fossils from four regions in East Asia, we have established the evolutionary history of EBLFs. Through floral similarity analysis and paleoclimatic reconstruction, we have revealed a diverse spatio-temporal pattern for the occurrence of EBLFs in East Asia. The earliest occurrence of EBLFs in southern China can be traced back to the middle Eocene, followed by southwestern China during the late Eocene-early Oligocene. Subsequently, EBLFs emerged in Japan during the early Oligocene and eventually appeared in central-eastern China around the Miocene. Paleoclimate simulation results suggest that the precipitation of wettest quarter(PWet Q, mm) exceeding 600 mm is crucial for the occurrence of EBLFs. Furthermore, the heterogeneous occurrence of EBLFs in East Asia is closely associated with the evolution of the Asian Monsoon. This study provides new insights into the occurrence of EBLFs in East Asia.
基金funding from the National Natural Science Foundation of China(62074123)Key Research and Development Plan of Shaanxi Province(No.2024GXZDCYL-01-06)China National Petroleum Corporation(CNPC)Basic Research and Strategic Reserve Technology Research Fund Project(No.2023DQ03-26).
文摘Carbon Capture,Utilization,and Storage(CCUS)is a crucial technology for achieving carbon neutrality,but it faces significant challenges.Despite substantial investments and policy support,CCUS projects have underperformed due to technical difficulties,high costs,and controversies surrounding the fossil fuel industry's involvement.The effectiveness and feasibility of CCUS in reducing carbon emissions remain uncertain.This viewpoint provides a comprehensive analysis of the current state of CCUS technology,examining its potential to reduce carbon emissions,the challenges hindering its deployment,and the strategies needed to overcome these barriers.We discuss the need for a combinatorial approach to unlock CCUS's full potential,and also emphasize the importance of selecting optimal CO_(2)utilization pathways to maximize economic benefits and CO_(2)absorption.Although CCUS faces technical,economic,and social barriers,it can still play a valuable role in mitigating emissions from hard-to-abate sectors when supported by comprehensive strategies and collaborative efforts among governments,industries,and research institutions.By addressing these challenges and investing in innovation,CCUS can contribute to achieving carbon neutrality and building a sustainable,low-carbon future.
文摘The increasing dependence on fossil fuels and the consequent CO_(2)emissions have prompted urgent energy and environmental challenges[1,2].Solar-driven CO_(2)conversion into value-added fuels offers a sustainable and promising solution to these issues[3].However,the practical implementation of CO_(2)photoreduction is constrained by low efficiency,primarily due to the rapid recombination of photogenerated electron-hole pairs[4].
基金jointly supported by the National Key Research and Development Plan(Grant No.2023YFB3907405)the National Natural Science Foundation of China(Grant No.42175132)the Chinese Academy of Sciences Project for Young Scientists in Basic Research(Grant No.YSBR-037)。
文摘The challenge of establishing top-down constraints for regional emissions of fossil fuel CO_(2)(FFCO_(2))arises from the difficulty in distinguishing between atmospheric CO_(2)concentrations released from fossil fuels and background variability,particularly owing to the influence of terrestrial biospheric fluxes.This necessitates the development of a regional inversion methodology based on atmospheric CO_(2)observations to verify bottom-up estimations independently.This study presents a promising approach for estimating China's FFCO_(2)emissions by incorporating the model residual errors(MREs)of the column-averaged dry-air mole fractions of CO_(2)(XCO_(2))from FFCO_(2)emissions(MREff)retained in the analysis of natural flux optimization.China's FFCO_(2)emissions during the COVID-19 lockdown in 2020 are estimated using the GEOS-Chem adjoint model.The relationship between the MREff and FFCO_(2)is determined using the model based on a regional FFCO_(2)anomaly suggested by posterior NOx emissions from air-quality data assimilation.The MREff is typically one-tenth in magnitude,but some positively skewed outliers exceed 1 ppm because the prior emissions lack lockdown impacts,thereby exerting considerable observation forcing given the satellite retrieval uncertainties.We initialize the FFCO_(2)with posterior NOx emissions and optimize the colinear emission ratio.Synthetic data experiments demonstrate that this approach reduces the FFCO_(2)bias to less than 10%.The real-data experiments estimate 19%lower FFCO_(2)with GOSAT XCO_(2)and 26%lower with OCO-2 XCO_(2)than the bottom-up estimations.This study proves the feasibility of our regional FFCO_(2)inversion,highlighting the importance of addressing the outlier behaviors observed in satellite XCO_(2)retrievals.
基金Supported by the CNPC Science and Technology Project(2024ZZ0203)。
文摘The ultra-deep(deeper than 8000 m)petroleum in the platform-basin zones of the Tarim Basin has been found mainly in the Lower Paleozoic reservoirs located to the east of the strike-slip fault F5 in the north depression.However,the source and exploration potential of the ultra-deep petroleum in the Cambrian on the west of F5 are still unclear.Through the analysis of lithofacies and biomarkers,it is revealed that there are at least three kinds of isochronous source rocks(SRs)in the Cambrian Newfoundland Series in Tarim Basin,which were deposited in three sedimentary environments,i.e.sulfide slope,deep-water shelf and restricted bay.In 2024,Well XT-1 in the western part of northern Tarim Basin has yielded a high production of condensate from the Cambrian.In the produced oil,entire aryl-isoprenoid alkane biomarkers were detected,but triaromatic dinosterane was absent.This finding is well consistent with the geochemical characteristics of the Newfoundland sulfidized slope SRs represented by those in wells LT-1 and QT-1,suggesting that the Newfoundland SRs are the main source of the Cambrian petroleum discovered in Well XT-1.Cambrian crude oil of Well XT-1 also presents the predominance of C29 steranes and is rich in long-chain tricyclic terpanes(up to C39),which can be the indicators for effectively distinguishing lithofacies such as siliceous mudstone and carbonate rock.Combined with the analysis of hydrocarbon accumulation in respect of conduction systems including thrust fault and strike-slip fault,it is found that the area to the west of F5 is possible to receive effective supply of hydrocarbons from the Cambrian Newfoundland SRs in Manxi hydrocarbon-generation center.This finding suggests that the area to the west of F5 will be a new target of exploration in the Cambrian ultra-deep structural-lithologic reservoirs in the Tarim Basin,in addition to the Cambrian ultra-deep platform-margin facies-controlled reservoirs in the eastern part of the basin.
文摘While the significant role of technological innovation in promoting renewable energy has been extensively explored in the literature,limited attention has been paid to the impact of energy patents,particularly clean energy patents and fossil fuel patents.This study pioneers an investigation into the effects of energy patents and energy prices on renewable energy consumption.The study utilizes data from 2000Q1 to 2023Q4 and,due to the nonlinear nature of the series,applies wavelet quantile-based methods.Specifically,it introduces the wavelet quantile cointegration approach to evaluate cointegration across different quantiles and time horizons,along with the wavelet quantile-on-quantile regression method.The results confirm cointegration across different periods and quantiles,highlighting the significant relationships between energy patents,economic factors,and renewable energy consumption.Furthermore,we found that fossil energy patents negatively affect renewable energy consumption,while clean energy patents have a similar but weaker effect,especially in the short term.In addition,higher energy prices promote renewable energy adoption while economic growth positively influences renewable energy consumption,particularly in the short term.The study formulates specific policies based on these findings.
文摘Global climate change has become one of the most pressing challenges of the 21st century.As anthropogenic CO_(2) emissions from fossil fuel consumption and industrial processes continue to disrupt Earth’s carbon cycle,atmospheric CO_(2) concentrations have reached unprecedented levels-exceeding 420 parts per million(ppm)in 2023 compared to pre-industrial 280 ppm.This rapid accumulation of greenhouse gases has resulted in measurable con-sequences including rising global temperatures,ocean acidifica-tion,and increased frequency of extreme weather events.
基金supported by the National Key Research and Development Program of China(Grant No.2023YFF0803600)National Natural Science Foundation of China(Grant Nos.42302009,42072003,and W2441016)+3 种基金HYZ thanks the Shaanxi Province postdoctoral research project and China Scholarship Council(202306970031)We also thank the Department of Science and Technology of Shaanxi Province(2022TD-11)TPT also acknowledges the Swedish Research Council(VR2017-05183 and VR2021-04295)This is also a contribution to the project of Theory of Hydrocarbon Enrichment under MultiSpheric Interactions of the Earth(THEMSIE04010106).
文摘Small shelly fossils(SSFs)have long been recognized as important to the studies of both metazoan evolution and the onset of biomineralization during the Cambrian radiation.The marked decline in the occurrence,diversity and abundance of SSFs in the middle to late Cambrian,when compared with the early Cambrian,has often been regarded as a result of the closure of a phosphatization window.Despite this,there have been numerous and consistent reports of SSFs from the middle Cambrian and younger deposits.To identify possible factors influencing SSF preservation,five microfacies including bioclastic limestone,flat-pebble conglomerates with bioclasts,hummocky cross-stratified grainstone with bioclasts,bioclastic grainstone in hardgrounds and glauconite bioclastic wackstone-packstone,from Cambrian Series 2 to Miaolingian in North China are compared to assess how differences in lithology impact the preservation potential of SSFs.Our results,based on 35,161 SSF specimens from deposits across six sections,suggest that there are still abundant and diverse SSFs in the middle Cambrian of North China preserved in ways not exclusively reliant on the presence of phosphate and that SSF preservation can be linked to the differences in microfacies in the early to middle Cambrian of North China.
