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Directional Three‑Dimensional Macroporous Carbon Foams Decorated with WC_(1−x)Nanoparticles Derived from Salting‑Out Protein Assemblies for Highly Effective Electromagnetic Absorption
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作者 Yongzheng Chen Lixue Gai +5 位作者 Bo Hu Yan Wang Yanyi Chen Xijiang Han Ping Xu Yunchen Du 《Nano-Micro Letters》 2026年第3期1-21,共21页
Directional three-dimensional carbon-based foams are emerging as highly attractive candidates for promising electromagnetic wave absorbing materials(EWAMs)thanks to their unique architecture,but their construction usu... Directional three-dimensional carbon-based foams are emerging as highly attractive candidates for promising electromagnetic wave absorbing materials(EWAMs)thanks to their unique architecture,but their construction usually involves complex procedures and extremely depends on unidirectional freezing technique.Herein,we propose a groundbreaking approach that leverages the assemblies of salting-out protein induced by ammonium metatungstate(AM)as the precursor,and then acquire directional three-dimensional carbon-based foams through simple pyrolysis.The electrostatic interaction between AM and protein ensures well dispersion of WC_(1−x)nanoparticles on carbon frameworks.The content of WC_(1−x)nanoparticles can be rationally regulated by AM dosage,and it also affects the electromagnetic(EM)properties of final carbon-based foams.The optimized foam exhibits exceptional EM absorption performance,achieving a remarkable minimum reflection loss of−72.0 dB and an effective absorption bandwidth of 6.3 GHz when EM wave propagates parallel to the directional pores.Such performance benefits from the synergistic effects of macroporous architecture and compositional design.Although there is a directional dependence of EM absorption,radar stealth simulation demonstrates that these foams can still promise considerable reduction in radar cross section with the change of incident angle.Moreover,COMSOL simulation further identifies their good performance in preventing EM interference among different electronic components. 展开更多
关键词 3D macroporous carbon-based foams Directional pore channels Salting-out protein assemblies EM wave absorption Directional dependence
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Multifunctional rigid polyimide foams with outstanding EMI shielding and wave absorption via densification strategy 被引量:2
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作者 Yugen Wang Yuanyuan Zhong +4 位作者 Jiahao Kang Bilin Zhang Zhonglei Ma Qiangli Zhao Jianwei Li 《Journal of Materials Science & Technology》 2025年第24期155-163,共9页
The rapid development of modern 5G technology has significantly increased the demand for multifunctional electromagnetic interference(EMI)shielding and wave-absorbing materials.Hence,a densification strategy was propo... The rapid development of modern 5G technology has significantly increased the demand for multifunctional electromagnetic interference(EMI)shielding and wave-absorbing materials.Hence,a densification strategy was proposed to fabricate multifunctional rigid polyimide(PI)composite foam.As a result,the composite PI foam exhibits excellent mechanical properties,with tensile and bending strengths of 4.7 and 21.1 MPa,respectively.Moreover,the composite PI foam achieves a promising EMI shielding performance with a high absorption coefficient(A)of 0.71,coupled with an X-band(8.2–12.4 GHz)EMI rating of 44 dB(2 mm)due to its high conductivity(20.29 ms/mm).Satisfyingly,the composite PI foam also has an optimal reflection loss(RL)of up to−46.4 dB and an effective absorption bandwidth(EAB)(RL<−10 dB)that covers the entire X-band.Meanwhile,the fabricated foam demonstrates a Joule heating performance of 89.2°C under supply voltages(3–9 V)and rapid response time(within 20 s)for stable and reproducible performance in long-term cycling.This work provides a versatile strategy for the development of lightweight and high-strength materials for EMI shielding and microwave absorption,demonstrating great potential for aerospace,microelectronics,and energy conversion applications. 展开更多
关键词 Polyimide foam Microwave absorbing Green EMI shielding Joule heating Flame retardancy
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Metal foams for the interfering energy conversion:Electromagnetic wave absorption,shielding,and sound attenuation 被引量:1
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作者 Yujing Zhang Rui Liu +5 位作者 Chuyang Liu Yilin Zhang Liang Yan Jie Jiang Er Liu Feng Xu 《Journal of Materials Science & Technology》 2025年第12期258-282,共25页
Metal foams are a fascinating group of materials that possess distinct physicochEMIcal properties and interconnected strut features with high surface area-to-volume ratios, high specific strength and lightweight natur... Metal foams are a fascinating group of materials that possess distinct physicochEMIcal properties and interconnected strut features with high surface area-to-volume ratios, high specific strength and lightweight nature. These characteristics make them ideal for applications in vibration damping, heat insulation and weight reduction. In recent years, there has been increasing interest in the application of interfering energy conversion such as electromagnetic wave (EMW) and sound, where the metal foams could emerge as a solution. This paper will present a comprehensive review of the preparation methods as well as the interference energy converting mechanisms for metal foams. Typically, the progress and prospective aspects of metal foams for EMW absorption, electromagnetic interference (EMI) shielding and sound absorption have been emphasized. Through this review, we aspire to offer valuable insights for the development of multifunctional applications with metal foam materials. 展开更多
关键词 Metal foams EMW absorption EMI shielding Sound absorption
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Pushing the Boundaries of Starch Foams: Novel Laminar Composites with Paper Reinforcement 被引量:1
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作者 Manisara Phiriyawirut Pukrapee Rodprasert +2 位作者 Peerapat Kulvorakulpitak Ratiwan Cothsila Nattarat Kengkla 《Journal of Renewable Materials》 2025年第1期101-114,共14页
This work explores the development of biodegradable laminar composite foams for cushioning applications.The focus lies on overcoming the inherent brittleness of starch foams by incorporating various paper types as rei... This work explores the development of biodegradable laminar composite foams for cushioning applications.The focus lies on overcoming the inherent brittleness of starch foams by incorporating various paper types as rein-forcement.Tapioca starch and glutinous starch were blended in varying ratios(100:0–0:100)to optimize the base material’s properties.The morphology,density,flexural strength,and impact strength of these starch blends were evaluated.The results revealed a trade-off between impact strength and density,with increasing glutinous starch content favoring impact resistance but also leading to higher density.The optimal ratio of tapioca to glutinous starch for achieving maximumflexural strength and modulus was determined to be 60:40.Theflexural strength of the composite material at this ratio reached a peak value of 5.3±0.6 MPa,significantly surpassing theflexural strength of pure tapioca foam,which was measured to be 3.5±0.4 MPa.Building on this foundation,novel lami-nar composite foams were fabricated using the 60:40 starch blend reinforced with mulberry paper,kraft paper,and newsprint paper.To enhance the interfacial adhesion between the starch matrix and paper reinforcement,a silane coupling agent was employed at a 10 wt%loading on the paper.The incorporation of paper reinforcement into starch foams was found to enhance their mechanical properties.Specifically,flexural strength values increased from 5.3±0.6 MPa for the unreinforced starch foam to 6.8±0.6 MPa,8.1±0.9 MPa,and 7.4±0.1 MPa when reinforced with mulberry paper,kraft paper,and newsprint paper,respectively.Notably,kraft paper reinforcement led to the most enhancements inflexural strength,flexural modulus,and impact strength.This research paves the way for developing sustainable cushioning materials with competitive mechanical properties using bio-based resources like starch and paper. 展开更多
关键词 Laminar composite starch foam tapioca starch glutinous starch kraft paper
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Hierarchically Porous Polypyrrole Foams Contained Ordered Polypyrrole Nanowire Arrays for Multifunctional Electromagnetic Interference Shielding and Dynamic Infrared Stealth 被引量:1
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作者 Yu-long Liu Ting-yu Zhu +5 位作者 Qin Wang Zi-jie Huang De-xiang Sun Jing-hui Yang Xiao-dong Qi Yong Wang 《Nano-Micro Letters》 2025年第4期399-418,共20页
As modern communication and detection technologies advance at a swift pace,multifunctional electromagnetic interference(EMI)shielding materials with active/positive infrared stealth,hydrophobicity,and electric-thermal... As modern communication and detection technologies advance at a swift pace,multifunctional electromagnetic interference(EMI)shielding materials with active/positive infrared stealth,hydrophobicity,and electric-thermal conversion ability have received extensive attention.Meeting the aforesaid requirements simultaneously remains a huge challenge.In this research,the melamine foam(MF)/polypyrrole(PPy)nanowire arrays(MF@PPy)were fabricated via one-step electrochemical polymerization.The hierarchical MF@PPy foam was composed of three-dimensional PPy micro-skeleton and ordered PPy nanowire arrays.Due to the upwardly grown PPy nanowire arrays,the MF@PPy foam possessed good hydrophobicity ability with a water contact angle of 142.00°and outstanding stability under various harsh environments.Meanwhile,the MF@PPy foam showed excellent thermal insulation property on account of the low thermal conductivity and elongated ligament characteristic of PPy nanowire arrays.Furthermore,taking advantage of the high conductivity(128.2 S m^(-1)),the MF@PPy foam exhibited rapid Joule heating under 3 V,resulting in dynamic infrared stealth and thermal camouflage effects.More importantly,the MF@PPy foam exhibited remarkable EMI shielding effectiveness values of 55.77 dB and 19,928.57 dB cm^(2)g^(-1).Strong EMI shielding was put down to the hierarchically porous PPy structure,which offered outstanding impedance matching,conduction loss,and multiple attenuations.This innovative approach provides significant insights to the development of advanced multifunctional EMI shielding foams by constructing PPy nanowire arrays,showing great applications in both military and civilian fields. 展开更多
关键词 Polypyrrole nanowire arrays Hierarchical foam HYDROPHOBICITY Infrared stealth Electromagnetic interference shielding
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New Rigid Furan Biofoams Based on Hydrolysable Chesnut(Castanea sativa)Tannin by Chemical Expansion
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作者 João Vitor Dorini Falavinha Pedro Henrique Gonzales De Cademartori +2 位作者 Philippe Gérardin Antonio Pizzi Christine Gérardin-Charbonnier 《Journal of Renewable Materials》 2025年第4期687-697,共11页
Tannins are polyphenols widely present in the plant kingdom,commonly divided into two groups:condensed and hydrolysable tannins.Sustainable furanic bio-foams based on condensed tannins have been largely studied,but li... Tannins are polyphenols widely present in the plant kingdom,commonly divided into two groups:condensed and hydrolysable tannins.Sustainable furanic bio-foams based on condensed tannins have been largely studied,but little is described about the use of hydrolysable tannins for this material.This study examined the potential of hydrolysable chestnut tannin in comparison to condensed mimosa tannins to produce furanic foams by chemical expansion.Due to the low reactivity of the hydrolysable tannin,the use of an external source for its polymerization and curing was necessary.Through Fourier transform infrared spectroscopy(FTIR)chromatography,it was possible to observe that the new foams presented small differences in functional groups compared to the condensed tannin foams,presenting peaks related to carboxyl groups.In terms of physical properties,the chestnut foams showed an apparent density 36%higher than the conventional mimosa tannin foams and a superior hydrophilic character.In terms of thermal properties,both foams exhibit high thermal stability,with the acacia tannin foam being slightly superior.In summary,this research paves the way for new applications of hydrolysable tannins in bio-foams and materials science. 展开更多
关键词 Tannin foams furfuryl alcohol hydrolysable tannin CHESTNUT
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Magnetic-dielectric synergistic enhancement effect of anti-perovskite medium-entropy alloy nitride foams designed by lattice expansion engineering
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作者 Wangchang Li Zengbao Ma +13 位作者 Wanjia Li Lun Fan Yue Kang Ting Zou Xiao Han Yao Ying Wenbo Xiang Zhiwei Li Jing Yu Jingwu Zheng Liang Qiao Juan Li Min Wu Shenglei Che 《Journal of Materials Science & Technology》 2025年第2期42-52,共11页
A single-phase anti-perovskite medium-entropy alloy nitride foams(MEANFs),as innovative materials for electromagnetic wave(EMW)absorption,have been successfully synthesized through the lattice expansion induced by nit... A single-phase anti-perovskite medium-entropy alloy nitride foams(MEANFs),as innovative materials for electromagnetic wave(EMW)absorption,have been successfully synthesized through the lattice expansion induced by nitrogen doping.This achievement notably overcomes the inherent constraints of conventional metal-based absorbers,including low resonance frequency,high conductivity,and elevated density,for the synergistic advantages provided by multimetallic alloys and foams.Microstructural analysis with comprehensive theoretical calculations provides in-depth insights into the formation mechanism,electronic structure,and magnetic moment of MEANFs.Furthermore,deliberate component design along with the foam structure proves to be an effective strategy for enhancing impedance matching and absorption.The results show that the MEANFs exhibit a minimum reflection loss(RL_(min))value of-60.32 dB and a maximum effective absorption bandwidth(EAB_(max))of 5.28 GHz at 1.69 mm.This augmentation of energy dissipation in EMW is predominantly attributed to factors such as porous structure,interfacial polarization,defect-induced polarization,and magnetic resonance.This study demonstrates a facile and efficient approach for synthesizing single-phase medium-entropy alloys,emphasizing their potential as materials for electromagnetic wave absorption due to their adjustable magnetic-dielectric properties. 展开更多
关键词 Medium-entropy alloy nitride foams Anti-perovskite structure Lattice expansion Engineering Magnetic-dielectric synergistic Electromagnetic wave absorption
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Electrically insulated C@Mn_(x)O_(y) foams with engineered defects and heterointerfaces toward superior microwave absorption,Radar wave stealth,and thermal dissipation
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作者 Yangbing Chen Ran Ji +7 位作者 Peiwen Wang Xuan Chen Huiming Ye Jingrui Zhuang Guoxiu Tong Liyan Xie Zhengquan Li Wenhua Wu 《Journal of Materials Science & Technology》 2025年第18期54-67,共14页
To address the severe electromagnetic(EM)pollution and thermal exhaustion issues in modern electronics,C@Mn_(x)O_(y) foams were first reported as an advanced multifunctional filler with superior microwave absorption,R... To address the severe electromagnetic(EM)pollution and thermal exhaustion issues in modern electronics,C@Mn_(x)O_(y) foams were first reported as an advanced multifunctional filler with superior microwave absorption,Radar wave stealth,and thermal dissipation.They were synthesized using a simple one-step annealing route,in which PVP and in-situ generated gas bubbles play a crucial role in the foam formation.Our results show that the C@Mn_(x)O_(y) foams possess excellent electrical insulation and a large thermal conductivity of 3.58 W(m K)^(–1) at a low load of 5 wt.%.Also,they exhibit prominent microwave absorption capabilities(MWACs)with a strong absorption(–46.03 dB)and a wide bandwidth(11.04 GHz)in a low load(30 wt.%).When they are then used as a patch,the wideband Radar cross-section can be effectively reduced by up to 41.34 dB m^(2).This performance outperforms most other heterostructures.Furthermore,the mechanism of dielectric loss and thermal transfer at the atomic level is revealed by the First-principle calculations of the density of states(DOS)and the phonon density of states(PDOS).The combination of C,MnO,and Mn_(3)O_(4) disrupts local microstructure symmetry and induces extra electrical dipoles at the heterointerfaces,benefiting the enhanced MWACs of C@Mn_(x)O_(y) foams along with defect polarization and multiple scattering.Their enhanced TC could be credited to the co-transmission of low phonon-boundary/phonon-defect scattering and multiple-frequency phonons from C,MnO,and Mn_(3)O_(4).Overall,the C@Mn_(x)O_(y) foams are highly promising for application in EM protection,absorption,and thermal management.What is more,this study provides a theoretical guide for designing heterostructures as effective microwave absorbing and thermally conductive materials used in modern electronics. 展开更多
关键词 C@Mn_(x)O_(y)foams PVP-assisted annealing strategy Thermal conductivity Microwave absorption Radar wave stealth Theoretical calculation
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Microcellular Foaming-derived Superlight Ultra-high Molecular Weight Poly(vinylidene fluoride)Foams for Outstanding Thermal InsulationApplications
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作者 Chao Wei Jia-Long Chai +1 位作者 Shuai Li Gui-Long Wang 《Chinese Journal of Polymer Science》 2025年第10期1837-1849,共13页
Poly(vinylidene fluoride)(PVDF)foam has received widespread attention due to its high strength,and excellent combination of flame-retardancy,antibacterial performance,and chemical stability.However,the foaming ability... Poly(vinylidene fluoride)(PVDF)foam has received widespread attention due to its high strength,and excellent combination of flame-retardancy,antibacterial performance,and chemical stability.However,the foaming ability of conventional PvDF is severely limited by its rapid crystallization kinetics and poor melt strength.Although ultra-high molecular weight PVDF(H-PVDF)theoretically offers prolonged melt elasticity favorable for foaming,the extremely high melt viscosity poses substantial processing challenges,and its foaming behavior has remained largely unexplored.To address these issues,this study proposes a novel fabrication strategy combining solvent casting with microcellular foaming to prepare H-PVDF foams.Dynamic mechanical analysis and differential scanning calorimetry reveal that extensive chain entanglements in H-PVDF impose constraints on crystallization and significantly enhance melt strength.By tuning the processing parameters,the distinctive foaming be-havior of H-PVDF under various conditions is systematically elucidated.Remarkably,a record-high expansion ratio of 55.6-fold is achieved,ac-companied by a highly uniform and fine cellular structure.The resulting H-PVDF foams exhibit a low thermal conductivity of 31.8 mW·m^(-1).K^(-1),while retaining excellent compressive strength,flame-retardancy,and hydrophobicity.These outstanding properties highlight the great potential of H-PVDF foams as the thermal insulation materials for applications in aerospace,energy infrastructure,and other extreme environments. 展开更多
关键词 Microcellular foaming Ultra-high molecular weight PVDF Superlight Thermal insulation FLAME-RETARDANCY
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Foaming of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)Foams with Double Melting Peaks
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作者 Ming-Hui Wu Dan Shi +1 位作者 Li Zhang Zong-Bao Wang 《Chinese Journal of Polymer Science》 2025年第12期2413-2421,I0016,共10页
Due to environmental concerns and the oil crisis,biodegradable polymer foams have garnered increasing attention.Among all biodegradable materials,Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)(P(HB-co-HV))distinguishes ... Due to environmental concerns and the oil crisis,biodegradable polymer foams have garnered increasing attention.Among all biodegradable materials,Poly(3-hydroxybutyrate-co-3-hydroxyvalerate)(P(HB-co-HV))distinguishes itself with the advantage of being biodegradable in all natural environments.However,preparing P(HB-co-HV)foam with a fine cellular structure remains challenging.Herein,P(HBco-HV)foams with a double melting peak structure were developed.P(HB-co-HV)samples were first heated briefly near the melting temperature to melt most of the crystals,followed by saturation and foaming at a lower temperature(foaming temperature).P(HB-co-HV)foams with cell sizes of 7.1-30.0μm and relative densities ranging from 0.3 to 0.9 were prepared,and the foaming temperature window was as wide as 16℃.The effect of heat treatment temperature and foaming temperature on the crystallization and cell structure was investigated through DSC and SEM.It was found that the high-melting temperature crystals generated during the saturation step significantly improved the cell structure of P(HB-coHV),since these crystals can enhance the heterogeneous cell nucleation and hinder the cell growth during foaming.The low-melting temperature crystals were formed during foaming.In situ WAXD analysis during heating showed that the high-and low-melting peaks corresponded to HV-unit-excluded and HV-unit-included PHB crystals,respectively. 展开更多
关键词 P(HB-co-HV) FOAMING Crystallization
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Environmentally Friendly Tannic Acid-Furfuryl Alcohol-Soybean Isolate/Casein Composite Foams Reinforced with Wood Fibers
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作者 Jinxing Li Mustafa Zor +3 位作者 Xiaojian Zhou Guanben Du Denis Rodrigue Xiaodong(Alice)Wang 《Journal of Renewable Materials》 2025年第2期329-347,共19页
In this study,two series of foams based on tannic acid(TA),furfuryl alcohol(FA),soybean protein isolate(SPI),and casein(CA),namely TA–FA–SPI(TS series)and TA–FA–CA(TC series)were developed,and their properties wer... In this study,two series of foams based on tannic acid(TA),furfuryl alcohol(FA),soybean protein isolate(SPI),and casein(CA),namely TA–FA–SPI(TS series)and TA–FA–CA(TC series)were developed,and their properties were enhanced by adding poplar fibers(WF).From the samples produced,a complete set of characterization was performed including possible crosslinking reactions,morphology,mechanical properties,flame retardancy,thermal insulation and thermal stability.Fourier-transform infrared spectroscopy(FTIR)revealed possible covalent crosslinking among the components and hydrogen bonding between WF and the matrix.Viscosity results indicated that lower prepolymer viscosity led to lower apparent density,while WF addition reduced even more the density.Mechanical tests showed that the maximum compressive strengths were good,while WF improved the compressive strength by up to 56%.Scanning electron microscopy(SEM)showed uniform cell structures,but small open pores were observed.Two-dimensional(2D)CT scan images confirmed the good compatibility between WF and the matrix,with low anisotropy in the material.Friability tests indicated that WF decreased the pulverization ratio of the materials by up to 42%.Thermogravimetric analysis(TGA)showed good thermal stability of the materials up to 328°C.Vertical burning tests showed that the materials were self-extinguishing without residue(dripping).The lowest thermal conductivity was 0.04 W/m·K.These results suggest that these novel formaldehyde-free,high biomass content(95%–96%)foams and composite foams have high potential to replace traditional phenolic foams(PF)in applications such as construction,transportation,packaging,and thermal insulation. 展开更多
关键词 Foam composite tannic acid soybean isolate protein CASEIN poplar fiber compressive strength flame retardancy thermal insulation
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Lightweight Ethylene-Vinyl Acetate Copolymer/Low-density Polyethylene/Carbon Nanotube Foams via Supercritical Carbon Dioxide Foaming for Piezoresistive Sensors
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作者 Hao-Hao Hou Xin He +4 位作者 Hui Ma Hong-Fu Zhou Bian-Ying Wen Xiang-Dong Wang Ya-Feng Deng 《Chinese Journal of Polymer Science》 2025年第7期1208-1221,共14页
Flexible polymer-based foam sensors have significant potential for application in wearable electronics and motion monitoring.However,these prospects are hindered by the complex and unenvironmentally friendly manufactu... Flexible polymer-based foam sensors have significant potential for application in wearable electronics and motion monitoring.However,these prospects are hindered by the complex and unenvironmentally friendly manufacturing processes.In this study,we employed melt blending and supercritical carbon dioxide foaming to fabricate an ethylene-vinyl acetate copolymer(EVA)/low-density polyethylene(LDPE)/carbon nanotube(CNT)piezoresistive foam sensor.The cross-linking agent bis(tert-butyldioxyisopropyl)benzene and the conductive filler CNT were incorporated into the EVA/LDPE composite,successfully achieving a chemically cross-linked and physically entangled composite structure that significantly enhanced the storage modulus and complex viscosity.Additionally,the compressive strength of EVA/LDPE/CNT foam with 10 parts per hundred rubber(phr)CNT reached 1.37 MPa at 50%compression,marking a 340%increase compared to the 0.31 MPa of the CNT-free sample.Furthermore,the EVA/LDPE/CNT composite foams,which incorporated 10 phr CNT,were prepared under specific foaming conditions,resulting in an ultra-low density of 0.11 g/cm^(3) and a higher sensitivity,with a gauge factor of–2.3.The piezoresistive foam sensors developed in this work could accurately detect human motion,thereby expanding their applications in the field of piezoresistive foam sensors and providing an effective strategy for the advancement of high-performance piezoresistive foam sensors. 展开更多
关键词 Ethylene-vinyl acetate copolymer Low-density polyethylene Carbon nanotube Supercritical carbon dioxide foaming Piezoresistive sensor
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Bending Crashworthiness of Thin⁃Walled Square Tubes Partially Filled with Metallic Foams
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作者 Zhongyou Xie Limin Guo +1 位作者 Cheng Li Jianwen Cai 《Journal of Harbin Institute of Technology(New Series)》 2025年第2期24-37,共14页
Two cross⁃sectional configurations of thin⁃walled square tubes partially filled with lightweight metallic foams are proposed,and termed as double⁃cell configuration partially filled with foam(DC⁃PF)and double⁃tube con... Two cross⁃sectional configurations of thin⁃walled square tubes partially filled with lightweight metallic foams are proposed,and termed as double⁃cell configuration partially filled with foam(DC⁃PF)and double⁃tube configuration partially filled with foam(DT⁃PF),respectively.The bending crashworthiness is investigated based on three⁃point bending tests using finite element ABAQUS/Explicit code.The two key mechanical indicators including Crash Load Efficiency(CLE)and Specific Energy Absorption(SEA)are introduced to evaluate the effect of foams in comparison with empty square tubes and fully filled square tubes.The numerical results show that the two partially filled configurations,especially DT⁃PF,display dramatically excellent bending crashworthiness compared with empty and fully filled square tubes.There exists a foam density threshold,beyond which the CLE of DT⁃PF achieves a maximum constant.In addition,there seems to be another foam density threshold,beyond which the SEA of DT⁃PF gets to the maximum value.It is also shown that the foam density threshold corresponding to the maximum SEA varies with the thickness of thin⁃walled square tubes. 展开更多
关键词 thin⁃walled tube lightweight foam bending crashworthiness energy absorption finite element analysis
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Preparation and characterization of aluminum foams with ZrH_2 as foaming agent 被引量:8
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作者 李大武 李杰 +3 位作者 李涛 孙挺 张小明 姚广春 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第2期346-352,共7页
Aluminum foams were fabricated by melt-based route using ZrH2 as a foaming agent. The factors which affected the foaming of aluminum foams during casting process were investigated. The powdered zirconium hydride with ... Aluminum foams were fabricated by melt-based route using ZrH2 as a foaming agent. The factors which affected the foaming of aluminum foams during casting process were investigated. The powdered zirconium hydride with content of 0.6%-1.4% (mass fraction) was added to the molten pure aluminum and the foaming condition was controlled in a temperature range from 933 to 1 013 K, Ca amount of 1.5%-3.0% (mass fraction), stirring time of 0.5-2.5 min and holding time of 1.5-4.0 min to obtain homogeneous aluminum foams. The fabricated aluminum foams were characterized by XRD, SEM and Image-pro plus. The mechanical properties of the aluminum foams with different relative density were tested. The result indicates that the foaming agent (ZrH2) is suitable for the preparation of small aperture aluminum foams with average pore diameter of 1 mm. Inter-metallic compounds and Al2O3 have effect on the melt viscosity. The aluminum foams experience linear elastic, platforms and densification process and had a higher efficiency of energy absorption. 展开更多
关键词 aluminum foams zirconium hydride BUBBLE melt-based route
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Oxide film on bubble surface of aluminum foams produced by gas injection foaming process 被引量:3
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作者 周宇通 李言祥 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第7期2429-2437,共9页
Based on A356 aluminum alloy,aluminum foams were prepared by gas injection foaming process with pure nitrogen,air and some gas mixtures.The oxygen volume fraction of these gas mixtures varied from 0.2%to 8.0%.Optical ... Based on A356 aluminum alloy,aluminum foams were prepared by gas injection foaming process with pure nitrogen,air and some gas mixtures.The oxygen volume fraction of these gas mixtures varied from 0.2%to 8.0%.Optical microscopy,scanning electron microscopy(SEM) and Auger electron spectroscopy(AES) were used to analyze the influence of oxygen content on cell structure,relative density,macro and micro morphology of cell walls,coverage area fraction of oxide film,thickness of oxide film and other aspects.Results indicate that the coverage area fraction of oxide film on bubble surface increases with the increase of oxygen content when the oxygen volume is less than 1.2%.While when the oxygen volume fraction is larger than 1.6%,an oxide film covers the entire bubble surface and aluminum foams with good cell structure can be produced.The thicknesses of oxide films of aluminum foams produced by gas mixtures containing 1.6%-21%oxygen are almost the same.The reasons why the thickness of oxide film nearly does not change with the variation of oxygen content and the amount of oxygen needed to achieve 100%coverage of oxide film are both discussed.In addition,the role of oxide film on bubble surface in foam stability is also analyzed. 展开更多
关键词 aluminum foam gas injection foaming process oxide film foam stability mechanism
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Preparation and oxidation resistance of B_2O_3-coated boron-modified carbon foams 被引量:1
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作者 王斌 李贺军 +1 位作者 张雨雷 王茜 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第7期2123-2128,共6页
To improve the oxidation resistance of boron-modified carbon foams, the B2O3 coating was prepared on boron-modified carbon foams by low-cost slurry method. The microstructures and phase compositions of the coated carb... To improve the oxidation resistance of boron-modified carbon foams, the B2O3 coating was prepared on boron-modified carbon foams by low-cost slurry method. The microstructures and phase compositions of the coated carbon foams were characterized by scanning electron microscopy and X-ray diffraction, respectively. Oxidation resistances of uncoated and coated boron-modified carbon foams were investigated at 873 K in air. The results showed that as-received B2O3 coating could protect boron-modified carbon foams from oxidation at 873 K. B2O3-coated carbon foam doped with 7% B2O3 (mass fraction) (BO-7) had better oxidation resistance, exhibiting mass loss of 17.40% after oxidation at 873 K for 120 min. The melting glass layer formed on the surface of BO-7 could prevent oxygen from diffusing into boron-modified carbon foams substrate during oxidation to some extent. 展开更多
关键词 carbon foam B2O3 COATING oxidation resistance
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Oxidation kinetics of oxide film on bubble surface of aluminum foams produced by gas injection foaming process 被引量:1
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作者 周宇通 李言祥 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第8期2781-2788,共8页
In the range of 620?710 °C, air was blown into A356 aluminum alloy melt to produce aluminum foams. In order to study the influence of temperature on the thickness of oxide film on bubble surface, Auger electron ... In the range of 620?710 °C, air was blown into A356 aluminum alloy melt to produce aluminum foams. In order to study the influence of temperature on the thickness of oxide film on bubble surface, Auger electron spectroscopy (AES) was used. Based on the knowledge of corrosion science and hydrodynamics, two oxidation kinetics models of oxide film on bubble surface were established. The thicknesses of oxide films produced at different temperatures were predicted through those two models. Furthermore, the theoretical values were compared with the experimental values. The results indicate that in the range of 620?710 °C, the theoretical values of the thickness of oxide film predicted by the model including the rising process are higher than the experimental values. While, the theoretical values predicted by the model without the rising process are in good agreement with the experimental values, which shows this model objectively describes the oxidation process of oxide film on bubble surface. This work suggests that the oxidation kinetics of oxide film on bubble surface of aluminum foams produced by gas injection foaming process follows the Arrhenius equation. 展开更多
关键词 aluminum foam gas injection foaming process oxide film oxidation kinetics
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Synthesis of CO2 Copolymer Based Polyurethane Foams 被引量:2
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作者 BaoHuaLIU LiBanCHEN +1 位作者 MinZHANG AiFangYU 《Chinese Chemical Letters》 SCIE CAS CSCD 2003年第7期752-754,共3页
CO2-copolymer based polyurethane foams were synthesized and characterized in this paper. The foams were found to have higher strength and lower heat of combustion than the conventional polyether polyurethane foams. ... CO2-copolymer based polyurethane foams were synthesized and characterized in this paper. The foams were found to have higher strength and lower heat of combustion than the conventional polyether polyurethane foams. They may find wide applications in many fields. 展开更多
关键词 CO2 EPOXIDES aliphatic polycarbonates polyurethane foams.
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Volume change of macropores of titanium foams during sintering
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作者 肖健 杨杨 +3 位作者 邱贵宝 廖益龙 崔豪 吕学伟 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第11期3834-3839,共6页
The porosity of titanium foams obtained from the space holder technique was theoretically analyzed in the cases of volume shrinking, retaining and expanding during sintering. The relationship between porosity and spac... The porosity of titanium foams obtained from the space holder technique was theoretically analyzed in the cases of volume shrinking, retaining and expanding during sintering. The relationship between porosity and spacer content was compared under different conditions. The kind of volume change of macropores during sintering was discussed. The results indicate that the relationship between porosity and spacer content depends on the decreased volume of macropores and the volume of micropores in cell-walls in the first case, while the porosity will be greater than the spacer content for the other two cases. It proves that the volume change of macropores during sintering decreases based on theory and practice. 展开更多
关键词 porous material titanium foam space holder technique SINTERING volume change POROSITY
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Influence of SiC Content on Foaming Stability,Cell Structure,and Compression Performance of SiC/Al-Based Composite Foam Prepared by Two-Step Foaming Method
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作者 Huang Wenzhan Liu Tao +3 位作者 Chen Yao Wang Lucai Wu Jianguo You Xiaohong 《稀有金属材料与工程》 北大核心 2026年第4期890-898,共9页
SiC/Al-based composite foams were prepared by a two-step foaming method.The influence of the SiC content and its distribution uniformity on the foaming stability,cell structure,and mechanical properties of the aluminu... SiC/Al-based composite foams were prepared by a two-step foaming method.The influence of the SiC content and its distribution uniformity on the foaming stability,cell structure,and mechanical properties of the aluminum foams was investigated.The macro/micro-features of the aluminum foams were characterized and analyzed.Results demonstrate that an appropriate increase in SiC content and the uniform distribution of SiC can improve the foaming stability,optimize the cell diameter and cell wall thickness,ameliorate the cell distribution,and enhance the hardness and compressive strength of the aluminum foams.However,either insufficient or excessive SiC leads to uneven distribution of SiC particles,which is unfavorable to foaming stability and good cell structure formation.With 6wt%SiC,both the foaming stability and cell structure of the aluminum foam reach the optimal state,resulting in the highest compressive strength and optimal energy absorption capacity. 展开更多
关键词 aluminum foam two-step foaming method foaming stability cell structure HARDNESS compressive strength
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