As a reliable additive manufacturing technology,the stereolithography(SLA)ceramic core necessitates a tailored sintering process to achieve optimal performance.This study explored the effects of final sintering temper...As a reliable additive manufacturing technology,the stereolithography(SLA)ceramic core necessitates a tailored sintering process to achieve optimal performance.This study explored the effects of final sintering temperatures(specifically 1,150,1,250,and 1,300°C)on the properties of SLA-fabricated SiO_(2)-based ceramic cores reinforced with nano-ZrO_(2)(at concentrations of 1.0wt.%,1.5wt.%,and 2.0wt.%).The results demonstrate that increasing the final sintering temperature and the incorporation of nano-ZrO_(2)enhance the viscous fiow of quartz glass,resulting in a higher sintering degree.As the final sintering temperature rises,the ceramic samples exhibit increased shrinkage rate,decreased apparent porosity,and increased bulk density.Higher final sintering temperatures also promote greater cristobalite precipitation,promoting an increase in the amount and precipitation rate of quartz during investment casting.The formation of a cristobalite and ZrSiO_4 network at elevated temperatures effectively inhibits the viscous flow of quartz glass,thereby significantly improving high-temperature flexural strength and creep resistance of ceramic cores.When the content of nano-ZrO_(2)is between 1.5wt.%and 2.0wt.%,the final sintering temperature of 1,250°C is the best choice.Under these conditions,the shrinkage rate along the Z direction ranges from 3.35%to 3.68%,the porosity lies between 25.57%and 26.03%,the bulk density varies from 1.612 to 1.645 g·cm^(-3),the room temperature fiexural strength is between 26.79 and 27.85 MPa,and the fiexural strength at high temperatures is within the range of 30.77 to 33.02 MPa.The defiection at high-temperatures is 3.37-5.31 mm,while the surface roughness of the upper surface is 3.26-4.79μm,and the surface roughness of the side surface is 4.97-5.79μm.These findings provide valuable guidance for optimizing the sintering processes of SLA ceramic cores,offering potential for industrial applications.展开更多
The strength-to-weight ratio is an important property of high-strength low-alloy(HSLA)steel in pipeline,whose precipitation strengthening can be improved.The final rolling temperature(FRT)and coiling temperature(CT)ar...The strength-to-weight ratio is an important property of high-strength low-alloy(HSLA)steel in pipeline,whose precipitation strengthening can be improved.The final rolling temperature(FRT)and coiling temperature(CT)are the key process parameters in the control of precipitates and microstructure.Continuous cooling rate was fixed at 10℃/s,and the effects of deformation and coiling temperatures on precipitates and microstructure of Ti-Nb microalloyed HSLA steel were investigated through thermo-mechanical controlled processing on Gleeble 3500.The microstructure is mainly acicular ferrite with high density dislocation and several microns scale.The size and volume fraction of the precipitates were studied under transmission electron microscopy.The results showed that the diameter of the precipitates was in the range between 4 and 240 nm.The optimized combination of parameters is FRT of 820℃and CT of 550℃,and the volume fraction of precipitates obtained under this process is 0.59%.展开更多
The influence of alloying design,controlled rolling technology and cooling system of X100 hot-rolled strips on microstructure and micro-hardness has been discussed in detail in this paper.The results show that optimal...The influence of alloying design,controlled rolling technology and cooling system of X100 hot-rolled strips on microstructure and micro-hardness has been discussed in detail in this paper.The results show that optimal chemical composition range of X100 hot-rolled strips is obtained on the basis of X80 by increasing contents of C,Mn,Ni and Mo of X80.The granular bainite microstructure could be refined and the volume fraction and size of M-A islands could be controlled in a reasonable range by reasonably regulating cooling rate and coiling temperature of X100 pipeline steel,which ensure high strength and toughness of X100 pipeline steel.展开更多
Significant waste resources are generated in the form of water-oil emulsions.These emulsions cannot be effectively destroyed on an industrial scale by traditional methods that rely on the settling of the aqueous phase...Significant waste resources are generated in the form of water-oil emulsions.These emulsions cannot be effectively destroyed on an industrial scale by traditional methods that rely on the settling of the aqueous phase,and therefore,they accumulate in large quantities.Thermomechanical dehydration,based on the evaporation of the water phase,presents a promising process for recycling such waste.However,within the framework of thermomechanical dehydration,the issue of optimizing energy costs for heating raw materials and controlling the water content in the product arises.Standard methods of determining water content under the boiling conditions of highly stable water-hydrocarbon emulsions are characterized by low efficiency,as they require constant sampling and the involvement of additional equipment and personnel.Consequently,this presents a challenge in predicting and creating an automated thermomechanical dehydration process.Therefore,dynamic curves depicting changes in the water content of these emulsions,depending on the temperature of the boiling liquid,have been obtained.It is proposed to determine the rate of temperature increase(dT/dt)of the boiling emulsion for continuous,real-time monitoring of the residual water content and for recording the moment of complete dehydration.Achieving a boiling emulsion temperature of 130-170℃(or higher)and/or the rate of temperature increase from 3.0 to 5.5(or above)indicates the complete dehydration of the emulsion.The proposed method can be implemented in any industrial or laboratory-scale unit for thermomechanical dehydration without significant capital costs.It is based on the use of simple devices consisting of temperature sensors and a computing unit for determining the temperature and rate of heating.展开更多
The effects of final air cooling temperature on the microstructure and mechanical properties of hot rolled 0.2C-1.9Mn-0.5Si-0.08P TRIP steel were studied by utilizing OM,SEM,TEM and tensile tests.Experimental results ...The effects of final air cooling temperature on the microstructure and mechanical properties of hot rolled 0.2C-1.9Mn-0.5Si-0.08P TRIP steel were studied by utilizing OM,SEM,TEM and tensile tests.Experimental results showed that in the multiphase microstructure of the investigated steel when the finish rolling temperature was about 820℃and the final air cooling temperature was in the range of 630-700℃,the grain size of most of ferrite was finer(about 4μm)and which had higher dislocation density,the bainite packets had chaotic orientations and lath boundaries of bainite were not quite straight,the retained austenite distributed in the ferrite grain boundaries or triradius was fine and dispersive,and their grain size was about 0.4-1.9μm.With increasing the amount of ferrite,the volume fraction of retained austenite had a slight decrease.When the final air cooling temperature was 630℃,the steel had excellent mechanical properties,which was characterized by combination of continuous yielding,high strength(about 796 MPa)and high elongation(22.7%)as well as low yield/strength ratio(0.58);when the final air cooling temperature increased to 700℃,the matrix structure was bainite packets and the comprehensive properties were deteriorated.展开更多
基金supported by the Natural Science Foundation of Shanghai(No.23ZR1421500)the National Natural Science Foundation of China(Nos.52474412,52127807,52271035)+3 种基金the Shanghai Municipal Commission of Economy and Informatization(No.GYOJ2022-2-02)the United Innovation Program of Shanghai Commercial Aircraft Engine(No.AR966)the SPMI Project from Shanghai Academy of Spaceflight Technology(No.SPMI2022-06)the Ningbo International Science and Technology Cooperation Program(No.2023H004)。
文摘As a reliable additive manufacturing technology,the stereolithography(SLA)ceramic core necessitates a tailored sintering process to achieve optimal performance.This study explored the effects of final sintering temperatures(specifically 1,150,1,250,and 1,300°C)on the properties of SLA-fabricated SiO_(2)-based ceramic cores reinforced with nano-ZrO_(2)(at concentrations of 1.0wt.%,1.5wt.%,and 2.0wt.%).The results demonstrate that increasing the final sintering temperature and the incorporation of nano-ZrO_(2)enhance the viscous fiow of quartz glass,resulting in a higher sintering degree.As the final sintering temperature rises,the ceramic samples exhibit increased shrinkage rate,decreased apparent porosity,and increased bulk density.Higher final sintering temperatures also promote greater cristobalite precipitation,promoting an increase in the amount and precipitation rate of quartz during investment casting.The formation of a cristobalite and ZrSiO_4 network at elevated temperatures effectively inhibits the viscous flow of quartz glass,thereby significantly improving high-temperature flexural strength and creep resistance of ceramic cores.When the content of nano-ZrO_(2)is between 1.5wt.%and 2.0wt.%,the final sintering temperature of 1,250°C is the best choice.Under these conditions,the shrinkage rate along the Z direction ranges from 3.35%to 3.68%,the porosity lies between 25.57%and 26.03%,the bulk density varies from 1.612 to 1.645 g·cm^(-3),the room temperature fiexural strength is between 26.79 and 27.85 MPa,and the fiexural strength at high temperatures is within the range of 30.77 to 33.02 MPa.The defiection at high-temperatures is 3.37-5.31 mm,while the surface roughness of the upper surface is 3.26-4.79μm,and the surface roughness of the side surface is 4.97-5.79μm.These findings provide valuable guidance for optimizing the sintering processes of SLA ceramic cores,offering potential for industrial applications.
基金supported by Science and Technology Innovation Cooperation Project between China and South Africa(2017YFE0113400).
文摘The strength-to-weight ratio is an important property of high-strength low-alloy(HSLA)steel in pipeline,whose precipitation strengthening can be improved.The final rolling temperature(FRT)and coiling temperature(CT)are the key process parameters in the control of precipitates and microstructure.Continuous cooling rate was fixed at 10℃/s,and the effects of deformation and coiling temperatures on precipitates and microstructure of Ti-Nb microalloyed HSLA steel were investigated through thermo-mechanical controlled processing on Gleeble 3500.The microstructure is mainly acicular ferrite with high density dislocation and several microns scale.The size and volume fraction of the precipitates were studied under transmission electron microscopy.The results showed that the diameter of the precipitates was in the range between 4 and 240 nm.The optimized combination of parameters is FRT of 820℃and CT of 550℃,and the volume fraction of precipitates obtained under this process is 0.59%.
文摘The influence of alloying design,controlled rolling technology and cooling system of X100 hot-rolled strips on microstructure and micro-hardness has been discussed in detail in this paper.The results show that optimal chemical composition range of X100 hot-rolled strips is obtained on the basis of X80 by increasing contents of C,Mn,Ni and Mo of X80.The granular bainite microstructure could be refined and the volume fraction and size of M-A islands could be controlled in a reasonable range by reasonably regulating cooling rate and coiling temperature of X100 pipeline steel,which ensure high strength and toughness of X100 pipeline steel.
文摘Significant waste resources are generated in the form of water-oil emulsions.These emulsions cannot be effectively destroyed on an industrial scale by traditional methods that rely on the settling of the aqueous phase,and therefore,they accumulate in large quantities.Thermomechanical dehydration,based on the evaporation of the water phase,presents a promising process for recycling such waste.However,within the framework of thermomechanical dehydration,the issue of optimizing energy costs for heating raw materials and controlling the water content in the product arises.Standard methods of determining water content under the boiling conditions of highly stable water-hydrocarbon emulsions are characterized by low efficiency,as they require constant sampling and the involvement of additional equipment and personnel.Consequently,this presents a challenge in predicting and creating an automated thermomechanical dehydration process.Therefore,dynamic curves depicting changes in the water content of these emulsions,depending on the temperature of the boiling liquid,have been obtained.It is proposed to determine the rate of temperature increase(dT/dt)of the boiling emulsion for continuous,real-time monitoring of the residual water content and for recording the moment of complete dehydration.Achieving a boiling emulsion temperature of 130-170℃(or higher)and/or the rate of temperature increase from 3.0 to 5.5(or above)indicates the complete dehydration of the emulsion.The proposed method can be implemented in any industrial or laboratory-scale unit for thermomechanical dehydration without significant capital costs.It is based on the use of simple devices consisting of temperature sensors and a computing unit for determining the temperature and rate of heating.
基金Fundamental Research Funds for the Central Universities(N090407001)National Key Project of Scientific and Technical Supporting Programs(2007BAE51B07)National Natural Science Foundation of China(50734001)
文摘The effects of final air cooling temperature on the microstructure and mechanical properties of hot rolled 0.2C-1.9Mn-0.5Si-0.08P TRIP steel were studied by utilizing OM,SEM,TEM and tensile tests.Experimental results showed that in the multiphase microstructure of the investigated steel when the finish rolling temperature was about 820℃and the final air cooling temperature was in the range of 630-700℃,the grain size of most of ferrite was finer(about 4μm)and which had higher dislocation density,the bainite packets had chaotic orientations and lath boundaries of bainite were not quite straight,the retained austenite distributed in the ferrite grain boundaries or triradius was fine and dispersive,and their grain size was about 0.4-1.9μm.With increasing the amount of ferrite,the volume fraction of retained austenite had a slight decrease.When the final air cooling temperature was 630℃,the steel had excellent mechanical properties,which was characterized by combination of continuous yielding,high strength(about 796 MPa)and high elongation(22.7%)as well as low yield/strength ratio(0.58);when the final air cooling temperature increased to 700℃,the matrix structure was bainite packets and the comprehensive properties were deteriorated.
