Point-of-care testing(POCT)refers to a category of diagnostic tests that are performed at or near to the site of the patients(also called bedside testing)and is capable of obtaining accurate results in a short time by...Point-of-care testing(POCT)refers to a category of diagnostic tests that are performed at or near to the site of the patients(also called bedside testing)and is capable of obtaining accurate results in a short time by using portable diagnostic devices,avoiding sending samples to the medical laboratories.It has been extensively explored for diagnosing and monitoring patients’diseases and health conditions with the assistance of development in biochemistry and microfluidics.Microfluidic paper-based analytical devices(μPADs)have gained dramatic popularity in POCT because of their simplicity,user-friendly,fast and accurate result reading and low cost.SeveralμPADs have been successfully commercialized and received excellent feedback during the past several decades.This review briefly discusses the main types ofμPADs,preparation methods and their detection principles,followed by a few representative examples.The future perspectives of the development inμPADs are also provided.展开更多
Nickel(II)as one of the primary categories of heavy metals can lead to serious health problems if achieving the critical levels in the water.Thus,it is vital to propose a stable,reliable,and economical approach for de...Nickel(II)as one of the primary categories of heavy metals can lead to serious health problems if achieving the critical levels in the water.Thus,it is vital to propose a stable,reliable,and economical approach for detecting Ni ions.The microfluidic paper-based analytical devices(µPADs)are potential candidates for the detection of water quality parameters including pH,heavy ions,nitrite and so on.However,it suffers from a huge error caused by the environment and artificial mistakes.In this study,we proposed an improved technique route to increase the stability and reliability of microfluidic paper-based analytical devices.The main technique points include a stable light source,a matched camera,improved reliability of the devices,and effective calculated methods.Finally,we established 15 standard curves that could be used to detect nickel ions and obtained uniform colorimetric results with reliability and repeatability.With those improvements,the relative errors for the five types of real water samples from the Zhongshan industrial parks were reduced to 0.26%,14.78%,24.20%,50.29%and 3.53%,respectively.These results were conducive to exploring this technique for the detection of nickel ions in wastewater from the Zhongshan industrial parks.The results demonstrated that the above technique route is promising for the detection of other heavy metal ions in industrial effluent.展开更多
This study systematically investigated the influence of deposition rate on the structure,broadband opti⁃cal properties(1.0-13.0μm),and stress characteristics of Germanium(Ge)films.Additionally,a method for enhancing ...This study systematically investigated the influence of deposition rate on the structure,broadband opti⁃cal properties(1.0-13.0μm),and stress characteristics of Germanium(Ge)films.Additionally,a method for enhancing the performance of infrared filters based on rate-modulated deposition of Ge films was proposed.The optical absorption of Ge films in the short-wave infrared(SWIR)and long-wave infrared(LWIR)bands can be effectively reduced by modulating the deposition rate.As the deposition rate increases,the Ge films maintain an amorphous structure.The optical constants of the films in the 1.0-2.5μm and 2.5-13.0μm bands were precisely determined using the Cody-Lorentz model and the classical Lorentz oscillator model,respectively.Notably,high⁃er deposition rates result in a gradual increase in the refractive index.The extinction coefficient increases with the deposition rate in the SWIR region,attributed to the widening of the Urbach tail,while it decreases in the LWIR region due to the reduced absorption caused by the Ge-O stretching mode.Additionally,the films exhibit a tensile stress that decreases with increasing deposition rate.Finally,the effectiveness of the proposed fabrication method for an infrared filter with Ge films deposited at an optimized rate was demonstrated through practical examples.This work provides theoretical and technical support for the application of Ge films in high-performance infrared filters.展开更多
The Savitzky-Golay(SG)filter,which employs polynomial least-squares approximations to smooth data and estimate derivatives,is widely used for processing noisy data.However,noise suppression by the SG filter is recogni...The Savitzky-Golay(SG)filter,which employs polynomial least-squares approximations to smooth data and estimate derivatives,is widely used for processing noisy data.However,noise suppression by the SG filter is recognized to be limited at data boundaries and high frequencies,which can significantly reduce the signal-to-noise ratio(SNR).To solve this problem,a novel method synergistically integrating Principal Component Analysis(PCA)with SG filtering is proposed in this paper.This approach avoids the is-sue of excessive smoothing associated with larger window sizes.The proposed PCA-SG filtering algorithm was applied to a CO gas sensing system based on Cavity Ring-Down Spectroscopy(CRDS).The perform-ance of the PCA-SG filtering algorithm is demonstrated through comparison with Moving Average Filtering(MAF),Wavelet Transformation(WT),Kalman Filtering(KF),and the SG filter.The results demonstrate that the proposed algorithm exhibits superior noise reduction capabilities compared to the other algorithms evaluated.The SNR of the ring-down signal was improved from 11.8612 dB to 29.0913 dB,and the stand-ard deviation of the extracted ring-down time constant was reduced from 0.037μs to 0.018μs.These results confirm that the proposed PCA-SG filtering algorithm effectively improves the smoothness of the ring-down curve data,demonstrating its feasibility.展开更多
Accurate estimation of the State of Charge(SOC),State of Health(SOH),and Terminal Resistance(TR)is crucial for the effective operation of Battery Management Systems(BMS)in lithium-ion batteries.This study conducts a c...Accurate estimation of the State of Charge(SOC),State of Health(SOH),and Terminal Resistance(TR)is crucial for the effective operation of Battery Management Systems(BMS)in lithium-ion batteries.This study conducts a comprehensive comparative analysis of four Kalman filter variants Extended Kalman Filter(EKF),Extended Kalman-Bucy Filter(EKBF),Unscented Kalman Filter(UKF),and Unscented Kalman-Bucy Filter(UKBF)under varying battery parameter conditions.These include temperature fluctuation,self-discharge,current direction,cell capacity,process noise,and measurement noise.Our findings reveal significant variations in the performance of SOC and SOH predictions across filters,emphasizing that UKF demonstrates superior robustness to noise,while EKF performs better under accurate system dynamics.The study underscores the need for adaptive filtering strategies that can dynamically adjust to evolving battery parameters,thereby enhancing BMS reliability and extending battery lifespan.展开更多
1 Introduction Recently,the increasing demand for advanced telecommunication systems has spurred extensive research into bandpass filters(BPFs),with particular emphasis on miniaturization,reduction of insertion loss(I...1 Introduction Recently,the increasing demand for advanced telecommunication systems has spurred extensive research into bandpass filters(BPFs),with particular emphasis on miniaturization,reduction of insertion loss(IL),and enhancement of upper stopband rejection(Huang et al.,2021;Snyder et al.,2021;Lin et al.,2023;Zeng et al.,2023).展开更多
In this study,a fifth-degree cubature particle filter(5CPF)is proposed to address the limited estimation accuracy in traditional particle filter algorithms for bearings-only tracking(BOT).This algorithm calculates the...In this study,a fifth-degree cubature particle filter(5CPF)is proposed to address the limited estimation accuracy in traditional particle filter algorithms for bearings-only tracking(BOT).This algorithm calculates the recommended density function by introducing a fifth-degree cubature Kalman filter algorithm to guide particle sampling,which effectively alleviates the problem of particle degradation and significantly improves the estimation accuracy of the filter.However,the 5CPF algorithm exhibits high computational complexity,particularly in scenarios with a large number of particles.Therefore,we propose the extended Kalman filter(EKF)-5CPF algorithm,which employs an EKF to replace the time update step for each particle in the 5CPF.This enhances the algorithm’s real-time capability while maintaining the high precision advantage of the 5CPF algorithm.In addition,we construct bearing-only dual-station and single-motion station target tracking systems,and the filtering performances of 5CPF and EKF-5CPF algorithms under different conditions are analyzed.The results show that both the 5CPF algorithm and EKF-5CPF have strong robustness and can adapt to different noise environments.Furthermore,both algorithms significantly outperform traditional nonlinear filtering algorithms in terms of convergence speed,tracking accuracy,and overall stability.展开更多
Color filters are essential components for optical modulation.However,conventional filters are restricted to operating exclusively in either reflective or transmissive mode.Furthermore,they suffer from limited UV and ...Color filters are essential components for optical modulation.However,conventional filters are restricted to operating exclusively in either reflective or transmissive mode.Furthermore,they suffer from limited UV and thermal stability,low color purity,and exhibit identical coloration on both surfaces.Herein,we propose a novel design strategy for trans-reflective color filters by integrating the absorptive properties of dye-doped polysulfone(PSU)with the diffractive capabilities of photonic crystals.This composite filter achieved broad-spectrum transmission with deep color outputs—yellow(0.410,0.510),magenta(0.446,0.231),and cyan(0.201,0.425)—closely aligned with standard color space coordinates.By tuning the refractive index of CeO_(2)@SiO_(2)nanoparticles to match dye-based PSU matrix,the transmittance of filters exceeded 70%.Moreover,dye-mediated absorption reduces the scattering light,thereby enhancing reflection color purity(full width at half maxima(FWHM)=25 nm)and producing vibrant blue,green,and red hues.The incorporation of UV-absorbing CeO_(2)@SiO_(2)nanoparticles effectively mitigated dye photodegradation,yielding exceptional UV stability(ΔT<2%under prolonged UV exposure).The filters also exhibited outstanding thermal stability(ΔT<1%after 30 min heat treatment at 230°C).This work establishes a robust materials design framework for multifunctional optical filters,advancing the development of highfidelity dual-mode color systems for next-generation display technologies.展开更多
Recommendation systems are an integral and indispensable part of every digital platform,as they can suggest content or items to users based on their respective needs.Collaborative filtering is a technique often used i...Recommendation systems are an integral and indispensable part of every digital platform,as they can suggest content or items to users based on their respective needs.Collaborative filtering is a technique often used in various studies,which produces recommendations by analyzing similarities between users and items based on their behavior.Although often used,traditional collaborative filtering techniques still face the main challenge of sparsity.Sparsity problems occur when the data in the system is sparse,meaning that only a portion of users provide feedback on some items,resulting in inaccurate recommendations generated by the system.To overcome this problem,we developed aHybrid Collaborative Filtering model based onMatrix Factorization andGradient Boosting(HCF-MFGB),a new hybrid approach.Our proposed model integrates SVD++,the XGBoost ensemble learning algorithm,and utilizes user demographic data and meta items.We utilize information,both explicitly and implicitly,to learn user preference patterns using SVD++.The XGBoost algorithm is used to create hundreds of decision trees incrementally,thereby improving model accuracy.Meanwhile,user demographic and meta-item data are clustered using the K-Means Clustering algorithm to capture similarities in user and item characteristics.This combination is designed to improve rating prediction accuracy by reducing reliance on minimal explicit rating data,while addressing sparsity issues in movie recommendation systems.The results of experiments on the MovieLens 100K,MovieLens 1M,and CiaoDVD datasets show significant improvements,outperforming various other baselinemodels in terms of RMSE and MAE.On theMovieLens 100K dataset,the HCF-MFGB model obtained an RMSE value of 0.853 and an MAE value of 0.674.On theMovieLens 1M dataset,the HCF-MFGB model obtained an RMSE value of 0.763 and an MAE value of 0.61.On the CiaoDCD dataset,the HCF-MFGB model achieved an RMSE value of 0.718 and an MAE value of 0.495.These results confirm a significant improvement in movie recommendation accuracy with the proposed approach.展开更多
This article presents an adaptive intelligent control strategy applied to a lumped-parameter evaporator model,i.e.,a simplified dynamic representation treating the evaporator as a single thermal node with uniform temp...This article presents an adaptive intelligent control strategy applied to a lumped-parameter evaporator model,i.e.,a simplified dynamic representation treating the evaporator as a single thermal node with uniform temperature distribution,suitable for control design due to its balance between physical fidelity and computational simplicity.The controller uses a wavelet-based neural proportional,integral,derivative(PID)controller with IIR filtering(infinite impulse response).The dynamic model captures the essential heat and mass transfer phenomena through a nonlinear energy balance,where the cooling capacity“Qevap”is expressed as a non-linear function of the compressor frequency and the temperature difference,specifically,Q_(evap)=k_(1)u(T_(in)−T_(e))with u as compressor frequency,Te evaporator temperature,and Tin inlet fluid temperature.The operating conditions of the system,in general terms,focus on the following variables,the overall thermal capacity is 1000 J/K,typical for small-capacity heat exchangers,The mass flow is 0.05 kg/s,typical for secondary liquid cooling circuits,the overall loss coefficient of 50 W/K that corresponds to small evaporators with partial insulation,the temperatures(inlet)of 10℃and the temperature of environment of 25℃,thermal load of 200 W that corresponds to a small-scaled air conditioning applications.To handle system nonlinearities and improve control performance,aMorlet wavelet-based neural network(Wavenet)is used to dynamically adjust the PID gains online.An IIR filter is incorporated to smooth the adaptive gains,improving stability and reducing oscillations.In contrast to prior wavelet-or neural-adaptive PID controllers in HVAC applications,which typically adjust gains without explicit filtering or not tailored to evaporator dynamics,this work introduces the first PID–Wavenet scheme augmented with an IIR-based stabilization layer,specifically designed to address the combined challenges of nonlinear evaporator behavior,gain oscillation,and real-time implementability.The proposed controller(PID-Wavenet+IIR)is implemented and validated inMATLAB/Simulink,demonstrating superior performance compared to a conventional PID tuned using Simulink’s auto-tuning function.Key results include a reduction in settling time from 13.3 to 8.2 s,a reduction in overshoot from 3.5%to 0.8%,a reduction in steady-state error from 0.12℃ to 0.02℃and a 13%reduction in energy overall consumption.The controller also exhibits greater robustness and adaptability under varying thermal loads.This explicit integration of wavelet-driven adaptation with IIR-filtered gain shaping constitutes the main methodological contribution and novelty of the work.These findings validate the effectiveness of the wavelet-based adaptive approach for advanced thermal management in refrigeration and HVAC systems,with potential applications in controlling variable-speed compressors,liquid chillers,and compact cooling units.展开更多
This article proposes a generalized strongly coupled resonator quartet(GSCRQ)filter along with its synthesis approach.By introducing out-of-band reflection zeros(RZs),the proposed GSCRQ can generate a transmission zer...This article proposes a generalized strongly coupled resonator quartet(GSCRQ)filter along with its synthesis approach.By introducing out-of-band reflection zeros(RZs),the proposed GSCRQ can generate a transmission zero on each side of the passband without negative couplings.The coupling coefficients in this coupling structure change with the positions of the out-of-band RZs.Thus,the GSCRQ configuration admits flexible design solutions.For GSCRQ coaxial combline filters,all couplings can be implemented as inductive couplings,simplifying the design and manufacturing process.In this article,a 6-2 filter in the GSCRQ configuration is synthesized and designed.The simulated results of the designed filter agree very well with the theoretical characteristics.展开更多
Deep graph contrastive clustering has attracted widespread attentions due to its self-supervised representation learning paradigm and superior clustering performance.Although,two challenges emerge and result in high c...Deep graph contrastive clustering has attracted widespread attentions due to its self-supervised representation learning paradigm and superior clustering performance.Although,two challenges emerge and result in high computational costs.Most existing contrastive methods adopt the data augmentation and then representation learning strategy,where representation learning with trainable graph convolution is coupled with complex and fixed data augmentation,inevitably limiting the efficiency and flexibility.The similarity metric between positive-negative sample pairs is complex and contrastive objective is partial,limiting the discriminability of representation learning.To solve these challenges,a novel wide graph clustering network(WGCN)adhering to representation and then augmentation framework is proposed,which mainly consists of multiorder filter fusion(MFF)and double-level contrastive learning(DCL)modules.Specifically,the MFF module integrates multiorder low-pass filters to extract smooth and multi-scale topological features,utilizing self-attention fusion to reduce redundancy and obtain comprehensive embedding representation.Further,the DCL module constructs two augmented views by the parallel parameter-unshared Siamese encoders rather than complex augmentations on graph.To achieve simple yet effective self-supervised learning,representation self-supervision and structural consistency oriented double-level contrastive loss is designed,where representation self-supervision maximizes the agreement between pairwise augmented embedding representations and structural consistency promotes the mutual information correlation between appending neighborhoods with similar semantics.Extensive experiments on six benchmark datasets demonstrate the superiority of the proposed WGCN,especially highlighting its time-saving characteristic.The code could be available in the https://github.com/Tianxiang Zhao0474/WGCN.展开更多
Convenient,rapid,and accurate detection of cardiac troponin I(cTnI)is crucial in early diagnosis of acute myocardial infarction(AMI).A paper-based electrochemical immunosensor is a promising choice in this field,becau...Convenient,rapid,and accurate detection of cardiac troponin I(cTnI)is crucial in early diagnosis of acute myocardial infarction(AMI).A paper-based electrochemical immunosensor is a promising choice in this field,because of the flexibility,porosity,and cost-efficacy of the paper.However,paper is poor in electronic conductivity and surface functionality.Herein,we report a paper-based electrochemical immunosensor for the label-free detection of cTnI with the working electrode modified by MXene(Ti_(3)C_(2))nanosheets.In order to immobilize the bio-receptor(anti-cTnI)on the MXene-modified working electrode,the MXene nanosheets were functionalized by aminosilane,and the functionalized MXene was immobilized onto the surface of the working electrode through Nafion.The large surface area of the MXene nanosheets facilitates the immobilization of antibodies,and the excellent conductivity facilitates the electron transfer between the electrochemical species and the underlying electrode surface.As a result,the paper-based immunosensor could detect cTnI within a wide range of 5-100 ng/mL with a detection limit of 0.58 ng/mL.The immunosensor also shows outstanding selectivity and good repeatability.Our MXene-modified paper-based electrochemical immunosensor enables fast and sensitive detection of cTnI,which may be used in real-time and cost-efficient monitoring of AMI diseases in clinics.展开更多
Supercapacitors are favored by researchers because of their high power density,especially with the acceleration of people’s life rhythm.However,their energy density,especially from the point of view of the whole ener...Supercapacitors are favored by researchers because of their high power density,especially with the acceleration of people’s life rhythm.However,their energy density,especially from the point of view of the whole energy storage device,is far lower than that of commercial batteries.In this work,a kind of customizable full paper-based supercapacitor device with excellent self-healing ability is fabricated by simple and low-cost screen printing,electropolymerization and dip coating methods.The resultant separatorfree supercapacitor device exhibits both ultrahigh gravimetric and areal specific energy(power)densities of 39 Wh kg^(-1)(69 k W kg^(-1))and 692μWh cm^(-2)(236 m W cm^(-2)),achieving excellent supercapacitor performance.Notably,the addition of vitrimers endows the whole device with outstanding self-healing properties,which is helpful for enhancing the adaptability of the device to the environment.In addition,this kind of paper-based device also displays good photothermal and electromagnetic shielding performances.These striking features make paper matrix composites attractive in the fields of supercapacitors,medical photothermal treatment and electromagnetic shielding.展开更多
It is well established that paper-based separators display short-circuit risk in lithium-ion batteries due to their intrinsic micron-sized pores.In this research,we have adjusted pore structure of paper by fiber swell...It is well established that paper-based separators display short-circuit risk in lithium-ion batteries due to their intrinsic micron-sized pores.In this research,we have adjusted pore structure of paper by fiber swelling in liquid electrolyte.Specifically,the paper-based separator is prepared by propionylated sisal fibers through a wet papermaking process.Scanning electron microscope(SEM)and multi-range X-ray nano-computed tomography(CT)images display strong swelling of modified fibers after electrolyte absorption,which can effectively decrease the pore size of separator.Due to the high electrolyte uptake(817 wt%),paper-based separator exhibits ionic conductivity of 2.93 mS cm^(-1).^(7)Li solid-state NMR spectroscopy and Gaussian simulation reveal that the formation of local high Li^(+)ion concentration in the separator and its low absorption energy with Li^(+) ion(62.2 kcal mol^(-1))is conducive to the ionic transportation.In particular,the assembled Li/separator/LiFePO_(4) cell displays wide electrochemical stability window(5.2 V)and excellent cycle performance(capacity retention of 96.6%after 100 cycles at 0.5C)due to the reduced side reactions as well as enhanced electrolyte absorption and retention capacity by propionylation.Our proposed strategy will provide a novel perspective to design high-performance biobased separators to boost the development of clean and sustainable energy economy.展开更多
Paper devices have recently attracted considerable attention as a class of cost-effective cell culture substrates for various biomedical applications.The paper biomaterial can be used to partially mimic the in vivo ce...Paper devices have recently attracted considerable attention as a class of cost-effective cell culture substrates for various biomedical applications.The paper biomaterial can be used to partially mimic the in vivo cell microenvironments mainly due to its natural three-dimensional characteristic.The paper-based devices provide precise control over their structures as well as cell distributions,allowing recapitulation of certain interactions between the cells and the extracellular matrix.These features have shown great potential for the development of normal and diseased human tissue models.In this review,we discuss the fabrication of paper-based devices for in vitro tissue modeling,as well as the applications of these devices toward drug screening and personalized medicine.It is believed that paper as a biomaterial will play an essential role in the field of tissue model engineering due to its unique performances,such as good biocompatibility,eco-friendliness,cost-effectiveness,and amenability to various biodesign and manufacturing needs.展开更多
In this paper,we presented a novel strategy to employ a plantderived carbohydrate polymer,i.e.,cellulose,to prepare a hydrophobic composite.Cellulose was used as a scaffold,and ethylene-propylene side by side(ES)fiber...In this paper,we presented a novel strategy to employ a plantderived carbohydrate polymer,i.e.,cellulose,to prepare a hydrophobic composite.Cellulose was used as a scaffold,and ethylene-propylene side by side(ES)fiber was thermally melted and then coated on the cellulose surface to achieve hydrophobicity.Experimental results revealed that the thermocoating ES fibers greatly increased the water contact angle of the cellulose scaffold from 25°to 153°while simultaneously enhanced the wet tensile strength of the composite approximately 6.7-fold(drying temperature of 170℃)compared with the pure cellulose paper.In particular,compared with other related research,the prepared cellulose-based composite possessed excellent hydrophobicity and superior mechanical strength,which introduces a new chemical engineering approach to prepare hydrophobic cellulose-based functional materials.展开更多
In recent years,paper-based functional materials have received extensive attention in the field of energy storage due to their advantages of rich and adjustable porous network structure and good flexibility.As an impo...In recent years,paper-based functional materials have received extensive attention in the field of energy storage due to their advantages of rich and adjustable porous network structure and good flexibility.As an important energy storage device,paper-based supercapacitors have important application prospects in many fields and have also received extensive attention from researchers in recent years.At present,researchers have modified and regulated paper-based materials by different means such as structural design and material composition to enhance their electrochemical storage capacity.The development of paper-based supercapacitors provides an important direction for the development of green and sustainable energy.Therefore,it is of great significance to summarize the relevant work of paper-based supercapacitors for their rapid development and application.In this review,the recent research progress of paper-based supercapacitors based on cellulose was summarized in terms of various cellulose-based composites,preparation skills,and electrochemical performance.Finally,some opinions on the problems in the development of this field and the future development trend were proposed.It is hoped that this review can provide valuable references and ideas for the rapid development of paper-based energy storage devices.展开更多
In traditional in situ polymerization preparation for solid-state electrolytes,initiators are directly added to the liquid precursor.In this article,a novel cellulose paper-based composite separator is fabricated,whic...In traditional in situ polymerization preparation for solid-state electrolytes,initiators are directly added to the liquid precursor.In this article,a novel cellulose paper-based composite separator is fabricated,which employs alumina as the inorganic reinforcing material and is loaded with polymerization initiator aluminum trifluoromethanesulfonate.Based upon this,a separator-induced in situ directional polymerization technique is demonstrated,and the extra addition of initiators into liquid precursors is no longer required.The polymerization starts from the surface and interior of the separator and extends outward with the gradually dissolving of initiators into the precursor.Compared with its traditional counterpart,the separator-induced poly(1,3-dioxolane)electrolyte shows improved interfacial contact as well as appropriately mitigated polymerization rate,which are conducive to practical applications.Electrochemical measurement results show that the prepared poly(1,3-dioxolane)solid electrolyte possesses an oxidation potential up to 4.4 V and a high Li+transference number of 0.72.After 1000 cycles at 2 C rate(340 mA g^(−1)),the assembled Li||LiFePO_(4)solid battery possesses a 106.8 mAh g^(−1)discharge capacity retention and 83.5%capacity retention ratio,with high average Coulombic efficiency of 99.5%achieved.Our work may provide new ideas for the design and application of in situ polymerization technique for solid electrolytes and solid batteries.展开更多
In this study,the effect of hot calendering process on the microstructure and properties of poly(p-phenylene terephthalamide)(PPTA) paper-based materials was investigated.The microstructures of the fracture surface,cr...In this study,the effect of hot calendering process on the microstructure and properties of poly(p-phenylene terephthalamide)(PPTA) paper-based materials was investigated.The microstructures of the fracture surface,crystalline structure,and single fiber strength of the PPTA paperbased materials as well as the different bonding behaviors between the PPTA fibers and PPTA fibrids obtained before and after the hot calendering process were examined.The results indicated that a high linear pressure would result in a limited improvement of the strength owing to the unimproved paper structure.The optimal values of tensile index and dielectric strength of 56.6 N·m/g and 27.6 kV/mm,respectively,could only be achieved with a synergistic effects of hot calendering temperature and linear pressure(240℃ and 110 k N/m,respectively).This result suggested it was possible to achieve a significant reinforcement and improvement in the interfacial bonding of functional PPTA paper-based materials,and avoid the formation of unexpected pleats and cracks in PPTA paper-based materials during the hot calendering process.展开更多
文摘Point-of-care testing(POCT)refers to a category of diagnostic tests that are performed at or near to the site of the patients(also called bedside testing)and is capable of obtaining accurate results in a short time by using portable diagnostic devices,avoiding sending samples to the medical laboratories.It has been extensively explored for diagnosing and monitoring patients’diseases and health conditions with the assistance of development in biochemistry and microfluidics.Microfluidic paper-based analytical devices(μPADs)have gained dramatic popularity in POCT because of their simplicity,user-friendly,fast and accurate result reading and low cost.SeveralμPADs have been successfully commercialized and received excellent feedback during the past several decades.This review briefly discusses the main types ofμPADs,preparation methods and their detection principles,followed by a few representative examples.The future perspectives of the development inμPADs are also provided.
基金funded by the Beijing Natural Science Foundation[Grant No.Z210006]the National Natural Science Foundation of China[Grant No.62275061].
文摘Nickel(II)as one of the primary categories of heavy metals can lead to serious health problems if achieving the critical levels in the water.Thus,it is vital to propose a stable,reliable,and economical approach for detecting Ni ions.The microfluidic paper-based analytical devices(µPADs)are potential candidates for the detection of water quality parameters including pH,heavy ions,nitrite and so on.However,it suffers from a huge error caused by the environment and artificial mistakes.In this study,we proposed an improved technique route to increase the stability and reliability of microfluidic paper-based analytical devices.The main technique points include a stable light source,a matched camera,improved reliability of the devices,and effective calculated methods.Finally,we established 15 standard curves that could be used to detect nickel ions and obtained uniform colorimetric results with reliability and repeatability.With those improvements,the relative errors for the five types of real water samples from the Zhongshan industrial parks were reduced to 0.26%,14.78%,24.20%,50.29%and 3.53%,respectively.These results were conducive to exploring this technique for the detection of nickel ions in wastewater from the Zhongshan industrial parks.The results demonstrated that the above technique route is promising for the detection of other heavy metal ions in industrial effluent.
基金Supported by the National Natural Science Foundation of China(62275053,62275256)the National key Research and Development Program of China(2021YFB3701500)+1 种基金the Youth Innovation Promotion Association of the Chinese Academy of Sciences(2023248)the Eastern Talent Plan Youth Project 2022,the Shanghai Key Laboratory of Optical Coatings and Spectral Modulation(23dz2260500).
文摘This study systematically investigated the influence of deposition rate on the structure,broadband opti⁃cal properties(1.0-13.0μm),and stress characteristics of Germanium(Ge)films.Additionally,a method for enhancing the performance of infrared filters based on rate-modulated deposition of Ge films was proposed.The optical absorption of Ge films in the short-wave infrared(SWIR)and long-wave infrared(LWIR)bands can be effectively reduced by modulating the deposition rate.As the deposition rate increases,the Ge films maintain an amorphous structure.The optical constants of the films in the 1.0-2.5μm and 2.5-13.0μm bands were precisely determined using the Cody-Lorentz model and the classical Lorentz oscillator model,respectively.Notably,high⁃er deposition rates result in a gradual increase in the refractive index.The extinction coefficient increases with the deposition rate in the SWIR region,attributed to the widening of the Urbach tail,while it decreases in the LWIR region due to the reduced absorption caused by the Ge-O stretching mode.Additionally,the films exhibit a tensile stress that decreases with increasing deposition rate.Finally,the effectiveness of the proposed fabrication method for an infrared filter with Ge films deposited at an optimized rate was demonstrated through practical examples.This work provides theoretical and technical support for the application of Ge films in high-performance infrared filters.
文摘The Savitzky-Golay(SG)filter,which employs polynomial least-squares approximations to smooth data and estimate derivatives,is widely used for processing noisy data.However,noise suppression by the SG filter is recognized to be limited at data boundaries and high frequencies,which can significantly reduce the signal-to-noise ratio(SNR).To solve this problem,a novel method synergistically integrating Principal Component Analysis(PCA)with SG filtering is proposed in this paper.This approach avoids the is-sue of excessive smoothing associated with larger window sizes.The proposed PCA-SG filtering algorithm was applied to a CO gas sensing system based on Cavity Ring-Down Spectroscopy(CRDS).The perform-ance of the PCA-SG filtering algorithm is demonstrated through comparison with Moving Average Filtering(MAF),Wavelet Transformation(WT),Kalman Filtering(KF),and the SG filter.The results demonstrate that the proposed algorithm exhibits superior noise reduction capabilities compared to the other algorithms evaluated.The SNR of the ring-down signal was improved from 11.8612 dB to 29.0913 dB,and the stand-ard deviation of the extracted ring-down time constant was reduced from 0.037μs to 0.018μs.These results confirm that the proposed PCA-SG filtering algorithm effectively improves the smoothness of the ring-down curve data,demonstrating its feasibility.
基金supported by the Royal Academy of Engineering,UK,in the scheme of Distinguished International Associate(DIA-2424-5-134).
文摘Accurate estimation of the State of Charge(SOC),State of Health(SOH),and Terminal Resistance(TR)is crucial for the effective operation of Battery Management Systems(BMS)in lithium-ion batteries.This study conducts a comprehensive comparative analysis of four Kalman filter variants Extended Kalman Filter(EKF),Extended Kalman-Bucy Filter(EKBF),Unscented Kalman Filter(UKF),and Unscented Kalman-Bucy Filter(UKBF)under varying battery parameter conditions.These include temperature fluctuation,self-discharge,current direction,cell capacity,process noise,and measurement noise.Our findings reveal significant variations in the performance of SOC and SOH predictions across filters,emphasizing that UKF demonstrates superior robustness to noise,while EKF performs better under accurate system dynamics.The study underscores the need for adaptive filtering strategies that can dynamically adjust to evolving battery parameters,thereby enhancing BMS reliability and extending battery lifespan.
基金supported by the National Natural Science Foundation of China(No.62371263)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.SJCK25_1995).
文摘1 Introduction Recently,the increasing demand for advanced telecommunication systems has spurred extensive research into bandpass filters(BPFs),with particular emphasis on miniaturization,reduction of insertion loss(IL),and enhancement of upper stopband rejection(Huang et al.,2021;Snyder et al.,2021;Lin et al.,2023;Zeng et al.,2023).
基金Supported by the Guangxi Special Program for Technological Innovation Guidance(No.GuiKeAC25069006).
文摘In this study,a fifth-degree cubature particle filter(5CPF)is proposed to address the limited estimation accuracy in traditional particle filter algorithms for bearings-only tracking(BOT).This algorithm calculates the recommended density function by introducing a fifth-degree cubature Kalman filter algorithm to guide particle sampling,which effectively alleviates the problem of particle degradation and significantly improves the estimation accuracy of the filter.However,the 5CPF algorithm exhibits high computational complexity,particularly in scenarios with a large number of particles.Therefore,we propose the extended Kalman filter(EKF)-5CPF algorithm,which employs an EKF to replace the time update step for each particle in the 5CPF.This enhances the algorithm’s real-time capability while maintaining the high precision advantage of the 5CPF algorithm.In addition,we construct bearing-only dual-station and single-motion station target tracking systems,and the filtering performances of 5CPF and EKF-5CPF algorithms under different conditions are analyzed.The results show that both the 5CPF algorithm and EKF-5CPF have strong robustness and can adapt to different noise environments.Furthermore,both algorithms significantly outperform traditional nonlinear filtering algorithms in terms of convergence speed,tracking accuracy,and overall stability.
基金supported by the Program of the National Natural Science Foundation of China(22238002)the Fundamental Research Funds for the Central Universities(DUT22-LAB610)Research and Innovation Team Project of Dalian University of Technology(DUT2022TB10).
文摘Color filters are essential components for optical modulation.However,conventional filters are restricted to operating exclusively in either reflective or transmissive mode.Furthermore,they suffer from limited UV and thermal stability,low color purity,and exhibit identical coloration on both surfaces.Herein,we propose a novel design strategy for trans-reflective color filters by integrating the absorptive properties of dye-doped polysulfone(PSU)with the diffractive capabilities of photonic crystals.This composite filter achieved broad-spectrum transmission with deep color outputs—yellow(0.410,0.510),magenta(0.446,0.231),and cyan(0.201,0.425)—closely aligned with standard color space coordinates.By tuning the refractive index of CeO_(2)@SiO_(2)nanoparticles to match dye-based PSU matrix,the transmittance of filters exceeded 70%.Moreover,dye-mediated absorption reduces the scattering light,thereby enhancing reflection color purity(full width at half maxima(FWHM)=25 nm)and producing vibrant blue,green,and red hues.The incorporation of UV-absorbing CeO_(2)@SiO_(2)nanoparticles effectively mitigated dye photodegradation,yielding exceptional UV stability(ΔT<2%under prolonged UV exposure).The filters also exhibited outstanding thermal stability(ΔT<1%after 30 min heat treatment at 230°C).This work establishes a robust materials design framework for multifunctional optical filters,advancing the development of highfidelity dual-mode color systems for next-generation display technologies.
基金funded by the Directorate General of Research and Development,Ministry of Higher Education,Science and Technology of the Republic of Indonesia,with grant number 2.6.63/UN32.14.1/LT/2025.
文摘Recommendation systems are an integral and indispensable part of every digital platform,as they can suggest content or items to users based on their respective needs.Collaborative filtering is a technique often used in various studies,which produces recommendations by analyzing similarities between users and items based on their behavior.Although often used,traditional collaborative filtering techniques still face the main challenge of sparsity.Sparsity problems occur when the data in the system is sparse,meaning that only a portion of users provide feedback on some items,resulting in inaccurate recommendations generated by the system.To overcome this problem,we developed aHybrid Collaborative Filtering model based onMatrix Factorization andGradient Boosting(HCF-MFGB),a new hybrid approach.Our proposed model integrates SVD++,the XGBoost ensemble learning algorithm,and utilizes user demographic data and meta items.We utilize information,both explicitly and implicitly,to learn user preference patterns using SVD++.The XGBoost algorithm is used to create hundreds of decision trees incrementally,thereby improving model accuracy.Meanwhile,user demographic and meta-item data are clustered using the K-Means Clustering algorithm to capture similarities in user and item characteristics.This combination is designed to improve rating prediction accuracy by reducing reliance on minimal explicit rating data,while addressing sparsity issues in movie recommendation systems.The results of experiments on the MovieLens 100K,MovieLens 1M,and CiaoDVD datasets show significant improvements,outperforming various other baselinemodels in terms of RMSE and MAE.On theMovieLens 100K dataset,the HCF-MFGB model obtained an RMSE value of 0.853 and an MAE value of 0.674.On theMovieLens 1M dataset,the HCF-MFGB model obtained an RMSE value of 0.763 and an MAE value of 0.61.On the CiaoDCD dataset,the HCF-MFGB model achieved an RMSE value of 0.718 and an MAE value of 0.495.These results confirm a significant improvement in movie recommendation accuracy with the proposed approach.
文摘This article presents an adaptive intelligent control strategy applied to a lumped-parameter evaporator model,i.e.,a simplified dynamic representation treating the evaporator as a single thermal node with uniform temperature distribution,suitable for control design due to its balance between physical fidelity and computational simplicity.The controller uses a wavelet-based neural proportional,integral,derivative(PID)controller with IIR filtering(infinite impulse response).The dynamic model captures the essential heat and mass transfer phenomena through a nonlinear energy balance,where the cooling capacity“Qevap”is expressed as a non-linear function of the compressor frequency and the temperature difference,specifically,Q_(evap)=k_(1)u(T_(in)−T_(e))with u as compressor frequency,Te evaporator temperature,and Tin inlet fluid temperature.The operating conditions of the system,in general terms,focus on the following variables,the overall thermal capacity is 1000 J/K,typical for small-capacity heat exchangers,The mass flow is 0.05 kg/s,typical for secondary liquid cooling circuits,the overall loss coefficient of 50 W/K that corresponds to small evaporators with partial insulation,the temperatures(inlet)of 10℃and the temperature of environment of 25℃,thermal load of 200 W that corresponds to a small-scaled air conditioning applications.To handle system nonlinearities and improve control performance,aMorlet wavelet-based neural network(Wavenet)is used to dynamically adjust the PID gains online.An IIR filter is incorporated to smooth the adaptive gains,improving stability and reducing oscillations.In contrast to prior wavelet-or neural-adaptive PID controllers in HVAC applications,which typically adjust gains without explicit filtering or not tailored to evaporator dynamics,this work introduces the first PID–Wavenet scheme augmented with an IIR-based stabilization layer,specifically designed to address the combined challenges of nonlinear evaporator behavior,gain oscillation,and real-time implementability.The proposed controller(PID-Wavenet+IIR)is implemented and validated inMATLAB/Simulink,demonstrating superior performance compared to a conventional PID tuned using Simulink’s auto-tuning function.Key results include a reduction in settling time from 13.3 to 8.2 s,a reduction in overshoot from 3.5%to 0.8%,a reduction in steady-state error from 0.12℃ to 0.02℃and a 13%reduction in energy overall consumption.The controller also exhibits greater robustness and adaptability under varying thermal loads.This explicit integration of wavelet-driven adaptation with IIR-filtered gain shaping constitutes the main methodological contribution and novelty of the work.These findings validate the effectiveness of the wavelet-based adaptive approach for advanced thermal management in refrigeration and HVAC systems,with potential applications in controlling variable-speed compressors,liquid chillers,and compact cooling units.
基金supported by the National Natural Science Foundation of China under Grant No.62471366。
文摘This article proposes a generalized strongly coupled resonator quartet(GSCRQ)filter along with its synthesis approach.By introducing out-of-band reflection zeros(RZs),the proposed GSCRQ can generate a transmission zero on each side of the passband without negative couplings.The coupling coefficients in this coupling structure change with the positions of the out-of-band RZs.Thus,the GSCRQ configuration admits flexible design solutions.For GSCRQ coaxial combline filters,all couplings can be implemented as inductive couplings,simplifying the design and manufacturing process.In this article,a 6-2 filter in the GSCRQ configuration is synthesized and designed.The simulated results of the designed filter agree very well with the theoretical characteristics.
基金supported by the National Natural Science Foundation of China(62225303,62403043,62433004)the Beijing Natural Science Foundation(4244085)+1 种基金the Postdoctoral Fellowship Program of China Postdoctoral Science Foundation(GZC20230203)the China Postdoctoral Science Foundation(2023M740201)。
文摘Deep graph contrastive clustering has attracted widespread attentions due to its self-supervised representation learning paradigm and superior clustering performance.Although,two challenges emerge and result in high computational costs.Most existing contrastive methods adopt the data augmentation and then representation learning strategy,where representation learning with trainable graph convolution is coupled with complex and fixed data augmentation,inevitably limiting the efficiency and flexibility.The similarity metric between positive-negative sample pairs is complex and contrastive objective is partial,limiting the discriminability of representation learning.To solve these challenges,a novel wide graph clustering network(WGCN)adhering to representation and then augmentation framework is proposed,which mainly consists of multiorder filter fusion(MFF)and double-level contrastive learning(DCL)modules.Specifically,the MFF module integrates multiorder low-pass filters to extract smooth and multi-scale topological features,utilizing self-attention fusion to reduce redundancy and obtain comprehensive embedding representation.Further,the DCL module constructs two augmented views by the parallel parameter-unshared Siamese encoders rather than complex augmentations on graph.To achieve simple yet effective self-supervised learning,representation self-supervision and structural consistency oriented double-level contrastive loss is designed,where representation self-supervision maximizes the agreement between pairwise augmented embedding representations and structural consistency promotes the mutual information correlation between appending neighborhoods with similar semantics.Extensive experiments on six benchmark datasets demonstrate the superiority of the proposed WGCN,especially highlighting its time-saving characteristic.The code could be available in the https://github.com/Tianxiang Zhao0474/WGCN.
基金financially supported by the National Key R&D Program of China(2017YFA0204700)the Joint Research Funds of Department of Science&Technology of Shaanxi Province and Northwestern Polytechnical University(2020GXLH-Z-021)+1 种基金the China-Sweden Joint Mobility Project(51811530018)the Fundamental Research Funds for the Central Universities.
文摘Convenient,rapid,and accurate detection of cardiac troponin I(cTnI)is crucial in early diagnosis of acute myocardial infarction(AMI).A paper-based electrochemical immunosensor is a promising choice in this field,because of the flexibility,porosity,and cost-efficacy of the paper.However,paper is poor in electronic conductivity and surface functionality.Herein,we report a paper-based electrochemical immunosensor for the label-free detection of cTnI with the working electrode modified by MXene(Ti_(3)C_(2))nanosheets.In order to immobilize the bio-receptor(anti-cTnI)on the MXene-modified working electrode,the MXene nanosheets were functionalized by aminosilane,and the functionalized MXene was immobilized onto the surface of the working electrode through Nafion.The large surface area of the MXene nanosheets facilitates the immobilization of antibodies,and the excellent conductivity facilitates the electron transfer between the electrochemical species and the underlying electrode surface.As a result,the paper-based immunosensor could detect cTnI within a wide range of 5-100 ng/mL with a detection limit of 0.58 ng/mL.The immunosensor also shows outstanding selectivity and good repeatability.Our MXene-modified paper-based electrochemical immunosensor enables fast and sensitive detection of cTnI,which may be used in real-time and cost-efficient monitoring of AMI diseases in clinics.
基金financially supported by the National Natural Science Foundation of China(No.22078184)the China Postdoctoral Science Foundation(No.2019M653853XB)+6 种基金the Natural Science Foundation of Shaanxi Province(No.2020JQ-729)the Key Projects of Collaborative Innovation Center of Shaanxi Provincial Department of Educationthe Opening Project of Guangxi Key Laboratory of Clean Pulp&Papermaking and Pollution Control(No.2019KF21)the Natural Science Advance Research Foundation of Shaanxi University of Science and Technology(No.2018QNBJ-03)the National Demonstration Center for Experimental Light Chemistry Engineering Education(No.2018QGSJ02-13)the Jiangxi Qingyue Technology Co.,Ltd(No.210200122)the Biomass Chemistry and Materials Academician Workstation Project in SUST(No.134090002)。
文摘Supercapacitors are favored by researchers because of their high power density,especially with the acceleration of people’s life rhythm.However,their energy density,especially from the point of view of the whole energy storage device,is far lower than that of commercial batteries.In this work,a kind of customizable full paper-based supercapacitor device with excellent self-healing ability is fabricated by simple and low-cost screen printing,electropolymerization and dip coating methods.The resultant separatorfree supercapacitor device exhibits both ultrahigh gravimetric and areal specific energy(power)densities of 39 Wh kg^(-1)(69 k W kg^(-1))and 692μWh cm^(-2)(236 m W cm^(-2)),achieving excellent supercapacitor performance.Notably,the addition of vitrimers endows the whole device with outstanding self-healing properties,which is helpful for enhancing the adaptability of the device to the environment.In addition,this kind of paper-based device also displays good photothermal and electromagnetic shielding performances.These striking features make paper matrix composites attractive in the fields of supercapacitors,medical photothermal treatment and electromagnetic shielding.
基金supported by the Natural Science Foundation of Guangxi Province(2018GXNSFBA138027)the Scientific Research Foundation of Guangxi University(XGZ170232)the National Enterprise Technology Center of Guangxi Bossco Environmental Protection Technology Co.,Ltd(202100033)。
文摘It is well established that paper-based separators display short-circuit risk in lithium-ion batteries due to their intrinsic micron-sized pores.In this research,we have adjusted pore structure of paper by fiber swelling in liquid electrolyte.Specifically,the paper-based separator is prepared by propionylated sisal fibers through a wet papermaking process.Scanning electron microscope(SEM)and multi-range X-ray nano-computed tomography(CT)images display strong swelling of modified fibers after electrolyte absorption,which can effectively decrease the pore size of separator.Due to the high electrolyte uptake(817 wt%),paper-based separator exhibits ionic conductivity of 2.93 mS cm^(-1).^(7)Li solid-state NMR spectroscopy and Gaussian simulation reveal that the formation of local high Li^(+)ion concentration in the separator and its low absorption energy with Li^(+) ion(62.2 kcal mol^(-1))is conducive to the ionic transportation.In particular,the assembled Li/separator/LiFePO_(4) cell displays wide electrochemical stability window(5.2 V)and excellent cycle performance(capacity retention of 96.6%after 100 cycles at 0.5C)due to the reduced side reactions as well as enhanced electrolyte absorption and retention capacity by propionylation.Our proposed strategy will provide a novel perspective to design high-performance biobased separators to boost the development of clean and sustainable energy economy.
基金This work was supported by the National Institutes of Health(R00CA201603,R21EB025270,R21EB026175,R01EB028143)the Brigham Research Institute.
文摘Paper devices have recently attracted considerable attention as a class of cost-effective cell culture substrates for various biomedical applications.The paper biomaterial can be used to partially mimic the in vivo cell microenvironments mainly due to its natural three-dimensional characteristic.The paper-based devices provide precise control over their structures as well as cell distributions,allowing recapitulation of certain interactions between the cells and the extracellular matrix.These features have shown great potential for the development of normal and diseased human tissue models.In this review,we discuss the fabrication of paper-based devices for in vitro tissue modeling,as well as the applications of these devices toward drug screening and personalized medicine.It is believed that paper as a biomaterial will play an essential role in the field of tissue model engineering due to its unique performances,such as good biocompatibility,eco-friendliness,cost-effectiveness,and amenability to various biodesign and manufacturing needs.
基金supported by Natural Science Foundation of China(No.31770624 and No.21978029)National Key R&D Program of China(No.2018YFD0400703)+2 种基金Natural Science Foundation of Liaoning(No.20170540069)the Program for Liaoning Excellent Talents in University(LR2016058)Liaoning Million Talents Program(201945).
文摘In this paper,we presented a novel strategy to employ a plantderived carbohydrate polymer,i.e.,cellulose,to prepare a hydrophobic composite.Cellulose was used as a scaffold,and ethylene-propylene side by side(ES)fiber was thermally melted and then coated on the cellulose surface to achieve hydrophobicity.Experimental results revealed that the thermocoating ES fibers greatly increased the water contact angle of the cellulose scaffold from 25°to 153°while simultaneously enhanced the wet tensile strength of the composite approximately 6.7-fold(drying temperature of 170℃)compared with the pure cellulose paper.In particular,compared with other related research,the prepared cellulose-based composite possessed excellent hydrophobicity and superior mechanical strength,which introduces a new chemical engineering approach to prepare hydrophobic cellulose-based functional materials.
基金supported by the fund of the National Natural Science Foundation of China(22078184,22171170)the China Postdoctoral Science Foundation(2019M653853XB)+1 种基金the Natural Science Advance Research Foundation of Shaanxi University of Science and Technology(2018QNBJ-03)Major Scientific and Technological Innovation Projects in Shandong Province(2019TSLH0316)
文摘In recent years,paper-based functional materials have received extensive attention in the field of energy storage due to their advantages of rich and adjustable porous network structure and good flexibility.As an important energy storage device,paper-based supercapacitors have important application prospects in many fields and have also received extensive attention from researchers in recent years.At present,researchers have modified and regulated paper-based materials by different means such as structural design and material composition to enhance their electrochemical storage capacity.The development of paper-based supercapacitors provides an important direction for the development of green and sustainable energy.Therefore,it is of great significance to summarize the relevant work of paper-based supercapacitors for their rapid development and application.In this review,the recent research progress of paper-based supercapacitors based on cellulose was summarized in terms of various cellulose-based composites,preparation skills,and electrochemical performance.Finally,some opinions on the problems in the development of this field and the future development trend were proposed.It is hoped that this review can provide valuable references and ideas for the rapid development of paper-based energy storage devices.
基金supported by the National Natural Science Foundation of China(Grant Nos.52072105,21676067)the Key R&D Program of Anhui Province(202104a05020044)+2 种基金the Anhui Provincial Natural Science Foundation(2108085J23)Science and Technology Major Project of Anhui Province(202003a05020014)the Fundamental Research Funds for the Central Universities(PA2021KCPY0028,JZ2020YYPY0109).
文摘In traditional in situ polymerization preparation for solid-state electrolytes,initiators are directly added to the liquid precursor.In this article,a novel cellulose paper-based composite separator is fabricated,which employs alumina as the inorganic reinforcing material and is loaded with polymerization initiator aluminum trifluoromethanesulfonate.Based upon this,a separator-induced in situ directional polymerization technique is demonstrated,and the extra addition of initiators into liquid precursors is no longer required.The polymerization starts from the surface and interior of the separator and extends outward with the gradually dissolving of initiators into the precursor.Compared with its traditional counterpart,the separator-induced poly(1,3-dioxolane)electrolyte shows improved interfacial contact as well as appropriately mitigated polymerization rate,which are conducive to practical applications.Electrochemical measurement results show that the prepared poly(1,3-dioxolane)solid electrolyte possesses an oxidation potential up to 4.4 V and a high Li+transference number of 0.72.After 1000 cycles at 2 C rate(340 mA g^(−1)),the assembled Li||LiFePO_(4)solid battery possesses a 106.8 mAh g^(−1)discharge capacity retention and 83.5%capacity retention ratio,with high average Coulombic efficiency of 99.5%achieved.Our work may provide new ideas for the design and application of in situ polymerization technique for solid electrolytes and solid batteries.
基金the financial support to this research from the open fund of state key laboratory for modification of chemical fibers and polymer materials (LK1601)projects of education department of Shaanxi provincial government (15JF012)National Natural Science Foundation of China (51402180)
文摘In this study,the effect of hot calendering process on the microstructure and properties of poly(p-phenylene terephthalamide)(PPTA) paper-based materials was investigated.The microstructures of the fracture surface,crystalline structure,and single fiber strength of the PPTA paperbased materials as well as the different bonding behaviors between the PPTA fibers and PPTA fibrids obtained before and after the hot calendering process were examined.The results indicated that a high linear pressure would result in a limited improvement of the strength owing to the unimproved paper structure.The optimal values of tensile index and dielectric strength of 56.6 N·m/g and 27.6 kV/mm,respectively,could only be achieved with a synergistic effects of hot calendering temperature and linear pressure(240℃ and 110 k N/m,respectively).This result suggested it was possible to achieve a significant reinforcement and improvement in the interfacial bonding of functional PPTA paper-based materials,and avoid the formation of unexpected pleats and cracks in PPTA paper-based materials during the hot calendering process.
