To examine the impact of anthropogenic land reconstruction,particularly the consolidation of small terraces into larger fields,on soil organic carbon(SOC),total nitrogen(TN)dynamics,rice yield,and its components,soil ...To examine the impact of anthropogenic land reconstruction,particularly the consolidation of small terraces into larger fields,on soil organic carbon(SOC),total nitrogen(TN)dynamics,rice yield,and its components,soil and plant samples were collected from seven newly reconstructed fields in Japanese Andosols in Tochigi,Japan.Samples were obtained from both the former low-and high-elevation sides within each field plot.During harvest season,nine rice plants were randomly selected from each plot(0.675 m^(2),comprising 3 rows and 3 hills per row),collected from a 3-m stretch along both the east(former low side)and west(former high side)ridges.Soil cores were collected from identical plots at two depths(0–15 and 15–30 cm)and combined into one composite sample per layer.Rice plant samples were air-dried for two weeks until reaching constant moisture content,after which stems and ears were separated and weighed to determine biomass,yield,yield components,and nitrogen uptake.This indicated that land reconstruction significantly affected rice yield and its components between the two sides of all field plots.SOC,TN,and their decomposition following land reconstruction showed notable changes,especially in the 15–30 cm subsurface soil layer.Additionally,grain weight demonstrated significant correlation with SOC,TN,and carbon decomposition in both the 0–15 and 15–30 cm layers,indicating that soil fertility to a depth of 30 cm was crucial for rice productivity after land reconstruction.展开更多
The deformation characteristics and thermal response of anchor rods are crucial for ensuring the stability and safety of surrounding rock support structures.However,existing research has predominantly concentrated on ...The deformation characteristics and thermal response of anchor rods are crucial for ensuring the stability and safety of surrounding rock support structures.However,existing research has predominantly concentrated on the mechanical performance of anchor rods,with limited attention to the coupled evolution of strain and temperature fields during tensile deformation.This knowledge gap hinders a comprehensive understanding of the synergistic mechanical-thermal response mechanisms in anchor rods under loading conditions.To address this limitation,the present study systematically investigated the evolution of strain and temperature fields,along with their correlation,during the test of micro-negative Poisson's ratio(NPR)and ordinary Poisson's ratio(PR)anchor rods.Digital image correlation(DIC)and infrared thermography(IRT)techniques were employed for this exploration.The uniaxial tensile tests were conducted at two different rates,and the ordinary PR anchor rod(Q235 anchor rod)was established as a control group for comparative analysis.The findings reveal that the micro-NPR anchor rod exhibit strain localization at multiple locations during the tensile process,whereas Q235 anchors show local strain concentration in only one region.The standard deviation evolution curves for both the strain and temperature field exhibit two distinct phases in the two anchor rods.The evolution patterns between these two types of curves are basically consistent.The two standard deviation curves for the micro-NPR anchor rod display a wavy increase in the second phase,while for the Q235 anchor rod,they increase steadily until the specimen is damaged.The correlation analysis reveals that the standard deviations of strain and temperature differences for both types of anchor rods are significantly correlated.These findings demonstrate the synergistic evolution mechanism of deformation and thermal response,providing a potential foundation for utilizing thermal monitoring to assess the stability of rock support structures.展开更多
While neural radiance field(NeRF)methods have shown promising results in generating talking faces,existing studies primarily focus on the correlation between avatars and driving sources.However,these studies often ove...While neural radiance field(NeRF)methods have shown promising results in generating talking faces,existing studies primarily focus on the correlation between avatars and driving sources.However,these studies often overlook emotion modeling,resulting in the generation of emotionless or unnatural facial animations.In response,this paper introduces an audio-driven and emotion-editing dynamic NeRF(AED-NeRF)approach,designed for the real-time generation of expressive talking face avatars driven by audio inputs.Specifically,we integrate audio features into a grid-based NeRF to compensate for the lack of a deformation channel,successfully capturing lip dynamics and enabling end-to-end generation from audio-driven sources to talking face avatars.Emotion labels,comprising emotion categories and intensity levels,guide the proposed NeRF framework to implicitly model visual emotions,allowing for explicit control and editing of facial expressions.Extensive qualitative and quantitative experiments validate the effectiveness and advantages of our proposed method,demonstrating its ability to achieve real-time,photo-realistic talking face avatar generation across different audio and emotion scenarios.展开更多
Current image inpainting models are primarily designed to achieve a large receptive field(RF)using refinement networks to incorporate different scales.However,these models fail to adapt the use of different RFs to the...Current image inpainting models are primarily designed to achieve a large receptive field(RF)using refinement networks to incorporate different scales.However,these models fail to adapt the use of different RFs to the specific patterns of image damage,resulting in artifacts and semantic information confusion in repaired images.To address the problems of artifacts and semantic information confusion,inspired by different sensitivities of different RFs to inpainting the same image damaged patterns,this study proposes an image inpainting method based on multiple receptive fields(MRFs)and dynamic matching of damaged patterns.First,the parallel filter banks are used to extract the MRF feature groups.Second,the features are dynamically weighted and screened,guided by the mask image,to construct a relationship that adaptively matches the most relevant RF to each specific damaged pattern.A fast Fourier convolution based decoder is used to enhance the fusion of global contextual features during the reconstruction of high dimensional features into low dimensional images.Comparative experimental results show that the proposed method achieves better subjective and objective inpainting results on three public datasets:Paris StreetView,CelebA-HQ,and Places2.展开更多
How to transform an electromagnetic field across non-inertial frames of reference is a common challenge encountered in electromagnetic space measurements and analyses.Finding clear and precise ways to evaluate transfo...How to transform an electromagnetic field across non-inertial frames of reference is a common challenge encountered in electromagnetic space measurements and analyses.Finding clear and precise ways to evaluate transformation formulas can be difficult.This study presents results of a thorough theoretical investigation that has yielded universal transformation formulas;these transformations are successfully applied to two specific scenarios.We find that,for space plasmas,if the relative velocities of structures are significantly lower than the speed of light,Galilean transformations are suitable.The transformations presented in this paper are applicable,in low speed situations,to electromagnetic fields,electric potentials and magnetic vector potentials,and to charge density and current density,measured in various non-inertial reference frames.Truncation errors associated with these simplified transformations are calculated and shown to be acceptable.These findings have broad implications for space physics measurements and analyses.We address two key issues related to non-inertial frame transformations:first,how to derive a general formula for the rotational electric potential of planets with intrinsic magnetic fields;second,how to verify rigorously the calculation of charge density from MMS(Magnetospheric Multiscale)electrostatic field measurements.We suggest that,due to the validity of the Coulomb gauge,the Poisson equation can be applied in situations of low-speed motion,allowing MMS measurement data to be used to calculate minimal-error charge density.展开更多
This paper introduces a framework for modeling random fields,with a particular emphasis on analyzing anisotropic spatial variability.It establishes a clear connection between the correlation function and the Kriging v...This paper introduces a framework for modeling random fields,with a particular emphasis on analyzing anisotropic spatial variability.It establishes a clear connection between the correlation function and the Kriging variogram across various anisotropic modes,providing mathematical models to enhance our understanding of random fields.A new anisotropy index,called LSAI,is introduced to quantify anisotropy based on the autocorrelation length and the orientation of the principal axes within the variogram.An LSAI value closer to one indicates a lower degree of anisotropy.The present study examines how the degree of anisotropy varies with different autocorrelation lengths and angles between the principal axes,providing valuable insights into these relationships.To improve the accuracy of parameter probability distribution estimations,this study integrates limited field test data using a Bayesian inference approach.Additionally,the Markov chain Monte Carlo simulation method is employed to develop a conditional random field(CRF)for the deformation modulus.By incorporating data from field bearing plate tests,the posterior variance data for the deformation modulus are derived.This process facilitates the construction of a detailed and reliable CRF for the deformation modulus.展开更多
Heliostat field design for tower solar thermal plants must jointly address solar geometry,optical losses,and layout optimization under engineering constraints.We develop an end-to-end workflow that(i)adopts a consiste...Heliostat field design for tower solar thermal plants must jointly address solar geometry,optical losses,and layout optimization under engineering constraints.We develop an end-to-end workflow that(i)adopts a consistent East–North–Up(ENU)convention for all plant-and sun-related vectors;(ii)integrates cosine efficiency,projection-based shading and blocking(SB),atmospheric transmittance,and an HFLCAL(heliostat field local calculation)truncation model into a single optical chain;and(iii)couples an Eliminate-Blocking(EB)layout prior with an improved“Cheetah”metaheuristic to search ring topology,mirror sizes,and heights while enforcing spacing,kinematics,and rated-power requirements.Projection-based SB is calibrated against Monte-Carlo ray tracing at representative sun positions,and the HFLCAL truncation model is used to quantify sensitivities to sunshape and error-budget parameters.In a three-phase study(fixed-size baseline,uniform sizing,heterogeneous sizing),the EB-guided optimizer improves annual per-area output relative to a radial baseline and reliably attains a 60 MW target.Under equal evaluation budgets,the proposed optimizer converges faster and with lower variance than GA-and PSO-based baselines,while respecting panel-level peak-flux limits through a smooth penalization of flux violations.The resulting layouts exhibit outward-increasing azimuthal spacing and ring-wise size sharing that are consistent with recent heliostat-field deployment experience.The framework is modular,auditable,and readily adaptable to alternative receivers,sites,and cost-aware objectives.展开更多
This study presents preliminary results of tidal-induced magnetic field signals extracted from 9 months of data collected by the Macao Science Satellite-1(MSS-1) from November 2023 to July 2024. Tidal signals were iso...This study presents preliminary results of tidal-induced magnetic field signals extracted from 9 months of data collected by the Macao Science Satellite-1(MSS-1) from November 2023 to July 2024. Tidal signals were isolated using sequential modeling techniques by subtracting non-tidal field model predictions from observed magnetic data. The extracted MSS-1 results show strong agreement with those from the Swarm and CryoSat satellites. MSS-1 effectively captures key large-scale tidal-induced magnetic anomalies, mainly due to its unique 41-degree low-inclination orbit, which provides wide coverage of local times. This finding underscores the strong potential of MSS-1 to recover high-resolution global tidal magnetic field models as more MSS-1 data become available.展开更多
With the continuous upgrading of traditional manufacturing industries and the rapid rise of emerging technology fields,the performance requirements for the permanent magnet synchronous motors(PMSMs)have become higher ...With the continuous upgrading of traditional manufacturing industries and the rapid rise of emerging technology fields,the performance requirements for the permanent magnet synchronous motors(PMSMs)have become higher and higher.The importance of fast and accurate electromagnetic thermal coupling analysis of such motors becomes more and more prominent.In view of this,the surfacemounted PMSM(SPMSM)equipped with unequally thick magnetic poles is taken as the main object and its electromagnetic thermal coupling analytical model(ETc AM)is investigated.First,the electromagnetic analytical model(EAM)is studied based on the modified subdomain method.It realizes the fast calculation of key electromagnetic characteristics.Subsequently,the 3D thermal analytical model(TAM)is developed by combining the EAM,the lumped parameter thermal network method(LPTNM),and the partial differential equation of heat flux.It realizes the fast calculation of key thermal characteristics in 3D space.Further,the information transfer channel between EAM and TAM is built with reference to the intrinsic connection between electromagnetic field and temperature field.Thereby,the novel ETcAM is proposed to realize the fast and accurate prediction of electromagnetic and temperature fields.Besides,ETcAM has a lot to commend it.One is that it well accounts for the complex structure,saturation,and heat exchange behavior.Second,it saves a lot of computer resources.It offers boundless possibilities for initial design,scheme evaluation,and optimization of motors.Finally,the validity,accuracy,and practicality of this study are verified by simulation and experiment.展开更多
Aircraft disturbs the adjacent atmospheric environment in flight,forming spatial distribution features of atmospheric density that differ from the natural background,which may potentially be utilized as tracer charact...Aircraft disturbs the adjacent atmospheric environment in flight,forming spatial distribution features of atmospheric density that differ from the natural background,which may potentially be utilized as tracer characteristics to introduce new technologies for indirectly sensing the presence of aircraft.In this paper,the concept of a long-range aircraft detection based on the atmospheric disturbance density field is proposed,and the detection mode of tomographic imaging of the scattering light of an atmospheric disturbance flow field is designed.By modeling the spatial distribution of the disturbance density field,the scattered echo signal images of active light towards the disturbance field at long distance are simulated.On this basis,the characteristics of the disturbance optical signal at the optimal detection resolution are analyzed.The results show that the atmospheric disturbance flow field of the supersonic aircraft presents circular in the light-scattering echo images.The disturbance signal can be further highlighted by differential processing of the adjacent scattering images.As the distance behind the aircraft increases,the diffusion range of the disturbance signal increases,and the signal intensity and contrast with the background decrease.Under the ground-based observation conditions of the aircraft at a height of 10000 m,a Mach number of1.6,and a detection distance of 100 km,the contrast between the disturbance signal and the back-ground was 30 d B at a distance of one time from the rear of the fuselage,and the diffusion diameter of the disturbance signal was 50 m.At a distance eight times the length of the aircraft,the contrast decreased to 10 dB,and the diameter increased to 290 m.The contrast was reduced to 3 dB at a distance nine times the length of the aircraft,and the diameter was diffused to 310 m.These results indicate the possibility of long-range aircraft detection based on the characteristics of the atmospheric density field.展开更多
Nitrate(NO_(3)^(-))accumulation and transport processes in the thick vadose zone affect the evolution of the groundwater NO_(3)^(-)content in intensive agricultural regions.Agricultural land-use change(ALUC),typically...Nitrate(NO_(3)^(-))accumulation and transport processes in the thick vadose zone affect the evolution of the groundwater NO_(3)^(-)content in intensive agricultural regions.Agricultural land-use change(ALUC),typically accompanied by substantial alterations in nitrogen fertilizer application and irrigation practices,is an important influencing factor.This study evaluated the changes in NO_(3)^(-)accumulation and transport in the deep vadose zone(DVZ,below the root zone),and the groundwater NO_(3)^(-)content associated with ALUC from grain to vegetable fields in the North China Plain(NCP).The ALUC from grain to vegetable resulted in nitrate–nitrogen(NO_(3)^(-)-N)accumulation in DVZ increased by 235.5 kg ha^(-1)m^(-1)(163.2%)in the piedmont plain and 224.9 kg ha^(-1)m^(-1)(102.7%)in the central plain,respectively.This change accelerated downward transport velocity in the DVZ(from 0.81±0.47 to 0.89±0.55 m yr^(-1)in the piedmont plain,and from 0.24±0.12 to 0.92±0.12 m yr^(-1)in the central plain)and increased NO_(3)^(-)leaching fluxes.High transport velocity and leaching fluxes resulted in chemical N-fertilizer entering the aquifer in several areas in the piedmont plain.The impact of the agricultural activity intensity changes,accompanied by the ALUC,on groundwater quantity and quality should be considered in similar regions.展开更多
In photocatalysis field,S-scheme heterojunctions show unique advantages and prospects.However,the carrier shielding effect of heterojunctions limits the separation and migration of interfacial charges.In this study,a ...In photocatalysis field,S-scheme heterojunctions show unique advantages and prospects.However,the carrier shielding effect of heterojunctions limits the separation and migration of interfacial charges.In this study,a strategy of“dynamic cascade electric fields to deplete unilaterally accumulated charges”was innovatively proposed to overcome this drawback.By modulating g-C_(3)N_(4)(CN)and Bi_(2)WO_(6)(BWO)using the polarized electric field(PEF)of spontaneously polarized ceramic(SPC),a BWO/SPC-CN composite with cascade internal electric field(IEF)and PEF was successfully constructed for efficient piezophotocatalytic degradation of recalcitrant pollutants.BWO/SPC-CN contributed to 96.8% degradation of carbamazepine,significantly surpassing BWO/CN(70.5%).BWO/SPC-CN performed excellent capacity of harvesting piezoelectric energy due to its unique three-dimensional porous nano-network structure.The PEF of SPC modulated the electronic band structure and thus strengthened the IEF of BWO/SPC-CN,providing a persistent driving force for interfacial charge migration.Moreover,SPC with a strong PEF unilaterally consumed the charges accumulated on CN under periodic piezoelectricity,weakening the shielding electric field to inhibit the recombination of electron-hole pairs.As a consequence,the dynamic cascade PEF-IEF ultimately broke the carrier shielding effect in heterojunction photocatalysis and enhanced interfacial electron transfer.This work provides reliable methods to enhance the interfacial charge transfer in heterojunction and new insights into piezo-photocatalytic mechanism.展开更多
Development of robust electrocatalyst for oxygen reduction reaction(ORR)in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries(SZABs).Herein,constructing a local electric field c...Development of robust electrocatalyst for oxygen reduction reaction(ORR)in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries(SZABs).Herein,constructing a local electric field coupled with chloride ions(Cl-)fixation strategy in dual single-atom catalysts(DSACs)was proposed,and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte,with a high half-wave potential(E_(1/2))of 0.868 V and a good maximum power density(Pmax)of 182 mW·cm^(−2)in the assembled SZABs,much higher than those of the Pt/C catalyst(E_(1/2):0.846 V;Pmax:150 mW·cm^(−2)).The in-situ characterization and theoretical calculations revealed that the Fe sites have a higher Cl^(−)adsorption affinity than the Co sites,and preferentially adsorbs Cl^(−)in a seawater electrolyte during the ORR process,and thus constructs a low-concentration Cl^(−)local microenvironment through the common-ion exclusion effect,which prevents Cl^(−)adsorption and corrosion in the Co active centers,achieving impressive catalytic stability.In addition,the directional charge movement between Fe and Co atomic pairs establishes a local electric field,optimizing the adsorption energy of Co sites for oxygen-containing intermediates,and further improving the ORR activity.展开更多
Seepage refers to the flow of water through porous materials.This phenomenon has a crucial role in dam,slope,excavation,tunnel,and well design.Performing seepage analysis usually is a challenging task,as one must cope...Seepage refers to the flow of water through porous materials.This phenomenon has a crucial role in dam,slope,excavation,tunnel,and well design.Performing seepage analysis usually is a challenging task,as one must cope with the uncertainty associated with the parameters such as the hydraulic conductivity in the horizontal and vertical directions that drive this phenomenon.However,at the same time,the data on horizontal and vertical hydraulic conductivities are typically scarce in spatial resolution.In this context,so-called non-traditional approaches for uncertainty quantification(such as intervals and fuzzy variables)offer an interesting alternative to classical probabilistic methods,since they have been shown to be quite effective when limited information on the governing parameters of a phenomenon is available.Therefore,the main contribution of this study is the development of a framework for conducting seepage analysis in saturated soils,where uncertainty associated with hydraulic conductivity is characterized using fuzzy fields.This method to characterize uncertainty extends interval fields towards the domain of fuzzy numbers.In fact,it is illustrated that fuzzy fields are an effective tool for capturing uncertainties with a spatial component,since they allow one to account for available physical measurements.A case study in confined saturated soil shows that with the proposed framework,it is possible to quantify the uncertainty associated with seepage flow,exit gradient,and uplift force effectively.展开更多
The article discusses the prospects of using algae in the soil—to improve the fertility of rice fields in the Osh oblast of Kyrgyzstan.The authors note that the Fergana Valley,where Osh oblast is located,is an import...The article discusses the prospects of using algae in the soil—to improve the fertility of rice fields in the Osh oblast of Kyrgyzstan.The authors note that the Fergana Valley,where Osh oblast is located,is an important rice-grow-ing region,and there are currently plans to expand rice fields.In this regard,the study of methods to increase rice yields,such as algolization,is of particular relevance.The article emphasizes that rice fields are unique aquatic ecosystems where microorganisms,especially algae,play an important role.Algae,particularly blue-green algae(cyanobacteria),are capable of fixing nitrogen from the air and enrich the soil with it,which is especially important for rice,which needs nitrogen for growth.The algolization method helps to improve soil structure,reduce the need for mineral fertilizers,control weeds and is an environmentally friendly method of fertility improvement.The authors provide data on the spe-cies composition of cyanobacteria found in rice fields in Osh oblast,noting the predominance of Chroococcus and Hor-mogonium forms.They also indicate seasonal fluctuations in algae abundance associated with climatic conditions.In conclusion,the authors highlight the promising application of algolization in rice farming in Osh oblast and the need for further research to identify the most effective algal species and develop optimal methods of their application.展开更多
The extreme removal of SiO2 and MnO inclusions in 304 stainless steel in supergravity fields was investigated using an inhouse high-temperature supergravity equipment.The influences of the gravity coefficient and sepa...The extreme removal of SiO2 and MnO inclusions in 304 stainless steel in supergravity fields was investigated using an inhouse high-temperature supergravity equipment.The influences of the gravity coefficient and separation time on the removal efficiency of the inclusions were studied.After supergravity treatment,the inclusions migrated to the top of the sample and formed large aggregates.Meanwhile,the lower part of the sample was purified considerably and appeared significantly cleaner than the raw material.At the gravity coefficient of 500 and separation time of 600 s,the total oxygen content at the bottom of the sample(position E)decreased from 240 to 28 ppm.This corresponded to a total oxygen removal rate of 88.33%.The volume fraction and number density of inclusions exhibited a gradient distribution along the supergravity direction,with values of 8.5%and 106 mm^(-2) at the top of the sample(position A)and 0.06%and 22 mm^(-2) at its bottom.展开更多
This study presents an experimental investigation of the coupled caloric effect driven by dual-fields in metamagnetic alloy ErCo_(2) with strong magneto-structural coupling.Magnetic measurements were conducted under d...This study presents an experimental investigation of the coupled caloric effect driven by dual-fields in metamagnetic alloy ErCo_(2) with strong magneto-structural coupling.Magnetic measurements were conducted under different pressures,revealing that the application of hydrostatic pressure stabilizes a small volume of paramagnetism(PM) phase,resulting in a shift of the phase transition temperature towards the low-temperature region.This shift is opposite to the temperature associated with the magnetic field-driven phase transition.As pressure increases,the metamagnetic transition in ErCo_(2) is suppressed,and the hysteresis disappears.However,the produced cross-coupling caloric effect compensates the decrease in entropy change caused by the disappearance of the metamagnetic transition.As a result,a reversible giant magnetocaloric effect of 46.2 J/(kg·K) without hysteresis is achieved at a pressure of 0.910 GPa.Moreover,we propose that the temperature span of ErCo_(2) can be significantly widened by optimizing the thermodynamic pathway of the magnetic and pressure fields,overcoming the defect of a narrow temperature range.展开更多
In this paper we present certain bilinear estimates for commutators on Besov spaces with variable smoothness and integrability,and under no vanishing assumptions on the divergence of vector fields.Such commutator esti...In this paper we present certain bilinear estimates for commutators on Besov spaces with variable smoothness and integrability,and under no vanishing assumptions on the divergence of vector fields.Such commutator estimates are motivated by the study of well-posedness results for some models in incompressible fuid mechanics.展开更多
As the plasma current power in tokamak devices increases,a significant number of stray magnetic fields are generated around the equipment.These stray magnetic fields can disrupt the operation of electronic power devic...As the plasma current power in tokamak devices increases,a significant number of stray magnetic fields are generated around the equipment.These stray magnetic fields can disrupt the operation of electronic power devices,particularly transformers in switched-mode power supplies.Testing flyback converters with transformers under strong background magnetic fields highlights electromagnetic compatibility(EMC)issues for such switched-mode power supplies.This study utilizes finite element analysis software to simulate the electromagnetic environment of switched-mode power supply transformers and investigates the impact of variations in different magnetic field parameters on the performance of switched-mode power supplies under strong stray magnetic fields.The findings indicate that EMC issues are associated with transformer core saturation and can be alleviated through appropriate configurations of the core size,air gap,fillet radius,and installation direction.This study offers novel solutions for addressing EMC issues in high magnetic field environments.展开更多
Lithium-sulfurized polyacrylonitrile(Li-SPAN)batteries are an advanced class of Li-S energy storage systems that effectively mitigate the poly sulfide shuttle effect.However,conventional SPAN cathodes experience low a...Lithium-sulfurized polyacrylonitrile(Li-SPAN)batteries are an advanced class of Li-S energy storage systems that effectively mitigate the poly sulfide shuttle effect.However,conventional SPAN cathodes experience low active material retention(<40 wt%)and sluggish electrochemical kinetics,which limit their practical application.To address these challenges,this study introduces a CoS_(2)/NiS_(2)@SeSPAN composite nanofiber membrane as a high-performance Li-SPAN cathode.The cathode was synthesized through electro spinning Co/Ni salts with PAN,followed by hydrothermal deposition of Ni-ZIF-67 and SeSx-assisted thermal treatment to form a CoS_(2)/NiS_(2)heterostructure within the SeSPAN matrix.Experimental validation and density functional theory simulations confirmed that the cathode electrolyte interphase layer effectively encapsulated the active material,extending the solidstate reaction pathway.This hierarchical porous architecture enabled a high active material loading of 59 wt%,which considerably exceeds that of conventional SPANbased cathodes.The three-dimensional interconnected fiber network maximized the exposure of the CoS_(2)/NiS_(2)heterojunction,while the metal sulfides increased the conductivity to facilitate efficient electron and ion transport.The intrinsic electric field within the CoS_(2)/NiS_(2)hetero structure further enhanced poly sulfide adsorption and catalytic conversion,accelerating the electrochemical kinetics.As a result,the CoS_(2)/NiS_(2)@SeSPAN cathode had an initial discharge capacity of 678 mAh g^(-1)at 0.2C,maintaining 634 mAh g^(-1)at 0.5C.Remarkably,the battery maintained 98.2%of its capacity after 800 cycles,highlighting its outstanding long-term cycling stability.The substantial potential of CoS_(2)/NiS_(2)@SeSPAN for highperformance Li-SP AN batteries and the critical role of hetero structure engineering in next-generation energy storage technologies are highlighted in this study.展开更多
基金support of the Japanese Government(Monbukagakusho)Scholarship for his studies in Japansupported by the Yamagata University YU-COE(S)program and by the Advanced Agri-food System Research Center of Yamagata University,Japan+2 种基金financially supported by a Japan Society for the Promotion of Science(JSPS)Grant-in-Aid for Scientific Research(26310304)Yamagata University YU-COE(S)programby the Advanced Agri-food System Research Center of Yamagata University,Japan。
文摘To examine the impact of anthropogenic land reconstruction,particularly the consolidation of small terraces into larger fields,on soil organic carbon(SOC),total nitrogen(TN)dynamics,rice yield,and its components,soil and plant samples were collected from seven newly reconstructed fields in Japanese Andosols in Tochigi,Japan.Samples were obtained from both the former low-and high-elevation sides within each field plot.During harvest season,nine rice plants were randomly selected from each plot(0.675 m^(2),comprising 3 rows and 3 hills per row),collected from a 3-m stretch along both the east(former low side)and west(former high side)ridges.Soil cores were collected from identical plots at two depths(0–15 and 15–30 cm)and combined into one composite sample per layer.Rice plant samples were air-dried for two weeks until reaching constant moisture content,after which stems and ears were separated and weighed to determine biomass,yield,yield components,and nitrogen uptake.This indicated that land reconstruction significantly affected rice yield and its components between the two sides of all field plots.SOC,TN,and their decomposition following land reconstruction showed notable changes,especially in the 15–30 cm subsurface soil layer.Additionally,grain weight demonstrated significant correlation with SOC,TN,and carbon decomposition in both the 0–15 and 15–30 cm layers,indicating that soil fertility to a depth of 30 cm was crucial for rice productivity after land reconstruction.
基金supported by State Key Laboratory for Geomechanics and Deep Underground Engineering,China University of Mining&Technology,Beijing(Grant No.SKLGDUEK2120)。
文摘The deformation characteristics and thermal response of anchor rods are crucial for ensuring the stability and safety of surrounding rock support structures.However,existing research has predominantly concentrated on the mechanical performance of anchor rods,with limited attention to the coupled evolution of strain and temperature fields during tensile deformation.This knowledge gap hinders a comprehensive understanding of the synergistic mechanical-thermal response mechanisms in anchor rods under loading conditions.To address this limitation,the present study systematically investigated the evolution of strain and temperature fields,along with their correlation,during the test of micro-negative Poisson's ratio(NPR)and ordinary Poisson's ratio(PR)anchor rods.Digital image correlation(DIC)and infrared thermography(IRT)techniques were employed for this exploration.The uniaxial tensile tests were conducted at two different rates,and the ordinary PR anchor rod(Q235 anchor rod)was established as a control group for comparative analysis.The findings reveal that the micro-NPR anchor rod exhibit strain localization at multiple locations during the tensile process,whereas Q235 anchors show local strain concentration in only one region.The standard deviation evolution curves for both the strain and temperature field exhibit two distinct phases in the two anchor rods.The evolution patterns between these two types of curves are basically consistent.The two standard deviation curves for the micro-NPR anchor rod display a wavy increase in the second phase,while for the Q235 anchor rod,they increase steadily until the specimen is damaged.The correlation analysis reveals that the standard deviations of strain and temperature differences for both types of anchor rods are significantly correlated.These findings demonstrate the synergistic evolution mechanism of deformation and thermal response,providing a potential foundation for utilizing thermal monitoring to assess the stability of rock support structures.
基金supported by ZTE Industry-University-Institute Cooperation Funds under Grant No.IA20230921015。
文摘While neural radiance field(NeRF)methods have shown promising results in generating talking faces,existing studies primarily focus on the correlation between avatars and driving sources.However,these studies often overlook emotion modeling,resulting in the generation of emotionless or unnatural facial animations.In response,this paper introduces an audio-driven and emotion-editing dynamic NeRF(AED-NeRF)approach,designed for the real-time generation of expressive talking face avatars driven by audio inputs.Specifically,we integrate audio features into a grid-based NeRF to compensate for the lack of a deformation channel,successfully capturing lip dynamics and enabling end-to-end generation from audio-driven sources to talking face avatars.Emotion labels,comprising emotion categories and intensity levels,guide the proposed NeRF framework to implicitly model visual emotions,allowing for explicit control and editing of facial expressions.Extensive qualitative and quantitative experiments validate the effectiveness and advantages of our proposed method,demonstrating its ability to achieve real-time,photo-realistic talking face avatar generation across different audio and emotion scenarios.
基金The National Natural Science Foundation of China(No.62261032)the Central Government Guiding Funds for Local Scienceand Technology Development Program(No.25ZYJA026).
文摘Current image inpainting models are primarily designed to achieve a large receptive field(RF)using refinement networks to incorporate different scales.However,these models fail to adapt the use of different RFs to the specific patterns of image damage,resulting in artifacts and semantic information confusion in repaired images.To address the problems of artifacts and semantic information confusion,inspired by different sensitivities of different RFs to inpainting the same image damaged patterns,this study proposes an image inpainting method based on multiple receptive fields(MRFs)and dynamic matching of damaged patterns.First,the parallel filter banks are used to extract the MRF feature groups.Second,the features are dynamically weighted and screened,guided by the mask image,to construct a relationship that adaptively matches the most relevant RF to each specific damaged pattern.A fast Fourier convolution based decoder is used to enhance the fusion of global contextual features during the reconstruction of high dimensional features into low dimensional images.Comparative experimental results show that the proposed method achieves better subjective and objective inpainting results on three public datasets:Paris StreetView,CelebA-HQ,and Places2.
基金supported by the National Natural Science Foundation of China(Grants No.42130202(CS),42564008(YJ))the National Key Research and Development Program of China(Grant No.2022YFA1604600(CS))+2 种基金supported by the Shenzhen Technology Project(Grant no.JCYJ20241202123905008)Ningxia Natural Science Foundation(No.2024AAC03080)the International Space Science Institute(ISSI)in Bern,through ISSI International Team project#556(Cross-scale energy transfer in space plasmas).
文摘How to transform an electromagnetic field across non-inertial frames of reference is a common challenge encountered in electromagnetic space measurements and analyses.Finding clear and precise ways to evaluate transformation formulas can be difficult.This study presents results of a thorough theoretical investigation that has yielded universal transformation formulas;these transformations are successfully applied to two specific scenarios.We find that,for space plasmas,if the relative velocities of structures are significantly lower than the speed of light,Galilean transformations are suitable.The transformations presented in this paper are applicable,in low speed situations,to electromagnetic fields,electric potentials and magnetic vector potentials,and to charge density and current density,measured in various non-inertial reference frames.Truncation errors associated with these simplified transformations are calculated and shown to be acceptable.These findings have broad implications for space physics measurements and analyses.We address two key issues related to non-inertial frame transformations:first,how to derive a general formula for the rotational electric potential of planets with intrinsic magnetic fields;second,how to verify rigorously the calculation of charge density from MMS(Magnetospheric Multiscale)electrostatic field measurements.We suggest that,due to the validity of the Coulomb gauge,the Poisson equation can be applied in situations of low-speed motion,allowing MMS measurement data to be used to calculate minimal-error charge density.
基金supported by the Doctoral Research Funds for Nanchang HangKong University,China(Grant No.EA202411211)support is gratefully acknowledged.
文摘This paper introduces a framework for modeling random fields,with a particular emphasis on analyzing anisotropic spatial variability.It establishes a clear connection between the correlation function and the Kriging variogram across various anisotropic modes,providing mathematical models to enhance our understanding of random fields.A new anisotropy index,called LSAI,is introduced to quantify anisotropy based on the autocorrelation length and the orientation of the principal axes within the variogram.An LSAI value closer to one indicates a lower degree of anisotropy.The present study examines how the degree of anisotropy varies with different autocorrelation lengths and angles between the principal axes,providing valuable insights into these relationships.To improve the accuracy of parameter probability distribution estimations,this study integrates limited field test data using a Bayesian inference approach.Additionally,the Markov chain Monte Carlo simulation method is employed to develop a conditional random field(CRF)for the deformation modulus.By incorporating data from field bearing plate tests,the posterior variance data for the deformation modulus are derived.This process facilitates the construction of a detailed and reliable CRF for the deformation modulus.
文摘Heliostat field design for tower solar thermal plants must jointly address solar geometry,optical losses,and layout optimization under engineering constraints.We develop an end-to-end workflow that(i)adopts a consistent East–North–Up(ENU)convention for all plant-and sun-related vectors;(ii)integrates cosine efficiency,projection-based shading and blocking(SB),atmospheric transmittance,and an HFLCAL(heliostat field local calculation)truncation model into a single optical chain;and(iii)couples an Eliminate-Blocking(EB)layout prior with an improved“Cheetah”metaheuristic to search ring topology,mirror sizes,and heights while enforcing spacing,kinematics,and rated-power requirements.Projection-based SB is calibrated against Monte-Carlo ray tracing at representative sun positions,and the HFLCAL truncation model is used to quantify sensitivities to sunshape and error-budget parameters.In a three-phase study(fixed-size baseline,uniform sizing,heterogeneous sizing),the EB-guided optimizer improves annual per-area output relative to a radial baseline and reliably attains a 60 MW target.Under equal evaluation budgets,the proposed optimizer converges faster and with lower variance than GA-and PSO-based baselines,while respecting panel-level peak-flux limits through a smooth penalization of flux violations.The resulting layouts exhibit outward-increasing azimuthal spacing and ring-wise size sharing that are consistent with recent heliostat-field deployment experience.The framework is modular,auditable,and readily adaptable to alternative receivers,sites,and cost-aware objectives.
基金financially supported by the National Natural Science Foundation of China(42250102,42250101)the Macao Foundation and Macao Science and Technology Development Fund(0001/2019/A1)the Pre-research Project on Civil Aerospace Technologies funded by China National Space Administration(D020303)。
文摘This study presents preliminary results of tidal-induced magnetic field signals extracted from 9 months of data collected by the Macao Science Satellite-1(MSS-1) from November 2023 to July 2024. Tidal signals were isolated using sequential modeling techniques by subtracting non-tidal field model predictions from observed magnetic data. The extracted MSS-1 results show strong agreement with those from the Swarm and CryoSat satellites. MSS-1 effectively captures key large-scale tidal-induced magnetic anomalies, mainly due to its unique 41-degree low-inclination orbit, which provides wide coverage of local times. This finding underscores the strong potential of MSS-1 to recover high-resolution global tidal magnetic field models as more MSS-1 data become available.
基金supported by the Project of National Natural Science Foundation of China under Grant 52077122。
文摘With the continuous upgrading of traditional manufacturing industries and the rapid rise of emerging technology fields,the performance requirements for the permanent magnet synchronous motors(PMSMs)have become higher and higher.The importance of fast and accurate electromagnetic thermal coupling analysis of such motors becomes more and more prominent.In view of this,the surfacemounted PMSM(SPMSM)equipped with unequally thick magnetic poles is taken as the main object and its electromagnetic thermal coupling analytical model(ETc AM)is investigated.First,the electromagnetic analytical model(EAM)is studied based on the modified subdomain method.It realizes the fast calculation of key electromagnetic characteristics.Subsequently,the 3D thermal analytical model(TAM)is developed by combining the EAM,the lumped parameter thermal network method(LPTNM),and the partial differential equation of heat flux.It realizes the fast calculation of key thermal characteristics in 3D space.Further,the information transfer channel between EAM and TAM is built with reference to the intrinsic connection between electromagnetic field and temperature field.Thereby,the novel ETcAM is proposed to realize the fast and accurate prediction of electromagnetic and temperature fields.Besides,ETcAM has a lot to commend it.One is that it well accounts for the complex structure,saturation,and heat exchange behavior.Second,it saves a lot of computer resources.It offers boundless possibilities for initial design,scheme evaluation,and optimization of motors.Finally,the validity,accuracy,and practicality of this study are verified by simulation and experiment.
文摘Aircraft disturbs the adjacent atmospheric environment in flight,forming spatial distribution features of atmospheric density that differ from the natural background,which may potentially be utilized as tracer characteristics to introduce new technologies for indirectly sensing the presence of aircraft.In this paper,the concept of a long-range aircraft detection based on the atmospheric disturbance density field is proposed,and the detection mode of tomographic imaging of the scattering light of an atmospheric disturbance flow field is designed.By modeling the spatial distribution of the disturbance density field,the scattered echo signal images of active light towards the disturbance field at long distance are simulated.On this basis,the characteristics of the disturbance optical signal at the optimal detection resolution are analyzed.The results show that the atmospheric disturbance flow field of the supersonic aircraft presents circular in the light-scattering echo images.The disturbance signal can be further highlighted by differential processing of the adjacent scattering images.As the distance behind the aircraft increases,the diffusion range of the disturbance signal increases,and the signal intensity and contrast with the background decrease.Under the ground-based observation conditions of the aircraft at a height of 10000 m,a Mach number of1.6,and a detection distance of 100 km,the contrast between the disturbance signal and the back-ground was 30 d B at a distance of one time from the rear of the fuselage,and the diffusion diameter of the disturbance signal was 50 m.At a distance eight times the length of the aircraft,the contrast decreased to 10 dB,and the diameter increased to 290 m.The contrast was reduced to 3 dB at a distance nine times the length of the aircraft,and the diameter was diffused to 310 m.These results indicate the possibility of long-range aircraft detection based on the characteristics of the atmospheric density field.
基金National Natural Science Foundation of China,No.41930865Project for Innovative Capacity Improvement in Hebei Province,No.225A4201D。
文摘Nitrate(NO_(3)^(-))accumulation and transport processes in the thick vadose zone affect the evolution of the groundwater NO_(3)^(-)content in intensive agricultural regions.Agricultural land-use change(ALUC),typically accompanied by substantial alterations in nitrogen fertilizer application and irrigation practices,is an important influencing factor.This study evaluated the changes in NO_(3)^(-)accumulation and transport in the deep vadose zone(DVZ,below the root zone),and the groundwater NO_(3)^(-)content associated with ALUC from grain to vegetable fields in the North China Plain(NCP).The ALUC from grain to vegetable resulted in nitrate–nitrogen(NO_(3)^(-)-N)accumulation in DVZ increased by 235.5 kg ha^(-1)m^(-1)(163.2%)in the piedmont plain and 224.9 kg ha^(-1)m^(-1)(102.7%)in the central plain,respectively.This change accelerated downward transport velocity in the DVZ(from 0.81±0.47 to 0.89±0.55 m yr^(-1)in the piedmont plain,and from 0.24±0.12 to 0.92±0.12 m yr^(-1)in the central plain)and increased NO_(3)^(-)leaching fluxes.High transport velocity and leaching fluxes resulted in chemical N-fertilizer entering the aquifer in several areas in the piedmont plain.The impact of the agricultural activity intensity changes,accompanied by the ALUC,on groundwater quantity and quality should be considered in similar regions.
基金financially supported by the National Natural Science Foundation of China(No.22068007).
文摘In photocatalysis field,S-scheme heterojunctions show unique advantages and prospects.However,the carrier shielding effect of heterojunctions limits the separation and migration of interfacial charges.In this study,a strategy of“dynamic cascade electric fields to deplete unilaterally accumulated charges”was innovatively proposed to overcome this drawback.By modulating g-C_(3)N_(4)(CN)and Bi_(2)WO_(6)(BWO)using the polarized electric field(PEF)of spontaneously polarized ceramic(SPC),a BWO/SPC-CN composite with cascade internal electric field(IEF)and PEF was successfully constructed for efficient piezophotocatalytic degradation of recalcitrant pollutants.BWO/SPC-CN contributed to 96.8% degradation of carbamazepine,significantly surpassing BWO/CN(70.5%).BWO/SPC-CN performed excellent capacity of harvesting piezoelectric energy due to its unique three-dimensional porous nano-network structure.The PEF of SPC modulated the electronic band structure and thus strengthened the IEF of BWO/SPC-CN,providing a persistent driving force for interfacial charge migration.Moreover,SPC with a strong PEF unilaterally consumed the charges accumulated on CN under periodic piezoelectricity,weakening the shielding electric field to inhibit the recombination of electron-hole pairs.As a consequence,the dynamic cascade PEF-IEF ultimately broke the carrier shielding effect in heterojunction photocatalysis and enhanced interfacial electron transfer.This work provides reliable methods to enhance the interfacial charge transfer in heterojunction and new insights into piezo-photocatalytic mechanism.
基金supported by the National Natural Science Foundation of China(52164028,52274297)the Start-up Research Foundation of Hainan University(KYQD(ZR)20008,KYQD(ZR)21125,KYQD(ZR)23169))+1 种基金Collaborative Innovation Center of Marine Science and Technology of Hainan University(XTCX2022HYC14)Innovative Research Project for Postgraduate Students in Hainan Province(Qhyb2024-95).
文摘Development of robust electrocatalyst for oxygen reduction reaction(ORR)in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries(SZABs).Herein,constructing a local electric field coupled with chloride ions(Cl-)fixation strategy in dual single-atom catalysts(DSACs)was proposed,and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte,with a high half-wave potential(E_(1/2))of 0.868 V and a good maximum power density(Pmax)of 182 mW·cm^(−2)in the assembled SZABs,much higher than those of the Pt/C catalyst(E_(1/2):0.846 V;Pmax:150 mW·cm^(−2)).The in-situ characterization and theoretical calculations revealed that the Fe sites have a higher Cl^(−)adsorption affinity than the Co sites,and preferentially adsorbs Cl^(−)in a seawater electrolyte during the ORR process,and thus constructs a low-concentration Cl^(−)local microenvironment through the common-ion exclusion effect,which prevents Cl^(−)adsorption and corrosion in the Co active centers,achieving impressive catalytic stability.In addition,the directional charge movement between Fe and Co atomic pairs establishes a local electric field,optimizing the adsorption energy of Co sites for oxygen-containing intermediates,and further improving the ORR activity.
文摘Seepage refers to the flow of water through porous materials.This phenomenon has a crucial role in dam,slope,excavation,tunnel,and well design.Performing seepage analysis usually is a challenging task,as one must cope with the uncertainty associated with the parameters such as the hydraulic conductivity in the horizontal and vertical directions that drive this phenomenon.However,at the same time,the data on horizontal and vertical hydraulic conductivities are typically scarce in spatial resolution.In this context,so-called non-traditional approaches for uncertainty quantification(such as intervals and fuzzy variables)offer an interesting alternative to classical probabilistic methods,since they have been shown to be quite effective when limited information on the governing parameters of a phenomenon is available.Therefore,the main contribution of this study is the development of a framework for conducting seepage analysis in saturated soils,where uncertainty associated with hydraulic conductivity is characterized using fuzzy fields.This method to characterize uncertainty extends interval fields towards the domain of fuzzy numbers.In fact,it is illustrated that fuzzy fields are an effective tool for capturing uncertainties with a spatial component,since they allow one to account for available physical measurements.A case study in confined saturated soil shows that with the proposed framework,it is possible to quantify the uncertainty associated with seepage flow,exit gradient,and uplift force effectively.
文摘The article discusses the prospects of using algae in the soil—to improve the fertility of rice fields in the Osh oblast of Kyrgyzstan.The authors note that the Fergana Valley,where Osh oblast is located,is an important rice-grow-ing region,and there are currently plans to expand rice fields.In this regard,the study of methods to increase rice yields,such as algolization,is of particular relevance.The article emphasizes that rice fields are unique aquatic ecosystems where microorganisms,especially algae,play an important role.Algae,particularly blue-green algae(cyanobacteria),are capable of fixing nitrogen from the air and enrich the soil with it,which is especially important for rice,which needs nitrogen for growth.The algolization method helps to improve soil structure,reduce the need for mineral fertilizers,control weeds and is an environmentally friendly method of fertility improvement.The authors provide data on the spe-cies composition of cyanobacteria found in rice fields in Osh oblast,noting the predominance of Chroococcus and Hor-mogonium forms.They also indicate seasonal fluctuations in algae abundance associated with climatic conditions.In conclusion,the authors highlight the promising application of algolization in rice farming in Osh oblast and the need for further research to identify the most effective algal species and develop optimal methods of their application.
基金supported by the National Natural Science Foundation of China(No.52174275).
文摘The extreme removal of SiO2 and MnO inclusions in 304 stainless steel in supergravity fields was investigated using an inhouse high-temperature supergravity equipment.The influences of the gravity coefficient and separation time on the removal efficiency of the inclusions were studied.After supergravity treatment,the inclusions migrated to the top of the sample and formed large aggregates.Meanwhile,the lower part of the sample was purified considerably and appeared significantly cleaner than the raw material.At the gravity coefficient of 500 and separation time of 600 s,the total oxygen content at the bottom of the sample(position E)decreased from 240 to 28 ppm.This corresponded to a total oxygen removal rate of 88.33%.The volume fraction and number density of inclusions exhibited a gradient distribution along the supergravity direction,with values of 8.5%and 106 mm^(-2) at the top of the sample(position A)and 0.06%and 22 mm^(-2) at its bottom.
基金supported by the National Key R&D Program of China (2021YFB3501202,2021YFB3501204,2019YFA0704900,2020YFA0711500,2023YFA1406003,2022YFB3505201)the National Natural Science Foundation of China (52088101,U23A20550,92263202,22361132534)the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB33030200)。
文摘This study presents an experimental investigation of the coupled caloric effect driven by dual-fields in metamagnetic alloy ErCo_(2) with strong magneto-structural coupling.Magnetic measurements were conducted under different pressures,revealing that the application of hydrostatic pressure stabilizes a small volume of paramagnetism(PM) phase,resulting in a shift of the phase transition temperature towards the low-temperature region.This shift is opposite to the temperature associated with the magnetic field-driven phase transition.As pressure increases,the metamagnetic transition in ErCo_(2) is suppressed,and the hysteresis disappears.However,the produced cross-coupling caloric effect compensates the decrease in entropy change caused by the disappearance of the metamagnetic transition.As a result,a reversible giant magnetocaloric effect of 46.2 J/(kg·K) without hysteresis is achieved at a pressure of 0.910 GPa.Moreover,we propose that the temperature span of ErCo_(2) can be significantly widened by optimizing the thermodynamic pathway of the magnetic and pressure fields,overcoming the defect of a narrow temperature range.
文摘In this paper we present certain bilinear estimates for commutators on Besov spaces with variable smoothness and integrability,and under no vanishing assumptions on the divergence of vector fields.Such commutator estimates are motivated by the study of well-posedness results for some models in incompressible fuid mechanics.
基金supported by the Natural Science Foundation of Anhui Province(No.228085ME142)the Comprehensive Research Facility for the Fusion Technology Program of China(No.20180000527301001228)the Open Fund of the Magnetic Confinement Fusion Laboratory of Anhui Province(No.2024AMF04003)。
文摘As the plasma current power in tokamak devices increases,a significant number of stray magnetic fields are generated around the equipment.These stray magnetic fields can disrupt the operation of electronic power devices,particularly transformers in switched-mode power supplies.Testing flyback converters with transformers under strong background magnetic fields highlights electromagnetic compatibility(EMC)issues for such switched-mode power supplies.This study utilizes finite element analysis software to simulate the electromagnetic environment of switched-mode power supply transformers and investigates the impact of variations in different magnetic field parameters on the performance of switched-mode power supplies under strong stray magnetic fields.The findings indicate that EMC issues are associated with transformer core saturation and can be alleviated through appropriate configurations of the core size,air gap,fillet radius,and installation direction.This study offers novel solutions for addressing EMC issues in high magnetic field environments.
基金financially supported by the National Natural Science Foundation of China (Nos.52271011 and 52102291)
文摘Lithium-sulfurized polyacrylonitrile(Li-SPAN)batteries are an advanced class of Li-S energy storage systems that effectively mitigate the poly sulfide shuttle effect.However,conventional SPAN cathodes experience low active material retention(<40 wt%)and sluggish electrochemical kinetics,which limit their practical application.To address these challenges,this study introduces a CoS_(2)/NiS_(2)@SeSPAN composite nanofiber membrane as a high-performance Li-SPAN cathode.The cathode was synthesized through electro spinning Co/Ni salts with PAN,followed by hydrothermal deposition of Ni-ZIF-67 and SeSx-assisted thermal treatment to form a CoS_(2)/NiS_(2)heterostructure within the SeSPAN matrix.Experimental validation and density functional theory simulations confirmed that the cathode electrolyte interphase layer effectively encapsulated the active material,extending the solidstate reaction pathway.This hierarchical porous architecture enabled a high active material loading of 59 wt%,which considerably exceeds that of conventional SPANbased cathodes.The three-dimensional interconnected fiber network maximized the exposure of the CoS_(2)/NiS_(2)heterojunction,while the metal sulfides increased the conductivity to facilitate efficient electron and ion transport.The intrinsic electric field within the CoS_(2)/NiS_(2)hetero structure further enhanced poly sulfide adsorption and catalytic conversion,accelerating the electrochemical kinetics.As a result,the CoS_(2)/NiS_(2)@SeSPAN cathode had an initial discharge capacity of 678 mAh g^(-1)at 0.2C,maintaining 634 mAh g^(-1)at 0.5C.Remarkably,the battery maintained 98.2%of its capacity after 800 cycles,highlighting its outstanding long-term cycling stability.The substantial potential of CoS_(2)/NiS_(2)@SeSPAN for highperformance Li-SP AN batteries and the critical role of hetero structure engineering in next-generation energy storage technologies are highlighted in this study.
