Development of robust electrocatalyst for oxygen reduction reaction(ORR)in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries(SZABs).Herein,constructing a local electric field c...Development of robust electrocatalyst for oxygen reduction reaction(ORR)in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries(SZABs).Herein,constructing a local electric field coupled with chloride ions(Cl-)fixation strategy in dual single-atom catalysts(DSACs)was proposed,and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte,with a high half-wave potential(E_(1/2))of 0.868 V and a good maximum power density(Pmax)of 182 mW·cm^(−2)in the assembled SZABs,much higher than those of the Pt/C catalyst(E_(1/2):0.846 V;Pmax:150 mW·cm^(−2)).The in-situ characterization and theoretical calculations revealed that the Fe sites have a higher Cl^(−)adsorption affinity than the Co sites,and preferentially adsorbs Cl^(−)in a seawater electrolyte during the ORR process,and thus constructs a low-concentration Cl^(−)local microenvironment through the common-ion exclusion effect,which prevents Cl^(−)adsorption and corrosion in the Co active centers,achieving impressive catalytic stability.In addition,the directional charge movement between Fe and Co atomic pairs establishes a local electric field,optimizing the adsorption energy of Co sites for oxygen-containing intermediates,and further improving the ORR activity.展开更多
Batteries play a critical role in electric vehicles and distributed energy generation.With the growing demand for energy storage solutions,new battery materials and systems are continually being developed.In this proc...Batteries play a critical role in electric vehicles and distributed energy generation.With the growing demand for energy storage solutions,new battery materials and systems are continually being developed.In this process,molecular dynamics(MD)simulations can reveal the microscopic mechanisms of battery processes,thereby boosting the design of batteries.Compared to other MD simulation techniques,the machine learning force field(MLFF)holds the advantages of first-principles accuracy along with large spatial and temporal scale,offering opportunities to uncover new mechanisms in battery systems.This review presents a detailed overview of the fundamental principles and model types of MLFFs,as well as their applications in simulating the structure,transport properties,and chemical reaction properties of bulk battery materials and interfaces.Notably,we emphasize the long-range interaction corrections and constant-potential methods in the model design of MLFFs.Finally,we discuss the challenges and prospects of applying MLFF models in the research of batteries.展开更多
In a rapid cycling synchrotron(RCS),the magnetic field is synchronized with the beam energy,creating a highly dynamic magnetic environment.A ceramic chamber with a shielding layer(RF shield),composed of a series of co...In a rapid cycling synchrotron(RCS),the magnetic field is synchronized with the beam energy,creating a highly dynamic magnetic environment.A ceramic chamber with a shielding layer(RF shield),composed of a series of copper strips connected to a capacitor at either end,is typically employed as a vacuum chamber to mitigate eddy current effects and beam coupling impedance.Consequently,the ceramic chamber exhibits a thin-walled multilayered complex structure.Previous theoretical studies have suggested that the impedance of such a structure has a negligible impact on the beam.However,recent impedance measurements of the ceramic chamber in the China Spallation Neutron Source(CSNS)RCS revealed a resonance in the low-frequency range,which was confirmed by further theoretical analysis as a source of beam instability in the RCS.Currently,the magnitude of this impedance cannot be accurately assessed using theoretical calculations.In this study,we used the CST Microwave Studio to confirm the impedance of the ceramic chamber.Further simulations covering six different types of ceramic chambers were conducted to develop an impedance model in the RCS.Additionally,this study investigates the resonant characteristics of the ceramic chamber impedance,finding that the resonant frequency is closely related to the capacitance of the capacitors.This finding provides clear directions for further impedance optimization and is crucial for achieving a beam power of 500 kW for the CSNS Phase-Ⅱ project(CSNS-Ⅱ).However,careful attention must be paid to the voltage across the capacitors.展开更多
Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is p...Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is proposed.The electric field applied between the template and the substrate drives the contact,tilting,filling,and holding processes.By accurately controlling the introduced included angle between the flexible template and the substrate,tilted nanostructures with a controllable angle are imprinted onto the substrate,although they are vertical on the template.By flexibly adjusting the electric field intensity and the included angle,large-area uniform-tilted,gradient-tilted,and high-angle-tilted nanostructures are fabricated.In contrast to traditional replication,the morphology of the nanoimprinting structure is extended to customized control.This work provides a cost-effective,efficient,and versatile technology for the fabrication of various large-area tilted metasurface structures.As an illustration,a tilted nanograting with a high coupling efficiency is fabricated and integrated into augmented reality displays,demonstrating superior imaging quality.展开更多
Peroxymonosulfate(PMS)-based advanced oxidation processes(AOPs)are an effective way to remove emerging contaminants(ECs)from water.The catalytic process involving PMS is hindered by the suboptimal electron trans-fer e...Peroxymonosulfate(PMS)-based advanced oxidation processes(AOPs)are an effective way to remove emerging contaminants(ECs)from water.The catalytic process involving PMS is hindered by the suboptimal electron trans-fer efficiency of current catalysts,the further application of AOPs technology is limited.Here,it is proposed that the interfacial electric field can be controlled by bor(B)-doped FeNC catalysts,which shows significant advantages in the efficient generation,release and participation of reactive oxygen species(ROS)in the reaction.The super exchange interaction between Fe sites and N and B sites is realized through the directional transfer of electrons in the interfacial electric field,which ensures the high efficiency and stability of the PMS catalytic process.B doping increases the d orbitals distribution at Fermi level,which facilitates enhanced electron transition activity,thereby promoting the effective generation of (1)^O_(2).At the same time,orbital hybridization causes the center of the d band to move to a lower energy level,which not only contributes to the desorption process of (1)^O_(2),but also accelerates its release.In addition,B-doping also improved the adsorption capacity of organic pollutants and shortened the migration distance of ROS,thereby significantly improving the degradation efficiency of ECs.The B-doping strategy outlined offers a novel approach to the development of FeNC catalysts,it lays a theoretical foundation and offers technical insights for the integration of PMS/AOPs technology in the ECs management.展开更多
We used data from 1960.0,1970.0,1980.0,1990.0,and 2000.0 to study the geomagnetic anomaly field over the Chinese mainland by using the three-dimensional Taylor polynomial（3DTP） and the surface spline（SS） models.To...We used data from 1960.0,1970.0,1980.0,1990.0,and 2000.0 to study the geomagnetic anomaly field over the Chinese mainland by using the three-dimensional Taylor polynomial（3DTP） and the surface spline（SS） models.To obtain the pure anomaly field,the main field and the induced field of the ionospheric and magnetospheric fields were removed from measured data.We also compared the SS model anomalies and the data obtained with Kriging interpolation（KI）.The geomagnetic anomaly distribution over the mainland was analyzed based on the SS and 3DTP models by transferring all points from 1960.0-1990.0 to 2000.0.The results suggest that the total intensity F anomalies estimated based on the SS and KI for each year are basically consistent in distribution and intensity.The anomalous distributions in the X-,Y-,and Z-direction and F are mainly negative.The 3DTP model anomalies suggest that the intensity in the X-direction increases from-100 nT to 0 nT with longitude,whereas the intensity in the Y-direction decreases from 400 nT to 20 nT with longitude and over the eastern mainland is almost negative.The intensity in the Z-direction and F are very similar and in most areas it is about-50 nT and higher in western Tibet.The SS model anomalies overall reflect the actual distribution of the magnetic field anomalies;however,because of the uneven distribution of measurements,it yields several big anomalies.Owing to the added altitude term,the 3DTP model offers higher precision and is consistent with KI.展开更多
Real-time laser holographic interferometry was applied to measure liquid concentrations of CO2 in the vicinity of gas-liquid free interface under the conditions of cocurrent gas-liquid flow for absorption of CO2 by et...Real-time laser holographic interferometry was applied to measure liquid concentrations of CO2 in the vicinity of gas-liquid free interface under the conditions of cocurrent gas-liquid flow for absorption of CO2 by ethanol. The influences of the Reynolds number on the measurable interface concentration and on the film thickness were discussed. The results show that CO2 concentration decreases exponentially along the mass transfer direction,and the concentration gradient increases as Reynolds number of either liquid or gas increases. CO2 concentrations fluctuate slightly along the direction of flow; on the whole, there is an increase in CO2 concentration. The investigation also demonstrated that film thickness decreases with the increase of Reynolds number of either of the two phases. Sherwood number representing the mass transfer coefficient was finally correlated as a function of the hydrodynamic parameters and the physical properties.展开更多
数据清洗、特征选择和预测模型建立是基于数据采集与监视控制系统(supervisory control and data acquisition,SCADA)数据,实现风电机组异常状态预警不可缺少的重要环节。先结合孤立森林(isolation forest,iForest)和基于密度的空间聚类...数据清洗、特征选择和预测模型建立是基于数据采集与监视控制系统(supervisory control and data acquisition,SCADA)数据,实现风电机组异常状态预警不可缺少的重要环节。先结合孤立森林(isolation forest,iForest)和基于密度的空间聚类(density-based spatial clustering of applications with noise,DBSCAN)算法对SCADA数据异常点进行有效清洗,并采用随机森林算法(random forests,RF)与Person相关系数法优选模型输入参数;再进而基于Optuna优化的类别提升树(categorical boosting,CATBoost)算法,建立风电机组正常工况齿轮箱油池温度的预测模型;然后采用滑动窗方法,构建状态评价指标,并使用区间估计理论确定油温异常状态判别的临界阈值;实现油温异常预警;最后,采用某风电机组SCADA系统油温异常的真实历史故障数据进行检验,验证了该方法的有效性。展开更多
Phosphorus (P) is the limiting factor for eutrophication in most freshwater ecosystems. In China, Ptransported from intensively cultivated land has been reported as an important source of P in surface waters.In this s...Phosphorus (P) is the limiting factor for eutrophication in most freshwater ecosystems. In China, Ptransported from intensively cultivated land has been reported as an important source of P in surface waters.In this study, we investigated P concentration and forms in surface and subsurface drainage from wetland ricefields in the Shaoxing plain, Zhejiang Province, China. From selected rice fields, surface drainage sampleswere collected at rice-growing, non-growing and fertilization periods, and subsurface drainage samples atdrought and rewetting (irrigation or precipitation after 5～10 d drought period in the surface soils) and wet(drainage under long-term wet soil condition) periods. Water samples were characterized for their totalreactive P (TRP), dissolved reactive P (DRP) and particulate reactive P (PRP). Concentrations of the TRPand DRP in the surface drainage ranged from 0.08 to 1.50 and 0.06 to 1.27 mg L-1, respectively. The TRPand DRP were dependent on field operation activities, and decreased in the order of fertilization period ＞rice-growing period ＞ non-growing period. Phosphorus concentration of runoff receiving P fertilizer can bean environmental concern. The PRP concentration in the surface drainage, ranging from 0.01 to 0.57 mgL-1, accounted for 8%～78% of the TRP. Concentration of the TRP in the subsurface drainage was from0.026 to 0.090 mg L-1, consisting of 29%～90 % of the DRP and 10%～71% of the PRP. In the droughtand rewetting period, the PRP accounted for, on average, 63% of the TRP, much higher than in the wetperiod (23%), suggesting that there was transport of P in preferential flow during drainage events after ashort-term drought period in the surface soils. Therefore, P losses in particulate form may be importantin the subsurface drainage from rice fields when surface soils form cracks and favor rapid flow downwardthrough the soil profiles, suggesting the important role of water-dispersible colloid particles in mediating andco-transporting P in the subsurface drainage of rice fields.展开更多
By using the D-InSAR technique, we have acquired the temporal-spatial evolution images of preseismic.cosesimci-postseismic interferometric deformation fields associated with the M 7.9 earthquake of Mani, Tibet on 8 No...By using the D-InSAR technique, we have acquired the temporal-spatial evolution images of preseismic.cosesimci-postseismic interferometric deformation fields associated with the M 7.9 earthquake of Mani, Tibet on 8 November 1997. The analysis of these images reveals the relationships between the temporal-spatial evolution features of the interferometric deformation fields and locking, rupturing, and elastic restoring of the source rupture plane, which represent the processes of strain accumulation, strain release, and postseismic restoration. The result shows that 10 months prior to the Mani event, a left-lateral shear trend appeared in the seismic area, which was in accordance with the earthquake fault in nature. The quantity of local deformation on the north wall was slightly larger than that on the south wall, and the deformation distribution area of the north wall was relatively large. With the event impending, the deformation of the south wall varied increasingly, and the deformation center shifted eastward. Two and half monthd before the event, the west side of the fault was still locked while the east side began to slide, implying that the whole fault would rupture at any moment. These features can be regarded as short-term precursors to this earthquake. Within the period from 16 April 1996 to two and half months before the earthquake, the most remarkable deformation zones appeared in the north and south walls, which were parallel to and about 40 km apart from the fault, with accumulated local displacements of 344 mm and 251 mm on the north and south walls, respectively. The south wall was the active one with larger displacements. Five months after the earthquake, the distribution feature of interferometric fringes was just opposite to that prior to the event, expressing evident right-lateral shear. The recovered displacements are -179 mm on the north wall and -79 mm on the south wall, close to the east side of the fault. However, in the area of the south wall far from the fault there still existed a trend of sinistral motion. The deformation of the north wall was small but recovered fast in a larger area, while the active south wall began to recover from the east section of the fault toward the WSW.展开更多
基金supported by the National Natural Science Foundation of China(52164028,52274297)the Start-up Research Foundation of Hainan University(KYQD(ZR)20008,KYQD(ZR)21125,KYQD(ZR)23169))+1 种基金Collaborative Innovation Center of Marine Science and Technology of Hainan University(XTCX2022HYC14)Innovative Research Project for Postgraduate Students in Hainan Province(Qhyb2024-95).
文摘Development of robust electrocatalyst for oxygen reduction reaction(ORR)in a seawater electrolyte is the key to realize seawater electrolyte-based zinc-air batteries(SZABs).Herein,constructing a local electric field coupled with chloride ions(Cl-)fixation strategy in dual single-atom catalysts(DSACs)was proposed,and the resultant catalyst delivered considerable ORR performance in a seawater electrolyte,with a high half-wave potential(E_(1/2))of 0.868 V and a good maximum power density(Pmax)of 182 mW·cm^(−2)in the assembled SZABs,much higher than those of the Pt/C catalyst(E_(1/2):0.846 V;Pmax:150 mW·cm^(−2)).The in-situ characterization and theoretical calculations revealed that the Fe sites have a higher Cl^(−)adsorption affinity than the Co sites,and preferentially adsorbs Cl^(−)in a seawater electrolyte during the ORR process,and thus constructs a low-concentration Cl^(−)local microenvironment through the common-ion exclusion effect,which prevents Cl^(−)adsorption and corrosion in the Co active centers,achieving impressive catalytic stability.In addition,the directional charge movement between Fe and Co atomic pairs establishes a local electric field,optimizing the adsorption energy of Co sites for oxygen-containing intermediates,and further improving the ORR activity.
基金funding support from the National Natural Science Foundation of China(92472109,T2325012)the Program for HUST Academic Frontier Youth Team+1 种基金support from the Fundamental Research Funds for the Central Universities(HUST,5003120083)supported by the Postdoctoral Fellowship Program of CPSF(GZC20240532)。
文摘Batteries play a critical role in electric vehicles and distributed energy generation.With the growing demand for energy storage solutions,new battery materials and systems are continually being developed.In this process,molecular dynamics(MD)simulations can reveal the microscopic mechanisms of battery processes,thereby boosting the design of batteries.Compared to other MD simulation techniques,the machine learning force field(MLFF)holds the advantages of first-principles accuracy along with large spatial and temporal scale,offering opportunities to uncover new mechanisms in battery systems.This review presents a detailed overview of the fundamental principles and model types of MLFFs,as well as their applications in simulating the structure,transport properties,and chemical reaction properties of bulk battery materials and interfaces.Notably,we emphasize the long-range interaction corrections and constant-potential methods in the model design of MLFFs.Finally,we discuss the challenges and prospects of applying MLFF models in the research of batteries.
基金supported by the Guangdong Basic and Applied Basic Research Foundation,China(No.2021B1515140007).
文摘In a rapid cycling synchrotron(RCS),the magnetic field is synchronized with the beam energy,creating a highly dynamic magnetic environment.A ceramic chamber with a shielding layer(RF shield),composed of a series of copper strips connected to a capacitor at either end,is typically employed as a vacuum chamber to mitigate eddy current effects and beam coupling impedance.Consequently,the ceramic chamber exhibits a thin-walled multilayered complex structure.Previous theoretical studies have suggested that the impedance of such a structure has a negligible impact on the beam.However,recent impedance measurements of the ceramic chamber in the China Spallation Neutron Source(CSNS)RCS revealed a resonance in the low-frequency range,which was confirmed by further theoretical analysis as a source of beam instability in the RCS.Currently,the magnitude of this impedance cannot be accurately assessed using theoretical calculations.In this study,we used the CST Microwave Studio to confirm the impedance of the ceramic chamber.Further simulations covering six different types of ceramic chambers were conducted to develop an impedance model in the RCS.Additionally,this study investigates the resonant characteristics of the ceramic chamber impedance,finding that the resonant frequency is closely related to the capacitance of the capacitors.This finding provides clear directions for further impedance optimization and is crucial for achieving a beam power of 500 kW for the CSNS Phase-Ⅱ project(CSNS-Ⅱ).However,careful attention must be paid to the voltage across the capacitors.
基金supported by National Natural Science Foundation of China(No.52025055 and 52275571)Basic Research Operation Fund of China(No.xzy012024024).
文摘Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is proposed.The electric field applied between the template and the substrate drives the contact,tilting,filling,and holding processes.By accurately controlling the introduced included angle between the flexible template and the substrate,tilted nanostructures with a controllable angle are imprinted onto the substrate,although they are vertical on the template.By flexibly adjusting the electric field intensity and the included angle,large-area uniform-tilted,gradient-tilted,and high-angle-tilted nanostructures are fabricated.In contrast to traditional replication,the morphology of the nanoimprinting structure is extended to customized control.This work provides a cost-effective,efficient,and versatile technology for the fabrication of various large-area tilted metasurface structures.As an illustration,a tilted nanograting with a high coupling efficiency is fabricated and integrated into augmented reality displays,demonstrating superior imaging quality.
基金supported by the National Natural Science Foundation of China(No.22278156)the Guangdong Special Support Program Project(No.2021JC060580)+1 种基金the Young Elite Scientists Sponsorship Program by CAST-Doctoral Student Special Plan,the China Scholarship Council Program(No.202406150148)the Natural Science Foundation of Guangdong Province(No.2023A1515011186).
文摘Peroxymonosulfate(PMS)-based advanced oxidation processes(AOPs)are an effective way to remove emerging contaminants(ECs)from water.The catalytic process involving PMS is hindered by the suboptimal electron trans-fer efficiency of current catalysts,the further application of AOPs technology is limited.Here,it is proposed that the interfacial electric field can be controlled by bor(B)-doped FeNC catalysts,which shows significant advantages in the efficient generation,release and participation of reactive oxygen species(ROS)in the reaction.The super exchange interaction between Fe sites and N and B sites is realized through the directional transfer of electrons in the interfacial electric field,which ensures the high efficiency and stability of the PMS catalytic process.B doping increases the d orbitals distribution at Fermi level,which facilitates enhanced electron transition activity,thereby promoting the effective generation of (1)^O_(2).At the same time,orbital hybridization causes the center of the d band to move to a lower energy level,which not only contributes to the desorption process of (1)^O_(2),but also accelerates its release.In addition,B-doping also improved the adsorption capacity of organic pollutants and shortened the migration distance of ROS,thereby significantly improving the degradation efficiency of ECs.The B-doping strategy outlined offers a novel approach to the development of FeNC catalysts,it lays a theoretical foundation and offers technical insights for the integration of PMS/AOPs technology in the ECs management.
基金supported by the National Natural Science Foundation of China(No.41404053)Special Project for MeteoScientific Research in the Public Interest(No.GYHY201306073)+1 种基金Natural Science Foundation of Jiangsu Province(No.BK20140994),Natural Science Foundation of Higher Education Institutions of Jiangsu Province(No.14KJB170012)Training Program of Innovation and Entrepreneurship for Undergraduates of NUIST(No.201510300178)
文摘We used data from 1960.0,1970.0,1980.0,1990.0,and 2000.0 to study the geomagnetic anomaly field over the Chinese mainland by using the three-dimensional Taylor polynomial（3DTP） and the surface spline（SS） models.To obtain the pure anomaly field,the main field and the induced field of the ionospheric and magnetospheric fields were removed from measured data.We also compared the SS model anomalies and the data obtained with Kriging interpolation（KI）.The geomagnetic anomaly distribution over the mainland was analyzed based on the SS and 3DTP models by transferring all points from 1960.0-1990.0 to 2000.0.The results suggest that the total intensity F anomalies estimated based on the SS and KI for each year are basically consistent in distribution and intensity.The anomalous distributions in the X-,Y-,and Z-direction and F are mainly negative.The 3DTP model anomalies suggest that the intensity in the X-direction increases from-100 nT to 0 nT with longitude,whereas the intensity in the Y-direction decreases from 400 nT to 20 nT with longitude and over the eastern mainland is almost negative.The intensity in the Z-direction and F are very similar and in most areas it is about-50 nT and higher in western Tibet.The SS model anomalies overall reflect the actual distribution of the magnetic field anomalies;however,because of the uneven distribution of measurements,it yields several big anomalies.Owing to the added altitude term,the 3DTP model offers higher precision and is consistent with KI.
基金Supported by the National Natural Science Foundation of China (No.20476072).
文摘Real-time laser holographic interferometry was applied to measure liquid concentrations of CO2 in the vicinity of gas-liquid free interface under the conditions of cocurrent gas-liquid flow for absorption of CO2 by ethanol. The influences of the Reynolds number on the measurable interface concentration and on the film thickness were discussed. The results show that CO2 concentration decreases exponentially along the mass transfer direction,and the concentration gradient increases as Reynolds number of either liquid or gas increases. CO2 concentrations fluctuate slightly along the direction of flow; on the whole, there is an increase in CO2 concentration. The investigation also demonstrated that film thickness decreases with the increase of Reynolds number of either of the two phases. Sherwood number representing the mass transfer coefficient was finally correlated as a function of the hydrodynamic parameters and the physical properties.
文摘数据清洗、特征选择和预测模型建立是基于数据采集与监视控制系统(supervisory control and data acquisition,SCADA)数据,实现风电机组异常状态预警不可缺少的重要环节。先结合孤立森林(isolation forest,iForest)和基于密度的空间聚类(density-based spatial clustering of applications with noise,DBSCAN)算法对SCADA数据异常点进行有效清洗,并采用随机森林算法(random forests,RF)与Person相关系数法优选模型输入参数;再进而基于Optuna优化的类别提升树(categorical boosting,CATBoost)算法,建立风电机组正常工况齿轮箱油池温度的预测模型;然后采用滑动窗方法,构建状态评价指标,并使用区间估计理论确定油温异常状态判别的临界阈值;实现油温异常预警;最后,采用某风电机组SCADA系统油温异常的真实历史故障数据进行检验,验证了该方法的有效性。
基金Project supported by the National Natural Science Foundation of China (No.49601013).
文摘Phosphorus (P) is the limiting factor for eutrophication in most freshwater ecosystems. In China, Ptransported from intensively cultivated land has been reported as an important source of P in surface waters.In this study, we investigated P concentration and forms in surface and subsurface drainage from wetland ricefields in the Shaoxing plain, Zhejiang Province, China. From selected rice fields, surface drainage sampleswere collected at rice-growing, non-growing and fertilization periods, and subsurface drainage samples atdrought and rewetting (irrigation or precipitation after 5～10 d drought period in the surface soils) and wet(drainage under long-term wet soil condition) periods. Water samples were characterized for their totalreactive P (TRP), dissolved reactive P (DRP) and particulate reactive P (PRP). Concentrations of the TRPand DRP in the surface drainage ranged from 0.08 to 1.50 and 0.06 to 1.27 mg L-1, respectively. The TRPand DRP were dependent on field operation activities, and decreased in the order of fertilization period ＞rice-growing period ＞ non-growing period. Phosphorus concentration of runoff receiving P fertilizer can bean environmental concern. The PRP concentration in the surface drainage, ranging from 0.01 to 0.57 mgL-1, accounted for 8%～78% of the TRP. Concentration of the TRP in the subsurface drainage was from0.026 to 0.090 mg L-1, consisting of 29%～90 % of the DRP and 10%～71% of the PRP. In the droughtand rewetting period, the PRP accounted for, on average, 63% of the TRP, much higher than in the wetperiod (23%), suggesting that there was transport of P in preferential flow during drainage events after ashort-term drought period in the surface soils. Therefore, P losses in particulate form may be importantin the subsurface drainage from rice fields when surface soils form cracks and favor rapid flow downwardthrough the soil profiles, suggesting the important role of water-dispersible colloid particles in mediating andco-transporting P in the subsurface drainage of rice fields.
基金This work was supported by the National Natural Science Foundation of China （grants 40574007 and 40374013）he radar data used are partially offered by the project ENVISAT A0-711 of Europe Space Administration.
文摘By using the D-InSAR technique, we have acquired the temporal-spatial evolution images of preseismic.cosesimci-postseismic interferometric deformation fields associated with the M 7.9 earthquake of Mani, Tibet on 8 November 1997. The analysis of these images reveals the relationships between the temporal-spatial evolution features of the interferometric deformation fields and locking, rupturing, and elastic restoring of the source rupture plane, which represent the processes of strain accumulation, strain release, and postseismic restoration. The result shows that 10 months prior to the Mani event, a left-lateral shear trend appeared in the seismic area, which was in accordance with the earthquake fault in nature. The quantity of local deformation on the north wall was slightly larger than that on the south wall, and the deformation distribution area of the north wall was relatively large. With the event impending, the deformation of the south wall varied increasingly, and the deformation center shifted eastward. Two and half monthd before the event, the west side of the fault was still locked while the east side began to slide, implying that the whole fault would rupture at any moment. These features can be regarded as short-term precursors to this earthquake. Within the period from 16 April 1996 to two and half months before the earthquake, the most remarkable deformation zones appeared in the north and south walls, which were parallel to and about 40 km apart from the fault, with accumulated local displacements of 344 mm and 251 mm on the north and south walls, respectively. The south wall was the active one with larger displacements. Five months after the earthquake, the distribution feature of interferometric fringes was just opposite to that prior to the event, expressing evident right-lateral shear. The recovered displacements are -179 mm on the north wall and -79 mm on the south wall, close to the east side of the fault. However, in the area of the south wall far from the fault there still existed a trend of sinistral motion. The deformation of the north wall was small but recovered fast in a larger area, while the active south wall began to recover from the east section of the fault toward the WSW.
