The development of all-electric,low-orbit satellite constellations requires low-power Hall thrusters with a wide thrust output.However,the efficiency at low flow rates decreases rapidly due to the deterioration of ion...The development of all-electric,low-orbit satellite constellations requires low-power Hall thrusters with a wide thrust output.However,the efficiency at low flow rates decreases rapidly due to the deterioration of ionization.Although magnetic fields are widely used to optimize Hall thrusters,they are rarely used in wide-range variable flow conditions.In this study,we investigate the influence of the magnetic field gradient on the flow-rate range experimentally.It is found that a small-gradient magnetic field is helpful to improve performance at low flow rates.Then,the experimental results are explained by theoretical deduction,and the quantitative relationship between the flow rate and gradient is given.These conclusions provide guidance and a theoretical basis for designing high-performance,wide-range Hall thrusters.展开更多
The magnetic field profiles,which are produced by three ways in the deposition chamber and plasma chamber of single coil divergent field MWECR CVD system,are investigated.The magnetic field gradient of these magnetic ...The magnetic field profiles,which are produced by three ways in the deposition chamber and plasma chamber of single coil divergent field MWECR CVD system,are investigated.The magnetic field gradient of these magnetic field profiles is obtained quantitatively by using Lorentz fit.The results indicate that the gradient value of the magnetic field profile near by the substrate,which is produced by a coil current with 137.7A if a SmCo permanent magnet is equipped under the substrate holder,is the largest;when the SmCo permanent magnet is taken away,the larger one is produced by the coil current with 137.7A and the smallest one produced by a coil current with 115.2A.High deposition rate of a-Si∶H film is observed near by the substrate with high magnetic field gradient.But uneven deposition rate along the radius of the sample holder is also found by infrared analysis technology when sample is deposited in magnetic field profile,which is produced by the coil current with 137.7A if the SmCo permanent magnet is equipped under the substrate holder.展开更多
In this study,the effects of high magnetic field gradients on the segregation of alloying elements,crystallized phases,and particles in alloys during solidification process and corresponding microstructures were discu...In this study,the effects of high magnetic field gradients on the segregation of alloying elements,crystallized phases,and particles in alloys during solidification process and corresponding microstructures were discussed.It was confirmed that applying an external high magnetic field gradient during solidification process is an effective processing route for controlling segregation in alloys and then fabricating functional materials which have special mierostruetures and properties.Such controlling and fabrication were realized by controlling the migration of the alloying elements, crystallized phases,and particles in the liquid matrix on the basis of the Lorentz and magnetic forces.展开更多
A method of measuring in-situ magnetic field gradient is proposed in this paper. The magnetic shield is widely used in the atomic magnetometer. However, there is magnetic field gradient in the magnetic shield, which w...A method of measuring in-situ magnetic field gradient is proposed in this paper. The magnetic shield is widely used in the atomic magnetometer. However, there is magnetic field gradient in the magnetic shield, which would lead to additional gradient broadening. It is impossible to use an ex-situ magnetometer to measure magnetic field gradient in the region of a cell, whose length of side is several centimeters. The method demonstrated in this paper can realize the in-situ measurement of the magnetic field gradient inside the cell, which is significant for the spin relaxation study. The magnetic field gradients along the longitudinal axis of the magnetic shield are measured by a spin-exchange relaxation-free （SERF） magnetometer by adding a magnetic field modulation in the probe beam＇s direction. The transmissivity of the cell for the probe beam is always inhomogeneous along the pump beam direction, and the method proposed in this paper is independent of the intensity of the probe beam, which means that the method is independent of the cell＇s transmissivity. This feature makes the method more practical experimentally. Moreover, the AC-Stark shift can seriously degrade and affect the precision of the magnetic field gradient measurement. The AC-Stark shift is suppressed by locking the pump beam to the resonance of potassium＇s D1 line. Furthermore, the residual magnetic fields are measured with σ＋- and σ--polarized pump beams, which can further suppress the effect of the AC-Stark shift. The method of measuring in-situ magnetic field gradient has achieved a magnetic field gradient precision of better than 30 pT/mm.展开更多
The effect of the Raman-pulse duration related to the magnetic field gradient, as a systematic error, is playing an important role on evaluating the performance of high-precision atomic gravimeters. We study this effe...The effect of the Raman-pulse duration related to the magnetic field gradient, as a systematic error, is playing an important role on evaluating the performance of high-precision atomic gravimeters. We study this effect with a simplified theoretical model of the time-propagation operator. According to the typical parameters, we find that this effect should be taken into account when the gravimeter reaches an accuracy of 10^-10g, and the larger the pulse duration is, the more obvious the systematic effect will be. Finally, we make a simple discussion on the possibility of testing this effect.展开更多
In the present work we calculate the energies,quadrupole moments,and electric field gradients（EFGs） of molecules C2,N2,and O2 based on the DIRRCI method with basis aug-cc-pVTZ-DK.We prove that the quadratic force co...In the present work we calculate the energies,quadrupole moments,and electric field gradients（EFGs） of molecules C2,N2,and O2 based on the DIRRCI method with basis aug-cc-pVTZ-DK.We prove that the quadratic force constant k2 is the product of charge and EFG at its equilibrium nuclear distance.The dipole charge distributions for these symmetrical molecules are all in equilibrium,however,the quadrupole charge distributions are far from equilibrium;among these,there is the most remarkable deviation from equilibrium for N2,for its many charges concentrate on two sides of the molecule,which is in agreement with the well-known characteristic of the nitrogen molecule.The relativistic effect is remarkable even for the same period.展开更多
Optically levitated nano-particle with spins is a promising system for high-precision measurement and quantum information processing. We theoretically analyze the ratio between the fluctuation of particle's displa...Optically levitated nano-particle with spins is a promising system for high-precision measurement and quantum information processing. We theoretically analyze the ratio between the fluctuation of particle's displacement caused by spins in magnetic field and caused by molecular collisions of the residual air. When the ratio is larger than unity, the displacement fluctuation of spins flipping can be remarkably detected. By theoretical analysis and numerical simulation, we propose and validate a scheme for the detection of gradient of the magnetic field by levitating ferromagnetic nano-particle, and also put forward a realizable detection scheme of the single spin by levitating nano-diamond particle with single nitrogen-vacancy(NV) centers.展开更多
The self-diffusion of water, ethanol and water-ethanol mixtures in chitosan (CS) membranes crosslinked by aqueous H2SO4 solution and uncrosslinked membrane was measured using pulsed-field gradient (PFG) nuclear magnet...The self-diffusion of water, ethanol and water-ethanol mixtures in chitosan (CS) membranes crosslinked by aqueous H2SO4 solution and uncrosslinked membrane was measured using pulsed-field gradient (PFG) nuclear magnetic resonance (NMR) spectroscopy to obtain the partial solubilities and self-diffusion coefficients. An attempt was made to explain the transport properties of water and ethanol through the CS membrane. It was concluded that there are two types of channel water and ethanol diffusate transfer. The water was localized in the hydrophilic ionic region formed by the ionized groups, and the ethanol was localized in the hydrophobic amorphous network of the polymer. There was a good agreement between. the separation factors estimated from PFG-NMR data and those obtained by pervaporation testing.展开更多
Nuclear magnetic resonance (NMR) spectroscopy is an excellent analytical tool for precise structural characterization of organic and bio-molecules. Though NMR is often used to characterize a single compound in solutio...Nuclear magnetic resonance (NMR) spectroscopy is an excellent analytical tool for precise structural characterization of organic and bio-molecules. Though NMR is often used to characterize a single compound in solution, emerging experimental methods using pulsed-field-gradients (PFGs) allow structural dynamic characterization of several compounds, simultaneously in the same solution. NMR as a chromatography tool is often an overlooked application by analytical chemists. Therefore, in this article we introduce the concept of NMR based diffusion measurements, basic operational methods and novel applications. We expect this article to increase the overall use and appreciation of NMR-based diffusion measurements in general and in particular, in analytical chemistry applications.展开更多
Gradient coil is an essential component of a magnetic resonance imaging(MRI)scanner.To achieve high spatial resolution and imaging speed,a high-efficiency gradient coil with high slew rate is required.In consideration...Gradient coil is an essential component of a magnetic resonance imaging(MRI)scanner.To achieve high spatial resolution and imaging speed,a high-efficiency gradient coil with high slew rate is required.In consideration of the safety and comfort of the patient,the mechanical stability,acoustic noise and peripheral nerve stimulation(PNS)are also need to be concerned for practical use.In our previous work,a high-efficiency whole-body gradient coil set with a hybrid cylindrical-planar structure has been presented,which offers significantly improved coil performances.In this work,we propose to design this transverse gradient coil system with transformed magnetic gradient fields.By shifting up the zero point of gradient fields,the designed new Y-gradient coil could provide enhanced electromagnetic performances.With more uniform coil winding arrangement,the net torque of the new coil is significantly reduced and the generated sound pressure level(SPL)is lower at most tested frequency bands.On the other hand,the new transverse gradient coil designed with rotated magnetic gradient fields produces considerably reduced electric field in the human body,which is important for the use of rapid MR sequences.It's demonstrated that a safer and patient-friendly design could be obtained by using transformed magnetic gradient fields,which is critical for practical use.展开更多
The large and small sized Cu（solid）/Al（liquid） couples were prepared to investigate the directional growth behavior of primary a（Al） phase during a concentration-gradient-controlled solidification process under ...The large and small sized Cu（solid）/Al（liquid） couples were prepared to investigate the directional growth behavior of primary a（Al） phase during a concentration-gradient-controlled solidification process under various static magnetic fields（SMFs）.The results show that in the large couples,the α（Al） dendrites reveal a directional growth character whether without or with the SMF.However,the 12 T magnetic field induces regular growth,consistent deflection and the decrease of secondary arm spacing of the dendrites.In the small couples,the α（Al） dendrites still reveal a directional growth character to some extent with a SMF of ≤5 T.However,an 8.8 T SMF destroys the directional growth and induces severe random deflections of the dendrites.When the SMF increases to 12 T,the a（Al） dendrites become quite regular despite of the consistent deflection.The directional growth arises from the continuous long-range concentration gradient field built in the melt.The morphological modification is mainly related to the suppression of natural convections and the induction of thermoelectric magnetic convection by the SMF.展开更多
We consider a cantilever mechanical oscillator(MO) made of diamond. A nitrogen-vacancy(NV) center lies at the end of the cantilever. Two magnetic tips near the NV center induce a strong second-order magnetic field gra...We consider a cantilever mechanical oscillator(MO) made of diamond. A nitrogen-vacancy(NV) center lies at the end of the cantilever. Two magnetic tips near the NV center induce a strong second-order magnetic field gradient. Under coherent driving of the MO, we find that the coupling between the MO and the NV center is greatly enhanced. We studied how to generate entanglement between the MO and the NV center and realize quantum state transfer between them. We also propose a scheme to generate two-mode squeezing between different MO modes by coupling them to the same NV center. The decoherence and dissipation effects for both the MO and the NV center are numerically calculated using the present parameter values of the experimental configuration. We have achieved high fidelity for entanglement generation, quantum state transfer, and large twomode squeezing.展开更多
We provide an effective method to investigate the field gradient effect in nanoconfined plasmon-matter interaction.Aligned ultralong SWNTs without defects were grown on marked substrates, followed by assembling gold n...We provide an effective method to investigate the field gradient effect in nanoconfined plasmon-matter interaction.Aligned ultralong SWNTs without defects were grown on marked substrates, followed by assembling gold nanoparticle clusters around individual nanotubes. The Raman scattering behavior of a nanotube placed in an atomic scale nanogap between adjacent nanoparticles was studied. In addition to the expected plasmon-induced Raman enhancement up to 103,the defect-free D-mode of an individual SWNT induced by gradient field is found for the first time. When the light is confined at atomic scale, gradient field Raman scattering becomes significant and dipole-forbidden phonon modes can be activated by quadrupole Raman tensor variation, indicating breakdown of the Raman selection rules.展开更多
We present a review of the principal developments in the evolution and synergism of solute and particle migration in a liquid melt in high-gradient magnetic fields and we also describe their effects on the solidificat...We present a review of the principal developments in the evolution and synergism of solute and particle migration in a liquid melt in high-gradient magnetic fields and we also describe their effects on the solidification microstructure of alloys.Diverse areas relevant to various aspects of theory and applications of high-gradient magnetic field-controlled migration of solutes and particles are surveyed.They include introduction,high-gradient magnetic field effects,migration behavior of solute and particles in high-gradient magnetic fields,microstructure evolution induced by high-gradient magnetic fieldcontrolled migrations of solute and particles,and properties of materials modified by high-gradient magnetic field-tailored microstructure.Selected examples of binary and multiphase alloy systems are presented and examined,with the main focus on the correlation between the high-gradient magnetic field-modified migration and the related solidification microstructure evolution.Particular attention is given to the mechanisms responsible for the microstructure evolution induced by highgradient magnetic fields.展开更多
Based on closed-orbit theory, the photodetachment of H- in a gradient electric field near a metal surface is studied. It is demonstrated that the gradient electric field has a significant influence on the photodetachm...Based on closed-orbit theory, the photodetachment of H- in a gradient electric field near a metal surface is studied. It is demonstrated that the gradient electric field has a significant influence on the photodetachment of negative ions near a metal surface. With the increase of the gradient of the electric field, the oscillation in the photodetachment cross section becomes strengthened. Besides, in contrast to the photodetachment of H- near a metal surface in a uniform electric field, the oscillating amplitude and the oscillating region in the cross section of a gradient electric field also become enlarged. Therefore, we can use the gradient electric field to control the photodetachment of negative ions near a metal surface. We hope that our results will be useful for understanding the photodetachment of negative ions in the vicinity of surfaces, cavities, and ion traps.展开更多
Magnetic field gradient tensor technique provides abundant data for delicate inversion of subsurface magnetic susceptibility distribution. Large scale magnetic data inversion imaging requires high speed and accuracy f...Magnetic field gradient tensor technique provides abundant data for delicate inversion of subsurface magnetic susceptibility distribution. Large scale magnetic data inversion imaging requires high speed and accuracy for forward modeling. For arbitrarily distributed susceptibility data on an undulated surface, we propose a fast 3D forward modeling method in the wavenumber domain based on(1) the wavenumber-domain expression of the prism combination model and the Gauss–FFT algorithm and(2) cubic spline interpolation. We apply the proposed 3D forward modeling method to synthetic data and use weighting coefficients in the wavenumber domain to improve the modeling for multiple observation surfaces, and also demonstrate the accuracy and efficiency of the proposed method.展开更多
Although 9.4 T magnetic resonance imaging(MRI) has been tested in healthy volunteers,its safety in diabetic patients is unclear.Furthermore,the effects of high static magnetic fields(SMFs),especially gradient vs.unifo...Although 9.4 T magnetic resonance imaging(MRI) has been tested in healthy volunteers,its safety in diabetic patients is unclear.Furthermore,the effects of high static magnetic fields(SMFs),especially gradient vs.uniform fields,have not been investigated in diabetics.Here,we investigated the consequences of exposure to 1.0-9.4 T high SMFs of different gradients(>10 T/m vs.0-10 T/m)on type 1 diabetic(T1D) and type 2 diabetic(T2D) mice.We found that 14 h of prolonged treatment of gradient(as high as 55.5 T/m) high SMFs(1.0-8.6 T) had negative effects on T1D and T2D mice,including spleen,hepatic,and renal tissue impairment and elevated glycosylated serum protein,blood glucose,inflammation,and anxiety,while 9.4 T quasi-uniform SMFs at 0-10 T/m did not induce the same effects.In regular T1D mice(blood glucose>16.7 mmol/L),the>10 T/m gradient high SMFs increased malondialdehyde(P<0.01) and decreased superoxide dismutase(P<0.05).However,in the severe T1D mice(blood glucose≥30.0 mmol/L),the>10 T/m gradient high SMFs significantly increased tissue damage and reduced survival rate.In vitro cellular studies showed that gradient high SMFs increased cellular reactive oxygen species and apoptosis and reduced MS-1 cell number and proliferation.Therefore,this study showed that prolonged exposure to high-field(1.0-8.6 T)>10 T/m gradient SMFs(35-1 380 times higher than that of current clinical MRI)can have negative effects on diabetic mice,especially mice with severe T1D,whereas 9.4 T high SMFs at 0-10T/m did not produce the same effects,providing important information for the future development and clinical application of SMFs,especially high-field MRI.展开更多
A plane strain mode 1 crack tip field with strain gradient effects is investigated.A new strain gradient theory is used.An elastic-power law hardening strain gradient material is considered and two hardening laws,i.e....A plane strain mode 1 crack tip field with strain gradient effects is investigated.A new strain gradient theory is used.An elastic-power law hardening strain gradient material is considered and two hardening laws,i.e.a separation law and an integration law are used respectively.As for the material with the separation law hardening,the angular distributions of stresses are consistent with the HRR field,which differs from the stress results;the angular distributions of couple stresses are the same as the couple stress results.For the material with the integration law hardening,the stress field and the couple stress field can not exist simultaneously,which is the same as the conclusion,but for the stress dominated field,the an- gular distributions of stresses are consistent with the HRR field;for the couple stress dominated field,the an- gular distributions of couple stresses are consistent with those in Ref.However,the increase in stresses is not observed in strain gradient plasticity because the present theory is based on the rotation gradient of the deformation only,while the crack tip field of mode 1 is dominated by the tension gradient,which will be shown in another paper.展开更多
The oscillating natural convection in the presence of transverse magnetic field with time depending pressure gradient is studied. The analysis of the problem is carried out by assuming that the fluid is flowing in a...The oscillating natural convection in the presence of transverse magnetic field with time depending pressure gradient is studied. The analysis of the problem is carried out by assuming that the fluid is flowing in a parallel plate configuration. The emphasis is on low frequency oscillating convective flows induced by g-jitter associated with micro gravity because of their importance to the space processing materials. A general solution for an oscillating flow in the presence of transverse magnetic field is carried out. Some special cases of the oscillating flow and its response to an applied magnetic field are performed. It was observed that the behavior of oscillating free convective flows depends on frequency, amplitude of the driving buoyancy forces, temperature gradient,magnetic field and the electric conditions of the channel walls. In the absence of magnetic field, buoyancy force plays a predominant role in driving the oscillatory flow pattern, and velocity magnitude is also affected by temperature gradients. To suppress the oscillating flow external magnetic field can be used. It is also found that the reduction of the velocity is inversely proportional to the square of the applied magnetic field with conducting wall but directly proportional to the inverse of the magnetic field with insulating wall. Detailed calculations and computational results are also carried out to depict the real situation.展开更多
The temporal interface microstructures and diffusions in the diffusion couples with the mutual interactions of the temperature gradient, concentration difference and initial aging time of the alloys are studied by pha...The temporal interface microstructures and diffusions in the diffusion couples with the mutual interactions of the temperature gradient, concentration difference and initial aging time of the alloys are studied by phase-field simulation, and the diffusion couples are produced by the initial aged spinodal alloys with different compositions. Temporal composition evolution and volume fraction of the separated phase indicate the element diffusion direction through the interface under the temperature gradient. The increased temperature gradient induces a wide single-phase region on two sides of the interface.The uphill diffusion proceeds through the interface, no matter whether the diffusion direction is up or down with respect to the temperature gradient. For an alloy with short initial aging time, phase transformation accompanying the interdiffusion results in the straight interface with the single-phase regions on both sides. Compared with the temperature gradient,composition difference of diffusion couple and initial aging time of the alloy show greater effects on diffusion and interface microstructure.展开更多
基金funded by National Natural Science Foundation of China(Nos.52076054 and 51736003).
文摘The development of all-electric,low-orbit satellite constellations requires low-power Hall thrusters with a wide thrust output.However,the efficiency at low flow rates decreases rapidly due to the deterioration of ionization.Although magnetic fields are widely used to optimize Hall thrusters,they are rarely used in wide-range variable flow conditions.In this study,we investigate the influence of the magnetic field gradient on the flow-rate range experimentally.It is found that a small-gradient magnetic field is helpful to improve performance at low flow rates.Then,the experimental results are explained by theoretical deduction,and the quantitative relationship between the flow rate and gradient is given.These conclusions provide guidance and a theoretical basis for designing high-performance,wide-range Hall thrusters.
文摘The magnetic field profiles,which are produced by three ways in the deposition chamber and plasma chamber of single coil divergent field MWECR CVD system,are investigated.The magnetic field gradient of these magnetic field profiles is obtained quantitatively by using Lorentz fit.The results indicate that the gradient value of the magnetic field profile near by the substrate,which is produced by a coil current with 137.7A if a SmCo permanent magnet is equipped under the substrate holder,is the largest;when the SmCo permanent magnet is taken away,the larger one is produced by the coil current with 137.7A and the smallest one produced by a coil current with 115.2A.High deposition rate of a-Si∶H film is observed near by the substrate with high magnetic field gradient.But uneven deposition rate along the radius of the sample holder is also found by infrared analysis technology when sample is deposited in magnetic field profile,which is produced by the coil current with 137.7A if the SmCo permanent magnet is equipped under the substrate holder.
基金Item Sponsored by the National Natural Science Foundation of China (Grant Nos.51006020 and 51174056) the Fundamental Research Funds for the Central Universities (Grant Nos.N090109001+3 种基金N100409008and N100609001) the National Basic Research Program of China (Grant Nos.2011CB612206 and 2011CB610405) the Wuhan National High Magnetic Field Center (Grant No.WHMFCK2011006)
文摘In this study,the effects of high magnetic field gradients on the segregation of alloying elements,crystallized phases,and particles in alloys during solidification process and corresponding microstructures were discussed.It was confirmed that applying an external high magnetic field gradient during solidification process is an effective processing route for controlling segregation in alloys and then fabricating functional materials which have special mierostruetures and properties.Such controlling and fabrication were realized by controlling the migration of the alloying elements, crystallized phases,and particles in the liquid matrix on the basis of the Lorentz and magnetic forces.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61227902,61374210,and 61121003)
文摘A method of measuring in-situ magnetic field gradient is proposed in this paper. The magnetic shield is widely used in the atomic magnetometer. However, there is magnetic field gradient in the magnetic shield, which would lead to additional gradient broadening. It is impossible to use an ex-situ magnetometer to measure magnetic field gradient in the region of a cell, whose length of side is several centimeters. The method demonstrated in this paper can realize the in-situ measurement of the magnetic field gradient inside the cell, which is significant for the spin relaxation study. The magnetic field gradients along the longitudinal axis of the magnetic shield are measured by a spin-exchange relaxation-free （SERF） magnetometer by adding a magnetic field modulation in the probe beam＇s direction. The transmissivity of the cell for the probe beam is always inhomogeneous along the pump beam direction, and the method proposed in this paper is independent of the intensity of the probe beam, which means that the method is independent of the cell＇s transmissivity. This feature makes the method more practical experimentally. Moreover, the AC-Stark shift can seriously degrade and affect the precision of the magnetic field gradient measurement. The AC-Stark shift is suppressed by locking the pump beam to the resonance of potassium＇s D1 line. Furthermore, the residual magnetic fields are measured with σ＋- and σ--polarized pump beams, which can further suppress the effect of the AC-Stark shift. The method of measuring in-situ magnetic field gradient has achieved a magnetic field gradient precision of better than 30 pT/mm.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11625417,11727809,11474115,91636219,and 91636221)the Post-doctoral Science Foundation of China(Grant No.2017M620308)
文摘The effect of the Raman-pulse duration related to the magnetic field gradient, as a systematic error, is playing an important role on evaluating the performance of high-precision atomic gravimeters. We study this effect with a simplified theoretical model of the time-propagation operator. According to the typical parameters, we find that this effect should be taken into account when the gravimeter reaches an accuracy of 10^-10g, and the larger the pulse duration is, the more obvious the systematic effect will be. Finally, we make a simple discussion on the possibility of testing this effect.
基金Project supported by the Fundamental Research Funds for the Central Universities
文摘In the present work we calculate the energies,quadrupole moments,and electric field gradients（EFGs） of molecules C2,N2,and O2 based on the DIRRCI method with basis aug-cc-pVTZ-DK.We prove that the quadratic force constant k2 is the product of charge and EFG at its equilibrium nuclear distance.The dipole charge distributions for these symmetrical molecules are all in equilibrium,however,the quadrupole charge distributions are far from equilibrium;among these,there is the most remarkable deviation from equilibrium for N2,for its many charges concentrate on two sides of the molecule,which is in agreement with the well-known characteristic of the nitrogen molecule.The relativistic effect is remarkable even for the same period.
基金Supported by the National Natural Science Foundation of China under Grant Nos.11374032,61435007,and 11704026the Joint Fund of the Ministry of Education of China under Grant No.6141A02011604+1 种基金NSAF(China)under Grant No.U1530401National Key Research and Development Program of China under Grant No.2016YFA0301201
文摘Optically levitated nano-particle with spins is a promising system for high-precision measurement and quantum information processing. We theoretically analyze the ratio between the fluctuation of particle's displacement caused by spins in magnetic field and caused by molecular collisions of the residual air. When the ratio is larger than unity, the displacement fluctuation of spins flipping can be remarkably detected. By theoretical analysis and numerical simulation, we propose and validate a scheme for the detection of gradient of the magnetic field by levitating ferromagnetic nano-particle, and also put forward a realizable detection scheme of the single spin by levitating nano-diamond particle with single nitrogen-vacancy(NV) centers.
文摘The self-diffusion of water, ethanol and water-ethanol mixtures in chitosan (CS) membranes crosslinked by aqueous H2SO4 solution and uncrosslinked membrane was measured using pulsed-field gradient (PFG) nuclear magnetic resonance (NMR) spectroscopy to obtain the partial solubilities and self-diffusion coefficients. An attempt was made to explain the transport properties of water and ethanol through the CS membrane. It was concluded that there are two types of channel water and ethanol diffusate transfer. The water was localized in the hydrophilic ionic region formed by the ionized groups, and the ethanol was localized in the hydrophobic amorphous network of the polymer. There was a good agreement between. the separation factors estimated from PFG-NMR data and those obtained by pervaporation testing.
文摘Nuclear magnetic resonance (NMR) spectroscopy is an excellent analytical tool for precise structural characterization of organic and bio-molecules. Though NMR is often used to characterize a single compound in solution, emerging experimental methods using pulsed-field-gradients (PFGs) allow structural dynamic characterization of several compounds, simultaneously in the same solution. NMR as a chromatography tool is often an overlooked application by analytical chemists. Therefore, in this article we introduce the concept of NMR based diffusion measurements, basic operational methods and novel applications. We expect this article to increase the overall use and appreciation of NMR-based diffusion measurements in general and in particular, in analytical chemistry applications.
基金supported by the Instrument Developing Project of Magnetic Resonance Union of Chinese Academy of Sciences,Grant No.2022GZL002.
文摘Gradient coil is an essential component of a magnetic resonance imaging(MRI)scanner.To achieve high spatial resolution and imaging speed,a high-efficiency gradient coil with high slew rate is required.In consideration of the safety and comfort of the patient,the mechanical stability,acoustic noise and peripheral nerve stimulation(PNS)are also need to be concerned for practical use.In our previous work,a high-efficiency whole-body gradient coil set with a hybrid cylindrical-planar structure has been presented,which offers significantly improved coil performances.In this work,we propose to design this transverse gradient coil system with transformed magnetic gradient fields.By shifting up the zero point of gradient fields,the designed new Y-gradient coil could provide enhanced electromagnetic performances.With more uniform coil winding arrangement,the net torque of the new coil is significantly reduced and the generated sound pressure level(SPL)is lower at most tested frequency bands.On the other hand,the new transverse gradient coil designed with rotated magnetic gradient fields produces considerably reduced electric field in the human body,which is important for the use of rapid MR sequences.It's demonstrated that a safer and patient-friendly design could be obtained by using transformed magnetic gradient fields,which is critical for practical use.
基金Projects(51201029,51071042,51374067)supported by the National Natural Science Foundation of ChinaProjects(N130409002,N130209001)supported by the Research Funds for the Central UniversitiesProject(2012M520637)supported by the China Postdoctoral Science Foundation
文摘The large and small sized Cu（solid）/Al（liquid） couples were prepared to investigate the directional growth behavior of primary a（Al） phase during a concentration-gradient-controlled solidification process under various static magnetic fields（SMFs）.The results show that in the large couples,the α（Al） dendrites reveal a directional growth character whether without or with the SMF.However,the 12 T magnetic field induces regular growth,consistent deflection and the decrease of secondary arm spacing of the dendrites.In the small couples,the α（Al） dendrites still reveal a directional growth character to some extent with a SMF of ≤5 T.However,an 8.8 T SMF destroys the directional growth and induces severe random deflections of the dendrites.When the SMF increases to 12 T,the a（Al） dendrites become quite regular despite of the consistent deflection.The directional growth arises from the continuous long-range concentration gradient field built in the melt.The morphological modification is mainly related to the suppression of natural convections and the induction of thermoelectric magnetic convection by the SMF.
基金supported by the National Natural Science Foundation of China(Grant Nos.61435007,11175094,91221205)the National Basic Research Program of China(Grant No.2015CB921002)
文摘We consider a cantilever mechanical oscillator(MO) made of diamond. A nitrogen-vacancy(NV) center lies at the end of the cantilever. Two magnetic tips near the NV center induce a strong second-order magnetic field gradient. Under coherent driving of the MO, we find that the coupling between the MO and the NV center is greatly enhanced. We studied how to generate entanglement between the MO and the NV center and realize quantum state transfer between them. We also propose a scheme to generate two-mode squeezing between different MO modes by coupling them to the same NV center. The decoherence and dissipation effects for both the MO and the NV center are numerically calculated using the present parameter values of the experimental configuration. We have achieved high fidelity for entanglement generation, quantum state transfer, and large twomode squeezing.
基金Project supported by the National Basic Research Program of China(Grant No.2012CB932302)the National Natural Science Foundation of China(Grant Nos.11634014,51172271,and 51372269)the "Strategic Priority Research Program" of the Chinese Academy of Sciences(Grant Nos.XDA09040202and XDA09040400)
文摘We provide an effective method to investigate the field gradient effect in nanoconfined plasmon-matter interaction.Aligned ultralong SWNTs without defects were grown on marked substrates, followed by assembling gold nanoparticle clusters around individual nanotubes. The Raman scattering behavior of a nanotube placed in an atomic scale nanogap between adjacent nanoparticles was studied. In addition to the expected plasmon-induced Raman enhancement up to 103,the defect-free D-mode of an individual SWNT induced by gradient field is found for the first time. When the light is confined at atomic scale, gradient field Raman scattering becomes significant and dipole-forbidden phonon modes can be activated by quadrupole Raman tensor variation, indicating breakdown of the Raman selection rules.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.51425401,51690161,51574073,and 51774086)Fundamental Research Funds for the Central Universities,China(Grant Nos.N170902002 and N170908001)Liaoning Innovative Research Team in University,China(Grant No.LT2017011)
文摘We present a review of the principal developments in the evolution and synergism of solute and particle migration in a liquid melt in high-gradient magnetic fields and we also describe their effects on the solidification microstructure of alloys.Diverse areas relevant to various aspects of theory and applications of high-gradient magnetic field-controlled migration of solutes and particles are surveyed.They include introduction,high-gradient magnetic field effects,migration behavior of solute and particles in high-gradient magnetic fields,microstructure evolution induced by high-gradient magnetic fieldcontrolled migrations of solute and particles,and properties of materials modified by high-gradient magnetic field-tailored microstructure.Selected examples of binary and multiphase alloy systems are presented and examined,with the main focus on the correlation between the high-gradient magnetic field-modified migration and the related solidification microstructure evolution.Particular attention is given to the mechanisms responsible for the microstructure evolution induced by highgradient magnetic fields.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11074104 and 10604045)the Higher Education Science and Technology Program of Shandong Province, China (Grant No. J09LA02)the University Student's Science and Technology Innovation Fund of Ludong University, China (Grant No. 10g003)
文摘Based on closed-orbit theory, the photodetachment of H- in a gradient electric field near a metal surface is studied. It is demonstrated that the gradient electric field has a significant influence on the photodetachment of negative ions near a metal surface. With the increase of the gradient of the electric field, the oscillation in the photodetachment cross section becomes strengthened. Besides, in contrast to the photodetachment of H- near a metal surface in a uniform electric field, the oscillating amplitude and the oscillating region in the cross section of a gradient electric field also become enlarged. Therefore, we can use the gradient electric field to control the photodetachment of negative ions near a metal surface. We hope that our results will be useful for understanding the photodetachment of negative ions in the vicinity of surfaces, cavities, and ion traps.
基金supported by the National Special Plan for the 13th Five-Year Plan of China(No.2017YFC0602204-10)Independent Exploration of the Innovation Project for Graduate Students at Central South University(No.2017zzts176)+3 种基金National Natural Science Foundation of China(Nos.41574127,41404106,and 41674075)Postdoctoral Fund Projects of China(No.2017M622608)National Key R&D Program of China(No.2018YFC0603602)Natural Science Youth Fund Project of the Hunan Province,China(No.2018JJ3642)
文摘Magnetic field gradient tensor technique provides abundant data for delicate inversion of subsurface magnetic susceptibility distribution. Large scale magnetic data inversion imaging requires high speed and accuracy for forward modeling. For arbitrarily distributed susceptibility data on an undulated surface, we propose a fast 3D forward modeling method in the wavenumber domain based on(1) the wavenumber-domain expression of the prism combination model and the Gauss–FFT algorithm and(2) cubic spline interpolation. We apply the proposed 3D forward modeling method to synthetic data and use weighting coefficients in the wavenumber domain to improve the modeling for multiple observation surfaces, and also demonstrate the accuracy and efficiency of the proposed method.
基金supported by the National Natural Science Foundation of China (U21A20148, 31900506, 52007185)International Partnership Program of the Chinese Academy of Sciences(116134KYSB20210052)+2 种基金Heye Health Technology Chong Ming Project(HYCMP2021010)CAS President’s International Fellowship Initiative Grant(2022VMA0009)CASHIPS Director’s Fund (BJPY2021A06,2021YZGH04, YZJJ2020QN26, YZJJZX202014, YZJJ2021QN32,YZJJ2023QN43)。
文摘Although 9.4 T magnetic resonance imaging(MRI) has been tested in healthy volunteers,its safety in diabetic patients is unclear.Furthermore,the effects of high static magnetic fields(SMFs),especially gradient vs.uniform fields,have not been investigated in diabetics.Here,we investigated the consequences of exposure to 1.0-9.4 T high SMFs of different gradients(>10 T/m vs.0-10 T/m)on type 1 diabetic(T1D) and type 2 diabetic(T2D) mice.We found that 14 h of prolonged treatment of gradient(as high as 55.5 T/m) high SMFs(1.0-8.6 T) had negative effects on T1D and T2D mice,including spleen,hepatic,and renal tissue impairment and elevated glycosylated serum protein,blood glucose,inflammation,and anxiety,while 9.4 T quasi-uniform SMFs at 0-10 T/m did not induce the same effects.In regular T1D mice(blood glucose>16.7 mmol/L),the>10 T/m gradient high SMFs increased malondialdehyde(P<0.01) and decreased superoxide dismutase(P<0.05).However,in the severe T1D mice(blood glucose≥30.0 mmol/L),the>10 T/m gradient high SMFs significantly increased tissue damage and reduced survival rate.In vitro cellular studies showed that gradient high SMFs increased cellular reactive oxygen species and apoptosis and reduced MS-1 cell number and proliferation.Therefore,this study showed that prolonged exposure to high-field(1.0-8.6 T)>10 T/m gradient SMFs(35-1 380 times higher than that of current clinical MRI)can have negative effects on diabetic mice,especially mice with severe T1D,whereas 9.4 T high SMFs at 0-10T/m did not produce the same effects,providing important information for the future development and clinical application of SMFs,especially high-field MRI.
基金the National Natural Science Foundation of China (No.19704100)Science Foundation of Chinese Academy of Sciences (Project KJ951-1-20)CASK.C.Wong Post-doctoral Research Award Fund and the Post Doctoral Science Fund of China.
文摘A plane strain mode 1 crack tip field with strain gradient effects is investigated.A new strain gradient theory is used.An elastic-power law hardening strain gradient material is considered and two hardening laws,i.e.a separation law and an integration law are used respectively.As for the material with the separation law hardening,the angular distributions of stresses are consistent with the HRR field,which differs from the stress results;the angular distributions of couple stresses are the same as the couple stress results.For the material with the integration law hardening,the stress field and the couple stress field can not exist simultaneously,which is the same as the conclusion,but for the stress dominated field,the an- gular distributions of stresses are consistent with the HRR field;for the couple stress dominated field,the an- gular distributions of couple stresses are consistent with those in Ref.However,the increase in stresses is not observed in strain gradient plasticity because the present theory is based on the rotation gradient of the deformation only,while the crack tip field of mode 1 is dominated by the tension gradient,which will be shown in another paper.
文摘The oscillating natural convection in the presence of transverse magnetic field with time depending pressure gradient is studied. The analysis of the problem is carried out by assuming that the fluid is flowing in a parallel plate configuration. The emphasis is on low frequency oscillating convective flows induced by g-jitter associated with micro gravity because of their importance to the space processing materials. A general solution for an oscillating flow in the presence of transverse magnetic field is carried out. Some special cases of the oscillating flow and its response to an applied magnetic field are performed. It was observed that the behavior of oscillating free convective flows depends on frequency, amplitude of the driving buoyancy forces, temperature gradient,magnetic field and the electric conditions of the channel walls. In the absence of magnetic field, buoyancy force plays a predominant role in driving the oscillatory flow pattern, and velocity magnitude is also affected by temperature gradients. To suppress the oscillating flow external magnetic field can be used. It is also found that the reduction of the velocity is inversely proportional to the square of the applied magnetic field with conducting wall but directly proportional to the inverse of the magnetic field with insulating wall. Detailed calculations and computational results are also carried out to depict the real situation.
基金Project supported by the National Natural Science Foundation of China(Grant No.51571122)the Fundamental Research Funds for the Central UniversitiesChina(Grant No.30920130121012)
文摘The temporal interface microstructures and diffusions in the diffusion couples with the mutual interactions of the temperature gradient, concentration difference and initial aging time of the alloys are studied by phase-field simulation, and the diffusion couples are produced by the initial aged spinodal alloys with different compositions. Temporal composition evolution and volume fraction of the separated phase indicate the element diffusion direction through the interface under the temperature gradient. The increased temperature gradient induces a wide single-phase region on two sides of the interface.The uphill diffusion proceeds through the interface, no matter whether the diffusion direction is up or down with respect to the temperature gradient. For an alloy with short initial aging time, phase transformation accompanying the interdiffusion results in the straight interface with the single-phase regions on both sides. Compared with the temperature gradient,composition difference of diffusion couple and initial aging time of the alloy show greater effects on diffusion and interface microstructure.
