Solvated zinc ions are prone to undergo desolvation at the electrode/electrolyte interfaces,and unstable H_(2)O molecules within the solvated sheaths tend to trigger hydrogen evolution reaction(HER),further accelerati...Solvated zinc ions are prone to undergo desolvation at the electrode/electrolyte interfaces,and unstable H_(2)O molecules within the solvated sheaths tend to trigger hydrogen evolution reaction(HER),further accelerating interfaces decay.Herein,we propose for the first time a novel strategy to enhance the interfacial stabilities by insitu dynamic reconstruction of weakly solvated Zn2þduring the desolvation processes at heterointerfaces.Theoretical calculations indicate that,due to built-in electric field effects(BEFs),the plating/stripping mechanism shifts from[Zn(H_(2)O)_(6)]_(2)þto[Zn(H_(2)O)_(5)(SO_(4))^(2-)]_(2)þwithout additional electrolyte additives,reducing the solvation ability of H_(2)O,enhancing the competitive coordination of SO_(4)^(2-),essentially eliminating the undesirable side effects of anodes.Hence,symmetric cells can operate stably for 3000 h(51.7-times increase in cycle life),and the full cells can operate stably for 5000 cycles(51.5-times increase in cycle life).This study provides valuable insights into the critical design of weakly solvated Zn^(2+) þand desolvation processes at heterointerfaces.展开更多
Rechargeable magnesium batteries(RMBs)are considered promising candidates for next-generation energy storage systems due to their high theoretical capacity.However,the non-uniform deposition/stripping behavior of Mg m...Rechargeable magnesium batteries(RMBs)are considered promising candidates for next-generation energy storage systems due to their high theoretical capacity.However,the non-uniform deposition/stripping behavior of Mg metal hinders the practical application of RMBs.This study demonstrates that the designed interfacial electric field effect,driven by a copper phthalocyanine(CuPc)conductive interlayer,enhances the kinetics and stability of the Mg anode.In situ electrochemical impedance spectroscopy coupled with distribution of relaxation times analysis reveals that the highly delocalized electron cloud network of CuPc establishes a low-energy-barrier electron transport pathway,significantly reducing charge transfer resistance.Electrochemical characterization and density functional theory calculations indicate that the interfacial electric field effect effectively improves interfacial Mg^(2+)diffusion by enhancing electron delocalization and reducing the Mg^(2+)migration energy barrier.Furthermore,finite element simulations substantiate that the interfacial electric field imparts uniform interfacial charge distribution and homogeneous Mg deposition during plating/stripping processes.Consequently,the symmetric cell with CuPc@Mg achieves an ultra-long lifetime(1,400h at 5mAcm^(−2))and a high Coulombic efficiency(99.3%).Furthermore,the CuPc@Mg||Mo6S8 cell achieves high capacity retention(92%).This work highlights the potential of metal phthalocyanines in stabilizing Mg anodes.展开更多
A study was made of magnetic field effects (MFEs) on the photoreduction reaction of 2-methyl-1,4-naphthoqui- none (MNQ) in Brij 35 micellar solution containing 4-lauroylamino-TEMPO (2,2,6,6-tetramethylpiperidine-1-oxy...A study was made of magnetic field effects (MFEs) on the photoreduction reaction of 2-methyl-1,4-naphthoqui- none (MNQ) in Brij 35 micellar solution containing 4-lauroylamino-TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl) radical (L-R) under magnetic fields below 1.75 T by a nanosecond laser flash photolysis technique. The triplet MNQ mainly underwent the hydrogen abstraction from Brij 35 molecule to give a radical pair. The escaped radical yield increased with magnetic fields from 0 to 0.62 T and then saturated from 0.62 to 1.75 T. MFEs for both sys-tems can be explained by the relaxation mechanism. However, it was supposed that additional radical, L-R affected the MFEs mainly through enhancing the spin-spin interactions of radical pairs. The effect of the micelle size on MFEs of the studying system was also discussed.展开更多
Photolysis of benzyl phenylacetate (ACO_2A), benzyl p-methylphenylacetate (BCO_2A) and 1-naphthyl phenylacetate (ACO_2Np) in homogeneous and micellar solutions results in products typical of radical coupling reactions...Photolysis of benzyl phenylacetate (ACO_2A), benzyl p-methylphenylacetate (BCO_2A) and 1-naphthyl phenylacetate (ACO_2Np) in homogeneous and micellar solutions results in products typical of radical coupling reactions and loss of carbon dioxide. The cage effects upon direct photolysis of these esters in acetonitrile are significantly greater than zero and those in SDS or HDTBr micellar solutions are even greater. In the triplet sensitization reaction of ACO_2 Np in micellar solutions the cage effects are smaller than those obtained upon direct irradiation. However, the application of a 0.05 or 0.2 T external magnetic field in the photolysis in micellar solutions decreases the cage effects dramatically. All these results suggest that the photoextrusions of carbon dioxide from these esters proceed via radical intermediates, and upon direct photolysis the reactive states for the cleavage re- action involve both singlet and triplet excited states.展开更多
The behavior of buoyancy-driven magnetohydrodynamic(MHD)nanofluid flows with temperature-sensitive viscosity plays a pivotal role in high-performance thermal systems such as electronics cooling,nuclear reactors,and me...The behavior of buoyancy-driven magnetohydrodynamic(MHD)nanofluid flows with temperature-sensitive viscosity plays a pivotal role in high-performance thermal systems such as electronics cooling,nuclear reactors,and metallurgical processes.This study focuses on the boundary layer flow of a Casson-based sodium alginate Fe3O4 nanofluid influenced by magnetic field-dependent viscosity and thermal radiation,as it interacts with a vertically stretching sheet under dissipative conditions.To manage the inherent nonlinearities,Lie group transformations are applied to reformulate the governing boundary layer equations into similarity forms.These reduced equations are then solved via the Spectral Quasi-Linearization Method(SQLM),ensuring high accuracy and computational efficiency.The analysis comprehensively explores the impact of key parameters-including mixed convection intensity,magnetic field strength,Casson fluid properties,temperature-dependent viscosity,thermal radiation,and viscous dissipation(Eckert number)-on flow characteristics and heat transfer rates.Findings reveal that increasing magnetic field-dependent viscosity diminishes both skin friction and thermal transport,while buoyancy effects enhance heat transfer but lower shear stress on the surface.This work provides critical insights into controlling heat and momentum transfer in Casson nanofluids,advancing the design of thermal management systems involving complex fluids under magnetic and buoyant forces.展开更多
We have combined molecular dynamics simulations with first-principles calculations to study electron transport in a single molecular junction of perylene tetracarboxylic diimide (PTCDI) in aqueous solution under exter...We have combined molecular dynamics simulations with first-principles calculations to study electron transport in a single molecular junction of perylene tetracarboxylic diimide (PTCDI) in aqueous solution under external electric gate fields. It is found that the statistics of the molecular conductance are very sensitive to the strength of the electric field. The statistics of the molecular conductance are strongly associated with the thermal fluctuation of the water molecules around the PTCDI molecule. Our simulations reproduce the experimentally observed three orders of magnitude enhancement of the conductance, as well as the temperature dependent conductance, under the electrochemical gates. The effects of the molecular polarization and the dipole rearrangement of the aqueous solution are also discussed.展开更多
We use the extended gate field effect transistor (EGFET)as the structure of the chlorine ion sensor,and the chlorine ion ionophores (ETH9033 and TDDMAC1)are incorporated into solvent polymeric membrane (PVC/DOS),then ...We use the extended gate field effect transistor (EGFET)as the structure of the chlorine ion sensor,and the chlorine ion ionophores (ETH9033 and TDDMAC1)are incorporated into solvent polymeric membrane (PVC/DOS),then the chlorine ion selective membrane is formed on the sensing window,and the fabrication of the EGFET chlorine ion sensing device is completed.The surface potential on the sensing membrane of the EGFET chlorine ion sensing device will be changed in the different chlorine ion concentration solutions,then changes further gate voltage and drain current to detect chlorine ion concentration.We will study non-ideal effects such as temperature,hysteresis and drift effects for the EGFET chlorine ion sensing device in this paper,these researches will help us to improve the sensing characteristics of the EGFET chlorine ion sensing device.展开更多
The magnetic field effects （MFEs） are studied on photocatalytic degradation of methylene blue （MB） solution using ZnO and TiO2 particles. The UV-VIS-NIR spectrometer is used to monitor the MB concentrations, and t...The magnetic field effects （MFEs） are studied on photocatalytic degradation of methylene blue （MB） solution using ZnO and TiO2 particles. The UV-VIS-NIR spectrometer is used to monitor the MB concentrations, and the dependence of the reaction rate on the initial dye concentration and settling duration is studied under UV light irradiation. It is found that the MFEs exist on the heterogeneous reaction systems for both ZnO and TiO2 powders and that the extraordinary phenomenon is reproducible. For ZnO powder, the results are in good agreement with the second-order reaction kinetics following the Langmuir-Hinshelwood （L-H） model, while the reaction for TiO2 follows first-order kinetics. It enhances the photodegradation for ZnO, while it reduces or enhances the reaction for TiO2 depending on the initial dye concentrations. The MFEs become small or negligible when the same photodecomposition experiment is carried out after settling the MB solution for more than three hours for both ZnO and TiO2. It is suggested that the key factors of MFEs on photocatalytic degradation is the condition of the MB solution as well as the characteristics of photocatalysts. The alteration of the MFEs ascribed to the solution condition caused by variation of the settling time.展开更多
The excitation and evolution of magnetohydrodynamic density waves are considered in a differentially rotating thin gaseous disk embedded with both an azimuthal magnetic field and a vertical magnetic field perpendicula...The excitation and evolution of magnetohydrodynamic density waves are considered in a differentially rotating thin gaseous disk embedded with both an azimuthal magnetic field and a vertical magnetic field perpendicular to the disk. Our results shows that the effect of isopedic vertical magnetic fields tend to stabilize the fast MHD density waves while slow MHD density waves are not affected by such vertical magnetic fields for either rigid or differential rotation.展开更多
In order to provide a reference basis for efficient prevention and control of apple rust,apple rust(Gymnosporangium yamadai)was used as the test material,the field control effects of six triazole fungicides with diffe...In order to provide a reference basis for efficient prevention and control of apple rust,apple rust(Gymnosporangium yamadai)was used as the test material,the field control effects of six triazole fungicides with different concentrations and different application times on apple rust,and the safety of application in different periods on the crop were investigated in field trials.The results showed that the control effect and safety of myclobutanil were excellent.In the prevention test,the effects of myclobutanil 40%EC 2000 times and 4000 times dilutions in protecting apple leaves from G.yamadai infection reached more than 98%at 10 d after the second spraying in the fruitlet stage,and in the treatment test,the control effects of inhibiting the spread of leaf lesions were 90.89%and 87.17%at 16 d after the fourth spraying in the fruit expansion stage,respectively.The results of the crop safety test showed that when applying the triazole fungicides with different concentrations from the red bud stage to the fruit expansion stage of apple trees,there were no adverse effects on the leaves,branches,flowers and fruit,as well as no rust or deformity on the fruit surface.When spraying the fungicides from the red bud stage to the fruit expansion stage,except that the single fruit weights in the treatment of the 10%difenoconazole DC 2000 times and myclobutanil 40%EC 4000 times dilutions were reduced without a significant difference from the control,and the values of other treatments were all reduced by more than 9%compared with the control.When applying the fungicides during the fruit expansion period,none of the tested fungicide treatments had a significant effect on the fruit growth.展开更多
The effects of magnetic field annealing on the properties of Fe48Co52 alloy nanowire arrays with various interwire distances （Di=30-60 nm） and wire diameters （Dw=22-46 nm） were investigated in detail. It was found...The effects of magnetic field annealing on the properties of Fe48Co52 alloy nanowire arrays with various interwire distances （Di=30-60 nm） and wire diameters （Dw=22-46 nm） were investigated in detail. It was found that the array＇s best annealing temperature and crys- talline structure did not show any apparent dependence on the treatment of applying a 3 kOe magnetic field along the wire during the annealing process. For arrays with small Dw or with large Di, the treatment of magnetic field annealing also had no obvious influence on their magnetic performances. However, such a magnetic field annealing constrained the shift of the easy magnetization direction and improved the coercivity and the squareness obviously for arrays with large Dw or with small Di. The difference in the intensity of the effective anisotropic field within the arrays was believed to be responsible for this different variation of the array＇s magnetic properties after magnetic field annealing.展开更多
We investigate the effects of pure Dzyaloshinskii Moriya （DM） interaction with magnetic field on entanglement in intrinsic decoherence, assuming that the system is initially in four Bell states ｜φ±〉 = （｜00...We investigate the effects of pure Dzyaloshinskii Moriya （DM） interaction with magnetic field on entanglement in intrinsic decoherence, assuming that the system is initially in four Bell states ｜φ±〉 = （｜00） ± ｜11〉）/√2 and ｜ψ±〉 = （｜01） ±｜10〉）/√2, respectively. It is found that if the system is initially in the state p1（0） = ｜φ＋〉〈φ＋1, the entanglement can obtain its maximum when the DM interaction vector D is in the plane of XOZ and magnetic field B = By with the infinite time t, moreover the entanglement is independent of By and t when By is perpendicular to D. In addition, we obtain similar results when the system is initially in the states p2（0） = ｜φ-〉〈φ-｜ or p3 （0） = ｜ψ＋〉〈ψ＋1. However, we find that if the system is initially in the state P4 （0） = ｜ψ-〉〈ψ-l, the entanglement can obtain its maximum for infinite t, when the DM vector is in the plane ofYOZ, XOZ, or XOY, with the magnetic field parallel to X, Y, or Z axis, respectively. Moreover, when the axial B is perpendicular to D for the initial state p4（O）, the negativity oscillates with time t and reaches a stable value, the larger the value of B is, the greater the stable value is, and the shorter the oscillation time of the negativity is. Thus we can adjust the direction and value of the external magnetic field to obtain the maximal entanglement, and avoid the adverse effects of external environment in some initial state. This is feasible within the cun＇ent experimental technology.展开更多
It is shown that the introduction of thermal effect, zero-point vibration, and phonon anharmonicity to a high quality and first-principle-Sased force field （atomic potential） results in a significant improvement in ...It is shown that the introduction of thermal effect, zero-point vibration, and phonon anharmonicity to a high quality and first-principle-Sased force field （atomic potential） results in a significant improvement in predict- ing the densities for the α phase crystalline hexahydro-1,3,5-trinitro-l,3,5-triazine （RDX）, and derivation of its high-fidelity Hugoniot locus and Mie-Grfineisen equation of state covering a very wide range of pressures and temperatures. This work can be used to efficiently and accurately predict the thermophysical properties of solid explosives over the pressures and temperatures to which they are subjected, which is a long-standing issue in the field of energetic materials.展开更多
A sensor,serving as a transducer,produces a quantifiable output in response to a predetermined input stimulus,which may be of a chemical or physical nature.The field of gas detection has experienced a substantial surg...A sensor,serving as a transducer,produces a quantifiable output in response to a predetermined input stimulus,which may be of a chemical or physical nature.The field of gas detection has experienced a substantial surge in research activity,attributable to the diverse functionalities and enhanced accessibility of advanced active materials.In this work,recent advances in gas sensors,specifically those utilizing Field Effect Transistors(FETs),are summarized,including device configurations,response characteristics,sensor materials,and application domains.In pursuing high-performance artificial olfactory systems,the evolution of FET gas sensors necessitates their synchronization with material advancements.These materials should have large surface areas to enhance gas adsorption,efficient conversion of gas input to detectable signals,and strong mechanical qualities.The exploration of gas-sensitive materials has covered diverse categories,such as organic semiconductor polymers,conductive organic compounds and polymers,metal oxides,metal-organic frameworks,and low-dimensional materials.The application of gas sensing technology holds significant promise in domains such as industrial safety,environmental monitoring,and medical diagnostics.This comprehensive review thoroughly examines recent progress,identifies prevailing technical challenges,and outlines prospects for gas detection technology utilizing field effect transistors.The primary aim is to provide a valuable reference for driving the development of the next generation of gas-sensitive monitoring and detection systems characterized by improved sensitivity,selectivity,and intelligence.展开更多
Studied by Mr. LIU Zhongzhu, ex Chairman of Fujian Academy of Agri Sciences, a combined technique of man—made biosphere in rice fields deserves notice. The research indicated that using man—made biosphere in rice fi...Studied by Mr. LIU Zhongzhu, ex Chairman of Fujian Academy of Agri Sciences, a combined technique of man—made biosphere in rice fields deserves notice. The research indicated that using man—made biosphere in rice fields can enrich soil, reduce the infects of diseases, insects and weeds, economize the use of pesticide and herbicide, decrease green house effect, and improve atmosphere. As tested, the yield for rice is usually 10500—12000 kg/ha, for fish is usually 2250—3250 kg/ha. Again, about 50%—60% fertilizer and 30%—50% pesticide can be saved. The net income increased $ 1,080—1,800 per ha.展开更多
Recent advances in atomic optical clocks based on electronic transitions have achieved frequency uncertainties at the10^(-19)level,enabling wide applications in testing variations of physical constants,exploring dark ...Recent advances in atomic optical clocks based on electronic transitions have achieved frequency uncertainties at the10^(-19)level,enabling wide applications in testing variations of physical constants,exploring dark matter signatures,and enhancing precision metrology for position,navigation,and timing systems.To pursue higher-precision optical clocks,the development of nuclear optical clocks has emerged,with the^(229)Th system distinguished by its unique low-lying isomeric state at~8.4 eV and a natural linewidth of approximately 100μHz,promising uncertainties below 10^(-19).The intrinsic insensitivity of nuclear transitions to external perturbations and their subatomic-scale spatial confinement provide significant advantages over electronic transitions in mitigating environmental shifts.Recent experimental breakthroughs include the excitation of the nuclear clock transition in solid-state^(229)Th-doped crystals with spectral resolution at the k Hz level.However,critical challenges persist,particularly in implementing effective laser excitation schemes(e.g.,via the electronic bridge mechanism)and closed-loop quantum control in trapped ion systems.Addressing these requires comprehensive understanding of complex many-body interactions in^(229)Th,encompassing electronic structure,nuclear deformation,hyperfine and field shift,and solid-state environmental coupling.This review synthesizes recent advancements in(i)the characterization of nuclear and atomic structures of the^(229)Th nuclear clock,and(ii)precise evaluation and mitigation of external perturbations affecting the clock transitions.The analysis provides a solid theoretical and experimental foundation for optimizing^(229)Th-based nuclear clock performance.展开更多
[Objective] This study was conducted to screen a synergistic biological fungicide complex to control Fusarium wilt, reducing the use of chemical pesticides. [Method] The inhibitory effects of Bacil us subtilis DJ-6 an...[Objective] This study was conducted to screen a synergistic biological fungicide complex to control Fusarium wilt, reducing the use of chemical pesticides. [Method] The inhibitory effects of Bacil us subtilis DJ-6 and pyraclostrobin alone or in combination at five ratios against Fusarium oxysporum were detected by mea-suring mycelium growth rate in laboratory tests. The growth promotion and disease control effect of combined or single use of 20% pyraclostrobin and 2 ×1011 cfu/g B. subtilis DJ-6 WP at 1∶1 000, 1∶2 000 and 1∶3 000 dilutions were detected in field trials. [Result] The EC50 values of combined use of B. subtilis DJ-6 and pyra-clostrobin at ratios of 1∶1, 1∶2, 1∶3, 1∶4 and 1∶5 against F. oxysporum were 5.311 5, 4.008 6, 3.570 6, 3.350 9 and 3.218 9 μg/ml, with the synergistic ratios （SR） of 2.28, 1.77, 1.53, 1.64, 1.11, among which the synergetic effect at 1∶1 was the best. The fungicidal activity of pyraclostrobin was greater than that of B. subtilis DJ-6 in laboratory tests. Field trials revealed that al the 1∶1 000, 1∶2 000 and 1∶3 000 dilu-tions of 20% pyraclostrobin·2×1011 cfu/g B. subtilis DJ-6 WP in combination, 1∶1 000 dilution of 1 ×1012 cfu/g B. subtilis DJ-6 WP and 1∶2 000 dilution of 250 g/L pyra-clostrobin EC promoted the growth of strawberry by increasing plant height, leaf petiole, leaf blade area and stem diameter. Among them, the treatments with 1∶1 000 and 1∶2 000 of 20% pyraclostrobin · 2×1011 cfu/g B. subtilis DJ-6 WP in combina-tion had better effects than other treatments. The control effects of al the treat-ments were measured 30 and 80 d after fungicide application. The control effects of 1∶1 000 dilution of 20% pyraclostrobin and 2×1011 cfu/g B. subtilis DJ-6 in combina-tion were up to 100% and 93.11%, which were higher than those in al other treat-ments. The second highest control effects were found in the treatment with 1∶ 2 000 dilution of 20% pyraclostrobin and 2×1011 cfu/g B. subtilis DJ-6 in combination, they were 92.49% and 86.49%, higher than those in other treatments except the 1∶1 000 dilution of 20% pyraclostrobin and 2 ×1011 cfu/g B. subtilis DJ-6 in combination. The control effects of 1∶3 000 dilution of 20% pyraclostrobin and 2×1011 cfu/g B. subtilis DJ-6 in combination were 82.61% and 72.42%, higher than those in treatment with 1∶1 000 dilution of 1×1012 cfu/g B. subtilis DJ-6 WP, but lower than those in treat-ment with 1∶2 000 dilution of 25% pyraclostrobin EC. [Conclusion] Al the results re-vealed that the combination use of 20% pyraclostrobin and 2 ×1011 cfu/g B. subtilis DJ-6 WP at 1∶1 000 to 1∶2 000 dilution had better control effect against strawberry Fusarium wilt.展开更多
ZnO nanosheets with thickness of a few nanometers are prepared by vapor transport and condensation method, and their structure and optical properties are well characterized. Field effect transistor （FET） and ultravi...ZnO nanosheets with thickness of a few nanometers are prepared by vapor transport and condensation method, and their structure and optical properties are well characterized. Field effect transistor （FET） and ultraviolet （UV） sensors are fabricated based on the ZnO nanosheets. Due to the peculiar structure of nanosheet, the FET shows n-type enhanced mode behavior and high electrical performance, and its field-effect mobility and on/off cur- rent ratio can reach 256 cm2/（V.s） and ~10^8, respectively. Moreover, the response of UV sensors can also be remarkably improved to ~3 × 10^8. The results make the ZnO nanosheets be a good material for the applications in nanoelectronic and optoelectronic devices.展开更多
A mechanism of oxygen transportation in Czochralski growth of silicon crystals under a horizontal magnetic field (HMCZ) is proposed. Oxygen depleted surface melt, driven to the growth interface by the thermal Marangon...A mechanism of oxygen transportation in Czochralski growth of silicon crystals under a horizontal magnetic field (HMCZ) is proposed. Oxygen depleted surface melt, driven to the growth interface by the thermal Marangoni flow, determines oxygen concentration in the grown crystals. Systematic study was carried out to investigate effects of growth parameters on oxygen incorporation into crystals.展开更多
基金financially supported by the National Natural Science Foundation of China(51977097).
文摘Solvated zinc ions are prone to undergo desolvation at the electrode/electrolyte interfaces,and unstable H_(2)O molecules within the solvated sheaths tend to trigger hydrogen evolution reaction(HER),further accelerating interfaces decay.Herein,we propose for the first time a novel strategy to enhance the interfacial stabilities by insitu dynamic reconstruction of weakly solvated Zn2þduring the desolvation processes at heterointerfaces.Theoretical calculations indicate that,due to built-in electric field effects(BEFs),the plating/stripping mechanism shifts from[Zn(H_(2)O)_(6)]_(2)þto[Zn(H_(2)O)_(5)(SO_(4))^(2-)]_(2)þwithout additional electrolyte additives,reducing the solvation ability of H_(2)O,enhancing the competitive coordination of SO_(4)^(2-),essentially eliminating the undesirable side effects of anodes.Hence,symmetric cells can operate stably for 3000 h(51.7-times increase in cycle life),and the full cells can operate stably for 5000 cycles(51.5-times increase in cycle life).This study provides valuable insights into the critical design of weakly solvated Zn^(2+) þand desolvation processes at heterointerfaces.
基金financially supported by the National Natural Science Foundation of China(52274295)Hebei Province Science and Technology Research and Development Platform Special Innovation Capability Enhancement Plan Project(24464402D)+3 种基金the Fundamental Research Funds for the Central Universities(N2423051,N2423005)the Science and Technology Project of Hebei Education Department(QN2024238)The Basic Research Program Project of Shijiazhuang City for Universities Stationed in Hebei Province(241790937A)2025 Hebei Provincial Post-graduate Student Innovation Ability Training Funding Project(CXZZBS2025202,CXZZSS2025157).
文摘Rechargeable magnesium batteries(RMBs)are considered promising candidates for next-generation energy storage systems due to their high theoretical capacity.However,the non-uniform deposition/stripping behavior of Mg metal hinders the practical application of RMBs.This study demonstrates that the designed interfacial electric field effect,driven by a copper phthalocyanine(CuPc)conductive interlayer,enhances the kinetics and stability of the Mg anode.In situ electrochemical impedance spectroscopy coupled with distribution of relaxation times analysis reveals that the highly delocalized electron cloud network of CuPc establishes a low-energy-barrier electron transport pathway,significantly reducing charge transfer resistance.Electrochemical characterization and density functional theory calculations indicate that the interfacial electric field effect effectively improves interfacial Mg^(2+)diffusion by enhancing electron delocalization and reducing the Mg^(2+)migration energy barrier.Furthermore,finite element simulations substantiate that the interfacial electric field imparts uniform interfacial charge distribution and homogeneous Mg deposition during plating/stripping processes.Consequently,the symmetric cell with CuPc@Mg achieves an ultra-long lifetime(1,400h at 5mAcm^(−2))and a high Coulombic efficiency(99.3%).Furthermore,the CuPc@Mg||Mo6S8 cell achieves high capacity retention(92%).This work highlights the potential of metal phthalocyanines in stabilizing Mg anodes.
基金Project supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars State Education Ministry+1 种基金 and the Scientific Research Foundation for the Returned Overseas University of Science and Technology of China (No. 2047308
文摘A study was made of magnetic field effects (MFEs) on the photoreduction reaction of 2-methyl-1,4-naphthoqui- none (MNQ) in Brij 35 micellar solution containing 4-lauroylamino-TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl) radical (L-R) under magnetic fields below 1.75 T by a nanosecond laser flash photolysis technique. The triplet MNQ mainly underwent the hydrogen abstraction from Brij 35 molecule to give a radical pair. The escaped radical yield increased with magnetic fields from 0 to 0.62 T and then saturated from 0.62 to 1.75 T. MFEs for both sys-tems can be explained by the relaxation mechanism. However, it was supposed that additional radical, L-R affected the MFEs mainly through enhancing the spin-spin interactions of radical pairs. The effect of the micelle size on MFEs of the studying system was also discussed.
基金This work was supported by the National Science Foundation of China and the National Laboratory for Structure Chemistry of Unstable and Stable Species
文摘Photolysis of benzyl phenylacetate (ACO_2A), benzyl p-methylphenylacetate (BCO_2A) and 1-naphthyl phenylacetate (ACO_2Np) in homogeneous and micellar solutions results in products typical of radical coupling reactions and loss of carbon dioxide. The cage effects upon direct photolysis of these esters in acetonitrile are significantly greater than zero and those in SDS or HDTBr micellar solutions are even greater. In the triplet sensitization reaction of ACO_2 Np in micellar solutions the cage effects are smaller than those obtained upon direct irradiation. However, the application of a 0.05 or 0.2 T external magnetic field in the photolysis in micellar solutions decreases the cage effects dramatically. All these results suggest that the photoextrusions of carbon dioxide from these esters proceed via radical intermediates, and upon direct photolysis the reactive states for the cleavage re- action involve both singlet and triplet excited states.
文摘The behavior of buoyancy-driven magnetohydrodynamic(MHD)nanofluid flows with temperature-sensitive viscosity plays a pivotal role in high-performance thermal systems such as electronics cooling,nuclear reactors,and metallurgical processes.This study focuses on the boundary layer flow of a Casson-based sodium alginate Fe3O4 nanofluid influenced by magnetic field-dependent viscosity and thermal radiation,as it interacts with a vertically stretching sheet under dissipative conditions.To manage the inherent nonlinearities,Lie group transformations are applied to reformulate the governing boundary layer equations into similarity forms.These reduced equations are then solved via the Spectral Quasi-Linearization Method(SQLM),ensuring high accuracy and computational efficiency.The analysis comprehensively explores the impact of key parameters-including mixed convection intensity,magnetic field strength,Casson fluid properties,temperature-dependent viscosity,thermal radiation,and viscous dissipation(Eckert number)-on flow characteristics and heat transfer rates.Findings reveal that increasing magnetic field-dependent viscosity diminishes both skin friction and thermal transport,while buoyancy effects enhance heat transfer but lower shear stress on the surface.This work provides critical insights into controlling heat and momentum transfer in Casson nanofluids,advancing the design of thermal management systems involving complex fluids under magnetic and buoyant forces.
基金This work was supported by the Swedish Research Council(VR),the Swedish National Infrastructure for Computing(SNIC)the Natural Science Foundation of China(No.20825312)and the Fok Ying Tong Education Foundation(No.111013).
文摘We have combined molecular dynamics simulations with first-principles calculations to study electron transport in a single molecular junction of perylene tetracarboxylic diimide (PTCDI) in aqueous solution under external electric gate fields. It is found that the statistics of the molecular conductance are very sensitive to the strength of the electric field. The statistics of the molecular conductance are strongly associated with the thermal fluctuation of the water molecules around the PTCDI molecule. Our simulations reproduce the experimentally observed three orders of magnitude enhancement of the conductance, as well as the temperature dependent conductance, under the electrochemical gates. The effects of the molecular polarization and the dipole rearrangement of the aqueous solution are also discussed.
文摘We use the extended gate field effect transistor (EGFET)as the structure of the chlorine ion sensor,and the chlorine ion ionophores (ETH9033 and TDDMAC1)are incorporated into solvent polymeric membrane (PVC/DOS),then the chlorine ion selective membrane is formed on the sensing window,and the fabrication of the EGFET chlorine ion sensing device is completed.The surface potential on the sensing membrane of the EGFET chlorine ion sensing device will be changed in the different chlorine ion concentration solutions,then changes further gate voltage and drain current to detect chlorine ion concentration.We will study non-ideal effects such as temperature,hysteresis and drift effects for the EGFET chlorine ion sensing device in this paper,these researches will help us to improve the sensing characteristics of the EGFET chlorine ion sensing device.
文摘The magnetic field effects （MFEs） are studied on photocatalytic degradation of methylene blue （MB） solution using ZnO and TiO2 particles. The UV-VIS-NIR spectrometer is used to monitor the MB concentrations, and the dependence of the reaction rate on the initial dye concentration and settling duration is studied under UV light irradiation. It is found that the MFEs exist on the heterogeneous reaction systems for both ZnO and TiO2 powders and that the extraordinary phenomenon is reproducible. For ZnO powder, the results are in good agreement with the second-order reaction kinetics following the Langmuir-Hinshelwood （L-H） model, while the reaction for TiO2 follows first-order kinetics. It enhances the photodegradation for ZnO, while it reduces or enhances the reaction for TiO2 depending on the initial dye concentrations. The MFEs become small or negligible when the same photodecomposition experiment is carried out after settling the MB solution for more than three hours for both ZnO and TiO2. It is suggested that the key factors of MFEs on photocatalytic degradation is the condition of the MB solution as well as the characteristics of photocatalysts. The alteration of the MFEs ascribed to the solution condition caused by variation of the settling time.
文摘The excitation and evolution of magnetohydrodynamic density waves are considered in a differentially rotating thin gaseous disk embedded with both an azimuthal magnetic field and a vertical magnetic field perpendicular to the disk. Our results shows that the effect of isopedic vertical magnetic fields tend to stabilize the fast MHD density waves while slow MHD density waves are not affected by such vertical magnetic fields for either rigid or differential rotation.
基金National Key R&D Program of China(2016YFD0201100)China Agriculture Research System of MOF and MARA(CARS-27)+2 种基金Key Common Technology Research Project for the High-quality Development of Agriculture in Hebei Province(19226508D)Special Fund for Science and Technology Development of Xinjiang Production and Construction Corps(2018AB035)Science and Technology Research Fund of the Second Agricultural Division of Xinjiang Production and Construction Corps(2019NYGG01).
文摘In order to provide a reference basis for efficient prevention and control of apple rust,apple rust(Gymnosporangium yamadai)was used as the test material,the field control effects of six triazole fungicides with different concentrations and different application times on apple rust,and the safety of application in different periods on the crop were investigated in field trials.The results showed that the control effect and safety of myclobutanil were excellent.In the prevention test,the effects of myclobutanil 40%EC 2000 times and 4000 times dilutions in protecting apple leaves from G.yamadai infection reached more than 98%at 10 d after the second spraying in the fruitlet stage,and in the treatment test,the control effects of inhibiting the spread of leaf lesions were 90.89%and 87.17%at 16 d after the fourth spraying in the fruit expansion stage,respectively.The results of the crop safety test showed that when applying the triazole fungicides with different concentrations from the red bud stage to the fruit expansion stage of apple trees,there were no adverse effects on the leaves,branches,flowers and fruit,as well as no rust or deformity on the fruit surface.When spraying the fungicides from the red bud stage to the fruit expansion stage,except that the single fruit weights in the treatment of the 10%difenoconazole DC 2000 times and myclobutanil 40%EC 4000 times dilutions were reduced without a significant difference from the control,and the values of other treatments were all reduced by more than 9%compared with the control.When applying the fungicides during the fruit expansion period,none of the tested fungicide treatments had a significant effect on the fruit growth.
基金ACKNOWLEDGMENTS This work was supported by the National Nature Science Foundation of China （No.50171033）, the National Key Project of Fundamental Research of China （No.2005CB623605）, and the Scientific Research Foundation for the Doctor of Hefei University of Technology （No.035032）.
文摘The effects of magnetic field annealing on the properties of Fe48Co52 alloy nanowire arrays with various interwire distances （Di=30-60 nm） and wire diameters （Dw=22-46 nm） were investigated in detail. It was found that the array＇s best annealing temperature and crys- talline structure did not show any apparent dependence on the treatment of applying a 3 kOe magnetic field along the wire during the annealing process. For arrays with small Dw or with large Di, the treatment of magnetic field annealing also had no obvious influence on their magnetic performances. However, such a magnetic field annealing constrained the shift of the easy magnetization direction and improved the coercivity and the squareness obviously for arrays with large Dw or with small Di. The difference in the intensity of the effective anisotropic field within the arrays was believed to be responsible for this different variation of the array＇s magnetic properties after magnetic field annealing.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11204061,11374085,11104057,11274010 and 11204002the Anhui Provincial Natural Science Foundation under Grant No 1408085MA16+4 种基金the Anhui Provincial Candidates for Academic and Technical Leaders Foundation under Grant No 2015H052the Discipline Top-Notch Talents Foundationthe Excellent Young Talents Support Plan of Anhui Provincial Universitiesthe Specialized Research Fund for the Doctoral Program of Higher Education under Grant No 20113401110002the 211 Project of Anhui University,and the Personnel Department of Anhui Province
文摘We investigate the effects of pure Dzyaloshinskii Moriya （DM） interaction with magnetic field on entanglement in intrinsic decoherence, assuming that the system is initially in four Bell states ｜φ±〉 = （｜00） ± ｜11〉）/√2 and ｜ψ±〉 = （｜01） ±｜10〉）/√2, respectively. It is found that if the system is initially in the state p1（0） = ｜φ＋〉〈φ＋1, the entanglement can obtain its maximum when the DM interaction vector D is in the plane of XOZ and magnetic field B = By with the infinite time t, moreover the entanglement is independent of By and t when By is perpendicular to D. In addition, we obtain similar results when the system is initially in the states p2（0） = ｜φ-〉〈φ-｜ or p3 （0） = ｜ψ＋〉〈ψ＋1. However, we find that if the system is initially in the state P4 （0） = ｜ψ-〉〈ψ-l, the entanglement can obtain its maximum for infinite t, when the DM vector is in the plane ofYOZ, XOZ, or XOY, with the magnetic field parallel to X, Y, or Z axis, respectively. Moreover, when the axial B is perpendicular to D for the initial state p4（O）, the negativity oscillates with time t and reaches a stable value, the larger the value of B is, the greater the stable value is, and the shorter the oscillation time of the negativity is. Thus we can adjust the direction and value of the external magnetic field to obtain the maximal entanglement, and avoid the adverse effects of external environment in some initial state. This is feasible within the cun＇ent experimental technology.
基金Supported by the National Natural Science Foundation of China under Grant Nos 11372053,11402031,11221202 and 11172044the Opening Project of the State Key Laboratory of Explosion Science and Technology under Grant No KFJJ14-06M
文摘It is shown that the introduction of thermal effect, zero-point vibration, and phonon anharmonicity to a high quality and first-principle-Sased force field （atomic potential） results in a significant improvement in predict- ing the densities for the α phase crystalline hexahydro-1,3,5-trinitro-l,3,5-triazine （RDX）, and derivation of its high-fidelity Hugoniot locus and Mie-Grfineisen equation of state covering a very wide range of pressures and temperatures. This work can be used to efficiently and accurately predict the thermophysical properties of solid explosives over the pressures and temperatures to which they are subjected, which is a long-standing issue in the field of energetic materials.
基金supported by the National Key R&D Program of China(No.2023YFC3707201)the National Natural Science Foundation of China(No.52320105003)+2 种基金the Informatization Plan of Chinese Academy of Sciences(No.CAS-WX2023PY-0103)the Fundamental Research Funds for the Central Universities(No.E3ET1803)sponsored by the Alliance of International Science Organizations(ANSO)scholarship for young talents.
文摘A sensor,serving as a transducer,produces a quantifiable output in response to a predetermined input stimulus,which may be of a chemical or physical nature.The field of gas detection has experienced a substantial surge in research activity,attributable to the diverse functionalities and enhanced accessibility of advanced active materials.In this work,recent advances in gas sensors,specifically those utilizing Field Effect Transistors(FETs),are summarized,including device configurations,response characteristics,sensor materials,and application domains.In pursuing high-performance artificial olfactory systems,the evolution of FET gas sensors necessitates their synchronization with material advancements.These materials should have large surface areas to enhance gas adsorption,efficient conversion of gas input to detectable signals,and strong mechanical qualities.The exploration of gas-sensitive materials has covered diverse categories,such as organic semiconductor polymers,conductive organic compounds and polymers,metal oxides,metal-organic frameworks,and low-dimensional materials.The application of gas sensing technology holds significant promise in domains such as industrial safety,environmental monitoring,and medical diagnostics.This comprehensive review thoroughly examines recent progress,identifies prevailing technical challenges,and outlines prospects for gas detection technology utilizing field effect transistors.The primary aim is to provide a valuable reference for driving the development of the next generation of gas-sensitive monitoring and detection systems characterized by improved sensitivity,selectivity,and intelligence.
文摘Studied by Mr. LIU Zhongzhu, ex Chairman of Fujian Academy of Agri Sciences, a combined technique of man—made biosphere in rice fields deserves notice. The research indicated that using man—made biosphere in rice fields can enrich soil, reduce the infects of diseases, insects and weeds, economize the use of pesticide and herbicide, decrease green house effect, and improve atmosphere. As tested, the yield for rice is usually 10500—12000 kg/ha, for fish is usually 2250—3250 kg/ha. Again, about 50%—60% fertilizer and 30%—50% pesticide can be saved. The net income increased $ 1,080—1,800 per ha.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant Nos.XDB0920100 and XDB0920101)the National Natural Science Foundation of China(Grant Nos.12174402,12393821,12274417)the Chinese Academy of Sciences Project for Young Scientists in Basic Research(Grant No.YSBR-055)。
文摘Recent advances in atomic optical clocks based on electronic transitions have achieved frequency uncertainties at the10^(-19)level,enabling wide applications in testing variations of physical constants,exploring dark matter signatures,and enhancing precision metrology for position,navigation,and timing systems.To pursue higher-precision optical clocks,the development of nuclear optical clocks has emerged,with the^(229)Th system distinguished by its unique low-lying isomeric state at~8.4 eV and a natural linewidth of approximately 100μHz,promising uncertainties below 10^(-19).The intrinsic insensitivity of nuclear transitions to external perturbations and their subatomic-scale spatial confinement provide significant advantages over electronic transitions in mitigating environmental shifts.Recent experimental breakthroughs include the excitation of the nuclear clock transition in solid-state^(229)Th-doped crystals with spectral resolution at the k Hz level.However,critical challenges persist,particularly in implementing effective laser excitation schemes(e.g.,via the electronic bridge mechanism)and closed-loop quantum control in trapped ion systems.Addressing these requires comprehensive understanding of complex many-body interactions in^(229)Th,encompassing electronic structure,nuclear deformation,hyperfine and field shift,and solid-state environmental coupling.This review synthesizes recent advancements in(i)the characterization of nuclear and atomic structures of the^(229)Th nuclear clock,and(ii)precise evaluation and mitigation of external perturbations affecting the clock transitions.The analysis provides a solid theoretical and experimental foundation for optimizing^(229)Th-based nuclear clock performance.
基金Supported by Agricultural Science and Technology Research and Development Program of Jiangsu Province(BE2012378)Six Talent Peaks Project of Jiangsu Province(2013-NY-001)Agricultural Science and Technology Research and Development Program of Zhenjiang City(NY2014029)~~
文摘[Objective] This study was conducted to screen a synergistic biological fungicide complex to control Fusarium wilt, reducing the use of chemical pesticides. [Method] The inhibitory effects of Bacil us subtilis DJ-6 and pyraclostrobin alone or in combination at five ratios against Fusarium oxysporum were detected by mea-suring mycelium growth rate in laboratory tests. The growth promotion and disease control effect of combined or single use of 20% pyraclostrobin and 2 ×1011 cfu/g B. subtilis DJ-6 WP at 1∶1 000, 1∶2 000 and 1∶3 000 dilutions were detected in field trials. [Result] The EC50 values of combined use of B. subtilis DJ-6 and pyra-clostrobin at ratios of 1∶1, 1∶2, 1∶3, 1∶4 and 1∶5 against F. oxysporum were 5.311 5, 4.008 6, 3.570 6, 3.350 9 and 3.218 9 μg/ml, with the synergistic ratios （SR） of 2.28, 1.77, 1.53, 1.64, 1.11, among which the synergetic effect at 1∶1 was the best. The fungicidal activity of pyraclostrobin was greater than that of B. subtilis DJ-6 in laboratory tests. Field trials revealed that al the 1∶1 000, 1∶2 000 and 1∶3 000 dilu-tions of 20% pyraclostrobin·2×1011 cfu/g B. subtilis DJ-6 WP in combination, 1∶1 000 dilution of 1 ×1012 cfu/g B. subtilis DJ-6 WP and 1∶2 000 dilution of 250 g/L pyra-clostrobin EC promoted the growth of strawberry by increasing plant height, leaf petiole, leaf blade area and stem diameter. Among them, the treatments with 1∶1 000 and 1∶2 000 of 20% pyraclostrobin · 2×1011 cfu/g B. subtilis DJ-6 WP in combina-tion had better effects than other treatments. The control effects of al the treat-ments were measured 30 and 80 d after fungicide application. The control effects of 1∶1 000 dilution of 20% pyraclostrobin and 2×1011 cfu/g B. subtilis DJ-6 in combina-tion were up to 100% and 93.11%, which were higher than those in al other treat-ments. The second highest control effects were found in the treatment with 1∶ 2 000 dilution of 20% pyraclostrobin and 2×1011 cfu/g B. subtilis DJ-6 in combination, they were 92.49% and 86.49%, higher than those in other treatments except the 1∶1 000 dilution of 20% pyraclostrobin and 2 ×1011 cfu/g B. subtilis DJ-6 in combination. The control effects of 1∶3 000 dilution of 20% pyraclostrobin and 2×1011 cfu/g B. subtilis DJ-6 in combination were 82.61% and 72.42%, higher than those in treatment with 1∶1 000 dilution of 1×1012 cfu/g B. subtilis DJ-6 WP, but lower than those in treat-ment with 1∶2 000 dilution of 25% pyraclostrobin EC. [Conclusion] Al the results re-vealed that the combination use of 20% pyraclostrobin and 2 ×1011 cfu/g B. subtilis DJ-6 WP at 1∶1 000 to 1∶2 000 dilution had better control effect against strawberry Fusarium wilt.
文摘ZnO nanosheets with thickness of a few nanometers are prepared by vapor transport and condensation method, and their structure and optical properties are well characterized. Field effect transistor （FET） and ultraviolet （UV） sensors are fabricated based on the ZnO nanosheets. Due to the peculiar structure of nanosheet, the FET shows n-type enhanced mode behavior and high electrical performance, and its field-effect mobility and on/off cur- rent ratio can reach 256 cm2/（V.s） and ~10^8, respectively. Moreover, the response of UV sensors can also be remarkably improved to ~3 × 10^8. The results make the ZnO nanosheets be a good material for the applications in nanoelectronic and optoelectronic devices.
文摘A mechanism of oxygen transportation in Czochralski growth of silicon crystals under a horizontal magnetic field (HMCZ) is proposed. Oxygen depleted surface melt, driven to the growth interface by the thermal Marangoni flow, determines oxygen concentration in the grown crystals. Systematic study was carried out to investigate effects of growth parameters on oxygen incorporation into crystals.
