Fiber-shaped energy storage devices(FSESDs)with exceptional flexibility for wearable power sources should be applied with solid electrolytes over liquid electrolytes due to short circuits and leakage issue during defo...Fiber-shaped energy storage devices(FSESDs)with exceptional flexibility for wearable power sources should be applied with solid electrolytes over liquid electrolytes due to short circuits and leakage issue during deformation.Among the solid options,polymer electrolytes are particularly preferred due to their robustness and flexibility,although their low ionic conductivity remains a significant challenge.Here,we present a redox polymer electrolyte(HT_RPE)with 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl(HT)as a multi-functional additive.HT acts as a plasticizer that transforms the glassy state into the rubbery state for improved chain mobility and provides distinctive ion conduction pathway by the self-exchange reaction between radical and oxidized species.These synergetic effects lead to high ionic conductivity(73.5 mS cm−1)based on a lower activation energy of 0.13 eV than other redox additives.Moreover,HT_RPE with a pseudocapacitive characteristic by HT enables an outstanding electrochemical performance of the symmetric FSESDs using carbon-based fiber electrodes(energy density of 25.4 W h kg^(−1) at a power density of 25,000 W kg^(−1))without typical active materials,along with excellent stability(capacitance retention of 91.2%after 8,000 bending cycles).This work highlights a versatile HT_RPE that utilizes the unique functionality of HT for both the high ionic conductivity and improved energy storage capability,providing a promising pathway for next-generation flexible energy storage devices.展开更多
Rapid development of portable or wearable devices, which is inspired by requirements of instant messaging,health monitoring and handling official business, urgently demands more tiny, flexible and light power sources....Rapid development of portable or wearable devices, which is inspired by requirements of instant messaging,health monitoring and handling official business, urgently demands more tiny, flexible and light power sources. Fibershaped batteries explored in recent years become a prospective candidate to satisfy these demands. With 1D architecture,the fiber-shaped batteries could be adapted to various deformations and integrated into soft textile and other devices.Numerous researches have been reported and achieved huge promotion. To give an overview of fiber-shaped batteries,we summarized the development of fiber-shaped batteries in this review, and discussed the structure and materials in fiber-shaped batteries. The flexibility of batteries with the potential application of the batteries was also exhibited and showed the future perspective. Finally, challenges in this field were discussed, hoping to reveal research direction towards further development of fiber-shaped batteries.展开更多
Fiber-shaped supercapacitors(FSSCs)show great potential in portable and wearable electronics due to their unique advantages of high safety,environmental friendliness,high performances,outstanding flexibility and integ...Fiber-shaped supercapacitors(FSSCs)show great potential in portable and wearable electronics due to their unique advantages of high safety,environmental friendliness,high performances,outstanding flexibility and integrability.They can directly act as the power sources or be easily integrated with other flexible devices to constitute self-powered and sustainable energy suppliers,providing excellent adaptability to irregular surfaces.This review mainly summarizes the recently reported works of FSSCs including preparation methods of various fiber electrodes,construction strategies of FSSCs and multi-functional device integrations,exploration of reaction mechanisms and strategies to improve the electrochemical performance and provision of suggestions on further designing and optimization of FSSCs.Meanwhile,it shares our perspectives on challenges and opportunities in this field,shedding light on the development of high-performance fiber-shaped supercapacitors with multifunctions.展开更多
Vitrimers have emerged as a prominent research area in the field of polymer materials.Most of the studies have focused on synthesizing polymers with versatile dynamic crosslinking structures,while the impact of chemic...Vitrimers have emerged as a prominent research area in the field of polymer materials.Most of the studies have focused on synthesizing polymers with versatile dynamic crosslinking structures,while the impact of chemical structure on aggregate structure of vitrimers,particularly during polymer processing,remains insufficiently investigated.The present study employed commercial maleic anhydride-grafted-high density polyethylene(M-g-HDPE)as the matrix and hexanediol as the crosslinker to facilely obtain fiber-shaped HDPE vitrimers through a reaction extrusion and post-drawing process.Through chemical structure characterization,morphology observation,thermal and mechanical properties investigation,as well as aggregate structure analysis,this work revealed the influence of dynamic bonds on the formation of aggregate structures during fiber-shaped vitrimers processing.A small amount of dynamic bonds in HDPE restricts the motion of PE chain during melt-extruding and post-drawing,resulting in a lower orientation of the PE chains.However,lamellar growth and fibril formation during post-drawing at high temperature are enhanced to some extent due to the competition between dynamic bond and chain relaxation.The uneven morphology of fibershaped HDPE vitrimers can be attributed to the stronger elastic effect brought by dynamic bonding,which plays a more dominant role in determining the mechanical properties of fiber-shaped vitrimers compared to aggregate structure.Abstract Vitrimers have emerged as a prominent research area in the field of polymer materials.Most of the studies have focused on synthesizing polymers with versatile dynamic crosslinking structures,while the impact of chemical structure on aggregate structure of vitrimers,particularly during polymer processing,remains insufficiently investigated.The present study employed commercial maleic anhydride-grafted-high density polyethylene(M-g-HDPE)as the matrix and hexanediol as the crosslinker to facilely obtain fiber-shaped HDPE vitrimers through a reaction extrusion and post-drawing process.Through chemical structure characterization,morphology observation,thermal and mechanical properties investigation,as well as aggregate structure analysis,this work revealed the influence of dynamic bonds on the formation of aggregate structures during fiber-shaped vitrimers processing.A small amount of dynamic bonds in HDPE restricts the motion of PE chain during melt-extruding and post-drawing,resulting in a lower orientation of the PE chains.However,lamellar growth and fibril formation during post-drawing at high temperature are enhanced to some extent due to the competition between dynamic bond and chain relaxation.The uneven morphology of fibershaped HDPE vitrimers can be attributed to the stronger elastic effect brought by dynamic bonding,which plays a more dominant role in determining the mechanical properties of fiber-shaped vitrimers compared to aggregate structure.展开更多
Fiber-shaped batteries,distinguished by their unique one-dimensional archi-tecture,offer ultra-high flexibility,remarkable stretchability,and excellent knittability,rendering them highly appealing as energy storage so...Fiber-shaped batteries,distinguished by their unique one-dimensional archi-tecture,offer ultra-high flexibility,remarkable stretchability,and excellent knittability,rendering them highly appealing as energy storage solutions for smart wearable fabrics.Among various fiber-shaped battery systems,aqueous zinc batteries stand out as one of the most promising candidates owing to their high specific capacity,inherent safety,and cost-effectiveness.However,the practical applicability of fiber-shaped zinc batteries(FZBs)is significantly hin-dered by challenges in scalable production,long-term operational stability,and seamless integration.Despite the growing interest in FZBs,a comprehen-sive and systematic review that critically examines the essential components,assembly configurations,manufacturing techniques,and performance-enhancing strategies is still lacking.This review aims to fill this gap by first summarizing the fundamental components of FZBs,including cathodes,anodes,electrolytes,current collectors,and encapsulation materials.It then compares the impact of various assembly configurations,including parallel,winding,coaxial,and weaving structures,on battery performance.Further-more,it provides an in-depth analysis of diverse manufacturing techniques for fiber electrodes,including dip-coating,hydrothermal synthesis,and electrode-position,as well as the assembly procedures ranging from manual to equipment-assisted and one-step assembly methods.In addition,this review highlights strategies for improving both electrochemical and wearable perfor-mance through material modification and structural design.It also under-scores the multifunctional applications of FZBs,such as thermosensitive,fluorescent,and sweat-driven variants,along with their potential in physiologi-cal sensing and environmental monitoring.Finally,it identifies the existing barriers to FZBs commercialization,including limited energy density,complex integration processes,and unclear internal mechanisms.Based on these insights,it proposes future research directions and development initiatives to advance the field of FZBs,thereby promoting their transition from laboratory prototypes to commercial products.展开更多
The rapid evolution of flexible wearable electronics has spurred a growing demand for energy storage devices,characterized by low-cost manufacturing processes,high safety standards,exceptional electrochemical performa...The rapid evolution of flexible wearable electronics has spurred a growing demand for energy storage devices,characterized by low-cost manufacturing processes,high safety standards,exceptional electrochemical performance and robust mechanical properties.Among novel flexible devices,fiber-shaped batteries(FSBs)have emerged as prominent solutions exceptionally suited to future applications,owing to their unique one-dimensional(1D)architecture,remarkable flexibility,potential for miniaturization,adaptability to deformation and compatibility with the conventional textile industry.In the forefront research on fiber-shaped batteries,zincbased FSBs(ZFSBs)have garnered significant attentions,featured by the promising electrochemical properties of metallic Zn.This enthusiasm is driven by the impressive capacity of Zn(820 mAh·g^(-1))and its low redox potential(Zn/Zn^(2+):-0.76 V vs.standard hydrogen electrode).This review aims to consolidate recent achievements in the structural design,fabrication processes and electrode materials of flexible ZFSBs.Notably,we highlight three representative structural configurations:parallel type,twisted type and coaxial type.We also place special emphasis on electrode modifications and electrolyte selection.Furthermore,we delve into the promising development opportunities and anticipate future challenges associated with ZFSBs,emphasizing their potential roles in powering the next generation of wearable electronics.展开更多
To meet the demand for energy storage devices with high safety,excellent flexibility,and environmental compatibility in wearable electronic devices,fiber-shaped aqueous batteries(FABs)have become a key research direct...To meet the demand for energy storage devices with high safety,excellent flexibility,and environmental compatibility in wearable electronic devices,fiber-shaped aqueous batteries(FABs)have become a key research direction in the field of flexible energy storage.This paper systematically reviews the latest research progress of FABs.Firstly,it elaborates on their core working mechanisms,including the intercalation mechanism involving reversible insertion/extraction of charge carriers,the conversion mechanism characterized by changes in the oxidation state and phase of electrode materials and the deposition/dissolution mechanism of metal ions.Subsequently,it summarizes the design principles from three dimensions:electrode fabrication(surface coating,in-situ growth,thermal drawing,solution spinning),device architectures(parallel,twisted,coaxial,crossing),and performance evaluation metrics(energy density,specific capacity,long-term cycling stability,flexibility).Additionally,the paper combs the research breakthroughs of FABs based on Li^(+)/Na^(+),multivalent ions(Zn^(2+)/Mg^(2+)/Ca^(2+)/Al^(3+)),NH_(4)^(+),and alkaline systems,and introduces their applications in energy storage-photoelectric response integration,energy storage-sensing integration,and multi-device power supply.Finally,it points out the challenges,such as low utilization efficiency of electrode materials and poor interface stability,and looks forward to the development directions including intelligent materials,manufacturing technologies,and standardization construction,which provides references for the industrialization of FABs and the development of next-generation flexible energy storage technologies.展开更多
The rapid advancement of wearable electronics has driven significant interest in the development of wearable energy storage technologies.Among them,aqueous zinc ion batteries(ZIBs)have gained considerable attention as...The rapid advancement of wearable electronics has driven significant interest in the development of wearable energy storage technologies.Among them,aqueous zinc ion batteries(ZIBs)have gained considerable attention as promising candidates for portable and wearable applications.In particular,aqueous fiber-shaped ZIBs offer distinctive advantages,such as miniaturization,flexibility,and wearability,making them especially suitable for powering next-generation wearable devices.This review provides a comprehensive overview of the recent advances in aqueous fiber-shaped ZIBs,focusing on the fabrication of fiber-based electrodes and various battery configurations.In addition,we highlight the evolution of fiber-shaped ZIBs from single-function to multi-function systems,exploring their potential for diverse applications.The review also addresses the key challenges in this field and discusses future research directions to drive the further development of aqueous fiber-shaped ZIBs.展开更多
As a promising candidate for future demand, fiber-shaped electrochemical energy storage devices, such as supercapacitors and lithium-ion batteries have obtained considerable attention from academy to industry. Carbon ...As a promising candidate for future demand, fiber-shaped electrochemical energy storage devices, such as supercapacitors and lithium-ion batteries have obtained considerable attention from academy to industry. Carbon nanomaterials, such as carbon nanotube and graphene, have been widely investigated as electrode materials due to their merits of light weight, flexibility and high capacitance. In this review, recent progress of carbon nanomaterials in flexible fiber-shaped energy storage devices has been summarized in accordance with the development of fibrous electrodes, including the diversified electrode preparation, functional and intelligent device structure, and large-scale production of fibrous electrodes or devices.展开更多
Graphene fiber supercapacitors(GFSCs)have garnered significant attention due to their exceptional features,including high power density,rapid charge/discharge rates,prolonged cycling durability,and versatile weaving c...Graphene fiber supercapacitors(GFSCs)have garnered significant attention due to their exceptional features,including high power density,rapid charge/discharge rates,prolonged cycling durability,and versatile weaving capabilities.Nevertheless,inherent challenges in graphene fibers(GFs),particularly the restricted ion-accessible specific surface area(SSA)and sluggish ion transport kinetics,hinder the achievement of optimal capacitance and rate performance.Despite existing reviews on GFSCs,a notable gap exists in thoroughly exploring the kinetics governing the energy storage process in GFSCs.This review aims to address this gap by thoroughly analyzing the energy storage mechanism,fabrication methodologies,property manipulation,and wearable applications of GFSCs.Through theoretical analysis of the energy storage process,specific parameters in advanced GF fabrication methodologies are carefully summarized,which can be used to modulate nano/micro-structures,thereby enhancing energy storage kinetics.In particular,enhanced ion storage is realized by creating more ion-accessible SSA and introducing extra-capacitive components,while accelerated ion transport is achieved by shortening the transport channel length and improving the accessibility of electrolyte ions.Building on the established structure-property relationship,several critical strategies for constructing optimal surface and structure profiles of GF electrodes are summarized.Capitalizing on the exceptional flexibility and wearability of GFSCs,the review further underscores their potential as foundational elements for constructing multifunctional e-textiles using conventional textile technologies.In conclusion,this review provides insights into current challenges and suggests potential research directions for GFSCs.展开更多
基金supported by Korea Institute of Science and Technology(KIST)Institutional Program and Open Research Program(ORP)This work was also supported by grant from the National Research Foundation(NRF)of Korea government(RS-2024-00433159 and RS-2023-00208313)from ITECH R&D program of MOTIE/KEIT(RS-2023-00257573).
文摘Fiber-shaped energy storage devices(FSESDs)with exceptional flexibility for wearable power sources should be applied with solid electrolytes over liquid electrolytes due to short circuits and leakage issue during deformation.Among the solid options,polymer electrolytes are particularly preferred due to their robustness and flexibility,although their low ionic conductivity remains a significant challenge.Here,we present a redox polymer electrolyte(HT_RPE)with 4-hydroxy-2,2,6,6-tetramethylpiperidine-1-oxyl(HT)as a multi-functional additive.HT acts as a plasticizer that transforms the glassy state into the rubbery state for improved chain mobility and provides distinctive ion conduction pathway by the self-exchange reaction between radical and oxidized species.These synergetic effects lead to high ionic conductivity(73.5 mS cm−1)based on a lower activation energy of 0.13 eV than other redox additives.Moreover,HT_RPE with a pseudocapacitive characteristic by HT enables an outstanding electrochemical performance of the symmetric FSESDs using carbon-based fiber electrodes(energy density of 25.4 W h kg^(−1) at a power density of 25,000 W kg^(−1))without typical active materials,along with excellent stability(capacitance retention of 91.2%after 8,000 bending cycles).This work highlights a versatile HT_RPE that utilizes the unique functionality of HT for both the high ionic conductivity and improved energy storage capability,providing a promising pathway for next-generation flexible energy storage devices.
基金Project(2016YFB0901503) supported by National Key Research and Development Program of ChinaProjects(22075320,21875284) supported by the National Natureal Science Foundation of China。
文摘Rapid development of portable or wearable devices, which is inspired by requirements of instant messaging,health monitoring and handling official business, urgently demands more tiny, flexible and light power sources. Fibershaped batteries explored in recent years become a prospective candidate to satisfy these demands. With 1D architecture,the fiber-shaped batteries could be adapted to various deformations and integrated into soft textile and other devices.Numerous researches have been reported and achieved huge promotion. To give an overview of fiber-shaped batteries,we summarized the development of fiber-shaped batteries in this review, and discussed the structure and materials in fiber-shaped batteries. The flexibility of batteries with the potential application of the batteries was also exhibited and showed the future perspective. Finally, challenges in this field were discussed, hoping to reveal research direction towards further development of fiber-shaped batteries.
基金upported by the National Natural Science Foundation of China(No.21875226)the Science Fund for Distinguished Young Scholars of Sichuan Province(No.2017JQ0036)the Chengdu Rongpiao Talent plan,the Sichuan'Ten-thousand Talents Program",the"QianYingBaiTuan"Plan of China Mianyang Science City,the Science Foundation of Institute of Chemical Materials(No.O11100301)the"Global Experts Recruitment"program.
文摘Fiber-shaped supercapacitors(FSSCs)show great potential in portable and wearable electronics due to their unique advantages of high safety,environmental friendliness,high performances,outstanding flexibility and integrability.They can directly act as the power sources or be easily integrated with other flexible devices to constitute self-powered and sustainable energy suppliers,providing excellent adaptability to irregular surfaces.This review mainly summarizes the recently reported works of FSSCs including preparation methods of various fiber electrodes,construction strategies of FSSCs and multi-functional device integrations,exploration of reaction mechanisms and strategies to improve the electrochemical performance and provision of suggestions on further designing and optimization of FSSCs.Meanwhile,it shares our perspectives on challenges and opportunities in this field,shedding light on the development of high-performance fiber-shaped supercapacitors with multifunctions.
基金financially supported by the National Natural Science Foundation of China(Nos.22278065 and 22073015)。
文摘Vitrimers have emerged as a prominent research area in the field of polymer materials.Most of the studies have focused on synthesizing polymers with versatile dynamic crosslinking structures,while the impact of chemical structure on aggregate structure of vitrimers,particularly during polymer processing,remains insufficiently investigated.The present study employed commercial maleic anhydride-grafted-high density polyethylene(M-g-HDPE)as the matrix and hexanediol as the crosslinker to facilely obtain fiber-shaped HDPE vitrimers through a reaction extrusion and post-drawing process.Through chemical structure characterization,morphology observation,thermal and mechanical properties investigation,as well as aggregate structure analysis,this work revealed the influence of dynamic bonds on the formation of aggregate structures during fiber-shaped vitrimers processing.A small amount of dynamic bonds in HDPE restricts the motion of PE chain during melt-extruding and post-drawing,resulting in a lower orientation of the PE chains.However,lamellar growth and fibril formation during post-drawing at high temperature are enhanced to some extent due to the competition between dynamic bond and chain relaxation.The uneven morphology of fibershaped HDPE vitrimers can be attributed to the stronger elastic effect brought by dynamic bonding,which plays a more dominant role in determining the mechanical properties of fiber-shaped vitrimers compared to aggregate structure.Abstract Vitrimers have emerged as a prominent research area in the field of polymer materials.Most of the studies have focused on synthesizing polymers with versatile dynamic crosslinking structures,while the impact of chemical structure on aggregate structure of vitrimers,particularly during polymer processing,remains insufficiently investigated.The present study employed commercial maleic anhydride-grafted-high density polyethylene(M-g-HDPE)as the matrix and hexanediol as the crosslinker to facilely obtain fiber-shaped HDPE vitrimers through a reaction extrusion and post-drawing process.Through chemical structure characterization,morphology observation,thermal and mechanical properties investigation,as well as aggregate structure analysis,this work revealed the influence of dynamic bonds on the formation of aggregate structures during fiber-shaped vitrimers processing.A small amount of dynamic bonds in HDPE restricts the motion of PE chain during melt-extruding and post-drawing,resulting in a lower orientation of the PE chains.However,lamellar growth and fibril formation during post-drawing at high temperature are enhanced to some extent due to the competition between dynamic bond and chain relaxation.The uneven morphology of fibershaped HDPE vitrimers can be attributed to the stronger elastic effect brought by dynamic bonding,which plays a more dominant role in determining the mechanical properties of fiber-shaped vitrimers compared to aggregate structure.
基金National Natural Science Foundation of China,Grant/Award Number:51702362Hunan Provincial Natural Science Foundation,Grant/Award Numbers:2022JJ30663,2022JJ40551Independent Science Foundation of National University of Defense Technology。
文摘Fiber-shaped batteries,distinguished by their unique one-dimensional archi-tecture,offer ultra-high flexibility,remarkable stretchability,and excellent knittability,rendering them highly appealing as energy storage solutions for smart wearable fabrics.Among various fiber-shaped battery systems,aqueous zinc batteries stand out as one of the most promising candidates owing to their high specific capacity,inherent safety,and cost-effectiveness.However,the practical applicability of fiber-shaped zinc batteries(FZBs)is significantly hin-dered by challenges in scalable production,long-term operational stability,and seamless integration.Despite the growing interest in FZBs,a comprehen-sive and systematic review that critically examines the essential components,assembly configurations,manufacturing techniques,and performance-enhancing strategies is still lacking.This review aims to fill this gap by first summarizing the fundamental components of FZBs,including cathodes,anodes,electrolytes,current collectors,and encapsulation materials.It then compares the impact of various assembly configurations,including parallel,winding,coaxial,and weaving structures,on battery performance.Further-more,it provides an in-depth analysis of diverse manufacturing techniques for fiber electrodes,including dip-coating,hydrothermal synthesis,and electrode-position,as well as the assembly procedures ranging from manual to equipment-assisted and one-step assembly methods.In addition,this review highlights strategies for improving both electrochemical and wearable perfor-mance through material modification and structural design.It also under-scores the multifunctional applications of FZBs,such as thermosensitive,fluorescent,and sweat-driven variants,along with their potential in physiologi-cal sensing and environmental monitoring.Finally,it identifies the existing barriers to FZBs commercialization,including limited energy density,complex integration processes,and unclear internal mechanisms.Based on these insights,it proposes future research directions and development initiatives to advance the field of FZBs,thereby promoting their transition from laboratory prototypes to commercial products.
基金supported by the National Natural Science Foundation of China(Nos.52201222 and 62174085)Jiangsu Specially-Appointed Professors Program,and the Natural Science Foundation of Jiangsu Higher Education Institutions(No.22KJB430008).
文摘The rapid evolution of flexible wearable electronics has spurred a growing demand for energy storage devices,characterized by low-cost manufacturing processes,high safety standards,exceptional electrochemical performance and robust mechanical properties.Among novel flexible devices,fiber-shaped batteries(FSBs)have emerged as prominent solutions exceptionally suited to future applications,owing to their unique one-dimensional(1D)architecture,remarkable flexibility,potential for miniaturization,adaptability to deformation and compatibility with the conventional textile industry.In the forefront research on fiber-shaped batteries,zincbased FSBs(ZFSBs)have garnered significant attentions,featured by the promising electrochemical properties of metallic Zn.This enthusiasm is driven by the impressive capacity of Zn(820 mAh·g^(-1))and its low redox potential(Zn/Zn^(2+):-0.76 V vs.standard hydrogen electrode).This review aims to consolidate recent achievements in the structural design,fabrication processes and electrode materials of flexible ZFSBs.Notably,we highlight three representative structural configurations:parallel type,twisted type and coaxial type.We also place special emphasis on electrode modifications and electrolyte selection.Furthermore,we delve into the promising development opportunities and anticipate future challenges associated with ZFSBs,emphasizing their potential roles in powering the next generation of wearable electronics.
基金supported by the National Natural Science Foundation of China(52473270,T2422028)the National Key R&D Program of China(2022YFA1203304)+3 种基金the Suzhou Institute of Nano-Tech and Nano-BionicsChinese Academy of Sciences(start-up grant,E1552102)the China Postdoctoral Science Foundation(2024M764385,GZC20250555,GZC20250062)the Jiangsu Funding Program for Excellent Postdoctoral Talent(2025ZB291)。
文摘To meet the demand for energy storage devices with high safety,excellent flexibility,and environmental compatibility in wearable electronic devices,fiber-shaped aqueous batteries(FABs)have become a key research direction in the field of flexible energy storage.This paper systematically reviews the latest research progress of FABs.Firstly,it elaborates on their core working mechanisms,including the intercalation mechanism involving reversible insertion/extraction of charge carriers,the conversion mechanism characterized by changes in the oxidation state and phase of electrode materials and the deposition/dissolution mechanism of metal ions.Subsequently,it summarizes the design principles from three dimensions:electrode fabrication(surface coating,in-situ growth,thermal drawing,solution spinning),device architectures(parallel,twisted,coaxial,crossing),and performance evaluation metrics(energy density,specific capacity,long-term cycling stability,flexibility).Additionally,the paper combs the research breakthroughs of FABs based on Li^(+)/Na^(+),multivalent ions(Zn^(2+)/Mg^(2+)/Ca^(2+)/Al^(3+)),NH_(4)^(+),and alkaline systems,and introduces their applications in energy storage-photoelectric response integration,energy storage-sensing integration,and multi-device power supply.Finally,it points out the challenges,such as low utilization efficiency of electrode materials and poor interface stability,and looks forward to the development directions including intelligent materials,manufacturing technologies,and standardization construction,which provides references for the industrialization of FABs and the development of next-generation flexible energy storage technologies.
基金Research Fund for International Scientists(52350710795)National Natural Science Foundation of China and the Shanghai Pujiang Program(24PJA090).
文摘The rapid advancement of wearable electronics has driven significant interest in the development of wearable energy storage technologies.Among them,aqueous zinc ion batteries(ZIBs)have gained considerable attention as promising candidates for portable and wearable applications.In particular,aqueous fiber-shaped ZIBs offer distinctive advantages,such as miniaturization,flexibility,and wearability,making them especially suitable for powering next-generation wearable devices.This review provides a comprehensive overview of the recent advances in aqueous fiber-shaped ZIBs,focusing on the fabrication of fiber-based electrodes and various battery configurations.In addition,we highlight the evolution of fiber-shaped ZIBs from single-function to multi-function systems,exploring their potential for diverse applications.The review also addresses the key challenges in this field and discusses future research directions to drive the further development of aqueous fiber-shaped ZIBs.
基金supported by the National Natural Science Foundation of China(Nos.21634003,21604012)
文摘As a promising candidate for future demand, fiber-shaped electrochemical energy storage devices, such as supercapacitors and lithium-ion batteries have obtained considerable attention from academy to industry. Carbon nanomaterials, such as carbon nanotube and graphene, have been widely investigated as electrode materials due to their merits of light weight, flexibility and high capacitance. In this review, recent progress of carbon nanomaterials in flexible fiber-shaped energy storage devices has been summarized in accordance with the development of fibrous electrodes, including the diversified electrode preparation, functional and intelligent device structure, and large-scale production of fibrous electrodes or devices.
基金Shanghai Municipal Commission for Science and Technology,Grant/Award Number:23ZR1402500National Natural Science Foundation of China,Grant/Award Number:51973034+1 种基金National Scholarship CouncilNational Key Research and Development Program of China,Grant/Award Number:2023YFB3809800.
文摘Graphene fiber supercapacitors(GFSCs)have garnered significant attention due to their exceptional features,including high power density,rapid charge/discharge rates,prolonged cycling durability,and versatile weaving capabilities.Nevertheless,inherent challenges in graphene fibers(GFs),particularly the restricted ion-accessible specific surface area(SSA)and sluggish ion transport kinetics,hinder the achievement of optimal capacitance and rate performance.Despite existing reviews on GFSCs,a notable gap exists in thoroughly exploring the kinetics governing the energy storage process in GFSCs.This review aims to address this gap by thoroughly analyzing the energy storage mechanism,fabrication methodologies,property manipulation,and wearable applications of GFSCs.Through theoretical analysis of the energy storage process,specific parameters in advanced GF fabrication methodologies are carefully summarized,which can be used to modulate nano/micro-structures,thereby enhancing energy storage kinetics.In particular,enhanced ion storage is realized by creating more ion-accessible SSA and introducing extra-capacitive components,while accelerated ion transport is achieved by shortening the transport channel length and improving the accessibility of electrolyte ions.Building on the established structure-property relationship,several critical strategies for constructing optimal surface and structure profiles of GF electrodes are summarized.Capitalizing on the exceptional flexibility and wearability of GFSCs,the review further underscores their potential as foundational elements for constructing multifunctional e-textiles using conventional textile technologies.In conclusion,this review provides insights into current challenges and suggests potential research directions for GFSCs.
