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Influencing factors and thermodynamic-kinetic mechanism of feldspar dissolution in deep-buried sandstone in Bozhong Depression
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作者 Haiqiang Bai Xin Li +2 位作者 Xiaojun Xie Ziyu Liu Lianqiao Xiong 《Acta Oceanologica Sinica》 2025年第10期112-129,共18页
The deep layer has become an important replacement field for oil and gas exploration,but the formation mechanism of effective reservoirs is unknown,and the distribution of dessert reservoirs is difficult to predict,wh... The deep layer has become an important replacement field for oil and gas exploration,but the formation mechanism of effective reservoirs is unknown,and the distribution of dessert reservoirs is difficult to predict,which seriously affects the discovery of deep resources.In this paper,the reservoir of the first and second members of the Shahejie Formation in the Caofeidian 6-4S area of the Bozhong Depression is taken as an example.Through the comprehensive means such as well-seismic calibration,denudation recovery,source-sink quantitative coupling,basin simulation,microscopic observation,X-ray diffraction,inclusion and thermodynamic analysis,the reservoir formation mechanism of dissolution pores and the favorable area distribution of thermodynamic prediction of dissolution reaction in the study area are carried out.The results show that the dissolution pores are the dominant type,accounting for more than 80%of the total pores.The dissolution reaction between soluble minerals such as feldspar accumulated in the near source and acidic fluids such as organic acids formed in the adjacent strata is the main mechanism for the development of dissolution pores.The organic matter in the adjacent strata is controlled by temperature and pressure during the burial evolution process to form organic acids,and migrates to the adjacent reservoirs for selective dissolution under the action of pressure and other driving forces.The characteristics of thermodynamic parameters(ΔG,which can determine whether feldspar is dissolved)and kinetic parameters(R,indicating the degree of feldspar dissolution)of feldspar dissolution reaction show that the thermodynamic parameters of feldspar dissolution are positively correlated with temperature,and the kinetic parameters are correlated with the concentration of organic acid discharge.The results of thermodynamic and kinetic parameters are coupled with provenance-sedimentary facies-diagenetic facies,and it is predicted that the plane area of TypeⅠfavorable area is 50 km^(2),and the plane area of TypeⅡfavorable area is 62.4 km2.This method provides theoretical reference and method guidance for the prediction of favorable reservoir distribution of deep clastic rocks,and has a good application prospect. 展开更多
关键词 feldspar dissolution thermo-dynamics kinetics reservoir acidic fluid Bozhong Depression
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Characteristics and control factors of feldspar dissolution in gravity flow sandstone of Chang 7 Member,Triassic Yanchang Formation,Ordos Basin,NW China 被引量:2
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作者 ZHU Haihua ZHANG Qiuxia +4 位作者 DONG Guodong SHANG Fei ZHANG Fuyuan ZHAO Xiaoming ZHANG Xi 《Petroleum Exploration and Development》 SCIE 2024年第1期114-126,共13页
To clarify the formation and distribution of feldspar dissolution pores and predict the distribution of high-quality reservoir in gravity flow sandstone of the 7^(th) member of Triassic Yanchang Formation(Chang 7 Memb... To clarify the formation and distribution of feldspar dissolution pores and predict the distribution of high-quality reservoir in gravity flow sandstone of the 7^(th) member of Triassic Yanchang Formation(Chang 7 Member)in the Ordos Basin,thin sections,scanning electron microscopy,energy spectrum analysis,X-ray diffraction whole rock analysis,and dissolution experiments are employed in this study to investigate the characteristics and control factors of feldspar dissolution pores.The results show that:(1)Three types of diagenetic processes are observed in the feldspar of Chang 7 sandstone in the study area:secondary overgrowth of feldspar,replacement by clay and calcite,and dissolution of detrital feldspar.(2)The feldspar dissolution of Chang 7 tight sandstone is caused by organic acid,and is further affected by the type of feldspar,the degree of early feldspar alteration,and the buffering effect of mica debris on organic acid.(3)Feldspars have varying degrees of dissolution.Potassium feldspar is more susceptible to dissolution than plagioclase.Among potassium feldspar,orthoclase is more soluble than microcline,and unaltered feldspar is more soluble than early kaolinized or sericitized feldspar.(4)The dissolution experiment demonstrated that the presence of mica can hinder the dissolution of feldspar.Mica of the same mass has a significantly stronger capacity to consume organic acids than feldspar.(5)Dissolution pores in feldspar of Chang 7 Member are more abundant in areas with low mica content,and they improve the reservoir physical properties,while in areas with high mica content,the number of feldspar dissolution pores decreases significantly. 展开更多
关键词 gravity flow sandstone differential feldspar dissolution mica-feldspar dissolution experiment Chang 7 Member of Triassic Yanchang Formation Ordos Basin
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Successive formation of secondary pores via feldspar dissolution in deeply buried feldspar-rich clastic reservoirs in typical petroliferous basins and its petroleum geological significance 被引量:6
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作者 Yingchang CAO Guanghui YUAN +6 位作者 Yanzhong WANG Nianmin ZAN Zihao JIN Keyu LIU Kelai XI Yihan WEI Peipei SUN 《Science China Earth Sciences》 SCIE EI CAS CSCD 2022年第9期1673-1703,共31页
Clastic rock reservoirs in petroliferous basins are generally rich in feldspars. Feldspar dissolution has developed widely in clastic reservoirs, and the resulting secondary pores are crucial in deeply buried reservoi... Clastic rock reservoirs in petroliferous basins are generally rich in feldspars. Feldspar dissolution has developed widely in clastic reservoirs, and the resulting secondary pores are crucial in deeply buried reservoirs. Based on a study of the diagenesis of clastic reservoirs in the Bohai Bay Basin, Tarim Basin, and Pearl River Mouth Basin and physical and numerical simulation experiments of fluid-rock interactions, this paper proposed a successive formation model of secondary pores via feldspar dissolution in deeply buried clastic reservoirs, considering the global research progresses in feldspar dissolution in clastic rocks. Feldspar dissolution can occur from shallow open systems to deep-ultra deep closed systems in petroliferous basins, resulting in the successive formation of secondary pores at different diagenetic stages. The successive mechanism includes three aspects. The first aspect is the succession of corrosive fluids that dissolve minerals. Meteoric freshwater dominates at the Earth’s surface and the early diagenetic A stage. Subsequently, organic acids and COformed via kerogen maturation dominate at the early diagenetic B stage to the middle diagenetic stage. COand organic acids formed via hydrocarbon oxidation in hydrocarbon reservoirs dominate at the middle diagenetic B stage to the late diagenetic stage. The second aspect is the successive formation processes of secondary pores via feldspar dissolution. Large-scale feldspar secondary pores identified in deep reservoirs include secondary pores formed at shallow-medium depths that are subsequently preserved into deep layers, as well as secondary pores formed at deep depths. Existing secondary pores in deeply buried reservoirs are the superposition of successively feldspar dissolution caused by different acids at different stages. The third aspect is a successive change in the feldspar alteration pathways and porosity enhancement/preservation effect. Open to semi-open diagenetic systems are developed from the Earth’s surface to the early diagenetic stage, and feldspar dissolution forms enhanced secondary pores. Nearly closed to closed diagenetic systems develop in the middle to late diagenetic stages, and feldspar dissolution forms redistributional secondary pores. The associated cementation causes compression resistance of the rock, which is favorable for the preservation of secondary pores in deep layers. These new insights extend the formation window of secondary pores in petroliferous basins from the traditional acid-oil generation window to a high-temperature gas generation window after hydrocarbon charging. The proposed model explains the genesis of deep-ultra deep high-quality reservoirs with low-permeability, medium-porosity and dominating feldspar secondary pores, which is significant for hydrocarbon exploration in deep to ultra-deep layers. 展开更多
关键词 Petroliferous basin Deep to ultra-deep layers Clastic reservoirs Acid generation via thermal evolution feldspar dissolution Successive formation of secondary pores
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