The CdS/Bi_(2)S_(3) supported three-dimensional(3D)porous faveolate carbon structure(CdS/Bi_(2)S_(3)@C)composite photocatalyst was constructed.Bi_(2)S_(3) nanoparticles are regarded as photothermal agents and pyroelec...The CdS/Bi_(2)S_(3) supported three-dimensional(3D)porous faveolate carbon structure(CdS/Bi_(2)S_(3)@C)composite photocatalyst was constructed.Bi_(2)S_(3) nanoparticles are regarded as photothermal agents and pyroelectric materials to absorb near infrared light(NIR)and convert it into heat.3D porous faveolate of carbon acts as incubator to reduce heat loss and optimize photothermal effects.There is a greater fluctuating temperature difference(ΔΤ)between photothermal effect of Bi_(2)S_(3) and cold photocatalytic system.This enhances the pyroelectric effect that Bi_(2)S_(3) undergoes spontaneous polarization and releases the surface charge.Therefore,the separation of electrons and holes in the CdS photocatalyst can be induced.The COMSOL simulation results show that,the higher pyroelectric potential producted by largerΔΤis more favorable to the photocatalytic process.The hydrogen evolution rate of CdS/Bi_(2)S_(3)@C photocatalyst can reach 5.88 mmol·g^(-1)·h^(-1) with excellent cycle stability.展开更多
文摘The CdS/Bi_(2)S_(3) supported three-dimensional(3D)porous faveolate carbon structure(CdS/Bi_(2)S_(3)@C)composite photocatalyst was constructed.Bi_(2)S_(3) nanoparticles are regarded as photothermal agents and pyroelectric materials to absorb near infrared light(NIR)and convert it into heat.3D porous faveolate of carbon acts as incubator to reduce heat loss and optimize photothermal effects.There is a greater fluctuating temperature difference(ΔΤ)between photothermal effect of Bi_(2)S_(3) and cold photocatalytic system.This enhances the pyroelectric effect that Bi_(2)S_(3) undergoes spontaneous polarization and releases the surface charge.Therefore,the separation of electrons and holes in the CdS photocatalyst can be induced.The COMSOL simulation results show that,the higher pyroelectric potential producted by largerΔΤis more favorable to the photocatalytic process.The hydrogen evolution rate of CdS/Bi_(2)S_(3)@C photocatalyst can reach 5.88 mmol·g^(-1)·h^(-1) with excellent cycle stability.
