BACKGROUND Intracranial blister-like microaneurysms are an extremely rare disease.Rupture of intracranial aneurysms can lead to subarachnoid hemorrhage(SAH).Patients with SAH may experience severe neurological symptom...BACKGROUND Intracranial blister-like microaneurysms are an extremely rare disease.Rupture of intracranial aneurysms can lead to subarachnoid hemorrhage(SAH).Patients with SAH may experience severe neurological symptoms,including severe headache,nausea,vomiting,transient or persistent loss of consciousness,limb weakness,and blurred vision.Ruptured aneurysms should be surgically treated as soon as possible.Intravascular electrocoagulation is becoming a promising treatment method for intracranial blister-like microaneurysms.The short-term follow-up results demonstrated that this method is safe and effective.This article presents a case of endovascular electrocoagulation for the treatment of a blisterlike microaneurysm.CASE SUMMARY This article reports the case of 71-year-old female patient with an intracranial aneurysm.The patient experienced a sudden headache with vomiting for 3 hours.Brain computed tomography(CT)scan showed a subarachnoid hemorrhage.She was diagnosed with rupture of an aneurysm and subarachnoid hemorrhage.The aneurysm was located in the choroidal segment of the right internal carotid artery.The size of the aneurysm was 2.00 mm×1.80 mm×1.97 mm,and the neck of the aneurysm was less than 0.5 mm wide.We successfully treated this aneurysm with endovascular electrocoagulation,and the patient was safely returned to the ward and discharged after subsequent supportive treatment.CT angiography reexamination 3 months after surgery revealed no contrast agent extravasation in the original lesion,with a good prognosis.CONCLUSION Endovascular electrocoagulation is an effective and safe method for the treatment of intracranial blister-like microaneurysms.展开更多
The Sichuan Basin(SCB),China has a high incidence of extremely persistent heavy rainfall(EPHR)events.The EPHR events from 2009 to 2019 in the SCB were mainly concentrated over the northern and northwestern windward sl...The Sichuan Basin(SCB),China has a high incidence of extremely persistent heavy rainfall(EPHR)events.The EPHR events from 2009 to 2019 in the SCB were mainly concentrated over the northern and northwestern windward slopes and the central basin.They occurred from June to September,but especially in July,and peaked at 0300 LST.ERA5 reanalysis data and objective classification were used to investigate the synoptic patterns and their effects.There were three synoptic patterns during EPHR events,all accompanied by a Southwest Vortex.The location and intensity of the Southwest Vortex,thermal forcing of the Tibetan Plateau(TP),and low-level winds can greatly affect the intensity and spatial distribution of EPHR.When the Southwest Vortex was located in the western SCB and there were southerly low-level jets(LLJs),convergence and upslope wind would lead to EPHR over the northwestern or northern windward slopes.If there was no LLJ and the whole SCB was under the center of the Southwest Vortex,nocturnal EPHR was controlled by the internal circulation of the Southwest Vortex and the updraft generated by the thermal forcing of the TP,and the rainfall was weaker.The southeastern entrance of the SCB was a key area where the low-level wind dominated the nocturnal peak of EPHR.The nocturnal strengthened southeasterly wind in the key area is attributable to inertial oscillation,and the topographic friction plays an essential role in transporting momentum and moisture into the basin by generating easterly and northeasterly ageostrophic winds.展开更多
In extremely close-distance coal seam(ECDCS)mining,section coal pillars remain after upper coal seam(UCS)extraction.Thus,for layout and support design of lower coal seam(LCS)mining roadways,it is critical to account f...In extremely close-distance coal seam(ECDCS)mining,section coal pillars remain after upper coal seam(UCS)extraction.Thus,for layout and support design of lower coal seam(LCS)mining roadways,it is critical to account for UCS goaf deterioration and residual coal pillar(RCP)-induced stress disturbance.Taking the 6.4 m layer spacing of ECDCS mining in Nanyangpo Coal Mine as a case study,this research aimed to determine the optimal layout and surrounding rock control method for the 24202-ventilation roadway in the RCP area.First,the challenges of roadway layout and support under RCP were clarified:three layout methods face distinct RCPinduced stress disturbances and goaf-related roof damage.A finite element model was established;the second invariant of deviatoric stress(J_(2))and horizontal stress index were introduced to analyze plastic zone and stress evolution after UCS mining.Results show that J_(2)distributes symmetrically,with its peak diffusing downward and attenuating in a“/”-shaped pattern.Six schemes were simulated to compare plastic zone distributions at different positions,revealing that the optimal layout consists of a roadway alignment with the RCP center.Based on roadway layout and roof conditions,a cooperative control scheme was proposed:deep,strong anchorage with long cables across the RCP,and shallow stable support with short bolts in the ECDCS.This scheme secures roof cables anchored to the UCS RCP roof to achieve cross-seam anchorage.On-site borehole peeping and loose circle tests confirm smooth surrounding rock hole walls and limited failure range.Specifically,surrounding rock deformation and roof separation were controlled within 200 mm and 80 mm,respectively,with stable bolt/cable support resistance.These results offer an innovative solution for roadway layout design and support strategies under RCP in ECDCS,with significant engineering application value.展开更多
Extremely large-scale array(XL-array)communications can significantly improve the transmission rate,spectral efficiency,and spatial resolution,and has great potential in next-generation mobile communication networks.A...Extremely large-scale array(XL-array)communications can significantly improve the transmission rate,spectral efficiency,and spatial resolution,and has great potential in next-generation mobile communication networks.A crucial problem in XLarray communications is to determine the boundary of applicable regions of the plane wave model(PWM)and spherical wave model(SWM).In this paper,we propose new PWM/SWM demarcations for XL-arrays from the viewpoint of channel gain and rank.Four sets of results are derived for four different array setups.First,an equi-power line is derived for a point-touniform linear array(ULA)scenario,where an inflection point is found at±π6 central incident angles.Second,an equi-power surface is derived for a point-touniform planar array(UPA)scenario,and it is proved that cos2(ϕ)cos2(φ)=12 is a dividing curve,where ϕ andφdenote the elevation and azimuth angles,respectively.Third,an accurate and explicit expression of the equi-rank surface is obtained for a ULA-to-ULA scenario.Finally,an approximated expression of the equirank surface is obtained for a ULA-to-UPA scenario.With the obtained closed-form expressions,the equirank surface for any antenna structure and any angle can be well estimated.Furthermore,the effect of scatterers is also investigated,from which some insights are drawn.展开更多
This study focuses on steeply inclined and extremely thick coal seams(SIETCS)characterized by immense thickness,a steep inclination of coal seams(87°),and high horizontal stress.The geological conditions and mini...This study focuses on steeply inclined and extremely thick coal seams(SIETCS)characterized by immense thickness,a steep inclination of coal seams(87°),and high horizontal stress.The geological conditions and mining technology associated with SIETCS differ significantly from those of generally inclined coal seams,resulting in notable variations in roadway stress distributions.On SIETCS have predominantly examined the impact of rock layers flanking coal seams on rock bursts,with limited emphasis on SIETCS roadways.This study employs comprehensive methods,integrating numerical simulations,theoretical analyses,and field detections to investigate the stress distribution of SIETCS and the mechanisms of rock burst-induced vertical damage,subsequently validated in situ.The vertical stress in SIETCS is minimal,while horizontal stress is concentrated,leading to the formation of layered crack structures(LCS)that distribute above and below the roadways.Additionally,elastic energy significantly concentrates within the LCS.Axial dynamic compressive stress and vertical dynamic tensile stress along the LCS diminish its stability,readily triggering failure.During the LCS failure process,the stored energy is released,converting into kinetic energy required for coal body ejection after reaching the minimum energy for failure and dissipative energy,ultimately leading to rock burst-induced vertical damage in roadways.On-site detection and analysis within SIETCS,along with historical rock burst data,confirm the existence of LCS and its role in inducing vertical rock burst damage.This research establishes essential foundations for preventing rock bursts within SIETCS.展开更多
The implementation of the ecological protection red line serves as a crucial protective barrier for the conservation of wild plants with extremely small populations by delineating specific geographical areas designate...The implementation of the ecological protection red line serves as a crucial protective barrier for the conservation of wild plants with extremely small populations by delineating specific geographical areas designated for their conservation.The implementation of a comprehensive set of conservation measures aimed at establishing a biodiversity conservation network for wild plants with extremely small populations has laid the foundation for the health and stability of ecosystems,as well as the harmonious coexistence of humans and the natural environment.Research on the conservation of wild plants with extremely small populations serves as a critical foundation for informing and enhancing the effective conservation of such populations.This paper provides a systematic examination of the theoretical and practical conservation status of certain wild plants with extremely small populations and discusses the conservation trends of these populations within the framework of ecological protection red line delineation.In the future,strategies for the conservation of wild plants with extremely small populations should be integrated with an analysis of the causes of endangerment.This approach will provide a robust foundation for applied research focused on the conservation of these vulnerable plant populations.展开更多
Magnetoresistance(MR)is a pivotal transport phenomenon within the realm of condensed matter physics.In recent years,materials exhibiting extremely large unsaturated magnetoresistance(XMR),which are often potential top...Magnetoresistance(MR)is a pivotal transport phenomenon within the realm of condensed matter physics.In recent years,materials exhibiting extremely large unsaturated magnetoresistance(XMR),which are often potential topological materials,have garnered significant attention.In this study,we synthesized single crystals of ZrBi_(2) and performed electrical and specific heat measurements on them.The resistivity of ZrBi_(2) displays metallic behavior with a high residual resistance ratio.Notably,the MR of ZrBi_(2) reaches approximately 2.0×10^(3)%at 2 K and 16 T without saturation.Weak Shubnikov-de Haas oscillations with two frequencies were observed above 13.5 T,which correspond to 237 T and 663 T.Hall effect fitting yields nearly equal concentrations of electron and hole carriers with concentrations of approximately 10^(21)cm^(-3)and mobilities of approximately 5000 cm^(2)·V^(-1)·s^(-1)at 2 K.The XMR could be attributed to the electron-hole compensation with high mobility.展开更多
A numerical simulation was performed using the Thompson microphysics scheme to preliminarily investigate the features of the microphysical processes involved in the record-breaking rainfall event that occurred in Hena...A numerical simulation was performed using the Thompson microphysics scheme to preliminarily investigate the features of the microphysical processes involved in the record-breaking rainfall event that occurred in Henan Province,China,on 20 July 2021.The simulation results showed that a strong meso-𝛾-scale vortical updraft was concurrent with the torrential rainfall.The main finding is that this event was characterized by typical midlatitude warm-rain processes.The simulation with the Thompson microphysics scheme further indicated that highly efficient collision-coalescence of cloud water to rainwater resulted in a considerably active rain droplet growth,leading to this record-breaking rainfall event.展开更多
Blast furnace(BF)burden surface contains the most abundant,intuitive and credible smelting information and acquiring high-definition and high-brightness optical images of which is essential to realize precise material...Blast furnace(BF)burden surface contains the most abundant,intuitive and credible smelting information and acquiring high-definition and high-brightness optical images of which is essential to realize precise material charging control,optimize gas flow distribution and improve ironmaking efficiency.It has been challengeable to obtain high-quality optical burden surface images under high-temperature,high-dust,and extremelydim(less than 0.001 Lux)environment.Based on a novel endoscopic sensing detection idea,a reverse telephoto structure starlight imaging system with large field of view and large aperture is designed.Combined with a water-air dual cooling intelligent self-maintenance protection device and the imaging system,a starlight high-temperature industrial endoscope is developed to obtain clear optical burden surface images stably under the harsh environment.Based on an endoscope imaging area model,a material flow trajectory model and a gas-dust coupling distribution model,an optimal installation position and posture configuration method for the endoscope is proposed,which maximizes the effective imaging area and ensures large-area,safe and stable imaging of the device in a confined space.Industrial experiments and applications indicate that the proposed method obtains clear and reliable large-area optical burden surface images and reveals new BF conditions,providing key data support for green iron smelting.展开更多
The interface of ceramic particles and metal matrixes extremely impacts the mechanical properties of particle-reinforced metal matrix composites,especially at elevated temperatures.We provide a strategy for constructi...The interface of ceramic particles and metal matrixes extremely impacts the mechanical properties of particle-reinforced metal matrix composites,especially at elevated temperatures.We provide a strategy for constructing extremely fine,in situ-formed coherent nanolamellar solute-twining architectures in a supersaturated MAX/Ni composite to modify the interface,aiming for higher strengths.Through this unique architecture,a coherent interface of ceramic particles and a metal matrix is formed,with an enormous coherent interface known as a ladder interface.The tensile strength at 1023 K is approximately 1 GPa by forming a thermally stable Schwarz crystal structure(<3 nm).Developing heat-tolerant composites using this architecture may enhance the materials’available properties for high-temperature applications.展开更多
This paper expounds upon a novel target detection methodology distinguished by its elevated discriminatory efficacy,specifically tailored for environments characterized by markedly low luminance levels.Conventional me...This paper expounds upon a novel target detection methodology distinguished by its elevated discriminatory efficacy,specifically tailored for environments characterized by markedly low luminance levels.Conventional methodologies struggle with the challenges posed by luminosity fluctuations,especially in settings characterized by diminished radiance,further exacerbated by the utilization of suboptimal imaging instrumentation.The envisioned approach mandates a departure from the conventional YOLOX model,which exhibits inadequacies in mitigating these challenges.To enhance the efficacy of this approach in low-light conditions,the dehazing algorithm undergoes refinement,effecting a discerning regulation of the transmission rate at the pixel level,reducing it to values below 0.5,thereby resulting in an augmentation of image contrast.Subsequently,the coiflet wavelet transform is employed to discern and isolate high-discriminatory attributes by dismantling low-frequency image attributes and extracting high-frequency attributes across divergent axes.The utilization of CycleGAN serves to elevate the features of low-light imagery across an array of stylistic variances.Advanced computational methodologies are then employed to amalgamate and conflate intricate attributes originating from images characterized by distinct stylistic orientations,thereby augmenting the model’s erudition potential.Empirical validation conducted on the PASCAL VOC and MS COCO 2017 datasets substantiates pronounced advancements.The refined low-light enhancement algorithm yields a discernible 5.9%augmentation in the target detection evaluation index when compared to the original imagery.Mean Average Precision(mAP)undergoes enhancements of 9.45%and 0.052%in low-light visual renditions relative to conventional YOLOX outcomes.The envisaged approach presents a myriad of advantages over prevailing benchmark methodologies in the realm of target detection within environments marked by an acute scarcity of luminosity.展开更多
Frequent occurrences of extreme heat are causing severe ozone pollution over China.This study examined the driving factors of urban ozone pollution in China during the extremely hot summer of 2022 and the impact of em...Frequent occurrences of extreme heat are causing severe ozone pollution over China.This study examined the driving factors of urban ozone pollution in China during the extremely hot summer of 2022 and the impact of emission control strategies using surface measurements and the GEOS-Chem model.The results show that ozone pollution was extremely severe in summer 2022,with a significant rebound by 12-15 ppbv in the North China Plain(NCP),Yangtze River Delta(YRD),and Sichuan basin(SCB),compared to 2021.Especially over the NCP,the MDA8(maximum daily 8-hourly average)ozone exceeded 160 ppbv,and the number of ozone exceedances was over 42 days.Based on an IPR(integrated process rate)analysis,the authors found that the net chemical production was the dominant factor contributing to the strong ozone increase in summer 2022.For example,in June over the NCP,the net chemical production resulted in an increase by 3.08 Gg d^(−1)(∼270%)in ozone mass change.Sensitivity simulations showed that both NO_(x)(nitrogen oxides)and VOC(volatile organic compound)reductions were important over the NCP,and NO_(x)reductions were more important than VOCs over southern China.To keep the ozone of 2022 at the same level as 2021,a joint reduction of NO_(x)and VOCs by at least 50%-60%would have been required.This study highlights the urgency to develop effective ozone management since extreme heat will become more frequent.展开更多
This study investigates high-amplitude Extreme Wall Pressure fluctuation Events(EWPEs)in Shock wave/Turbulent Boundary Layer Interactions(STBLIs)through the conditional sampling of direct numerical simulation database...This study investigates high-amplitude Extreme Wall Pressure fluctuation Events(EWPEs)in Shock wave/Turbulent Boundary Layer Interactions(STBLIs)through the conditional sampling of direct numerical simulation databases.The aim is to evaluate the effect of STBLIs and their strength on the statistical properties and associated turbulent structures of EWPEs using the conditional-averaging and clustering method.The temporal statistical results show that the occurrence probability and contribution ratio of EWPEs decrease downstream of strong STBLI,but their duration and interval time increase.Regarding two-dimensional wall pressure structures,the large population of small-scale structures becomes more elongated,but strong interactions induce a greater number of large-scale structures.The pairing of wall pressure events with a higher occurrence probability is verified by the joint probability density functions.Conditional analysis reveals that,as the interaction strength increases,the ejection motion associated with positive events occurs farther downstream and the spanwise vortex core locating above negative events is lifted up along the wall-normal direction.Moreover,analysis associates the paired wall pressure events with the sweep,ejection,and swirl motions in STBLIs,where hairpin eddies play an important role in the formation of positive-negative paired wall pressure structures.展开更多
Introduction: The purpose of this retrospective study is to identify medical conditions impacting neurodevelopmental outcomes of extremely low birth weight and very low birth weight preterm infants at three years of a...Introduction: The purpose of this retrospective study is to identify medical conditions impacting neurodevelopmental outcomes of extremely low birth weight and very low birth weight preterm infants at three years of age. Methods: Infants born in Banner Diamond Children’s University Medical Center, receiving services in the Newborn Intensive Care Unit, and attending Neonatal Developmental Follow-Up Clinic were identified. Participants received developmental assessment and follow-up from August 2012 through December 2018. Relevant clinical conditions during initial hospital stay and up to three years of age were obtained by reviewing medical and developmental records. Bayley Scales of Infant Toddler Development (Bayley III) was used to evaluate skill development at 6, 9, 12, 18, 24, 30, 36 months. Results: Data analysis did not reveal significant p-values;it did demonstrate that some predictor variables impact neurodevelopmental outcomes in cognitive, language and motor skill development. Conclusion: This retrospective study reports significant association between birth weight and low cognitive scores. Correlations were also found between gestational age and Total Language, and the longer an infant stayed in the NICU, the poorer the Total Language Scaled Scores at 8 to 12 months, 15 to 18 months, and 24 to 36 months. Birth weight was found to be the greatest predictor of poor motor scores.展开更多
By selecting the daily maximum temperatures during 1961-2005 in 35 representative stations in Liaoning Province, the temporal and spatial distribution characteristics of extremely maximum temperature event were studie...By selecting the daily maximum temperatures during 1961-2005 in 35 representative stations in Liaoning Province, the temporal and spatial distribution characteristics of extremely maximum temperature event were studied. By using REOF, the mean-square deviation and so on, the variation and distribution situation of extremely maximum temperature in the different regions of Liaoning were reflected. The results showed that the extremely maximum temperature in Liaoning Province could be divided into 3 regions where were respectively the northeast area, the west and the northwest area, the south and the southeast area. The distribution characteristic of extremely maximum temperature threshold value in Liaoning Province was basically consistent with the distribution characteristic of average temperature. The zone where the extremely maximum temperature threshold was relatively high was in the northwest area of Liaoning, and the low threshold zone was in the southeast area and most areas in the east. The variation of extremely maximum temperature in winter was the greatest and in summer was the smallest. The variation of extremely maximum temperature days was the greatest in summer and wasn’t great in spring, autumn, winter.展开更多
AIM： Minimal deviation carcinoma of the uterine cervix, otherwise known as extremely well-differentiated adenocarcinoma （EWDA）, is characterized by its benign microscopic appearance in contrast to its aggressive be...AIM： Minimal deviation carcinoma of the uterine cervix, otherwise known as extremely well-differentiated adenocarcinoma （EWDA）, is characterized by its benign microscopic appearance in contrast to its aggressive behavior. In order to elucidate the clinicopathological features and biological behavior of the gastric counterpart of EWDA, we, using immunohistochemistry, analyzed nine lesions for the phenotypic expression, proliferative activity, and the expression of oncogene-associated products. METHODS： Clinicopathological features, including preoperative biopsy diagnosis, were reviewed. Using immunohitstochemistry, Ki-67 labeling index and expression of p53 and c-erbB-2 protein in the gastric lesions were detected.RESULT： Locations in the middle or upper third of the stomach and polypoid macroscopic features are characteristic of EWDA of the stomach. Although 4 of the 9 lesions showed only focal lymphatic or venous invasion, lymph node metastasis was not present and none of the patients died of the lesions （mean follow-up period, 56 too）. All 9 cases of EWDA could be classified into gastric phenotype （5 lesions） and intestinal phenotype （4 lesions）. The former resembled gastric foveolar epithelium, mucous neck cells or pyloric glands, but their papillary structures were frequently elongated and the tumor cellsand their nuclei were slightly larger and more hyperchromatic compared to normal epithelium. The latter resembled intestinal metaplasia with minimal nulcear atypia and irregular glands; two of these lesions demonstrated complete intestinal phenotype, while two demonstrated incomplete intestinal phenotype. Ki-67 labeling index was low and none of the cases revealed over-expression of p53 and c-erbB-2 protein. CONCLUSION： Unlike minimal deviation carcinoma of the cervix, these findings suggest that EWDA of the stomach is a lesion of low-grade malignancy. This favorable biological behavior is supported by the data of a low Ki-67 labeling index and a lack of p53 or c-erbB-2 protein over-expression. Because of its resemblance to normal gastric mucosa or mucosa with intestinal metaplasia, EWDA is often misdiagnosed. To prevent the misdiagnosis of such lesions, the clinical and pathologic characteristics should be taken into consideration.展开更多
In the first half of winter 2020/21,China has experienced an extremely cold period across both northern and southern regions,with record-breaking low temperatures set in many stations of China.Meanwhile,a moderate La ...In the first half of winter 2020/21,China has experienced an extremely cold period across both northern and southern regions,with record-breaking low temperatures set in many stations of China.Meanwhile,a moderate La Niña event which exceeded both oceanic and atmospheric thresholds began in August 2020 and in a few months developed into its mature phase,just prior to the 2020/21 winter.In this report,the mid−high-latitude large-scale atmospheric circulation anomalies in the Northern Hemisphere,which were forced by the negative phase of Arctic Oscillation,a strengthened Siberian High,an intensified Ural High and a deepened East Asian Trough,are considered to be the direct reason for the frequent cold surges in winter 2020/21.At the same time,the synergistic effect of the warm Arctic and the cold tropical Pacific(La Niña)provided an indispensable background,at a hemispheric scale,to intensify the atmospheric circulation anomalies in middle-to-high latitudes.In the end,a most recent La Niña prediction is provided and the on-coming evolution of climate is discussed for the remaining part of the 2020/21 winter for the purpose of future decision-making and early warning.展开更多
An extremely heavy rainfall event lasting from 17 to 22 July 2021 occurred in Henan Province of China, with accumulated precipitation of more than 1000 mm over a 6-day period that exceeded its mean annual precipitatio...An extremely heavy rainfall event lasting from 17 to 22 July 2021 occurred in Henan Province of China, with accumulated precipitation of more than 1000 mm over a 6-day period that exceeded its mean annual precipitation. The present study examines the roles of persistent low-level jets(LLJs) in maintaining the precipitation using surface station observations and reanalysis datasets. The LLJs triggered strong ascending motions and carried moisture mainly from the outflow of Typhoon In-fa(2021). The varying directions of the LLJs well corresponded to the meridional shifts of the rainfall. The precipitation rate reached a maximum during 20-21 July as the LLJs strengthened and expanded vertically into double LLJs, including synoptic-weather-system-related LLJs(SLLJs) at 850–700 hPa and boundary-layer jets(BLJs)at ~950 hPa. The coupling of the SLLJ and BLJ provided strong mid-and low-level convergence on 20 July, whereas the SLLJ produced mid-level divergence at its entrance that coupled with low-level convergence at the terminus of the BLJ on21 July. The formation mechanisms of the two types of LLJs are further examined. The SLLJs and the low-pressure vortex(or inverted trough) varied synchronously as a whole and were affected by the southwestward movement of the WPSH in the rainiest period. The persistent large total pressure gradient force at low levels also maintained the strength of low-level geostrophic winds, thus sustaining the BLJs on the synoptic scale. The results based on a Du-Rotunno 1D model show that the Blackadar and Holton mechanisms jointly governed the BLJ dynamics on the diurnal scale.展开更多
A direct synthesis of methyl levulinate from cellulose alcoholysis in methanol medium under mild condition(180 210 C)catalyzed by extremely low concentration sulfuric acid(0.01 mol/L)and the product isolation were dev...A direct synthesis of methyl levulinate from cellulose alcoholysis in methanol medium under mild condition(180 210 C)catalyzed by extremely low concentration sulfuric acid(0.01 mol/L)and the product isolation were developed in this study.Effects of different process variables towards the catalytic performance were performed as a function of reaction time.The results indicated that sulfuric acid concentration,temperature and initial cellulose concentration had significant effects on the synthesis of methyl levulinate.An optimized yield of around 50%was achieved at 210 C for 120 min with sulfuric acid concentration of 0.01 mol/L and initial cellulose concentration below 100 g/L.The resulting product mixture was isolated by a distillation technique that combines an atmospheric distillation with a vacuum distillation where n-dodecane was added to help distill the heavy fraction.The light fraction including mainly methanol could be reused as the reaction medium without any substantial change in the yield of methyl levulinate.The chemical composition and structural of lower heavy fraction were characterized by GC/MS,FTIR,1H-NMR and13C-NMR techniques.Methyl levulinate was found to be a major ingredient of lower heavy fraction with the content over 96%.This pathway is efficient,environmentally benign and economical for the production of pure levulinate esters from cellulose.展开更多
When an extremely thick rock bed exists above a protected coal seam in the bending zone given the condition of a mining protective seam, this extremely thick rock bed controls the movement of the entire overlying stra...When an extremely thick rock bed exists above a protected coal seam in the bending zone given the condition of a mining protective seam, this extremely thick rock bed controls the movement of the entire overlying stratum. This extremely thick rock bed, called a ＂main key stratum＂, will not subside nor break for a long time, causing lower fractures and bed separations not to close and gas can migrate to the bed separation areas along the fractures. These bed separations become gas enrichment areas. By analyzing the rule of fracture evolution and gas migration under the main key stratum after the deep protective coal seam has been mined, we propose a new gas drainage method which uses bore holes, drilled through rock and coal seams at great depths for draining pressure relief gas. In this method, the bores are located at a high level suction roadway （we can also drill them in the drilling field located high in an air gateway）. Given the practice in the Haizi mine, the gas drainage rate can reach 73% in the middie coal group, with a gas drainage radius over 100 m.展开更多
文摘BACKGROUND Intracranial blister-like microaneurysms are an extremely rare disease.Rupture of intracranial aneurysms can lead to subarachnoid hemorrhage(SAH).Patients with SAH may experience severe neurological symptoms,including severe headache,nausea,vomiting,transient or persistent loss of consciousness,limb weakness,and blurred vision.Ruptured aneurysms should be surgically treated as soon as possible.Intravascular electrocoagulation is becoming a promising treatment method for intracranial blister-like microaneurysms.The short-term follow-up results demonstrated that this method is safe and effective.This article presents a case of endovascular electrocoagulation for the treatment of a blisterlike microaneurysm.CASE SUMMARY This article reports the case of 71-year-old female patient with an intracranial aneurysm.The patient experienced a sudden headache with vomiting for 3 hours.Brain computed tomography(CT)scan showed a subarachnoid hemorrhage.She was diagnosed with rupture of an aneurysm and subarachnoid hemorrhage.The aneurysm was located in the choroidal segment of the right internal carotid artery.The size of the aneurysm was 2.00 mm×1.80 mm×1.97 mm,and the neck of the aneurysm was less than 0.5 mm wide.We successfully treated this aneurysm with endovascular electrocoagulation,and the patient was safely returned to the ward and discharged after subsequent supportive treatment.CT angiography reexamination 3 months after surgery revealed no contrast agent extravasation in the original lesion,with a good prognosis.CONCLUSION Endovascular electrocoagulation is an effective and safe method for the treatment of intracranial blister-like microaneurysms.
基金supported by the National Natural Science Foundation of China(Grant Nos.42330610 and 42075010)。
文摘The Sichuan Basin(SCB),China has a high incidence of extremely persistent heavy rainfall(EPHR)events.The EPHR events from 2009 to 2019 in the SCB were mainly concentrated over the northern and northwestern windward slopes and the central basin.They occurred from June to September,but especially in July,and peaked at 0300 LST.ERA5 reanalysis data and objective classification were used to investigate the synoptic patterns and their effects.There were three synoptic patterns during EPHR events,all accompanied by a Southwest Vortex.The location and intensity of the Southwest Vortex,thermal forcing of the Tibetan Plateau(TP),and low-level winds can greatly affect the intensity and spatial distribution of EPHR.When the Southwest Vortex was located in the western SCB and there were southerly low-level jets(LLJs),convergence and upslope wind would lead to EPHR over the northwestern or northern windward slopes.If there was no LLJ and the whole SCB was under the center of the Southwest Vortex,nocturnal EPHR was controlled by the internal circulation of the Southwest Vortex and the updraft generated by the thermal forcing of the TP,and the rainfall was weaker.The southeastern entrance of the SCB was a key area where the low-level wind dominated the nocturnal peak of EPHR.The nocturnal strengthened southeasterly wind in the key area is attributable to inertial oscillation,and the topographic friction plays an essential role in transporting momentum and moisture into the basin by generating easterly and northeasterly ageostrophic winds.
基金supported by the National Natural Science Foundation of China(No.52074296)。
文摘In extremely close-distance coal seam(ECDCS)mining,section coal pillars remain after upper coal seam(UCS)extraction.Thus,for layout and support design of lower coal seam(LCS)mining roadways,it is critical to account for UCS goaf deterioration and residual coal pillar(RCP)-induced stress disturbance.Taking the 6.4 m layer spacing of ECDCS mining in Nanyangpo Coal Mine as a case study,this research aimed to determine the optimal layout and surrounding rock control method for the 24202-ventilation roadway in the RCP area.First,the challenges of roadway layout and support under RCP were clarified:three layout methods face distinct RCPinduced stress disturbances and goaf-related roof damage.A finite element model was established;the second invariant of deviatoric stress(J_(2))and horizontal stress index were introduced to analyze plastic zone and stress evolution after UCS mining.Results show that J_(2)distributes symmetrically,with its peak diffusing downward and attenuating in a“/”-shaped pattern.Six schemes were simulated to compare plastic zone distributions at different positions,revealing that the optimal layout consists of a roadway alignment with the RCP center.Based on roadway layout and roof conditions,a cooperative control scheme was proposed:deep,strong anchorage with long cables across the RCP,and shallow stable support with short bolts in the ECDCS.This scheme secures roof cables anchored to the UCS RCP roof to achieve cross-seam anchorage.On-site borehole peeping and loose circle tests confirm smooth surrounding rock hole walls and limited failure range.Specifically,surrounding rock deformation and roof separation were controlled within 200 mm and 80 mm,respectively,with stable bolt/cable support resistance.These results offer an innovative solution for roadway layout design and support strategies under RCP in ECDCS,with significant engineering application value.
基金supported in part by the National Natural Science Foundation of China (NSFC) under Grants 62271310 and 62125108in part by the Fundamental Research Funds for the Central Universities of Chinain part by the NSFC under Grant 62431014
文摘Extremely large-scale array(XL-array)communications can significantly improve the transmission rate,spectral efficiency,and spatial resolution,and has great potential in next-generation mobile communication networks.A crucial problem in XLarray communications is to determine the boundary of applicable regions of the plane wave model(PWM)and spherical wave model(SWM).In this paper,we propose new PWM/SWM demarcations for XL-arrays from the viewpoint of channel gain and rank.Four sets of results are derived for four different array setups.First,an equi-power line is derived for a point-touniform linear array(ULA)scenario,where an inflection point is found at±π6 central incident angles.Second,an equi-power surface is derived for a point-touniform planar array(UPA)scenario,and it is proved that cos2(ϕ)cos2(φ)=12 is a dividing curve,where ϕ andφdenote the elevation and azimuth angles,respectively.Third,an accurate and explicit expression of the equi-rank surface is obtained for a ULA-to-ULA scenario.Finally,an approximated expression of the equirank surface is obtained for a ULA-to-UPA scenario.With the obtained closed-form expressions,the equirank surface for any antenna structure and any angle can be well estimated.Furthermore,the effect of scatterers is also investigated,from which some insights are drawn.
基金support of the National Natural Science Foundation of China(52374180,52327804).
文摘This study focuses on steeply inclined and extremely thick coal seams(SIETCS)characterized by immense thickness,a steep inclination of coal seams(87°),and high horizontal stress.The geological conditions and mining technology associated with SIETCS differ significantly from those of generally inclined coal seams,resulting in notable variations in roadway stress distributions.On SIETCS have predominantly examined the impact of rock layers flanking coal seams on rock bursts,with limited emphasis on SIETCS roadways.This study employs comprehensive methods,integrating numerical simulations,theoretical analyses,and field detections to investigate the stress distribution of SIETCS and the mechanisms of rock burst-induced vertical damage,subsequently validated in situ.The vertical stress in SIETCS is minimal,while horizontal stress is concentrated,leading to the formation of layered crack structures(LCS)that distribute above and below the roadways.Additionally,elastic energy significantly concentrates within the LCS.Axial dynamic compressive stress and vertical dynamic tensile stress along the LCS diminish its stability,readily triggering failure.During the LCS failure process,the stored energy is released,converting into kinetic energy required for coal body ejection after reaching the minimum energy for failure and dissipative energy,ultimately leading to rock burst-induced vertical damage in roadways.On-site detection and analysis within SIETCS,along with historical rock burst data,confirm the existence of LCS and its role in inducing vertical rock burst damage.This research establishes essential foundations for preventing rock bursts within SIETCS.
基金Supported by 2024 Central Financial Comprehensive Protection Project for Abies chensiensis(610000242000000026647)2024 Provincial Forestry and Grassland Reform and Development Fund for the National Key Wild Plant Protection Project(610000242000000028574)2024 Biodiversity Conservation Project(610000242000000024911).
文摘The implementation of the ecological protection red line serves as a crucial protective barrier for the conservation of wild plants with extremely small populations by delineating specific geographical areas designated for their conservation.The implementation of a comprehensive set of conservation measures aimed at establishing a biodiversity conservation network for wild plants with extremely small populations has laid the foundation for the health and stability of ecosystems,as well as the harmonious coexistence of humans and the natural environment.Research on the conservation of wild plants with extremely small populations serves as a critical foundation for informing and enhancing the effective conservation of such populations.This paper provides a systematic examination of the theoretical and practical conservation status of certain wild plants with extremely small populations and discusses the conservation trends of these populations within the framework of ecological protection red line delineation.In the future,strategies for the conservation of wild plants with extremely small populations should be integrated with an analysis of the causes of endangerment.This approach will provide a robust foundation for applied research focused on the conservation of these vulnerable plant populations.
基金Project supported by the National Natural Science Foundation of China(Grant No.12274440)the National Key R&D Program of China(Grant No.2022YFA1403903)the Synergetic Extreme Condition User Facility(SECUF)。
文摘Magnetoresistance(MR)is a pivotal transport phenomenon within the realm of condensed matter physics.In recent years,materials exhibiting extremely large unsaturated magnetoresistance(XMR),which are often potential topological materials,have garnered significant attention.In this study,we synthesized single crystals of ZrBi_(2) and performed electrical and specific heat measurements on them.The resistivity of ZrBi_(2) displays metallic behavior with a high residual resistance ratio.Notably,the MR of ZrBi_(2) reaches approximately 2.0×10^(3)%at 2 K and 16 T without saturation.Weak Shubnikov-de Haas oscillations with two frequencies were observed above 13.5 T,which correspond to 237 T and 663 T.Hall effect fitting yields nearly equal concentrations of electron and hole carriers with concentrations of approximately 10^(21)cm^(-3)and mobilities of approximately 5000 cm^(2)·V^(-1)·s^(-1)at 2 K.The XMR could be attributed to the electron-hole compensation with high mobility.
基金jointly supported by the National Natural Science Foundation of China[grant numbers U2342202 and 42175005]the Qing Lan Project[grant number R2023Q06]。
文摘A numerical simulation was performed using the Thompson microphysics scheme to preliminarily investigate the features of the microphysical processes involved in the record-breaking rainfall event that occurred in Henan Province,China,on 20 July 2021.The simulation results showed that a strong meso-𝛾-scale vortical updraft was concurrent with the torrential rainfall.The main finding is that this event was characterized by typical midlatitude warm-rain processes.The simulation with the Thompson microphysics scheme further indicated that highly efficient collision-coalescence of cloud water to rainwater resulted in a considerably active rain droplet growth,leading to this record-breaking rainfall event.
基金the National Natural Science Foundation of China(62273359)the General Project of Hunan Natural Science Foundation of China(2022JJ30748)the National Major Scientific Research Equipment of China(61927803)。
文摘Blast furnace(BF)burden surface contains the most abundant,intuitive and credible smelting information and acquiring high-definition and high-brightness optical images of which is essential to realize precise material charging control,optimize gas flow distribution and improve ironmaking efficiency.It has been challengeable to obtain high-quality optical burden surface images under high-temperature,high-dust,and extremelydim(less than 0.001 Lux)environment.Based on a novel endoscopic sensing detection idea,a reverse telephoto structure starlight imaging system with large field of view and large aperture is designed.Combined with a water-air dual cooling intelligent self-maintenance protection device and the imaging system,a starlight high-temperature industrial endoscope is developed to obtain clear optical burden surface images stably under the harsh environment.Based on an endoscope imaging area model,a material flow trajectory model and a gas-dust coupling distribution model,an optimal installation position and posture configuration method for the endoscope is proposed,which maximizes the effective imaging area and ensures large-area,safe and stable imaging of the device in a confined space.Industrial experiments and applications indicate that the proposed method obtains clear and reliable large-area optical burden surface images and reveals new BF conditions,providing key data support for green iron smelting.
基金supported financially by the Beijing Natural Science Foundation(No.2212046)the National Natural Science Foundation of China(Nos.51871011 and 51572017)+2 种基金the Research Fund for Commercialization of Major Scientific and Technological Achievements of Hebei Province(No.22281006Z)the Beijing Government Funds for the Constructive Project of Central UniversitiesThe financial supports by them are greatly appreciated.
文摘The interface of ceramic particles and metal matrixes extremely impacts the mechanical properties of particle-reinforced metal matrix composites,especially at elevated temperatures.We provide a strategy for constructing extremely fine,in situ-formed coherent nanolamellar solute-twining architectures in a supersaturated MAX/Ni composite to modify the interface,aiming for higher strengths.Through this unique architecture,a coherent interface of ceramic particles and a metal matrix is formed,with an enormous coherent interface known as a ladder interface.The tensile strength at 1023 K is approximately 1 GPa by forming a thermally stable Schwarz crystal structure(<3 nm).Developing heat-tolerant composites using this architecture may enhance the materials’available properties for high-temperature applications.
基金supported by National Sciences Foundation of China Grants(No.61902158).
文摘This paper expounds upon a novel target detection methodology distinguished by its elevated discriminatory efficacy,specifically tailored for environments characterized by markedly low luminance levels.Conventional methodologies struggle with the challenges posed by luminosity fluctuations,especially in settings characterized by diminished radiance,further exacerbated by the utilization of suboptimal imaging instrumentation.The envisioned approach mandates a departure from the conventional YOLOX model,which exhibits inadequacies in mitigating these challenges.To enhance the efficacy of this approach in low-light conditions,the dehazing algorithm undergoes refinement,effecting a discerning regulation of the transmission rate at the pixel level,reducing it to values below 0.5,thereby resulting in an augmentation of image contrast.Subsequently,the coiflet wavelet transform is employed to discern and isolate high-discriminatory attributes by dismantling low-frequency image attributes and extracting high-frequency attributes across divergent axes.The utilization of CycleGAN serves to elevate the features of low-light imagery across an array of stylistic variances.Advanced computational methodologies are then employed to amalgamate and conflate intricate attributes originating from images characterized by distinct stylistic orientations,thereby augmenting the model’s erudition potential.Empirical validation conducted on the PASCAL VOC and MS COCO 2017 datasets substantiates pronounced advancements.The refined low-light enhancement algorithm yields a discernible 5.9%augmentation in the target detection evaluation index when compared to the original imagery.Mean Average Precision(mAP)undergoes enhancements of 9.45%and 0.052%in low-light visual renditions relative to conventional YOLOX outcomes.The envisaged approach presents a myriad of advantages over prevailing benchmark methodologies in the realm of target detection within environments marked by an acute scarcity of luminosity.
基金supported by the National Key Research and Development Program of China[grant number 2022YFE0136100]the National Natural Science Foundation of China[grant number 42205114].
文摘Frequent occurrences of extreme heat are causing severe ozone pollution over China.This study examined the driving factors of urban ozone pollution in China during the extremely hot summer of 2022 and the impact of emission control strategies using surface measurements and the GEOS-Chem model.The results show that ozone pollution was extremely severe in summer 2022,with a significant rebound by 12-15 ppbv in the North China Plain(NCP),Yangtze River Delta(YRD),and Sichuan basin(SCB),compared to 2021.Especially over the NCP,the MDA8(maximum daily 8-hourly average)ozone exceeded 160 ppbv,and the number of ozone exceedances was over 42 days.Based on an IPR(integrated process rate)analysis,the authors found that the net chemical production was the dominant factor contributing to the strong ozone increase in summer 2022.For example,in June over the NCP,the net chemical production resulted in an increase by 3.08 Gg d^(−1)(∼270%)in ozone mass change.Sensitivity simulations showed that both NO_(x)(nitrogen oxides)and VOC(volatile organic compound)reductions were important over the NCP,and NO_(x)reductions were more important than VOCs over southern China.To keep the ozone of 2022 at the same level as 2021,a joint reduction of NO_(x)and VOCs by at least 50%-60%would have been required.This study highlights the urgency to develop effective ozone management since extreme heat will become more frequent.
基金co-supported by the National Natural Science Foundation of China(Nos.12232018 and 11972356)the National Key Research and Development Program of China(No.2019YFA0405200)。
文摘This study investigates high-amplitude Extreme Wall Pressure fluctuation Events(EWPEs)in Shock wave/Turbulent Boundary Layer Interactions(STBLIs)through the conditional sampling of direct numerical simulation databases.The aim is to evaluate the effect of STBLIs and their strength on the statistical properties and associated turbulent structures of EWPEs using the conditional-averaging and clustering method.The temporal statistical results show that the occurrence probability and contribution ratio of EWPEs decrease downstream of strong STBLI,but their duration and interval time increase.Regarding two-dimensional wall pressure structures,the large population of small-scale structures becomes more elongated,but strong interactions induce a greater number of large-scale structures.The pairing of wall pressure events with a higher occurrence probability is verified by the joint probability density functions.Conditional analysis reveals that,as the interaction strength increases,the ejection motion associated with positive events occurs farther downstream and the spanwise vortex core locating above negative events is lifted up along the wall-normal direction.Moreover,analysis associates the paired wall pressure events with the sweep,ejection,and swirl motions in STBLIs,where hairpin eddies play an important role in the formation of positive-negative paired wall pressure structures.
文摘Introduction: The purpose of this retrospective study is to identify medical conditions impacting neurodevelopmental outcomes of extremely low birth weight and very low birth weight preterm infants at three years of age. Methods: Infants born in Banner Diamond Children’s University Medical Center, receiving services in the Newborn Intensive Care Unit, and attending Neonatal Developmental Follow-Up Clinic were identified. Participants received developmental assessment and follow-up from August 2012 through December 2018. Relevant clinical conditions during initial hospital stay and up to three years of age were obtained by reviewing medical and developmental records. Bayley Scales of Infant Toddler Development (Bayley III) was used to evaluate skill development at 6, 9, 12, 18, 24, 30, 36 months. Results: Data analysis did not reveal significant p-values;it did demonstrate that some predictor variables impact neurodevelopmental outcomes in cognitive, language and motor skill development. Conclusion: This retrospective study reports significant association between birth weight and low cognitive scores. Correlations were also found between gestational age and Total Language, and the longer an infant stayed in the NICU, the poorer the Total Language Scaled Scores at 8 to 12 months, 15 to 18 months, and 24 to 36 months. Birth weight was found to be the greatest predictor of poor motor scores.
文摘By selecting the daily maximum temperatures during 1961-2005 in 35 representative stations in Liaoning Province, the temporal and spatial distribution characteristics of extremely maximum temperature event were studied. By using REOF, the mean-square deviation and so on, the variation and distribution situation of extremely maximum temperature in the different regions of Liaoning were reflected. The results showed that the extremely maximum temperature in Liaoning Province could be divided into 3 regions where were respectively the northeast area, the west and the northwest area, the south and the southeast area. The distribution characteristic of extremely maximum temperature threshold value in Liaoning Province was basically consistent with the distribution characteristic of average temperature. The zone where the extremely maximum temperature threshold was relatively high was in the northwest area of Liaoning, and the low threshold zone was in the southeast area and most areas in the east. The variation of extremely maximum temperature in winter was the greatest and in summer was the smallest. The variation of extremely maximum temperature days was the greatest in summer and wasn’t great in spring, autumn, winter.
基金Supported by Grants-in-aid for Cancer Research from the Ministry of Education, Science and Culture, Japan and the Fukuoka Cancer Society, Fukuoka, Japan
文摘AIM： Minimal deviation carcinoma of the uterine cervix, otherwise known as extremely well-differentiated adenocarcinoma （EWDA）, is characterized by its benign microscopic appearance in contrast to its aggressive behavior. In order to elucidate the clinicopathological features and biological behavior of the gastric counterpart of EWDA, we, using immunohistochemistry, analyzed nine lesions for the phenotypic expression, proliferative activity, and the expression of oncogene-associated products. METHODS： Clinicopathological features, including preoperative biopsy diagnosis, were reviewed. Using immunohitstochemistry, Ki-67 labeling index and expression of p53 and c-erbB-2 protein in the gastric lesions were detected.RESULT： Locations in the middle or upper third of the stomach and polypoid macroscopic features are characteristic of EWDA of the stomach. Although 4 of the 9 lesions showed only focal lymphatic or venous invasion, lymph node metastasis was not present and none of the patients died of the lesions （mean follow-up period, 56 too）. All 9 cases of EWDA could be classified into gastric phenotype （5 lesions） and intestinal phenotype （4 lesions）. The former resembled gastric foveolar epithelium, mucous neck cells or pyloric glands, but their papillary structures were frequently elongated and the tumor cellsand their nuclei were slightly larger and more hyperchromatic compared to normal epithelium. The latter resembled intestinal metaplasia with minimal nulcear atypia and irregular glands; two of these lesions demonstrated complete intestinal phenotype, while two demonstrated incomplete intestinal phenotype. Ki-67 labeling index was low and none of the cases revealed over-expression of p53 and c-erbB-2 protein. CONCLUSION： Unlike minimal deviation carcinoma of the cervix, these findings suggest that EWDA of the stomach is a lesion of low-grade malignancy. This favorable biological behavior is supported by the data of a low Ki-67 labeling index and a lack of p53 or c-erbB-2 protein over-expression. Because of its resemblance to normal gastric mucosa or mucosa with intestinal metaplasia, EWDA is often misdiagnosed. To prevent the misdiagnosis of such lesions, the clinical and pathologic characteristics should be taken into consideration.
基金supported by the national key R&D Program of China(Grant No 2018YFC1505603)the Key Research Program of Frontier Sciences,CAS(Grant No.ZDBS-LY-DQC010)the National Natural Science Foundation of China(Grant Nos.41876012,41861144015).
文摘In the first half of winter 2020/21,China has experienced an extremely cold period across both northern and southern regions,with record-breaking low temperatures set in many stations of China.Meanwhile,a moderate La Niña event which exceeded both oceanic and atmospheric thresholds began in August 2020 and in a few months developed into its mature phase,just prior to the 2020/21 winter.In this report,the mid−high-latitude large-scale atmospheric circulation anomalies in the Northern Hemisphere,which were forced by the negative phase of Arctic Oscillation,a strengthened Siberian High,an intensified Ural High and a deepened East Asian Trough,are considered to be the direct reason for the frequent cold surges in winter 2020/21.At the same time,the synergistic effect of the warm Arctic and the cold tropical Pacific(La Niña)provided an indispensable background,at a hemispheric scale,to intensify the atmospheric circulation anomalies in middle-to-high latitudes.In the end,a most recent La Niña prediction is provided and the on-coming evolution of climate is discussed for the remaining part of the 2020/21 winter for the purpose of future decision-making and early warning.
基金supported by Guangdong Major Project of Basic and Applied Basic Research(2020B0301030004)the National Natural Science Foundation of China(Grant Nos.42122033,41875055,and 42075006)Guangzhou Science and Technology Plan Projects(202002030346 and 202002030196).
文摘An extremely heavy rainfall event lasting from 17 to 22 July 2021 occurred in Henan Province of China, with accumulated precipitation of more than 1000 mm over a 6-day period that exceeded its mean annual precipitation. The present study examines the roles of persistent low-level jets(LLJs) in maintaining the precipitation using surface station observations and reanalysis datasets. The LLJs triggered strong ascending motions and carried moisture mainly from the outflow of Typhoon In-fa(2021). The varying directions of the LLJs well corresponded to the meridional shifts of the rainfall. The precipitation rate reached a maximum during 20-21 July as the LLJs strengthened and expanded vertically into double LLJs, including synoptic-weather-system-related LLJs(SLLJs) at 850–700 hPa and boundary-layer jets(BLJs)at ~950 hPa. The coupling of the SLLJ and BLJ provided strong mid-and low-level convergence on 20 July, whereas the SLLJ produced mid-level divergence at its entrance that coupled with low-level convergence at the terminus of the BLJ on21 July. The formation mechanisms of the two types of LLJs are further examined. The SLLJs and the low-pressure vortex(or inverted trough) varied synchronously as a whole and were affected by the southwestward movement of the WPSH in the rainiest period. The persistent large total pressure gradient force at low levels also maintained the strength of low-level geostrophic winds, thus sustaining the BLJs on the synoptic scale. The results based on a Du-Rotunno 1D model show that the Blackadar and Holton mechanisms jointly governed the BLJ dynamics on the diurnal scale.
基金supported by the National Key Basic Research Program (2010CB732201) from the Ministry of Science and Technology of Chinathe State Key Laboratory Open Foundation of Pulp and Paper Engineering of China (201225)
文摘A direct synthesis of methyl levulinate from cellulose alcoholysis in methanol medium under mild condition(180 210 C)catalyzed by extremely low concentration sulfuric acid(0.01 mol/L)and the product isolation were developed in this study.Effects of different process variables towards the catalytic performance were performed as a function of reaction time.The results indicated that sulfuric acid concentration,temperature and initial cellulose concentration had significant effects on the synthesis of methyl levulinate.An optimized yield of around 50%was achieved at 210 C for 120 min with sulfuric acid concentration of 0.01 mol/L and initial cellulose concentration below 100 g/L.The resulting product mixture was isolated by a distillation technique that combines an atmospheric distillation with a vacuum distillation where n-dodecane was added to help distill the heavy fraction.The light fraction including mainly methanol could be reused as the reaction medium without any substantial change in the yield of methyl levulinate.The chemical composition and structural of lower heavy fraction were characterized by GC/MS,FTIR,1H-NMR and13C-NMR techniques.Methyl levulinate was found to be a major ingredient of lower heavy fraction with the content over 96%.This pathway is efficient,environmentally benign and economical for the production of pure levulinate esters from cellulose.
基金Projects 2005CB221503 supported by the National Basic Research Program of China70533050 and 50674089 by the National Natural Science Foundation of China2005BA813B-3-06 by the National Tenth 5-Year Key Scientific and Technological Project
文摘When an extremely thick rock bed exists above a protected coal seam in the bending zone given the condition of a mining protective seam, this extremely thick rock bed controls the movement of the entire overlying stratum. This extremely thick rock bed, called a ＂main key stratum＂, will not subside nor break for a long time, causing lower fractures and bed separations not to close and gas can migrate to the bed separation areas along the fractures. These bed separations become gas enrichment areas. By analyzing the rule of fracture evolution and gas migration under the main key stratum after the deep protective coal seam has been mined, we propose a new gas drainage method which uses bore holes, drilled through rock and coal seams at great depths for draining pressure relief gas. In this method, the bores are located at a high level suction roadway （we can also drill them in the drilling field located high in an air gateway）. Given the practice in the Haizi mine, the gas drainage rate can reach 73% in the middie coal group, with a gas drainage radius over 100 m.
