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Artificial intelligence-enabled high-precision colony extraction and isolation system
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作者 ZHAO Xu-feng JIA Zhi-qiang +5 位作者 CHEN Wei-xue HU Peng-tao SU Xin-ran LI Jun-lin GE Ming-feng DONG Wen-fei 《中国光学(中英文)》 北大核心 2026年第1期190-204,共15页
Standard bacterial suspensions play a crucial role in microbiological diagnosis.Traditional prepar-ation methods,which rely heavily on manual operations,face challenges such as poor reproducibility,low ef-ficiency,and... Standard bacterial suspensions play a crucial role in microbiological diagnosis.Traditional prepar-ation methods,which rely heavily on manual operations,face challenges such as poor reproducibility,low ef-ficiency,and biosafety concerns.In this study,we propose a high-precision automated colony extraction and separation system that combines large-field imaging and artificial intelligence(AI)to facilitate intelligent screening and localization of colonies.Firstly,a large-field imaging system was developed to capture high-resolution images of 90 mm Petri dishes,achieving a physical resolution of 13.2μm and an imaging speed of 13 frames per second.Subsequently,AI technology was employed for the automatic recognition and localiza-tion of colonies,enabling the selection of target colonies with diameters ranging from 1.9 to 2.3 mm.Next,a three-axis motion control platform was designed,accompanied by a path planning algorithm for the efficient extraction of colonies.An electronic pipette was employed for accurate colony collection.Additionally,a bacterial suspension concentration measurement module was developed,incorporating a 650 nm laser diode as the light source,achieving a measurement accuracy of 0.01 McFarland concentration(MCF).Finally,the system’s performance was validated through the preparation of an Esckerichia coli(E.coli)suspension.After 17 hours of cultivation,E.coli was extracted four times,achieving the target concentration set by the system.This work is expected to enable rapid and accurate microbial sample preparation,significantly reducing de-tection cycles and alleviating the workload of healthcare personnel. 展开更多
关键词 artificial intelligence colony extraction and isolation large-field imaging AUTOMATION
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Flexible High-Aspect-Ratio COF Nanofibers:Defect-Engineered Synthesis,Superelastic Aerogels,and Uranium Extraction Applications
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作者 Binbin Fan Jianyong Yu +2 位作者 Xueli Wang Yang Si Peixin Tang 《Nano-Micro Letters》 2026年第5期15-30,共16页
The lack of macro-continuity and mechanical strength of covalent organic frameworks(COFs)has significantly limited their practical applications.Here,we propose an“alcohol-triggered defect cleavage”strategy to precis... The lack of macro-continuity and mechanical strength of covalent organic frameworks(COFs)has significantly limited their practical applications.Here,we propose an“alcohol-triggered defect cleavage”strategy to precisely regulate the growth and stacking of COF grains through a moderate reversed Schiff base reaction,realizing the direct synthesis of COF nanofibers(CNFs)with high aspect ratio(L/D=103.05)and long length(>20μm).An individual CNF exhibits a biomimetic scale-like architecture,achieving superior flexibility and fatigue resistance under dynamic bending via a multiscale stress dissipation mechanism.Taking advantages of these structural features,we engineer CNF aerogels(CNF-As)with programmable porous structures(e.g.,honeycomb,lamellar,isotropic)via directional ice-template methodology.CNF-As demonstrate 100%COF content,high specific surface area(396.15 m^(2)g^(-1))and superelasticity(~0%elastic deformation after 500 compression cycles at 50%strain),outperforming most COF-based counterparts.Compared with the conventional COF aerogels,the unique structural features of CNF-A enable it to perform outstandingly in uranium extraction,with an 11.72-fold increment in adsorption capacity(920.12 mg g^(-1))and adsorption rate(89.9%),and a 2.48-fold improvement in selectivity(U/V=2.31).This study provides a direct strategy for the development of next-generation COF materials with outstanding functionality and structural robustness. 展开更多
关键词 Defect cleavage COF nanofibers Flexibility AEROGELS Uranium extraction
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Microfluidic-templating fabrication of milli-capsules with ultrarigid and homogeneous shells for long-term retention and explosive release of water-soluble cargoes
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作者 Haoyue Zhang Qiaoxia Lin +9 位作者 Zheng Zhang Tengfei Tian Chengze Li Chuanfeng An Kaiwen Chen Yonggang Zhang Rongming Liu Liya Liang Wei He Huanan Wang 《Bio-Design and Manufacturing》 2026年第1期153-164,I0022-I0029,共20页
Encapsulation of water-soluble cargoes in millimeter-sized capsules has enabled major advances in various fields,including pharmaceuticals,food,cosmetics,packaging,and materials.However,because of the lack of fabricat... Encapsulation of water-soluble cargoes in millimeter-sized capsules has enabled major advances in various fields,including pharmaceuticals,food,cosmetics,packaging,and materials.However,because of the lack of fabrication precision,low cargo retention,suboptimal mechanical properties,and difficulty in preventing water evaporation,this technique is more challenging than microencapsulation techniques.In this study,we developed a surfactant-free and organic solvent-free water-in-oil in-air emulsification approach for synthesizing double-layered“milli-capsules”for the precise encapsulation,enhanced retention,and force-triggered burst release of water-soluble bioactive cargoes.In particular,we synthesized milli-capsules with a first shell of poly(ethylene glycol dimethacrylate)for the efficient encapsulation of bioactive cargoes and a second shell of beeswax to prolong the retention of the entrapped bioactive compounds.Unlike traditional milli-capsules,which exhibit poor shape uniformity and mechanical stability,we introduced metallic ions to stabilize the interfacial tension and employed constant rotation to balance the gravity,buoyancy,inertial,and viscous forces imposed on the droplets,resulting in uniform and rigid milli-capsules with narrow rupture forces.Furthermore,additional hydrophobic beeswax coating prevented water volatilization and substantially prolonged the shelf life of the encapsulated compounds from a few days to a few months while maintaining their bioactivities.The proposed milli-capsule system addresses the challenge of precise fabrication of large carriers for water-soluble cargoes,representing a significant step toward the long-term storage and controlled release of bioactive cargoes for various industrial applications. 展开更多
关键词 Droplet microfluidics Millimeter-sized capsule Double-emulsion droplet Controlled release Organic solvent-free encapsulation
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Straightforward and versatile construction of phenanthroline-derived diamide ligands for f-block element extraction
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作者 Dong Fang Xiaofan Yang +1 位作者 Fengxin Gao Chengliang Xiao 《Chinese Chemical Letters》 2026年第1期602-605,共4页
As an important class of phenanthroline derivatives containing soft N and hard O donor atoms,the laborious syntheses of unsymmetrical 1,10-phenanthroline-derived diamide ligands(DAPhen) have hindered its extensive stu... As an important class of phenanthroline derivatives containing soft N and hard O donor atoms,the laborious syntheses of unsymmetrical 1,10-phenanthroline-derived diamide ligands(DAPhen) have hindered its extensive study.In this work,we first report a convenient synthetic method for the construction of DAPhen using Friedländer reaction by two facile steps(vs.previous 12 steps).A variety of DAPhen ligands are readily available,especially unsymmetrical ones,which give us a platform to systematically study the substituent effect on f-block elements extraction performance.The performance of unsymmetrical extractants is experimentally confirmed to falls between that of their corresponding symmetrical extractants by extracting UO_(2)^(2+) as the representative f-block element.This work provides a direct and versatile method to synthesize symmetrical and unsymmetrical DAPhen,which paves way for the investigations on their coordination properties with metal ions and other applications. 展开更多
关键词 Phenanthroline diamide ligand Friedlander reaction UNSYMMETRICAL SYMMETRICAL Solvent extraction
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Cutting-edge aminated conjugated microporous poly(aniline)s enabled high-performance membrane for seawater uranium extraction
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作者 Xiaoxia Ye Bingqing Huang +7 位作者 Xueying Chen Yaping Wang Zhihong Zheng Yifan Liu Yuancai Lv Chunxiang Lin Jian Huang Jie Chen 《Green Energy & Environment》 2026年第1期181-194,共14页
The extraction of uranium from seawater via membrane adsorption is a promising strategy for ensuring a long-term supply of uranium and the sustainability of nuclear energy.However,this approach has been hindered by th... The extraction of uranium from seawater via membrane adsorption is a promising strategy for ensuring a long-term supply of uranium and the sustainability of nuclear energy.However,this approach has been hindered by the longstanding challenge of identifying sustainable membrane materials.In response,we propose a prototypal hybridization strategy to design a novel series of aminated conjugated microporous polymer(CMPN)@collagen fiber membrane(COLM).These sustainable and low-cost membrane materials allow a rapid and high-affinity kinetic to capture 90%of the uranium in just 30 min from 50 ppm with a high selectivity of Kd>105 mL·g^(−1).They also afford a robustly reusable adsorption capacity as high as 345 mg·g^(−1)that could harvest 1.61 mg·g^(−1)of uranium in a short 7-day real marine engineering in Fujian Province,even though suffered from very low uranium concentration of 3.29μg·L^(−1)and tough influence of salts such as 10.77 g·L^(−1)of Na^(+),1.75μg·L^(−1)of VO_(3)^(−)etc.in the rough seas.The structural evidence from both experimental and theoretical studies confirmed the formation of favorable chelating motifs from the amino group on CMPN-COLM,and the intensification by the synergistic effect from the size-sieving action of CMPN and the capillary inflow effect of COLM. 展开更多
关键词 Conjugated microporous polymer Collagen fiber MEMBRANE Seawater Uranium extraction
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Enhanced Multi-Scale Feature Extraction Lightweight Network for Remote Sensing Object Detection
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作者 Xiang Luo Yuxuan Peng +2 位作者 Renghong Xie Peng Li Yuwen Qian 《Computers, Materials & Continua》 2026年第3期2097-2118,共22页
Deep learning has made significant progress in the field of oriented object detection for remote sensing images.However,existing methods still face challenges when dealing with difficult tasks such as multi-scale targ... Deep learning has made significant progress in the field of oriented object detection for remote sensing images.However,existing methods still face challenges when dealing with difficult tasks such as multi-scale targets,complex backgrounds,and small objects in remote sensing.Maintaining model lightweight to address resource constraints in remote sensing scenarios while improving task completion for remote sensing tasks remains a research hotspot.Therefore,we propose an enhanced multi-scale feature extraction lightweight network EM-YOLO based on the YOLOv8s architecture,specifically optimized for the characteristics of large target scale variations,diverse orientations,and numerous small objects in remote sensing images.Our innovations lie in two main aspects:First,a dynamic snake convolution(DSC)is introduced into the backbone network to enhance the model’s feature extraction capability for oriented targets.Second,an innovative focusing-diffusion module is designed in the feature fusion neck to effectively integrate multi-scale feature information.Finally,we introduce Layer-Adaptive Sparsity for magnitude-based Pruning(LASP)method to perform lightweight network pruning to better complete tasks in resource-constrained scenarios.Experimental results on the lightweight platform Orin demonstrate that the proposed method significantly outperforms the original YOLOv8s model in oriented remote sensing object detection tasks,and achieves comparable or superior performance to state-of-the-art methods on three authoritative remote sensing datasets(DOTA v1.0,DOTA v1.5,and HRSC2016). 展开更多
关键词 Deep learning object detection feature extraction feature fusion remote sensing
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Design and experimental validation of a low-impact wing locking/release mechanism based on energy conversion strategy
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作者 Yanbing Wang Honghao Yue +5 位作者 Jun Wu Xueting Pan Fei Yang Yong Zhao Jicheng Liu Xue Bai 《Defence Technology(防务技术)》 2026年第1期241-256,共16页
Conventional locking/release mechanisms often face challenges in aircraft wing separation processes,such as excessive impact loads and insufficient synchronization.These may cause structural damage to the airframe or ... Conventional locking/release mechanisms often face challenges in aircraft wing separation processes,such as excessive impact loads and insufficient synchronization.These may cause structural damage to the airframe or attitude instability,seriously compromising mission reliability.To address this engineering challenge,this paper proposes a multi-point low-impact locking/release mechanism based on the mobility model and energy conversion strategy.Through establishing a DOF constraint framework system,this paper systematically analyzes the energy transfer and conversion characteristics during the wing separation process,reveals the generation mechanism of impact loads,and conducts research on low-impact design based on energy conversion strategy.Building on this foundation,a single-point locking/release mechanism employing parallel trapezoidal key shaft structure was designed,which increases frictional contact time and reduces the energy release rate,thereby achieving low-impact characteristics.The mechanism's performance was validated through physical prototype development and systematic functional testing(including unlocking force,synchronization,and impact tests).Experimental results demonstrate:(1)Under 14 kN preload condition,the maximum unlocking force was only 92.54 N,showing a linear relationship with preload that satisfies the"strong-connection/weak-unlock"design requirement;(2)Wing separation was completed within 46 ms,with synchronization time difference among three separation mechanisms stably controlled within 12-14 ms,proving rapid and reliable operation;(3)The unlocking impact acceleration ranged between 26 and 73 g,below the 100 g design limit,confirming the effectiveness of the energy conversion strategy.The proposed low-impact locking/release mechanism design method based on energy conversion strategy resolves the traditional challenges of high impact and synchronization deficiencies.The synergistic optimization mechanism of"structural load reduction and performance improvement"provides a highly reliable technical solution for wing separable mechanisms while offering novel design insights for wing connection/separation systems engineering. 展开更多
关键词 Hypersonic vehicle Energy conversion strategy Low-impact Wing separation Locking/release mechanism
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LLM-KE: An Ontology-Aware LLM Methodology for Military Domain Knowledge Extraction
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作者 Yu Tao Ruopeng Yang +3 位作者 Yongqi Wen Yihao Zhong Kaige Jiao Xiaolei Gu 《Computers, Materials & Continua》 2026年第1期2045-2061,共17页
Since Google introduced the concept of Knowledge Graphs(KGs)in 2012,their construction technologies have evolved into a comprehensive methodological framework encompassing knowledge acquisition,extraction,representati... Since Google introduced the concept of Knowledge Graphs(KGs)in 2012,their construction technologies have evolved into a comprehensive methodological framework encompassing knowledge acquisition,extraction,representation,modeling,fusion,computation,and storage.Within this framework,knowledge extraction,as the core component,directly determines KG quality.In military domains,traditional manual curation models face efficiency constraints due to data fragmentation,complex knowledge architectures,and confidentiality protocols.Meanwhile,crowdsourced ontology construction approaches from general domains prove non-transferable,while human-crafted ontologies struggle with generalization deficiencies.To address these challenges,this study proposes an OntologyAware LLM Methodology for Military Domain Knowledge Extraction(LLM-KE).This approach leverages the deep semantic comprehension capabilities of Large Language Models(LLMs)to simulate human experts’cognitive processes in crowdsourced ontology construction,enabling automated extraction of military textual knowledge.It concurrently enhances knowledge processing efficiency and improves KG completeness.Empirical analysis demonstrates that this method effectively resolves scalability and dynamic adaptation challenges in military KG construction,establishing a novel technological pathway for advancing military intelligence development. 展开更多
关键词 Knowledge extraction natural language processing knowledge graph large language model
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Recycling of High-Purity Lithium Metal from Waste Battery by Photoelectrochemical Extraction at Ultralow Overall Potential
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作者 Longfei Yang Chao Huang +3 位作者 Yanhong Lyu Dawei Chen Aibin Huang Jianyun Zheng 《Nano-Micro Letters》 2026年第4期371-388,共18页
To ease the scarcity of lithium(Li)resource and cut down on environmental pollution,an efficient,selective,inexpensive and sustainable Li recycling process from waste batteries is needed,which is yet to be achieved.He... To ease the scarcity of lithium(Li)resource and cut down on environmental pollution,an efficient,selective,inexpensive and sustainable Li recycling process from waste batteries is needed,which is yet to be achieved.Here,we report a low-potential photoelectrochemical(PEC)system that selectively and efficiently extracts Li metals from multi-cation electrolytes under 1 sun illumination.Based on the difference of redox potential,we can get rid of the disturbance of other cations(i.e.,Fe,Co and Ni ions)by a bias-free PEC device to realize the extraction of high-purity Li metals on a coplanar Si-based photocathode-TiO_(2) photoanode tandem device at 2 V of applied bias(far less than the redox potentials of Li^(+)/Li).In such system,the extraction rate of Li metals(purity>99.5%)exceeds 1.35 g h^(-1)m^(-2)with 90%of Faradaic efficiency.Long-term experiments,different electrode/electrolyte tests,and various price assessments further demonstrate the stability,compatibility and economy of PEC extraction system,enabling a solar-driven pathway for the recycling of critical metal resources. 展开更多
关键词 Photoelectrochemical method Lithium metals Waste batteries Ultralow-potential device Selective and efficient extraction
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Synergistic lock-anchor engineered diketopyrrolopyrrole-COFs for efficient photocatalytic uranium extraction
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作者 Fengtao Yu Xiaolong Zhang +5 位作者 Jie Xu Guihong Wu Huiying Lei Zhiwu Yu Jianding Qiu Jianli Hua 《Journal of Energy Chemistry》 2026年第1期284-293,I0007,共11页
As a key low-carbon energy source,nuclear power plays a vital role in the global transition toward sustainable energy.Photocatalytic uranium extraction from seawater(UES)offers a promising solution to ensure long-term... As a key low-carbon energy source,nuclear power plays a vital role in the global transition toward sustainable energy.Photocatalytic uranium extraction from seawater(UES)offers a promising solution to ensure long-term uranium supply but is challenged by ultra-low uranium concentrations and ion interference.To overcome these issues,we design three diketopyrrolopyrrole-based covalent organic frameworks(COFs)via a synergisticπ-extended lock and carboxyl-functionalized anchor molecular engineering strategy.Among them,TPy-DPP-COF features a covalently lockedπ-conjugated structure that enhances planarity,optimizes energy alignment,and minimizes exciton binding energy,thereby promoting charge transfer and suppressing recombination.Concurrently,carboxyl groups enable uranyl-specific coordination and create local electric fields to facilitate charge separation.These features contribute to the outstanding performance of TPy-DPP-COF,which achieves a high uranium adsorption capacity of 16.33 mg g−1 in natural seawater under irradiation,with only 29.3%capacity loss after 10 cycles,surpassing industrial benchmarks.Density functional theory(DFT)calculations and experimental studies reveal a synergistic photocatalysis-adsorption pathway,with DPP units acting as active sites for uranium reduction.This work highlights a molecular design strategy for developing efficient COF-based photocatalysts for practical marine uranium recovery. 展开更多
关键词 DIKETOPYRROLOPYRROLE Covalent organic frameworks Exciton binding energy Photocatalytic uranium extraction Synergistic effect
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Long-term outcomes following lens extraction surgery in acute primary angle closure
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作者 Yi-Ning Guo Jing Ding +3 位作者 Hao-Ran Ai Xin-Zuo Zhou Xue-Min Li Chun Zhang 《International Journal of Ophthalmology(English edition)》 2026年第2期281-290,共10页
AIM:To investigate the long-term outcomes in acute primary angle closure(APAC)patients treated with lens extraction(LE)surgery and to identify risk factors for glaucomatous optic neuropathy(GON).METHODS:In this longit... AIM:To investigate the long-term outcomes in acute primary angle closure(APAC)patients treated with lens extraction(LE)surgery and to identify risk factors for glaucomatous optic neuropathy(GON).METHODS:In this longitudinal observational study,detailed medical histories of APAC patients and comprehensive ophthalmic examinations at final followup were collected.Logistic regression analysis was performed to identify predictors of blindness.Univariate and multivariate linear regression analyses were conducted to determine risk factors associated with visual outcomes.RESULTS:This study included 39 affected eyes of 31 subjects(26 females)with an average age of 74.1±8.0y.At 6.7±4.2y after APAC attack,2(5.7%)eyes had bestcorrected visual acuity(VA)worse than 3/60.Advanced glaucomatous visual field loss was observed in 15(39.5%)affected eyes and 5(25.0%)fellow eyes.Nine affected eyes(23.7%)had GON,and 11(28.9%)were blind.Six(15.4%)affected eyes and 2(9.1%)fellow eyes had suspicious progression.A significantly higher blindness rate in factory workers compared to office workers.Logistic regression identified that worse VA at attack(OR 10.568,95%CI 1.288-86.695;P=0.028)and worse early postoperative VA(OR 13.214,95%CI 1.157-150.881;P=0.038)were risk factors for blindness.Multivariate regression showed that longer duration of elevated intraocular pressure(P=0.004)and worse early postoperative VA(P=0.009)were associated with worse visual outcomes.CONCLUSION:Despite LE surgery,some APAC patients experience continued visual function deterioration.Lifelong monitoring is necessary.Target pressure and progression rates should be re-evaluated during follow-up. 展开更多
关键词 acute primary angle closure lens extraction surgery long-term follow-up visual impairment glaucomatous optic neuropathy
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Acid Release from an Acid Sulfate Soil Sample Under Successive Extractions with Different Extractants 被引量:5
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作者 C.LIN M.M.ISLAM 《Pedosphere》 SCIE CAS CSCD 2000年第3期221-228,共8页
An acid sulfate soil sample was successively extracted with deionized water, 1 mol L-1 KCl and 0.000 5 mol L-l Ca(OH)2 solutions. The results showed that only very small amounts of acidity were extracted by deionized ... An acid sulfate soil sample was successively extracted with deionized water, 1 mol L-1 KCl and 0.000 5 mol L-l Ca(OH)2 solutions. The results showed that only very small amounts of acidity were extracted by deionized water, possibly through slow jarosite hydrolysis. Acid release through jarosite hydrolysis was greatly enhanced by Ca(OH)2 extraction at the expense of the added OH- being neutralized by the acid released. Successive extraction of the sample with KCl removed the largest amounts of acidity from the sample. However, it is likely that the major form of acidity released by KCl extraction was exchangeable acidity. The results also show the occurrence of low or non charged Al and Fe species in water and Ca(OH)2 extracts after first a few extractions. It appears that such a phenomenon was related to a decreasing EC value with increasing number of extractions. 展开更多
关键词 acid release acid sulfate soil successive extractio`
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A comparison between heavy metals released from soil and its efficient speciation extracted by sequential extraction procedure 被引量:5
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作者 ZHANG Hui 《Chinese Journal Of Geochemistry》 EI CAS 2008年第1期36-40,共5页
A simulating experiment was carried out on the interaction between natural precipitation and soil. The results demonstrated that the contents of heavy metals (V, Co, Cr, and Ni) released from soil into the solution un... A simulating experiment was carried out on the interaction between natural precipitation and soil. The results demonstrated that the contents of heavy metals (V, Co, Cr, and Ni) released from soil into the solution under Earth’s surface conditions are higher than the contents of those metals bonded to exchangeable species, which were extracted by sequential extraction procedure recommended by Tessier and others in 1979. It is demonstrated that the metals bonded to other 3 species (carbonate, Fe-Mn oxide, and organic matter) except those bonded to the ex- changeable species in efficient speciation can be released under the Earth’s surface conditions, when pH=4 in the reaction system, and the higher correlation coefficient indicated that the concentrations of heavy metals released from soil into the solution vary approximately with reaction time in terms of index regulations. 展开更多
关键词 重金属 土壤 物种 测定方法
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基于改进HOLD&RELEASE机制的变电站通信流量调度
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作者 尼俊红 刘含磊 +3 位作者 周飞飞 马涛 管荑 高会生 《科学技术与工程》 北大核心 2025年第26期11286-11293,共8页
随着变电站智能化的不断演进,站内通信网络流量激增,而与一次设备关联的业务又有严格的实时性要求,这对通信流量的综合调度提出了新的挑战。时间敏感网络(time-sensitive networking,TSN)技术能够保障变电站高可靠低时延业务传输需求,... 随着变电站智能化的不断演进,站内通信网络流量激增,而与一次设备关联的业务又有严格的实时性要求,这对通信流量的综合调度提出了新的挑战。时间敏感网络(time-sensitive networking,TSN)技术能够保障变电站高可靠低时延业务传输需求,近年来备受关注。首先,对TSN技术中的HOLD&RELEASE机制“保护带”带宽资源有效利用问题进行研究,通过重新设定“保护带”内帧传输条件,改进HOLD&RELEASE机制,实现带宽资源的动态利用;然后,结合IEEE Std 802.3br-2016标准,给出改进后HOLD&RELEASE机制的实现过程。最后,通过仿真算例验证了所提算法的可行性和有效性。仿真结果表明,改进后的HOLD&RELEASE机制在不产生任何额外开销的条件下,可有效提高变电站内通信网络的带宽利用率。 展开更多
关键词 时间敏感网络 HOLD&release机制 变电站通信网 流量调度
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Application of Kinetic Models in Describing Soil Potassium Release Characteristics and Their Correlations with Potassium Extracted by Chemical Methods 被引量:8
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作者 A. R. HOSSEINPUR H. R. MOTAGHIAN 《Pedosphere》 SCIE CAS CSCD 2013年第4期482-492,共11页
Potassium (K) release characteristics in soil play a significant role in supplying available K. Information on K-release characteristics in soils of central Iran is limited. The objectives of this study were to dete... Potassium (K) release characteristics in soil play a significant role in supplying available K. Information on K-release characteristics in soils of central Iran is limited. The objectives of this study were to determine K release characteristics and correlations of K release rate constants with K extracted by different chemical methods in surface soils of ten calcareous soils of central Iran. The kinetics of K release in the soils was determined by successive extraction with 0.01 mol L-1 CaC12 in a period of 2-2017 h at 25±1℃. Soil K was extracted by distilled water, 0.5 mol L-1 MgNO3, 0.002 mol L-1 SrC12, 0.1 mol L-1 BaC12, 0.01 mol L-1 CaC12, 1 mol L-1 NaC1, 1 mol L-1 boiling HNO3, 1 mol L-1 NH4OAC, Mehlich 1, 0.002 mol L-1 SrC12 + 0.05 mol L-1 citric acid, and ammonium bicarbonate-diethylenetriamine pentaacetic acid (AB-DTPA). A plot of cumulative amounts of K released showed a discontinuity in slope at 168 h. Thus, two equations were applied to two segments of the total reaction time (2-168 and 168-2 017 h). Cumulative amounts of K released ranged from 55 to 299 mg kg-1 in 2-168 h and from 44 to 119 mg kg-1 in 168-2 017 h. Release kinetics of K in the two time segments conformed fairly well to parabolic diffusion, simplified Elovich, and power function models. There was a wide variation in the K release rate constants. Increasingly higher average concentrations of soil K were extracted by distilled water, Mehlich 1, SrC12, CaC12, SrC12 + citric acid, AB-DTPA, MgNO3, NaCI, NH4OAc, BaCI2, and HNO3. Potassium release rate constants were significantly correlated with K extracted. The results of this study showed that information obtained from mathematical modeling in two reaction time segments can help to estimate the K-supplying power of soils. 展开更多
关键词 chemical extraction calcareous soils mathematical modeling release rate constant time segments
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Construction of a Maritime Knowledge Graph Using GraphRAG for Entity and Relationship Extraction from Maritime Documents 被引量:3
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作者 Yi Han Tao Yang +2 位作者 Meng Yuan Pinghua Hu Chen Li 《Journal of Computer and Communications》 2025年第2期68-93,共26页
In the international shipping industry, digital intelligence transformation has become essential, with both governments and enterprises actively working to integrate diverse datasets. The domain of maritime and shippi... In the international shipping industry, digital intelligence transformation has become essential, with both governments and enterprises actively working to integrate diverse datasets. The domain of maritime and shipping is characterized by a vast array of document types, filled with complex, large-scale, and often chaotic knowledge and relationships. Effectively managing these documents is crucial for developing a Large Language Model (LLM) in the maritime domain, enabling practitioners to access and leverage valuable information. A Knowledge Graph (KG) offers a state-of-the-art solution for enhancing knowledge retrieval, providing more accurate responses and enabling context-aware reasoning. This paper presents a framework for utilizing maritime and shipping documents to construct a knowledge graph using GraphRAG, a hybrid tool combining graph-based retrieval and generation capabilities. The extraction of entities and relationships from these documents and the KG construction process are detailed. Furthermore, the KG is integrated with an LLM to develop a Q&A system, demonstrating that the system significantly improves answer accuracy compared to traditional LLMs. Additionally, the KG construction process is up to 50% faster than conventional LLM-based approaches, underscoring the efficiency of our method. This study provides a promising approach to digital intelligence in shipping, advancing knowledge accessibility and decision-making. 展开更多
关键词 Maritime Knowledge Graph GraphRAG Entity and Relationship extraction Document Management
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Review on micro-mechanism of forming emulsification during rare earth extraction by acidic extractants 被引量:2
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作者 Jie Liu Yuxiu Zhao +6 位作者 Zhirong Wang Minghui Jia Wenxiang Xia Guizhi Wu Wenda Guo Ru'an Chi Kun Huang 《Journal of Rare Earths》 2025年第1期9-20,I0001,共13页
Solvent extraction is the main method used to separate and purify rare earth elements.In the process of rare earths extraction,emulsification often generated due to the instability of the aqueous and organic phases or... Solvent extraction is the main method used to separate and purify rare earth elements.In the process of rare earths extraction,emulsification often generated due to the instability of the aqueous and organic phases or improper operating conditions.Once emulsification occurs,it would not only lead to low rare earths recovery efficiency,small product quantities,high production costs and the losing of extractant and rare earth resources,but also result in serious environmental pollution.Therefore,it is very important to study the micro-mechanisms of emulsification and establish new methods to prevent emulsification at the source.In this paper,possible factors resulting in emulsification,such as the compositions and properties of the organic and aqueous phases,the operating conditions of the rare earths extraction are reviewed.The micro-mechanisms of emulsification are summarized basing on the microscopic structures in the bulk phase,aggregations of the extractants at the organic-aqueous interface,spectral characterizations and computational simulations.On this basis,new formation mechanisms are proposed for emulsification.Preliminary explorations are employed to verify the correctness of these new viewpoints.Finally,future directions for studies of the emulsification micro-mechanism are proposed.This study provides a theoretical basis for further understanding the micro-mechanisms of interfacial instability resulting in emulsification in the process of rare earths extraction. 展开更多
关键词 extraction Rare earths EMULSIFICATION Mechanism Interface
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Cement-mortar lining failure and metal release caused by electrochemical corrosion of ductile iron pipes in drinking water distribution systems 被引量:2
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作者 Hao Guo Rui Wang +5 位作者 Menghan Jiang Yimei Tian Yapeng Jin Weigao Zhao Chenwan Wang Jianhua Yin 《Journal of Environmental Sciences》 2025年第6期488-502,共15页
The electrochemical corrosion of ductile pipes(DPs)in drinking water distribution systems(DWDS)has a crucial impact on cement-mortar lining(CML)failure and metal release,potentially leading to drinking water quality d... The electrochemical corrosion of ductile pipes(DPs)in drinking water distribution systems(DWDS)has a crucial impact on cement-mortar lining(CML)failure and metal release,potentially leading to drinking water quality deterioration and posing a risk to public health.An in-situ scanning vibrating electrode technique(SVET)with micron-scale resolution,microscopic scale detection and water quality analysis were used to investigate the corrosion behavior and metal release from DPs throughout the whole CML failure process.Metal pollutants release occurred at three different stages of CML failure process,and there are potential risks of water quality deterioration exceeding the maximum allowable levels set by national standards in the partial failure stage and lining peeling stage.Furthermore,the effects of water chemistry(Cl^(−),SO_(4)^(2−),NO_(3)−,and Ca^(2+))on corrosion scale growth and iron release activity,were investigated during the CML partial failure stage.Results showed that the CML failure process in DPs was accelerated by the autocatalysis of localized corrosion.Cl^(−)was found to damage the uncorroded metal surface,while SO_(4)^(2−)mainly dissolved the corrosion scale surface,increasing iron release.Both the oxidation of NO_(3)−and selective sedimentation of Ca2+were found to enhance the stability of corrosion scales and inhibit iron release. 展开更多
关键词 Water distribution system Cement mortar lining Corrosion Metal release SVET
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Numerical simulation of heat release performance of filling body under condition of heat extracted by fluid flowing in buried tube 被引量:6
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作者 ZHANG Xiao-yan LIU Li +2 位作者 LIU Lang LIU Lu JIA Yu-hang 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第8期2160-2174,共15页
It is the basic requirement of the synergetic exploitation of deep mineral resources and geothermal resources to arrange the heat transfer tube in filling body. The heat release performance of filling body directly im... It is the basic requirement of the synergetic exploitation of deep mineral resources and geothermal resources to arrange the heat transfer tube in filling body. The heat release performance of filling body directly impacts on the exploiting efficiency of geothermal energy. Based on heat transfer theory, a three-dimensional unsteady heat transfer model of filling body is established by using FLUENT simulation software. Taking the horizontal U-shaped buried pipe as research object, the variation of temperature field in filling body around buried pipe is analyzed during the heat release process of filling body;the initial temperature of filling body, the diameter of buried pipe, the inlet temperature and inlet velocity of heat transfer fluid influencing of coupling heat transfer, which exists between heat transfer fluid and surrounding filling body within a certain axial distance of buried tube, and influencing of temperature difference between inlet and outlet of heat transfer fluid and on heat transfer performance of filling body are also discussed. It not only lays a theoretical foundation for the synergetic exploitation of mineral resources and geothermal energy in deep mines, but also provides a reference basis for the arrangement of buried pipes in filling body as well as the selection of working conditions for heat transfer fluid. 展开更多
关键词 filling body buried pipe heat transfer fluid heat release performance
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Chinese satellite frequency and orbit entity relation extraction method based on dynamic integrated learning 被引量:2
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作者 Yuanzhi He Zhiqiang Li Zheng Dou 《Digital Communications and Networks》 2025年第3期787-794,共8页
Given the scarcity of Satellite Frequency and Orbit(SFO)resources,it holds paramount importance to establish a comprehensive knowledge graph of SFO field(SFO-KG)and employ knowledge reasoning technology to automatical... Given the scarcity of Satellite Frequency and Orbit(SFO)resources,it holds paramount importance to establish a comprehensive knowledge graph of SFO field(SFO-KG)and employ knowledge reasoning technology to automatically mine available SFO resources.An essential aspect of constructing SFO-KG is the extraction of Chinese entity relations.Unfortunately,there is currently no publicly available Chinese SFO entity Relation Extraction(RE)dataset.Moreover,publicly available SFO text data contain numerous NA(representing for“No Answer”)relation category sentences that resemble other relation sentences and pose challenges in accurate classification,resulting in low recall and precision for the NA relation category in entity RE.Consequently,this issue adversely affects both the accuracy of constructing the knowledge graph and the efficiency of RE processes.To address these challenges,this paper proposes a method for extracting Chinese SFO text entity relations based on dynamic integrated learning.This method includes the construction of a manually annotated Chinese SFO entity RE dataset and a classifier combining features of SFO resource data.The proposed approach combines integrated learning and pre-training models,specifically utilizing Bidirectional Encoder Representation from Transformers(BERT).In addition,it incorporates one-class classification,attention mechanisms,and dynamic feedback mechanisms to improve the performance of the RE model.Experimental results show that the proposed method outperforms the traditional methods in terms of F1 value when extracting entity relations from both balanced and long-tailed datasets. 展开更多
关键词 Knowledge graph Relation extraction One-class classification Satellite frequency and orbit resources BERT
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