It is very significant to recover rare earths （REs） from wet-process phosphoric acid, in terms of extraction rate and selectivity, the current carrier di（2-ethlhexly） phosphate （D2EHPA） out there is still inferi...It is very significant to recover rare earths （REs） from wet-process phosphoric acid, in terms of extraction rate and selectivity, the current carrier di（2-ethlhexly） phosphate （D2EHPA） out there is still inferior. Based on this question, our team modified D2EHPA to synthesize new extractants. This paper presents a comprehensive study on the extraction of rare earth ions （RE3＋） from phosphate leach solution using emulsion liquid membrane （ELM） in concentrated nitric acid medium. The ELM system is made up of （RO）2P（O）OPh-COOH as carrier, polyisocrotyl succinimide （T154） as surfactant, sulfonated kerosene as diluent, phosphoric acid （H3PO4） as stripping solution. Different chemical parameters such as type and concentration of carrier, surfactant, stripping solution, volume ratio of oil phase to internal phase, and volume ratio of emulsion ratio to external phase were analyzed. The extraction of RE^3＋ was evaluated by the yield of extraction. In addition, the demulsification process was also investigated. The proposed method of ELM using （RO）2P（O）OPh-COOH as carrier can he expected to provide an efficient, simplify operation, and facilitated method for extractine RE^3＋.展开更多
A model GM （grey model） （1,1） for forecasting the rate of copper extraction during the bioleaching of primary sulphide ore was established on the basis of the mathematical theory and the modeling process of grey s...A model GM （grey model） （1,1） for forecasting the rate of copper extraction during the bioleaching of primary sulphide ore was established on the basis of the mathematical theory and the modeling process of grey system theory. It was used for forecasting the rate of copper extraction from the primary sulfide ore during a laboratory microbial column leaching experiment. The precision of the forecasted results were examined and modified via ＂posterior variance examination＂. The results show that the forecasted values coincide with the experimental values. GM （1,1） model has high forecast accuracy; and it is suitable for simulation control and prediction analysis of the original data series of the processes that have grey characteristics, such as mining, metallurgical and mineral processing, etc. The leaching rate of such copper sulphide ore is low. The grey forecasting result indicates that the rate of copper extraction is approximately 20% even after leaching for six months.展开更多
The dynamic analysis and optimal design of reactive extraction are challenging due to high nonlinearity of model equations and tough decision of judging criteria. In this work, a dynamic rate-based method is developed...The dynamic analysis and optimal design of reactive extraction are challenging due to high nonlinearity of model equations and tough decision of judging criteria. In this work, a dynamic rate-based method is developed on g PROMS platform to get easy access to the solutions of reactive extraction with phase splitting. Based on rigorous criteria, dynamic analysis from initial state to final equilibrium(e.g., evolution of phase composition, mass transfer rate and reaction rate) and optimal design of operating conditions(e.g., extractant dosage and feed molar ratio) are achieved. To illustrate the method, the esterification of n-hexyl acetate is taken as an example. The approach proves to be reliable in the analysis and optimization of the exemplified system, which provides instructive reference for further process design and simulation of reactive extraction.展开更多
Factors directly affecting the extraction rate of the piles pulled out by a vibratory pulling system are summarized and classified into five categories(excitation force,resistance,vibration amplitude,pile plumbness ke...Factors directly affecting the extraction rate of the piles pulled out by a vibratory pulling system are summarized and classified into five categories(excitation force,resistance,vibration amplitude,pile plumbness keeping,and slowing down at the later stage) from the mechanics and engineering practice.Field tests on steel sheet piles extracted by vibratory technique in different soil conditions are conducted to ascertain how these factors affect the extraction rate of a pile with regard to three major actors of vibratory pile pulling:the pile to be extracted,the selected pulling system,and the imposed soil conditions.The extraction rates of three different sheet pile types(having up to four different lengths) pulled out by two different vibratory pulling systems are documented.The piles with different lengths and types,pulled out with or without a clutch,have different extraction rates.The working parameters governing the vibratory hammer,such as excitation force and vibration amplitude,exert significant influences on the rate of pile extraction,especially in the early stages of up-lift process.The extraction rate of the piles driven in different soil conditions is uniform because different extraction resistances mainly refer to shaft friction.The properties of the pile-soil interface influence the extraction rate of the piles,and the extraction rate decreases with the time for which the piles have been buried in the earth.展开更多
In this paper,the method of extracting guidance information such as the line-of-sight(LOS)rates under the anti-infrared decoy state for the roll-pitch seeker is researched.Coordinate systems which are used to describe...In this paper,the method of extracting guidance information such as the line-of-sight(LOS)rates under the anti-infrared decoy state for the roll-pitch seeker is researched.Coordinate systems which are used to describe the angles transform are defined.The LOS angles reconstruction model of the roll-pitch seeker in inertial space is established.A Kalman filter model for extracting LOS rates of the roll-pitch seeker is proposed.In this model,the target performs constant acceleration(CA)model maneuvers.The error model of LOS rates extraction under infrared decoy state is established.Several existing methods of extracting LOS rates under anti-infrared decoy state are listed in this paper.Different from the existing methods,a novel method that uses extrapolated values of target accelerations as filter measurements is proposed to solve the guidance information extraction problem under the anti-infrared decoy state.Numerical simulations are conducted to verify the effectiveness of the proposed method under different target maneuvering models such as the CA model,the CA extended model and the singer model.The simulation results show that the proposed method of extracting guidance information such as LOS rates for the rollpitch seeker under the anti-infrared decoy state is effective.展开更多
基金Project supported by National Natural Science Foundation of China(21461005)"Top Hundred Talents" Program of Science and Technology Development of Guizhou Province([2016]5658)
文摘It is very significant to recover rare earths （REs） from wet-process phosphoric acid, in terms of extraction rate and selectivity, the current carrier di（2-ethlhexly） phosphate （D2EHPA） out there is still inferior. Based on this question, our team modified D2EHPA to synthesize new extractants. This paper presents a comprehensive study on the extraction of rare earth ions （RE3＋） from phosphate leach solution using emulsion liquid membrane （ELM） in concentrated nitric acid medium. The ELM system is made up of （RO）2P（O）OPh-COOH as carrier, polyisocrotyl succinimide （T154） as surfactant, sulfonated kerosene as diluent, phosphoric acid （H3PO4） as stripping solution. Different chemical parameters such as type and concentration of carrier, surfactant, stripping solution, volume ratio of oil phase to internal phase, and volume ratio of emulsion ratio to external phase were analyzed. The extraction of RE^3＋ was evaluated by the yield of extraction. In addition, the demulsification process was also investigated. The proposed method of ELM using （RO）2P（O）OPh-COOH as carrier can he expected to provide an efficient, simplify operation, and facilitated method for extractine RE^3＋.
基金supported by the National Key Basic Research and Development Programme of China(No.2004CB619200)the National Science Foundation for Distinguished Young Scholars of China(No.50325415)the National Natural Science Foundation of China(No.50321402).
文摘A model GM （grey model） （1,1） for forecasting the rate of copper extraction during the bioleaching of primary sulphide ore was established on the basis of the mathematical theory and the modeling process of grey system theory. It was used for forecasting the rate of copper extraction from the primary sulfide ore during a laboratory microbial column leaching experiment. The precision of the forecasted results were examined and modified via ＂posterior variance examination＂. The results show that the forecasted values coincide with the experimental values. GM （1,1） model has high forecast accuracy; and it is suitable for simulation control and prediction analysis of the original data series of the processes that have grey characteristics, such as mining, metallurgical and mineral processing, etc. The leaching rate of such copper sulphide ore is low. The grey forecasting result indicates that the rate of copper extraction is approximately 20% even after leaching for six months.
基金Supported by the National Natural Science Foundation of China(21776074,21576081,2181101120).
文摘The dynamic analysis and optimal design of reactive extraction are challenging due to high nonlinearity of model equations and tough decision of judging criteria. In this work, a dynamic rate-based method is developed on g PROMS platform to get easy access to the solutions of reactive extraction with phase splitting. Based on rigorous criteria, dynamic analysis from initial state to final equilibrium(e.g., evolution of phase composition, mass transfer rate and reaction rate) and optimal design of operating conditions(e.g., extractant dosage and feed molar ratio) are achieved. To illustrate the method, the esterification of n-hexyl acetate is taken as an example. The approach proves to be reliable in the analysis and optimization of the exemplified system, which provides instructive reference for further process design and simulation of reactive extraction.
基金the National Natural Science Foundation of China(Nos.51428901 and 51379122)
文摘Factors directly affecting the extraction rate of the piles pulled out by a vibratory pulling system are summarized and classified into five categories(excitation force,resistance,vibration amplitude,pile plumbness keeping,and slowing down at the later stage) from the mechanics and engineering practice.Field tests on steel sheet piles extracted by vibratory technique in different soil conditions are conducted to ascertain how these factors affect the extraction rate of a pile with regard to three major actors of vibratory pile pulling:the pile to be extracted,the selected pulling system,and the imposed soil conditions.The extraction rates of three different sheet pile types(having up to four different lengths) pulled out by two different vibratory pulling systems are documented.The piles with different lengths and types,pulled out with or without a clutch,have different extraction rates.The working parameters governing the vibratory hammer,such as excitation force and vibration amplitude,exert significant influences on the rate of pile extraction,especially in the early stages of up-lift process.The extraction rate of the piles driven in different soil conditions is uniform because different extraction resistances mainly refer to shaft friction.The properties of the pile-soil interface influence the extraction rate of the piles,and the extraction rate decreases with the time for which the piles have been buried in the earth.
基金supported by the Key Laboratory of Defense Science and Technology Foundation of Luoyang Electro-optical Equipment Research Institute(6142504200108)。
文摘In this paper,the method of extracting guidance information such as the line-of-sight(LOS)rates under the anti-infrared decoy state for the roll-pitch seeker is researched.Coordinate systems which are used to describe the angles transform are defined.The LOS angles reconstruction model of the roll-pitch seeker in inertial space is established.A Kalman filter model for extracting LOS rates of the roll-pitch seeker is proposed.In this model,the target performs constant acceleration(CA)model maneuvers.The error model of LOS rates extraction under infrared decoy state is established.Several existing methods of extracting LOS rates under anti-infrared decoy state are listed in this paper.Different from the existing methods,a novel method that uses extrapolated values of target accelerations as filter measurements is proposed to solve the guidance information extraction problem under the anti-infrared decoy state.Numerical simulations are conducted to verify the effectiveness of the proposed method under different target maneuvering models such as the CA model,the CA extended model and the singer model.The simulation results show that the proposed method of extracting guidance information such as LOS rates for the rollpitch seeker under the anti-infrared decoy state is effective.
