Molecular tailoring of self-assembled hole-transporting monolayers(SAMs)has been proven as an efficient approach for improving the device performance of inverted perovskite solar cells.Herein,a novel SAM with extended...Molecular tailoring of self-assembled hole-transporting monolayers(SAMs)has been proven as an efficient approach for improving the device performance of inverted perovskite solar cells.Herein,a novel SAM with extended conjugation is designed and synthesized,named NaPh-4PACz.Compared to Ph-4PACz,NaPh-4PACz exhibits a larger adsorption energy with the ITO substrate,enabling the formation of a more uniform and dense film,thereby preventing direct contact between the perovskite and ITO.Additionally,NaPh-4PACz also has a stronger interaction with the perovskite,which can reduce buried interface defects and suppress non-radiative recombination.Consequently,NaPh-4PACz-based devices achieved a power conversion efficiency of 25.48%due to their interfacial“adhesive”ability.Importantly,the stability of the NaPh-4PACz-based devices was significantly improved.展开更多
Increasing the hole expansion ratio is significant for developing high formability parts.Hole expansion tests were carried out on low carbon hot-rolled steel containing 0.11%Ti,0.072%Ti–0.03%Nb and 0.097%Ti–0.059%Nb...Increasing the hole expansion ratio is significant for developing high formability parts.Hole expansion tests were carried out on low carbon hot-rolled steel containing 0.11%Ti,0.072%Ti–0.03%Nb and 0.097%Ti–0.059%Nb,respectively.The effects of microstructure,texture,crack propagation behavior and second phase precipitation behavior on hole expansion ratio were investigated.The precipitation behavior of TiC and(Ti,Nb)C in austenite and ferrite in three groups of steel samples was calculated theoretically.The results showed that the hole expansion ratios of 0.11Ti,0.072Ti–0.03Nb and 0.097Ti–0.059Nb test steels were 51.73%,51.17%and 66.24%following simulated coiling at 600℃,respectively.The microstructure was mainly polygonal ferrite with a small amount of pearlite.The grain refinement of 0.097Ti–0.059Nb test steel and the low texture ratio of{110}//ND improved the hole expansion ratio.The low overall hole expansion ratio was due to the microstructure inhomogeneity.The microstructure uniformity was improved by the quenching and tempering treatment,and the hole expansion ratio of the three test steels was greatly increased.The fastest precipitation temperatures in the austenitic region of 0.11Ti,0.072Ti–0.03Nb and 0.097Ti–0.059Nb test steels were 880,860 and 830℃,while those in the ferrite region were 680,675 and 675℃,respectively.The addition of Nb element increased the volume free energy,so that the critical core size of the nucleation on the dislocation line increased,resulting in the decrease in the fastest precipitation temperature.展开更多
In this work,the influences of surface layer slurry at different temperatures(10℃,14℃,18℃,22℃)on wax patterns deformation,shrinkage,slurry coating characteristics,and the surface quality of the casting were invest...In this work,the influences of surface layer slurry at different temperatures(10℃,14℃,18℃,22℃)on wax patterns deformation,shrinkage,slurry coating characteristics,and the surface quality of the casting were investigated by using a single factor variable method.The surface morphologies of the shell molds produced by different temperatures of the surface(first)layer slurries were observed via electron microscopy.Furthermore,the microscopic composition of these shell molds was obtained by EDS,and the osmotic effect of the slurry on the wax patterns at different temperatures was also assessed by the PZ-200 Contact Angle detector.The forming reasons for the surface cracks and holes of thick and large ZTC4 titanium alloy by investment casting were analyzed.The experimental results show that the surface of the shell molds prepared by the surface layer slurry with a low temperature exhibits noticeable damage,which is mainly due to the poor coating performance and the serious expansion and contraction of wax pattern at low temperatures.The second layer shell material(SiO_(2),Al_(2)O_(3))immerses into the crack area of the surface layer,contacts and reacts with the molten titanium to form surface cracks and holes in the castings.With the increase of the temperature of surface layer slurry,the damage to the shell surface tends to weaken,and the composition of the shell molds'surface becomes more uniform with less impurities.The results show that the surface layer slurry at 22℃is evenly coated on the surface of the wax patterns with appropriate thickness,and there is no surface shell mold rupture caused by sliding slurry after sand leaching.The surface layer slurry temperature is consistent with the wax pattern temperature and the workshop temperature,so there is no damage of the surface layer shell caused by expansion and contraction.Therefore,the shell mold prepared by the surface layer slurry at this temperature has good integrity,isolating the contact between the low inert shell material and the titanium liquid effectively,and the ZTC4 titanium alloy cylinder casting prepared by this shell mold is smooth,without cracks and holes.展开更多
The hole transport layer(HTL)-free carbon-based perovskite solar cells(C-PSCs)are promising for commercialization owing to their excellent operational stability and simple fabrication process.However,the power convers...The hole transport layer(HTL)-free carbon-based perovskite solar cells(C-PSCs)are promising for commercialization owing to their excellent operational stability and simple fabrication process.However,the power conversion efficiencies(PCE)of C-PSCs are inferior to the metal electrode-based devices due to their open-circuit voltage(V_(oc))loss.Herein,time-resolved confocal photoluminescence microscopy reveals that grain boundary defects at the perovskite/carbon interface are very likely to function as nonradiative recombination centers in HTL-free C-PSCs.A versatile additive Li_(2)CO_(3)is used to modify the conformal tin oxide electron transport layer for HTL-free C-PSCs.Li_(2)CO_(3)modification can result in enhanced charge extraction and optimized energy alignment at electron transport layer/perovskite interface,as well as suppressed defects at perovskite top surface due to Li_(2)CO_(3)-induced formation of PbI_(2)crystallites.Such dual interfacial passivation ultimately leads to significantly improved Voc up to 1.142 V,which is comparable to the metal electrode-based devices with HTL.Moreover,a record-high PCE of 33.2%is achieved for Li_(2)CO_(3)-modified C-PSCs under weak light illumination conditions,demonstrating excellent indoor photovoltaic performance.This work provides a practical approach to fabricate low-cost,highly efficient carbon-based perovskite solar cells.展开更多
Strong surface impact will produce strong vibration,which will pose a threat to the safety of nearby buried pipelines and other important lifeline projects.Based on the verified numerical method,a comprehensive numeri...Strong surface impact will produce strong vibration,which will pose a threat to the safety of nearby buried pipelines and other important lifeline projects.Based on the verified numerical method,a comprehensive numerical parameter analysis is conducted on the key influencing factors of the vibration isolation hole(VIH),which include hole diameter,hole net spacing,hole depth,hole number,hole arrangement,and soil parameters.The results indicate that a smaller ratio of net spacing to hole diameter,the deeper the hole,the multi-row hole,the hole adoption of staggered arrangements,and better site soil conditions can enhance the efficiency of the VIH barrier.The average maximum vibration reduction efficiency within the vibration isolation area can reach 42.2%.The vibration safety of adjacent oil pipelines during a dynamic compaction projection was evaluated according to existing standards,and the measurement of the VIH was recommended to reduce excessive vibration.The single-row vibration isolation scheme and three-row staggered arrangement with the same hole parameters are suggested according to different cases.The research findings can serve as a reference for the vibration safety analysis,assessment,and control of adjacent underground facilities under the influence of strong surface impact loads.展开更多
Large-diameter drilling method is a prevalent method for preventing and controlling rock burst,and the spacing between the large-diameter drilling hole and anchoring hole is a critical factor influencing the roadway s...Large-diameter drilling method is a prevalent method for preventing and controlling rock burst,and the spacing between the large-diameter drilling hole and anchoring hole is a critical factor influencing the roadway stability and relief effectiveness.In this study,a mechanical model for optimal matching between the large-diameter drilling hole and anchoring hole was established following the principle of synergistic control.The influence of large-diameter drilling hole diameter on the optimal spacing under the synergistic relief effect was investigated by integrating theoretical analysis,numerical simulation,and field practice.The results suggest that the hole spacing achieved a synergistic effect in a certain range when the optimal hole spacing increased linearly with the hole diameter.For instance,when the anchoring hole diameter was 20 mm,an increase in the aperture ratio from 5 to 10 brought about an increase in the optimal spacing from 0.25 m to 0.45 m.Additionally,the vertical stress between the large-diameter drilling hole and anchor hole increased nonlinearly under the condition of constant pore ratio but varying hole spacing.Both excessively small and excessively large hole spacings were detrimental to the pressure relief effect.In the engineering practice,optimizing the hole spacing from 0.55 m to 0.45 m in the 1208 working face contributed to reducing coal body drilling cuttings and the roadway moving quantity by 33%and 19.2%,respectively.This demonstrates that the pressure relief-support reinforcement synergistic effect should be fully considered in optimization design.展开更多
The complex vibration directly affects the dynamic safety of drill string in ultra-deep wells and extra-deep wells.It is important to understand the dynamic characteristics of drill string to ensure the safety of dril...The complex vibration directly affects the dynamic safety of drill string in ultra-deep wells and extra-deep wells.It is important to understand the dynamic characteristics of drill string to ensure the safety of drill string.Due to the super slenderness ratio of drill string,strong nonlinearity implied in dynamic analysis and the complex load environment,dynamic simulation of drill string faces great challenges.At present,many simulation methods have been developed to analyze drill string dynamics,and node iteration method is one of them.The node iteration method has a unique advantage in dealing with the contact characteristics between drill string and borehole wall,but its drawback is that the calculation consumes a considerable amount of time.This paper presents a dynamic simulation method of drilling string in extra-deep well based on successive over-relaxation node iterative method(SOR node iteration method).Through theoretical analysis and numerical examples,the correctness and validity of this method were verified,and the dynamics characteristics of drill string in extra-deep wells were calculated and analyzed.The results demonstrate that,in contrast to the conventional node iteration method,the SOR node iteration method can increase the computational efficiency by 48.2%while achieving comparable results.And the whirl trajectory of the extra-deep well drill string is extremely complicated,the maximum rotational speed downhole is approximately twice the rotational speed on the ground.The dynamic torque increases rapidly at the position of the bottom stabilizer,and the lateral vibration in the middle and lower parts of drill string is relatively intense.展开更多
We assume exponential corrections to the entropy of 5D charged Ad S black hole solutions,which are derived within the framework of Einstein-Gauss-Bonnet gravity and nonlinear electrodynamics.Additionally,we consider t...We assume exponential corrections to the entropy of 5D charged Ad S black hole solutions,which are derived within the framework of Einstein-Gauss-Bonnet gravity and nonlinear electrodynamics.Additionally,we consider two distinct versions of 5D charged Ad S black holes by setting the parameters q→0 and k→0(where q represents the charge,and k is the non-linear parameter).We investigate these black holes in the extended phase space,where the cosmological constant is interpreted as pressure,demonstrating the first law of black hole thermodynamics.The focus extends to understanding the thermal stability or instability,as well as identifying first and second-order phase transitions.This exploration is carried out through the analysis of various thermodynamic quantities,including heat capacity at constant pressure,Gibbs free energy(GFE),Helmholtz free energy(HFE),and the trace of the Hessian matrix.In order to visualize phase transitions,identify critical points,analyze stability and provide comprehensive analysis,we have made the contour plot of the mentioned thermodynamic quantities and observed that our results are very consistent.These investigations are conducted within the context of exponentially corrected entropies,providing valuable insights into the intricate thermodynamic behavior of these 5D charged Ad S black holes under different parameter limits.展开更多
Primordial black holes(PBHs) offer a compelling candidate for dark matter. The production of PBHs through well-tested and accepted physical processes is highly worthy of investigation. This work highlights the role of...Primordial black holes(PBHs) offer a compelling candidate for dark matter. The production of PBHs through well-tested and accepted physical processes is highly worthy of investigation. This work highlights the role of turbulences in the very early universe in sustaining intense and persistent fluctuations in energy or mass density,which could provide a natural mechanism for PBH formation in the primordial universe. We analyze the mass range and abundance of PBHs produced in the magnetohydrodynamic turbulence induced by the electroweak phase transition. Remarkably, we find that the mass range of the produced PBHs falls within the most viable“asteroid mass” window from the present-day observations, and within natural parameter regions their abundance can be sufficiently large. These findings suggest that PBHs produced during magnetohydrodynamic turbulence in the very early universe may comprise a dominant part of dark matter.展开更多
The photon region surrounding a black hole is crucial for distant observers to receive the emitted spectrum from its vicinity.This paper investigates the optical features of a regular spinning antide Sitter(AdS)black ...The photon region surrounding a black hole is crucial for distant observers to receive the emitted spectrum from its vicinity.This paper investigates the optical features of a regular spinning antide Sitter(AdS)black hole.These kinds of black holes hold deviation parameter k,and the cosmological constant A including their mass M and spin a.The cosmological parameter depends on the curvature radius by A=-3/l~2.We investigate the structure of geodesics for unstable circular orbits of photons as observed by an observer at specific Boyer-Lindquist coordinates(r_(O),v_(O))in the region between the outer and cosmological horizon,so-called the domain of outer communication.Our investigations include the analysis of three observables from its shadow plot:the black hole shadow radius(R_(s)),the distortion of the black hole(δ_(s)),and shadow area A.With the help of these observables,we calculate the angular diameter of the apparent size of the shadow.The shadows cast by spinning regular spacetimes are smaller compared to those produced by rotating black holes in both general relativity and regular spacetimes.We also calculate the rate at which energy is emitted from the black hole.展开更多
AIM:To evaluate whether fluid-air exchange is an effective treatment for unclosed macular hole(MH)after primary vitrectomy.METHODS:This retrospective study included patients with an unclosed MH within 1–2wk after vit...AIM:To evaluate whether fluid-air exchange is an effective treatment for unclosed macular hole(MH)after primary vitrectomy.METHODS:This retrospective study included patients with an unclosed MH within 1–2wk after vitrectomy.Patients were divided into the vitrectomy,fluid-air exchange,and observation groups according to the secondary treatment.The anatomical outcomes and postoperative visual acuity were recorded.RESULTS:The analysis included 25 eyes in 25 patients(16 females)aged 37–74y(vitrectomy group,n=10;fluid-air exchange group,n=9;observation group,n=6).Closure rate after secondary treatment was 100%in the vitrectomy group,88.9%in the fluid-air exchange group and 33.3%in the observation group.Optical coherence tomography images obtained at the last follow-up revealed that continuity of the external limiting membrane(ELM)was significantly more common(P=0.004)in the fluid-air group(8/9 eyes,88.9%)than in the vitrectomy group(2/10 eyes,20.0%)and that macular morphology was better in the fluid-air group than in the vitrectomy group.No serious complications were observed after secondary treatment.CONCLUSION:Fluid-air exchange is an alternative option to repeat vitrectomy for patients with an unclosed MH after initial vitrectomy with elevated macular edge.展开更多
The gravitational deflection of light signals restricted in the polar-axis plane of a moving Kerr–Newman(KN)black hole with a constant velocity along the polar axis is studied within the second post-Minkowskian(PM)ap...The gravitational deflection of light signals restricted in the polar-axis plane of a moving Kerr–Newman(KN)black hole with a constant velocity along the polar axis is studied within the second post-Minkowskian(PM)approximation.For this purpose,the Lorentz boosting technique is adopted to obtain the exact metric of a moving KN black hole with an arbitrary constant velocity in Kerr–Schild coordinates for the first time.Based on the weak field limit of the exact metric,we then derive the equations of motion of test particles constrained in the polaraxis plane of a moving KN source whose velocity is along the polar axis and collinear with its angular momentum.An iterative technique is utilized subsequently in the calculations of the null deflection angle up to the 2PM order caused by the moving lens,and this deflection angle is found to be spin-independent.Finally,we discuss the influence of the motion of the lens on the gravitational deflection and estimate the possibility of detecting this kinematical effect.Our work might be helpful for future astronomical observations.展开更多
Enhancing the activity of photocatalysts is a critical challenge for improving the photocatalytic degradation of contaminated wastewater.Here,a novel Ce single-atom-doped titanate nanotube photocatalyst(CeH_(2)Ti_(2)O...Enhancing the activity of photocatalysts is a critical challenge for improving the photocatalytic degradation of contaminated wastewater.Here,a novel Ce single-atom-doped titanate nanotube photocatalyst(CeH_(2)Ti_(2)O_(5)·H_(2)O)was successfully synthesized using a onepot solvothermal method.Degradation experiments revealed that the optimal Ce doping ratio was 1.0%.The ultraviolet-visible diffuse reflectance spectroscopy results showed that the bandgap of the Ce-doped sample decreased from 3.02 to 2.87 eV,enhancing the absorption in the visible spectral range.At the same time,the BrunauerEmmett-Teller specific surface area increased from 63.68 to 88.95 m^(2)g^(-1).The 1.0%Ce-H_(2)Ti_(2)O_(5)·H_(2)O(HTC_(1))could degrade 99.04%of 100 mg L-1rhodamine B(RhB)after 40 min of visible-light irradiation.The degradation efficiency decreased by only 21.24%after five cycles.The results of free-radical quenching and electron spin resonance spectroscopy analyses indicated that HTC_(1)achieved efficient degradation of RhB through a direct hole oxidation mechanism.Compared with pure protonated titanate nanotubes(H_(2)Ti_(2)O_(5)·H_(2)O),HTC_(1)had a higher specific surface area,more electron traps,narrower bandgap,longer hole lifetime,and suppressed photogenerated charge recombination rate owing to the Ce single-atom doping.展开更多
The shape of underground chambers in deep mining varies due to their geological environment and intended use,which results in different failure modes under the influence of mining activities.However,the effect of cham...The shape of underground chambers in deep mining varies due to their geological environment and intended use,which results in different failure modes under the influence of mining activities.However,the effect of chamber shape on the mechanism of structural integrity under dynamic load is still unclear.In this paper,granite samples with circular(C),rectangular(R),long ellipse(EL),and short ellipse(ES)holes were prepared.The dynamic mechanical response and cracking mechanism of granite were systematically analyzed using the split Hopkinson pressure bar(SHPB)test system and the hybrid finite and discrete element method(HFDEM).The results indicate that the dynamic strengths of granite with EL and ES represent the maximum and minimum values within the range of close strain rates,respectively.When EL granite is subjected to dynamic load,the axial stress concentration(in the load direction)is weak,and the transverse stress shows relative dispersion,which is the primary reason for its highest dynamic strength.The failure of granite with various holes primarily involves a tensile-shear mixed fracture,with relatively few pure typeⅡcracks.The chamber’s transverse span is the primary factor influencing the distribution range of the fracture area.展开更多
Using the Melnikov method,the phenomenon of thermal chaos under periodic perturbation in the extended phase space of the modified thermodynamics of Kerr-AdS black holes is investigated.On the(P,v)section in the extend...Using the Melnikov method,the phenomenon of thermal chaos under periodic perturbation in the extended phase space of the modified thermodynamics of Kerr-AdS black holes is investigated.On the(P,v)section in the extended phase space,it is shown that temporal chaos will appear in the unstable spinodal region when the perturbation amplitude is larger than critical value δ_(c)^(Pv).We findδ_(c)^(Pv) is monotonically decreasing with respect to the angular momentum parameter a,which implies a large a leads to chaotic behavior more easily under time-periodic thermal perturbation.Similarly,on the(Ω_(H),J)section,we show there exists a critical value δ_(c)^(ΩJ) which depends on the cosmological parameter l=√-3/Λ.When the perturbation amplitude exceeds δ_(c)^(ΩJ),temporal chaos occurs.As l increases,chaos becomes easier.For spatial perturbation,chaos always exists irrespective of perturbation amplitude in both the(P,v)section and(Ω_(H),J)section.展开更多
Active holes outperform photoelectron-mediated oxygen reduction in degrading recalcitrant organics under anaerobic conditions,yet their utilization is limited by rapid charge recombination.This challenge was addressed...Active holes outperform photoelectron-mediated oxygen reduction in degrading recalcitrant organics under anaerobic conditions,yet their utilization is limited by rapid charge recombination.This challenge was addressed through Cu-based yolk-double-shell microspheres(Cu/Cu_(2)O@C-2shell)engineered via heterogeneous contraction and reduction strategies.Work function analyses confirm Schottky junction-driven electron transfer from Cu_(2)O to Cu,generating an internal electric field that suppresses backflow.Density functional theory reveals Cu-mediated enhancement of near-Fermi states(Cu 3d orbitals)and a directional Cu_(2)O→Cu→C electron pathway,spatially isolating holes in Cu_(2)O.Finite-difference time-domain simulations reveal light-induced electric field gradients in the dual-shell architecture:Cu^(0)-mediated localized surface plasmon resonance effect enhances surface field concentration,while hierarchical interfaces create an outward-to-inward gradient,directing electron migration inward and stabilizing oxidative holes at the surface.The optimized(Cu/Cu_(2)O)@C-2shell exhibits 38-fold higher tetracycline degradation under sunlight versus benchmarks,with treated water supporting Escherichia coli survival and wheat growth.This study provides a design strategy for the accumulation of long-lived holes on semiconductor photocatalysts.展开更多
The effects and rules of the dimensionless parameterξon neutrino annihilation v+v→e^(-)+e^(+)dominated gamma-ray bursts are analysed and investigated within the context of black holes in asymptotic safety.We also co...The effects and rules of the dimensionless parameterξon neutrino annihilation v+v→e^(-)+e^(+)dominated gamma-ray bursts are analysed and investigated within the context of black holes in asymptotic safety.We also computationally model photon orbits around black holes,as photons and neutrinos have the same geodesic equations near black holes.We show that the black hole shadow radius decreases with increasingξ.Calculations are made to determine the temperature of the accretion disk surrounding the black hole and the ratio Q/Q_(Newt)of energy deposition per unit time and compared to that of the Newtonian scenario.The accretion disk temperature peaks at a higher temperature due to quantum gravity corrections,which increases the probability of neutrino emission from the black hole.It is interesting to note that larger quantum gravity effects cause the ratio value to significantly decline.In the neutrinoantineutrino annihilation process,the energy deposition rate is sufficient even while the energy conversion is inhibited because of quantum corrections.Gamma-ray bursts might originate from the corrected annihilation process.Additionally,we examine the derivative dQ/dr about the star radius r.The findings demonstrate that the ratio is lowered by the black hole's quantum influence.The neutrino pair annihilation grows weaker the more prominent the influence of quantum gravity.展开更多
Einstein aimed to find a unified theoretical model to explain various interactions in nature,and the relationship between gravitational and electric fields was particularly important.For the first time,this paper prov...Einstein aimed to find a unified theoretical model to explain various interactions in nature,and the relationship between gravitational and electric fields was particularly important.For the first time,this paper provides the internal relationship equations of the electric and magnetic fields.Further,the relationship between the magnetic and gravity fields is analyzed,and the relationship equations of the electric,magnetic,and gravity fields are established.On this basis,a general formula for calculating the radius of charged particles is derived.Simultaneously,we also discussed and made predictions on black holes,providing convenience for future research and experimental detection.展开更多
基金supported by the National Natural Science Foundation of China(61904053,22279033)the National Key Research and Development Program of China(2023YFB4204502)+2 种基金the 111 Project(B16016)the Fundamental Research Funds for the Central Universities(2025MS043)the Special Foundation for Carbon Peak Carbon Neutralization Technology Innovation Program of Jiangsu Province(BE2022026).
文摘Molecular tailoring of self-assembled hole-transporting monolayers(SAMs)has been proven as an efficient approach for improving the device performance of inverted perovskite solar cells.Herein,a novel SAM with extended conjugation is designed and synthesized,named NaPh-4PACz.Compared to Ph-4PACz,NaPh-4PACz exhibits a larger adsorption energy with the ITO substrate,enabling the formation of a more uniform and dense film,thereby preventing direct contact between the perovskite and ITO.Additionally,NaPh-4PACz also has a stronger interaction with the perovskite,which can reduce buried interface defects and suppress non-radiative recombination.Consequently,NaPh-4PACz-based devices achieved a power conversion efficiency of 25.48%due to their interfacial“adhesive”ability.Importantly,the stability of the NaPh-4PACz-based devices was significantly improved.
基金financially supported by the CITIC niobium steel development award Fund(M1656-2021)Central Iron and Steel Research Institute for its independent research and development fund(No.21G62460ZD).
文摘Increasing the hole expansion ratio is significant for developing high formability parts.Hole expansion tests were carried out on low carbon hot-rolled steel containing 0.11%Ti,0.072%Ti–0.03%Nb and 0.097%Ti–0.059%Nb,respectively.The effects of microstructure,texture,crack propagation behavior and second phase precipitation behavior on hole expansion ratio were investigated.The precipitation behavior of TiC and(Ti,Nb)C in austenite and ferrite in three groups of steel samples was calculated theoretically.The results showed that the hole expansion ratios of 0.11Ti,0.072Ti–0.03Nb and 0.097Ti–0.059Nb test steels were 51.73%,51.17%and 66.24%following simulated coiling at 600℃,respectively.The microstructure was mainly polygonal ferrite with a small amount of pearlite.The grain refinement of 0.097Ti–0.059Nb test steel and the low texture ratio of{110}//ND improved the hole expansion ratio.The low overall hole expansion ratio was due to the microstructure inhomogeneity.The microstructure uniformity was improved by the quenching and tempering treatment,and the hole expansion ratio of the three test steels was greatly increased.The fastest precipitation temperatures in the austenitic region of 0.11Ti,0.072Ti–0.03Nb and 0.097Ti–0.059Nb test steels were 880,860 and 830℃,while those in the ferrite region were 680,675 and 675℃,respectively.The addition of Nb element increased the volume free energy,so that the critical core size of the nucleation on the dislocation line increased,resulting in the decrease in the fastest precipitation temperature.
文摘In this work,the influences of surface layer slurry at different temperatures(10℃,14℃,18℃,22℃)on wax patterns deformation,shrinkage,slurry coating characteristics,and the surface quality of the casting were investigated by using a single factor variable method.The surface morphologies of the shell molds produced by different temperatures of the surface(first)layer slurries were observed via electron microscopy.Furthermore,the microscopic composition of these shell molds was obtained by EDS,and the osmotic effect of the slurry on the wax patterns at different temperatures was also assessed by the PZ-200 Contact Angle detector.The forming reasons for the surface cracks and holes of thick and large ZTC4 titanium alloy by investment casting were analyzed.The experimental results show that the surface of the shell molds prepared by the surface layer slurry with a low temperature exhibits noticeable damage,which is mainly due to the poor coating performance and the serious expansion and contraction of wax pattern at low temperatures.The second layer shell material(SiO_(2),Al_(2)O_(3))immerses into the crack area of the surface layer,contacts and reacts with the molten titanium to form surface cracks and holes in the castings.With the increase of the temperature of surface layer slurry,the damage to the shell surface tends to weaken,and the composition of the shell molds'surface becomes more uniform with less impurities.The results show that the surface layer slurry at 22℃is evenly coated on the surface of the wax patterns with appropriate thickness,and there is no surface shell mold rupture caused by sliding slurry after sand leaching.The surface layer slurry temperature is consistent with the wax pattern temperature and the workshop temperature,so there is no damage of the surface layer shell caused by expansion and contraction.Therefore,the shell mold prepared by the surface layer slurry at this temperature has good integrity,isolating the contact between the low inert shell material and the titanium liquid effectively,and the ZTC4 titanium alloy cylinder casting prepared by this shell mold is smooth,without cracks and holes.
基金supported by the National Natural Science Foundation of China(62104059,12104126,61935016,52173153)Nature Science Foundation of Hebei Province(F2021202044)the Science Research Project of Hebei Education Department(ZD2021031)。
文摘The hole transport layer(HTL)-free carbon-based perovskite solar cells(C-PSCs)are promising for commercialization owing to their excellent operational stability and simple fabrication process.However,the power conversion efficiencies(PCE)of C-PSCs are inferior to the metal electrode-based devices due to their open-circuit voltage(V_(oc))loss.Herein,time-resolved confocal photoluminescence microscopy reveals that grain boundary defects at the perovskite/carbon interface are very likely to function as nonradiative recombination centers in HTL-free C-PSCs.A versatile additive Li_(2)CO_(3)is used to modify the conformal tin oxide electron transport layer for HTL-free C-PSCs.Li_(2)CO_(3)modification can result in enhanced charge extraction and optimized energy alignment at electron transport layer/perovskite interface,as well as suppressed defects at perovskite top surface due to Li_(2)CO_(3)-induced formation of PbI_(2)crystallites.Such dual interfacial passivation ultimately leads to significantly improved Voc up to 1.142 V,which is comparable to the metal electrode-based devices with HTL.Moreover,a record-high PCE of 33.2%is achieved for Li_(2)CO_(3)-modified C-PSCs under weak light illumination conditions,demonstrating excellent indoor photovoltaic performance.This work provides a practical approach to fabricate low-cost,highly efficient carbon-based perovskite solar cells.
基金National Natural Science Foundation of China under Grant Nos.52078386 and 52308496SINOMACH Youth Science and Technology Fund under Grant No.QNJJ-PY-2022-02+2 种基金Young Elite Scientists Sponsorship Program under Grant No.BYESS2023432Fund of State Key Laboratory of Precision Blasting and Hubei Key Laboratory of Blasting Engineering,Jianghan University under Grant No.PBSKL2023A9Fund of China Railway Construction Group Co.,Ltd.under Grant No.LX19-04b。
文摘Strong surface impact will produce strong vibration,which will pose a threat to the safety of nearby buried pipelines and other important lifeline projects.Based on the verified numerical method,a comprehensive numerical parameter analysis is conducted on the key influencing factors of the vibration isolation hole(VIH),which include hole diameter,hole net spacing,hole depth,hole number,hole arrangement,and soil parameters.The results indicate that a smaller ratio of net spacing to hole diameter,the deeper the hole,the multi-row hole,the hole adoption of staggered arrangements,and better site soil conditions can enhance the efficiency of the VIH barrier.The average maximum vibration reduction efficiency within the vibration isolation area can reach 42.2%.The vibration safety of adjacent oil pipelines during a dynamic compaction projection was evaluated according to existing standards,and the measurement of the VIH was recommended to reduce excessive vibration.The single-row vibration isolation scheme and three-row staggered arrangement with the same hole parameters are suggested according to different cases.The research findings can serve as a reference for the vibration safety analysis,assessment,and control of adjacent underground facilities under the influence of strong surface impact loads.
基金Project(52274086)supported by the National Natural Science Foundation of ChinaProject(2024KJH069)supported by the Shandong Provincial Youth Innovation and Technology Support Program,ChinaProject(tstp20221126)supported by the Project of Taishan Scholar in Shandong Province,China。
文摘Large-diameter drilling method is a prevalent method for preventing and controlling rock burst,and the spacing between the large-diameter drilling hole and anchoring hole is a critical factor influencing the roadway stability and relief effectiveness.In this study,a mechanical model for optimal matching between the large-diameter drilling hole and anchoring hole was established following the principle of synergistic control.The influence of large-diameter drilling hole diameter on the optimal spacing under the synergistic relief effect was investigated by integrating theoretical analysis,numerical simulation,and field practice.The results suggest that the hole spacing achieved a synergistic effect in a certain range when the optimal hole spacing increased linearly with the hole diameter.For instance,when the anchoring hole diameter was 20 mm,an increase in the aperture ratio from 5 to 10 brought about an increase in the optimal spacing from 0.25 m to 0.45 m.Additionally,the vertical stress between the large-diameter drilling hole and anchor hole increased nonlinearly under the condition of constant pore ratio but varying hole spacing.Both excessively small and excessively large hole spacings were detrimental to the pressure relief effect.In the engineering practice,optimizing the hole spacing from 0.55 m to 0.45 m in the 1208 working face contributed to reducing coal body drilling cuttings and the roadway moving quantity by 33%and 19.2%,respectively.This demonstrates that the pressure relief-support reinforcement synergistic effect should be fully considered in optimization design.
基金supported by the National Natural Science Foundation of China(52174003,52374008).
文摘The complex vibration directly affects the dynamic safety of drill string in ultra-deep wells and extra-deep wells.It is important to understand the dynamic characteristics of drill string to ensure the safety of drill string.Due to the super slenderness ratio of drill string,strong nonlinearity implied in dynamic analysis and the complex load environment,dynamic simulation of drill string faces great challenges.At present,many simulation methods have been developed to analyze drill string dynamics,and node iteration method is one of them.The node iteration method has a unique advantage in dealing with the contact characteristics between drill string and borehole wall,but its drawback is that the calculation consumes a considerable amount of time.This paper presents a dynamic simulation method of drilling string in extra-deep well based on successive over-relaxation node iterative method(SOR node iteration method).Through theoretical analysis and numerical examples,the correctness and validity of this method were verified,and the dynamics characteristics of drill string in extra-deep wells were calculated and analyzed.The results demonstrate that,in contrast to the conventional node iteration method,the SOR node iteration method can increase the computational efficiency by 48.2%while achieving comparable results.And the whirl trajectory of the extra-deep well drill string is extremely complicated,the maximum rotational speed downhole is approximately twice the rotational speed on the ground.The dynamic torque increases rapidly at the position of the bottom stabilizer,and the lateral vibration in the middle and lower parts of drill string is relatively intense.
基金the Deanship of Research and Graduate Studies at King Khalid University for funding this work through Large Research Project under Grant No.RGP2/539/45。
文摘We assume exponential corrections to the entropy of 5D charged Ad S black hole solutions,which are derived within the framework of Einstein-Gauss-Bonnet gravity and nonlinear electrodynamics.Additionally,we consider two distinct versions of 5D charged Ad S black holes by setting the parameters q→0 and k→0(where q represents the charge,and k is the non-linear parameter).We investigate these black holes in the extended phase space,where the cosmological constant is interpreted as pressure,demonstrating the first law of black hole thermodynamics.The focus extends to understanding the thermal stability or instability,as well as identifying first and second-order phase transitions.This exploration is carried out through the analysis of various thermodynamic quantities,including heat capacity at constant pressure,Gibbs free energy(GFE),Helmholtz free energy(HFE),and the trace of the Hessian matrix.In order to visualize phase transitions,identify critical points,analyze stability and provide comprehensive analysis,we have made the contour plot of the mentioned thermodynamic quantities and observed that our results are very consistent.These investigations are conducted within the context of exponentially corrected entropies,providing valuable insights into the intricate thermodynamic behavior of these 5D charged Ad S black holes under different parameter limits.
基金supported by the International Partnership Program of the Chinese Academy of Sciences (Grant No.025GJHZ2023106GC)。
文摘Primordial black holes(PBHs) offer a compelling candidate for dark matter. The production of PBHs through well-tested and accepted physical processes is highly worthy of investigation. This work highlights the role of turbulences in the very early universe in sustaining intense and persistent fluctuations in energy or mass density,which could provide a natural mechanism for PBH formation in the primordial universe. We analyze the mass range and abundance of PBHs produced in the magnetohydrodynamic turbulence induced by the electroweak phase transition. Remarkably, we find that the mass range of the produced PBHs falls within the most viable“asteroid mass” window from the present-day observations, and within natural parameter regions their abundance can be sufficiently large. These findings suggest that PBHs produced during magnetohydrodynamic turbulence in the very early universe may comprise a dominant part of dark matter.
基金supported by the National Postdoctoral Fellowship of the Science and Engineering Research Board(SERB),Department of Science and Technology(DST),Government of India,File No.PDF/2021/003491。
文摘The photon region surrounding a black hole is crucial for distant observers to receive the emitted spectrum from its vicinity.This paper investigates the optical features of a regular spinning antide Sitter(AdS)black hole.These kinds of black holes hold deviation parameter k,and the cosmological constant A including their mass M and spin a.The cosmological parameter depends on the curvature radius by A=-3/l~2.We investigate the structure of geodesics for unstable circular orbits of photons as observed by an observer at specific Boyer-Lindquist coordinates(r_(O),v_(O))in the region between the outer and cosmological horizon,so-called the domain of outer communication.Our investigations include the analysis of three observables from its shadow plot:the black hole shadow radius(R_(s)),the distortion of the black hole(δ_(s)),and shadow area A.With the help of these observables,we calculate the angular diameter of the apparent size of the shadow.The shadows cast by spinning regular spacetimes are smaller compared to those produced by rotating black holes in both general relativity and regular spacetimes.We also calculate the rate at which energy is emitted from the black hole.
文摘AIM:To evaluate whether fluid-air exchange is an effective treatment for unclosed macular hole(MH)after primary vitrectomy.METHODS:This retrospective study included patients with an unclosed MH within 1–2wk after vitrectomy.Patients were divided into the vitrectomy,fluid-air exchange,and observation groups according to the secondary treatment.The anatomical outcomes and postoperative visual acuity were recorded.RESULTS:The analysis included 25 eyes in 25 patients(16 females)aged 37–74y(vitrectomy group,n=10;fluid-air exchange group,n=9;observation group,n=6).Closure rate after secondary treatment was 100%in the vitrectomy group,88.9%in the fluid-air exchange group and 33.3%in the observation group.Optical coherence tomography images obtained at the last follow-up revealed that continuity of the external limiting membrane(ELM)was significantly more common(P=0.004)in the fluid-air group(8/9 eyes,88.9%)than in the vitrectomy group(2/10 eyes,20.0%)and that macular morphology was better in the fluid-air group than in the vitrectomy group.No serious complications were observed after secondary treatment.CONCLUSION:Fluid-air exchange is an alternative option to repeat vitrectomy for patients with an unclosed MH after initial vitrectomy with elevated macular edge.
基金supported in part by the National Natural Science Foundation of China(grant Nos.11973025,12205139,12303079,12475057,and 12481540180)the Natural Science Foundation of Hunan Province(grant No.2022JJ40347)。
文摘The gravitational deflection of light signals restricted in the polar-axis plane of a moving Kerr–Newman(KN)black hole with a constant velocity along the polar axis is studied within the second post-Minkowskian(PM)approximation.For this purpose,the Lorentz boosting technique is adopted to obtain the exact metric of a moving KN black hole with an arbitrary constant velocity in Kerr–Schild coordinates for the first time.Based on the weak field limit of the exact metric,we then derive the equations of motion of test particles constrained in the polaraxis plane of a moving KN source whose velocity is along the polar axis and collinear with its angular momentum.An iterative technique is utilized subsequently in the calculations of the null deflection angle up to the 2PM order caused by the moving lens,and this deflection angle is found to be spin-independent.Finally,we discuss the influence of the motion of the lens on the gravitational deflection and estimate the possibility of detecting this kinematical effect.Our work might be helpful for future astronomical observations.
基金financially supported by the National Key Technology R&D Program of China(No.2021YFB3500801)
文摘Enhancing the activity of photocatalysts is a critical challenge for improving the photocatalytic degradation of contaminated wastewater.Here,a novel Ce single-atom-doped titanate nanotube photocatalyst(CeH_(2)Ti_(2)O_(5)·H_(2)O)was successfully synthesized using a onepot solvothermal method.Degradation experiments revealed that the optimal Ce doping ratio was 1.0%.The ultraviolet-visible diffuse reflectance spectroscopy results showed that the bandgap of the Ce-doped sample decreased from 3.02 to 2.87 eV,enhancing the absorption in the visible spectral range.At the same time,the BrunauerEmmett-Teller specific surface area increased from 63.68 to 88.95 m^(2)g^(-1).The 1.0%Ce-H_(2)Ti_(2)O_(5)·H_(2)O(HTC_(1))could degrade 99.04%of 100 mg L-1rhodamine B(RhB)after 40 min of visible-light irradiation.The degradation efficiency decreased by only 21.24%after five cycles.The results of free-radical quenching and electron spin resonance spectroscopy analyses indicated that HTC_(1)achieved efficient degradation of RhB through a direct hole oxidation mechanism.Compared with pure protonated titanate nanotubes(H_(2)Ti_(2)O_(5)·H_(2)O),HTC_(1)had a higher specific surface area,more electron traps,narrower bandgap,longer hole lifetime,and suppressed photogenerated charge recombination rate owing to the Ce single-atom doping.
基金Project(52409128)supported by the National Natural Science Foundation of ChinaProject(SDGZK2425)supported by the Opening Fund of State Key Laboratory of Intelligent Construction and Healthy Operation and Maintenance of Deep Underground Engineering,China。
文摘The shape of underground chambers in deep mining varies due to their geological environment and intended use,which results in different failure modes under the influence of mining activities.However,the effect of chamber shape on the mechanism of structural integrity under dynamic load is still unclear.In this paper,granite samples with circular(C),rectangular(R),long ellipse(EL),and short ellipse(ES)holes were prepared.The dynamic mechanical response and cracking mechanism of granite were systematically analyzed using the split Hopkinson pressure bar(SHPB)test system and the hybrid finite and discrete element method(HFDEM).The results indicate that the dynamic strengths of granite with EL and ES represent the maximum and minimum values within the range of close strain rates,respectively.When EL granite is subjected to dynamic load,the axial stress concentration(in the load direction)is weak,and the transverse stress shows relative dispersion,which is the primary reason for its highest dynamic strength.The failure of granite with various holes primarily involves a tensile-shear mixed fracture,with relatively few pure typeⅡcracks.The chamber’s transverse span is the primary factor influencing the distribution range of the fracture area.
基金supported by the special foundation for Guangxi Ba Gui Scholars and Junwu Scholars of Guangxi Universitysupported by the National Natural Science Foundation of China(Grant No.12475049)。
文摘Using the Melnikov method,the phenomenon of thermal chaos under periodic perturbation in the extended phase space of the modified thermodynamics of Kerr-AdS black holes is investigated.On the(P,v)section in the extended phase space,it is shown that temporal chaos will appear in the unstable spinodal region when the perturbation amplitude is larger than critical value δ_(c)^(Pv).We findδ_(c)^(Pv) is monotonically decreasing with respect to the angular momentum parameter a,which implies a large a leads to chaotic behavior more easily under time-periodic thermal perturbation.Similarly,on the(Ω_(H),J)section,we show there exists a critical value δ_(c)^(ΩJ) which depends on the cosmological parameter l=√-3/Λ.When the perturbation amplitude exceeds δ_(c)^(ΩJ),temporal chaos occurs.As l increases,chaos becomes easier.For spatial perturbation,chaos always exists irrespective of perturbation amplitude in both the(P,v)section and(Ω_(H),J)section.
基金supported by the National Natural Science Foundation of China(Grant no.52260009,U2102211)Yunnan Fundamental Research Projects(Grant no.202201BE070001-044,202401BE070001-025)+1 种基金Yunnan Fundamental Research Projects(Grant no.202301AT070405)the Yunnan Major Scientific and Technological Projects(No.202402AO370002).
文摘Active holes outperform photoelectron-mediated oxygen reduction in degrading recalcitrant organics under anaerobic conditions,yet their utilization is limited by rapid charge recombination.This challenge was addressed through Cu-based yolk-double-shell microspheres(Cu/Cu_(2)O@C-2shell)engineered via heterogeneous contraction and reduction strategies.Work function analyses confirm Schottky junction-driven electron transfer from Cu_(2)O to Cu,generating an internal electric field that suppresses backflow.Density functional theory reveals Cu-mediated enhancement of near-Fermi states(Cu 3d orbitals)and a directional Cu_(2)O→Cu→C electron pathway,spatially isolating holes in Cu_(2)O.Finite-difference time-domain simulations reveal light-induced electric field gradients in the dual-shell architecture:Cu^(0)-mediated localized surface plasmon resonance effect enhances surface field concentration,while hierarchical interfaces create an outward-to-inward gradient,directing electron migration inward and stabilizing oxidative holes at the surface.The optimized(Cu/Cu_(2)O)@C-2shell exhibits 38-fold higher tetracycline degradation under sunlight versus benchmarks,with treated water supporting Escherichia coli survival and wheat growth.This study provides a design strategy for the accumulation of long-lived holes on semiconductor photocatalysts.
基金partly supported by the Shanghai Key Laboratory of Astrophysics 18DZ2271600。
文摘The effects and rules of the dimensionless parameterξon neutrino annihilation v+v→e^(-)+e^(+)dominated gamma-ray bursts are analysed and investigated within the context of black holes in asymptotic safety.We also computationally model photon orbits around black holes,as photons and neutrinos have the same geodesic equations near black holes.We show that the black hole shadow radius decreases with increasingξ.Calculations are made to determine the temperature of the accretion disk surrounding the black hole and the ratio Q/Q_(Newt)of energy deposition per unit time and compared to that of the Newtonian scenario.The accretion disk temperature peaks at a higher temperature due to quantum gravity corrections,which increases the probability of neutrino emission from the black hole.It is interesting to note that larger quantum gravity effects cause the ratio value to significantly decline.In the neutrinoantineutrino annihilation process,the energy deposition rate is sufficient even while the energy conversion is inhibited because of quantum corrections.Gamma-ray bursts might originate from the corrected annihilation process.Additionally,we examine the derivative dQ/dr about the star radius r.The findings demonstrate that the ratio is lowered by the black hole's quantum influence.The neutrino pair annihilation grows weaker the more prominent the influence of quantum gravity.
基金supported by the Hunan Provincial Natural Science Foundation(No.2016JJ3034).
文摘Einstein aimed to find a unified theoretical model to explain various interactions in nature,and the relationship between gravitational and electric fields was particularly important.For the first time,this paper provides the internal relationship equations of the electric and magnetic fields.Further,the relationship between the magnetic and gravity fields is analyzed,and the relationship equations of the electric,magnetic,and gravity fields are established.On this basis,a general formula for calculating the radius of charged particles is derived.Simultaneously,we also discussed and made predictions on black holes,providing convenience for future research and experimental detection.
